Processes Involving An Ethylenically Unsaturated Material Derived From Poly 1,2-epoxide As Reactant Or A Solid Polymer; Or Compositions Thereof Patents (Class 522/100)
  • Patent number: 7238731
    Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultraviolet and visible radiation. In addition, the disclosed coating compositions are suitable for coating flexible objects and/or objects having angular features, such as, but not limited to, flexible metal objects with angular features. In addition, methods are disclosed for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, including, for example leaf springs. Also disclosed are methods, processes, production lines, articles of manufacture, and factories which incorporate these environmentally friendly, substantially all solids coating compositions curable using ultraviolet and visible radiation.
    Type: Grant
    Filed: March 8, 2005
    Date of Patent: July 3, 2007
    Assignee: Ecology Coating, Inc.
    Inventor: Sally Judith Weine Ramsey
  • Patent number: 7232851
    Abstract: An energy curable lithographic ink composition having an asymptotic relative viscosity of about 0.4 to about 1.5 and a water up-take number of at least about 30%. Also disclosed is a method of improving various rheological properties and increasing the water window of an energy curable lithographic ink by varying the composition of the ink in order to result in an asymptotic relative viscosity of about 0.4 to about 1.5 and a water up-take number of at least about 30%. A method of identifying and selecting an energy curable lithographic ink composition having optimal press performance is also disclosed.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: June 19, 2007
    Assignee: Sun Chemical Corporation
    Inventors: Stan Miezeiwski, Paul Sirotto, Mikhail Laksin, Jean Dominique-Turgis
  • Patent number: 7232540
    Abstract: The present invention relates to radiation-curable coating formulations specifically for plastic substrates. The present invention specifically relates to resinous Michael addition products of ?-dicarbonyl compounds and Lewis-functional multifunctional acrylate esters. The present invention further relates to methods of fabricating and using the inventive compounds.
    Type: Grant
    Filed: May 2, 2004
    Date of Patent: June 19, 2007
    Assignee: Ashland Licensing and Intellectual Property LLC
    Inventors: Michael Gould, Matthew S. Sheridan, Thomas L. Marino, Alexandre Mejiritski, Dustin B. Martin
  • Patent number: 7232850
    Abstract: A photocurable composition comprising cationically curable compound, an acrylate-containing compound; a hydroxyl-containing compound; a cationic photoinitiator; and a free radical photoinitiator; wherein said composition has less than 0.54 equivalents of cationically curable groups, less than 0.10 equivalents of acrylate groups and less than 0.10 equivalents of hydroxyl groups per 100 grams of said composition.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: June 19, 2007
    Assignee: Huntsman Advanced Materials Americas Inc.
    Inventors: David Johnson, Frank Tran, John Fong, Richard Leyden, Ranjana Patel
  • Patent number: 7226710
    Abstract: A photocurable and thermosetting resin composition comprising (A) a photosensitive prepolymer having a carboxyl group in combination with at least two ethylenically unsaturated double bonds in its molecule, (B) a polymerization initiator, (C) a diluent, (D) an oxetane compound having at least two oxetanyl groups in its molecule, and (E) a curing promotor is developable with an alkaline solution and can be formulated as a one package preparation. Such a photocurable and thermosetting resin composition and a photosensitive dry film prepared by the use thereof are useful as various resist materials and electrical insulating materials, particularly as solder resists for printed circuit boards, interlaminar insulating materials for build-up multi-layer printed circuit boards, and the like.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: June 5, 2007
    Assignees: Kanagawa University, Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Tadatomi Nishikubo, Atsushi Kameyama, Masaki Sasaki, Masatoshi Kusama, Seiya Onodera
  • Patent number: 7220787
    Abstract: It is an object to provide a photoreactive hot-melt adhesive composition which exhibits high adhesive strength immediately after combination of adherends and excellent bond strength after completion of curing and provides a highly durable bonded laminate. A photoreactive hot-melt adhesive composition containing: (a) a bisphenol F epoxy resin that assumes a solid form at ordinary temperature; (b) at least one compound selected from the group consisting of a compound represented by the following formula (1), a copolymer of tetramethylene oxide and ethylene oxide and a copolymer of tetramethylene oxide and propylene oxide; and (c) a cationic photoinitiator; R1-(OR2)n—OR3??Formula (1) (In the formula, R1 and R3 independently represent any of a hydrogen atom, a glycidyl group, and a monofunctional substituted or unsubstituted hydrocarbon group having 1–8 carbon atoms; R2 represents a bifunctional, substituted or unsubstituted hydrocarbon group having 2–8 carbon atoms; and n is an integer of 2 or larger.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: May 22, 2007
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Kenji Yamauchi, Takashi Shinjo, Takeshi Miyake
  • Patent number: 7217743
    Abstract: A curable ink for jet-ink recording comprising a white pigment and a polymerizable compound, wherein the polymerizable compound is a compound selected from the group consisting of: (a) oxetane compounds; (b) pyrrole or substituted pyrroles; (c) aniline or substituted anilines; and (d) thiophene or an substituted thiophenes, provided that when the polymerizable compound is the oxetane compound, the curable ink further comprises an epoxy compound or a vinyl ether compound.
