Ingredient Contains A -c-x-c- Group Wherein X Is A Chalcogen Atom And None Of The C Atoms Bonded To The Chalcogen Are Double-bonded To An Additional Chalcogen Atom Patents (Class 521/114)
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Patent number: 11466194Abstract: Certain foamed gel treatment fluids and methods of using the treatment fluids in wellbores penetrating subterranean formations are provided. In one embodiment, the treatment fluids comprise: an aqueous base fluid, a gas, a plurality of particulates, and a plurality of swellable particles each comprising a material having a first monomer, a second monomer, and a third monomer comprising a foamable surfactant. In one embodiment, the methods comprise: preparing a treatment fluid comprising an aqueous base fluid and a swellable particle that comprises a material having a first monomer, a second monomer, and a third monomer comprising a foamable surfactant; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and blending the treatment fluid while in the wellbore to form a foamed gel.Type: GrantFiled: February 8, 2021Date of Patent: October 11, 2022Assignee: Halliburton Energy Services, Inc.Inventors: Sairam Eluru, Rajender Salla
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Patent number: 11123364Abstract: A medical composition and devices made from the composition for the delivery of extracts obtained from Boswellia genus, similar compounds synthetically derived, and in particular derivatives of triterpenes is disclosed. The medical device may be implantable, or alternatively a device which contacts the interior of a mammalian body. The medical device may be comprised, of or present an absorbable component containing Boswellia derivatives, or an eluting component. When administered into a particular body site, the Boswellia component may be released substantially and immediately, released slowly, or not released, into the body and residing actively on the medical device surface.Type: GrantFiled: June 21, 2012Date of Patent: September 21, 2021Assignee: BVW Holding AGInventors: Michael T. Milbocker, Lukas von Bluecher
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Patent number: 10988566Abstract: Additives for making polyurethanes are disclosed. The additives are based on combining specific carboxylic acids or carboxylic di-acids together with a gelling catalysts obtained when mixing an isocyanate-reactive tertiary amine catalysts with dimethyl tin di carboxylate salts and/or dimethyltin mercaptide salts.Type: GrantFiled: September 19, 2018Date of Patent: April 27, 2021Assignee: Evonik Operations GmbHInventors: Juan Jesus Burdeniuc, Stephan Wendel, Christian Brandl, Torsten Panitzsch, Renee Jo Keller
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Patent number: 10865285Abstract: Two-component formulation for producing open-cell flexible foams having compressive strength of ?1N/cm2, contained in 2-component aerosol can with crosslinker sleeve which can be opened prior to deploying formulation from aerosol can wherein the contents thereof enter aerosol can, wherein first component is present in aerosol can and second component that is reactive to first component is present separately in crosslinker sleeve and wherein aerosol can includes prepolymer composed of 25-35% by weight MDI and 40-55% by weight of polyol mixture having free isocyanate groups, and 10-21% by weight of propellant gas mixture and crosslinker sleeve includes 4-10% by weight of crosslinker mixture, wherein weight data are based on weight of formulation.Type: GrantFiled: July 28, 2017Date of Patent: December 15, 2020Assignee: SIKA TECHNOLOGY AGInventor: Natalie Wagner
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Patent number: 10836939Abstract: Disclosed is a one-part, atmospheric curing, polyurethane adhesive composition that includes a polyurethane prepolymer that includes a reaction product of a polyol component and an isocyanate component, the polyol component comprising an unsaturated fatty acid esterified polyol comprising a reaction product of a first polyol and at least one of an ethylenically unsaturated oil and an ethylenically unsaturated fatty acid, the first polyol comprising at least three hydroxyl groups, and a % NCO of from at least 4% by weight to no greater than 7% by weight based on the weight of the prepolymer, the adhesive composition exhibiting a viscosity of no greater than 15,000 centipoise at 60° C., and a T-peel value of greater than 40 grams per 25 millimeter in no greater than 4 hours, a method of making a laminate, and a laminate that includes a one-part, atmospheric curing, polyurethane adhesive composition.Type: GrantFiled: January 19, 2017Date of Patent: November 17, 2020Assignee: H.B. Fuller CompanyInventors: Anthony J. Ostlund, Dorian P. Nelson, Wayne G. Eklund, Marlen A. Valverde
