With Ethylenic Reactant Patents (Class 522/96)
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Patent number: 7659324Abstract: Dental materials which contain a radically polymerizable organic binder, at least one radical polymerization initiator and at least one radical polymerization accelerator, both the initiator and the accelerator each having at least one radically polymerizable group.Type: GrantFiled: December 17, 2004Date of Patent: February 9, 2010Assignee: Ivoclar Vivadent AGInventors: Norbert Moszner, Urs Karl Fischer, Peter Burtscher, Jörg Angermann, Volker M. Rheinberger
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Patent number: 7655174Abstract: A fully curable jettable composition having a viscosity less than 30 cps at a temperature within the range of 15-180° C., more preferably at a temperature of 15-100° C., e.g. 60-80° C. the composition comprising: (A) at least one low viscosity reactive resin selected from the group consisting of compounds containing an oxetane ring, cycloaliphatic epoxy resins, tetrahydrofurans, hexahydropyrans and mono-functional (meth)acrylates, said resin having a molecular weight of not greater than 300 Daltons, e.g. 250 Daltons or less, and a viscosity at a temperature in the said range of less than 30 cps, e.g.Type: GrantFiled: May 23, 2003Date of Patent: February 2, 2010Assignee: Huntsman Advanced Materials Americas LLCInventors: Ranjana C Patel, Yong Zhao, Richard John Peace
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Publication number: 20100006217Abstract: The invention relates to a solvent-free, reactive composition comprising at least a photoinitiator and a polymer A, capable of reacting under UV-radiation using a photoinitiator and optionally further components, characterised in that the polymer A contains at least one in-chain olefinically unsaturated group and that the polymer A and/or a polymer B contains further a) at least two groups capable of reacting in the presence of moisture, and/or b) at least two olefinically unsaturated groups in terminal position, and/or c) at least one group capable of reacting in the presence of moisture and at least one olefinically unsaturated group in terminal position. The invention relates also to the process making the same, and its use as adhesive and/or as coating composition.Type: ApplicationFiled: June 8, 2009Publication date: January 14, 2010Inventors: Andrew Trevithick Slark, Mireia Diaz Simo, Renee Josie Gide Van Schijndel
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Patent number: 7645565Abstract: A polymerizable composition comprising: a polyurethane resin synthesized by using a compound represented by the following formula (I) as one of starting materials; a photopolymerization or thermal polymerization initiator; and an addition-polymerizable compound having an ethylenically unsaturated bond: wherein X represents a tri- or higher valent atom; R1 and R2 each independently represent a single bond or an alkylene group optionally having a substituent, provided that R1 and R2 do not represent a single bond at a same time; A represents a straight chain linking group; and n is an integer of from 1 to 5.Type: GrantFiled: October 8, 2008Date of Patent: January 12, 2010Assignee: FUJIFILM CorporationInventor: Atsushi Sugasaki
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Patent number: 7641966Abstract: A curable re-release adhesive which, when subjected to a curing reaction caused by irradiation with radiation, shows a sufficient drop of adhesion and causes the adherend to be warped to a minimized extent as developed by the shrinkage force caused by the curing reaction. The re-release adhesive contains a radiation-reactive polymer including a main chain and a plurality of intramolecular side chains, each such side chain having a terminal carbon-carbon double bond, a chain length of 6 or more in terms of number of atoms, and the same or a different number of atoms as each other side chain in the polymer. The release adhesive shows a shrinkage force of 30 MPa or less as developed by a curing reaction upon irradiation. A re-release adhesive sheet is also disclosed, including a substrate film and an adhesive layer containing the re-release adhesive, provided on one surface thereof.Type: GrantFiled: December 13, 2001Date of Patent: January 5, 2010Assignee: Nitto Denko CorporationInventors: Kouichi Hashimoto, Takahiro Fukuoka, Koji Akazawa, Yoshio Nakagawa, Tatsuya Kubozono
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Patent number: 7632874Abstract: A hardcoat agent composition comprising a fluorine-containing polyether compound (A) having a perfluoropolyether unit, urethane bond and active energy ray reactive group and a curable compound (B) having equal to or more than 2 active energy ray polymerizing groups in the molecule. An optical information medium having a film substance composed of single or multiple layers containing at least the recording layer 4 or the reflecting layer on the supporting substrate 20, the optical information medium wherein at least either the surface of the supporting substrate 20 or that of the above-mentioned film substance is formed by the hardcoat layer 8 containing a curable substance of the above-mentioned hardcoat agent composition.Type: GrantFiled: October 21, 2004Date of Patent: December 15, 2009Assignee: TDK CorporationInventors: Naoki Hayashida, Rie Ihara, Hidetake Itoh, Kazushi Tanaka
