Abstract: Polystyrene melts treated with flameproofing agents and nucleating agents are foamed by addition of alkanes, such as propane, butane or propane/butane mixtures, as blowing agents, such that the flame retardant properties of the polystyrene foams are achieved after a very short storage time, or at the latest after storage for three weeks at room temperature. Even after a storage time of one week, sufficient blowing agent is still present in the closed-cell pores of the polystyrene foams to be able to undertake adequate post-expansion of the foams with a foaming factor of 1.8 to 2.0.

Abstract: Disclosed is a process for making a thermoplastic polymer foam structure with a blowing agent having water. The process comprises in sequence: a) melting the polymer to form a polymer melt; b) incorporating a brominated aliphatic fire retardant into the polymer melt; c) incorporating and mixing a first blowing agent into the polymer melt to form a first foamable gel; d) cooling the first foamable gel to a suitable foaming temperature; e) incorporating and mixing a second blowing agent comprising water into the cooled first foamable gel to form a second foamable gel; f) optionally further cooling the second foamable gel to a suitable foaming temperature; and g) extruding the second foamable gel through an extrusion die to form a foam structure. Incorporating of the water blowing agent downstream in the process after the foamable gel has been cooled reduces or minimizes process corrosion problems. Further disclosed is an apparatus for making the foam structure.

Abstract: To replace chlorofluorocarbons as refrigerant fluids, the invention proposes to employ mixtures containing, on a mass basis, approximately 25 to 65% of 1,1,1-trifluoroethane, 1 to 70% of perfluoropropane and 5 to 34% of propane.The mixtures according to the invention can also be employed as aerosol propellants or as blowing agents for plastic foams.

Abstract: Polystyrene melts treated with flameproofing agents and nucleating agents are foamed by addition of alkanes, such as propane, butane or propane/butane mixtures, as blowing agents, such that the flame retardant properties of the polystyrene foams are achieved after a very short storage time, or at the latest after storage for three weeks at room temperature. Even after a storage time of one week, sufficient blowing agent is still present in the closed-cell pores of the polystyrene foams to be able to undertake adequate post-expansion of the foams with a foaming factor of 1.8 to 2.0.

Abstract: The invention relates to a method for inhibiting the degradation by dehydrohalogenation of hydrochlorofluorocarbons, such as for example the mixture of 123 and 123a, used as foaming agents during the formation reaction of foamed polyurethanes or polyisocyanurates starting from polyols and polyisocyanates. Prior to the reaction starting, a little amount of a stabilizing substance selected from the group consisting of nitromethane, nitroethane and 1-nitropropane is added to the reaction medium.

Abstract: An expandable thermoplastic composition is disclosed for extrusion foaming wherein the composition comprises a polyethylene resin; a blowing agent, which is either ethane or a blend of carbon dioxide and either normal butane, isobutane, propane, ethane, or a mixture of any two or more of these hydrocarbons in admixture with the resin in a ratio of about one part blowing agent to about 10 parts resin; nucleation agent in an amount of from about 0.05 to 0.5 kg per 100 kg of the resin; and glycerol monostearate aging modifier in an amount of from about 0.5 to 5 kg per 100 kg of the resin. A process for extrusion foaming of the composition is also disclosed.

Abstract: A new set of effective, environmentally safe, nonflammable, low-toxicity refrigerants, solvents, foam blowing agents, propellants, and firefighting agents is disclosed. The agents are clean, electrically nonconductive, and have short atmospheric lifetimes, zero ozone-depletion potential, and low global warming potentials. The agents comprise at least one fluoroiodocarbon agent satisfying the general formula C.sub.a H.sub.b Br.sub.c Cl.sub.d F.sub.e I.sub.f N.sub.g O.sub.h, wherein a is between and including 1 and 8; b is between and including 0 and 2; c, d, g, and h are each between and including 0 and 1; e is between and including 1 and 18; and f is between and including 1 and 2, either neat or mixed with additives selected from the group consisting of: alcohols, esters, ethers, fluoroethers, hydrocarbons, hydrofluorocarbons, and perfluorocarbons.

Abstract: This invention relates to the production of low density resol foams from resol resins. The foams have a density of 2.0 pounds per cubic foot or less and are produced with a blowing agent of low boiling point HCFCs and perfluoroalkane.

