Nitrogen Reactant Contains At Least Two Amino Nitrogen Atoms Patents (Class 521/184)
  • Patent number: 4367296
    Abstract: High density structural ("blocking") materials composed of a polyimide filled with glass microballoons. Structural components such as panels which have integral edgings and/or other parts made of the high density materials.
    Type: Grant
    Filed: November 24, 1981
    Date of Patent: January 4, 1983
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4363690
    Abstract: High density structural ("blocking") materials composed of a polyimide filled with glass microballoons and methods for making such materials. Structural components such as panels which have integral edgings and/or other parts made of the high density materials.
    Type: Grant
    Filed: August 27, 1981
    Date of Patent: December 14, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4360604
    Abstract: Copolyimide foams derived from a diester of 3,3',4,4'-benzophenonetetracarboxylic acid, an aromatic diamine, and a heterocyclic diamine. A molar concentration of the heterocyclic diamine approaching but not exceeding 0.42 is employed. This results in a flexible foam with a homogeneous cellular structure and a reduced compression set loss.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: November 23, 1982
    Assignee: International Harvester Co.
    Inventors: John Gagliani, Raymond Lee, Usman A. K. Sorathia
  • Patent number: 4358548
    Abstract: For forming synthetic cellular materials, gas is generated by the reaction of an isocyanate and a hydroperioxide. The reactants produce a novel polymeric amine oxide foam. When the reactants are introduced to a base resin, cellular foam products (densities throughout the 50 to 2 lbs/ft.sup.3 range), extended resin products of even higher densities, and non-shrink resinous solids (with microcellular distribution of gas) can be obtained. When employed in resins curable with hydroperoxide, a small fraction of the hydroperoxide interacts with a promoter and serves to cure the resin while the larger fraction reacts earlier with the isocyanate to evolve gas before the gellation state of the base resin is reached. The foaming agent can be made commercially available as a premixture of isocyanate and appropriate surfactant for the hydroperoxide reaction. By mixing with low hydroxyl and carboxyl base resin, long pot life is obtainable.
    Type: Grant
    Filed: January 14, 1980
    Date of Patent: November 9, 1982
    Assignee: Whitney & Company, Inc.
    Inventor: Glen W. Saidla
  • Patent number: 4355120
    Abstract: Copolyimide foams derived from a diester of 3,3',4,4'-benzophenonetetracarboxylic acid, an aromatic diamine, and a heterocyclic diamine. A molar concentration of the heterocyclic diamine approaching but not exceeding 0.42 is employed. This results in a flexible foam with a homogeneous cellular structure and a reduced compression set loss.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: October 19, 1982
    Assignee: International Harvester Co.
    Inventors: John Gagliani, Raymond Lee, Usman A. K. Sorathia
  • Patent number: 4353998
    Abstract: High density structural ("blocking") materials composed of a polyimide filled with glass microballoons. Structural components such as panels which have integral edgings and/or other parts made of the high density materials.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: October 12, 1982
    Assignee: International Harvester Company
    Inventors: John Gagliani, Raymond Lee
  • Patent number: 4346214
    Abstract: Polyester amide silicate resinous products are produced by heating a mixture of an oxidated silicon compound, polyhydroxy compound, a polycarboxylic acid and/or polycarboxylic acid anhydride and a polyamine in the presence of an alkali catalyst.
    Type: Grant
    Filed: August 31, 1981
    Date of Patent: August 24, 1982
    Inventor: David H. Blount
  • Patent number: 4334030
    Abstract: Foamable blends are provided of high performance thermoplastic polymers such as polyphenylene oxides, polystyrenes, etc., and an effective amount of a first blowing agent which is an amide derivative of azodicarboxylic acid and a second blowing agent which is a dihydrooxadiazinone.
    Type: Grant
    Filed: November 23, 1979
    Date of Patent: June 8, 1982
    Assignee: General Electric Company
    Inventor: John E. Kochanowski
  • Patent number: 4331776
    Abstract: Masterbatches useful for lightweight polyamide molding or extrusion comprise polyamide, a pore-forming agent and a fusible binder that is compatible with the polyamide. Admixture of the masterbatch and granular polyamide polymer results in a polyamide composition which can be molded or extruded into a product having increased homogeneity and expansion uniformity.
