Processes Involving A Polyurethane Having Terminal Ethylenic Unsaturation As Reactant Or As Solid Polymer; Or Compositions Therefore Patents (Class 522/90)
Abstract: A composition is also provided that includes mercapto modified resin; aliphatic urethane acrylate; a multifunctional crosslinking agent; photoinitiator; and a hindered amine light stabilizer. The composition provides a fast curing coating that utilizes photopolymerization reactions using a variety of light sources such as low energy consuming and environmentally-friendly UV-LED and sunlight. Features of the coating include clarity, hardness, non-yellowing, scratch resistance, and complete surface cure as well as outstanding adhesion to substrates such as plastic, wood, stone and metal.
Abstract: A lower part protection film for an OLED panel is provided. More particularly, a lower part protection film for an OLED panel, having a significantly improved recognition rate of an alignment process, being capable of preventing generation of static electricity through an antistatic treatment, and having excellent adhesion to an OLED panel at the same time, and an organic light-emitting display apparatus including the lower part protection film for an OLED panel are provided.
Type:
Grant
Filed:
August 20, 2021
Date of Patent:
April 16, 2024
Assignee:
Samsung Display Co., Ltd.
Inventors:
Youngseo Choi, Sangshin Kim, Jinhyuk Kim, Youngdon Park, Youngbin Baek, Sangwoo Lee
Abstract: Provided are methods and compositions relating to a dental composition more specifically to prepare the damaged dentin of the tooth for animals and pets such as canine, feline and members of the taxonomic family Equidae prior to repair. The dental compositions include a bioactive glass and a non-aqueous solvent comprising an alcohol, anti-inflammatory and anti-pain reliever.
Abstract: A photocurable composition can comprise a polymerizable material and a photoinitiator, wherein the polymerizable material may comprise at least one first polymerizable monomer having a structure of Formula (1): (R1)x—Ar—(R2)y (1), with Ar being one or more substituted or unsubstituted aromatic rings; R1 being a structure covalently bonded to Ar including at least one acrylate group; x being 1-4; and R2 being —CH?CH2 or —CCH3=CH2 covalently bonded to Ar; y being 1-4.
Abstract: To provide an active-energy-ray-curable composition including a compound represented by General Formula (I) below: where in the General Formula (I), R is hydrogen or a methyl group; A is a structure expressed by one selected from the group consisting of Structural Formulas (II) to (VII) below, each of which may have a substituent such as an alkyl group or an alkoxy group, or both; j and k in the Structural Formulas (VI) and (VII) are an integer of 0 or more; X denotes a substituent including a heteroatom; n is an integer of 0 or more, m is an integer of 1 or more, and n+m is 3 or more, or n is an integer of 0 and m is an integer of 2; and wavy lines in the Structural Formulas (II) to (VII) each independently denote a bond with X or a (meth)acryloyl group (H2C?CR—C(?O)—):
Type:
Grant
Filed:
April 1, 2020
Date of Patent:
March 5, 2024
Assignees:
Ricoh Company, Ltd., Tokyo University of Science Foundation
Abstract: The presently claimed invention is directed to a copolymer obtained by reacting at least one isocyanate (A) comprising at least one allophanate group and at least one active double bond with at least one isocyanate reactive component (B) to form an intermediate product (C); and reacting the intermediate product (C) with at least one active double bond reactive component (D) to obtain the copolymer which can be used as dispersant. The at least one isocyanate reactive component (B) is selected from the group consisting of monofunctional polyether amine (B1), monofunctional polyether alcohol (B2), C6-C30 monofunctional alcohol (B3) and monofunctional polyester alcohol (B4).
Type:
Grant
Filed:
July 17, 2020
Date of Patent:
February 13, 2024
Assignee:
BASF SE
Inventors:
Andreas Gernandt, Huiguang Kou, Steffen Onclin, Clemens Auschra, Johannes Hermann Willenbacher
Abstract: The present invention relates to curable compositions, in particular, thiol-ene-curing compositions, a method of coating using said curable compositions, cured compositions obtained by curing said curable compositions, cured articles, comprising said cured compositions, a certain compound comprising olefinically unsaturated functional groups and a silyl functional group for use in said curable compositions and a method of manufacturing the curable compositions.
