With Ethylenic Reactant Patents (Class 522/96)
  • Patent number: 10745576
    Abstract: The invention relates to compositions, comprising. a) 1.00 to 65.00% by weight of at least one compound of formula (I), wherein R1, R2, R3, R4 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy-C1-C6-alkyl; R is H or C1-C6-alkyl; X is CR6R7, O, or NR8; R6R7 are each independently H, C1-C6-alkyl, C1-C6-alkoxy, or C1-C6-alkoxy-C1-C6-alkyl; R8 is H, C1-C6-alkyl, or C1-C6-alkoxy-C1-C6-alkyl; k is 1, 2, 3, 4 or 5, as component A; b) 1.00 to 60.00% by weight of at least one monomer having two (meth)acrylate groups and having a molecular weight of no more than 500 Dalton, as component B; c) 0 to 25% by weight of at least one monomer having at least three (meth)acrylate groups and having a molecular weight of no more than 600 Dalton, as component C; and d) 1.00 to 30.
    Type: Grant
    Filed: February 9, 2018
    Date of Patent: August 18, 2020
    Assignee: BASF SE
    Inventors: Christoph Fleckenstein, Juergen Baro, Erich Beck, Martin Kaller, Andrea Misske, Friederike Fleischhaker
  • Patent number: 10723889
    Abstract: The present invention provides substantially isocyanate-free multicomponent compositions useful in making rapid dry automotive primer compositions and coatings, the compositions having a % PVC of from 20 to 60, or preferably, from 25 to 50, and comprising one or more pigment, extender or filler, one or more a) polycarbamates from alkyd polyol or acrylic polyol and one or more b) a polyaldehydes or the acetal or hemiacetal thereof as a second component. The multicomponent compositions cure quickly at a temperature of from 0° C. to less than 80° C. to form a crosslinked polyurethane which dries to enable sanding after only 15 to 45 minutes.
    Type: Grant
    Filed: May 26, 2015
    Date of Patent: July 28, 2020
    Assignee: Dow Global Technologies LLC
    Inventors: Jeff R. Anderson, John N. Argyropoulos, Nahrain E. Kamber, Rebecca S. Ortiz, Christopher D. Rainey, Gary E. Spilman
  • Patent number: 10568814
    Abstract: Photo-curable compositions for artificial teeth and denture base and a method for manufacturing denture by a three-dimensional printing system are provided. The compositions include photo-curable organic compounds, surface modified nano-sized inorganic filler, photo-initiator, colorant, and stabilizer. The composition is in a viscous liquid state having 1,000-5,200 cps at room temperature and has a low viscosity of 50-500 cps at 70° C. The composition also has an excellent curing rate for three-dimensional printing. Using the compositions, denture having a distinctive denture base and a set of artificial teeth can be manufactured via an inkjet type or digital light process type three-dimensional printing according to Computer Aided Design (CAD) data.
    Type: Grant
    Filed: October 11, 2017
    Date of Patent: February 25, 2020
    Assignee: DENTCA, Inc.
    Inventor: Jae Sik Lee
  • Patent number: 10562996
    Abstract: When achieving high hardness by forming a hardcoat layer including only organic matter, cure shrinkage increases, a film on which the hardcoat layer is formed curls, and in extreme cases, the hardcoat layer is prone to cracking; on the other hand, when attempting to suppress cure shrinkage, it is difficult for sufficient high hardness to be exhibited. Furthermore, organic/inorganic hybrid curable resin compositions use inorganic matter such as silica in order to increase hardness. However, this leads to the problem of the inherent properties of the resin, such as workability, being lost. The abovementioned problems have been solved by a curable resin composition containing: a urethane (meth)acrylate, which is a reactant comprising norbornane diisocyanate and a compound having one hydroxyl group and one or more (meth)acryloyl groups in a molecule; and a (meth)acrylate monomer, which is a reactant comprising a polyol having a condensed polycyclic structure, and (meth)acrylic acid.
    Type: Grant
    Filed: February 3, 2016
    Date of Patent: February 18, 2020
    Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Fumiaki Kakeya, Takahiro Matsumoto
  • Patent number: 10376686
    Abstract: The present invention relates to a cap for a medical connector. More specifically, the present invention related to an antimicrobial cap for placement over a connector, wherein various features of the antimicrobial cap maintain the connector in an antiseptic state.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: August 13, 2019
    Assignee: Becton, Dickinson and Company
    Inventors: Jonathan Karl Burkholz, Huibin Liu, S. Ray Isaacson, Weston F. Harding, Lawrence J. Trainer
  • Patent number: 10377918
    Abstract: A coating composition that exhibits high cure speed is described. The coating composition includes one or more monomers, one or more oligomers, and a photoinitiator. The coating composition further includes a photo sensitizer that acts in cooperation with a photoinitiator to increase cure speed.
