Ingredient Contains A Silicon Atom Patents (Class 521/91)
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Patent number: 4933372Abstract: Porous, rigid resin particles are prepared having a predetermined particle size distribution, surface area and porosity by polymerizing in the pores of porous inorganic template particles a reaction mixture comprising monovinyl monomers, polyvinyl crosslinking monomers and a polymerization initiator in a liquid medium in which the monomers and initiator are phase separable and extractable therefrom into the pores of the template particles. The extracted mixture is polymerized in the pores of the template particles, and the template particles are removed without destruction of the polymerizate. The isolated polymerizate mirrors the characteristics of the template particles. The surface of the polymerizate may be modified in various ways to contain desired functionality. The particles of the invention are useful in chromatography, adsorption, ion exchange, and in catalysis.Type: GrantFiled: November 7, 1989Date of Patent: June 12, 1990Assignee: Supelco, Inc.Inventors: Binyamin Feibush, Nai-Hong Li
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Patent number: 4931490Abstract: An expandable polymer concrete or mortar composition, and process for producing it, which allows the use of low temperature cure resins by incorporating a substituted mineral which is able to expand in the polymer concrete mix so that the dilation of the mineral will counteract the shrinking effect of the curing resin. The substituted mineral may be selected from the montmorillonite group and is produced by substituting its water of hydration with a higher volatility composition such as ammonia.Type: GrantFiled: December 7, 1988Date of Patent: June 5, 1990Inventor: C. D. Armeniades
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Patent number: 4923907Abstract: A method of making thermal insulating products comprising porous, lightweight, high temperature resistant inorganic particles in a polyimide foam matrix and the product thereof. A polyimide precursor powdered is mixed with about equal weight of flake-like porous inorganic particles to substantially uniformly coat the particles with powder. The mixture is placed in a mold and compressed slightly. The assembly is heated to the foaming temperature of the polyimide precursor for a period suitable to product uniform foaming. Then the temperature is raised to the curing and crosslinking temperature of the precursor for a time period sufficient to product complete cure. A high temperature and flame resistant, light weight, highly insulating product results. If desired, protective sheets of material may be bonded to selected product surfaces during or after the molding operation.Type: GrantFiled: July 24, 1989Date of Patent: May 8, 1990Assignee: Sorrento Engineering, Inc.Inventor: Francis U. Hill
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Patent number: 4923538Abstract: A method of making thermal insulating products comprising porous, lightweight, high temperature resistant inorganic particles in a polyimide foam matrix and the product thereof. A polyimide precursor powdered is mixed with about equal weight of flake-like porous inorganic particles to substantially uniformly coat the particles with powder. The mixture is placed in a mold and compressed slightly. The assembly is heated to the foaming temperature of the polyimide precursor for a period suitable to produce uniform foaming. Then the temperature is raised to the curing and crosslinking temperature of the precursor for a time period sufficient to produce complete cure. A high temperature and flame resistant, light weight, highly insulating product results. If desired, protective sheets of material may be bonded to selected product surfaces during or after the molding operation.Type: GrantFiled: June 19, 1989Date of Patent: May 8, 1990Assignee: Sorrento Engineer, Inc.Inventor: Frank U. Hill
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Patent number: 4897141Abstract: Profound improvements and advantages are realized in the process of cutting semiconductor ingots to provide wafers if the adhesive used to bond said ingot to a mounting or cutting beam contains hollow microspheres.Type: GrantFiled: June 9, 1988Date of Patent: January 30, 1990Assignee: Valtech CorporationInventor: Richard T. Girard
