Composition Devoid Of Asbestos Patents (Class 523/155)
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Publication number: 20130096228Abstract: In accordance with the present invention, there is provided a friction material. The friction material of the present invention includes a fibrous material, a binder, and a friction modifier. The friction modifier contains an artificial graphite and an inorganic filler. The artificial graphite has an average particle diameter of 1,000 to 3,000 ?m. The inorganic filler has a plurality of convex parts.Type: ApplicationFiled: June 16, 2011Publication date: April 18, 2013Applicant: AKEBONO BRAKE INDUSTRY CO., LTD.Inventors: Hiroshi Yamamoto, Rie Sugie, Masayo Shitara, Akihiro Hikichi
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Publication number: 20130090409Abstract: The present invention provides a rubber composition that achieves a well-balanced improvement in fuel economy, wet-grip performance, and abrasion resistance, and a pneumatic tire formed from the rubber composition. The present invention relates to a rubber composition, including a rubber component and silica, wherein the rubber component contains not less than 5% by mass of a conjugated diene polymer, based on 100% by mass of the rubber component, the conjugated diene polymer containing a constituent unit derived from a conjugated diene and a constituent unit represented by the following formula (I): at least one terminal of the conjugated diene polymer being modified by a compound containing a group represented by the following formula (II): and wherein the silica is contained in an amount of 5 to 150 parts by mass per 100 parts by mass of the rubber component.Type: ApplicationFiled: July 22, 2011Publication date: April 11, 2013Applicant: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Yuko Hinohara, Kazuyuki Nishioka, Takahiro Mabuchi
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Publication number: 20130030083Abstract: The present invention provides a rubber composition for a tread which enables improvement in fuel economy, breaking performance, and abrasion resistance in a balanced manner; a method for producing the rubber composition; and a heavy-load tire. The present invention relates to a rubber composition for a tread of a heavy-load tire, including a modified natural rubber having a phosphorus content of 200 ppm or less, and carbon black.Type: ApplicationFiled: July 27, 2012Publication date: January 31, 2013Inventors: Takafumi TAGUCHI, Naoya Ichikawa
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Publication number: 20120283354Abstract: The present invention provides a tire rubber composition which has good silica dispersibility and improves in terms of the reinforcement, the abrasion resistance, the mechanical strength, the rolling resistance, the wet grip performance, and the handling stability on a dry road surface in a balanced manner; and provides a pneumatic tire produced using the tire rubber composition. The present invention relates to a tire rubber composition, comprising: a rubber component; a first silica; and a second silica, wherein the first silica has a CTAB specific surface area of 180 m2/g or more, a BET specific surface area of 185 m2/g or more, and an aggregate size of 45 nm or more, and the second silica has a CTAB specific surface area of 95 m2/g or less, and a BET specific surface area of 100 m2/g or less.Type: ApplicationFiled: January 12, 2011Publication date: November 8, 2012Inventors: Takayuki Hattori, Ai Matsuura, Yoji Imoto, Michio Hirayama, Kenichi Uesaka
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Publication number: 20120264849Abstract: The invention relates to a method for preparing a silica/diene elastomer masterbatch, comprising the following successive steps: doping the silica with an at least divalent metallic element; preparing at least one dispersion of the resulting doped silica in water; bringing a diene elastomer latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.Type: ApplicationFiled: October 25, 2010Publication date: October 18, 2012Applicants: Michelin Recherche et Technique S. A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Julien Berriot, Benoît De Gaudemaris, Géraldine Laffargue
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Publication number: 20120259036Abstract: To provide a highly heat-resistant brake pad adaptable to high temperatures/high loads and producible only by adding a baking step to the same production process as that for an organic friction material. A friction material comprising a fibrous material, a friction modifier, a binder and an inorganic material, wherein a silicon-containing polymer is blended as a binder and after thermoforming, the polymer is heat-treated in an oxidizing atmosphere at a temperature of 160 to 350° C. for 1 to 10 hours to cause crosslinking with oxygen and then, subjected to a baking treatment. As the silicon-containing polymer, one compound or two or more compounds are preferably selected from the group consisting of polycarbosilane, polyorganoborosilazane, polyborosiloxane, polycarbosilazane, and perhydropolysilazane.Type: ApplicationFiled: December 22, 2010Publication date: October 11, 2012Applicant: AKEBONO BRAKE INDUSTRY CO., LTD.Inventors: Yuki Takahashi, Shou Kurihara