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Patent number: 10316132Abstract: A polyurethane elastomer, e.g., for use in polyurethane mats, includes the reaction product of an isocyanate component that includes at least one isocyanate and an isocyanate-reactive component that includes (a) a first polyol component including from 40 wt % to 90 wt % of at least one polyether polyol having an average hydroxyl functionality that is greater than 2.5 and a number average molecular weight from 300 g/mol to 1,500 g/mol; (b) a second polyol component including from 2 wt % to 20 wt % of at least one ethylene oxide capped polyoxypropylene-polyoxyethylene polyol having an average hydroxyl functionality greater than 1.5 and less than 4.0, a number average molecular weight from 4,000 g/mol to 6,000 g/mol, and from 60% to 85% of a primary hydroxyl group content; and (c) a third polyol component including from 1 wt % to 20 wt % of at least one polyoxypropylene polyol having an average hydroxyl functionality greater than 1.5 and less than 4.Type: GrantFiled: September 2, 2015Date of Patent: June 11, 2019Assignees: Dow Global Technologies LLC, Dow Italia Divisione Commerciale SRLInventors: Carlo Cocconi, Giuseppe Lista, Silvia Scussolin
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Patent number: 10118985Abstract: Embodiments of the present technology may include an open cell spray polyurethane foam. The foam may include a polymer. The polymer may formed by the polymerization of a reaction product of (1) a saccharide with an epoxide and (2) an isocyanate. The reaction product may have greater than 25 weight percent and less than 99 weight percent of the saccharide. The foam may exhibit a fire retardancy sufficient to pass flame tests in accordance with Appendix X and/or ASTM E-4.Type: GrantFiled: March 18, 2015Date of Patent: November 6, 2018Assignee: Johns ManvilleInventors: Scott Snider, Lance Wang, Jawed Asrar
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Patent number: 9926403Abstract: Process for preparing rigid polyurethane or urethane-modified polyisocyanurate foams from polyisocyanates and polyfunctional isocyanate-reactive compounds in the presence of blowing agents wherein the polyfunctional isocyanate-reactive compounds comprise a polyether polyol having a hydroxyl number of between 50 and 650 mg KOH/g obtained by reacting a polyfunctional initiator first with ethylene oxide and subsequently with propylene oxide wherein the propoxylation degree is between 0.33 and 2 mole propylene oxide per active hydrogen atom in the initiator and wherein the molar ratio of ethylene oxide to propylene oxide in said polyether polyol is at least 2.Type: GrantFiled: January 20, 2015Date of Patent: March 27, 2018Assignee: HUNTSMAN INTERNATIONAL LLCInventors: Kristof Dedecker, Luca Binaghi, Mauro Corio
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Patent number: 9718225Abstract: Injection molded parts with a small dimension that exhibit high heat resistance are described. Thermoplastic compositions that can be utilized to form the injection molded parts are described. The thermoplastic composition includes a polyarylene sulfide and a crosslinked impact modifier. The thermoplastic composition can also include siloxane polymers, thermoplastic elastomers, or other additives that can further improve the characteristics of the injection molded parts.Type: GrantFiled: August 25, 2014Date of Patent: August 1, 2017Assignee: Ticona LLCInventors: Rong Luo, Kent Miller, Xinyu Zhao, Xiaoyan Tu
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Patent number: 9676896Abstract: Polyurethane foams which are highly flame resistant are described, as well as the production of such polyurethane foams by the reaction between a natural polyol, such as sucrose or a blend of mono- or disaccharides in place of the standard hydrocarbon-based polyol component, a polyisocyanate and water in the presence of a suitable polyurethane forming catalyst and a non-halogenated flame retardant, and optionally one or more components such as surfactants and/or emulsifiers. The resultant polyurethane foam has a bio-based solid content ranging from about 17% to 30%, may be formulated in a variety of foam densities for a variety of applications, and exhibits a high degree of fire and burn resistance, as exhibited by the flame spread index, flash over resistance determination, and the smoke spread values.Type: GrantFiled: February 28, 2014Date of Patent: June 13, 2017Assignee: INNOVATIVE URETHANE, LLCInventors: Joseph Mooney, Thomas Rathke, Jose Luna, Douglas Svenson
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Patent number: 9593135Abstract: The present invention relates to a composition comprising (A) an isocyanate of formula (I) OCN-A-SiR1R2R3 (I), wherein A is straight-chain, branched, substituted and/or unsubstituted aliphatic hydrocarbyl of 1 to 12 carbon atoms or substituted or unsubstituted cycloaliphatic hydrocarbyl of 4 to 18 carbon atoms, wherein R1 is selected from the group comprising —O—Ralk, wherein R2 and R3 are each independently selected from the group of substituents comprising —Ralk and —O—Ralk, and wherein —Ralk is hydrocarbyl of 1 to 6 carbon atoms, and B) a Bronstedt or Lewis acid or a compound which releases a Bronstedt or Lewis acid at room temperature; and also to a process for producing a stabilized alkoxysilane-containing isocyanate comprising the step of adding a Lewis or Bronstedt acid or a compound which releases a Bronstedt or Lewis acid at room temperature to an alkoxysilane-containing isocyanate.Type: GrantFiled: September 25, 2013Date of Patent: March 14, 2017Assignee: EVONIK DEGUSSA GmbHInventors: Emmanouil Spyrou, Manfred Kreczinski, Holger Loesch, Andrea Thesing, Lars Hellkuhl
