Cellular Product-forming Process Wherein The Removable Material Is Present Or Is Produced In Situ During The Solid Polymer Formation Step Patents (Class 521/63)
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Patent number: 11485066Abstract: A method of forming a porous structure involves mixing a solvent with a curable material which disperses in the solvent such that the mixture has greater than 50% solvent content. The mixture is deposited on a substrate and viscosity of the mixture is increased. The curable material in the mixture is cured while a shape of the curable material is maintained by the solvent. After curing, the solvent is removed from the structure.Type: GrantFiled: December 17, 2018Date of Patent: November 1, 2022Assignee: Palo Alto Research Center IncorporatedInventors: Junhua Wei, Gabriel Iftime, Jessica Louis Baker Rivest, Anne Plochowietz
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Patent number: 11097986Abstract: A process of forming a Si-containing ceramic comprises forming a Si-based polymeric composition. The process includes neutralizing a charge of said Si-based polymeric composition. The process includes adding thermal energy under a controlled atmosphere to the Si-based polymeric composition. A turbine engine component comprises an airfoil and the airfoil comprises a Ceramic Matrix Composite (CMC) material.Type: GrantFiled: October 29, 2018Date of Patent: August 24, 2021Assignee: Raytheon Technologies CorporationInventor: Wayde R. Schmidt
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Patent number: 11091681Abstract: A method of treating a subterranean formation penetrated by a wellbore, wherein the subterranean formation comprises one or more permeable zones, comprising introducing a superabsorbent polymer (SAP) fluid into the wellbore, wherein the SAP fluid comprises an aqueous fluid and an SAP material comprising a reaction product of a reaction mixture comprising one or more viscosifying polymeric materials, one or more crosslinking agents, and water, allowing the SAP fluid to flow into at least a portion of the one or more permeable zones in the subterranean formation, and allowing the SAP material to absorb water and form a swollen SAP material, wherein the swollen SAP material impedes fluid flow through at least a portion of the one or more permeable zones.Type: GrantFiled: October 31, 2019Date of Patent: August 17, 2021Assignee: Halliburton Energy Services, Inc.Inventors: Nivika Rajendra Gupta, Edwin Gnanakumar Solomon Raja, Jay Paul Deville
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Patent number: 10825439Abstract: In an embodiment, the present invention provides a sound-absorbing textile composite, including: a) at least one open-pore support layer comprising coarse staple fibers having a titer of from 3 dtex to 17 dtex and fine staple fibers having a titer of from 0.3 dtex to 2.9 dtex, as scaffold fibers; and b) a microporous flow layer arranged on the support layer and including microfibers having a fiber diameter of less than 10 ?m. A flow resistance of the sound-absorbing textile composite is from 250 Ns/m3 to 5000 Ns/m3.Type: GrantFiled: November 6, 2017Date of Patent: November 3, 2020Assignee: CARL FREUDENBERG KGInventors: Angela Weik, Sandra Villing-Falusi, Peter Rutsch
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Patent number: 10789931Abstract: In an embodiment, the present invention provides a sound-absorbing textile composite having a flow resistance of from 250 Ns/m3 to 5000 Ns/m3, including: a) at least one open-pore support layer including coarse staple fibers having a titer of from 3 dtex to 17 dtex and fine staple fibers having a titer of from 0.3 dtex to 2.9 dtex as scaffold fibers; and b) a flow layer arranged on the support layer, which flow layer includes a microporous foam layer.Type: GrantFiled: November 7, 2017Date of Patent: September 29, 2020Assignee: CARL FREUDENBERG KGInventors: Angela Weik, Gunter Scharfenberger, Sandra Villing-Falusi
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Patent number: 9279048Abstract: The use of water-absorbing polymer particles for dewatering feces, the water-absorbing polymer particles being obtainable by polymerizing a foamed monomer solution or suspension, drying the polymeric foam and grinding the dried foam.Type: GrantFiled: May 15, 2012Date of Patent: March 8, 2016Assignee: BASF SEInventors: Francisco Javier Lopez Villanueva, Markus Linsenbühler, Matthias Weismantel, Bernd Siegel, Klaus Dieter Hörner, Sandra Engelhardt
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Patent number: 9051445Abstract: A multipackage sponge-forming liquid silicone rubber composition that characteristically comprises at least (A) an alkenyl-containing polydiorganosiloxane comprising (A1) a polydiorganosiloxane that has alkenyl groups on both molecular chain terminals and that does not contain alkenyl groups in the side chains on the molecular chain, and (A2) a polydiorganosiloxane that has at least two alkenyl groups in the side chains on the molecular chain; (B) an organopolysiloxane that has at least two silicon-bonded hydrogen atoms in each molecule; (C) a mixture comprising water and an inorganic thickener; (D) an emulsifying agent; (E) a hydrosilylation reaction catalyst; and (F) a cure retarder; and is stored as a plurality of separate compositions wherein none of this plurality of separately stored compositions contain both component (A) and component (C), none of this plurality of separately stored compositions contain both component (B) and component (C), and none of this plurality of separately stored compositionsType: GrantFiled: July 30, 2009Date of Patent: June 9, 2015Assignee: DOW CORNING TORAY CO., LTD.Inventors: Tsugio Nozoe, Fumitaka Suto, Hiroaki Yoshida, Atsushi Sakuma, Yuichi Tsuji