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Publication number: 20090296033Abstract: A thin display unit that incorporates a high-luminance, high-contrast display part that is free of image detects caused by the deformation of the display part is provided. The display unit of the present invention includes an image display part 2 and a light-transmitting protective part 3 arranged on the image display part 2. A cured resin layer 5 is arranged between the display part 2 and the protective part 3. The cured resin layer 5 has a transmittance of 90% or higher in the visible range and a storage modulus at 25° C. of 1×107 Pa or less. The cured resin layer 5 is formed from a resin composition that has a cure shrinkage of 5% or less.Type: ApplicationFiled: July 17, 2007Publication date: December 3, 2009Applicant: Sony Chemical & Information Device CorporationInventors: Yoshihisa Shinya, Yusuke Kamata
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Patent number: 7615110Abstract: An intaglio printing ink, curing by free radical acrylate chemistry, which does not fluoresce in at least the visible region under ultraviolet light is prepared by using an acylphosphine oxide as the photoinitiator.Type: GrantFiled: March 30, 2005Date of Patent: November 10, 2009Assignee: Sun Chemical CorporationInventors: Michael W. Leonard, John A. Dyer, James R. Tucker, Shaun L. Herlihy
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Patent number: 7612122Abstract: Compounds of formula (I): [where: the substituents R1 are individually selected from C1-C10 alkyl groups and optionally substituted benzyl groups; the substituents R2 are individually selected from alkyl groups or, together with the nitrogen atom to which they are attached, represent a nitrogen-containing heterocyclic group; Z is selected from C6-C10 arylene groups and groups of formula —(CHR3)n—, where R3 is hydrogen, hydroxy or a C1-C4 alkyl group, and n is 0 to 6; Y is carbonyl or —CH2—; Q is a residue of a mono- or poly-hydroxy compound; and x is 1 to 6; and esters thereof] are useful as multi-functional photoinitiators for use in coating compositions to be cured by radiant energy.Type: GrantFiled: November 9, 2005Date of Patent: November 3, 2009Assignee: Sun Chemical CorporationInventors: Shaun Lawrence Herlihy, Brian Rowatt, Robert Stephen Davidson
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Publication number: 20090258961Abstract: Stable, highly filled cationic dental compositions useful for the production of dental prostheses and dental restoration materials contain: (1) at least one compound which is reactive cationically when activated, advantageously at least one UV-and cationically reactive oxirane-functionalized silicone; (2) at least one dental filler, advantageously SiO2; (3) at least one organic polymer or copolymer dispersant having an amine index less than or equal to 100 mg of potassium hydroxide per gram of dispersant, advantageously a polyurethane/acrylate copolymer or alkylammonium salt thereof; (4) at least one cationic photoinitiator, advantageously iodonium borate; and (5) optionally, at least one photosensitizer.Type: ApplicationFiled: March 9, 2009Publication date: October 15, 2009Inventor: Jean-Marc FRANCES
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Patent number: 7595352Abstract: A photo-curable adhesive composition includes oligourethane acrylate in a range of about 11 to about 23% by weight, reactive monomer-diluent in a range of about 11 to about 24% by weight, silicate filler in a range of about 50 to about 65% by weight, photoinitiator in a range of about 2.5 to about 5.0% by weight, organic peroxide in a range of about 0.1 to about 0.5% by weight, thixotropic agent in a range of about 0.5 to about 3.5% by weight, antioxidant in a range of about 0.005 to about 0.02% by weight, silane finishing agent in a range of about 0.1 to about 2.5% by weight, and oxalic acid in a range of about 0.5 to about 1.5% by weight, based on the total weight of the composition.Type: GrantFiled: May 24, 2006Date of Patent: September 29, 2009Assignee: Samsung Electronics Co., Ltd.Inventors: Young-se Choi, Hyung-tae Kim, Do-hoan Nam, Soo-han Park, Dovid Azrielevich Aronovich, Valentin Vasilievich Guzeev, Vladimir Borisovich Mozzhukhin, Alexandr Petrovich Sineokov, Natalya Alexandrovna Ustyuzhantseva, Zyakia Saibasakhovna Khamidulova
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Patent number: 7579066Abstract: There are provided a novel ethylenically unsaturated group-containing isocyanate compound, a process for producing the same, and a reactive monomer produced from the isocyanate compound, a reactive polymer and its use. The ethylenically unsaturated group-containing isocyanate compound according to the present invention is represented by formula (I).Type: GrantFiled: October 31, 2005Date of Patent: August 25, 2009Assignee: Showa Denko K.K.Inventors: Kaneo Nozawa, Katsutoshi Morinaka, Toru Sasaki, Katsumi Murofushi