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Patent number: 9382399Abstract: The present invention provides a foam composition comprising a polyol, an isocyanate, a first catalyst capable of accelerating a reaction between the polyol and the isocyanate and a second catalyst capable of initiating a reaction between the polyol and the isocyanate at a rate slower than the first catalyst. There is also provided a method for preparing the foam composition.Type: GrantFiled: May 11, 2012Date of Patent: July 5, 2016Assignee: MAS INNOVATION (PRIVATE) LIMITEDInventors: Gaya Keerthi Liyanage, Ranil Kirthi Vitarana
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Patent number: 9254546Abstract: A chemical mechanical polishing machine includes a polishing head assembly including a polishing head body and a membrane disposed at a bottom of the polishing head body. The bottom surface of the membrane includes a hydrophobic area and a hydrophilic area.Type: GrantFiled: October 3, 2013Date of Patent: February 9, 2016Assignee: SAMSUNG ELECTRONICS CO., LTD.Inventors: In-Kwon Kim, Kyung-Hyun Kim, Ki-Jong Park, Ki-Ho Bae, Jong-Heun Lim
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Publication number: 20150133573Abstract: The invention relates to a method for producing foamed molded bodies comprising the steps of A) providing a mold, and B) introducing a foam-forming reaction mixture into the mold under variable pressure of injection, wherein the method is characterized in that the foam-forming reaction mixture has a fiber time of ?20 s to ?60 s.Type: ApplicationFiled: April 26, 2013Publication date: May 14, 2015Inventors: Reinhard Albers, Hans-Guido Wirtz, Michael Loof, Andreas Pielasch
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Publication number: 20150028247Abstract: A rigid polyurethane or polyisocyanurate foam includes 1 to 50 weight percent of a particulate poly(phenylene ether) having a mean particle size of 1 to 40 micrometers. The particulate poly(phenylene ether) imparts reduced flammability and reduced water absorption to the foam. The foam is useful as a thermally insulating material in articles including domestic appliances, building materials, tanks, pipelines, heating pipes, cooling pipes, cold stores, and refrigerated vehicles.Type: ApplicationFiled: July 23, 2013Publication date: January 29, 2015Inventor: Edward Norman Peters
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Publication number: 20140303269Abstract: Disclosed is a method of preparing a bio-based thermosetting foam material with improved properties, in particular improved flame retardant properties, which method includes the steps of a) producing a prepolymer by condensation of at least one phenolic compound and formaldehyde in a ratio of 1:1.0 to 3.0 using 0.15 to 5 wt % of an alkaline catalyst in the temperature range of 50 to 100° C. until the refractive index of the reaction mixture is 1.4990 to 1.5020, b) adding 2 to 40 wt % of at least one natural polyphenol at a temperature of 50 to 100° C., c) adding 2 to 10 wt % of one or more emulsifiers and mixtures thereof, d) adding 2 to 10 wt % of one or more foaming agents and mixtures thereof and e) adding 10 to 20 wt % of a curing agent and f) curing. All wt % being related to the amount of the raw materials used.Type: ApplicationFiled: November 14, 2012Publication date: October 9, 2014Applicant: Momentive Specialty Chemicals Inc.Inventors: Daniel Dahlhaus, Gunda Kuhlmann, Rosel Bölke
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Publication number: 20140288201Abstract: A one component precursor for the polymeric foam (OCF) composition comprising a very low amount of free monomeric MDI. The present OCF composition may be obtained without any free MDI removal step, and without the addition of extra solvent to compensate for the substantially lower amount of free MDI, compared with traditional compositions. The present composition comprises a source of free NCO of functionality of at least 2.6, a tri- or higher functional alcohol, all polyols being characterized by a rather low molecular weight and at least a specific mono-functional alcohol as well as an isocyanate end-capped prepolymer of toluene diisocyanate (=end capped TDI). The OCF composition is suitable for being dispensed from a pressurized can with a blowing agent.Type: ApplicationFiled: January 26, 2012Publication date: September 25, 2014Inventors: Aster De Schrijver, Joao Moura Bordado, Georgi Goerigev
