Abstract: A radiation curable ink composition has improved adhesion towards rigid recording media, good jetting behavior and no or minimal health and safety risks. The radiation curable ink has a viscosity of 30 mPa·s, or less, at 50° C.

Abstract: The present invention relates to a composite powder, preparation and use thereof. The composite powder according to the present invention is prepared by intimately mixing an irradiated or non-irradiated rubber latex with a slurry of inorganic particles in a ratio corresponding to that of rubber particles to inorganic particles in the composite powder according to the present invention, and then drying the resultant mixture. The composite powder according to the present invention comprises agglomerates composed of powdery rubber particles and inorganic particles, with inorganic particles being uniformly distributed either inside the agglomerats or both inside the agglomerates and on the surfaces thereof. The composite powder according to the present invention can be easily dispersed in plastic matrixes and thus can be compounded with plastics to produce toughened plastics and thermoplastic elastomers.

Abstract: This invention is related to compositions that can be used to protect surfaces, such as those found on bowling lanes (both synthetic and wood). The compositions are low viscosity and contain little to no VOCs (volatile organic compounds). In one embodiment, the flowable compositions are 100% solids, while in another embodiment, they are solvent-borne compositions that only include VOC-exempt solvents. Regardless of the embodiment, the compositions can be cured via UV LED light to yield scratch, abrasion, and impact resistant coatings.

Abstract: The present invention provides a zirconium oxide dispersion which contains zirconium oxide particles, a metal complex, and a dispersion medium and which has excellent storage stability; a photo-curing composition containing zirconium oxide particles which contains zirconium oxide particles, a metal complex, an actinic energy ray-curing compound, a photopolymerization initiator, and a dispersion medium and which composition can form, on a surface of a substrate, a cured film having excellent transparency and high refractive index, and which composition does not corrode a metal-made apparatus employed in a dispersion process and a coating apparatus; and a cured film produced by applying onto a substrate the photo-curing composition containing zirconium oxide particles through coating or printing, followed by hardening.

Abstract: A thermoplastic resin composition includes a thermoplastic resin and a first metal particle, wherein the first metal particle has a ratio of a short diameter relative to a long diameter of about 1/50 to about 1/6. Also a thermoplastic resin composition includes a thermoplastic resin, a plate-shaped second metal particle, and plate-shaped mica, wherein the plate-shaped mica is included in an amount of about 0.01 parts by weight to about 4.9 parts by weight based on about 100 parts by weight of the thermoplastic resin. In addition a thermoplastic resin composition includes a thermoplastic resin, a plate-shaped third metal particle or a spherical fourth metal particle, and thermally expandable particulate, wherein the thermally expandable particulate includes a polymer particle including a hydrocarbon foamable compound therein.

Abstract: A method for preparing an organopolysiloxane compound by mixing (A) an organopolysiloxane of the formula (1): wherein R1 is a monovalent hydrocarbon group and may be the same or different, R is a divalent hydrocarbon group, and n is an integer of at least 2, with (B) an organic compound of the formula (2) or (3): wherein R2 is H or a monovalent hydrocarbon and R3 is a divalent hydrocarbon and (C) an organic compound of the formula (4): wherein R1 and R3, respectively, have the same meanings as defined above, R4 is a monovalent hydrocarbon group, and p is 0 or 1, wherein components (A), (B) and (C) are reacted with one another under conditions that a ratio between an amino group equivalent PNH in component (A) and an isocyanate group equivalent PNCO in components (B) and (C) is such that 0.8?(PNCO/PNH) and a molar ratio between component (B) and component (C) is such that 0.6?[component (B)/component (C)].

Abstract: Provided is a method for protecting the surface of a member to be processed, which comprises providing a protective film made of a photocurable resin composition for surface protection on the surface of the member to be processed, processing the member to be processed, and removing the protective film from the member to be processed, wherein the photocurable resin composition comprises (A) a polyfunctional (meth)acrylate, (B) a monofunctional (meth)acrylate, (C) a resin having a cyclopentadiene skeleton and (D) a photopolymerization initiator, which comprises from 1 to 50 parts by weight of (A), from 5 to 95 by mass of (B) and from 0.1 to 50 parts by mass of (C).