Abstract: An object of the present invention is to provide a method for producing a coated material by using a composition that can be spray-coated, and that does not run downward after coating (i.e., rheology controllable). The method for producing a coated material includes step (1) of applying an electron beam-curable composition containing an ethylenically unsaturated group-containing compound to a substrate to form a coating film that has a surface viscosity of 1 Pa·s to 300 Pa·s as measured based on an electric-field pickup method, step (2) of drying the coating film obtained in step (1) to form a dry coating film when the electron beam-curable composition contains a volatile component, and step (3) of irradiating the substrate that has the coating film obtained in step (1) or the dry coating film obtained in step (2) with electron beams in an inert gas atmosphere to form a cured coating film.
Type:
Grant
Filed:
December 21, 2020
Date of Patent:
October 17, 2023
Assignees:
TOAGOSEI CO., LTD., TOYOTA JIDOSHA KABUSHIKI KAISHA
Abstract: The present invention provides an emulsified gel composition comprising a physiologically active substance, water, a gelling agent, an anti-peeling agent, and a surfactant having an HLB value of 18 to 20, in which the gelling agent is a nonionic water-soluble polymer, and the anti-peeling agent is one or more compounds selected from the group consisting of sucrose, sorbitol, polyethylene glycol, glycerin, a (meth)acrylic-based polymer compound, and a polyoxyethylene hydrogenated castor oil.
Type:
Grant
Filed:
November 29, 2021
Date of Patent:
May 30, 2023
Assignee:
HISAMITSU PHARMACEUTICAL CO.. INC.
Inventors:
Shinya Matsumura, Toshihiro Nakanishi, Yasuhisa Kose
Abstract: Provided are methods and compositions relating to a dental composition more specifically to prepare the damaged dentin of the tooth prior to repair. The dental compositions include a bioactive glass and a non-aqueous solvent comprising an alcohol, anti-inflammatory and anti-pain reliver.
Abstract: A method of preparing an acrylic adhesive, in which the durability of an adhesive film may be improved through additional photocuring and the residual components according to solution photopolymerization are efficiently removed, and an adhesive film prepared therefrom.
Type:
Grant
Filed:
February 27, 2018
Date of Patent:
November 29, 2022
Inventors:
Jun Man Choi, Sang Hwan Kim, Jang Soon Kim, Kwang Su Seo, Won Gu Choi, Chi Gwan An
Abstract: Photocurable colloid binders are provided that overcome deficiencies associated with 3D printing of high molecular weight polymers via VAT photopolymerization. Methods of additive manufacturing are also provided using the binders. The approaches described herein effectively decouple the viscosity-molecular weight relationship by synthesizing and processing photo-reactive aqueous colloids that are sequestered within a photocrosslinkable scaffold. Sequestering polymers within discrete internal phases prevents inter-particle entanglement of the polymer chains, thus ensuring low viscosity. VP of polymer colloids results in a solid green body embedded with high molecular weight polymer particles. A post-processing heated drying step allows the polymers to coalesce and further entangle, forming a semi-interpenetrating network with mechanical performance of the high molecular weight material. The resins can further include inorganic particles such as silica and other ceramics, metal particles, and the like.
Type:
Grant
Filed:
March 26, 2020
Date of Patent:
September 6, 2022
Assignee:
VIRGINIA TECH INTELLECTUAL PROPERTIES, INC.
Inventors:
Timothy E. Long, Viswanath Meenakshisundaram, Philip J. Scott, Christopher B. Williams
Abstract: A polymerizable composition for an optical material according to the present invention includes one or two or more compounds selected from the group consisting of component (A): an ester compound having a specific structure and component (B): an ether compound having a specific structure, and a polymerizable compound.
Abstract: Described in preferred embodiments are UV curable coating compositions including a unique blend of aliphatic urethane acrylate resins. Also described are coated articles and methods for their production involving the use of the coating compositions.
Abstract: The present invention relates to a polymer electrolyte for a secondary battery and a lithium secondary battery comprising the same, and particularly, to a polymer electrolyte for a secondary battery, in which mechanical properties, ionic conductivity, and electrical conductivity are improved by comprising a polymer and an electron-acceptor having at least one double bond, as a dopant, and a lithium secondary battery in which electrochemical stability at high temperature and high voltage is enhanced by comprising the polymer electrolyte.