    Type: Grant
    Filed: May 20, 1981
    Date of Patent: May 25, 1982
    Assignee: Rhone-Poulenc Industries
    Inventor: Jean-Pierre Gazonnet
  • Patent number: 4288560
    Abstract: A process for foaming thermoplastic materials by adding to the plastics material 0.05 to 5 percent by weight of a dioxazolone of the formula I ##STR1## in which n is 1, 2 or 3, and when n is 1R is C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.12 -alkenyl, C.sub.7 -C.sub.9 -aralkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.6 -C.sub.10 -aryl, or phenyl substituted by C.sub.1 -C.sub.9 -alkyl, halogen, C.sub.1 -C.sub.9 -alkoxy or nitro, or it is a heterocyclic radical, or when n is 2R is C.sub.1 -C.sub.8 -alkylene, ethenylene, m- or p-phenylene, m- or p-halophenylene, biphenylene, oxy-bis-(p-phenylene), 2,5-thienylene, 2,5-furylene, 2,6-pyridylene or naphthylene, or when n is 3R is phenenyl,and subsequently heating the mixture.
    Type: Grant
    Filed: August 25, 1980
    Date of Patent: September 8, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf Kirchmayr, Werner Fussenegger, Hugo Illy
  • Patent number: 4262094
    Abstract: Highly useful novel microcellular polymeric structures, especially films and fibers, are prepared from certain solid polymers. Aromatic polysulfones, polyimides, polyhydantoins, polyamides and polyparabanic acid are the preferred ones for the novel structures of the invention.
    Type: Grant
    Filed: July 24, 1979
    Date of Patent: April 14, 1981
    Assignee: Exxon Research & Engineering Co.
    Inventor: Burnett H. Johnson
  • Patent number: 4259453
    Abstract: A composition comprising a gas-expandable polymeric material and an activated hydrazodicarboxylate blowing agent, wherein the activator is selected from nickelbis(3,5-di-t-butyl-4-hydroxybenzoate), a mixture of 2-hydroxy-4-n-octoxybenzophenone and nickelbis(2-oxy-4-n-octoxybenzophenone), nickel stearate, nickel trifluoroacetylacetonate, [2,2'-thiobis(4-t-thiobis(4-t-octylphenolato)]nickel, nickelbis [O-ethyl-(3,5-di-t-butyl-4-hydroxybenzyl)phosphonate], nickelammoniumsulfate, ethylenediaminetetra(methylenephosphonic acid), and hexamethylenediaminetetra(methylenephosphonic acid).
    Type: Grant
    Filed: June 4, 1980
    Date of Patent: March 31, 1981
    Assignee: Uniroyal, Inc.
    Inventor: Rhomie L. Heck, III
  • Patent number: 4258138
    Abstract: Method of foaming thermoplastic polymeric materials using as blowing agents polycyclic fused ring heterocycles containing the tetrazole moiety.
    Type: Grant
    Filed: October 15, 1979
    Date of Patent: March 24, 1981
    Assignee: The Dow Chemical Company
    Inventor: Thomas C. Britton
  • Patent number: 4228259
    Abstract: A dye for keratinic material comprises a water-soluble cationic polymer having a molecular weight ranging between about 800 and 10,000 and having secondary, tertiary or quaternary ammonium amine groups wherein said amine groups are either a part of, or aid in the direct or indirect linking to the polymer chain, an aryl or arylaliphatic chromophore or chromogen group carrying compound, with the proviso that when the main chain of the polymer has amine groups derived from the said chromophore or chromogen group carrying compound, the said main chain must also have at least 10 percent aliphatic amine groups relative to the total number of amine groups of the said chain.