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Publication number: 20120259035Abstract: The invention relates to a method for preparing a silica/synthetic diene elastomer masterbatch, comprising the following successive steps: doping the silica with an at least divalent metallic element; preparing at least one dispersion of the resulting doped silica in water; bringing a synthetic diene elastomer latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.Type: ApplicationFiled: October 25, 2010Publication date: October 11, 2012Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Julien Berriot, Benoît De Gaudemaris, Géraldine Laffargue
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Publication number: 20120252928Abstract: The present invention relates to a specific functionalized diene elastomer. This functionalized elastomer exhibits a reduced cold flow without, however, damaging the properties of a reinforced rubber composition in which it is present, in particular the processing properties and the hysteresis properties. This functionalized diene elastomer carries, at the chain end, a silanol functional group or a polysiloxane block having a silanol end and is partially coupled by or star-branched by tin.Type: ApplicationFiled: October 7, 2010Publication date: October 4, 2012Applicants: MICHELIN RECHERCHE ET TECHNIQUE, SOCIETE DE TECHNOLOGIE MICHELINInventors: Jean-Marc Marechal, Stéphanie De Landtsheer, Jean-Michel Favrot
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Patent number: 8278370Abstract: A friction lining made of a fibrous mixture with fillers and resin for a wet clutch. In order to design the friction lining able to withstand the higher torque to be transmitted, it is proposed to admix further filler with a Mohs hardness greater or equal to 9.0 and smaller or equal to 9.5 in addition to the ingredients of aramid fibers, cellulose fibers, phenol resin and amorphous silicon dioxide and first filler.Type: GrantFiled: March 1, 2010Date of Patent: October 2, 2012Assignee: Schaeffler Technologies AG & Co. KGInventors: Firoz Jafri, Martin Fuss, Michael Wilfong
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Patent number: 8273804Abstract: An object of the present invention is to provide a rubber composition for a tire, which can achieve well-balanced improvement in fuel economy, abrasion resistance, and performance on ice and snow, and a studless tire for a passenger vehicle using the rubber composition. The present invention relates to a rubber composition for a tire, including a rubber component and silica, wherein the rubber component contains a modified natural rubber with a phosphorus content of 200 ppm or less, and butadiene rubber, and the silica has a CTAB specific surface area of 180 m2/g or more and a BET specific surface area of 185 m2/g or more.Type: GrantFiled: January 3, 2011Date of Patent: September 25, 2012Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Akihiro Nishimura
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Publication number: 20120225974Abstract: A rubber composition for tire, comprising at least a rubber component and an inorganic filler, wherein the inorganic filler has an angle of repose of 40 degrees or more, a Mohs' hardness of 2.0 or less, a BET specific surface area (BETS) (m2/g) of 10 m2/g or more, and a ratio (DBP)/(BET5) of the amount (ml/100 g) of dibutyl phthalate (DBP) absorbed to the BET specific surface area (BET5) (m2/g) of 2.0 or more, and wherein the content of the inorganic filler is from 0.5 to 50 parts by mass based on 100 parts by mass of the rubber component.Type: ApplicationFiled: February 24, 2012Publication date: September 6, 2012Applicant: TOYO TIRE & RUBBER CO., LTD.Inventors: Makoto Uno, Shinya Hasegawa
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Patent number: 8222317Abstract: The purpose of the present invention is to provide a wet friction material which has a high coefficient of friction, has reduced overall thickness change, and excellent heat resistance (resistance to heat spots). In order to accomplish the purpose, the present invention provides a wet friction material prepared by impregnating a base material including a fibrous substance with a thermosetting resin, and then thermally curing it, wherein the aspect ratio of the fibrous substance is 10 or higher, and the fibrous substance is contained in the base material in an amount of 60 to 75 weight %.Type: GrantFiled: October 2, 2008Date of Patent: July 17, 2012Assignee: Showa Denko K.K.Inventor: Toshihiko Kozutsumi
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Publication number: 20120108698Abstract: One exemplary embodiment includes a friction material including a base including a plurality of fibers. The base including an engagement surface, and a plurality of binder particles and friction modifying particles at the engagement surface.Type: ApplicationFiled: January 9, 2009Publication date: May 3, 2012Inventors: Robert C. Lam, Feng Dong