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Patent number: 7576143Abstract: A polyurethane acrylate (A), comprises, as synthesis components, (a) at least one polyisocyanate which comprises isocyanurate groups, based on 1-isocyanato-3,3,5-trimethyl-5-(isocyanatomethyl)cyclohexane, (b) at least one polyisocyanate which comprises isocyanurate groups, based on hexamethylene diisocyanate, (c) at least one aliphatic and/or cycloaliphatic diisocyanate, (d1) at least one polyetherdiol or polyesterdiol having a molecular weight ranging from 500 to 2000, (d2) optionally, at least one diol having a molecular weight of less than 220 g/mol, (e) at least one compound having at least one group reactive toward isocyanate and at least one unsaturated group capable of free radical polymerization, and (f) optionally, at least one compound having exactly one group reactive toward isocyanate.Type: GrantFiled: March 8, 2006Date of Patent: August 18, 2009Assignee: BASF AktiengesellschaftInventors: Reinhold Schwalm, Erich Beck, Klaus Menzel
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Patent number: 7576138Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 100 nm and about 200 nm.Type: GrantFiled: August 23, 2006Date of Patent: August 18, 2009Assignee: The Procter & Gamble CompanyInventors: Andreas Flohr, Torsten Lindner, Esther Oliveros, Yoshiro Mitsukami
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Patent number: 7569335Abstract: There is provided a photosensitive resin composition for forming an optical waveguide which has high shape precision and excellent transmission characteristics under high temperature and high humidity. A composition of the present invention contains (A) a polymer having structures represented by the following general formulae (I) and (2) (in the formulae, each of R1 and R2 is independently a hydrogen atom or an alkyl group having 1 to 12 carbon atoms; R3 is an organic group containing a radical-polymerizable reactive group; X is a single bond or a bivalent organic group; and Y is a non-polymerizable organic group), (B) a compound having at least one ethylenic unsaturated group in the molecule thereof, having a molecular weight below 1,000 and having a boiling point of at least 130° C. at 0.1 MPa, and (C) a photoradical polymerization initiator.Type: GrantFiled: February 19, 2008Date of Patent: August 4, 2009Assignee: JSR CorporationInventors: Yukio Maeda, Yuuichi Eriyama
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Patent number: 7569618Abstract: A method of surface cross-linking superabsorbent polymer particles using UV irradiation is provided. The method is carried out in a so-called drum reactor, which comprises a hollow drum and an irradiation source. The drum has a longitudinal axis and a cross-section. Radical former molecules are applied on the surface of superabsorbent polymer particles. These superabsorbent polymer particles are fed into the drum and are irradiated while they move within the drum, which is rotated around its longitudinal axis. The irradiation source is provided such that the radiation emitted by the irradiation source is able to reach superabsorbent polymer particles within said drum. The irradiation source for use in the method is able to emit UV radiation of a wavelength between about 201 nm and about 400 nm.Type: GrantFiled: August 23, 2006Date of Patent: August 4, 2009Assignee: The Procter & Gamble CompanyInventors: Andreas Flohr, Torsten Lindner, Esther Oliveros, Yoshiro Mitsukami
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Patent number: 7556844Abstract: An ink that may be used in ink jet devices is a photochromic ink comprising an ink vehicle that includes at least one radiation curable component, at least one photochromic material and at least one photoinitiator. The ink is cured via exposure to radiation that cures the at least one radiation curable component of the ink. A radiation curable ink capable of exhibiting photochromatic color changes, which may be used to indicate a document's authenticity, is thus achieved.Type: GrantFiled: March 9, 2006Date of Patent: July 7, 2009Assignee: Xerox CorporationInventors: Gabriel Iftime, Christopher A Wagner, Eniko Toma, Jennifer L Belelie, Peter G Odell
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Publication number: 20090169872Abstract: Radiation curable coatings and methods of utilizing the coatings are provided. In a general embodiment, the present disclosure provides a coating composition containing about 15% to about 80% by weight of one or more radiation curable compounds such as polycarbonate acrylate oligomers, polyurethane acrylate oligomer, polyester acrylate oligomers, silicone-based acrylate oligomers, or a combination thereof, and about 10% to about 80% by weight of one or more acrylate monomers.Type: ApplicationFiled: December 22, 2008Publication date: July 2, 2009Applicants: BAXTER INTERNATIONAL INC., BAXTER HEALTHCARE S.A.Inventors: Vadim V. Krongauz, Michael T. K. Ling, Lecon Woo