    Type: Grant
    Filed: July 21, 2003
    Date of Patent: May 15, 2007
    Assignee: Konica Corporation
    Inventor: Ai Kondo
  • Patent number: 7202285
    Abstract: Compositions suitable for use as base coats and varnishes, preferably for use in combination with electrostatic of set inks printed onto plastics substrates, particularly polycarbonate compact discs. They contain a photopolymerisable material, a photoinitiator, an inorganic transfer agent and heavy metal salt, preferably a metallic carboxylate. They have a good shelf life and good adhesion after hardening with ultraviolet light.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: April 10, 2007
    Assignee: Sericol Limited
    Inventors: Angelique Runacre, Paul Geoffrey Day
  • Patent number: 7192992
    Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultraviolet and visible radiation. In addition, the disclosed coating compositions are suitable for coating thermally sensitive objects and/or rusted surfaces. In addition, methods are disclosed for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces are also disclosed. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, including, for example gas tanks such as, barbeque propane tanks. Also disclosed are methods, processes, production lines, articles of manufacture, and factories which incorporate these environmentally friendly, substantially all solids coating compositions curable using ultraviolet and visible radiation.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: March 20, 2007
    Assignee: Ecology Coating, Inc.
    Inventor: Sally W. Ramsey
  • Patent number: 7189766
    Abstract: The printing ink of the present invention is characterized by containing a photo-curable high polymer precursor, and a photopolymerization initiator, and containing 3 to 8 parts by weight of inorganic fine particles having a mean particle size of 0.1 ?m or less to 100 parts by weight of the high polymer precursor. Moreover, the printing ink of the present invention is characterized by having a viscosity at a shear rate of 5 (l/s) of 8 to 75 (Pa·s), a viscosity at a shear rate of 20 (l/s) of 3 to 25 (Pa·s), and a thixotropic index value of 1.5 to 3.5. As a result of using this printing ink, letters, figures, symbols, graphics, etc., having a thickness of 0.2 mm or more can be printed rapidly without affecting the printed base material.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: March 13, 2007
    Assignees: Toppan Printing Co., Ltd., Maxell Seiki, Ltd.
    Inventors: Masashi Takahashi, Yoshie Arai, Masayoshi Onishi, Hiroshi Okubo, Yoshinari Yasuda
  • Patent number: 7186772
    Abstract: Self-coating or self-layering lacquer systems from at least two different resins, oligomers, or polymers, which are emulsifiable or dispersible in water, have different surface tensions, and form self-layering phases. After the application, the phases separate into the components of the formulation.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: March 6, 2007
    Assignee: DaimlerChrysler AG
    Inventors: Reinhold Berkau, Michael Gailberger, Thomas Gruber, Karl Holdik, Georg Meichsner, Fritz Mezger
  • Patent number: 7169828
    Abstract: The invention relates to a method of manufacturing a replica, which method comprises the provision of a polymerizable resin composition between a front mold having a pre-shaped surface and a back mold having a pre-shaped surface, carrying out a curing treatment and removing the replica thus manufactured from the molds. The invention further relates to a replica obtained by carrying out a UV light-initiated cationic polymerization.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: January 30, 2007
    Assignee: Koninklijke Philips Electronics N.V.