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Patent number: 4889875Abstract: The present invention relates to hard foams having foamed and hardened phenolic resins as binding agents, and in which over 90% of the filler is aluminum hudroxide. The filler content is more than 100% with respect to the resin content of the foams. The foamble, filler-containing composition used for the production of the foams is very fluid and can be used directly for the production of moldings of any desired geometry. The aluminum hydroxide used has a grain size distribution such that between 30 to 60% of the filler is in the grain size range under 5 microns. The moldings containing the hard foam can also be in the form of composites. They are characterized not only by their good insulating properties but also by improved compressive strength, extremely little shirinkage tendency and extraordinarily high fire resistance. They are used mainly in the construction industry.Type: GrantFiled: December 23, 1987Date of Patent: December 26, 1989Assignees: Dynamit Nobel AG, Isobloc GmbHInventors: Aloys Aust, Josef Tiroux, Franz Weissenfels
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Patent number: 4879320Abstract: A fire-retardant coating material includes a fluid intumescent material and refractory fibers of various sizes dispersed or suspended therein for particular applications. The fluid intumescent material includes a foaming agent, a blowing agent gas source, a carbonific or charring agent, a film-forming binder, a solvent and, in some cases, a pigment or filler. The refractory fibers consist of aluminum oxide, silicon dioxide, and one or more other metal oxides.Type: GrantFiled: March 15, 1989Date of Patent: November 7, 1989Inventor: Otis H. Hastings
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Patent number: 4879138Abstract: A moldable and foamable thermoplastic composition comprising a major portion of moldable polypropylene resin; from about 1.25 to about 6 parts per hundred of resin (pphr) foam concentrate; from about 0.15 to about 1 pphr calcium carbonate; from about 0.03 to about 0.15 pphr amorphous silicon dioxide; from about 0.1 to about 0.4 pphr lubricant selected from the group consisting of synthetic waxes and distilled monoglycerides; from about 0.1 to about 0.4 pphr lubricant selected from the group consisting of N,N'-dioleoylethylenediamine and calcium stearoyl-2-lactylate; from about 0.15 to about 0.3 pphr unsaturated fatty monoamide; and from about 0.5 to about 2 pphr titanium dioxide concentrate.Type: GrantFiled: May 8, 1989Date of Patent: November 7, 1989Assignee: Permian Research CorporationInventors: Marion Johnson, Granville J. Hahn, Ramiro V. Ramoos
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Patent number: 4879317Abstract: A method is provided for reducing the density of silicone foam resulting from the generation of hydrogen gas by employing a hydride polysiloxane in the form of a mixture of linear hydride polysiloxane and cyclic hydride polysiloxane. Aqueous methanol is also found to be an effective density-reducing agent.Type: GrantFiled: January 24, 1989Date of Patent: November 7, 1989Assignee: General Electric CompanyInventors: Kennith A. Smith, Connie L. Haig
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Patent number: 4871782Abstract: Low viscosity elastomeric silicone foam compositions are produced which do not bleed, split or rupture with cure where viscosity is controlled by controlling the content of the vinyl containing polysiloxane portion of the foam.Type: GrantFiled: July 29, 1988Date of Patent: October 3, 1989Assignee: General Electric CompanyInventors: Frank J. Modic, Richard A. Striker
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Patent number: 4870111Abstract: Moldable foam beads comprising a silane-crosslinked polyolefin foam are produced by mixing a composition comprising a silane-modified polyolefin (such as a silane-grafted polyethylene) and a silanol condensation catalyst in an extruder to produce a melt, then injecting a blowing agent into the melt at a rate effective to produce a desired foam density in the extrudate; extruding and cutting the melt to form foam beads; and exposing the foam beads to moisture to produce silane crosslinking of the polyolefin foam.Type: GrantFiled: July 15, 1987Date of Patent: September 26, 1989Assignee: Astro-Valcour, IncorporatedInventors: Thomas M. Donuiff, Frederick H. Collins
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Patent number: 4865784Abstract: A method of making thermal insulating products comprising porous, lightweight, high temperature resistant inorganic particles in a polyimide foam matrix and the product thereof. A polyimide precursor provided is mixed with about equal weight of flake-like porous inorganic particles to substantially uniformly coat the particles with powder. The mixture is placed in a mold and compressed slightly. The assembly is heated to the foaming temperature of the polyimide precursor for a period suitable to produce uniform foaming. Then the temperature is raised to the curing and crosslinking temperature of the precursor for a time period sufficient to produce complete cure. A high temperature and flame resistant, light weight, highly insulating product results. If desired, protective sheets of material may be bonded to selected product surfaces during or after the molding operation.Type: GrantFiled: February 21, 1989Date of Patent: September 12, 1989Inventor: Francis U. Hill