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Patent number: 8993646Abstract: A porous polymer separator for use in a lithium ion battery is formed by a temperature-induced phase separation method. The porous polymer separator includes a polymer matrix having opposed major faces and a network of pore openings that extends between the major faces and permits intrusion of a lithium-ion conducting electrolyte solution. As part of the temperature-induced phase separation method, a single phase polymer solution that includes a polymer material dissolved in a miscible mixture of a real polymer solvent and a polymer non-solvent is prepared at an elevated temperature above room temperature. A film is then formed from the single phase polymer solution and cooled to phase-separate the polymer material into a solid polymer precipitate. Additional polymer non-solvent is then used to remove the real polymer solvent from the solid polymer precipitate followed by drying.Type: GrantFiled: November 18, 2011Date of Patent: March 31, 2015Assignee: GM Global Technology Operations LLCInventor: Xiaosong Huang
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Publication number: 20150087731Abstract: Methods for making wet gels and dried gels therefrom are provided. The method for making a wet gel can include combining a hydroxybenzene compound, an aldehyde compound, and an additive to produce a reaction mixture. The additive can include a carboxylic acid, an anhydride, a homopolymer, a copolymer, or any mixture thereof. At least the hydroxybenzene compound and the aldehyde compound can be reacted to produce a wet gel. The reaction mixture can include about 10 wt % to about 65 wt % of the hydroxybenzene compound, about 5 wt % to about 25 wt % of the aldehyde compound, up to about 85 wt % of the carboxylic acid, up to about 40 wt % of the anhydride, up to about 40 wt % of the homopolymer, and up to about 40 wt % of the copolymer, where weight percent values are based on the combined weight of the hydroxybenzene compound, the aldehyde compound, and the additive.Type: ApplicationFiled: September 18, 2014Publication date: March 26, 2015Inventors: Xing Dong, Shahid P. Qureshi, Christopher M. Lee, Kelly A. Shoemake, Joseph Frank Ludvik
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Publication number: 20150072147Abstract: Embodiments of the present disclosure include organic polymeric particles, paper coating compositions, coated paper, and methods of forming coated paper with the paper coating compositions. The embodiments of the organic polymeric particle include an organic hydrophilic polymer with a unit for hydrogen bonding, and a hollow porous structure that comprises an organic polymer that at least partially surrounds the organic hydrophilic polymer, where the hollow porous structure has a pore surface area greater than 1 percent of a total theoretical exterior surface area of the hollow porous structure and the organic hydrophilic polymer and the hollow porous structure give the organic polymeric particle a void volume fraction of 40 percent to 85 percent.Type: ApplicationFiled: November 14, 2014Publication date: March 12, 2015Inventors: David J. BRENNAN, John P. KELLY, Brian J. NINNESS, James G. GALLOWAY, Alan B. CHAPUT, JR., John S. ROPER, III, John D. OATES
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Publication number: 20150045463Abstract: The invention provides a hollow nano-particle comprising a crosslinked shell and a void core; and a preparation method thereof. The hollow nano-particle may be used in rubber composition, tire product, and pharmaceutical delivery system etc.Type: ApplicationFiled: November 3, 2014Publication date: February 12, 2015Applicant: BRIDGESTONE CORPORATIONInventors: Xiaorong Wang, Mindaugas Rackaitis, Pat Sadhukhan
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Publication number: 20150041703Abstract: Macroporous beads and a method of manufacturing and using such macroporous beads. wherein the beads are distinguishable for use in a multiplex assay. Preferably, the beads are distinguishable by two or more unique fluorochromes, and at least some of the beads are magnetically responsive. In a preferred form, some of the macroporous beads have interior pores with a different moiety from the exterior surface, allowing beads with different attached functional groups.Type: ApplicationFiled: September 29, 2014Publication date: February 12, 2015Inventors: Jason BEDRE, Don Chandler, Ben Mize