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Patent number: 7553906Abstract: An organic polyisocyanate with at least one unsaturated functional group is capable of copolymerizing when exposed to actinic radiation. The polyisocyanate comprises structural units with the formula (1): wherein: X is an electron-attracting group; R1, and R2 are hydrogen atoms, a saturated or unsaturated aliphatic or cycloaliphatic radical, or an aromatic or araliphatic radical; and n is an integer from 0 to 5. A process for producing this polyisocyanate is also disclosed.Type: GrantFiled: December 17, 2003Date of Patent: June 30, 2009Assignee: Bayer MaterialScience AGInventors: Jan Weikard, Christoph Gürtler, Wolfgang Fischer, Diethelm Rappen, Michael Schelhaas
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Patent number: 7544381Abstract: An ultraviolet curable lubricious coating including at least one lubricious polymer and at least one oxygen-insensitive crosslinkable polymer, methods of making and using the same, and articles coated therewith.Type: GrantFiled: September 9, 2003Date of Patent: June 9, 2009Assignee: Boston Scientific Scimed, Inc.Inventor: Steve Kangas
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Publication number: 20090135238Abstract: An ultraviolet ray curable ink-jet ink comprising at least a mono-functional monomer, a bi-functional monomer, and a photo-polymerization initiator, wherein an amount of the mono-functional monomer is at least 35 weight % based on the total weight of the ink-jet ink, and an amount of the photo-polymerization initiator is at least 20 weight % based on the total weight of the mono-functional monomer.Type: ApplicationFiled: May 24, 2006Publication date: May 28, 2009Applicant: Konica Minolta Medical & Graphic, Inc.Inventor: Atsushi Nakajima
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Patent number: 7538145Abstract: The phase change, curable composition comprises curable monomer, photoinitiator that initiates polymerization of the curable monomer, and phase change agent that provides the composition with an increase in viscosity of at least four orders of magnitude, from a first temperature, the first temperature being from 50° C. to 130° C., to a second temperature, the second temperature being from 0° C. to 70° C., wherein the second temperature is at least 10° C. below the first temperature. A coating over an image may be applied by providing a composition comprising curable monomer at a first temperature; applying the composition over the image, the image being at a second temperature; and exposing the composition to radiation to initiate polymerization of the curable monomer. In this process, the composition has a viscosity at the second temperature that is at least four orders of magnitude greater than its viscosity at the first temperature.Type: GrantFiled: November 30, 2005Date of Patent: May 26, 2009Assignee: Xerox CorporationInventors: Jennifer L. Belelie, Peter G. Odell, Darly Vanbesien, Marcel P. Breton
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Patent number: 7532795Abstract: The invention relates to a radiation-curable liquid resin composition comprising: (A) 20-90 wt % of a urethane(meth)acrylate oligomer, and (B) 1-35 wt % of a monomer shown by the following formula (1), wherein R1 represents a hydrogen atom or a methyl group, R2 and R3 individually represent a hydrogen atom or an alkyl group having 1-4 carbon atoms, R4 represents a hydrogen atom or a methyl group, and n represents an integer of 1-6, or a monomer including a hydroxyl group.Type: GrantFiled: August 20, 2004Date of Patent: May 12, 2009Assignees: DSM IP Assets B.V., JSR CorporationInventors: Atsuya Takahashi, Takeo Shigemoto, Zen Komiya, Hiroki Ohara
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Patent number: 7531580Abstract: (A) a polycarbonatediol, (B) a trifunctional alcohol, and (C) a diisocyanate are subjected to reaction in the presence of (D) a (meth)acrylate compound represented by the general formula CH2?CRCO(OCnH2n)pR? or CH2?CRCO(OCmH2m)qOCOCH?CH2, and (E) a di(meth)acrylate compound of alkylene glycol whose alkylene group is substituted as a lower alkyl group, and then (F) a hydroxyl group-containing (meth)acrylate is added to the resulting solution of urethane oligomers in (meth)acrylate to conduct terminal (meth)acrylating reaction of the urethane oligomers, thereby producing a UV-curable liquid polyurethane resin having a viscosity (25° C.) of preferably 150,000-1,000,000 mPa·s, where before or after the terminal (meth)acrylating reaction of the urethane oligomers (G) a photopolymerization initiator and (H) a hindered phenol-based antioxidant having a molecular weight of 500-2,000 are added thereto to form the UV-curable liquid polyurethane resin.Type: GrantFiled: April 7, 2004Date of Patent: May 12, 2009Assignee: Unimatec Co., Ltd.Inventors: Tetsuya Watanabe, Takashi Chiba, Shuzo Yamada