Type:
Grant
Filed:
July 3, 2018
Date of Patent:
September 7, 2021
Inventors:
Sol Ji Park, Kyoung Ho Ahn, Young Jea Kim, Yong Jin Jang, Joong Jin Han, Chul Haeng Lee
Abstract: Processing tapes for use in preparing optical articles include a thermally stable tape backing and a low tack adhesive layer at least partially coated on tape backing. The low tack adhesive layer includes a crosslinked, polyester-containing (meth)acrylate-based polymer that is essentially free of volatile components, is unchanged after heat aging of 150 C for 1 hour under a pressure of 4.31 kiloPascals, and is able to removably adhere to the anti-reflective, nanostructured surface coating of an optical construction.
Type:
Grant
Filed:
December 27, 2016
Date of Patent:
July 7, 2020
Assignee:
3M INNOVATIVE PROPERTIES COMPANY
Inventors:
Lan H. Liu, Edward J. Kivel, Steven D. Solomonson, Stephen A. Johnson
Abstract: A method of accelerating self-healing includes contacting a scratched portion of a self-healing urethane(meth)acrylate-derived material with a plasticizing solvent, wherein the plasticizing solvent comprises water, an alcohol, a ketone, or a combination thereof.
Type:
Grant
Filed:
February 12, 2018
Date of Patent:
November 26, 2019
Assignee:
SAMSUNG ELECTRONICS CO., LTD.
Inventors:
Chung Kun Cho, Mikhail Kovalev, Ginam Kim, Nobuji Sakai, Myung Man Kim
Abstract: Described in preferred embodiments are UV curable coating compositions including a unique blend of aliphatic urethane acrylate resins. Also described are coated articles and methods for their production involving the use of the coating compositions.
Abstract: Methods of producing an elastomer are disclosed that include (I) applying an actinic radiation curable composition preferably selected from a urethane (meth)acrylate, an allophanate urethane (meth)acrylate or a lactone-containing (meth)acrylate to a substrate at a thickness of at least 0.25 mm (10 mils); (II) exposing the composition ultraviolet radiation to produce a cured film; and (III) removing the film from the substrate. Related compositions are also disclosed.
Type:
Grant
Filed:
March 10, 2014
Date of Patent:
October 16, 2018
Assignee:
ALLNEX NETHERLANDS B.V.
Inventors:
Michael Jeffries, Myron Shaffer, Charles Gambino, Christine Mebane, Michael Dvorchak
Abstract: Described in preferred embodiments are UV curable coating compositions including a unique blend of aliphatic urethane acrylate resins. Also described are coated articles and methods for their production involving the use of the coating compositions.
Abstract: The present invention relates to the use of a radiation-hardenable resin composition for producing solar laminates, a method for creating a solar laminate using the resin composition according to the invention, and a solar laminate that can be produced using this method.
Type:
Grant
Filed:
March 25, 2013
Date of Patent:
November 7, 2017
Assignee:
Covestro Deutschland AG
Inventors:
Bernd Rothe, Jens Geschke, Dirk Achten, Helmut Kuczewski, Wolfgang Fischer
Abstract: Described herein is a process for preparing urethane (meth)acrylates. In a first step, a hydroxyalkyl (meth)acrylate is reacted with a lactone (B) in the presence of at least one zinc compound and/or bismuth compound (C) to produce a resulting zinc-containing product and/or a bismuth-containing product, and, in a further step, the zinc-containing product and/or the bismuth-containing product is reacted with at least one cycloaliphatic or asymmetric aliphatic diisocyanate (D).
Type:
Grant
Filed:
May 16, 2014
Date of Patent:
August 22, 2017
Assignee:
BASF SE
Inventors:
Reinhold Schwalm, Susanne Neumann, Delphine Kimpel
Abstract: A photocurable material that allows dark portion curing even if the form of a material to be cured is complicated and the length of an unirradiated portion is long. The photocurable material has both of radical curability and anionic curability, is a photocurable liquid composition curable by irradiation of light, and contains (meth)acrylate and a chain transfer agent, wherein the chain transfer agent is a compound containing one or more of at least one kind selected from a urethane bond, a urea bond, and an isocyanate group, and one or more alkoxysilyl groups. The photocurable material is capable of curing even a portion that irradiation light does not reach.