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Publication number: 20150030842Abstract: Disclosed are porous resin particles which contain a polymer of a monomer mixture containing, as monomers, at least a monofunctional (meth)acrylic acid ester and a crosslinking monomer. The monofunctional (meth)acrylic acid ester accounts for 1 wt % to 50 wt % of the monomer mixture, and the crosslinking monomer accounts for 50 wt % to 99 wt % of the monomer mixture. The porous resin particles have a specific surface area of 190 m2/g to 300 m2/g and a bulk specific gravity of 0.25 g/mL to 0.45 g/mL.Type: ApplicationFiled: March 29, 2013Publication date: January 29, 2015Inventors: Yukio Hama, Koichiro Okamoto, Junko Hiroi
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Patent number: 8911762Abstract: The invention relates to a method of preparing a composite or porous composite used as a biodegradable scaffold, the composite prepared therefrom and the use of the composite. In particular, the composite is a calcium sulfate-polylactic acid composite or porous composite and the composite can be especially used as an in situ pore forming scaffold.Type: GrantFiled: November 30, 2010Date of Patent: December 16, 2014Assignee: Taipei Medical UniversityInventors: Wei-Chung Yang, Jen-Chang Yang, Duen-Jeng Wang, Sheng-Yang Lee, Yan-Chih Chen
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Patent number: 8906973Abstract: Disclosed and claimed herein are hybrid silica aerogels containing non-polymeric, functional organic materials covalently bonded at one or both ends to the silica network of the aerogels through a C—Si bond between a carbon atom of the organic material and a silicon atom of the aerogel network. Methods of their preparation are also disclosed.Type: GrantFiled: November 30, 2011Date of Patent: December 9, 2014Assignee: Aspen Aerogels, Inc.Inventors: Wendell E Rhine, Decio Coutinho, Kiranmayi Deshpande
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Patent number: 8889751Abstract: The present specification discloses porous materials, methods of forming such porous materials, materials and devices comprising such porous materials, and methods of making such materials and devices.Type: GrantFiled: September 28, 2011Date of Patent: November 18, 2014Assignee: Allergan, Inc.Inventors: Futian Liu, Nicholas J. Manesis, Alexei Goraltchouk, Dimitrios Stroumpoulis
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Publication number: 20140322122Abstract: Porous three-dimensional networks of polyimide and porous three-dimensional networks of carbon and methods of their manufacture are described. For example, polyimide aerogels are prepared by mixing a dianhydride and a diisocyanate in a solvent comprising a pyrrolidone and acetonitrile at room temperature to form a sol-gel material and supercritically drying the sol-gel material to form the polyimide aerogel. Porous three-dimensional polyimide networks, such as polyimide aerogels, may also exhibit a fibrous morphology. Having a porous three-dimensional polyimide network undergo an additional step of pyrolysis may result in the three dimensional network being converted to a purely carbon skeleton, yielding a porous three-dimensional carbon network. The carbon network, having been derived from a fibrous polyimide network, may also exhibit a fibrous morphology.Type: ApplicationFiled: April 24, 2014Publication date: October 30, 2014Applicant: Aerogel Technologies, LLCInventors: Nicholas Leventis, Chariklia Sotiriou-Leventis, Chakkaravarthy Chidambareswarapattar
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Publication number: 20140256834Abstract: A non-particulate organic porous material with optical resolution capability, the non-particulate organic porous material having a continuous pore structure, which comprises macropores and mesopores, the macropores being interconnected forming mesopores with a radius of 0.01-100 ?m in the interconnected parts, and optically active groups uniformly introduced therein possesses high physical stability, can be used under wide separating conditions, and has a large capacity for separating optically active substances (enantiometers).Type: ApplicationFiled: May 15, 2014Publication date: September 11, 2014Applicant: ORGANO CORPORATIONInventors: Masahiro TERAGUCHI, Takashi Kaneko, Toshiki Aoki, Hiroshi Inoue, Akiko Yoshida
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Patent number: 8815967Abstract: A porous polyurea material may be prepared by polymerization and crosslinking of tetra(4-aminophenyl)methane or tetra(4-aminophenyl)silane with a monomer having two to four isocyanate (—NCO) groups, or by polymerization and crosslinking of tetra(4-isocyanatophenyl)methane or tetra(4-isocyanatophenyl)silane with a monomer having two to four amino groups. The method includes: mixing an organic solution of tetra(4-aminophenyl)methane with an organic solution of a monomer having two to four isocyanate groups; reacting the mixed solution under a nitrogen atmosphere; and drying a semi-solid or solid material formed by gelation of the reaction solution, or adding the reaction solution to a non-solvent before gelation of the reaction solution to form a precipitate, followed by drying, or applying the reaction solution to a substrate before gelation of the reaction solution, followed by drying.Type: GrantFiled: July 26, 2010Date of Patent: August 26, 2014Assignee: Gwangju Institute of Science an TechnologyInventors: Ji-Woong Park, Su-Young Moon, Jae-Sung Bae