Abstract: Energy curable inks formulations are disclosed having improved resistance properties.

Abstract: Disclosed are photopolymerizable compositions suitable for uses such as dental composite resins, and that comprise (A) a radical-polymerizable monomer, (B) a photopolymerization initiator that comprises (B1) an ?-diketone compound, (B2) a photoacid generating agent, (B3) an aromatic amine compound, and (C) an organic filler containing a phthalate ester fluorescent agent.

Abstract: A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.

Abstract: A method of preparing colored UV-curable artificial nail gel compositions comprising dispersing a pigment in an organic liquid to form a pigment concentrate and mixing the pigment concentrate with a polyfunctional acrylic monomer and/or a polyfunctional acrylic oligomer, and the resultant highly colored artificial nail gel are disclosed.

Abstract: There is provided a photo-curable composition that shows the suppression of a residual film formation and a high adhesion thereof to a substrate in a process for forming a three-dimensional pattern by a photo-imprinting method. A photo-curable composition for forming a three-dimensional pattern by a photo-imprinting method, comprises a monomer having a photopolymerizable group; an inorganic fine particle to which a dispersant is added; and a photopolymerization initiator. It is preferred that the inorganic fine particle (e.g., silica) has an average particle diameter of 1 to 1,000 nm, and the dispersant is a silane coupling agent, particularly a silane coupling agent containing an organic group having a carbon-carbon unsaturated bond or an organic group having an epoxy group.

Abstract: Coating compositions yielding cured coatings that exhibit excellent abrasion-resistance and hardness for use on polymeric substrates such as the front side of optical lenses, in a manner that meets or exceeds the stringent requirements for such use. The compositions include a monomeric organofunctional silane, and colloidal silica present in an amount sufficient to improve abrasion resistance as compared to a composition lacking the colloidal silica.

Abstract: A method for temporarily fixing a member with a curable composition that includes (A) a polyfunctional (meth)acrylate, (B) phenol 2-mol ethylene oxide-modified acrylate, (C) a photopolymerization initiator, (D) a polar solvent, and (H) at least one granular material selected from the group consisting of polypropylene particles, crosslinked polymethyl methacrylate particles and crosslinked polystyrene particles.

Abstract: The present invention relates to low temperature, cationically curable compositions with improved cure speed and toughness.

Abstract: A highly heat-conductive epoxy resin composition, which comprises epoxy resin in a liquid state at room temperature, a latent curing agent, a highly heat-conductive filler, and a non-ionic surfactant, where preferably the latent curing agent is mixed with a portion of the epoxy resin in a liquid state at room temperature to form a master batch, can keep a relatively low viscosity, even if a large amount of the filler is contained, and can be cured at a relatively low temperature for a short time, and has a distinguished storage stability as one-component composition.

Abstract: A dental adhesive composition comprising (i) at least one non-acidic polymerizable monomer having at least one ethylenically unsaturated group, (ii) optionally one or more acidic compounds, (iii) at least one photoinitiator, (iv) at least one solvent, and (v) about 0-40% by weight of one or more fillers; wherein the weight ratio of non-acidic polymerizable monomers/acidic compounds in the adhesive composition is more than about 4.5; the viscosity of the adhesive composition is less than about 350 centipoise (cP) at 25° C.; and the adhesive composition excluding solvent and filler has an acid number of less than about 0.75 mmol NaOH/g. The dental adhesive composition is used with a dental primer composition, which may be provided together in a kit.

Abstract: The invention relates to silica-containing radiation-curable formulations which in the cured state offer a particular degree of corrosion control for metallic substrates.

Abstract: An eco friendly radiation cross-linked composition is described that demonstrates excellent resistance to fire and high temperature along with good mechanical properties. The composition which is based on a blend of EVA with a LLDPE, is free of monomer such as vinyl co-agent for radiation cross-linking. The halogen free flame retardant composition is a mixture of 20 to 90% by weight of magnesium hydroxide (powder A) and 90% to 20% of powder B. Preferably the powder B is a double salt of magnesium carbonate and calcium carbonate and the magnesium hydroxide has a specific surface treatment. In addition, 0.5 to 5 parts of flame retardancy agents are selected from talc, zinc borate or molybdate derivative. The chemicals used here reduce toxicity in the environment and do not release toxic chemicals to air and soil during fire. The flame retardant cross-linked polyolefin composition is particularly useful for insulating wires and cables.