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Publication number: 20140242313Abstract: A cavity between inner and outer walls of an open-box-shaped mould is filled with a polyurethane reaction mixture, containing an isocyanate and an emulsion of an isocyanate-reactive composition with three polyols and a blowing agent, which is cured to a polyurethane containing polymer. The inner and outer wall are a fixed distance from one another and each wall comprises a bottom and sides. The mixture is fed through an inlet in the bottom of the outer wall. Before filling the cavity, the mould is turned downwards so that the mixture foams upwards, filling the cavity. The three polyols are polyether polyol obtained by adding an epoxy to carbohydrates or difunctional or higher-functional alcohols; polyether polyol obtained by adding an epoxy to an aromatic amine; and polyester polyether polyol obtained by adding an epoxy to the esterification product of an aromatic dicarboxylic acid derivative and a difunctional or higher-functional alcohol.Type: ApplicationFiled: February 20, 2014Publication date: August 28, 2014Applicant: BAYER MATERIALSCIENCE AGInventors: Stephanie VOGEL, Reinhard ALBERS, Michael LOOF, Frank OTTO
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Publication number: 20140228460Abstract: An interconnected microcellular material, a method for preparing said material using low-value waste from the paper industry, such as industrial lignin, and the use thereof for the production of items such as catalysts, filters or absorbent elements.Type: ApplicationFiled: September 27, 2012Publication date: August 14, 2014Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIQUE (CNRS), UNIVERSITE DE BORDEAUXInventors: Herve Deleuze, Claire Forgacz, Marc Birot
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Patent number: 8729146Abstract: A catalyst composition including a solution of at least one member selected from the group consisting of an alkali metal carboxylate and an alkaline earth metal carboxylate in a solvent which is nonreactive with the isocyanate groups of a polyisocyanate.Type: GrantFiled: June 14, 2005Date of Patent: May 20, 2014Assignee: Momentive Performance Materials Inc.Inventor: Vittorio Bonapersona
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Publication number: 20140066532Abstract: Polyurethane/polyisocyanurate foams having a NFPA 101 Class A rating (ASTM E-84) are produced from a foam-forming reaction mixture that includes: an organic polyisocyanate, an isocyanate-reactive composition that includes at least one polyether polyol or polyester polyol with a nominal hydroxyl functionality of at least 2.0, a blowing agent composition and at least one halogen-free flame retardant. The blowing agent composition includes: (1) up to 5% by weight, based on total weight of the foam-forming composition, of one or more hydrocarbons having an LEL less than 2% by volume in air; and/or (2) a hydrocarbon having an LEL greater than 2% by volume in air; and (3) up to 1% by weight, based on total weight of foam-forming composition, of water.Type: ApplicationFiled: September 6, 2012Publication date: March 6, 2014Applicant: Bayer MaterialScience LLCInventors: George G. Combs, Susan C. Pigott
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Patent number: 8642669Abstract: The invention relates to a foamable mixture which contains at least one alkoxysilane-terminated prepolymer and which can be produced of a) at least one alkoxysilane that was functionalized with isocyanate groups and that can be produced of at least one hydroxyfunctional and/or aminofunctional alkoxysilane and at least one diisocyanate or polyisocyanate, and b) at least one compound that contains at least one OH group, and at least one blowing agent, characterized in that the foamable mixture has a dynamic viscosity of 100 to 25,000 mPas, preferably 500 to 10,000 mPas, at 23° C. The invention further relates to a method for producing said foamable mixture. The foamable mixtures according to the invention are suitable for sealing, insulating and mounting joints, roof surfaces, windows and doors or for filling hollow spaces.Type: GrantFiled: January 20, 2011Date of Patent: February 4, 2014Assignee: Henkel AG & Co., KGaAInventors: Wilfried Huebner, Milan Sebestian, Christiane Kunze, Lars Zander, Johann Klein
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Publication number: 20140005288Abstract: A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst. The oxygen-containing amine catalyst may be, an alkanol amine, an ether amine, or a morpholine group. containing compound such as, 2.(2.dimethylaminoethoxy)ethanol or N.N.N?.trimethylaminoethylethanolamine. A stabilized thermosetting foam blend comprises: (a) a polyisocyanate and, optionally, isocyanate compatible raw materials; and (b) a polyol pre. mix composition. A method for stabilizing thermosetting foam blends comprises combining: (a) a polyisocyanate and, optionally, isocyanate compatible raw materials; and (b) a polyol pre. mix composition. A polyurethane or polyisocyanurate foam having uniform cell structure with little or no foam collapse comprises a mixture of: (a) a polyisocyanate and, optionally, one or more isocyanate compatible raw materials; and (b) a polyol pre-mix composition.Type: ApplicationFiled: March 6, 2012Publication date: January 2, 2014Applicant: Arkema Inc.Inventors: Benjamin Bin Chen, Joseph S. Costa, Laurent Abbas, Haiming Liu, Sri R. Seshadri