Type:
Grant
Filed:
August 9, 2013
Date of Patent:
July 4, 2017
Assignees:
AUTONETWORKS TECHNOLOGIES, LTD., SUMITOMO WIRING SYSTEMS, LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD., KYUSHU UNIVERSITY
Abstract: An optical fiber ribbon according to the present invention includes a collective coating layer containing an ultraviolet curable resin containing amorphous PPG and an amorphous monomer, the collective coating layer formed around coated optical fibers. The collective coating layer has an equilibrium elastic modulus of 12 MPa to 20 MPa, both inclusive, and a yield point elongation of 5% to 9%, both inclusive, and the adhesion between the collective coating layer and the outermost layers of the coated optical fibers is 12 N/cm to 15 N/cm, both inclusive.
Abstract: A chemical mechanical polishing pad for polishing a substrate selected from at least one of a magnetic substrate, an optical substrate and a semiconductor substrate is provided containing a polishing layer, wherein the polishing layer comprises the reaction product of raw material ingredients, including: a polyfunctional isocyanate; and, a curative package; wherein the curative package contains an amine initiated polyol curative and a high molecular weight polyol curative; wherein the polishing layer exhibits a density of greater than 0.6 g/cm3; a Shore D hardness of 5 to 40; an elongation to break of 100 to 450%; and, a cut rate of 25 to 150 ?m/hr; and, wherein the polishing layer has a polishing surface adapted for polishing the substrate. Also provide are methods of making and using the chemical mechanical polishing pad.
Type:
Grant
Filed:
November 1, 2012
Date of Patent:
September 29, 2015
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Bainian Qian, David B. James, James Murnane, Fengji Yeh, Marty W. DeGroot
Abstract: An overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a urethane resin having at least six radical polymerizable functional groups. The at least six radical polymerizable functional groups may include acrylate group, methacrylate group, styrenic group, allylic group, vinylic group, glycidyl ether group, epoxy group, or combinations thereof. This overcoat layer has an improved wear resistance, thus protecting the organic photoconductor drum from damage and extending its useful life.
Abstract: An overcoat layer for an organic photoconductor drum of an electrophotographic image forming device is provided. The overcoat layer is prepared from a curable composition including a urethane resin having at least six radical polymerizable functional groups. The at least six radical polymerizable functional groups may include acrylate group, methacrylate group, styrenic group, allylic group, vinylic group, glycidyl ether group, epoxy group, or combinations thereof. This overcoat layer has an improved wear resistance, thus protecting the organic photoconductor drum from damage and extending its service life.
Abstract: This invention is directed to a polymer thick film UV-curable thermoformable dielectric composition. Dielectrics made from the composition can be used in various electronic applications to protect electrical elements and particularly to insulate and protect both the conductive thermoformable silver and the polycarbonate substrate below it in capacitive switch applications. The thermoformed capacitive switch circuit may be subsequently subjected to an injection molding process.
Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
Type:
Grant
Filed:
September 1, 2005
Date of Patent:
March 17, 2015
Assignee:
ALLNEX IP S.a.r.L.
Inventors:
Jan Weikard, Dorota Greszta-Franz, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock, Christophe Detrembleur
Abstract: Fiber coatings with low Young's modulus and high tear strength are realized with coating compositions that include an oligomeric material formed from an isocyanate, a hydroxy acrylate compound and a polyol. The oligomeric material includes a polyether urethane acrylate and a di-adduct compound, where the di-adduct compound is present in an amount of at least 2.35 wt %. The reaction mixture used to form the oligomeric material may include a molar ratio of isocyanate:hydroxy acrylate:polyol of n:m:p, where n may be greater than 3.0, m may be between n?1 and 2n?4, and p may be 2. Young's modulus and tear strength of coatings made from the compositions increase with increasing n. Coatings formed from the present oligomers feature high tear strength for a given Young's modulus.
Abstract: An optical adhesive film prepared from an optical adhesive composition, an optical adhesive composition, and a display panel, the optical adhesive film having an elongation of about 200 to about 800% and a tensile strength of about 10 gf/mm2 or less, and the optical adhesive composition including a urethane (meth)acrylate copolymer, a reactive monomer, and an initiator.
Type:
Grant
Filed:
December 27, 2011
Date of Patent:
February 17, 2015
Assignee:
Cheil Industries, Inc.
Inventors:
Lee June Kim, Ji Hye Kwon, Kyoung Jin Ha, Kil sung Lee
Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.