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Patent number: 4866100Abstract: A moldable and foamable thermoplastic composition comprising a major portion of moldable polypropylene resin; from about 1.25 to about 6 parts per hundred of resin (pphr) foam concentrate; from about 0.15 to about 1 pphr calcium carbonate; from about 0.03 to about 0.15 pphr amorphous silicon dioxide; from about 0.1 to about 0.4 pphr lubricant selected from the group consisting of synthetic waxes and distilled monoglycerides; from about 0.1 to about 0.4 pphr lubricant selected from the group consisting of N,N'-dioleoylethylenediamine and calcium stearoyl-2-lactylate; from about 0.15 to about 0.3 pphr unsaturated fatty monoamide; and from about 0.5 to about 2 pphr titanium dioxide concentrate.Type: GrantFiled: May 17, 1988Date of Patent: September 12, 1989Assignee: Permian Research CorporationInventors: Marion Johnson, Granville J. Hahn, Ramiro V. Ramos
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Patent number: 4851452Abstract: A method is provided for reducing the density of silicone foam from a platinum catalyzed foamable two-package mixture of vinyl organosiloxane, organohydrogen siloxane, and hydroxylated material. The platinum catalyst used in the foamable mixture is in the form of a mixture of a platinum vinyl siloxane and a platinum triarylphosphine. A platinum catalyst mixture of platinum vinylsiloxane and triarylphosphine also has been found effective.Type: GrantFiled: August 1, 1988Date of Patent: July 25, 1989Assignee: General Electric CompanyInventors: David C. Gross, Larry N. Lewis, Connie L. Haig
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Patent number: 4843109Abstract: Shaped articles are provided containing a polymer which is capable of exhibiting anisotropy in the melt characterized in that the ratio of the stiffness in any two directions at right angles in the shaped article differs by at least 10%, and preferably by at least 50%, from the ratio in the same two directions for a control sample made from a melt consisting entirely of the polymer in anisotropic form.These may be obtained by a variety of methods including disturbing the normal flow pattern of flow into a mould by including obstacles to flow in the mould, disturbing the pattern of flow by foaming in the mould, by including fillers or by using polymers capable of existing as a bi-phase anisotropic and isotropic melt and forming shaped articles in which the two-phase disposition is retained.Type: GrantFiled: December 15, 1987Date of Patent: June 27, 1989Assignee: Imperial Chemical Industries PLCInventors: Derrick S. Bailey, Frederic N. Cogswell, Brian P. Griffin
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Patent number: 4843103Abstract: Foamed resinous products having excellent fire resistance, high thermal insulation and good resistance to heat are obtained at temperatures as low as room temperature and without the need for an added blowing agent by forming a mixture of a phenolic resole having a specified reactivity, an acid hardener for the resole and, uniformly dispersed through the mixture of resole and hardener, at least 20% by weight of a finely divided inert and insoluble particulate solid; products capable of being employed as wood-substitutes are obtained when a dihydric compound is included in the mixture and the solid is talc, fly ash and/or a hydraulic cement.Type: GrantFiled: April 2, 1986Date of Patent: June 27, 1989Assignee: Company "A" (Foam) LimitedInventors: Aldino Albertelli, Lothar M. Hohmann, Anthony N. Curtis
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Patent number: 4840974Abstract: A method is provided for reducing the density of silicone foam from a platinum catalyzed foamable two-package mixture of vinyl organosiloxane, organohydrogen siloxane, and hydroxylated material. The platinum catalyst used in the foamable mixture is in the form of a mixture of a platinum vinyl siloxane and a platinum triarylphosphine. A platinum catalyst mixture of platinum vinylsiloxane and triarylphosphine also has been found effective.Type: GrantFiled: December 5, 1988Date of Patent: June 20, 1989Assignee: General Electric CompanyInventors: David C. Gross, Larry N. Lewis, Connie L. Haig
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Patent number: 4808634Abstract: Ketoxime compounds are added to foamable elastomeric silicone foam contain organic alcohol as a hydroxyl source to reduce foam density.Type: GrantFiled: March 24, 1988Date of Patent: February 28, 1989Assignee: General Electric CompanyInventors: Richar J. Uriarte, David C. Gross