    Type: Grant
    Filed: August 31, 2018
    Date of Patent: August 13, 2019
    Assignee: Corning Incorporated
    Inventor: Yangbin Chen
  • Patent number: 10316133
    Abstract: An ethylenically unsaturated polyurethane, which is an oligomer or polymer, results from the reaction of A) an alcohol component comprising: A1) at least one hydroxylated polydiene oligomer or polymer which may optionally be alkoxylated and A2) at least one hydroxyl-functional ethylenically unsaturated compound, which is a monomer or oligomer, bearing at least one ethylenic unsaturation and B) an isocyanate component comprising at least one polyisocyanate with a functionality of at least 2, wherein the molar ratio OH/NCO is greater than 1 and wherein said polyurethane bears reactive free hydroxyl groups. Such ethylenically unsaturated polyurethanes are useful as components of curable compositions such as coatings or adhesives.
    Type: Grant
    Filed: April 28, 2015
    Date of Patent: June 11, 2019
    Assignee: ARKEMA FRANCE
    Inventors: Jin Lu, Xiaoxing Dong
  • Patent number: 10294331
    Abstract: [Problem] To provide an active energy ray-curable composition which provides a cured product having excellent transparency as well as superior shock absorption and vibration absorption, and a cured product, a shock-absorbing material, a vibration-absorbing material and a sheet material in which said active energy ray-curable composition is used. [Solution] An active energy ray-curable composition containing (A) diallyl 1,4-cyclohexane dicarboxylate, (B) a compound having two or more mercapto groups, and (C) a polymerization initiator.
    Type: Grant
    Filed: December 21, 2015
    Date of Patent: May 21, 2019
    Assignee: SHOWA DENKO K.K.
    Inventors: Akiko Sato, Eri Hatakeyama, Manabu Nakamura, Asuka Toda
  • Patent number: 10189944
    Abstract: Provided are methods for surface-modifying a rubber vulcanizate or a thermoplastic elastomer, the methods forming a surface with a chemically fixed lubricant instead of resin coating which has drawbacks, such as that the coating is, for example, removed or peeled during the movement within a vessel, whereby the lubricity is reduced. The present invention relates to a method for surface-modifying an object of a rubber vulcanizate or a thermoplastic elastomer, the method including step 1 of forming polymerization initiation points on a surface of the object, and step 2 of radically polymerizing a deliquescent monomer starting from the polymerization initiation points by irradiation with ultraviolet light having a wavelength within the range of 300 to 400 nm, to grow polymer chains on the surface of the object.
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: January 29, 2019
    Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.
    Inventor: Yasuhisa Minagawa
  • Patent number: 9994672
    Abstract: The present invention relates to a process for the preparation of a hydroxy-amino polymer, comprising the steps: a) reacting an H-functional starter compound carrying at least one Zerewitinoff-active H atom with an unsaturated cyclic carboxylic acid anhydride and at least one alkylene oxide compound to give a hydroxyl-group-carrying prepolymer, b) adding a primary amine and/or ammonia to the double bonds of the hydroxyl-group-carrying prepolymer obtained according to step a) to give the hydroxy-amino polymer, wherein the reaction of the H-functional starter compound with the unsaturated cyclic carboxylic acid anhydride and/or the addition of the alkylene oxide compound is carried out using a double metal cyanide catalyst (DMC catalyst). The invention relates additionally to a hydroxy-amino polymer obtainable by the above-mentioned process, wherein the ratio of the amount of alkylene oxide compound to the amount of carboxylic acid anhydride is at least 1.
    Type: Grant
    Filed: December 17, 2012
    Date of Patent: June 12, 2018
    Assignee: Covestro Deutschland AG
    Inventors: Klaus Lorenz, Jorg Hofmann, Hartmut Nefzger
  • Patent number: 9975313
    Abstract: A decorative sheet (1) pertaining to the present invention comprises a base material (2), a colored ink layer (3), a primer layer (4), and a surface-protecting layer (5) in this order, wherein the base material (2) comprises a polyester-based film wherein a thickness of the base material (2) is 20 ?m or more but 95 ?m or less; the surface-protecting layer (5) comprises a cured product of an ionizing radiation-curable resin composition wherein elongation of the cured product according to JIS K6732 is 1% or more; and elongation of the decorative sheet according to JIS K6732 is 30% or more but 180% or less. This enables all of secondary workability, weather resistance, and fire resistance to be enhanced.
    Type: Grant
    Filed: September 28, 2012
    Date of Patent: May 22, 2018
    Assignee: DAI NIPPON PRINTING CO., LTD.