Abstract: The invention features a dental composition containing a polycyclic aromatic compound, such as 2-ethyl 9,10-dimethoxy anthracene (EDMOA), in an amount that provides the composition with fluorescence mimicking that of natural teeth.

Abstract: The present invention provides a composition for hard coat capable of forming a hard coat layer having the improved anti-staining property, anti-staining durability, scratch resistance, abrasion resistance, antistatic property and the like. A composition for hard coat comprising: an active energy ray-curable silicone-acrylic copolymer (A); an active energy ray-curable polyfunctional compound (B); and an electrically conductive material (C), wherein the active energy ray-curable silicone-acrylic copolymer (A) contains: a polysiloxane block (a-1), an acrylic block (a-2) containing an active energy ray-curable double bond group, and a fluoroalkyl group-containing acrylic block (a-3).

Abstract: This invention relates to polymerizable compositions comprising a salt of a barbituric acid derivative. The compositions are typically shelf-life stable and may be polymerized through mixing of an acidic component with the salt of a barbituric acid derivative.

Abstract: A radiation curable inkjet fluid includes a radiation curable composition including at least 25 wt % of a vinylether acrylate and at least 15 wt % of a polymerizable compound including at least three acrylate groups, each wt % being based upon the total weight of the radiation curable composition; and a photoinitiator including a tertiary amine group and 0 to 3 wt % of isopropylthioxanthone based upon the total weight of the radiation curable inkjet fluid. Also, an inkjet printing method using the radiation curable inkjet fluid.

Abstract: Described is a UV-curable sealant composition, which is preferably a one part sealant. The one part sealant is made from urethane acrylate, acrylate ester, precipitated silica, and photoinitiator. More specifically, the one part sealant is made from about 15-35 weight percent aliphatic and/or alicyclic urethane acrylates, about 40-70 weight percent of acrylate esters, about 0-10 weight percent of precipitated silica, and about 3-8 weight percent of photoinitiator. Also described are methods of applying UV-curable sealant composition to a surface such as a floor and UV curing the UV-curable sealant composition, thereby extending the life of the surface.

Abstract: Hydrophilic and self cleaning UV nano-epoxy/acrylate cationic hybrid coating composition, methods for coating transparent polymeric materials, and coated transparent polymeric materials are provided herein. In one example, a coating composition for a transparent polymeric material comprises a cationically polymerizable compound, a radically polymerizable compound, a surfactant with both hydrophilic and hydrophobic segments, and a nano-particular filler. The cationically polymerizable compound comprises at least one epoxy group. The radically polymerizable compound comprises at least one (meth)acrylate group and the nano-sized particulate filler comprises TiO2, and SiO2 and/or Al2O3.

Abstract: Radiation-curable coating compositions for a surface such as a concrete floor, which include one or more acrylate monomers or oligomers having at least four crosslinkable double bonds, at least one photoinitiator, one or more fillers, and at least one pigment or dye are described and claimed. These coating compositions allow for application of at least 0.10 mm (4 mil) thickness of the coating composition over an area larger than a radiation source, without the formation of wrinkles along the shoulder area of each pass of the radiation source in the areas where weak intensity light from a side edge of the radiation source is capable of partially curing only a portion of the coating composition thickness. The coating compositions optionally further comprise one or more tertiary amine compounds comprising zero or one crosslinkable double bonds, the one or more tertiary amine compounds providing an amine value of at least 7.5 mg KOH per gram of the total radiation-curable resins of the coating composition.

Abstract: A dental, paste/paste self-adhesive cement includes a polymerizable acidic monomer or monomer mixtures; a polymerizable non-acidic monomer or monomer mixtures, a photo-initiator and/or a co-initiator, a reducing agent such as a benzoylthiourea and other substituted benzoylthiourea, an oxidizing agent, a thermal stabilizer and a glass filler.