Type:
Grant
Filed:
October 13, 2010
Date of Patent:
January 27, 2015
Assignees:
Kabushiki Kaisha Toyota Jidoshokki, Toagosei Co., Ltd.
Abstract: Disclosed is an actinic radiation-curing type ink composition comprising (Component A) a monofunctional radically polymerizable monomer and (Component B) a polyfunctional acrylate oligomer having a glass transition temperature of no greater than 20° C. and having an acrylate equivalent of at least 300 g/eq, Component A comprising (Component A-1) an N-vinyl compound and (Component A-2) an acrylamide derivative, Component A having a content of at least 70 mass % of the entire ink composition, and Component A-1 having a content of at least 18 mass % of the entire ink composition.
Abstract: There are provided a fluorine-containing photocurable resin composition and a method of preparing a mold comprising the same and more particularly, a photocurable resin composition having chemical resistance, mechanical properties and high transmittance, etc. as well as being easily wetted with and released from thermosetting or photocurable resins for pattern formation regardless of additional surface treatment, as opposed to the existing polymer resin materials used for resin molds, and a method of preparing a resin mold using the same.
Type:
Grant
Filed:
July 7, 2010
Date of Patent:
January 20, 2015
Assignee:
Dongjin Semichem Co., Ltd.
Inventors:
Jae-won Yoo, Byung-uk Kim, Un-yong Kim, Eun-jin Kwak
Abstract: Disclosed is a urethane (meth)acrylate oligomer which is obtained by reacting at least one polyoxyalkylene polyol (A), at least one monool (B1) soluble in the component (A) and/or at least one silane coupling agent (B2) reactive with an isocyanate group, at least one polyisocyanate (C) and at least one hydroxylated mono (meth)acrylate compound (D) at a ratio at which the equivalent weights of hydroxy groups, active hydrogen groups and isocyanate groups in the respective components satisfy the following formulae (1)-(3). The urethane (meth)acrylate oligomer does not substantially contain an unreacted isocyanate group. B(active hydrogen)+D(OH)=C(NCO)?A(OH) (1) 1.05?C(NCO)/A(OH)?2 (2) {C(NCO)?2A(OH)+2m}×0.35?D(OH)?{C(NCO)?2A(OH)+2m}×0.
Type:
Grant
Filed:
December 31, 2013
Date of Patent:
January 13, 2015
Assignee:
Hitachi Chemical Company, Ltd.
Inventors:
Yoshinobu Ogawa, Kazutoshi Doki, Osamu Kawata, Yoshihiro Tani
Abstract: A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.
Abstract: A photocurable material for sealing including (A) an oligomer having a weight average molecular weight of 10,000 to 30,000 and having (meth)acryloyl group(s), (B) a (meth)acrylate monomer, (C) a polythiol compound, and optionally (D) a carbodiimide compound enables the provision of a sealing material that has high compression recovery performance, high tensile strength and excellent flexibility, can have low hardness if required, and therefore has excellent sealing properties including air-tightness performance and water-proof performance and undergoes the formation of little surface tacks and the like.
Abstract: The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions that provide improved adhesion-promoting and improved solvent-susceptibility.
Type:
Grant
Filed:
March 7, 2011
Date of Patent:
December 2, 2014
Assignee:
Creative Nail Design, Inc.
Inventors:
Thong Vu, Chad Conger, Diane Marie Larsen, David Valia, Douglas D. Schoon
Abstract: The invention relates to a method for functionalizing a thermoset, crosslinked isocyanate-based polymeric solid material which is made of isocyanate and isocyanate reactive components, at least one of which comprises an anchor component which has at least one anchor group. The anchor groups on the solid material are formed by terminal alkene and/or alkyne groups. To functionalize this polymeric solid material it is brought in contact with a solution which contains at least one functional component. This functional component comprises at least one thiol group and is allowed to bind covalently to the polymeric solid material by a free-radical addition reaction between the thiol groups on the functional component and the terminal alkene and/or alkyne anchor groups on the undissolved solid material. An effective functionalization of the polymeric material can thus be achieved notwithstanding the heterogeneous reaction conditions.
Type:
Grant
Filed:
May 14, 2012
Date of Patent:
December 2, 2014
Assignee:
Recticel
Inventors:
Laura Jonckheere, Filip Du Prez, Thu Nguyen
Abstract: Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
Type:
Grant
Filed:
November 5, 2010
Date of Patent:
December 2, 2014
Assignee:
PPG Industries Ohio, Inc.
