Glass Patents (Class 523/217)
  • Patent number: 11767433
    Abstract: A method of forming a titania-coated inorganic particle comprising the steps of (a) stirring a mixture of a titania precursor such as a titanium alkoxide and an inorganic particle such as a hollow glass particles in an organic solvent such as an alcohol for more than 1 h to cause adsorption of the titania precursor on the surface of the inorganic particle; and (b) adding water dropwise to the mixture under stirring to convert the titania precursor to titania which then forms a coating on the inorganic particle. A method for forming a paint formulation, a titania-coated inorganic particle, a paint formulation comprising a titania-coated inorganic particle and use of a titania-coated inorganic particle in a paint formulation is also described.
    Type: Grant
    Filed: January 28, 2021
    Date of Patent: September 26, 2023
    Assignee: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH
    Inventors: Chao Chen, Xu Li, Suxi Wang, Xikui Zhang, Siew Yee Wong
  • Patent number: 10711110
    Abstract: The invention relates to a method for producing a thermoplastic fibre composite containing a thermoplastic moulding compound (A) as a polymer-matrix (M), reinforcement fibres (B), and optionally additive (C). Said method comprises the following steps: i) flat structures (F) made from reinforcing fibres (B) treated with a silane sizing material are provided, ii) the flat structures (F) are placed in a thermoplastic molding compound (A) which comprises at least 0.3 mol %, with respect to components (A), of a chemically reactive functionality, iii) chemically reactive groups of the thermoplastic molding compound (A) are reacted in the polymer matrix (M) with the polar groups of the treated reinforcing fibres (B), iv) the at least one additive (C) is optionally incorporated v) cooling. Said method is particularly suitable for producing fibrous composites.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: July 14, 2020
    Assignee: INEOS STYROLUTION GROUP GMBH
    Inventors: Norbert Niessner, Eike Jahnke
  • Patent number: 10563038
    Abstract: A polycarbonate resin composition and a molded article manufactured using the same. The polycarbonate resin composition includes: (A) a polycarbonate resin including end groups, wherein the end groups include a hydroxyl group (—OH) in an amount of about 1% to about 20% based on the total weight (100 wt %) of all end groups; and (B) a metal compound comprising at least one of a metal oxide, a heavy metal complex oxide, and a copper salt. The polycarbonate resin composition and a molded article manufactured using the same can have excellent properties in terms of impact strength, flexural strength, and processability.
    Type: Grant
    Filed: April 21, 2016
    Date of Patent: February 18, 2020
    Assignee: Lotte Advanced Materials Co., Ltd.
    Inventors: Yoo Jin Jung, Eun Taek Woo, Eric Arifin, Jung Ki Kim, Na Ri Park, Mi Rae Jang, Sang Hyun Hong
  • Patent number: 9944745
    Abstract: Flame retardant polyesters obtainable by reacting an aromatic or aliphatic dicarboxylic acid and/or ester of anhydride thereof, with an aliphatic polyol or mixtures thereof and with melamine, are provided. Methods of making said polyesters are also provided.
    Type: Grant
    Filed: May 30, 2016
    Date of Patent: April 17, 2018
    Assignee: COIM ASIA PACIFIC PTE. LTD.
    Inventor: Wally Liyuan Chang
  • Publication number: 20150132586
    Abstract: Addition-curable encapsulants for electrical and electronic components contain amorphous glass particles doped with silver, and are efficient scavengers of sulfur and sulfur compounds.
    Type: Application
    Filed: April 4, 2013
    Publication date: May 14, 2015
    Inventor: Philipp Mueller
  • Patent number: 9018280
    Abstract: A molding composition formulation includes a thermoset cross-linkable 12 to 45 micron polymeric resin. Hollow glass microspheroids are present from 2 to 12 total weight percent. An article formed from such a composition is further strengthened by the addition of a surface activating agent bonded to the surface of the glass microspheroids. Conventional particulate fillers when added to an inventive formulation provide enhanced performance when the filler particle has a size sufficiently small to insert within adjacent microspheroid interstitial voids. An unsaturated polyester resin so formed is particularly well suited for the formation of sheet molding compound formulations.
    Type: Grant
    Filed: April 21, 2010
    Date of Patent: April 28, 2015
    Assignee: Continental Structural Plastics, Inc.
    Inventors: Brian A. Beach, Probir K. Guha, Brad Haskell, Michael J. Siwajek
  • Patent number: 8841358
    Abstract: The invention relates to a ceramic particulate and polymer composite having enhanced viscoelastic and rheological properties.