    Inventors: Johan George Kloosterboer, Fredericus Johannes Touwslager, Emile Johannes Karel Verstegen, Hendrik Roelof Stapert
  • Patent number: 7151123
    Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultra violet and visible radiation. In addition, methods for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces are also disclosed. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, in particular motor vehicles and motor vehicle parts or accessories.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: December 19, 2006
    Assignee: Ecology Coating, Inc.
    Inventor: Sally W. Ramsey
  • Patent number: 7144927
    Abstract: A visible light photopolymerizable composition comprising a) an aryliodonium salt and b) an acylphosphine oxide compound. These compositions can be used together with an epoxy resin as a dental composition.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: December 5, 2006
    Assignee: S & C Polymer Silicon-und Composite-Spezialitaten GmbH
    Inventors: Juergen Engelbrecht, Gunther Groeger, Wolfram Ziegler
  • Patent number: 7144544
    Abstract: An ultraviolet (UV) light curable formulation useful for repairing composite materials, comprising: an acrylic oligomer, an acrylic monomer, and a photoinitiator. This formulation may include fiberglass. The photoinitiator can be a combination of a bis-acylphosphine oxide and an alpha hydroxy ketone. The formulation can cure rapidly, such as in about 20 minutes. The cured formulation can have a Tg above 150° C.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: December 5, 2006
    Assignee: Texas Research International, Inc.
    Inventors: John W. Bulluck, Brad A. Rix
  • Patent number: 7129280
    Abstract: Mixtures curable thermally and with actinic radiation and containing carbamate and/or allophanate groups, comprising (A) at least one of (A1) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and (A2) low molecular mass compounds, oligomers and polymers containing allophanate groups, carbamate groups, and carbamate and allophanate groups, and additionally allophanate- and/or carbamate-reactive functional groups, ?which are substantially or entirely free from reactive functional groups which contain at least one bond which can be activated with actinic radiation, and (C) at least one constituent containing on average per molecule at least one reactive functional group having at least one bond which can be activated with actinic radiation; with the proviso that if only (A1) is used, the mixtures further comprise (B) at least one of low molecular mass compounds, oligomers and polymers containing allophanate- and/or c
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: October 31, 2006
    Assignee: BASF Coatings AG
    Inventors: Hubert Baumgart, Sandra Hasse, Uwe Meisenburg, Vincent Cook
  • Patent number: 7119130
    Abstract: Disclosed is an actinic ray curable ink-jet ink comprising a an epoxy compound having at least two oxirane rings and a linkage chain linking the two oxirane rings, wherein the linkage chain has a branched structure.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 10, 2006
    Assignee: Konica Minolta Medical & Graphic Inc.
    Inventor: Nobumasa Sasa
  • Patent number: 7119129
    Abstract: The present invention discloses an ultraviolet light curable transparent conductive composition and method for making such a composition that may be used to produce a transparent conductive coating on a suitable substrate. These coatings may be used in such applications as touch screens, membrane switches, TV screens, and VCRs. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: August 6, 2004
    Date of Patent: October 10, 2006
    Assignee: Allied PhotoChemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 7109262
    Abstract: An aqueous effect coating material, comprising (A) at least one water-soluble, -dilutable and/or -dispersible binder, (B) at least one effect pigment, and (C) at least one silicon compound of the general formula I [(E)nL]Si(R1)(R2)(R3)??(I) in which the index and the variables are defined as follows: n is an integer from 1 to 5; E is a reactive functional group; L is an at least divalent, linking, organic group; R1 is a substituted or unsubstituted cycloalkoxy, alkoxy, aryloxy, cycloalkyl, alkyl or aryl radical; and R2 and R3 independently of one another are substituted or unsubstituted cycloalkoxy, alkoxy or aryloxy radicals or hydroxyl groups; preparation process, and its use.