    Inventors: Saori Miyazaki, Takeshi Kobayashi, Hitoshi Nishikawa
  • Patent number: 9534151
    Abstract: A sheet is produced by curing an energy ray curable composition which includes a urethane acrylate oligomer and a compound having a thiol group in the molecule. The sheet has heat resistance to prevent outgassing.
    Type: Grant
    Filed: September 20, 2010
    Date of Patent: January 3, 2017
    Assignees: LINTEC Corporation, Arakawa Chemical Industries, LTD
    Inventors: Hironobu Fujimoto, Tsutomu Iida, Tomohide Fukuzaki
  • Patent number: 9394436
    Abstract: A method of preparing a flexible, substantially tack free gasket by forming a liquid composition which is a radiation polymerizable admixture of a free radical polymerizable urethane(meth)acrylate monomer, free radical polymerizable urethane(meth)acrylate oligomer, or combinations thereof; a free radical polymerizable diluent; a free radical polymerization photoinitiator; a wax; a thixotropic agent; and optionally an adhesion promoter and a colorant. The composition is distributed onto a substrate and then exposed to actinic radiation to cure the liquid composition into a flexible, substantially tack free gasket having a Shore A hardness of from about A20 to about A80.
    Type: Grant
    Filed: August 26, 2013
    Date of Patent: July 19, 2016
    Assignee: DYMAX CORPORATION
    Inventors: Aysegul Kascatan Nebioglu, Marufur Rahim
  • Patent number: 9243160
    Abstract: A sheet for forming a hard coating having outstanding low-temperature formability and slip properties and a composition for hard coatings used therefor are disclosed. The sheet for forming a hard coating includes a coating layer formed on one side thereof and containing a hard coating composition prepared by blending a UV curable resin having a (meth)acryloyl functional group with a bi- or higher valent polycarbonate.
    Type: Grant
    Filed: April 5, 2012
    Date of Patent: January 26, 2016
    Assignee: LG HAUSYS, LTD.
    Inventors: Jin-Woo Kim, Yun-Bong Kim, Won-Kook Kim
  • Patent number: 9097867
    Abstract: A coated optical fiber 1 comprising a glass fiber 10 and a primary coating layer 20 on the outer circumference of the glass fiber 10, wherein a resin constituting the primary coating layer 20 contains ingredient(s) having a molecular weight of more than 1,000, which is extracted with methyl ethyl ketone, in an amount of 5% by weight or more and 21% by weight or less and has a Young's modulus of 0.2 to 1.0 MPa. The resin constituting the primary coating layer 20 of the coated optical fiber 1 has a good curability, and the coated optical fiber 1 exhibits a reduced microbending loss.
    Type: Grant
    Filed: June 21, 2013
    Date of Patent: August 4, 2015
    Assignee: SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Kumiko Tachibana, Takashi Fujii, Takashi Takada, Noriaki Iwaguchi, Yoshinori Yamamoto
  • Patent number: 9086526
    Abstract: A photocurable adhesive composition, a module apparatus, and a method of assembling a module, the composition including a urethane (meth)acrylate binder, the composition having a viscosity of about 3,000 to about 6,000 cps at 25° C., and providing an adhesive film having an adhesive strength of about 30 N/cm2 or more.
    Type: Grant
    Filed: December 23, 2011
    Date of Patent: July 21, 2015
    Assignee: CHEIL INDUSTRIES, INC.
    Inventors: Kyoung Jin Ha, Ji Hye Kwon, Kil Sung Lee, Irina Nam, Lee June Kim
  • Patent number: 9074112
    Abstract: An adhesive composition, especially suitable for a two-part adhesive system curable via free radical polymerization comprises; (A) (meth)acrylate ester monomer; (B) chlorinated elastomeric polymer; (C) core-shell impact modifier; and (D) urethane (meth)acrylate oligomer. Example adhesive compositions include urethane (meth)acrylate oligomer (D) derived from (i) a di- or higher isocyanate having at least two isocyanate groups which differ in reactivity; (ii) a chain-extending reagent which has at least two groups selected from hydroxyl and/or amino groups, each capable of reaction with an isocyanate group of (i); (iii) a hydroxymethacrylate component or hydroxyacrylate component.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: July 7, 2015
    Assignee: Scott Bader Company Limited
    Inventors: Samuel Boadu Osae, Steven Lochiel Brown, Roy Gordon Phillipps
  • Patent number: 9034937
    Abstract: A method of treating a surface of a substrate using modified urushiol derived from Toxicodendron vernicifluum is provided. More particularly, the reactivity of a hydroxyl group of urushiol extracted from fresh Toxicodendron vernicifluum is removed before the lacquer is used as a UV coating agent for a substrate such as a steel sheet. Therefore, the substrate may have high antibacterial activity, and excellent appearance and functionalities such as far-infrared radiation, blocking of electromagnetic waves, enhanced corrosion resistance, high crosslinking speed when a low content of a photoinitiator is used, excellent surface gloss and high scratch resistance.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: May 19, 2015
    Assignee: POSCO
    Inventors: Hye Jin Yoo, In Woo Cheong, Chang Se Byeon, Jae Ryung Lee, Jin Tae Kim, Jung Hwan Lee, Yang Ho Choi
  • Publication number: 20150130878
    Abstract: Provided is an active energy ray-curable inkjet ink containing at least photopolymerizable compounds. The photopolymerizable compounds include: at least one monofunctional monomer selected from the group consisting of a monofunctional monomer of which homopolymer has a glass transition temperature of 90° C. or higher, a monofunctional monomer having a ring structure, and a monofunctional monomer of which homopolymer has a glass transition temperature of 90° C. or higher and that has a ring structure; and urethane (meth)acrylate.