Abstract: A sealant composition is provided. The sealant composition includes (a) an oligomer including an unsaturated mono-carboxylic acid modified bisphenol A epoxy resin and an unsaturated mono-carboxylic acid modified bisphenol F epoxy resin, wherein an equivalence ratio of the bisphenol A epoxy resin to the bisphenol F epoxy resin is 0.05:0.95 to 0.3:0.7, the bisphenol A epoxy resin has a melting point higher than 40° C. and the bisphenol F epoxy resin has a melting point lower than 40° C.; (b) an epoxy resin having at least two or more than two epoxy groups; and (c) a photoinitiator.

Abstract: The disclosure provides a new photopolymerizable resin system for dental restorative materials. The resin system utilizes a thiol-ene component as the reactive diluent in dimethacrylate systems. The ternary resin system comprises a thiol monomer, an ene monomer and a dimethacrylate monomer. Use of an off-stoichiometric ratio of thiol:ene functional groups in favor of excess thiols results in enhanced overall functional group conversion, improved polymer mechanical properties, and reduced shrinkage stress of the ternary system when compared to either traditional dimethacrylate or thiol-ene resin systems.

Abstract: A dental restorative composition comprises: (A) polymerizable monomer(s) selected from hydroxyethyl (meth)acrylate phosphate, hydroxypropyl (meth)acrylate phosphate, hydroxybutyl (meth)acrylate phosphate, dipentaerythritol penta(meth)acrylate phosphate, pentaerythritol tri(meth)acrylate phosphate, phenyl (meth)acryloxyethyl phosphate, and a combination thereof; (B) polymerizable monomer(s) having a molecular weight of 100-250, at least one hydroxyl group, and at least one ethylenically unsaturated group; (C) polymerizable monomer(s) having a molecular weight of 270-900, at least two ethylenically unsaturated groups and no acidic functional group; (D) photo-initiator(s); and (E) filler(s) each having a mean particle size of more than 0.005 microns and less than 70 microns. The weight ratio of (A+B):(C) ranges from 30:70 to 90:10, and the composition has a shear bond strength of at least 10MPa to both dentin and enamel after being light-cured.

Abstract: A photopolymerizable dental composition for application to and for the isolation and protection of gums and/or teeth during dental treatment is described. The composition can include (a) one or more photopolymerizable monomers selected from the group consisting of acrylates and methacrylates, (b) one or more photoinitiators, preferably selected from the group consisting of alpha-diketones, benzoin alkyl ethers, thioxanthones, benzophenones, acyl phosphine oxides, acetophenones, ketals, titanocenes, borates and sensitizing dyes, and (c) one or more molecular weight regulators selected from the group consisting of compounds which can be reacted with a radical of a monomer of component (a) with abstraction of an H radical from the molecular weight regulator in the allyl position. Also disclosed are kits comprising such a composition, methods for producing a corresponding protective layer, methods for treating one or more teeth, and methods of using the compositions as a masking compound.

Abstract: An ink composition is provided that includes (A) an N-vinyllactam, (B) another polymerizable compound, (C) a polymerization initiator, and (D) a basic compound, the content of the N-vinyllactam (A) being less than 15 wt % of the total weight of the ink composition. There is also provided an inkjet recording method that includes (a1) a step of discharging the ink composition onto a recording medium and (b1) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation. There is also provided a printed material recorded by the inkjet recording method.

Abstract: To provide a composition useful for forming a heat conductive sheet that satisfies both high heat conductivity and sufficient softness, has sufficient cohesive strength at a surface portion of a heat conductive sheet and does not cause remaining paste and breakage of an electronic appliance when the sheet is peeled. The composition comprises (A) a photo polymerizable component consisting of a (meth)acryl type monomer or its partial polymer; (B) a heat conductive filler; (C) a photo reaction initiator for initiating the polymerization of the photo polymerizable component; and (D) a photo absorber for absorbing and removing a predetermined wavelength band from electromagnetic rays used for the polymerization of the photo polymerizable component.

Abstract: An ink set for inkjet recording is provided that includes at least a colored liquid comprising at least a radically polymerizable compound, a photopolymerization initiator, and a colorant and an undercoat liquid comprising at least a radically polymerizable compound and a photopolymerization initiator, the undercoat liquid comprising a sensitizer represented by Formula (I) below. In Formula (I) above, X denotes O, S, or NR, n denotes 0 or 1, R denotes a hydrogen atom, an alkyl group, or an acyl group, and R1, R2, R3, R4, R5, R6, R7, and R8 independently denote a hydrogen atom or a monovalent substituent. There is also provided an inkjet recording method employing the ink set for inkjet recording, the method including a step of applying the undercoat liquid on top of a recording medium, a step of semi-curing the undercoat liquid, and a step of carrying out image formation by discharging the colored liquid on top of the semi-cured undercoat liquid.