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Publication number: 20110319519Abstract: A rubber composition from which a vulcanized rubber suitable for producing, for example, a pneumatic tire having excellent abrasion resistance, breaking strength, rolling resistance, wet skid resistance, and the like can be prepared. The rubber composition comprises a rubber component (A) comprising a diene rubber comprising 20 mass % or more of a modified styrene-butadiene copolymer (a1) and 5 mass % or more of a modified conjugated diene polymer (a2), and a filler (B), wherein the modified conjugated diene polymer (a2) is a conjugated diene polymer obtained by modifying the active terminals of a conjugated diene polymer having a cis-1,4 bond content of 80% or higher, with an alkoxysilane compound, and the filler (B) comprises at least either of 2 to 100 mass parts, relative to 100 mass parts of the rubber component (A), of carbon black (b1) and 30 to 100 mass parts, relative to 100 mass parts of the rubber component (A), of silica (b2).Type: ApplicationFiled: March 11, 2010Publication date: December 29, 2011Applicant: JSR CORPORATIONInventors: Takuo Sone, Ryouji Tanaka
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Publication number: 20110301261Abstract: A chain end modified polymer comprising the reaction product of a living anionic elastomeric polymer and a silane-sulfide modifier A preferred class of modifiers includes compounds represented by the formula: (RO)x(R)ySi—R?—S—SiR3, wherein Si is silicon; S is sulfur; O is oxygen; x is an integer selected from 1, 2 and 3; y is an integer selected from 0, 1, and 2; x+y=3; R is the same or different and is: (C1-C16) alkyl; and R? is aryl, alkylaryl, or (C1-C16) alkyl. The invention further includes methods for making such chain end modified polymers, their use in preparing vulcanized elastomeric polymer compositions, and articles made from such compositions, including pneumatic tires, tire treads, belts, and the like. The subject compositions exhibit lower Tan ? at 60° C. values, while maintaining good processing characteristics, and a good balance of physical properties, including: abrasion resistance, tensile strength, modulus and elongation at break.Type: ApplicationFiled: August 4, 2011Publication date: December 8, 2011Inventors: Sven Thiele, Joachim Kiesekamp, Norbert Jantsch, Thomas Knispel
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Publication number: 20110294915Abstract: The invention relates to a rubber compound containing no or less than 0.5 phr zinc, which can be used for the manufacture of tyres, the compound being based on at least: a diene elastomer; a sulphur-based crosslinking system; an inorganic filler as reinforcing filler; and a blocked mercaptosilane of the following general formula (I) in which formula (I): R1 which are the same or different, each represent a monovalent hydrocarbon group chosen from alkyls, whether linear or branched, cycloalkyls or aryls, having 1 to 18 carbon atoms; A represents hydrogen or a monovalent hydrocarbon group chosen from alkyls, whether linear or branched, cycloalkyls or aryls, having 1 to 18 carbon atoms; Z represents a divalently bonded group having 1 to 18 carbon atoms; and n is an integer equal to 0, 1 or 2.Type: ApplicationFiled: December 18, 2009Publication date: December 1, 2011Applicants: Michelin Recherche et Technique S.A., Societe De Technologie MichelinInventors: Laure Belin, Karine Longchambon, José Carlos Araujo Da Silva
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Publication number: 20110288200Abstract: A method for preparing a functionalized polymer, the method comprising the steps of polymerizing monomer to form a reactive polymer, and reacting the reactive polymer with a polycyano compound.Type: ApplicationFiled: January 22, 2010Publication date: November 24, 2011Inventor: Steven Luo
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Publication number: 20110250372Abstract: A process for producing a nanocomposite of a halogenated elastomer and an inorganic, exfoliated clay includes the in-situ protonation of a modifier, which may be an alkylamine, arylamine or an alkylarylamine. This process can be integrated with a polymer halogenation process. The nanocomposite so formed has improved air barrier properties and is suitable for use as a tire innerliner or innertube.Type: ApplicationFiled: October 14, 2008Publication date: October 13, 2011Inventors: Weiqing Weng, James P. Stokes, Edmund J. Stachowski III, Molly W. Upton, Robert N. Webb, Ramesh Varadaraj, Cornelius H. Brons, David J. Lohse
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Publication number: 20110245370Abstract: The invention aims to provide a tire rubber composition that is excellent in the low heat build-up property (fuel economy), wet grip performance, and abrasion resistance, and can be suitably used for a tread (cap tread); and a tire rubber composition that is excellent in the low heat build-up property and breaking properties, and can be suitably used for a base tread or sidewall.Type: ApplicationFiled: April 4, 2011Publication date: October 6, 2011Inventors: Kenichi UESAKA, Tetsuya Kunisawa