Abstract: A method for lowering the melt flow rate of flame retardant expanded polystyrene is provided. The method comprises treating the flame retardant expanded polystyrene with an aqueous solution of sodium bicarbonate. In another aspect of the present invention a method for pelletizing recycled flame retardant expanded polystyrene is provided. The method comprises treating ground flame retardant polystyrene in an aqueous solution of sodium bicarbonate; condensing the treated polystyrene; extruding the polystyrene; and pelletizing the polystyrene. In another aspect of the present invention the electrostatic build-up on polystyrene is reduced by contacting the polystyrene with an aqueous solution of sodium bicarbonate.

Abstract: A process for providing extrudable polyacrylonitrile compositions. Dry, particulate polyacrylonitrile having a moisture content of less than about 1.5 percent is mixed with a liquid plasticizer such as ethylene carbonate or propylene carbonate at a mixing temperature of about 140.degree. C. to about 180.degree. C. This process produces an extrudable polyacrylonitrileplasticizer composition which can be extruded to form film, fiber or other extruded or co-extruded products.

Abstract: A coated wire comprising:(i) an electrical conductor coated with(ii) a mixture of (a) two linear copolymers of ethylene and one alpha-olefin having 3 to 8 carbon atoms, the first ethylene copolymer having a density of about 0.900 to 0.930 gram per cubic centimeter and a melt index of about 0.1 to about 5 grams per 10 minutes and the second ethylene copolymer having a density of 0.931 to about 0.950 gram per cubic centimeter and a melt index of about 0.1 to about 5 grams per 10 minutes, and for each 100 parts by weight of the first ethylene copolymer, there are about 15 to about 100 parts by weight of the second ethylene copolymer, and (b) for each 100 parts by weight of component (a), there are about 65 to about 150 parts by weight of a mixture comprising huntite and hydromagnesite in a weight ratio of about 2:1 to about 1:1.

Abstract: An expandable monovinylidene aromatic polymer resin composition comprising: a) a monovinylidene aromatic substrate polymer; b) a plasticizing amount of a solid (at room temperature and pressure), low molecular weight polymer of limonene or alpha methyl styrene and, optionally, another copolymerizable vinyl aromatic monomer, having a weight average molecular weight of from about 1,000 to about 70,000, a volatiles content of up to about 30% and a glass transition temperature of at least about 25.degree. C.; and c) a blowing agent. The invention further includes a process for producing a closed-cell polymer foam from the composition of the invention, and the resulting polymer foam. Advantageously, the foam of the invention can be produced using only CO.sub.2 as a blowing agent.

Abstract: Substantially constant boiling blowing agent compositions of 1,1,1,2-tetrafluoroethane and dimethyl ether.

Abstract: Disclosed is an ethylene polymer foam structure having enhanced processing and physical properties. The foam structure comprises an ethylenic polymer material and a blowing agent of isobutane and 1,1-difluoroethane. Further disclosed is a process for making the foam structure.

Abstract: Disclosed are a foamable resin composition which comprises a copolymer with a weight-average molecular weight of 150,000-350,000 produced by copolymerization of a monomer mixture of 55-85% by weight of styrene and 45-15% by weight of a methacrylic acid ester represented by general formula (I)CH.sub.2 .dbd.C(CH.sub.3)COOR (I)(wherein R represents a C.sub.

Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.

Abstract: Disclosed is an ethylene polymer foam structure having enhanced processing and physical properties. The foam structure comprises an ethylenic polymer material and a blowing agent. The blowing agent has a primary blowing agent of isobutane and a secondary blowing agent of 1,1,1-trifluoroethane, 1,1,1,2-tetrafluoroethane, or a blend of them. Further disclosed is a process for making the foam structure.

Abstract: Disclosed is a compatibilized carbon black useful in melt processing of plastic material. The carbon black is coated with a compatibilizing agent which enhances the dispersibility of the carbon black in a melt of the plastic material. Further disclosed are processes for making plastic foam structures with the compatibilized carbon black.