    Type: Application
    Filed: October 27, 2014
    Publication date: May 14, 2015
    Inventors: Shizuka KOHZUKI, Mie Yoshino, Takao Hiraoka
  • Patent number: 9012555
    Abstract: This invention is directed to a polymer thick film UV-curable thermoformable dielectric composition. Dielectrics made from the composition can be used in various electronic applications to protect electrical elements and particularly to insulate and protect both the conductive thermoformable silver and the polycarbonate substrate below it in capacitive switch applications. The thermoformed capacitive switch circuit may be subsequently subjected to an injection molding process.
    Type: Grant
    Filed: October 9, 2013
    Date of Patent: April 21, 2015
    Assignee: E I du Pont de Nemours and Company
    Inventor: Jay Robert Dorfman
  • Patent number: 8999509
    Abstract: This invention relates to film composites with a single coating of hard coat material which have a significant improved adhesion together with improved weather resistance while also increasing resistance to abrasion and cracking. In one embodiment, this film composite is comprised of a transparent base sheet having on one side thereof a weather resistant hard coat comprised of: at least one multifunctional acrylate monomer or oligomer; a dual-curable resin comprising an aliphatic urethane acrylate resin having isocyanate functional groups and an aliphatic urethane acrylate having hydroxyl functional groups; an ultraviolet (UV) stabilizer; and a photoinitiator.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: April 7, 2015
    Assignee: CPFilms Inc.
    Inventors: Anthony B. Port, Scott E. Pickett, Steven A. Barth
  • Publication number: 20150087741
    Abstract: The invention relates to a photo-curing and strippable adhesive composition, and it has the advantages of good reworkability, weathering resistance, coating property and visibility. The invention also provides a strippable material and method for manufacturing the same and an electronic component and method for manufacturing the same.
    Type: Application
    Filed: September 15, 2014
    Publication date: March 26, 2015
    Inventor: KUANG-CHIEH LI
  • Patent number: 8980970
    Abstract: The invention relates to a process for preparing binders which contain 1) allophanate groups, 2) groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups) and 3) optionally NCO-reactive groups, by reacting at temperatures ?130° C. A) one or more NCO-functional compounds containing uretdione groups with B) one or more compounds that contain isocyanate-reactive groups and groups that react with ethylenically unsaturated compounds with polymerization on exposure to actinic radiation (radiation-curing groups), and then C) with one or more saturated, hydroxyl-containing compounds other than B), at least one of these compounds having an OH functionality of ?2, in the presence of D) a catalyst containing one or more zinc compounds, the reaction with compounds C) taking place at least proportionally with the formation of allophanate groups. The present invention also relates to the binders obtained by the process of the invention.
    Type: Grant
    Filed: September 1, 2005
    Date of Patent: March 17, 2015
    Assignee: ALLNEX IP S.a.r.L.
    Inventors: Jan Weikard, Dorota Greszta-Franz, Wolfgang Fischer, Jörg Schmitz, Holger Mundstock, Christophe Detrembleur
  • Patent number: 8957156
    Abstract: An optical adhesive film prepared from an optical adhesive composition, an optical adhesive composition, and a display panel, the optical adhesive film having an elongation of about 200 to about 800% and a tensile strength of about 10 gf/mm2 or less, and the optical adhesive composition including a urethane (meth)acrylate copolymer, a reactive monomer, and an initiator.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: February 17, 2015
    Assignee: Cheil Industries, Inc.