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: September 23, 2014
    Assignee: Tundra Composites, LLC
    Inventors: Kurt E. Heikkila, Rodney K. Williams, John S. Kroll
  • Publication number: 20140235754
    Abstract: The present disclosure relates to a fiber reinforced composite material. In an embodiment, the composite material includes a PLLA fiber material and a matrix material that does not have the same chemical element composition as the fiber material. Other fiber reinforced composite materials are also disclosed.
    Type: Application
    Filed: April 25, 2014
    Publication date: August 21, 2014
    Applicant: Smith & Nephew, Inc.
    Inventors: John Rose, Malcolm Brown, Nicola Macauley, Mike Hall
  • Publication number: 20140128501
    Abstract: In a fibrous planar structure in which fibers are embedded in a matrix, an increase in mechanical resistance is achieved by improving the adhesion between the fiber and the matrix.
    Type: Application
    Filed: January 16, 2012
    Publication date: May 8, 2014
    Applicant: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Christian Seidel, Heinrich Zeininger
  • Patent number: 8669302
    Abstract: The application of certain (preferably photocurable) composite materials comprising a monomer with a polyalicyclic structure element as a dental sealing material is described herein. A description is also provided of novel polymerizable monomers comprising at least one polyalicyclic structure element and certain ethylenic structure elements, which are particularly suitable for use in a composite material to be applied and their application in a composite material.
    Type: Grant
    Filed: September 29, 2011
    Date of Patent: March 11, 2014
    Assignee: VOCO GmbH
    Inventors: Tobias Blömker, Manfred Stepputtis, Manfred Thomas Plaumann, Reinhard Maletz
  • Patent number: 8536248
    Abstract: The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: September 17, 2013
    Assignee: UMG ABS, Ltd.
    Inventors: Masahito Nakamoto, Koichi Tezuka
  • Patent number: 8507586
    Abstract: The reinforced thermoplastic resin composition of the present invention includes: 50 to 90% by weight of a polycarbonate resin (A); 10 to 50% by weight of a graft copolymer mixture (B) (provided that a total amount of the component (A) and the component (B) accounts for 100% by weight) which is obtained by graft-polymerizing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) onto a rubber polymer (B1); and 6 to 22 parts by weight of an inorganic filler (D) which has been surface-treated with a water-soluble polyamide, relative to the total of 100 parts by weight of the polycarbonate resin (A) and the graft copolymer mixture (B). There is provided a reinforced thermoplastic resin composition exhibiting excellent moldability, generates a minimal amount of gas during molding, and also being capable of improving the rigidity of the resulting molded article and the impact resistance when dropping the product.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: August 13, 2013
    Assignee: UMG ABS, Ltd.
    Inventors: Masahito Nakamoto, Koichi Tezuka
  • Patent number: 8349460
    Abstract: Organosilicon composites are described, comprising 30 to 90 vol. % of a cured organosilicon copolymer derived by curing an organosilicon polymer having, in the same copolymer, silicon-containing repeating units comprising a silicon hydride and silicon-containing repeating units comprising a C1-10 ethylenically unsaturated group; and 10 to 70 vol. % of a dielectric filler. The composites are used in the manufacture of circuit subassemblies.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: January 8, 2013
    Assignee: World Properties, Inc.
    Inventor: Sankar K. Paul
  • Patent number: 8318833
    Abstract: The present invention is drawn to pigment suspensions, methods of forming pigment suspensions, and ink sets. The pigment suspension can comprise an aqueous liquid vehicle and a polymer-encapsulated pigment suspended in the liquid vehicle. The polymer-encapsulated pigment can include a pigment core, a passivation layer formed from a passivation component including an amphiphilic polymer and deposited on a surface of the pigment core, and a polymer-encapsulation layer attached to or deposited on the passivation layer.
    Type: Grant
    Filed: April 26, 2007
    Date of Patent: November 27, 2012
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Sivapackia Ganapathiappan
  • Patent number: 8143330
    Abstract: Provided is a polycarbonate resin composition which contains specific amounts of a glass filler and glossy particles, which can be molded into an article in which no difference in lightness is visually observed between the left side and the right side of the weld line, and which has excellent optical properties and flame retardancy. The polycarbonate resin composition contains: a composition formed of an aromatic polycarbonate resin (A) and a glass filler (B) having a difference in refractive index 0.002 or less from the aromatic polycarbonate resin of; glossy particles (C-1) having an average particle diameter of 10 ?m or more and less than 50 ?m; glossy particles (C-2) having an average particle diameter of 50 to 300 ?m; a silicone compound (D) having a reactive functional group; and an organic alkali metal salt compound and/or an organic alkali earth metal salt compound (E).