Abstract: Disclosed is a foamable styrenic polymer gel capable of forming a closed-cell foam structure, comprising: a) a flowable melt of a styrenic polymer material comprising greater than 50 percent by weight styrenic monomeric units and about 0.1 to about 40 percent by weight of oxygen-containing monomeric units based upon the total weight of the styrenic polymer material; and b) a blowing agent comprising about 5 weight percent or more carbon dioxide based upon the total weight of the blowing agent. Further disclosed is a process for making the foam structure. The oxygen-containing comonomer content in the styrenic polymer material enables process operating pressures to be significantly reduced when using carbon dioxide as a blowing agent compared to a styrenic polymer material without comonomer content. The foam structure formed is of low density and of good quality.

Abstract: A process for producing shaped foamable parts from a polymer composition containing polymer and a foaming and curing additive package which includes the steps of:(a) dry blending at least the blowing agent part of the foaming and curing additive package of the composition with a wax powder to produce a dry blend;(b) melt blending the dry blend and any residual parts of the composition at a temperature between the melting point and not more than 10.degree. C., preferably not more than 5.degree. C., above the melting point using a low shear condition to produce a melt blend;(c) molding the melt blend within the temperature and shear conditions of step (b).Foamable parts having good foam characteristics can be made on an industrial scale. The closed-foam cells are even. The foam adheres to metal surfaces.

Abstract: A water-permeable and fire-resistant product and the preparing method thereof is disclosed. The waterpermeable and fire-resistant product is made of a fabric layer and a purous film adhered thereon. The porous film of this invention comprises polyurethane resin; a first fire-resistant agent; a second fire-resistant agent, an inorganic fire-resistant agent and an additive agent. The first fire-resistant agent used is selected from the group consisting of paraffine chlorinated, decabromodiphenyl oxide, hexachloro benzene, hexabromo benzene, pentabromo ethyl benzene, pentabromo diphenyl oxide and octabromo diphenyl ether. The second fire-resistant agent used is selected from the group consisting of Sb2O3 and Sb2O5. The surface of the product produced is smooth.

Abstract: Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63; b) a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation M.sub.w /M.sub.n .gtoreq.(I.sub.10 /I.sub.2)-4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n. The foam structures have toughness and elasticity similar to those formed from conventional LLDPE without the poor dimensional stability and foam quality associated with those structures. The foam structures have foam quality similar to those made with conventional LDPE but with enhanced toughness and elasticity. Further disclosed is a process for making the above foam structure and making it in a foam bead form.

Abstract: A process for producing an expandable resin composition for a small diameter electric wire insulated with highly expanded cellular polyethylene which comprises (1) heat-kneading at a temperature higher than 135.degree. C. a mixture comprising: (i) a low density polyethylene having a density ranging from about 0.890 to 0.925 g/ml; (ii) a high density polyethylene having a melting point higher than 130.degree. C.; and (iii) a polyolefin wax having an average molecular weight ranging from about 1500 to 8000 and a melting point ranging from about 100.degree. C. to 160.degree. C.; and (2) heat kneading at a temperature ranging from 120.degree. C. to 130.degree. C. and at a preliminary expansion ratio lower than 5% the mixture of step (1) with a low temperature decomposable chemical blowing agent.

Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.

Abstract: An elastomeric, hot-melt adhesive foam is disclosed. The adhesive foam preferably comprises an elastomeric, hot-melt adhesive material formed from:(a) about 15% to about 60%, by weight of the adhesive material, of an A-B-A block copolymer, in which the A block is derived from styrene and the B block is derived from butadiene or isoprene;(b) about 30% to about 70%, by weight of the adhesive material, of an aromatic modified hydrocarbon resin which associates with both the B block and A blocks of the A-B-A block copolymer; and(c) 0 to about 30%, by weight of the adhesive material, of a processing oil.The proportions of the components (a), (b), and (c) are selected such that the elastomeric, hot-melt adhesive material has a viscosity of less than about 200,000 centipoise at 325.degree. F. and an elastomeric retention value of at least 75%.

Abstract: An improved polystyrene foam having less corrugation is disclosed which uses carbon dioxide as the blowing agent and 1-30 weight percent endothermic agent, such as water, with the weight based on the total carbon dioxide blowing agent and endothermic agent weight. This combination of carbon dioxide and endothermic agent decreases the corrugation of the thermoplastic foam, while just slightly increasing density, when the process parameters, including throughput, are equivalent to using only carbon dioxide. The process an also allow an increased foaming temperature and greater process throughput of an equivalent density thermoplastic foam at approximately equivalent corrugation levels when compared to the use of only using only carbon dioxide.