    Type: Grant
    Filed: October 21, 2002
    Date of Patent: September 19, 2006
    Assignee: BASF Coatings AG
    Inventor: Ekkehard Sapper
  • Patent number: 7098256
    Abstract: The invention is a radiation curable coating containing an antimicrobial agent, where upon irradiation with UV light, the radiation curable coating rapidly cures to a polymeric coating. The polymeric coating has durable antimicrobial properties, being especially effective at preventing the growth of Staphylococcus aureaus and Kleibsella pneumoniae on wood flooring and furniture. The major components in the radiation curable coating are a urethane acrylic oligomer, a radiation cure package, an antimicrobial agent, a cross-linking agent, and optionally, an additive package. The radiation curable urethane oligomer is a relatively short chain backbone urethane polymer that is end capped with a radiation curable moiety, where the moiety is an acrylic. The cross-linking agent is one or more monomers used to lower the viscosity and promote cross-linking, and include acrylate esters of mono-, di-, tri-, or tetrafunctional alcohols. The radiation cure package contains at least one photoinitiator.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: August 29, 2006
    Assignee: Microban Products Company
    Inventors: Ivan W. Ong, Julia M. Watterson, legal representative, C. Barry Wilson, Robert S. Watterson, deceased
  • Patent number: 7081494
    Abstract: The present invention has for its object to provide a curable composition which, despite its low viscosity, gives a cured product with a high gel fraction, low residual tack, low modulus, high elongation, and good flexibility. The present invention relates to a curable composition comprising the following two components: (A) a vinyl polymer having at least one crosslinking silyl group on the average per molecule: and (B) a photocurable substance, (C) an air oxidation-curable substance, (D) a high molecular plasticizer, (E) a reactive plasticizer or (F) a compound having one silanol group in its molecule and/or a compound capable of reacting with moisture to give a compound having one silanol group in the molecule.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: July 25, 2006
    Assignee: Kaneka Corporation
    Inventors: Masayuki Fujita, Nobuhiro Hasegawa, Yoshiki Nakagawa
  • Patent number: 7071243
    Abstract: A photo curable resin composition, which comprises (A) an acid-modified, vinyl group-containing epoxy resin, (B) an elastomer, (C) a photopolymerization initiator, (D) a diluent and (E) a curing agent, can give a high performance cured film having distinguished heat resistance, humidity-heat resistance, adhesibility, mechanical characteristics and electrical characteristics, and a photosensitive element, which comprises a support and a layer of the photo curable resin composition laid on the support, has distinguished heat resistance, humidity-heat resistance, adhesibility, mechanical characteristics and electrical characteristics.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: July 4, 2006
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Kuniaki Sato, Hiroaki Hirakura, Toshihiko Ito, Takao Hirayama, Toshizumi Yoshino
  • Patent number: 7067565
    Abstract: The invention relates to primer coating compositions exhibiting very good adhesion properties on a large variety of substrates, in particular plastic substrates such as ophthalmic lenses made of organic glasses and which also impart good impact resistance properties to the thus coated substrates. The invention also concerns substrates coated with these primer coating compositions as well as a method for making such coated substrates.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: June 27, 2006
    Assignee: Essilor International Compagnie Generale d'Optique
    Inventors: Robert A. Valeri, Kimberly D. Anderson, Sidney S. White
  • Patent number: 7064153
    Abstract: A radiation-curable ink jet ink can be formulated with less than 20% by weight of monofunctional monomer by dispersing the pigment or pigments with an acrylated epoxy resin having an average of from about 1.6 to about 2.0 functional groups per molecule, a number average molecular weight of from about 350 to about 600, and a glass transition temperature of from about ?20° C. to about +25° C.
    Type: Grant
    Filed: September 20, 2004
    Date of Patent: June 20, 2006
    Assignee: Jetrion, L.L.C.
    Inventor: Frank J. Bruck
  • Patent number: 7049350
    Abstract: A polymerizable compound represented by formula (1): wherein each R1 independently represents at least one organic residue selected from the group consisting of alkylene groups, branched alkylene groups, cycloalkylene groups and arylene groups, R2 represents an organic residue derived from an alcohol compound, a phenol compound or a carboxylic acid compound, n represents an integer of 0 to 20, a production process of the polymerizable composition, a composition using the polymerizable compound, a cured product obtained by curing the composition and a production process of the cured product. The polymerizable compound exhibits a good adhesive property to a substrate such as glass and is imparted with radical polymerizability to enable heat curing and/or active energy ray curing.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: May 23, 2006
    Assignee: Showa Denko K.K.