Inventors:
Charles M. Kania, Kenneth T. Phelps, Kurt A. Humbert, Todd M. Roper, Jiping Shao, David C. Martin
Abstract: The ultraviolet cured optic binder has low curing shrinkage, low hardness and high optical transmittance. Technology programs are as follows: an ultraviolet cured optic binder composition includes the following raw material in parts by weight: 50 to 100 parts of prepolymer, 20 to 90 parts of inert resin, 35 to 70 parts of monomer, 5 to 12 parts of photoinitiator, 2 to 3 parts of coupling reagent, 1 to 2 parts of auxiliaries.
Abstract: This invention relates to a photo-curing or electron beam-curing adherent resin composition being excellent in the adhesiveness to various adherends such as metal oxide, metal, resin and so on, and more particularly to an adherent resin composition of a photo-curing or electron beam-curing type comprising a difunctional urethane (metha)acrylate oligomer (A) and a monomer component (B), characterized in that the urethane (metha)acrylate oligomer includes a urethane prepolymer portion composed of a polyol and a polyisocyanate wherein repetitive number of urethane prepolymer portion (n) is 10-30, and the monomer component (B) is a cyclic monomer having a (metha)acryloyl group.
Abstract: The invention relates to radiation-curable aqueous composition comprising a high molecular weight ethylenically unsaturated polyurethane obtained from the reaction of a polyisocyanate, at least one hydrophilic compound which is capable to render the polyurethane prepolymer dispersible in aqueous medium, an ethylenically unsaturated compound containing at least two reactive groups capable to react with isocyanate groups and an active hydrogen containing chain extender and a low molecular weight ethylenically unsaturated polyurethane end-capped with an ethylenically unsaturated compound containing essentially one reactive group capable to react with isocyanate groups.
Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.
Type:
Grant
Filed:
February 12, 2010
Date of Patent:
October 7, 2014
Assignee:
ALLNEX IP S.a.r.L.
Inventors:
Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
Abstract: A variety of biomedical devices are provided which include thiol-ene or thiol-yne shape memory polymers. The biomedical devices of the invention are capable of exhibiting shape memory behavior at physiological temperatures and may be used in surgical procedures. Methods of making the devices of the invention are also provided.
Type:
Grant
Filed:
April 22, 2009
Date of Patent:
September 30, 2014
Assignee:
The Regents of the University of Colorado, a Body Corporate
Inventors:
Christopher Bowman, Neil Cramer, Robin Shandas, Devatha P. Nair
Abstract: The present invention provides a polymer having the structure of formula (I) wherein n, R1, R2, R3, R4, R5, R6, a, b and c are as defined in the specification. The present invention also provides a negative-acting photoimageable composition comprising the above-mentioned polymer of formula (I), which is suitable for the fabrication of printed circuit boards.
Abstract: An optical adhesive composition includes a urethane (meth)acrylate resin having at least one hydroxyl group and at least one vinyl group, the urethane (meth)acrylate resin having a curing contraction ratio expressed by Equation 1 of about 0 to about 3%; and an adhesion of about 30 to about 80 kgf: Curing contraction ratio (%)=(A?B)/A×100,??[Equation 1] where A is a specific gravity of the optical adhesive composition before curing, and B is a specific gravity of the solid optical adhesive composition after curing.
Type:
Grant
Filed:
October 14, 2011
Date of Patent:
September 16, 2014
Assignee:
Cheil Industries, Inc.
Inventors:
Kyoung Jin Ha, Ji Hye Kwon, Kil Sung Lee, Irina Nam, Lee June Kim
Abstract: Ink deposited on a substrate by an ink-jet arrangement to form a protective layer includes hardenable oligomer, hardenable monomer selected from a group including alkoxylated and/or poly-alkoxylated acrylic monomers comprising one or more di- or tri-acrylates, and a photoinitiator. The oligomer has a room temperature viscosity greater than 1 Pa·s. The oligomer to monomer weight ratio is between 1/6 and 1/25. The ink has a room temperature viscosity between 15 and 22 mPa·s and between 5 and 2 mPa·s at 60° C., and a room temperature surface tension between 15 and 28 mN/m. The photoinitiator is activated by a UV source having an appropriate wavelength and intensity.