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Patent number: 8796343Abstract: Use in hygiene articles of articles formed of water-absorbent, predominantly open-celled crosslinked acid-functional addition polymer foams Abstract The use of articles formed of water-absorbent open-celled crosslinked acid-functional addition polymer foams and containing finely divided silicon dioxide and/or at least one surfactant on their surface as an acquisition and/or distribution layer in hygiene articles.Type: GrantFiled: October 29, 2008Date of Patent: August 5, 2014Assignee: BASF SEInventors: Samantha Champ, Hans-Joachim Hähnle, Mariola Wanior
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Publication number: 20140206783Abstract: The present invention relates to a process for producing flame-retardant porous materials comprising the following steps: (a) reacting at least one polyfunctional isocyanate (a1) and at least one polyfunctional aromatic amine (a2) in an organic solvent optionally in the presence of water as component (a3) and optionally in the presence of at least one catalyst (a5); and then (b) removing the organic solvent to obtain the organic porous material, where step (a) is carried out in the presence of at least one organic flame retardant as component (a4), where this flame retardant is soluble in the solvent. The invention further relates to the porous materials thus obtainable, and also to the use of the porous materials for thermal insulation.Type: ApplicationFiled: March 26, 2014Publication date: July 24, 2014Applicant: BASF SEInventors: Marc FRICKE, Mark ELBING
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Patent number: 8741974Abstract: A method for forming a filter in a fluid flow path in a microfluidic device is provided. The method includes introducing a photopolymerization reaction solution into the microfluidic device; and performing polymerization of photopolymerization reaction solution to form a filter in the fluid flow path in a microfluidic device.Type: GrantFiled: June 18, 2008Date of Patent: June 3, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Chang-eun Yoo, Jong-myeon Park
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Patent number: 8703834Abstract: Crosslinked organic polymeric porous particles have a crosslinked organic solid phase and discrete pores dispersed within the crosslinked solid phase which pores are isolated from each other. These porous particles are prepared using one or more water-in-oil emulsions containing a polyfunctional reactive compound, a reagent that causes crosslinking, optionally an ethylenically unsaturated polymerizable monomer, and optionally an organic solvent, and can include various marker materials.Type: GrantFiled: July 28, 2011Date of Patent: April 22, 2014Assignee: Eastman Kodak CompanyInventor: Mridula Nair
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Patent number: 8691883Abstract: An aerogel-foam composite includes an open cell foam and an aerogel matrix polymer disposed in the open cell foam. The aerogel-foam composite has compression strength of about 15 megaPascals (MPa) or more. The open cell foam may be a polyurethane foam including a carbonate group (—OC(O)O—).Type: GrantFiled: June 21, 2011Date of Patent: April 8, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Myung-Dong Cho, Sang-Ho Park, Kwang-Hee Kim, Sung-Woo Hwang
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Publication number: 20140080932Abstract: Microporous polyolefin and microporous polydicyclopentadiene (polyDCPD) based aerogels and methods for preparing and using the same are provided. The aerogels are produced by forming a polymer gel structure within a solvent from a olefin or dicyclopentadiene monomer 5 via Ring Opening Metathesis Polymerization (ROMP) reactions, followed by supercritical drying to remove the solvent from the aerogel. Other aerogels are prepared by sequentially (1) mixing at least one dicyclopentadiene monomer, at least one solvent at least one catalyst and at least one inorganic and/or organic reinforcing material, (2) gelling the mixture, (3) aging, and (4) supercritical drying. Aerogels provided herein are inexpensive to prepare, possess desirable 10 thermal, mechanical, acoustic, chemical, and physical properties and are hydrophobic.Type: ApplicationFiled: May 16, 2013Publication date: March 20, 2014Applicant: ASPEN AEROGELS, INC.Inventors: Je Kyun Lee, George L. Gould
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Patent number: 8586641Abstract: The present invention relates to a monolithic organic copolymer prepared by copolymerization of at least one monomer of the group consisting of styrene, (C1-C3)alkylstyrene, (meth)acrylic acid and esters thereof with a crosslinker in the presence of a macroporogen and a microporogen, wherein a) the sum of said at least one monomer of the group and the crosslinker is 10-20%, preferably 10-15%, by volume of the reaction mixture, with the rest being essentially macroporogen and microporogen, and the degree of said copolymerization is at least 70%, preferably at least 90%, more preferably at least 99%, or b) the sum of said at least one monomer of the group and the crosslinker is 30-50%, preferably 35-45%, by volume of the reaction mixture, with the rest being essentially macroporogen and microporogen, and the degree of said copolymerization is in the range of 25-60%, preferably 35-50%.Type: GrantFiled: October 19, 2006Date of Patent: November 19, 2013Assignee: Leopold-Franzens-Universitat InnsbruckInventors: Lukas Trojer, Günther Bonn