    Inventors: Yoshihiro Honda, Keisuke Ohta, Kazuhiko Ooga, Kazufumi Kai, Hiroshi Uchida
  • Patent number: 7041711
    Abstract: To provide a polymerizable composition suitable for a lithographic printing plate precursor which can satisfy the requirements of high sensitivity, excellent storage stability and long press life and enables direct plate making from digital data from computer, etc. when recording is conducted a solid laser or semiconductor laser emitting ultraviolet ray, visible light or infrared ray and a compound therefore, the present invention relates to a photoradical polymerizable composition comprising a polyfunctional crosslinking agent having a specific structure represented by formula (I) or (II) defined in the specification.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: May 9, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazuto Kunita
  • Patent number: 7041712
    Abstract: A radiation-curable composition for an ink base, ink composition, outer primary composition, buffering material or matrix material for fiber optics includes, in the uncured state, a secondary amino or tertiary amino silicone-containing additive.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: May 9, 2006
    Assignee: DSM IP Assets B.V.
    Inventors: Edward J. Murphy, Edward P. Zahora, Nancy L. Coster, Glenn Evans
  • Patent number: 7037953
    Abstract: A method for producing a solvent resistant, low-extractable, film from an actinic radiation curable homogenous aqueous composition containing a water soluble compound, having at least one alpha, beta-ethylenically unsaturated radiation polymerizable double bond, and water as essential components.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: May 2, 2006
    Assignee: Sun Chemical Corporation
    Inventors: Subhankar Chatterjee, Mikhail Laksin, David Biro, Jean Dominique Turgis
  • Patent number: 7034063
    Abstract: A solvent-containing multicomponent system curable thermally and with actinic radiation (dual cure) and comprising (A) at least one component comprising (A1) at least one constituent containing at least 1.8 meq/g of isocyanate-reactive functional groups, (A2) at least one constituent containing at least 1.8 meq/g of isocyanate-reactive functional groups and at least one functional group having at least one bond which can be activated with actinic radiation, and (B) at least one component comprising at least one polyisocyanate (B1); and its use as a coating material, adhesive or sealing compound.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: April 25, 2006
    Assignee: BASF Coatings AG
    Inventors: Egbert Nienhaus, Bernhard Lettmann
  • Patent number: 7015256
    Abstract: A photosensitive composition for forming a dielectric of the present invention comprising inorganic particles, an alkali developable resin and additives, wherein the additives comprise a compound having a quinonediazido group (C1), a compound containing at least two alkyletherified amino groups in the molecule (C2) and a thermal acid generator (C3), or wherein the inorganic particles comprise inorganic superfine particles (A-I) having a mean particle diameter of less than 0.05 ?m and inorganic fine particles (A-II) having a mean particle diameter of not less than 0.05 ?m. The composition can be calcined at low temperatures to form a dielectric layer with high dimensional precision, said layer having a high dielectric constant and a low dielectric loss. Also provided are a dielectric and an electronic part prepared from the composition.
    Type: Grant
    Filed: December 26, 2002
    Date of Patent: March 21, 2006
    Assignee: JSR Corporation
    Inventors: Nobuyuki Ito, Hideaki Masuko, Satomi Hasegawa, Atsushi Ito, Katsumi Inomata
  • Patent number: 6995193
    Abstract: A photocurable composition which can be produced and cured while utilizing two different polymerization modes, can be used for bonding over a sufficiently long time period, and has excellent peel strength. The composition comprises (A) a compound containing a polymerizable unsaturated bond and giving a homopolymer having a glass transition temperature of 0 to 100° C., (B) a compound which has an unsaturated bond and is copolymerizable with the compound (A), (C) a compound having at least one cationically polymerizable group per molecule, (D) a polymerization catalyst which upon irradiation with light initiates the polymerization of the compounds (A) and (B), and (E) a cationic polymerization catalyst which upon irradiation with light initiates the cationic polymerization of the compound (C) at the cationically polymerizable group(s).
    Type: Grant
    Filed: February 14, 2000
    Date of Patent: February 7, 2006
    Assignee: Sekisui Chemical Co., Ltd.