    Inventors: Lee June Kim, Ji Hye Kwon, Kyoung Jin Ha, Kil sung Lee
  • Patent number: 8940808
    Abstract: Disclosed is a curable coating agent composition which exhibits excellent wear resistance and weather resistance when applied as a coating agent to plastic or other substrates to be used outdoors. The curable coating agent composition comprises 95 to 65 parts by mass of a component (A) comprising an urethane adduct compound having weather resistance, 5 to 35 parts by mass of a component (B) comprising a specific organosilicon compound, 0.1 to 10 parts by mass of a component (C) which is a radical polymerization initiator, 1 to 12 parts by mass of a component (D) which is an ultraviolet ray absorber, and 10 to 1,000 parts by mass of a component (E) which is an organic solvent, with respect to 100 parts by mass of the components (A) and (B) in total.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: January 27, 2015
    Assignees: Kabushiki Kaisha Toyota Jidoshokki, Toagosei Co., Ltd.
    Inventors: Tetsuya Mitsuoka, Hidetaka Hayashi, Toshihisa Shimo, Kyoko Kumagai, Naoharu Ueda, Kazumasa Inata, Takeshi Fujita, Yasuyuki Sanai, Eiichi Okazaki, Hiroshi Suzuki, Naomasa Furuta
  • Patent number: 8936744
    Abstract: There are provided a fluorine-containing photocurable resin composition and a method of preparing a mold comprising the same and more particularly, a photocurable resin composition having chemical resistance, mechanical properties and high transmittance, etc. as well as being easily wetted with and released from thermosetting or photocurable resins for pattern formation regardless of additional surface treatment, as opposed to the existing polymer resin materials used for resin molds, and a method of preparing a resin mold using the same.
    Type: Grant
    Filed: July 7, 2010
    Date of Patent: January 20, 2015
    Assignee: Dongjin Semichem Co., Ltd.
    Inventors: Jae-won Yoo, Byung-uk Kim, Un-yong Kim, Eun-jin Kwak
  • Patent number: 8933146
    Abstract: The present invention describes the preparation of an aqueous polyurethane dispersion which is cured by radiation, and its use as binder.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: January 13, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Stefan Sommer, Richard Kopp, Harald Blum, Christoph Irle, Jan Weikard, Erhard Luehmann
  • Patent number: 8927615
    Abstract: A method and a system for producing a change in a medium disposed in an artificial container. The method places in a vicinity of the medium at least one of a plasmonics agent and an energy modulation agent. The method applies an initiation energy through the artificial container to the medium. The initiation energy interacts with the plasmonics agent or the energy modulation agent to directly or indirectly produce the change in the medium. The system includes an initiation energy source configured to apply an initiation energy to the medium to activate the plasmonics agent or the energy modulation agent.
    Type: Grant
    Filed: May 8, 2013
    Date of Patent: January 6, 2015
    Assignees: Immunolight, LLC, Duke University
    Inventors: Frederic Avery Bourke, Jr., Tuan Vo-Dinh
  • Publication number: 20150005406
    Abstract: Provided is a photocurable moisture-proof insulating coating material which places little burden on the environment and has excellent surface curability with low irradiation. In addition, this photocurable moisture-proof insulating coating material is hydrophobic and exhibits high adhesion to a substrate material. Also provided is a novel urethane (meth)acrylate which is used for this moisture-proof insulating coating material. A urethane (meth)acrylate of the present invention is obtained by reacting (a) a polyester polyol that has a structural unit derived from a hydrogenated dimer acid and a structural unit derived from a hydrogenated dimer diol, (b) a polyisocyanate compound and (c) a hydroxyl group-containing (meth)acrylate. A moisture-proof insulating coating material of the present invention contains this urethane (meth)acrylate and a (meth)acryloyl group-containing compound that does not contain a silicon atom.
    Type: Application
    Filed: February 1, 2013
    Publication date: January 1, 2015
    Applicant: SHOWA DENKO K.K.
    Inventors: Kazuhiko Ooga, Hiroto Kouka, Kai Suzuki
  • Patent number: 8921445
    Abstract: Curable adhesive compositions are provided that exhibit a high refractive index.
    Type: Grant
    Filed: April 12, 2010
    Date of Patent: December 30, 2014
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yassin Turshani, Omar Mohamed Buazza
  • Patent number: 8923681
    Abstract: An optical fiber core having a primary layer and a secondary layer, which are laminated on a bare optical fiber. The primary layer is formed by curing an ultraviolet-curable resin composition containing a first silane coupling agent, which can be incorporated into a resin skeleton, and a second silane coupling agent, which cannot be incorporated into a resin skeleton. The first silane coupling agent contains a compound having a methoxy group, and the second silane coupling agent contains a compound having an ethoxy group.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: December 30, 2014
    Assignee: Fujikura Ltd.