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Publication number: 20130316164Abstract: Combinations of gelatinous elastomer and polyurethane foam may be made by introducing a plasticized triblock copolymer resin and/or a diblock copolymer resin at least partially cured into gel particles into a mixture of polyurethane foam forming components including a polyol and an isocyanate. The plasticized copolymer resin is polymerized to form a cured gelatinous elastomer or gel, which is then reduced in size, for instance to give an average particle size of 10 millimeters or less. Polymerizing the polyol and the isocyanate forms polyurethane foam. The polyurethane reaction is exothermic and can generate sufficient temperature to at least partially melt the styrene-portion of the triblock copolymer resin thereby extending the crosslinking and in some cases integrating the triblock copolymer within the polyurethane polymer matrix. The gel component has higher heat capacity than polyurethane foam and thus has good thermal conductivity and acts as a heat sink.Type: ApplicationFiled: July 31, 2013Publication date: November 28, 2013Applicant: Peterson Chemical Technology, Inc.Inventors: Bruce W. Peterson, Mark L. Crawford
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Publication number: 20130310474Abstract: A polyurethane foam is prepared by combining a polyether triol with a hydroxyl value of from 25 to 30 and a molecular weight from 5000 to 7000 g/mol; a polyether diol with a hydroxyl value of from 25 to 30 and a molecular weight from 3000 to less than 5000 g/mol; a chain extender mixture including 1,4-butanediol and at least one of monoethylene glycol, hexanediol, neopentyl glycol, and isomers thereof; a copolymer polyether polyol having a styrene acrylonitrile solids content of at least 38 wt % and an average hydroxyl number of at least 23; an isocyanate component; and a blowing agent. It is particularly suitable for shoe sole applications, where it exhibits improvement in slip resistance under wet conditions when compared with some other polyether-polyurethane formulations.Type: ApplicationFiled: January 23, 2012Publication date: November 21, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Silvia Scussolin, Andrea Benvenuti
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Patent number: 8586642Abstract: An aerogel including a polymerization product of a first monomer selected from an aryl polyol compound including at least two aryl groups linked to each other by a linker, an aryl polyol compound including at least two aryl groups fused to each other, or a combination thereof, and a second monomer including a benzene substituted with at least two hydroxyl groups.Type: GrantFiled: March 25, 2011Date of Patent: November 19, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-Ho Park, Myung-Dong Cho, Kwang-Hee Kim, Sung-Woo Hwang
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Publication number: 20130245145Abstract: The present invention relates to an acrylamide-based mesoporous polymer and its preparation method, where the acrylamide-based mesoporous polymer is fabricated by a simple preparation method to have uniform minute pores controllable in pore size and thereby applicable to a wide variety of fields. The acrylamide-based mesoporous polymer includes at least one of a defined repeating unit and contains a plurality of pores having a diameter of 2.0 to 10.0 nm in the solid state.Type: ApplicationFiled: August 26, 2011Publication date: September 19, 2013Applicants: IUCF-HYU ( Industry-University Cooperation Foundation Hanyang Unversity), LG Chem, Ltd.Inventors: Yang-Kyoo Han, Je-Gwon Lee, Ji-soo Jeong, Dae-Won Sohn, Sung-Hwan Han, Hyun-Hoon Song, Kwan-Mook Kim
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Patent number: 8470902Abstract: A continuous pore elastomer featured by being made of a polyurethane, having a three dimensional network pore structure of which skeletons have an average thickness of 20 ?m or less and 80% or more of the skeletons have a thickness within the range of 2 to 20 ?m, having an apparent density of 0.2 to 0.4 g/cm3, containing a surfactant with a HLB value of 8 or more, and being capable of absorbing water instantly; a process for producing the continuous pore elastomer, comprising a step of extracting out the pore generation agent from the molding with water; and a water-absorbing roller and a swab obtained by using the continuous pore elastomer.Type: GrantFiled: November 22, 2005Date of Patent: June 25, 2013Assignee: Fushimi Pharmaceutical Company, LimitedInventors: Yoshiaki Ito, Katsuyoshi Watanabe