    Inventor: Hiroji Fukui
  • Patent number: 6967042
    Abstract: The present invention discloses an ultraviolet light curable mar resistant composition and method for making such a composition that may be used to produce an mar resistant layer. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: November 22, 2005
    Assignee: Allied PhotoChemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 6964813
    Abstract: An ultraviolet curable resin composition is provided, which is excellent in developing width and resolution, and exhibits good solder heat resistance and resistance to gold plating.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: November 15, 2005
    Assignee: Goo Chemical Co., Ltd.
    Inventor: Soichi Hashimoto
  • Patent number: 6933325
    Abstract: A high refractive index, curable, synthetic resin composition comprising a core resin composition composed of a mixture of ethylenically unsaturated compounds, and an initiation system containing both photo and thermal initiators, particularly a photochromic resin composition which further includes at least one photochromic dye. Also a curing process, which includes a combination of multi-step radiation curing and thermal annealing. Articles produced of cured composition exhibit superior physical and, in appropriate cases, photochromic properties and can be easily mass produced on a commercial scale due to short processing time and use of readily available chemicals.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: August 23, 2005
    Assignee: Rodenstock GmbH
    Inventors: Qiang Zheng, Donald Scott Nelson, Charles William Carper, Jr., Manfred Melzig, Herbert Schuster, Herbert Zinner
  • Patent number: 6919385
    Abstract: An energy-ray curing resin composition comprising a photopolymerizable resin component which can be cured by irradiation with an energy ray, a photopolymerization initiator component which makes it possible to cure the above photopolymerizable resin component by irradiation with an energy ray and a curing agent component used for curing at least one of the above photopolymerizable resin components by a method other than irradiation with an energy ray. To provide a high curability energy-ray curing resin composition which has a very high curing capacity as compared with those of conventional energy-ray curing resins and which is simple and has a high design freedom.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: July 19, 2005
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventor: Noriya Hayashi
  • Patent number: 6914086
    Abstract: A crosslinkable UV absorbing agent prepared by the following steps: (1) preparing a mixture of reactants comprising a UV absorbing compound (A) with multiple pendant hydroxyl groups and an unsaturated monoglycidyl compound (B) with both reactive glycidyl and vinyl groups; (2) mixing a base catalyst (C) with the mixture of reactants; (3) initiating a synthesis reaction of the crosslinkable UV absorbing agent under heating; and (4) recovering the resulting product after the synthesis reaction is completed. The crosslinkable UV absorbing agent is directly applicable in the lens formulation to replace conventional crosslinking agent and UV absorber used in the production of the soft contact lens without any purification or modification.
    Type: Grant
    Filed: June 24, 2003
    Date of Patent: July 5, 2005
    Inventor: Shinn-Gwo Hong
  • Patent number: 6906114
    Abstract: The present invention discloses an ultraviolet light curable silver chloride compositions and method for making such a composition that may be used to produce a silver coating on a substrate. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: September 6, 2001
    Date of Patent: June 14, 2005
    Assignee: Allied PhotoChemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 6903145
    Abstract: A process for preparing a multicomponent system curable thermally and with actinic radiation (dual cure), where (A) at least one component comprising at least one constituent (A1) containing per molecule at least two isocyanate-reactive functional groups, and (B) one component containing one polyisocyanate (B1), are mixed with one another, which comprises mixing component (A) and/or component (B), shortly before their mixing, with one further liquid component (C) comprising (C1) one constituent which is curable with actinic radiation and contains per molecule at least two functional groups which contain bond which can be activated with actinic radiation, and/or (C2) one constituent which is curable thermally and with actinic radiation and contains per molecule at least one functional group which contains at least one bond which can be activated with actinic radiation, and containing per molecule at least one isocyanate-reactive functional group or containing at least one isocyanate group, and subsequently mi
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: June 7, 2005
    Assignee: BASF Coatings AG
    Inventors: Egbert Nienhaus, Bernhard Lettmann
  • Patent number: 6903144
    Abstract: This invention is a process for making UV curable adhesives, sealants, coatings, ink, flexible printing plates, laminating adhesives, fibers, gaskets, and related compositions, films, and thin parts, wherein an epoxidized monohydroxylated polydiene polymer comprised of at least two different diene monomers wherein at least one is a diene monomer which yields unsaturation suitable for epoxidation is used as the binder for the composition. The preferred epoxidized monohydroxylated polymers are block copolymers of isoprene and butadiene wherein a hydroxyl group is attached at one end of the polymer molecule. These polymers may be hydrogenated or unhydrogenated. The process involves mixing the above polymer or the polymer with one or more other formulating ingredients together with and insoluble photoinitiator which is preferably selected from the group consisting of triaryl sulfonium salts.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: June 7, 2005
    Assignee: Kraton Polymers U.S. LLC
    Inventors: James R. Erickson, Esther M. Zimmermann
  • Patent number: 6897248
    Abstract: The present invention discloses an ultraviolet light curable ferromagnetic composition and method for making such a composition that may be used to produce a ferromagnetic coating on a suitable substrate. These coatings may be used to produce printed capacitors and inductors. The disclosed composition does not contain any significant amount of volatile organic solvents that do not become incorporated in the active layer after curing.