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Patent number: 4791144Abstract: Disclosed is a microporous polyproplene film comprising a propylene homopolymer, a copolymer of propylene with other copolymerizable monomer or a blend thereof, which has an intrinsic viscosity (.eta.) of 1.9 to 3.0 dl/g, especially 2.0 to 3.0 dl/g, as measured at 135.degree. C. in tetralin, said microporous film having a network structure comprising intercommunicating pores having a maximum pore size smaller than 1.mu. and an average pore size of 0.005 to 0.6.mu. and having a porosity of 30 to 90%, an air permeability of 5 to 500 sec/100 cc and a thickness of 5 to 200.mu., said microporous film being molecularly oriented by stretching.Type: GrantFiled: June 12, 1987Date of Patent: December 13, 1988Assignee: Tokuyama Soda Kabushiki KaishaInventors: Satoshi Nagou, Shunichi Nakamura
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Patent number: 4781781Abstract: A solid flexible polymeric material is formed by solidifying a water-based latex which contains an inorganic filler. The filler is sand and this may be stabilized in the latex with xanthan gum. The solid material may be a foamed or non-foamed layer which may be used as integral carpet backing, as carpet underlay, or as an adhesive for bonding a reinforcing fabric to the back of carpeting.Type: GrantFiled: August 27, 1987Date of Patent: November 1, 1988Inventor: Gerald Hallworth
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Patent number: 4765915Abstract: A method for filtering liquid or gaseous materials where the filtration is conducted with a porous filter media prepared from an aqueous wet-laid, lofted fiber-reinforced composite sheet, the composite sheet comprising a heat fusible polymer, reinforcing fibers and a binder. The random fiber composite sheet can be selectively lofted or recompressed to form filter media having variable porosity. Also, a membrane support means prepared by applying or treating the fiber-reinforced composite sheet with a discriminating membrane layer.Type: GrantFiled: April 14, 1986Date of Patent: August 23, 1988Assignee: The Dow Chemical CompanyInventor: Charles F. Diehl
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Patent number: 4764535Abstract: Elastomer compositions suitable for use in foaming operations and elastomeric cellular products and processes of forming such products. The elastomer compositions comprise a mixture of two thermoplastic rubber compounds, at least one of which has a vinyl aromatic component and a higher aromaticity than the other rubber compound. The compositions also contains a nucleating agent which functions when gas is entrained in the molten elastomer formulation to enhance the neutrophilic structure of the elastomer. An unstable resin is also present in the elastomer compositions. This resin is oxidized or thermally decomposed as the foamed product is cured to produce a relatively nontactified skin. Cellular elastomeric products may be formed by incorporating an inert gas into the molten elastomer compositions by the use of gas infusing equipment or by the decomposition of blowing agents. The blowing agents may be supplied to the molten elastomer compositions entrained within a plasticizing oil.Type: GrantFiled: August 6, 1984Date of Patent: August 16, 1988Assignee: Q'SO, Inc.Inventor: Larry F. Leicht
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Patent number: 4762859Abstract: Treated filler having surface nitrogen groups is added to silicone foam to reduce density.Type: GrantFiled: October 26, 1987Date of Patent: August 9, 1988Assignee: General Electric CompanyInventors: Frank J. Modic, Richard A. Striker
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Patent number: 4753746Abstract: The invention is directed to a detergent and a method of producing the same. The detergent is for textile surfaces and especially for textile floor coverings. The detergent includes a pulverized, porous carrier including a foamed, plastified urea-formaldehyde resin foam. The carrier material is enriched with detergent so that the finished product with respect to the carrier material has a weight per unit volume of 60 kg/m.sup.3 and an apparent density of 50 to 150 grams/liter; the granular size of the carrier material is between 0.01 and 12 mm; the surfactant containing water, which adheres to the carrier material, is stored in the carrier material in a completely homogeneous manner in a share of maximally 80% by weight referred to the weight of the carrier material; and, the detergent is produced from the mixture of the carrier material with a highly concentrated aqueous cleaning solution.Type: GrantFiled: December 19, 1986Date of Patent: June 28, 1988Assignee: Vorwerk & Co. Interholding GmbHInventors: Otto Mesmer, Wolfgang Polligkeit, Ernst-Uwe Schiffer, Wolfgang Troger, Andreas Wolter