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Patent number: 8389589Abstract: A nanoporous material exhibiting a lamellar structure is disclosed. The material comprises three or more substantially parallel sheets of an organosilicate material, separated by highly porous spacer regions. The distance between the centers of the sheets lies between 1 nm and 50 nm. The highly porous spacer regions may be substantially free of condensed material. For the manufacture of such materials, a process is disclosed in which matrix non-amphiphilic polymeric material and templating polymeric material are dispersed in a solvent, where the templating polymeric material includes a polymeric amphiphilic material. The solvent with the polymeric materials is distributed onto a substrate. Organization is induced in the templating polymeric material. The solvent is removed, leaving the polymeric materials in place. The matrix polymeric material is cured, forming a lamellar structure.Type: GrantFiled: December 18, 2008Date of Patent: March 5, 2013Assignee: International Business Machines CorporationInventors: Jennifer Nam Cha, Geraud Jean-Michel Dubois, James Lupton Hedrick, Ho-Cheol Kim, Victor Yee-Way Lee, Teddie Peregrino Magbitang, Robert Dennis Miller, Willi Volksen
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Patent number: 8349907Abstract: Preparation and use of polyurethane foams with the use of foam stabilizers of the general formula (I)Type: GrantFiled: December 15, 2008Date of Patent: January 8, 2013Assignee: Evonik Goldschmidt GmbHInventors: Frauke Henning, Wilfried Knott, Oliver Thum, Carsten Schiller, Martin Glos, Annegret Terheiden
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Publication number: 20120235073Abstract: Methods, apparatuses, and systems for fabricating porous materials using thixotropic gels. A shear force is applied to a thixotropic material causing the material to flow. Multiple components are added to the thixotropic material while applying the shear force causing the multiple components to be distributed in the material. The shear force is removed such that the static properties of the thixotropic material in the absence of the shear force retain a distribution of the multiple components in the thixotropic material to form a composite gel material that includes liquid within a network of inter-connected solid particles that include the distributed plurality of components. The liquid in the composite gel material is removed to form a porous composite material.Type: ApplicationFiled: October 12, 2010Publication date: September 20, 2012Applicant: Arizona Board of Regents for and on Be-half of Arizona State UniversityInventors: Dong-Kyun Seo, Alex Volosin
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Publication number: 20120225225Abstract: A crosslinkable foamable composition with low content of monomeric isocyanates comprising a) 10 to 90 wt % of a prepolymer of polyester diols reacted with an excess of diisocyanates and subsequent removal of the excess monomeric diisocyanate, b) 90 to 10 wt % of a component based on polyether polyols which possesses at least one Si(OR)3 group or at least one NCO group, c) 0.1 to 30 wt % additives, d) and at least one blowing agent, wherein the polyester diols and the polyether diols have a molecular mass (MN) below 5000 g/mol and the mixture of a and b comprises a content of monomeric diisocyanates below 2 wt %.Type: ApplicationFiled: March 22, 2012Publication date: September 6, 2012Applicant: Henkel AG & Co., KGaAInventors: Uwe Franken, Michael Krebs, Milan Sebestian
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Publication number: 20120201806Abstract: Disclosed are compositions-of-matter composed of a continuous elastomeric matrix and a liquid; the matrix entrapping the liquid therein in the form of closed-cell droplets dispersed throughout the matrix. The disclosed compositions-of-matter are characterized by a low tensile/compressive modulus and are capable of retaining the liquid for exceedingly long periods of time. Further disclosed are processes for forming the compositions-of-matter and uses thereof.Type: ApplicationFiled: February 9, 2012Publication date: August 9, 2012Applicant: Technion Research & Development Foundation Ltd.Inventors: Michael S. Silverstein, Inna Gurevitch
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Publication number: 20120172470Abstract: Polyether polyols are initiated 1,3- and/or 1,4-bis(aminomethyl)cyclohexane) and with either or both of a methylene bis(cyclohexylamine) compound and a cyclohexanediamine compound. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.Type: ApplicationFiled: September 21, 2010Publication date: July 5, 2012Inventors: Timothy A. Morley, Francois M. Casati, Adrian J. Birch, Phillip S. Athey, Hans Kramer