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Patent number: 8557270Abstract: The present invention relates to a method of manufacture of an interconnected porous non-biodegradable polymer implant suitable for implantation into a mammal for the treatment, repair or replacement of defects or injury in musculoskeletal tissue, wherein the mechanical properties of the implant can be controlled by varying the concentration of the non-biodegradable polymer and/or varying the duration and number of freeze-thaw cycles and the interconnected porous non-biodegradable polymer implant has sufficient percent porosity and pore diameter to facilitate integration of cells and attachment within the mammal via ingrowth of surrounding tissue. The present invention also relates to an implant manufactured by the method.Type: GrantFiled: January 12, 2012Date of Patent: October 15, 2013Assignee: New York Society for the Ruptured and Crippled Maintaining the Hospital for Special SurgeryInventors: Suzanne A. Maher, Kenneth Ng, Tony Chen, Florian Wanivenhaus
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Patent number: 8550256Abstract: A method of photo-grafting onto a separation membrane a copolymer includes at least one of: and; For example, in Structure 1A, x1?2 and y1?1; R1 and R2 are independently selected from the group consisting of CH3 and H; R3 is independently selected from the group consisting of poly(oxyalkylene), quaternary ammonium salts, pyridinium salts, sulfonium salts, sulfobetaines, carboxybetaines, alcohols, phenols, tertiary amines, aryl groups; linear, branched and cyclic alkylenes; linear, branched and cyclic heteroalkylenes; linear, branched and cyclic fluoroalkylenes; and siloxyl; R4 is independently selected from the group consisting of linear, branched, and cyclic alkylenes; linear, branched and cyclic hetroalkylenes; linear, branched and cyclic fluoroalkylenes; phenyl; and siloxyl; and Z1 is 0 or 1.Type: GrantFiled: July 27, 2012Date of Patent: October 8, 2013Assignee: International Business Machines CorporationInventors: Jacquana T. Diep, Young-Hye Na, Ankit Vora
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Publication number: 20130209661Abstract: Described herein are methods of making open celled foams including a matrix of interconnected spheres. The open celled foams are silicone based materials and can be used to coat implants, such as breast implants, and function to encourage tissue ingrowth and reduce capsular formation.Type: ApplicationFiled: March 27, 2013Publication date: August 15, 2013Applicant: Allergan, Inc.Inventor: Allergan, Inc.
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Publication number: 20130192739Abstract: Sulfur contaminants, such as elemental sulfur (S8), hydrogen sulfide and other sulfur components in fluids (e.g., air, natural gas, and other gases, as well as water and other liquids) are removed using a silicone-based chemical filter/bath. In one embodiment, a silicone-based chemical filter includes a membrane having a cross-linked silicone that is a reaction product of an olefin and a polyhydrosiloxane. For example, sulfur contaminants in air may be removed by passing the air through the membrane before the air enters a data center or other facility housing computer systems. In another embodiment, a silicone-based chemical bath includes a housing having an inlet port, an outlet port, and a chamber containing a silicone oil. For example, sulfur contaminants in air may be removed by passing the air through the silicone oil in the chamber before the air enters a data center or other facility housing computer systems.Type: ApplicationFiled: March 13, 2013Publication date: August 1, 2013Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventor: INTERNATIONAL BUSINESS MACHINES CORPORATION
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Patent number: 8487013Abstract: The present invention relates to a method for producing a porous resin particle containing an aromatic vinyl compound-aromatic divinyl compound copolymer having a hydroxyl group, the method including: dissolving a monomer mixture containing an aromatic vinyl compound, an aromatic divinyl compound and a (meth)acrylic acid ester having one hydroxyl group within the molecule thereof, and a polymerization initiator in an organic solvent to obtain a solution containing the monomer mixture and the polymerization initiator; suspending the solution in water in the presence of a dispersion stabilizer; and performing a suspension copolymerization. The method of the invention is capable of easily producing a porous resin particle containing an aromatic vinyl compound-aromatic divinyl compound copolymer having a hydroxyl group, that is used as a support for solid phase synthesis and enables efficient nucleic acid synthesis.Type: GrantFiled: November 5, 2008Date of Patent: July 16, 2013Assignee: Nitto Denko CorporationInventors: Kenjiro Mori, Tatsuya Konishi