Abstract: Azeotrope-like mixtures of 1,1-dichloro-2,2,2-trifluoroethane and 1,1-dichloro-1-fluoroethane, being useful as cleaning solvents, refrigerants and foam blowing agents.

Abstract: The present invention provides hydrochlorofluorocarbons having 3 to 5 carbons atoms, 1 to 2 chlorine atoms, and an OH rate constant from about 8 to about 25 cm.sup.3 /molecule/sec.times.10.sup.-14. The hydrochlorofluorocarbons are useful as solvents and blowing agents.

Abstract: Blowing agents for use in foamable plastics such as polystyrene, polyvinyl chloride, polyethylene and other non-polyisocyanate-based foams, comprising a mixture of 1,1,1,2,3,3,3-heptafluoropropane in combination with one or more hydrocarbons or partially halogenated alkanes. In one aspect of the invention the hydrocarbon adjuvant is selected from the group consisting of propane, butane, isobutane, n-pentane, i-pentane, neopentane, n-hexane, 2-methylpentane, 3-methylpentane and 2,2-dimethylbutane.

Abstract: The invention relates to azeotropic and pseudoazeotropic compositions comprising difluoromethoxy-2,2,2-trifluoroethane with 2,2-dichloro-1,1,1-trifluoroethane or with 1,1-dichloro-1-fluoroethane. These compositions can be employed as solvents, especially for cleaning electronic components and for degreasing metals, as blowing agents, especially for the preparation of polyurethane foams, or as refrigerants.

Abstract: Process of mixing a fugitive plasticizer, e.g., ethylene carbonate, with moist particulate polyacrylonitrile then removing the water enabling adjustment of the melt viscosity for extrusion of the polyacrylonitrile into film, fiber, pellets and shaped articles. Stretching and heating the extruded polyacrylonitrile film or fiber causes the fugitive plasticizer to exude and vaporize from the film or fiber, carrying with it any remaining acrylonitrile monomer. The resulting film or fiber exhibits substantially increased molecular weight, thus enhancing the tensile strength and barrier properties of the polyacrylonitrile product. The process also produces polyacrylonitrile foam products. A novel cross-linking agent for polyacrylonitrile, divinyloxybutane, is disclosed. Thermostabilizing agents for polyacrylonitrile, N-maleimides and stilbene derivatives, are also disclosed.

Abstract: The present invention relates to a process to produce polystyrene foam comprising mixing a predetermined amount of masterbatch mix and a styrenic polymer, heating this mixture, injecting CO.sub.2 and/or nitrogen, in gas or liquid form, as a blowing agent and subsequently extruding, cooling and drying the resulting polystyrene foam.

Abstract: A method for lowering the melt flow rate of flame retardant expanded polystyrene is provided. The method comprises treating the flame retardant expanded polystyrene with an aqueous solution of sodium bicarbonate. In another aspect of the present invention a method for pelletizing recycled flame retardant expanded polystyrene is provided. The method comprises treating ground flame retardant polystyrene in an aqueous solution of sodium bicarbonate; condensing the treated polystyrene; extruding the polystyrene; and pelletizing the polystyrene. In another aspect of the present invention the electrostatic build-up on polystyrene is reduced by contacting the polystyrene with an aqueous solution of sodium bicarbonate.

Abstract: A process for the production of plastic foams, preferably rigid foams containing urethane groups or urethane and isocyanurate groups, by reactinga) an organic and/or modified organic polyisocyanate withb) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and, if desired,c) a low-molecular-weight chain extender and/or cross-linking agent,in the presence ofd) a blowing agent,e) a catalyst and, if desired,f) assistants and/or additives,in which the blowing agent (d) used is at least one vinylfluoroalkane of the formula CH.sub.2 .dbd.CH--C.sub.n F.sub.