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Publication number: 20090111904Abstract: Disclosed is an active energy ray-curable coating composition containing (A) 10 to 70% by mass of a poly(meth)acrylate of a mono- or polypentaerythritol; (B) 5 to 50% by mass of (B-1) a polyester type aliphatic urethanedi(meth)acrylate compound which is obtained by reacting an aliphatic isocyanate compound, a caprolactone-modified polyester diol, and an acrylate having a hydroxyl group, (B-2) a compound represented by formula (2), or (B-3) a polyether type urethane di(meth)acrylate compound having two (meth)acryloyloxy groups in a molecule, wherein, in the case that component (B) is component (B-3), component (A) contains at least one caprolactone-modified (meth)acryloyloxy group; (C) 5 to 70% by mass of a poly[(meth)acryloyloxyalkyl](iso)cyanurate represented by formula (3) or (4); and (D) 0.1 to 10% by mass of a photopolymerization initiator. The active energy ray-curable coating composition can form a cured film excellent in weatherability, mar resistance, and adhesion to a base material.Type: ApplicationFiled: April 9, 2007Publication date: April 30, 2009Applicant: Mitsubishi Rayon Co., Ltd.Inventors: Kazuyoshi Odaka, Koji Furukawa, Hiroyuki Satou
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Patent number: 7524890Abstract: The present invention is directed to a photocurable and antistatic resin composition for coating an optical fiber, comprising (A) a photopolymerizable urethane acrylate oligomer, (B) a reactive monomer having at least one (meth)acrylate or vinyl group, (C) a photoinitiator, and (D) an antistatic agent compatible with the oligomer and monomer components, and optionally (E) a pigment or dye. The coating of the inventive composition can increase the productivity of the optical fiber, and provide an optical fiber having a uniform coating layer.Type: GrantFiled: August 13, 2004Date of Patent: April 28, 2009Assignee: Luvantix Co., LtdInventors: Dae Sung Lee, Kyoung Beom Min, Jae Myoung Ryu, Hae Woog Choi, Yong Min Kim
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Patent number: 7521015Abstract: Curable thiol-ene compositions containing urethane (meth)acrylate oligomers that are readily polymerized to produce optical articles and coatings are described.Type: GrantFiled: July 22, 2005Date of Patent: April 21, 2009Assignee: 3M Innovative Properties CompanyInventors: Ming Cheng, Peter M. Olofson, Michele A. Craton, Ying-Yuh Lu
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Patent number: 7514477Abstract: A biocompatible, low-viscosity, radiation-curable composition for producing antimicrobial earpieces contains: a) 20-75 wt. % of one or a plurality of monomeric/oligomeric urethane(meth)acrylates having an acrylate functionality of <4, viscosity <30 Pa s, and molecular weight <3500; b) 5-45 weight % of a monomeric or oligomeric dimethacrylate of bisphenol A or bisphenol F and or of a monomeric aliphatic or cycloaliphatic di(meth)acrylate having a viscosity <6 Pa s; c) 2.5-25 weight % of a cross-linking monomeric or oligomeric component containing 4 methacrylate and/or acrylate functionalities; d) 0-15 wt. % of one or a plurality of monofunctional (meth)acrylates; e) 0.01-5 wt. % of one or a combination of antimicrobially active glass fillers and silver particles; and f) 0.5-6 wt. % of one or a plurality of photoinitiators whose absorption is in the wavelength range of an ND:YVO4 laser beam used or of an actinic radiation source used to promote free radical formation.Type: GrantFiled: October 12, 2006Date of Patent: April 7, 2009Assignee: Derve-Otoplastik GmbHInventors: Martin Klare, Reiner Altmann, Michael Kutschinski, Thomas Veit
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Patent number: 7514478Abstract: Powder coating binders having a glass temperature of ?35° C. containing at least one polymer and one or more radiation-curing reactive thinners, a process for the production of these powder coating binders and their use as a component of powder coatings.Type: GrantFiled: November 22, 2004Date of Patent: April 7, 2009Assignee: Bayer MaterialScience AGInventors: Thomas Fäcke, Jan Weikard, Peter Thometzek
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Patent number: 7498362Abstract: Disclosed are environmentally friendly, substantially all solids coating compositions which are curable using ultraviolet and visible radiation. In certain embodiments, the disclosed coating compositions are suitable for coating flexible objects and/or objects having angular features, such as, but not limited to, flexible metal objects with angular features. In other embodiments, the cured coatings have improved slip properties and at least 6 H hardness. Such embodiments can served as substitutes for “hard chrome” coatings, TEFLON® coatings, coatings comprising TEFLON®, or TEFLON® like coatings. In addition, methods are disclosed for coating surfaces, or at least a portion of the surfaces, and curing of the coated surface to obtain partially or fully cured coated surfaces. Furthermore, articles of manufacture incorporating fully cured coated surfaces are disclosed, including, for example leaf springs, hydraulic rods and cylinders.Type: GrantFiled: October 24, 2005Date of Patent: March 3, 2009Assignee: Ecology Coatings, Inc.Inventor: Sally Judith Weine Ramsey