    Type: Grant
    Filed: August 8, 1977
    Date of Patent: October 14, 1980
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Alexandre Zysmann, Henri Sebag, Guy Vanlerberghe, Jean-Louis Huron, Andree Bugaut
  • Patent number: 4226949
    Abstract: Aromatic polyamide foams having a density of 0.025 to 0.7 g./cm..sup.3 are prepared by heating N-alkyl aromatic polyamides having at least one .beta. hydrogen atom on the alkyl groups, a plasticizer and an aromatic sulfonic acid catalyst at 250.degree. to 340.degree. C. for a length of time sufficient to remove substantially all of the N-alkyl groups.
    Type: Grant
    Filed: August 1, 1979
    Date of Patent: October 7, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Wesley Memeger, Jr.
  • Patent number: 4183822
    Abstract: The present invention relates to a process for expanding thermoplastic polymer compositions, notably those containing polymers having processing temperatures in excess of 200.degree. C. and/or containing an ingredient which is susceptible to ammonia, characterized in that as the blowing agent certain carbonates (notably zinc carbonate) are used. Preferably a nucleating agent and a weak acid are present to aid cell formation.The invention also includes expandable polymer compositions and blowing agent formulations containing the carbonates.
    Type: Grant
    Filed: January 18, 1978
    Date of Patent: January 15, 1980
    Assignee: Fisons Limited
    Inventors: Kenneth T. Collington, Rishi R. Puri, Peter J. Gibson
  • Patent number: 4180632
    Abstract: Rigid thermoset polyaminoesters are prepared by reacting a mixture of acrylate monomer having an average acrylate functionality of at least 2.5 and aliphatic amine having an average amine hydrogen functionality of at least 3.
    Type: Grant
    Filed: November 25, 1977
    Date of Patent: December 25, 1979
    Assignee: Rohm and Haas Company
    Inventor: Casmir S. Ilenda
  • Patent number: 4179298
    Abstract: Flame retardant intumescent polyamides comprising repeating structural units of the formulas ##STR1## wherein X is independently chloro or bromo, and n and n' are each independently a positive integer are disclosed.
    Type: Grant
    Filed: January 18, 1978
    Date of Patent: December 18, 1979
    Assignee: The Dow Chemical Company
    Inventors: Linnea E. Nelson, Charles E. Reineke
  • Patent number: 4178419
    Abstract: Aromatic polyamide foams having a density of 0.025 to 0.7 g./cm..sup.3 are prepared by heating N,N'-dialkyl aromatic polyamides having at least one .beta. hydrogen atom on the alkyl groups, a plasticizer and an aromatic sulfonic acid catalyst at 250.degree. to 340.degree. C. for a length of time sufficient to remove substantially all of the N-alkyl groups.
    Type: Grant
    Filed: February 27, 1978
    Date of Patent: December 11, 1979
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Wesley Memeger, Jr.
  • Patent number: 4164603
    Abstract: A filament of a thermoplastic synthetic polymer having a plurality of adjacent, separate discontinuous cavities is made by a process wherein a silicone oil and an inert gas or gas-forming substance are dispersed in a polymer melt, and the melt is extruded into a filament. The melt contains up to and including 1% by weight of the silicone oil, based on the weight of the melt, at the time it is extruded and up to and including 10% by weight of an inert gas.
    Type: Grant
    Filed: November 4, 1976
    Date of Patent: August 14, 1979
    Assignee: Akzona Incorporated
    Inventors: Erhard Siggel, Gerhard Wick, Heinz Linhart, Erich Kessler
  • Patent number: 4158724
    Abstract: Tris-tetrazoles of formula I, ##STR1## wherein A is alkylene and R is hydrogen, alkyl or phenyl, are suitable blowing agents for thermoplastic resins, especially for polycarbonates and aromatic polyethers. The foaming process can be carried out at a temperature range of 230.degree. to 300.degree. C., the resulting foamed articles have a fine and homogeneous cellular structure.The tris-tetrazoles I can be synthesized from the corresponding tris-nitriles or tris-imidchlorides by reaction with an alkali azide.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: June 19, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Hugo Illy, Werner Fussenegger