    Inventors: Akira Namazue, Akira Murata, Mizuki Isaji
  • Patent number: 8921446
    Abstract: A photocurable material for sealing including (A) an oligomer having a weight average molecular weight of 10,000 to 30,000 and having (meth)acryloyl group(s), (B) a (meth)acrylate monomer, (C) a polythiol compound, and optionally (D) a carbodiimide compound enables the provision of a sealing material that has high compression recovery performance, high tensile strength and excellent flexibility, can have low hardness if required, and therefore has excellent sealing properties including air-tightness performance and water-proof performance and undergoes the formation of little surface tacks and the like.
    Type: Grant
    Filed: July 19, 2013
    Date of Patent: December 30, 2014
    Assignee: Nitta Gelatin Inc.
    Inventors: Hiroyuki Nakatani, Seiki Ueno, Kazuyoshi Sekita
  • Patent number: 8901242
    Abstract: [Problem] To provide a composite film having light-curing property and weather resistance. [Means for solving] A composite film is one that comprises at least a urethane polymer, wherein both an initial b* value of the composite film measured by a spectrocolorimeter (value at an angle of 15 degrees) and a b* value after performing an accelerated weathering test for 120 hours (value at an angle of 15 degrees) are 4.0 or less, and a non-volatile component after heating the composite film at 130° C. for two hours is 96% or more.
    Type: Grant
    Filed: April 8, 2009
    Date of Patent: December 2, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Hidenori Suzuki, Masanori Uesugi, Makoto Kai, Mitsuyoshi Shirai
  • Patent number: 8901198
    Abstract: Disclosed herein are solventborne liquid UV-curable coating compositions comprising: a radiation curable compound comprising an acrylate-terminated compound having greater than two unsaturated sites, wherein the acrylate-terminated compound comprises a reaction product of reactants comprising: an adduct of a polyisocyanate, wherein the adduct of a polyisocyanate comprises a reaction product of reactants comprising a polyisocyanate comprising greater than two isocyanate groups and a compound having groups reactive with the isocyanate groups of the polyisocyanate; and an active hydrogen-containing acrylate; and a photoinitiator composition that includes a first photoinitiator composition for providing surface cure and a second photoinitiator composition for providing through cure of the resultant coating layer. Also disclosed are related multi-component composite coatings, coated substrates, and methods for coating a substrate.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: December 2, 2014
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Charles M. Kania, Kenneth T. Phelps, Kurt A. Humbert, Todd M. Roper, Jiping Shao, David C. Martin
  • Patent number: 8901199
    Abstract: The present disclosure relates generally to compositions for natural and artificial nail coatings, and particularly, but not by way of limitation, to polymerizable compositions that provide improved adhesion-promoting and improved solvent-susceptibility.
    Type: Grant
    Filed: March 7, 2011
    Date of Patent: December 2, 2014
    Assignee: Creative Nail Design, Inc.
    Inventors: Thong Vu, Chad Conger, Diane Marie Larsen, David Valia, Douglas D. Schoon
  • Publication number: 20140343186
    Abstract: The ultraviolet cured optic binder has low curing shrinkage, low hardness and high optical transmittance. Technology programs are as follows: an ultraviolet cured optic binder composition includes the following raw material in parts by weight: 50 to 100 parts of prepolymer, 20 to 90 parts of inert resin, 35 to 70 parts of monomer, 5 to 12 parts of photoinitiator, 2 to 3 parts of coupling reagent, 1 to 2 parts of auxiliaries.
    Type: Application
    Filed: February 13, 2012
    Publication date: November 20, 2014
    Applicant: darbond technology co., ltd
    Inventors: Hengli Cui, Jianbin Wang, Haihua Xie
  • Patent number: 8883392
    Abstract: A radiation curing composition suitable for building a three-dimensional object by a solid freeform method is disclosed. The composition includes one or more mono-functional monomers where a respective polymer has a Glass Transition Temperature higher than about 60° C., one or more di-functional oligomers where a respective polymer has a Glass Transition Temperature lower than about 40° C. and a phase separation inducing component. The phase separation may be induced during curing, resulting in a non-clear cured material having an improved impact strength and higher elongation, when compared to similar compositions without a phase separation inducing component.
    Type: Grant
    Filed: June 13, 2013
    Date of Patent: November 11, 2014
    Assignee: Stratasys Ltd.