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Publication number: 20090053653Abstract: A polymerizable composition comprising: a polyurethane resin synthesized by using a compound represented by the following formula (I) as one of starting materials; a photopolymerization or thermal polymerization initiator; and an addition-polymerizable compound having an ethylenically unsaturated bond: wherein X represents a tri- or higher valent atom; R1 and R2 each independently represent a single bond or an alkylene group optionally having a substituent, provided that R1 and R2 do not represent a single bond at a same time; A represents a straight chain linking group; and n is an integer of from 1 to 5.Type: ApplicationFiled: October 8, 2008Publication date: February 26, 2009Applicant: FUJIFILM CorporationInventor: Atsushi Sugasaki
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Patent number: 7495034Abstract: A curable composition and method for producing a tear resistant, yet soft and deformable in-the-ear product yielding the user greater comfort and durability. The curable composition incorporated into a hearing aid apparatus provides a deformable, yet tear resistant housing, which may be mated to a soft tip component. The hearing aid housing provides better comfort, durability and acoustic performance for a variety of ear canal shapes. The curable composition that provides these properties includes at least one urethane acrylate oligomer, at least one reactive diluent and a cure system. The composition when cured desirably produces a tear strength of at least about 75 pli and a hardness of about Shore A 60 to about 75.Type: GrantFiled: August 20, 2004Date of Patent: February 24, 2009Assignee: Henkel CorporationInventors: Alan Edward Litke, JoAnn DeMarco, Victor Karol Kadziela
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Publication number: 20090030104Abstract: An active energy ray curable resin composition for a sheet-like optical article capable of providing a cured material having a dynamic elastic modulus at 25° C. of 950 MPa or less and a dynamic elastic modulus at 60° C. of 100 MPa or more and a sheet-like optical article prepared from the resin composition are disclosed. The sheet-like optical article (e.g., prism sheet) has good heat resistance and extremely small warpage.Type: ApplicationFiled: October 12, 2005Publication date: January 29, 2009Inventors: Shinji Makino, Tsuyoshi Nakagawa, Koichiro Sanefuji
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Patent number: 7479510Abstract: Compositions suitable for support in building a three-dimensional object are described. The compositions may include a non-curable component and a curable component not reactive with the non-curable component. The composition may further include a surface-active agent and a stabilizer, wherein the composition has a first viscosity of about 20-500 cps at ambient temperature, and a viscosity lower than 20 cps at a temperature higher than the ambient temperature. After irradiation, the composition results in a solid, a semi-solid or liquid material.Type: GrantFiled: September 11, 2006Date of Patent: January 20, 2009Assignee: Objet Geometries Ltd.Inventors: Eduardo Napadensky, Avi Levy
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Publication number: 20090018231Abstract: Mixtures comprising at least one radiation-curable composition (I) and at least one pressure-sensitive adhesive (II).Type: ApplicationFiled: September 25, 2008Publication date: January 15, 2009Applicant: BASF AktiengesellschaftInventors: Ralf Fink, Wolfgang Paulus
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Publication number: 20090012198Abstract: An ultraviolet ray curing type resin composition comprising (A) an urethane acrylate produced from, as essential ingredients, an isocyanate compound comprising an aliphatic isocyanate compound and an alicyclic isocyanate compound at a molar ratio of from 80/20 to 20/80; a polyol compound comprising an ester-based polyol, an ether-based polyol or a polycarbonate-based polyol; and an acrylate compound having a hydroxyl group, (B) an acrylate-based reactive diluent, and (C) a photo-reactive initiator. The coated film obtained by coating the composition to a substrate, followed by photocuring has a following capability in molding owing to its excellent elongation, and only-causes a low level of yellowing upon long time heating to show an excellent thermal resistance. The cured product has a decreased residual odor and, therefore, useful in improving designing property and beauty in using for an automobile interior or the like.Type: ApplicationFiled: November 5, 2003Publication date: January 8, 2009Applicant: HONDA MOTOR CO LTD.Inventors: Makoto Araumi, Norio Suzuki, Naoto Ishii