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Publication number: 20110196063Abstract: The present invention relates to a rubber composition for tread which is capable of improving wear resistance and tear resistance and reducing rolling resistance in a compatible manner. Specifically, the present invention relates to a rubber composition for tread, produced by blending carbon black with rubber components including modified conjugated diene-based polymer having at least one nitrogen-containing functional group, wherein the carbon black is obtained by a specific process and light transmittance of toluene extract thereof observed at the multi-stage rapid cooling medium introduction means satisfies relationships of formula (I) and formula (II) below.Type: ApplicationFiled: September 1, 2009Publication date: August 11, 2011Applicant: BRIDGESTONE CORPORATIONInventor: Daigo Yonemoto
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Publication number: 20110190416Abstract: A rubber composition usable as tread for a winter tire, having a high grip on melting ice, comprising at least one diene elastomer such as natural rubber and/or a polybutadiene, more than 30 phr of a liquid plasticizing agent, between 50 and 150 phr of a reinforcing filler such as silica and/or carbon black, and between 5 and 40 phr of magnesium sulphate microparticles.Type: ApplicationFiled: July 20, 2009Publication date: August 4, 2011Inventors: Masayuki Maesaka, Salvatore Pagano, Makiko Watanabe
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Publication number: 20110166254Abstract: An object of the present invention is to provide a rubber composition for a tire, which can achieve well-balanced improvement in fuel economy, abrasion resistance, and performance on ice and snow, and a studless tire for a passenger vehicle using the rubber composition. The present invention relates to a rubber composition for a tire, including a rubber component and silica, wherein the rubber component contains a modified natural rubber with a phosphorus content of 200 ppm or less, and butadiene rubber, and the silica has a CTAB specific surface area of 180 m2/g or more and a BET specific surface area of 185 m2/g or more.Type: ApplicationFiled: January 3, 2011Publication date: July 7, 2011Inventor: Akihiro NISHIMURA
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Publication number: 20110152405Abstract: A diene rubber composition for tires based on at least (i) one diene elastomer, (ii) one reinforcing inorganic filler and (iii) one coupling agent which provides the bonding between the inorganic filler and the elastomer. The inorganic filler comprises at least one silica capable of being obtained by the preparation process of the type comprising the reaction of a silicate with an acidifying agent, whereby a silica suspension is obtained, followed by the separation and the drying of this suspension. The reaction of the silicate with the acidifying agent is carried out according to the following successive stages: (i) an aqueous suspension of precipitated silica, exhibiting a pH of between 2.5 and 5.3, is brought into contact (mixing) with acidifying agent and silicate, in such a way that the pH of the reaction medium is maintained between 2.5 and 5.3, (ii) silicate is added to the reaction medium obtained, so as to increase the pH of the reaction medium up to a value of between 4.7 and 6.3.Type: ApplicationFiled: March 9, 2009Publication date: June 23, 2011Applicants: SOCIETE DE TECHNOLOGIE MICHELIN, Michelin Recherche et Technique S.A.Inventors: Damien Thomasson, Emmanuelle Allain, Julien Hernandez
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Publication number: 20110144233Abstract: A process for modifying natural rubber and modified natural rubber with improved processing performance. The process for modifying natural rubber includes at least the following process steps: comminuting the natural rubber in a first process step; blending and purifying the natural rubber in a second process step; further comminuting the natural rubber in a third process step; and, drying the natural rubber in a fourth process step. The modified natural rubber is modified by at least four process steps.Type: ApplicationFiled: February 16, 2011Publication date: June 16, 2011Inventors: Sandra Stollberg, Hajo Weinreich
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Publication number: 20110086943Abstract: A rubber composition for use in tire treads including 100 parts by mass of a diene rubber and from 70 to 100 parts by mass of silica, wherein the diene rubber includes from 50 to 90 mass % of a terminal-modified styrene-butadiene rubber having a hydroxy group on an end of the molecule, and from 10 to 25 mass % of a butadiene rubber; the silica has a BET specific surface area of from 45 to 550 m2/kg, a CTAB specific surface area of from 40 to 525 m2/kg, a particle size distribution width Ld((d84?d16)/d50) of at least 0.91, and wherein V(d5-d50)/V(d5-d100) is at least 0.66; and a durometer hardness of the rubber composition when measured at 20° C. is from 70 to 80.Type: ApplicationFiled: August 6, 2010Publication date: April 14, 2011Inventors: Masaki Sato, Takeshi Kiyohara