    Inventors: Eduardo Napadensky, David Brusilovsky
  • Patent number: 8859634
    Abstract: This invention relates to a photo-curing or electron beam-curing adherent resin composition being excellent in the adhesiveness to various adherends such as metal oxide, metal, resin and so on, and more particularly to an adherent resin composition of a photo-curing or electron beam-curing type comprising a difunctional urethane (metha)acrylate oligomer (A) and a monomer component (B), characterized in that the urethane (metha)acrylate oligomer includes a urethane prepolymer portion composed of a polyol and a polyisocyanate wherein repetitive number of urethane prepolymer portion (n) is 10-30, and the monomer component (B) is a cyclic monomer having a (metha)acryloyl group.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: October 14, 2014
    Assignee: BRIDGESTONE Corporation
    Inventors: Junji Sakata, Hajime Kitano, Hiroyuki Kanesugi
  • Patent number: 8859633
    Abstract: Provided are a temporal fixation method in processing of optical members and a resin composition suitable therefore, which uses a composition which is characterized by containing the following (A3), (B3) and (D3), wherein (A3) is a urethane(meth)acrylate; (B3) is one or more (meth)acrylic acid derivative monomers selected from the group consisting of n-(meth)acryloyloxyalkyl hexahydrophthalimides, carboxyl group-containing (meth)acrylates and (meth)acrylic acid derivative monomers represented by the formula (C3): Z—O—(R2O)p—R1??Formula (C3): wherein Z represents a (meth)acryloyl group, R1 represents a phenyl group or a phenyl group having an alkyl group with 1 to 3 carbon atoms, R2 represents —C2H4—, —C3H6—, —CH2CH(CH3)—, —CH2CH(OH)CH2—, —C4H8— or —C6H12—, and p represents an integer of from 1 to 10; and D(3) is a photopolymerization initiator, along with methods for temporarily fixing a member.
    Type: Grant
    Filed: July 7, 2011
    Date of Patent: October 14, 2014
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiro Oshima, Tomoyuki Kanai, Kunio Iriuchijima
  • Patent number: 8853318
    Abstract: The invention relates to radiation-curable aqueous composition comprising a high molecular weight ethylenically unsaturated polyurethane obtained from the reaction of a polyisocyanate, at least one hydrophilic compound which is capable to render the polyurethane prepolymer dispersible in aqueous medium, an ethylenically unsaturated compound containing at least two reactive groups capable to react with isocyanate groups and an active hydrogen containing chain extender and a low molecular weight ethylenically unsaturated polyurethane end-capped with an ethylenically unsaturated compound containing essentially one reactive group capable to react with isocyanate groups.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: October 7, 2014
    Assignee: Allnex Belgium S.A.
    Inventor: Michel Tielemans
  • Patent number: 8853295
    Abstract: The present invention relates to a process for the preparation of particularly reactive and low-viscosity reaction products of polyisocyanates which contain activated ethylenically unsaturated groups which react by polymerization under the action of actinic radiation, and the use of these reaction products in coating compositions, and particularly scratch-resistant coatings obtainable therefrom.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: October 7, 2014
    Assignee: ALLNEX IP S.a.r.L.
    Inventors: Michael Ludewig, Wolfgang Fischer, Helmut Kuczewski
  • Patent number: 8846777
    Abstract: A variety of biomedical devices are provided which include thiol-ene or thiol-yne shape memory polymers. The biomedical devices of the invention are capable of exhibiting shape memory behavior at physiological temperatures and may be used in surgical procedures. Methods of making the devices of the invention are also provided.
    Type: Grant
    Filed: April 22, 2009
    Date of Patent: September 30, 2014
    Assignee: The Regents of the University of Colorado, a Body Corporate
    Inventors: Christopher Bowman, Neil Cramer, Robin Shandas, Devatha P. Nair
  • Patent number: 8835522
    Abstract: The present invention provides a polymer having the structure of formula (I) wherein n, R1, R2, R3, R4, R5, R6, a, b and c are as defined in the specification. The present invention also provides a negative-acting photoimageable composition comprising the above-mentioned polymer of formula (I), which is suitable for the fabrication of printed circuit boards.
    Type: Grant
    Filed: March 26, 2007
    Date of Patent: September 16, 2014
    Assignee: Eternal Chemical Co., Ltd.
    Inventors: Gerng-Horng Lin, Hui-Kuan Mao, Ming-Hsiung Yang, Feng-Chih Tsai
  • Patent number: 8834670
    Abstract: An optical adhesive composition includes a urethane (meth)acrylate resin having at least one hydroxyl group and at least one vinyl group, the urethane (meth)acrylate resin having a curing contraction ratio expressed by Equation 1 of about 0 to about 3%; and an adhesion of about 30 to about 80 kgf: Curing contraction ratio (%)=(A?B)/A×100,??[Equation 1] where A is a specific gravity of the optical adhesive composition before curing, and B is a specific gravity of the solid optical adhesive composition after curing.
    Type: Grant
    Filed: October 14, 2011
    Date of Patent: September 16, 2014
    Assignee: Cheil Industries, Inc.