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Publication number: 20080311483Abstract: The present invention provides polyurethane systems which cure by radiation and thermal action with crosslinking, and use thereof for the production of holographic media. The polyurethane compositions of the invention comprise A) polyisocyanates, B) polyols, comprising at least one poly(?-caprolactone)polyester polyol, C) compounds having groups which react on exposure to actinic radiation with ethylenically unsaturated compounds with polymerization (radiation-curing groups), D) optionally free radical stabilizers and E) photoinitiators.Type: ApplicationFiled: April 10, 2008Publication date: December 18, 2008Applicant: Bayer MaterialScience AGInventors: Nicolas Stockel, Friedrich-Karl Bruder, Meike Niesten, Harald Blum, Stephanie Strazisar
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Patent number: 7462652Abstract: A water based coating mixture for the application of a polymeric coating to a substrate mixture includes water and optionally an organic solvent, at least one free-radically polyerizable compound. Preferably the coating is weldable.Type: GrantFiled: November 4, 2005Date of Patent: December 9, 2008Assignee: Chemetall GmbHInventor: Georg Gros
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Patent number: 7462651Abstract: A radiation-curable desiccant-filled adhesive/sealant composition comprising a radiation-curable resin, one or more desiccant fillers, one or more photoinitiators or photosensitizers, and optionally, one or more inorganic or organic fillers.Type: GrantFiled: March 30, 2006Date of Patent: December 9, 2008Assignee: National Starch and Chemical Investment Holding CorporationInventors: Jie Cao, Donald E. Herr
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Publication number: 20080287564Abstract: The invention relates to a biocompatible, low-viscosity, radiation-curable formulation for producing medical products, in particular adaptive ear pieces, otoplastic parts, shells or ear parts, by means of PNP methods or stereolithographic methods. Said formulation comprises: a) 15-60 wt. % of a monomeric or oligomeric dimethacrylate based on bisphenol A or bisphenol F; b) 0-50 wt. % one or more monomeric or oligomeric urethane (meth)acrylates with a functionality n<4, a viscosity <30 Pa s and a molecular weight <3500; c) 2-25 wt. % of a monomeric, aliphatic or cycloaliphatic dimethacrylate with a viscosity <3 Pa s; d) 2-35 wt. % of an iminooxadiazone dion derivative, characterised by 3 methacrylate and/or acrylate functions; 0-15 wt. % one or more monofunctional methacrylates; f) 0.5-6 wt. % of a photo initiator or a combination of photo initiators, whose absorption lies in the wavelength range of the laser beam that is used or the irradiation source; g) 0-0.5 wt.Type: ApplicationFiled: October 13, 2005Publication date: November 20, 2008Applicant: DREVE OTOPLASTIK GMBHInventors: Martin Klare, Reiner Altman, Michael Kutschinski, Thomas Veit
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Patent number: 7452923Abstract: The present invention discloses an anisotropic conductive adhesive comprising an insulating adhesive component and a number of conductive particles dispersed in the insulating adhesive component, wherein the insulating adhesive component contains a crosslinked rubber resin. The anisotropic conductive adhesive of the present invention prevents exfoliation of an adhesive or reduction in adhesive strength of circuit by minimizing its the heat-contraction occurring in the process of a polymerization or a hardening reaction when connecting micro-circuits, whereby a short circuit between adjacent electrodes can be prevented when connecting the circuits, and excellent connection reliability according to a long-term use is achieved.Type: GrantFiled: October 5, 2004Date of Patent: November 18, 2008Assignee: LG Cable Ltd.Inventors: Young Mi Jeon, Yoon Jae Chung, Jong Yoon Jang, Woo Young Ahn, Yong Seok Han
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Patent number: 7446133Abstract: Anti-glare film including anti-glare layer. The anti-glare film is obtained by coating or casting a liquid composition containing a polymer, a curable resin precursor, and a solvent on a transparent plastic film, evaporating the solvent, forming a phase separation structure by spinodal decomposition, and curing the curable resin precursor by irradiation with light. The disclosed anti-glare film prevents reflection of surrounding scenery and dazzle in a display surface.Type: GrantFiled: July 2, 2007Date of Patent: November 4, 2008Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroshi Takahashi, Hiroaki Ushida
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Patent number: 7439279Abstract: To provide a coating composition which forms a coating film having excellent fingerprint removability and having favorable abrasion resistance and transparency, and a molded product having a coating film made of a cured product of the composition. An active energy ray curable coating composition comprising an active energy ray curable polymerizable monomer (A), a water and oil repellency-imparting agent (B) and an active energy ray polymerization initiator (C), wherein the water and oil repellency-imparting agent (B) contains a water and oil repellency-imparting agent (B-T) having a moiety (b-1) exerting water and oil repellency, an active energy ray curable functional group (b-2) and a moiety (b-3) excellent in compatibility with the polymerizable monomer (A) and a molded product having a coating film made of a cured product of the composition.Type: GrantFiled: May 13, 2005Date of Patent: October 21, 2008Assignee: Asahi Glass Company, LimitedInventors: Satoshi Kondo, Daisuke Shirakawa, Toshihiko Higuchi, Hirotsugu Yamamoto