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Publication number: 20110065833Abstract: The invention relates to a rubber mixture, in particular for pneumatic vehicle tires, bands, and belts, having improved abrasion behavior. The rubber mixture is characterized by the following composition: at least one diene rubber and—at least one precipitated silicic acid having a CTAB surface area greater than or equal to 150 m2/g and a BET surface area greater than or equal to 150 m2/g and a DBP number between 180 and 350 g/100 g and a full width at half maximum, which is standardized to the location of the reflection, of the reflection of less than or equal to 0.95 and a homogeneity ratio d 25% to d 75% of 1.00 to 1.80 and a relative width Ypressed in the compressed state of less than or equal to 2.8 (g nm)/ml and a fineness index F.V.pressed in the compressed state between 100 and 140, and further additives.Type: ApplicationFiled: October 6, 2010Publication date: March 17, 2011Inventors: Carmen Schmidt, Carla Recker, Thomas Fey
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Publication number: 20110039976Abstract: A tire having a tread, said tread being provided with a plurality of cavities, at least some of said cavities having a filling composition based on at least: a diene elastomer; more than 50 phr of filler (denoted filler A), the particles of which are nanoparticles having an average size (by weight) of less than 500 nm; and more than 70 phr of filler (denoted filler B), the particles of which are microparticles having a median particle size (by weight) of greater than 1 ?m. This filling composition is sufficiently cohesive to ensure excellent mechanical behaviour of the cavities. It also has the capability of progressively wearing during running, without cracking, more quickly than the constituent composition of the tread itself.Type: ApplicationFiled: December 18, 2008Publication date: February 17, 2011Applicants: Societe De Technologie Michelin, Michelin Recherche et Technique S.A.Inventor: Didier Vasseur
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Publication number: 20100256259Abstract: The purpose of the present invention is to provide a wet friction material which has a high coefficient of friction, has reduced overall thickness change, and excellent heat resistance (resistance to heat spots). In order to accomplish the purpose, the present invention provides a wet friction material prepared by impregnating a base material comprising a fibrous substance with a thermosetting resin, and then thermally curing it, wherein the aspect ratio of the fibrous substance is 10 or higher, and the fibrous substance is contained in the base material in an amount of 60 to 75 weight % .Type: ApplicationFiled: October 2, 2008Publication date: October 7, 2010Applicant: SHOWA HIGHPOLYMER CO., LTD.Inventor: Toshihiko Kozutsumi
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Patent number: 7759410Abstract: There is provided a rubber composition for a sidewall, use of which makes it possible to consider an effect on environment, prepare for decrease in petroleum supply in future and further improve tear strength, flex crack growth resistance and weather resistance. The rubber composition comprises 15 to 120 parts by weight of a white filler and 5 to 50 parts by weight of graphite having an average particle diameter of 3 to 50 ?m on the basis of 100 parts by weight of a rubber component comprising a natural rubber in an amount of not less than 30% by weight.Type: GrantFiled: May 14, 2007Date of Patent: July 20, 2010Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazuo Hochi
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Patent number: 7741382Abstract: The present invention provides a rubber composition for a tread which can improve both of grip performance and rolling resistance in good balance and a tire having a tread prepared by using it. The rubber composition for a tread of the present invention contains 30 to 80 parts by weight of a silica having a pH of 7.1 to 12.0 when dispersed in water to prepare a 5% aqueous dispersion; and not more than 10 parts by weight of a carbon black on the basis of 100 parts by weight of a rubber component comprising an epoxidized natural rubber and the tire of the present invention has a tread prepared by using the rubber composition.Type: GrantFiled: May 14, 2007Date of Patent: June 22, 2010Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kazuo Hochi
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Publication number: 20090275675Abstract: A method of compounding a modified, epoxidized natural rubber for use as a tire tread which includes the steps of modifying an epoxidized natural rubber containing a ring-opened epoxy group, compounding the modified, epoxidized natural rubber with another rubber, to form a rubber compound, together with silica and/or carbon black to form a rubber composition, and forming the rubber composition into a tire tread.Type: ApplicationFiled: July 13, 2009Publication date: November 5, 2009Inventors: Noriko Yagi, Kiyoshige Muraoka