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Patent number: 8143335Abstract: An adhesive composition for use in the manufacture of wood-based boards, wherein the adhesive composition is foamable and comprises a resin, a filler and a foaming agent without any cationic acrylamide copolymer. According to the invention, the adhesive composition contains 40-80 wt % resin, 5-30 wt % filler, 0-40 wt % solvent, and 0.1-10 wt % foaming agent, which has been selected from organic and/or inorganic surface-active sulfate, sulfonate, phosphate or phosphonate compounds or their derivatives or mixtures.Type: GrantFiled: June 9, 2008Date of Patent: March 27, 2012Assignee: Momentive Specialty Chemicals Inc.Inventor: Jouni Rainio
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Patent number: 8034848Abstract: The subject matter of the present invention relates to a low-viscosity aqueous hot-cure flexible polyurethane foam stabilizer solution which can be used in the production of hot-cure flexible polyurethane foams, wherein the low-viscosity aqueous hot-cure flexible polyurethane foam stabilizer solution comprises the following components: ?40% to ?70% by weight of polyethersiloxane, ?0.5% to ?20% by weight of organic surfactant, ?10% by weight of water, ?0% by weight of organic solvent additions, in which the polyethersiloxane has the following formula (I) —R1—Si(CH3)2O—[Si(CH3)(OSi(CH3)2R0)O—]u—[Si(OSi(CH3)2R0)2O—]v—[Si(CH3)2O—]w—[SiCH3R2O—]x—[SiCH3R3O—]y—[SiCH3R4O]z—[SiR3R4O]t—Si(CH3)2—R5 (I).Type: GrantFiled: August 16, 2007Date of Patent: October 11, 2011Assignee: Evonik Goldschmidt GmbHInventors: Ruediger Landers, Berend-Jan De Gans
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Patent number: 8030366Abstract: The invention relates to the use of polyethers containing urethane or urea groups as foam stabilizers, obtained by reacting at least one isocyanate with (a) at least one hydrophilic polyether which statistically carries at least one OH and/or NH2 and/or NH function and (b) at least one hydrophobic polyether which statistically carries at least one OH and/or NH2 and/or NH function and optionally (c) further compounds which carry at least one OH and/or NH2 and/or NH function and/or other isocyanate-reactive groups, such as carboxyl or epoxide functions, with the proviso that at least one isocyanate is ?difunctional.Type: GrantFiled: September 6, 2007Date of Patent: October 4, 2011Assignee: Evonik Goldschmidt GmbHInventors: Michael Ferenz, Christian Eilbracht, Jutta Esselborn, Sascha Herrwerth, Gabriele Platte
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Publication number: 20110224319Abstract: The invention relates to a foamable mixture which contains at least one alkoxysilane-terminated prepolymer and which can be produced of a) at least one alkoxysilane that was functionalized with isocyanate groups and that can be produced of at least one hydroxyfunctional and/or aminofunctional alkoxysilane and at least one diisocyanate or polyisocyanate, and b) at least one compound that contains at least one OH group, and at least one blowing agent, characterized in that the foamable mixture has a dynamic viscosity of 100 to 25,000 mPas, preferably 500 to 10,000 mPas, at 23° C. The invention further relates to a method for producing said foamable mixture. The foamable mixtures according to the invention are suitable for sealing, insulating and mounting joints, roof surfaces, windows and doors or for filling hollow spaces.Type: ApplicationFiled: January 20, 2011Publication date: September 15, 2011Applicant: Henkel AG & Co. KGaAInventors: Wilfried Huebner, Milan Sebestian, Christiane Kunze, Lars Zander, Johann Klein
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Patent number: 7972695Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: January 11, 2011Date of Patent: July 5, 2011Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H. Piispanan, Michael T. Williams
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Publication number: 20110130477Abstract: Polyether polyols initiated with ortho-cyclohexanediamines such as 1,2- diaminocyclohexane are used in rigid polyurethane foam formulations in conjunction with an aromatic amine-initiated polyol, a polyester polyol, or a polyol derived from a renewable resource. The polyol mixture are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.Type: ApplicationFiled: July 29, 2009Publication date: June 2, 2011Inventors: Adrian J. Birch, Hans Kramer, Timothy A. Morley
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1,3- OR 1,4-BIS(AMINOMETHYL)CYCLOHEXANE-INITIATED POLYOLS AND RIGID POLYURETHANE FOAM MADE THEREFROM
Publication number: 20110077314Abstract: Polyether polyols are initiated with 1,3- or 1,4-bis(aminomethyl)cyclohexanes. The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.Type: ApplicationFiled: June 5, 2009Publication date: March 31, 2011Inventors: Timothy A. Morley, Francois M. Casati, Adrian J. Birch -
Publication number: 20110077315Abstract: Polyether polyols are initiated with methylene bis(cyclohexylamines). The polyols are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times.Type: ApplicationFiled: June 5, 2009Publication date: March 31, 2011Inventors: Timothy A. Morley, Casati M. Francois, Birch J. Adrian