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Publication number: 20080255264Abstract: A high-solid UV-curable coating composition of the present invention, comprising a low viscosity multifunctional urethane acrylate oligomer, a UV-curable monomer, 10% by weight or less of an organic solvent and a photoinitiator has good workability and environmental characteristics and provides a coating film having improved properties including thermal shock resistance.Type: ApplicationFiled: February 7, 2006Publication date: October 16, 2008Applicant: SSCP CO., LTDInventors: Su Dong Hong, Dong Soo Kim, Tae Yun Jeong, Sang Hwan Kim, Jung Hyun Oh
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Patent number: 7436115Abstract: The present invention discloses a method for fabricating an electroluminescent lamp that includes a step in which an electroluminescent active layer is formed by curing a UV curable electroluminescent composition. Embodiments of the method of the present invention in which each layer of a multilayer electroluminescent device are fabricated from UV curable compositions are also disclosed. A UV curable dielectric composition suitable for utilization in an electroluminescent lamp is also provided.Type: GrantFiled: March 1, 2005Date of Patent: October 14, 2008Inventors: Roy C. Krohn, Scott E. Howe, Christopher C. Ryan
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Publication number: 20080242757Abstract: The present invention is directed to a composition curable by radiation having a wavelength of 300 nm or more, a method of producing a coated substrate using such composition and the coated product so-produced.Type: ApplicationFiled: May 9, 2008Publication date: October 2, 2008Inventors: Michael J. Dvorchak, Larry Galeza, Robert A. Wade, Clifford M. Bridges, Ramesh Subramanian
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Publication number: 20080233397Abstract: A Radiation Curable Secondary Coating comprising A) a Secondary Coating Oligomer Blend, which is mixed with B) a first diluent; C) a second diluent; D) an antioxidant; E) a first photoinitiator; F) a second photoinitiator; and G) optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: ?) an Alpha Oligomer, which is non-urethane; ?) a Beta Oligomer; which is a urethane or non-urethane. ?) a Gamma Oligomer; wherein said Gamma Oligomer is an epoxy diacrylate.Type: ApplicationFiled: December 13, 2007Publication date: September 25, 2008Inventors: Wendell Wayne Cattron, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
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Publication number: 20080234403Abstract: The present invention relates to a radiation curable and developable polyurethane which is characterized by having a carboxy group in its main chain and a acryloyl group in its side chain and comprising the following repeat units (I), (II), and (II) in a random arrangement: wherein R1, R2, R3, R4, and T are defined in the specification. The polyurethane has a weight molecular weight measured by GPC in a range of from 3,000 to 400,000; an acid value in a range of from 5 to 120 mgKOH/g. The present invention also relates to a radiation curable and developable composition containing the polyurethane.Type: ApplicationFiled: March 20, 2008Publication date: September 25, 2008Inventors: Wei Hsiang Huang, Ying Jen Chen, Jui Ming Chang, Chun Hung Kuo, Hong Ye Lin, Li Chung Chang
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Publication number: 20080226914Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes for coating optical fibers.Type: ApplicationFiled: December 13, 2007Publication date: September 18, 2008Inventors: Tyson Dean Norlin, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello
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Publication number: 20080226916Abstract: Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and methods for the preparation of coated optical fibers. The radiation curable coating comprises at least one (meth)acrylate functional oligomer and a photoinitiator, wherein the urethane-(meth)acrylate oligomer CA/CR comprises (meth)acrylate groups, at least one polyol backbone and urethane groups, wherein about 15% or more of the urethane groups are derived from one or both of 2,4- and 2,6-toluene diisocyanate, wherein at least 15% of the urethane groups are derived from a cyclic or branched aliphatic isocyanate, and wherein said (meth)acrylate functional oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/mol; and wherein a cured film of the radiation curable Primary Coating composition has a modulus of less than or equal to about 1.2 MPa.Type: ApplicationFiled: December 13, 2007Publication date: September 18, 2008Inventors: Paulus Antonius Maria STEEMAN, Xiansong Wu, Steven R. Schmid, Edward J. Murphy, John M. Zimmerman, Anthony Joseph Tortorello