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Publication number: 20090124724Abstract: A rubber composition that can improve rolling resistance of a tire without impairing other performances such as processability or wet performance, and a pneumatic tire using the same are provided. The rubber composition includes a diene rubber as a rubber component, and clay treated with a lignin sulfonate.Type: ApplicationFiled: November 6, 2008Publication date: May 14, 2009Applicant: Toyo Tire & Rubber Co., Ltd.Inventors: Takashi Sakurai, Hirofumi Hayashi
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Publication number: 20090084476Abstract: The invention provides a rubber composition that is superior in low heat build-up property and wear resistance. It is a manufacturing method of a rubber composition containing 30 to 150 parts by mass of silica and 0.5 to 10 parts by mass of an organic vulcanization agent represented by the following general formula (1) to 100 parts by mass of a rubber component, including a first kneading step of kneading the organic vulcanization agent and silica into the rubber component, and a second kneading step of kneading a vulcanization agent and a vulcanization accelerator thereafter: R1—(R—Sx)n—R2 ??(1) (wherein R is (CH2—CH2—O)m—CH2—CH, and R1 and R2 are independently hydrogen, a methyl group, a thiol group, a hydroxy group, a carboxyl group, or an aldehyde group, X is an integer of 3 to 6, n is an integer of 10 to 400, and m is an integer of 1 to 5).Type: ApplicationFiled: September 5, 2008Publication date: April 2, 2009Inventor: Kazuo HOCHI
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Publication number: 20090071764Abstract: A brake pad (5) having a braking surface (9, 109), intended to be pressed during braking against a side (8) of a rim (3) of a wheel (2) of the bicycle (1), and thermal transmission means (11, 111) suitable for transferring heat away from the braking surface (9, 109) is disclosed. The heat that is generated at the braking surface (9, 109) during braking is taken away from the braking surface (9, 109) and transferred into other areas of the pad (5).Type: ApplicationFiled: August 29, 2008Publication date: March 19, 2009Applicant: CAMPAGNOLO S.R.L.Inventor: Paolo Fabris
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Publication number: 20090054550Abstract: The present invention provides a rubber composition for a tread which can improve both of grip performance and rolling resistance in good balance and a tire having a tread prepared by using it. The rubber composition for a tread of the present invention contains 30 to 80 parts by weight of a silica having a pH of 7.1 to 12.0 when dispersed in water to prepare a 5% aqueous dispersion; and not more than 10 parts by weight of a carbon black on the basis of 100 parts by weight of a rubber component comprising an epoxidized natural rubber and the tire of the present invention has a tread prepared by using the rubber composition.Type: ApplicationFiled: May 14, 2007Publication date: February 26, 2009Inventor: Kazuo Hochi
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Publication number: 20090043011Abstract: In a wet friction material, to be able to reduce a drag torque, while being greater in a disengagement feature and a positive ?-V slope characteristic by keeping a pore diameter large without generating strength reduction or increase in settling quantity. By adding small-particle inorganic filler 2, it attaches the inorganic filler 2 to inter-fiber 3 and it can obtain an effect to improve strength of friction material substrates 1 by connecting the inter-fiber 3 when an impregnated resin is hardened. Moreover, by keeping an absolute specific gravity of the inorganic filler 2, its compounded capacity becomes small and it can secure a pore diameter 5 of the friction material substrates 1 without being filled in pores of the friction material substrates 1 with the inorganic filler 2. As a result, it makes faster to absorb ATF from a friction surface. Therefore, it improves the disengagement feature and the positive ?-V slope characteristic, while reducing the drag torque.Type: ApplicationFiled: August 7, 2008Publication date: February 12, 2009Applicant: AISIN KAKO KABUSHIKI KAISHAInventors: Yuko HIGASHIJIMA, Ryouhei Hoshino, Takuya Muranaka
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Publication number: 20090036567Abstract: There is provided a process for producing a modified diene polymer rubber comprising the steps of: (1) polymerizing a conjugated diene monomer or a combination thereof with an aromatic vinyl monomer in a hydrocarbon solvent, in the presence of an alkali metal catalyst, to form an alkali metal end-carrying active polymer, and (2) reacting the alkali metal end-carrying active polymer with a silane compound defined by a specific formula.Type: ApplicationFiled: September 29, 2008Publication date: February 5, 2009Inventors: Mayumi OSHIMA, Seiichi MABE, Katsunari INAGAKI