Abstract: To provide a photocurable composition with which a fine pattern molded product on which a fine pattern of a mold is highly precisely transferred can efficiently be produced. A photocurable composition comprising 100 parts by mass of a photocurable monomer (A), from 5 to 60 parts by mass of a colloidal silica (B) (solid content) having an average particle size of at most 200 nm, and from 0.1 to 10 parts by mass of a photopolymerization initiator (C), wherein the photocurable monomer (A) comprises a multifunctional monomer (A1) having at least 3(meth)acryloyloxy groups in one molecule and a bifunctional monomer (A2) having two (meth)acryloyloxy groups in one molecule, at least one compound belonging to the multifunctional monomer (A1) or the bifunctional monomer (A2) has a hydroxy group, and the ratio of the total amount (mol) of hydroxy groups to the total amount (mol) of the multifunctional monomer (A1) and the bifunctional monomer (A2) is at least 10%.

Abstract: Methods for generating metallic particles in situ in a polymer are disclosed. A method includes (a) contacting the polymer with a solution comprising (i) a solvent, (ii) a metal salt, and (iii) a free radical generator; (b) removing the polymer from the solution; and (c) exposing the polymer to actinic radiation. Polymer composites and polymer nanocomposites comprising inorganic particulates comprising metallic particles generated in the polymer are also disclosed.

Abstract: A UV-curable undercoat that contains barium sulfate, production thereof, methods of coating substrates with the undercoat and the coated substrates.

Abstract: The invention provides a polymer mixture which is cross-linkable and halogen-free. The polymer mixture is particularly suitable as casing for cables or lines and is distinguished by a high cold strength and resistance to oils.

Abstract: The invention concerns a dental filling material with dual hardening mechanism, wherein i) a first hardening mechanism is based on a photocuring reaction, preferably a radical reaction, and ii) a second hardening mechanism is dependent on H2O as a reactant, especially as a ligand. Preferably, the second hardening mechanism is a gypsum-type reaction. Owing to the expansion of the composition an excellent marginal seal can be achieved, while the first hardening mechanism allows for a rapid cure on demand.

Abstract: A radiation curing composition suitable for building a three-dimensional object by a solid freeform method is disclosed. The composition includes one or more mono-functional monomers where a respective polymer has a Glass Transition Temperature higher than about 60° C., one or more di-functional oligomers where a respective polymer has a Glass Transition Temperature lower than about 40° C. and a filler that comprises particles having an average diameter of less than 100 nm. The functional groups of the components may include meth(acrylic) and the composition has a viscosity of about 50-500 cps at ambient temperature. Further, the concentration of the mono-functional monomer may be at least 30% by weight elative to the total weight of the composition and the concentration of the di-functional oligomer may be at least 20% by weight elative to the total weight of the composition.

Abstract: The present invention is to provide a solar cell sealing film which suppresses occurrence of rust on conducting wires or electrodes and which is improved in transparency and generating efficiency of the solar cell, and a solar cell having the sealing film. The solar cell sealing film comprises ethylene-vinyl acetate copolymer, a crosslinker and an adsorbent, which comprises, as the adsorbent, an inorganic fine particle having refractive index of not more than 1.54 in an amount of 0.1 to 1.5 part by weight based on 100 parts by weight of the ethylene-vinyl acetate copolymer.

Abstract: The claimed invention relates to a flexible substrate having reduced shrinkage and curling, wherein said substrate is coated with a coating having a dual cure system, wherein said coating comprises a free radical curable component and a cationically curable component.