    Inventors: Kyoung Jin Ha, Ji Hye Kwon, Kil Sung Lee, Irina Nam, Lee June Kim
  • Patent number: 8822562
    Abstract: Ink deposited on a substrate by an ink-jet arrangement to form a protective layer includes hardenable oligomer, hardenable monomer selected from a group including alkoxylated and/or poly-alkoxylated acrylic monomers comprising one or more di- or tri-acrylates, and a photoinitiator. The oligomer has a room temperature viscosity greater than 1 Pa·s. The oligomer to monomer weight ratio is between 1/6 and 1/25. The ink has a room temperature viscosity between 15 and 22 mPa·s and between 5 and 2 mPa·s at 60° C., and a room temperature surface tension between 15 and 28 mN/m. The photoinitiator is activated by a UV source having an appropriate wavelength and intensity.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: September 2, 2014
    Assignee: M.G.I. USA, Inc.
    Inventor: Edmond Abergel
  • Patent number: 8796348
    Abstract: The invention provides an isocyanate free UV curable hot melt composition which may be hardened upon exposure to UV radiation to provide a protective coating. The coating is particularly useful in wood-working and furniture applications.
    Type: Grant
    Filed: September 26, 2007
    Date of Patent: August 5, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Andrew Trevithick Slark, Mireia Diaz Simo
  • Patent number: 8765833
    Abstract: A UV-curable optical resin adhesive composition is provided having excellent transparency, adhesion reliability, and durability without causing any adverse affect on image qualities such as luminance and contrast, and suitable for a reworking (repairing) process. The UV-curable optical resin adhesive composition fills a gap between an image display panel and a protective cover plate. The UV-curable optical resin adhesive composition contains, a urethane acrylate-based polymer (A) having a (meth) acryloyl group and a hydroxyl group on side chains thereof, and a photopolymerization initiator (B).
    Type: Grant
    Filed: January 27, 2012
    Date of Patent: July 1, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Kazumasa Igarashi, Yuki Hasegawa
  • Publication number: 20140167300
    Abstract: Photo-curable compositions for artificial teeth and denture base and a method for manufacturing denture by a three-dimensional printing system are provided. The compositions include photo-curable organic compounds, surface modified nano-sized inorganic filler, photo-initiator, colorant, and stabilizer. The composition is in a viscous liquid state having 1500-5000 cps at ambient temperature and has a low viscosity of 50-500 cps at jetting temperature or dispensing temperature. The composition also has an excellent curing rate for three-dimensional printing. Using the compositions, denture having a distinctive denture base and a set of artificial teeth can be manufactured via an inkjet type or digital light process type three-dimensional printing according to Computer Aided Design (CAD) data.
    Type: Application
    Filed: April 18, 2013
    Publication date: June 19, 2014
    Applicant: DENTCA, Inc.
    Inventor: Jae Sik LEE
  • Patent number: 8748506
    Abstract: Disclosed herein are ultraviolet (UV) curable coating compositions that provide transparent, flexible, and abrasion-resistant coatings when cured on a substrate. The coating compositions comprise an adduct of a multifunctional acrylate monomer component and an amino-organofunctional silane; an organic solvent component; an acid; a colloidal silica component; and a multifunctional urethane acrylate oligomer component. The amino-organofunctional silane is represented by the formula XaSi[Q1(NHQ2)bNZH]4-a, where X is an alkoxy group having from 1 to 6 carbon atoms; Q1 and Q2 are the same or different divalent hydrocarbon groups; Z is a hydrogen or a monovalent hydrocarbon group; a is an integer from 1 to 3; and b is an integer from 0 to 6. Also disclosed herein are processes for preparing such coating compositions and articles comprising coatings cured from such coating compositions.
    Type: Grant
    Filed: October 26, 2012
    Date of Patent: June 10, 2014
    Assignee: SDC Technologies, Inc.
    Inventor: Ren-Zhi Jin
  • Publication number: 20140151607
    Abstract: Compositions, methods and manufactures are disclosed for an ultraviolet-curable conductive ink and for a binding medium which may be utilized for both a dielectric ink and for a conductive ink. A representative ultraviolet-curable binding medium composition comprises: a difunctional aliphatic polycarbonate urethane acrylate oligomer; a monofunctional monomer such as an isophoryl acrylate monomer or an acrylate ester monomer; a difunctional monomer such as a difunctional alkoxylated acrylate or methacrylate monomer; a first photoinitiator such as an ?-hydroxyketone class photoinitiator; and a second photoiniator such as an ?-aminoketone class photoinitiator. A plurality of conductive particles, such as silver particles and graphene particles, may be included in the binding medium to provide an ultraviolet-curable conductive ink and, when cured, a conductive layer or wire, for example.
    Type: Application
    Filed: November 21, 2013
    Publication date: June 5, 2014
    Inventors: Mark David Lowenthal, Mark Lewandowski, Alexandra Elyse Hartman