    Type: Grant
    Filed: February 24, 2004
    Date of Patent: May 24, 2005
    Assignee: Allied PhotoChemical, Inc.
    Inventor: Roy C. Krohn
  • Patent number: 6896967
    Abstract: An ultraviolet curable resin composition comprises (A) an ultraviolet curable resin obtained by reacting an epoxy group containing polymer (a), which is prepared by polymerizing an ethylenically unsaturated monomer component including an ethylenically unsaturated monomer (i) having an epoxy group, with an ethylenically unsaturated monomer (b) having a carboxyl group, and then reacting a resultant intermediate product with a saturated or unsaturated polybasic acid anhydride (c); (B) an epoxy compound having at least two epoxy groups in molecule; (C) a photopolymerization initiator; and (D) a diluent The ultraviolet curable resin includes 0.3 to 10 mol of a polymerizable unsaturated group in 1 kg thereof. A photo solder resist ink containing this resin composition has the capability of providing a permanent film with excellent flexibility and solder heat resistance, and is preferably used to manufacture flexible printed circuit boards.
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: May 24, 2005
    Assignee: Goo Chemical Co., Ltd.
    Inventors: Hiroko Daido, Soichi Hashimoto
  • Patent number: 6880296
    Abstract: A visible light photopolymerizable composition comprising a) an aryliodonium salt and b) a titanocene derivate. These compositions can be used together with an epoxide resin as a dental composition.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: April 19, 2005
    Assignee: S & C Polymer Silicon- und Composite-Spezialitaten GmbH
    Inventors: Juergen Engelbrecht, Gunther Groeger, Wolfram Ziegler
  • Patent number: 6878755
    Abstract: A system, apparatus, and method for processing a sample for chemical and/or biological analysis, and detecting one or more target substances. A first system of microfabricated components includes at least a reservoir and a channel, and a second system of detection components including at least a lens. The lens is focused on a sensing platform of the first system. The sensing platform is coupled to the reservoir by the channel. Various types of detection systems can be utilized with the present invention including fluorescence detection systems with a laser that is positioned to illuminate a sample in the sensing platform. The microfabricated components include one or more pumps, valves, mixers, and filters. A thermoelectric cooler can be positioned to control the temperature of at least one of the microfabricated components. A variety of component configurations can be implemented, and a variety of different processes can be performed, depending on the configuration of components.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: April 12, 2005
    Assignee: Microgen Systems, Inc.