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Patent number: 7473727Abstract: A friction material for a synchronizer ring comprises (A) a petroleum coke with an ash content of 0.1 mass % to 8 mass % or (B) a pitch coke with an ash content of 0.1 mass % to 8 mass %, more preferably (C) a calcined petroleum coke with an ash content of 0.1 mass % to 1 mass % or (D) a foundry coke with an ash content of 5 mass % to 8 mass %. The friction material is effectively used for a synchronizer ring requiring high coefficient of dynamic friction.Type: GrantFiled: June 3, 2004Date of Patent: January 6, 2009Assignee: Tanaka Seimitsu Kogyo Co., Ltd.Inventors: Yoshiaki Takagi, Eishin Matsui, Yoshihiro Fukushima, Tomoya Takata
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Patent number: 7338987Abstract: There are disclosed a friction material composition which comprises a fibrous material except for asbestos, an inorganic friction regulator, an organic friction regulator and a binder, part of the inorganic friction regulator is ? alumina and ? alumina in combination, a weight ratio of the ? alumina and the ? alumina, ? alumina:? alumina, is in the range of 1:20 to 1:5, and part or whole part of the binder is a silicon-containing phenol resin, and a friction material obtained by molding the friction material composition under heating and pressure.Type: GrantFiled: May 21, 2004Date of Patent: March 4, 2008Assignees: Hitachi Chemical Co., Ltd., Nissan Motor Co., Ltd.Inventors: Manabu Ono, Teruyuki Nagayoshi, Mitsuhiro Inoue, Hiroki Morozumi, Takahiro Mibe, Yukio Takai
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Patent number: 7326742Abstract: The present invention provides a wet type friction material comprising a paper base material and binder, in which the paper base material includes silica having an average particle diameter of 1 to 10 ?m and disc-shaped diatom earth, and the binder comprises a cured substance of liquid resin composition material obtained by mixing resol type phenol resin with silicone resin, where a weight ratio between non-volatile components of the resol type phenol resin and the silicone resin is adjusted to a range of 95/5 to 85/15.Type: GrantFiled: October 16, 2003Date of Patent: February 5, 2008Assignees: Toyota Jidosha Kabushiki Kaisha, NSK-Warner K.K.Inventors: Masataka Kawabata, Atsushi Suzuki, Hideki Tatewaki, Katsumi Takezawa
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Patent number: 7326741Abstract: In a friction material, columnar or scaly non-whisker-like alkali metal titanate or non-whisker-like alkali metal•alkaline-earth metal titanate having an average particle diameter in the range of 0.1 to 100 ?m and an aspect ratio of 3 or less and an inorganic porous filler are compounded, and a friction material in which non-whisker-like lithium.potassium titanate having an average particle diameter in the range of 0.1 to 100 ?m and an aspect ratio of 3 or less is compounded.Type: GrantFiled: July 14, 2004Date of Patent: February 5, 2008Assignee: Akebono Brake Industry Co., Ltd.Inventors: Satoshi Kusaka, Hidetoshi Hishinuma
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Patent number: 7306665Abstract: A friction material composition containing a fibrous material, a binder and a friction adjusting agent, wherein the friction adjusting agent is secondary aggregates of an activated alumina being spherical and having a diameter of 10 to 300 ?m, or an activated alumina having a specific surface area of 100 to 400 m2/g and an average particle diameter of 1 to 200 ?m. The composition can be used for producing a friction material which exhibits significant improvement with respect to fading phenomenon, without adversely affecting its characteristics of attacking to a disc rotor, which is the article mating therewith, and without marked reduction of the friction coefficient at an elevated temperature, and is capable of controlling the thickness of the sliding film formed on a frictionally sliding face and preventing a high frequency noise (grabbing chatter).Type: GrantFiled: December 13, 2002Date of Patent: December 11, 2007Assignee: Hitachi Chemical Co., Ltd.Inventors: Teruyuki Nagayoshi, Noboru Suzuki, Manabu Ono
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Patent number: 7297728Abstract: A friction material is made by molding and curing a composition containing a fibrous base that includes stainless steel fibers but not other steel fibers, a binder, and a friction modifier that includes at least two types of hard particles having a large Mohs hardness, bronze powder and a specific amount of tin sulfide. The friction material has a excellent balance of properties, including a high strain linearity that provides a excellent brake feel, a high torque linearity and a excellent effectiveness, and also minimizes disc rotor attack, disc pad wear and metal pickup. Such friction materials are particularly suitable for automotive applications, such as disc pads.Type: GrantFiled: July 1, 2004Date of Patent: November 20, 2007Assignee: Nisshinbo, Industries, Inc.Inventors: Kazuhide Yamamoto, Yasuki Hattori
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Patent number: 7294188Abstract: An improved method of producing a friction material for use in the production of brake pads. A first mixing step blends binder, fiber, and filler materials together in a mixer to create a pre-mix, with one of the materials doubling as a wetting agent promoting the homogeneity of the mixture. A second non-asbestos material is added to the pre-mix in the same mixer, and the two are mixed together to produce the final friction material.Type: GrantFiled: December 20, 2005Date of Patent: November 13, 2007Assignee: Akebono Corporation (North America)Inventors: Xinming Shao, Sunil Kesavan