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Patent number: 4737523Abstract: Foamable, thermoplastic molding composition exhibiting an improved level of impact resistance is provided. The composition, which is suitable for the preparation of expanded molded parts, comprise a thermoplastic resin, preferably at least one selected from a group consisting of polycarbonate, polyalkylene terephthalate, aromatic polyester and polyester carbonate, a nucleating agent, a chemical blowing agent and an anhydride. It was unexpectedly found that the composition is suitable for the molding of articles having an improved level of impact resistance.Type: GrantFiled: June 19, 1987Date of Patent: April 12, 1988Assignee: Mobay CorporationInventors: Roger J. White, Sivaram Krishnan, Wolfgang J. Siebourg
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Patent number: 4731389Abstract: The invention relates to foams for insulating cavities and structures, such as spaces between walls in houses. The inventive foam compositions are prepared in separate portions, generally comprising (A) cement and (B) foam. Air is added initially to foam one of the components or a mixture of components.In a first embodiment, the first component comprises an aqueous solution of polyvinyl alcohol and a dispersant. This component is mechanically foamed by injection of air, for example. After the mechanical foaming a second, cement component is added to the first component. This second component comprises an aqueous solution, mixture or suspension of magnesium oxide and barium metaborate, and a dispersant.In a second, preferred embodiment, the first component comprises an aqueous solution of polyvinyl alcohol and calcium chloride, which component is mechanically foamed by injection of air.Type: GrantFiled: November 14, 1985Date of Patent: March 15, 1988Assignee: Air Krete, Inc.Inventors: R. Keene Christopher, Donald Thomson
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Patent number: 4719243Abstract: The specification is directed to polysiloxane foams. There are disclosed compositions capable of curing at room temperature which comprise a hydroxypolysiloxane, an alkylhydrogen polysiloxane, a tin compound as catalyst and finely divided filler. According to the invention storage stability of these foam forming polysiloxane compositions is improved by use as filler of silica which has been pretreated to render is hydrophobic. The subject compositions may comprise two components which do not require individual mixing prior to mixing together of the components. The compositions may be packaged in any convenient manner. The compositions may be used for a variety of purposes, for example to provide medical dressings.Type: GrantFiled: November 10, 1986Date of Patent: January 12, 1988Assignee: Dow Corning France S.A.Inventor: David Pocknell
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Patent number: 4713285Abstract: A high temperature filter material, comprising a non-woven glass fiber matrix including mica particles, polymer micro-bits and a uniformly distributed binder system, is made by a wet laid procedure, as used in paper-making. A composition comprising the mica particles and polymer micro-bits, used in making the filter material, and a method of preparing the composition are also disclosed.Type: GrantFiled: May 2, 1986Date of Patent: December 15, 1987Assignees: Frederick G. Crane, Jr., Max Klein, TrusteeInventor: Max Klein
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Patent number: 4710520Abstract: A high temperature filter material, comprising a non-woven glass fiber matrix including mica particles, polymer micro-bits and a uniformly distributed binder system, is made by a wet laid procedure, as used in paper-making. A composition comprising the mica particles and polymer micro-bits, used in making the filter material, and a method of preparing the composition are also disclosed.Type: GrantFiled: May 2, 1986Date of Patent: December 1, 1987Inventor: Max Klein
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Patent number: 4704408Abstract: A process for manufacturing foamed silicone compositions by foaming a cross-linkable composition which comprises:(a) 100 parts by weight of a vinyl-containing polysiloxane containing 0.0002 to 3% by weight of vinyl groups and a viscosity of from 0.1 to 1,000 Pascal-seconds at 25.degree. C.,(b) up to 10 parts by weight of a silanol-containing silicon compound with a viscosity from 0.01 to 10 Pascal-seconds at 25.degree. C.,(c) up to 200 parts by weight of filler,(d) 1 to 50 parts by weight of a polysiloxane with a viscosity of 0.005 to 0.1 Pascal-seconds at 25.degree. C., and(e) a platinum catalyst, is characterized by foaming the cross-linkable composition with a substance containing hydroxyl groups at temperatures of 50.degree. to 150.degree. C.Type: GrantFiled: November 20, 1985Date of Patent: November 3, 1987Assignee: Bayer AktiengesellschaftInventors: Wolfgang Krug, Gottfried Knispel, Dieter Wrobel