Abstract: A composition including from 40 to 55 mol % of 1,1,1,,2-tetrafluoroethane and from 45 to 60 mol % of methyl chloride; and a composition including from 68 to 75 mol % of 1,1,1,2-tetrafluoroethane and from 25 to 32 mol % of methyl chloride. These compositions are useful as porogenic agents for polystyrene, as refrigerating fluids, and as blowing agents for polyurethane and polyolefin foams.

Abstract: An electro-responsive elastomeric material comprising (A) an electrically insulating polymer having a specific modulus of elasticity and (B) a fine powder dispersed in the polymer which electrically polarizes under an electric field independent of water changes its viscoelasticity upon voltage application. The powder has a mean particle size of 0.5 to 500 .mu.m and is (1) a fine carbonaceous powder having a C/H atomic ratio of from 1.2 to 5, (2) composite particles having minute particulates of an insulating material dispersed in a matrix phase of a carbonaceous or carbide material, (3) composite particles having minute particulates of a carbonaceous or carbide material dispersed in a matrix phase of an insulating material, or (4) a fine composite powder of a stratum clay mineral having a two-dimensional stratum structure with a carbonaceous or carbide material incorporated between the strata.

Abstract: Disclosed is a process for making closed-cell, alkenyl aromatic polymer foam packing bodies. An alkenyl aromatic polymer material is heated to form a melt polymer material. The melt polymer material comprises greater than 50 percent by weight alkenyl aromatic monomeric units. A blowing agent is incorporated into the melt polymer material at an elevated pressure to form a foamable gel. The blowing agent has about 20 weight percent or more based upon the total weight of the first blowing agent selected from the group consisting of carbon dioxide and ethane. The foamable gel is extruded through a die to form a foam strand. The foam strand is pelletized to form a plurality of foam bodies. The bodies are further expanded by exposing them one or more times to heated air or steam. Preferably, the bodies are allowed to age for a preselected period of time after pelletizing and between subsequent expansions.

Abstract: Disclosed is a process for making extruded, closed-cell alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters. The process comprises: a) heating an alkenyl aromatic polymer material having greater than 50 percent by weight alkenyl aromatic monomeric units to form a melt polymer material; b) incorporating into the melt polymer material at an elevated pressure a blowing agent comprising at least 50 percent by weight 1,1-difluoroethane (HFC-152a) based upon the total weight of the blowing agent to form a foamable gel; c) cooling the foamable gel to an optimum foaming temperature prior to extrusion through a die; and d) extruding the foamable gel through a die to form the foam structure. Further disclosed is a foamable gel capable of forming an alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters.

Abstract: Substantially constant boiling compositions of 1,1,1,2-tetrafluoroethane and dimethyl ether and its use as a refrigerant, aerosol propellant and polymer foam blowing agent are disclosed.

Abstract: Blowing agents for use in foamable plastics such as polystyrene, polyvinyl chloride, polyethylene and other non-polyisocyanate-based foams, comprising a mixture of 1,1,1,2,3,3,3-heptafluoropropane in combination with one or more hydrocarbons or partially halogenated alkanes. In one aspect of the invention the hydrocarbon adjuvant is selected from the group consisting of propane, butane, isobutane, n-pentane, i-pentane, neopentane, n-hexane, 2-methylpentane, 3-methylpentane and 2,2-dimethylbutane.

Abstract: A process for the production of plastic foams, preferably rigid foams containing urethane groups or urethane and isocyanurate groups, by reactinga) an organic and/or modified organic polyisocyanate withb) at least one relatively high-molecular-weight compound containing at least two reactive hydrogen atoms, and, if desired,c) a low-molecular-weight chain extender and/or cross-linking agent,in the presence ofd) a blowing agent,e) a catalyst and, if desired,f) assistants and/or additives,in which the blowing agent (d) used is at least one vinylfluoroalkane of the formula CH.sub.2 .dbd.CH--C.sub.n F.sub.

Abstract: Near-Azeotropic blends of:pentafluoroethane and 1,1,1-trifluoroethane with one or more of chlorodifluoromethane, 1,2,2,2-tetrafluoroethane, 1,1,2,2-tetrafluoroethane, 1-chloro-1,1,2,2-tetrafluoroethane, 1-chloro-1,2,2,2-tetrafluoroethane, 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,2,3,3-heptafluoropropane, and perfluorocyclopropane;chlorodifluoromethane and pentafluoroethane with one or more of ethane, butane, isobutane, dimethyl ether, propylene, and difluoromethane;chlorodifluoromethane with 1,1,1-trifluoroethane and 1,2,2,2-tetrafluoroethane, propane and pentafluoroethane, or 1,1,1-trifluoroethane and octafluoropropane;and pentafluoroethane with fluoroethane and 1,2,2,2-tetrafluoroethane,along with their use as refrigerants.