Abstract: The present invention provides a multi-layered object having a hard coat layer capable of improving anti-staining property, anti-staining durability, scratch resistance, abrasion resistance and the like. A multi-layered object comprising a hard coat layer and a light transmitting layer, wherein the hard coat layer is formed from a composition for hard coat comprising: an active energy ray-curable silicone-acrylic copolymer (A); and an active energy ray-curable polyfunctional compound (B), and wherein the active energy ray-curable silicone-acrylic copolymer (A) contains: a polysiloxane block (a-1), an acrylic block (a-2) containing an active energy ray-curable double bond group and a fluoroalkyl group-containing acrylic block (a-3).

Abstract: An eco friendly radiation cross-linked composition is described that demonstrates excellent resistance to fire and high temperature along with good mechanical properties. The composition which is based on a blend of EVA with a LLDPE, is free of monomer such as vinyl co-agent for radiation cross-linking. The halogen free flame retardant composition is a mixture of 20 to 90% by weight of magnesium hydroxide (powder A) and 90% to 20% of powder B. Preferably the powder B is a double salt of magnesium carbonate and calcium carbonate and the magnesium hydroxide has a specific surface treatment. In addition, 0.5 to 5 parts of flame retardancy auxiliary agents are selected from talc, zinc borate or molybdate derivative. The chemicals used here reduce toxicity in the environment and do not release toxic chemicals to air and soil during fire. The flame retardant cross-linked polyolefin composition is particularly useful for insulating wires and cables.

Abstract: The invention provides a coating composition comprising a thermal plastic resin selected from the group consisting of a polycycloolefin resin, polyester resin, polyacrylate resin, and a mixture thereof; and a radiation curable resin comprising a radiation polymer containing at least one mono- or multi-functional acrylic acid based monomer as a polymerization unit, an oligomer containing an ethylenically unsaturated functional group, and a photoinitiator, wherein the radiation curable resin is used in an amount of 220-1000% by weight on the basis of the weight of the thermal plastic resin. The invention improves the hardness of the coating composition, prevent the coated substrate from being scratched or impaired, and impart the substrate with high transparency without causing warping problem.

Abstract: A transparent laminate comprises an optically clear, cured coating layer including abrasion-resistant nanoparticles, and one or more monomers and/or one or more oligomers that are reacted in the presence of an ultraviolet light photoinitiator. The coating layer also contains a surface portion rich in hydrophilic surfactant so that the coating layer when residing on a transparent substrate forms a laminate having good abrasion resistant properties as well as good anti-fog properties.

Abstract: Multilayer radiation curable liquid coating compositions are provided that include one or more UV oligomers including at least one aliphatic urethane acrylic oligomer; at least one acrylate diluent monomer selected from a mono-, bi-, and tri-functional reactive acrylate diluent monomers; at least one photo-initiator; at least one UV absorber; at least one hindered amine light stabilizer; and at least one antioxidant, where the liquid composition does not comprise a solvent and does not comprise an adhesion promoter. The UV oligomer in the base coat composition has elongation higher than 200% and tensile strength lower than 1000 psi. The UV oligomer in the top coat composition has tensile strength higher than 5000 psi. A coating system is provided that includes a liquid primer coat composition, a liquid base coat composition and a liquid top coat composition.

Abstract: A silica aerogel coating is produced by reacting a wet gel obtained by the hydrolysis and polymerization of alkoxysilane with an organic-modifying agent to form organically modified silica, dispersing the organically modified silica by an ultrasonic treatment to form an organically modified silica dispersion, adding an ultraviolet-curable resin and a photo-polymerization initiator to the dispersion to prepare a coating liquid, applying the coating liquid to a substrate, and then irradiating ultraviolet rays to the coated layer.

Abstract: The present invention provides an inkjet ink composition including color material particles, a water soluble polymerizable compound, a water soluble silicate salt and water, which is excellent in ejection stability even in a case in which the ink composition is stopped from ejecting in the inkjet recording device and left alone for a certain period of time, and ejection of the ink composition is resumed thereafter, which has a good maintenance property, and in which abrasion resistance of images formed with the ink composition is excellent; an ink set including the inkjet ink composition; and an image forming method using the ink set.

Abstract: A plasticized ceramic-forming mixture and a method for stiffening the mixture, the mixture comprising a combination of inorganic powder, one or more plasticizing organic binders, a radiation-curable monomer, a photoinitiator, and water, and the method comprising stiffening the surfaces of extruded shapes of the mixture by applying electromagnetic energy to the surfaces following extrusion.