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Publication number: 20070219289Abstract: A friction material includes a binder, a reinforcement fiber, and a friction modifier which in turn includes flat layered titanate particles and baryte particles, wherein the baryte particles constitute less than 25% by volume of the friction material. The flat layered titanate particle may include alkali metal titanate particles, and more specifically potassium lithium titanate particles. Other flat layered titanates, including alkali metal alkaline earth metal titanates may also be used. The titanate particles may be used in an amount of 3-25% by volume of the friction material, and more specifically 5-15% by volume thereof. They may also have particle sizes ranging from 0.1-500 ?m, and more specifically 1-30 ?m, and even more specifically 15-30 ?m. The friction material may include a binder or binders in an amount of about 8-31% by volume of the friction material. The friction material may also include reinforcement fibers in an amount of about 2-13% by volume of the friction material.Type: ApplicationFiled: March 14, 2007Publication date: September 20, 2007Applicant: FEDERAL-MOGUL WORLD WIDE, INC.Inventors: Mark Phipps, Gregory Vyletel
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Patent number: 7179850Abstract: A friction material matrix is described, containing a tin oxide, such as but not limited to stannous oxide or stannic oxide, and a binder system, the binder system physically or chemically binding the tin oxide. The tin oxide is preferably present in an amount in the range of about 0.3 to about 20 weight percent, based on the total weight of the friction material matrix. The tin oxide preferably has a Mohs hardness level of about 6.5. The tin oxide improves the performance behavior of a friction couple at an interface between the friction material matrix and an automotive braking element.Type: GrantFiled: September 25, 2001Date of Patent: February 20, 2007Assignee: Honeywell International, Inc.Inventor: Sunil K. Kesavan
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Patent number: 6887549Abstract: A friction material obtainable by molding and curing a material composition having a fibrous base, a binder, and a filler, wherein an amount of sulfate ions extracted from the friction material measured in accordance with JIS K 0127 is about 0.2 mg/g or smaller and the pH of the friction material is about 10.0 or higher and less than about 13.0.Type: GrantFiled: June 24, 2004Date of Patent: May 3, 2005Assignee: Nisshinbo Industries, Inc.Inventors: Seiji Suzuki, Yasuki Hattori, Kazuhide Yamamoto
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Patent number: 6777461Abstract: The polymeric composition for friction elements comprises a co-polymer between (I) a resin containing phenolic groups and a reticulation agent, and (II) an organopolysiloxane resin containing terminal silanol groups. A part at least of the phenolic groups is bound to the terminal silanol groups. A process of the preparation of the above polymeric composition may comprise the following steps: a) mixing (I) a resin containing the phenolic groups and the reticulation agent, (II) resin containing the terminal silanol groups, and (III) an epoxy resin or the epoxidisesd organopolysiloxane; b) curing the mixture for a period of time sufficient to complete substantially the reaction between the phenolic groups and the terminal silanol groups, c) post-heating the product obtained under b).Type: GrantFiled: December 1, 2000Date of Patent: August 17, 2004Assignee: Nisshinbo Industries, Inc.Inventors: Vasilios Kanellopoulos, Isabelle Louis-Joseph-Dogue, Vincent Daniel McGinniss, Duryodhan Mangaraj, Tomoki Tsuchiya Nakamura
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Publication number: 20040030000Abstract: A non-asbestos friction material is made of a molded and cured composition containing a fibrous base other than asbestos, a binder, a filler and an abrasive. The abrasive includes zirconium silicate beads. Friction materials thus constituted have suitable coefficients of friction, exhibit a good noise performance, and minimize mating surface attack.Type: ApplicationFiled: August 6, 2003Publication date: February 12, 2004Inventors: Kazuhiro Takeuchi, Takeo Nagata
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Patent number: 6660355Abstract: An annular body, and method of making same, comprising at least one wear surface portion, the portion comprising a plurality of layers held in a matrix, each layer consisting essentially of fibres which extend generally in one direction and parallel to each other and from the centre of the body to the periphery, whereby the wear of that surface portion is improved. The body can be formed into an aircraft brake disc.Type: GrantFiled: December 22, 2000Date of Patent: December 9, 2003Assignee: Dunlop Aerospace LimitedInventor: David Callum Johnson