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: March 27, 2012
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshio Isozaki, Kouji Satou, Takayoshi Tanaka
  • Patent number: 8138252
    Abstract: It is an object of the present invention to provide a thermally disappearing resin particle and a thermally disappearing hollow resin particle which can be decomposed at a low temperature in a short time and do not cause deformation or cracking of a sintered body to be obtained in the case of using as a binder for a ceramic or a lightening material; a method of producing the thermally disappearing hollow resin particle; a ceramic composition which can be degreased and fired at a low temperature in a short time and gives a molded body with a high porosity without deformation or cracking even in the case a large quantity of a pore-forming material is used; and a method of producing a porous ceramic filter. The present invention is directed to a thermally disappearing resin particle, which contains a polyoxyalkylene resin, and 10% by weight or more of the whole particle disappearing within an hour by heating at a prescribed temperature in a range from 100 to 300° C.
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: March 20, 2012
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Takahiro Oomura, Naoyuki Nagatani, Miki Inaoka, Hiroshi Yamauchi
  • Patent number: 8133939
    Abstract: Provided are: a polycarbonate resin composition which is excellent in mechanical properties, physical properties, optical properties, and flame retardancy, including: a composition formed of an aromatic polycarbonate resin (A) and a glass filler (B) having a difference in refractive index of 0.002 or less from the aromatic polycarbonate resin; glossy particles (C-1) having an average particle diameter of 10 ?m or more and less than 50 ?m; glossy particles (C-2) having an average particle diameter of 50 to 300 ?m; and a silicone compound (D) having a reactive functional group; a polycarbonate resin molded article obtained by molding the polycarbonate resin composition; and a method of producing a polycarbonate resin molded article, involving subjecting the polycarbonate resin composition to injection molding at a mold temperature of 120° C. or higher.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: March 13, 2012
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshio Isozaki, Kouji Satou, Takayoshi Tanaka
  • Publication number: 20100255282
    Abstract: A high temperature resistant insulating composition includes an organic polymer and an inorganic binder. The inorganic binder is ranged between 10% and 90% by weight of the high temperature resistant insulating composition. The high temperature resistant insulating composition still possesses strength and insulating property after a high temperature treatment.
    Type: Application
    Filed: April 5, 2010
    Publication date: October 7, 2010
    Applicant: DELTA ELECTRONICS, INC.
    Inventors: Shou-Yu Hong, Wei Yang, Jian-Hong Zeng, Jian-Ping Ying
  • Patent number: 7700670
    Abstract: A molding composition formulation includes a thermoset cross-linkable polymeric resin. Glass microspheroids are present such that upon cure of the resin the resulting article has a linear shrinkage of less than ±0.06% and a density of less than 1.65. An article formed from such a composition is further strengthened by the addition of a surface activating agent bonded to the surface of the glass microspheroids. Conventional particulate fillers when added to an inventive formulation provide enhanced performance when the filler particle has a size sufficiently small to insert within adjacent microspheroid interstitial voids. An unsaturated polyester resin so formed is particularly well suited for the formation of sheet molding compound formulations.
    Type: Grant
    Filed: May 15, 2006
    Date of Patent: April 20, 2010
    Inventors: Brian A. Beach, Probir K. Guha, Brad Haskell, Michael J. Siwajek
  • Patent number: 7649032
    Abstract: A polycarbonate composition comprising a polycarbonate-polysiloxane copolymer resin and a glass flake additive wherein the polycarbonate-polysiloxane copolymer resin has a silicone content in the range of from 3.5 weight % to 7 weight % based on the total weight of the polycarbonate composition and wherein the polycarbonate-polysiloxane copolymer has a haze of less than 10% and wherein the glass flake additive is present in the range of 0.025 weight % to 0.70 weight % based on the total weight of the polycarbonate composition.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: January 19, 2010
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Brett D. Ermi, Sriramakrishna Maruvada, Niles Richard Rosenquist, Philippe Schottland
  • Patent number: 7649034
    Abstract: The present invention is directed to a coating powder base composition having a viscosity of between about 2 to about 85 Pa·s and including a particulate organic pigment tinting agent. Such base composition can be produced in large batches and then smaller portions of such batches can be mixed with a tinting agent comprising solid organic pigment particles characterized by a maximum surface index of about 50 to obtain a desired color for the final coating powder. The invention also includes methods for making such coating powders as well as for coating substrates using such coating powders.