Abstract: Disclosed is a process for making extruded, closed-cell alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters. The process comprises: a) heating an alkenyl aromatic polymer material having greater than 50 percent by weight alkenyl aromatic monomeric units to form a melt polymer material; b) incorporating into the melt polymer material at an elevated pressure a blowing agent comprising at least 50 percent by weight 1,1-difluoroethane (HFC-152a) based upon the total weight of the blowing agent to form a foamable gel; c) cooling the foamable gel to an optimum foaming temperature prior to extrusion through a die; and d) extruding the foamable gel through a die to form the foam structure. Further disclosed is a foamable gel capable of forming an alkenyl aromatic polymer foam structure having an average cell size of from about 0.3 to about 3.0 millimeters.

Abstract: The present invention includes an improved blowing agent concentrate, comprising:(a) a vinyl aromatic polymer;(b) a preformed blend of a styrene/diene block copolymer and a hydrocarbon rubber extending oil; and(c) at least one blowing agent.The blowing agent concentrate is utilized to prepare foamable materials based on a variety of thermoplastic organic polymers. The foamable materials can in turn be molded into a variety of thermoplastic structures.

Abstract: Azeotrope-like blends are disclosed comprising effective amounts of 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a) and a halocarbon selected from the group consisting of 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), 2-chloro-1,1,2,2-tetrafluoroethane (HCFC-124a), 1-hydroperfluoropropane (HFC-227ca), 2-hydroperfluoropropane (HFC-227ea), and mixtures thereof.

Abstract: A process for preparing a cellular polymer containing perforated cell windows in the presence of a perforating agent being a substance that has a critical surface free energy of less than about 23 mJ/m.sup.2 is disclosed. The cellular polymers obtained according to this invention have a fine cell structure and show enhanced dimensional and thermal insulation stability. The invention also relates to rigid polyurethane foam prepared in the presence of, for example, particulate poly(tetrafluoroethylene) or a liquid polyfluoro- or perfluorocarbon, with a boiling point of at least 130.degree. C., as perforating agent.

Abstract: Azeotropic or azeotrope-like compositions of effective amounts of 1,1,2,2,3,3,4,4,-octofluorobutane; trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, 1,1-dichloroethane, or 1,3-dichloro-1,2,2,3,3-HCFC-225cb; and an alcohol such as methanol, ethanol, or isopropanol, to form an azeotropic or azeotrope-like composition are disclosed that are useful as cleaning agents, refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.

Abstract: Constant boiling azeotropic or azeotrope-like mixtures of octafluoropropane and fluoroethane are useful as refrigerants, aerosol propellants, heat transfer media, gaseous dielectrics, fire extinguishing agents, expansion agents for polyolefins and polyurethanes and as power cycle working fluids.

Abstract: Storage-stable 141b prepared by contacting 141b with alumina at temperatures of about 0-100 degrees Centigrade, compositions containing the thus treated 141b, and uses thereof for the production of polyurethane and polyisocyanurate foams.

Abstract: It is an object of the present invention to provide volatile foaming agent compositions for thermoplastic resins capable of producing a thermoplastic resin foam without any shinkage or expansion after foaming.A volatile foaming agent composition for thermoplastic resin according to the present invention comprises 1,1,1,2-tetrafluoro-ethane.As the permeability of 1,1,1,2-tetrafluoro-ethane in thermoplastic resins is smaller than that of the air, volatile foaming agent composition containing 1,1,1,2-tetrafluoro-ethane and other kind of volatile foaming agent having permeability higher than that of the air can be regulated to have the permeability similar to that of the air.Accordingly, the permeating speed of volatile foaming agent from the inside of foam cells to the outside and the permeating speed of substituting air into the foam cells from outside can be balanced and any shrinkage or expansion after foaming can be avoided.