    Inventors: Angad Singh, Shahzi S. Iqbal
  • Patent number: 6872759
    Abstract: The present invention provides a material having adhesiveness to bone and/or fascia, which is composed of a polymeric material comprising carbon as a constituent element, and at least a part of a surface of which is modified by ion bombardment. The material of the present invention is applicable as a prosthesis in surgery of spinal diseases and as a prosthesis in surgery on thoracic organs and abdominal organs or musculoskeleton in addition to the application thereof to the artificial dura mater.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: March 29, 2005
    Assignee: Riken
    Inventors: Yoshiaki Suzuki, Masaya Iwaki, Makoto Kaibara, Masami Kamio
  • Patent number: 6858260
    Abstract: A radiation curable, flexible, paintable composition produced from epoxy compounds and one or more polyol(s) has enhanced durability, thick and thin film adhesion, resistance to mold growth and dimensional changes while reducing solvent emissions. The composition can reduce, if not eliminate, runs and drips during the thermal bake cycles which are associated with using conventional compositions in automotive applications.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: February 22, 2005
    Assignee: Denovus LLC
    Inventors: Donald W. Taylor, Todd W. Scrivens, Laurie Denise Lovshe, Jeffrey T. Pachl
  • Patent number: 6855746
    Abstract: This invention provides a process for the production of molded particles for enzyme- or microbial cell-immobilization which is characterized in that: an aqueous liquid composition which comprises: (A) an unsaturated group-containing urethane resin which is obtained by making a compound (a) having one hydroxyl group and one epoxy group in a molecule react with a compound (b) having one carboxyl group and one ethylenically unsaturated group in a molecule, and further making thus obtained unsaturated group-containing diol (c) react with polyisocyanate compound (d); (B) a polymerization initiator; and (C) water-soluble macromolecular polysaccharides which are capable of gelation by contact with metal ion; is gelatinized, in an aqueous medium which contains metal ion, to be particulate gel, which is then subjected to photopolymerization and/or thermopolymerization by which to cause the crosslinking reaction of ethylenically unsaturated group in said particulate gel.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: February 15, 2005
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Junya Yoshitake, Kenji Miyagawa, Kenji Seko
  • Patent number: 6852768
    Abstract: The invention provides curable organic coatings with improved scratch resistance. More particularly, the present invention relates to a combination of inorganic filler having a 50th percentile particle diameter of from about 3 to about 9 micrometers comprised of aluminum oxide, silicon dioxide, ceramic spheres or mixtures thereof, and particles having a 50th percentile particle diameter of from about 10 to about 150 micrometers. The liquid coatings have a viscosity before curing of from about 100 cps (mPa-s) to about 70,000 cps (mPa-s) at a shear rate of 0.15 s?1. The use of inorganic filler materials of the defined type and particle size are combined with the curable organic coating to improve the scratch resistance of the coating without a negative impact on the physical and performance properties or application parameters of the original coating material.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: February 8, 2005
    Assignee: Lord Corporation
    Inventors: Pei Wen Jin, Kimberly R. Benca, Ian C. Quarmby, Thomas Kurpiewski, Victor E. Ferrell
  • Patent number: 6844374
    Abstract: The invention provides organic coatings with improved scratch resistance. More particularly, the present invention relates to the use of inorganic filler materials of a defined type and particle size which can be added to curable organic coatings to improve the scratch resistance of the coating without a negative impact on the physical and performance properties or application parameters of the original coating material.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: January 18, 2005
    Assignee: Lord Corporation
    Inventors: Pei Wen Jin, Kimberly R. Benca, Ian C. Quarmby, Thomas Kurpiewski, Victor E. Ferrell
  • Patent number: 6835759
    Abstract: The coating composition comprises a radiation curable component (a1), a thermally curable binder component (a2), a thermally curable crosslinking component (a3), and optionally, one or more reactive diluents (a4). Radiation curable component (a1) is polymerizable upon exposure to electromagnetic radiation and comprises at least two functional groups (a11) comprising at least one bond activatable with electromagnetic radiation. Thermally curable binder component (a2) is polymerizable upon exposure to heat and has at least two functional groups (a21) which are reactive with functional groups (a31). Third component (a3) comprises at least 2.0 functional groups (a31) which are reactive with functional groups (a21). The value of UV/TH, the nonvolatile weight ratio of the sum of radiation curable component (a1) and optional reactive diluent (a4) to the sum of thermally curable binder component (a2) and thermally curable crosslinking component (a3) is from 0.20 to 0.60.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: December 28, 2004
    Assignee: BASF Corporation
    Inventors: Christopher J. Bradford, Marcy Zimmer, Ryan F. O'Donnell, Lyle Caillouette, Jennifer A. Rischke
  • Patent number: 6833231
    Abstract: A liquid radiation-curable composition that comprises (A) at least one polymerizing organic substance; (B) at least one free-radical polymerizing organic substance; (C) at least one cationic polymerization initiator; (D) at least one free-radical polymerization initiator; (E) at least one hydroxyl-functional compound; and (F) at least one epoxy interpenetrating polymer compound;
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: December 21, 2004
    Assignee: 3D Systems, Inc.
    Inventors: Khalil M. Moussa, Jiaching Liu