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Patent number: 4702868Abstract: Moldable foam beads comprising a silane-crosslinked polyolefin foam are produced by mixing a composition comprising a silane-modified polyolefin (such as a silane-grafted polyethylene) and a silanol condensation catalyst in an extruder to produce a melt, then injecting a blowing agent into the melt at a rate effective to produce a desired foam density in the extrudate; extruding and cutting the melt to form foam beads; and exposing the foam beads to moisture to produce silane crosslinking of the polyolefin foam.Type: GrantFiled: February 24, 1987Date of Patent: October 27, 1987Assignee: Valcour IncorporatedInventors: Thomas M. Pontiff, Frederick H. Collins
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Patent number: 4692473Abstract: A foam polyvinyl product prepared from a composition comprising a vinyl polymer and an alkali carbonate foaming agent.Type: GrantFiled: April 26, 1985Date of Patent: September 8, 1987Assignee: Orin Chemical CompanyInventors: Thomas C. Wright, Grover L. Johnson
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Patent number: 4686244Abstract: The intumescent material of this invention comprises a filled polyorganosiloxane composition that is elastomeric in the cured form and up to 70 parts by weight per 100 parts by weight of said composition of hollow, thermoplastic microspheres filled with a volatile liquid. The materials are particularly useful as flame and smoke barriers in passages of partitions that are traversed by thermoplastic articles such as pipes and conduits, and can optionally contain chemical blowing agents.Type: GrantFiled: December 17, 1986Date of Patent: August 11, 1987Assignee: Dow Corning CorporationInventors: John E. Dietlein, Thomas C. Hampton
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Patent number: 4683247Abstract: Foamable thermoplastic compositions are described which are based on pre-compounded concentrated blends of an inorganic non-fibrous particulate foaming agent and a carrier polymer. The foamable thermoplastic polymer is selected from among aromatic polycarbonates alone or with acrylonitrile-butadiene-styrene copolymers polyesters, poly(ester-carbonates), and polyetherimides. The foaming agent may optionally be added as part of the concentrate.Type: GrantFiled: December 28, 1984Date of Patent: July 28, 1987Assignee: General Electric CompanyInventors: Richard B. Allen, Roger W. Avakian
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Patent number: 4681715Abstract: A steam expandable alkenyl aromatic polymer composition and methods of preparation are provided. The composition is mixed with a volatile blowing agent containing, as a primary blowing agent, dichlorodifluoromethane and as a secondary blowing agent, a halogenated hydrocarbon, a hydrocarbon, or an aliphatic alcohol containing from 1 to 4 carbon atoms, the secondary blowing agent having a normal atmospherpic boiling point of from about 0.degree. to about 100.degree. C. The composition may be expanded by steam immediately after extrusion foaming or may be expanded after aging of the composition which has been impregnated with volatile blowing agent.Type: GrantFiled: September 20, 1985Date of Patent: July 21, 1987Assignee: The Dow Chemical CompanyInventors: Chung P. Park, Gerald A. Garcia
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Patent number: 4655952Abstract: The invention is directed to a detergent and a method of producing the same. The detergent is for textile surfaces and especially for textile floor coverings. The detergent includes a pulverized, porous carrier including a foamed, plastified urea-formaldehyde resin foam. The carrier material is enriched with detergent so that the finished product with respect to the carrier material has a weight per unit volume of 60 kg/m.sup.3 and an apparent density of 50 to 150 grams/liter; the granular size of the carrier material is between 0.01 and 12 mm; the surfactant containing water, which adheres to the carrier material, is stored in the carrier material in a completely homogeneous manner in a share of maximally 80% by weight referred to the weight of the carrier material; and, the detergent is produced from the mixture of the carrier material with a highly concentrated aqueous cleaning solution.Type: GrantFiled: February 26, 1985Date of Patent: April 7, 1987Assignee: Vorwerk & Co. Interholding GmbHInventors: Otto Mesmer, Wolfgang Polligkeit, Ernst-Uwe Schiffer, Wolfgang Troger, Andreas Wolter
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Patent number: 4650816Abstract: Disclosed are rigid materials such as sheets, boards or tubes made of expanded polypropylene, which have a uniform specific gravity d of from about 4.1.times.10.sup.-6 to about 8.1.times.10.sup.-6 Newton/mm.sup.3, a crystallization temperature of from about 115.degree. C. to about 135.degree. C. and a flexural modulus Mf expressed in Newton/mm.sup.3 such that the ratio Mf:d is from about 1.5.times.10.sup.8 to about 1.7.times.10.sup.8 mm.Type: GrantFiled: September 30, 1985Date of Patent: March 17, 1987Assignee: Montefina, S.A.Inventor: Jean-Noel M. Bertrand