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Patent number: 8481603Abstract: The present invention relates to a polymer bead material that are characterised by having pore sizes that can be pre-determined and that can be obtained with a narrow distribution of such pore sizes created by use of sacrificial filler materials within the polymer material. The invention also discloses processes for production of the material as spherical or approximately spherical beads or resins with predefined sizes. Also, the invention relates to the preparation of molecularly imprinted polymer materials that are created by the said method. Further the invention relates to the use of said polymer materials for separation, detection, catalysis or entrapment of chemicals, metal ions, inorganic compounds, drags, peptides, proteins, DNA, natural and artificial polymers, natural or artificial compounds, food or pharma products, viruses, bacteria, cells and other entities.Type: GrantFiled: December 6, 2006Date of Patent: July 9, 2013Assignee: Biotage ABInventors: Ecevit Yilmaz, Johan Billing
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Patent number: 8470898Abstract: A porous thin-film polymer separator for use in a lithium ion battery may be formed by a phase separation method in which hydrophobic-treated ceramic particles are used to help induce the formation of a tortuous, interconnected network of pores coextensively across the thickness of the separator. As part of the phase separation method, a wet thin-film layer is formed from a polymer slurry that comprises a polymer solvent in which a polymer material is dissolved and the hydrophobic-treated ceramic particles are dispersed. The wet thin-film layer is subsequently exposed to a polymer non-solvent to form a solvent-exchanged thin-film precipitated polymer layer which is then heated to produce the separator.Type: GrantFiled: May 31, 2011Date of Patent: June 25, 2013Assignee: GM Global Technology Operations LLCInventor: Xiaosong Huang
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Patent number: 8470901Abstract: A composition for manufacturing an organic aerogel including at least one monomer having at least two substituted or unsubstituted acrylamide groups and a solvent is provided, along with an organic aerogel including a polymeric reaction product of the monomer or monomers.Type: GrantFiled: September 20, 2010Date of Patent: June 25, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Sang-Ho Park, Sung-Woo Hwang, Myung-Dong Cho
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Publication number: 20130153830Abstract: Porous materials are fabricated using interpenetrating inorganic-organic composite gels. A mixture or precursor solution including an inorganic gel precursor, an organic polymer gel precursor, and a solvent is treated to form an inorganic wet gel including the organic polymer gel precursor and the solvent. The inorganic wet gel is then treated to form a composite wet gel including an organic polymer network in the body of the inorganic wet gel, producing an interpenetrating inorganic-organic composite gel. The composite wet gel is dried to form a composite material including the organic polymer network and an inorganic network component. The composite material can be treated further to form a porous composite material, a porous polymer or polymer composite, a porous metal oxide, and other porous materials.Type: ApplicationFiled: August 3, 2011Publication date: June 20, 2013Inventors: Dong-Kyun Seo, Alex Volosin
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Patent number: 8436062Abstract: Substantially or roughly spherical micellar structures useful in the formation of nanoporous materials by templating are disclosed. A roughly spherical micellar structure is formed by organization of one or more spatially unsymmetric organic amphiphilic molecules. Each of those molecules comprises a branched moiety and a second moiety. The branched moiety can form part of either the core or the surface of the spherical micellar structure, depending on the polarity of the environment. The roughly spherical micellar structures form in a thermosetting polymer matrix. They are employed in a templating process whereby the amphiphilic molecules are dispersed in the polymer matrix, the matrix is cured, and the porogens are then removed, leaving nanoscale pores.Type: GrantFiled: May 4, 2011Date of Patent: May 7, 2013Assignee: International Business Machines CorporationInventors: Jennifer Nam Cha, James Lupton Hedrick, Ho-Cheol Kim, Victor Yee-Way Lee, Teddie Peregrino Magbitang, Robert Dennis Miller, Willi Volksen
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Patent number: 8436060Abstract: An organic aerogel includes a polymer prepared from a substituted or unsubstituted maleimide compound and a compound having at least two vinyl groups. A composition for the organic aerogel includes a substituted or unsubstituted maleimide compound and a compound having at least two vinyl groups.Type: GrantFiled: December 30, 2010Date of Patent: May 7, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Kwang-Hee Kim, Myung-Dong Cho, Sang-Ho Park, Sung-Woo Hwang