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Publication number: 20110065821Abstract: A method is disclosed for making a polyol comprising: fully-epoxidizing a partially hydrogenated vegetable oil to obtain a fully-epoxidized vegetable oil derivative having an iodine value less than 4 g I2/100 gram, an EOC of from 4.0 to 5.7% and a Gardner color value of 2 or less; and then reacting the fully-epoxidized vegetable oil derivative with a ring opener to form a polyol having a hydroxyl number from 40 to 80 mg KOH/gram, a number average molecular weight of at least 1500 Daltons, a dynamic viscosity less than 10 pascal-seconds, and an EOC below 3.0 wt %.Type: ApplicationFiled: May 13, 2009Publication date: March 17, 2011Applicant: Cargill, IncorporatedInventors: Timothy W. Abraham, William C. Gower
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Patent number: 7892645Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: August 19, 2010Date of Patent: February 22, 2011Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David Allen Cowan, Dennis H Piispanen, Michael T Williams
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Patent number: 7862749Abstract: A free-flowing, stable liquid flame retardant mixture comprised of or formed by mixing together components comprised of: A) at least one organic halogen-containing reactive flame retardant in which the halogen is bromine, chlorine or both; and B) a liquid additive that is comprised of at least one aliphatic polyepoxide of the formula R(EP)n, wherein R is a straight chain or branched chain aliphatic moiety which consists of carbon, hydrogen, and optionally, one or more ether oxygen atoms and/or one or more epoxy oxygen atoms; Ep is a terminal epoxy group: and n is a whole or fractional number in the range of 2 to about 6. Such mixtures can be effectively used in the preparation of flame retardant rigid polyurethanes and rigid foams thereof, and rigid polyisocyanurate and rigid foams thereof. Component B) serves as an effective hardener for such polymers and foams.Type: GrantFiled: May 28, 2004Date of Patent: January 4, 2011Assignee: Albemarle CorporationInventor: Rinus Sjerps
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Publication number: 20100305227Abstract: The invention relates generally to protein-containing polyurethane foams, methods and compositions for making the polyurethane foams, and articles comprising the polyurethane foams.Type: ApplicationFiled: March 8, 2010Publication date: December 2, 2010Inventors: Anthony A. Parker, Joseph J. Marcinko
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Publication number: 20100280140Abstract: Propylene oxide, ethylene oxide, or a propylene oxide/ethylene oxide mixture are reacted with 1,2-phenylene diamine to form adducts having hydroxyl and amino groups. The 1,2-phenylene diamine adducts are useful in making rigid polyurethane foams, especially foams for pour-in-place applications, where they give a good combination of low k-factor and short demold times. The polyols also have unexpectedly low viscosities.Type: ApplicationFiled: January 13, 2009Publication date: November 4, 2010Inventors: Timothy A. Morley, Francois M. Casati, Adrian J. Birch, Hans Kramer
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Patent number: 7785711Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: April 29, 2010Date of Patent: August 31, 2010Assignee: NOVA Chemicals Inc.Inventors: Jiansheng Tang, David A. Cowan, Dennis H. Piispanen, Michael T. Williams
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Patent number: 7763578Abstract: Use of high boiling hydrofluoroethers as nucleating agents in the production of a polymeric foam, in particular in the production of polyurethane foams and phenolic foams. Also, blowing agent compositions and foamable compositions comprising one or more high boiling hydrofluoroether nucleating agents and foams made using such blowing agent compositions and foamable compositions.Type: GrantFiled: November 8, 2005Date of Patent: July 27, 2010Assignee: 3M Innovative Properties CompanyInventors: John G. Owens, Rudolf J. Dams
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Patent number: 7736740Abstract: Expandable or pre-expanded thermoplastic particles, e.g. polystyrene particles, used to form foam containers e.g. cups, bowls, are coated with a coating composition comprising a liquid part consisting of a) liquid polyethylene glycol with an average molecular weight of 200 to 800; and a solid part comprising components selected from the group consisting of b) polyolefin wax, e.g. polyethylene wax, c) a metal salt of higher fatty acids, e.g. zinc stearate or calcium stearate; d) polyethylene glycol with an average molecular weight of 900 to 10,000; and e) a fatty bisamide or fatty amide, e.g. ethylene bis-stearamide; and combinations of b) through e). The coating composition prevents or resists leakage of liquids and foods with oil and/or fatty components and improves the rim strength and ATF properties of foam containers.Type: GrantFiled: July 3, 2006Date of Patent: June 15, 2010Assignee: NOVA Chemicals Inc.Inventors: Jainsheng Tang, David Allen Cowan, Dennis H. Piispanen, Michael T. Williams