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Patent number: 4638015Abstract: Disclosed are films made of expanded polypropylene, which have a uniform specific gravity d of from about 4.25.times.10.sup.-6 to about 6.50.times.10.sup.-6 Newton/mm.sup.3, a crystallization temperature of from about 115.degree. C. to about 135.degree. C. and an elastic modulus Me expressed in Newton/mm.sup.3 such that the ratio Me:d is from about 1.6.times.10.sup.8 to about 2.0.times.10.sup.8 mm.Type: GrantFiled: September 30, 1985Date of Patent: January 20, 1987Assignee: Montefina, S.A.Inventor: Jean-Noel M. Bertrand
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Patent number: 4623478Abstract: A composition for foaming polyester which includes a carbonate or bicarbonate salt and water intermixed with a finely divided solid free flow agent such as synthetic amorphous silica. The free flow agent is added in an amount sufficient to absorb all of the water and render the composition a free flowing powder. The composition is readily mixable with an unsaturated polyester resin media. A source of acid in the mixture liberates gas from the carbonate or bicarbonate, and good foam structures having small uniform cells are obtained.Type: GrantFiled: March 6, 1986Date of Patent: November 18, 1986Assignee: U.S. Peroxygen CompanyInventor: Ronald L. Pastorino
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Patent number: 4608396Abstract: A method of producing elastomeric silicone foams from a two-part system is disclosed. The method mixes the ingredients then allows a froth to form and cure at ambient temperature to an elastomeric silicone foam. The method mixes a vinyl-containing polydiorganosiloxane (1), a hydroxylated polydiorganosiloxane (2), a platinum catalyst (3), an organohydrogensiloxane (4) and a profoamer (5). The profoamer is a resinous, benzene-soluble organosiloxane copolymer consisting essentially of SiO.sub.4/2 units, silicone bonded hydroxyl groups, (CH.sub.3).sub.3 SiO.sub.1/2 units, and fluorine-containing units. An embodiment of the method includes a liquified blowing agent and stores the mixture under superatmospheric pressure, forming a foam by releasing the mixture to atmospheric pressure. Another embodiment includes an alcohol in the mixture to provide a foam of lower density.Type: GrantFiled: February 3, 1986Date of Patent: August 26, 1986Assignee: Dow Corning CorporationInventors: Therese M. Bauman, Chi-Long Lee, James A. Rabe
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Patent number: 4607060Abstract: Crosslinked elastomeric and/or thermoplastic closed-cell foams having low densities are prepared from an admixture which comprises a crosslinkable thermoplastic and/or elastomeric polymer, a free radical initiator which is activated at temperatures from about 50.degree. C. to about 350.degree. C., and a t-alkylhydrazinium salt or a carbonylhydrazine.Type: GrantFiled: September 30, 1985Date of Patent: August 19, 1986Assignee: Pennwalt CorporationInventors: Chester J. Kmiec, Michael F. Novits, Edward P. Hibbard
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Patent number: 4604408Abstract: A composition for making a cellular thermoset polymer comprised of polymerized units of dicyclopentadiene monomer. The composition includes dicyclopentadiene, a catalyst, and a blowing agent.Type: GrantFiled: June 17, 1985Date of Patent: August 5, 1986Assignee: Hercules IncorporatedInventor: Norman R. Newburg, deceased
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Patent number: 4594362Abstract: A dry-type textile cleaning article is disclosed which comprises a friable hydrophilic polyurethane foam body which incorporates abrasive particles, solvents, surfactants, and adjuvants such as fragrance, biocides, and fiber emollients. When rubbed over a textile surface the foam body yields shreds which are effective to remove both liquid and dry soils from textiles.Type: GrantFiled: October 31, 1985Date of Patent: June 10, 1986Assignee: Creative Products Resource Associates, Ltd.Inventors: James A. Smith, Betty J. Murphy
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Patent number: 4594368Abstract: Intumescent coatings which form a thick, uniform, fine celled, low density foam upon exposure to a high intensity heat flux or flame are disclosed, the invention coatings comprise phenolic resin prepolymer containing a blowing agent and a nucleating agent; in the preferred embodiments the coatings also contains a silicone surfactant, the coatings are useful in thermal and fire protection systems.Type: GrantFiled: June 27, 1984Date of Patent: June 10, 1986Assignee: University of DaytonInventors: Ival O. Salyer, Bernard L. Fox