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Patent number: 8415403Abstract: The invention relates to a process for manufacturing porous materials, which comprises the following steps: preparation of a solution of at least one structuring agent, having at least two structuring parts linked by at least one type of reversible non-covalent interaction; formation of the structured or porous material; separation of the at least two parts of the structuring agent at low temperature; and recovery of at least 50% by weight of the two non-degraded structuring parts and the porous material.Type: GrantFiled: December 11, 2008Date of Patent: April 9, 2013Assignees: Total Raffinage Marketing, Centre National de la Recherche ScientifiqueInventors: Niki Baccile, Martin In, Corine In-Gerardin, Francis Luck, Julien Reboul, Sander Van Donk
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Patent number: 8410186Abstract: The present invention relates to a process for manufacturing a porous epoxy network, especially a porous epoxy membrane. The process according the present invention comprises the steps of: providing a reactant solution comprising an epoxy resin, a solvent and a curing agent; performing a first curing process to transform the reactant solution to a gel; and performing a second curing process to essentially remove the remaining solvent and transform the gel to form a porous epoxy network with open pores; wherein the curing agent is a tertiary amine.Type: GrantFiled: October 22, 2010Date of Patent: April 2, 2013Assignee: National Taipei University of TechnologyInventors: Kuo-Chung Cheng, Yu-Shun Luo, Ching-Lin Wu, Chiu-Ya Wang, Yi-Min Chang
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Patent number: 8399530Abstract: A process for producing polymer foams by precise control of their morphology through use of microfluidic processes, foams produced in this way and use thereof.Type: GrantFiled: March 26, 2009Date of Patent: March 19, 2013Assignee: BASF SEInventors: Meik Ranft, Armin Alteheld, Andre Guerin Moreira, Wiebke Drenckhan, Antje van der Net, Alexander Gryson, Florence Elias
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Patent number: 8389589Abstract: A nanoporous material exhibiting a lamellar structure is disclosed. The material comprises three or more substantially parallel sheets of an organosilicate material, separated by highly porous spacer regions. The distance between the centers of the sheets lies between 1 nm and 50 nm. The highly porous spacer regions may be substantially free of condensed material. For the manufacture of such materials, a process is disclosed in which matrix non-amphiphilic polymeric material and templating polymeric material are dispersed in a solvent, where the templating polymeric material includes a polymeric amphiphilic material. The solvent with the polymeric materials is distributed onto a substrate. Organization is induced in the templating polymeric material. The solvent is removed, leaving the polymeric materials in place. The matrix polymeric material is cured, forming a lamellar structure.Type: GrantFiled: December 18, 2008Date of Patent: March 5, 2013Assignee: International Business Machines CorporationInventors: Jennifer Nam Cha, Geraud Jean-Michel Dubois, James Lupton Hedrick, Ho-Cheol Kim, Victor Yee-Way Lee, Teddie Peregrino Magbitang, Robert Dennis Miller, Willi Volksen
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Patent number: 8383693Abstract: An aerogel including a polymeric reaction product of (a) a first monomer including an aromatic compound having at least two unsaturated functional groups, and (b) a second monomer represented by the following Chemical Formula 1 and including at least two groups independently chosen from (meth)acrylate groups and NR?R? (where R? and R? are the same or different and are (meth)acryloyl groups) is provided. Each substituent is as defined in the specification.Type: GrantFiled: September 13, 2010Date of Patent: February 26, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Kwang-Hee Kim, Myung-Dong Cho, Sang-Ho Park, Sung-Woo Hwang
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Publication number: 20130043514Abstract: A multiphase ultra low k dielectric process incorporating an organo-silicon precursor including an organic porogen, high frequency radio frequency power just above plasma initiation in a PECVD chamber and energy post treatment. A porous SiCOH dielectric material having a k less than 2.7 and a modulus of elasticity greater than 7 GPa. A graded carbon adhesion layer of SiO2 and porous SiCOH.Type: ApplicationFiled: August 19, 2011Publication date: February 21, 2013Applicant: International Business Machines CorporationInventors: Alfred Grill, Thomas J. Haigh, JR., Kelly Malone, Son V. Nguyen, Vishnubhai V. Patel, Hosadurga Shobha
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Publication number: 20130041055Abstract: A composition comprising a block copolymer that includes at least one polyester block and at least one linear polyolefin block, wherein the composition is in the form of a nano-structured, bicontinuous composite that includes a continuous matrix phase and a second continuous phase. The continuous matrix phase comprises the linear polyolefin block of the block copolymer, and the second continuous phase comprises the polyester block of the block copolymer. The composite may be treated to remove the polyester block, thereby forming a plurality of nano-pores.Type: ApplicationFiled: March 11, 2011Publication date: February 14, 2013Applicant: REGENTS OF THE UNIVERSITY OF MINNESOTAInventors: Marc Hillmyer, Louis Pitet, Mark Amendt