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Patent number: 4593049Abstract: A method of producing elastomeric silicone foams from a two-part system is disclosed. The method mixes the ingredients then allows a froth to form and cure at ambient temperature to an elastomeric silicone foam. The method mixes a vinyl-containing polydiorganosiloxane (1), a hydroxylated polydiorganosiloxane (2), a platinum catalyst (3), an organohydrogensiloxane (4) and a profoamer (5). The profoamer is a resinous, benzene-soluble organosiloxane copolymer consisting essentially of SiO.sub.4/2 units, silicone bonded hydroxyl groups, (CH.sub.3).sub.3 SiO.sub.1/2 units, and fluorine-containing units. An embodiment of the method includes a liquified blowing agent and stores the mixture under superatmospheric pressure, forming a foam by releasing the mixture to atmospheric pressure. Another embodiment includes an alcohol in the mixture to provide a foam of lower density.Type: GrantFiled: October 16, 1985Date of Patent: June 3, 1986Assignee: Dow Corning CorporationInventors: Therese M. Bauman, Chi-Long Lee, James A. Rabe
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Patent number: 4590222Abstract: This invention discloses a method of controlling the relative physical properties of foams such as density and compressibility or density and Bashore resiliency for compositions which consist essentially of triorganosiloxy endblocked polydiorganosiloxane having at least two vinyl radicals, platinum catalyst, organohydrogensiloxane, and hydroxyl endblocked polydiorganoisiloxane. The relative values of the physical properties are adjusted by the addition of varying amounts of organic alcohol having from 3 to 12 carbon atoms to the composition.Type: GrantFiled: October 16, 1985Date of Patent: May 20, 1986Assignee: Dow Corning CorporationInventor: Therese M. Bauman
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Patent number: 4590220Abstract: This invention describes a method of producing a silicone elastomer from an emulsion. When the ingredients are mixed together, the resulting latex can be used immediately. Removing the water from the latex results in a silicone elastomer. The method combines (A) an anionically stabilized, hydroxyl endblocked polydiorganosiloxane, present as an emulsion of dispersed particles in water, the emulsion having a pH of greater than 9, (B) dialkyltindicarboxylate, (C) alkylorthosilicate, (D) colloidal silica, and optionally (E) water, admixing (A) and (B) only in the presence of (C) to produce a dispersion of the ingredients in water. The ingredients can be distributed into a two-part system for storage. One embodiment includes fibers, lauryl alcohol, or a mixture of both in the emulsion; then forms an open-cell, elastomeric foam by forming a froth from the emulsion and removing the water from the froth.Type: GrantFiled: May 24, 1985Date of Patent: May 20, 1986Assignee: Dow Corning CorporationInventors: Therese M. Bauman, Alan L. Freiberg
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Patent number: 4590123Abstract: A soft, low-resilience, cured rubber composition is prepared by mixing(a) 100 parts by weight of a polymeric material comprising a styrene-butadiene copolymer or styrene-butadiene copolymer mixture having a styrene content of 53 to 75% by weight, and 0 to 40% by weight of the polymeric material of another rubber ingredient,(b) 30 to 300 parts by weight of a filler, and(c) 5 to 100 parts by weight of a plasticizer, adding effective amounts of a vulcanizing agent and a vulcanizing accelerator to the mixture, and then heat curing the mixture. A similar composition further containing a foaming agent may be heat cured into a low-resilience rubber foam. Rubber and foamed rubber compositions have improved vibration-attenuating and shock-absorbing properties.Type: GrantFiled: July 16, 1985Date of Patent: May 20, 1986Assignee: Bridgestone Tire Co., Ltd.Inventors: Takatsugu Hashimoto, Takashi Ohashi
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Patent number: 4588752Abstract: Closed-cell crosslinked sponges of varying densities are prepared from an admixture of a vulcanizable elastomer, vulcanizing ingredients selected from sulfur or sulfur donor compounds together with metal oxides and/or sulfur vulcanization accelerators and a t-alkylhydrazinium salt and/or carbonylhydrazine. The crosslinked sponges have uniform cellular structures and are easily prepared with the desired density.Type: GrantFiled: September 30, 1985Date of Patent: May 13, 1986Assignee: Pennwalt CorporationInventors: Chester J. Kmiec, Michael F. Novits
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Patent number: 4584324Abstract: A composition useful in producing an open-cell, elastomeric silicone foam combines a silicone oil-in-water emulsion, which forms an elastomer upon removal of the water, with an aerosol propellant. When the composition is discharged to atmospheric pressure, a froth is formed. Removing water from the froth yields an open-cell foam. The froth is stabilized by surfactants, thickeners, or froth stabilizers selected from fibers or lauryl alcohol.Type: GrantFiled: September 30, 1985Date of Patent: April 22, 1986Assignee: Dow Corning CorporationInventors: Therese M. Bauman, Chi-Long Lee, James A. Rabe