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Patent number: 8371475Abstract: Superabsorbents are metered by a process using a screw conveyor, wherein the superabsorbent is selected, or treated with a cohesion control agent, to have an unconfined yield strength of from 0.75 to 1.5 kPa at consolidation stress of 6 kPa.Type: GrantFiled: September 12, 2008Date of Patent: February 12, 2013Assignee: BASF SEInventors: Norbert Herfert, Herman Josef Feise, Hanno Rüdiger Wolf
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Publication number: 20120305827Abstract: The invention relates to a porous material comprising at least one polyfunctional isocyanate (a1) and at least one polyfunctional substituted aromatic amine (a2-s) of the general formula I where R1 and R2 are selected from among hydrogen and linear or branched alkyl groups having from 1 to 6 carbon atoms and all substituents Q1 to Q5 and Q1? to Q5? are selected from among hydrogen, a primary amino group and a linear or branched alkyl group having from 1 to 12 carbon atoms, where at least one of Q1, Q3 and Q5 and at least one of Q1?, Q3? and Q5? is a primary amino group and the compound has at least one linear or branched alkyl group having from 1 to 12 carbon atoms in the ? position relative to at least one primary amino group bound to the aromatic ring. The invention further relates to a process for producing porous materials, the porous materials which can be obtained in this way and the use of the porous materials as insulation material and in vacuum insulation panels.Type: ApplicationFiled: December 6, 2010Publication date: December 6, 2012Applicant: BASF SEInventors: Marc Fricke, Mark Elbing
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Publication number: 20120309053Abstract: A 3-dimensional porous polymeric structure comprising a porous polymer structure optionally with particles within the pores of the polymer and wherein the pores have a narrow pore-size distribution. The structure may be made by closely packing particles in a zone to provide a 3-dimensional array, contacting a polymerisable monomer with the array such that the composition fills interstitial spaces between the particles and effecting polymerisation of the monomer whereby a polymer structure is formed around the particles and optionally removing the particles from the structure. The 3-dimensional porous structure may be used in solid phase synthesis, immobilisation, cell culturing and preparation of a stationary phase for chromatographic separation, as an absorbent, an insulating material or in tissue regeneration.Type: ApplicationFiled: September 16, 2010Publication date: December 6, 2012Applicant: SPHERITECH LTDInventor: Donald A. Wellings
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Publication number: 20120302648Abstract: The invention relates to an implant material comprising a polymer which is partially cross-linked by means of a metal salt.Type: ApplicationFiled: September 20, 2010Publication date: November 29, 2012Applicant: AAP BIOMATERIALS GMBHInventors: Oliver Bielenstein, Stefan Deusser, Christoph Sattig, Volker Stirnal
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Patent number: 8304465Abstract: A method for the preparation of high strength air-dried organic aerogels. The method involves the sol-gel polymerization of organic gel precursors, such as resorcinol with formaldehyde (RF) in aqueous solvents with R/C ratios greater than about 1000 and R/F ratios less than about 1:2.1. Using a procedure analogous to the preparation of resorcinol-formaldehyde (RF) aerogels, this approach generates wet gels that can be air dried at ambient temperatures and pressures. The method significantly reduces the time and/or energy required to produce a dried aerogel compared to conventional methods using either supercritical solvent extraction. The air dried gel exhibits typically less than 5% shrinkage.Type: GrantFiled: January 18, 2006Date of Patent: November 6, 2012Assignee: Lawrence Livermore National Security, LLCInventors: Paul R. Coronado, Joe H. Satcher, Jr.
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Patent number: 8277719Abstract: A process for the preparation of thermoplastic auxetic foams comprising the steps of: a) taking conventional thermoplastic foam; b) subjecting said foam to at least one process cycle wherein the foam is biaxially compressed and heated; c) optionally subjecting the foam to at least one process cycle wherein the biaxial compression is removed and the foam mechanically agitated prior to reapplying biaxial compression and heating; d) cooling said foam to a temperature below the softening temperature of said foam; and e) removing said compression and heat.Type: GrantFiled: November 6, 2006Date of Patent: October 2, 2012Assignee: Auxetic Technologies Ltd.Inventors: Andrew Alderson, Kim Lesley Alderson, Philip John Davies, Gillian Mary Smart