    Type: Grant
    Filed: November 18, 2004
    Date of Patent: January 19, 2010
    Assignee: Spraylat Corporation
    Inventors: Steven M. Ladatto, Travis O. Bush
  • Patent number: 7611598
    Abstract: An aqueous glass fiber sizing composition that includes a polymeric film forming component, at least one silane coupling agent, and one or more lubricants is provided. The polymeric film forming component of the sizing composition includes a silanated polyvinyl acetate, an epoxidized polyvinyl acetate, and a modified epoxy emulsion. In preferred embodiments, the film formers are present in the sizing composition in ratios of 70:25:5, 50:25:25, or 63:18:18 of silanated polyvinyl acetate, epoxidized polyvinyl acetate, and modified epoxy emulsion respectively. Fibers sized with the sizing composition in a sheet molding compound process have improved wet-out characteristics.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: November 3, 2009
    Assignee: OCV Intellectual Capital, LLC
    Inventors: Steven E. Baker, Jeffrey L. Antle, Donald R. Holman
  • Patent number: 7468400
    Abstract: The glittering ink composition of the present invention contains a glass flake pigment, a water-soluble resin, a water-soluble organic solvent and water as essential ingredients. The content of the glass flake pigment is 0.01-40% by weight relative to the total amount of the ink composition. Moreover, the ink composition contains a synthetic resin emulsion as a binder component for fixing the glass flake pigment to a handwriting or a coated film in 0.01-40% by weight in solids relative to the total amount of the ink composition. The synthetic resin emulsion has an anionic property or a nonionic property and its minimum film forming temperature is not higher than 20° C.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: December 23, 2008
    Assignee: Sakura Color Products Corporation
    Inventors: Yasuyuki Yoshimura, Naoshi Murata, Yuki Yamamoto, Tomohiro Sawa
  • Publication number: 20080250974
    Abstract: A dental material comprising a symmetrically rod-shaped fiber-reinforced composite comprising at least two layers of preimpregnated fibers, wherein the preimpregnated fibers comprise fibers coated with a resin, wherein the layers are unbraided, and wherein each layer is unidirectionally disposed on the preceding layer in a direction that is different from the direction of the preceding layer. The rod-shaped composite may be hollow and contain a channel throughout the axial length of the rod or may contain a shaft or other material that is inserted into the channel.
    Type: Application
    Filed: April 12, 2007
    Publication date: October 16, 2008
    Applicant: Pentron Clinical Technologies, LLC
    Inventor: Weitao Jia
  • Patent number: 7285508
    Abstract: The present invention provides a glass flake that is substantially free of boron trioxide (B2O3), barium oxide (BaO), zinc oxide (ZnO), and fluorine (F) and has sufficient heat resistance and good formability for glass flake. The glass flake of the present invention includes a glass composition that contains the following components, expressed in mol %; 50?SiO2?65; 4?Al2O3<12; 5?SrO?25; 10<(MgO+SrO)?30; 20?(MgO+CaO+SrO)?45; and 0<(Li2O+Na2O+K2O)<2; wherein the glass composition is substantially free of B2O3, BaO, ZnO, and F. This glass flake is useful for resin compositions, paints, cosmetics, ink compositions, and the like.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: October 23, 2007
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Kosuke Fujiwara, Akihiro Koyama
  • Patent number: 7276282
    Abstract: The present invention relates to reinforcement yarns coated with a sizing composition comprising at least one silane satisfying the formula: Si(R1)(R2)(R3)(R4) in which: R1, R2 and R3 are chosen from the following atoms or groups: —H (except in the case of R3), —Cl, —O—R5, —O—R6—O—R5, —O—(C?O)—R5, —O—R6—(C?O)—R5, R5 and R6 being chosen from hydrocarbon radicals whose main chain has from 1 to 4 carbon atoms; R4?—R7—NHR8 R7 being chosen from branched hydrocarbon radicals whose main chain has from 2 to 6 carbon atoms, R8 being chosen from the following groups: —H, —R9—NH2, —R10—NH—R9—NH2, R9 being chosen from hydrocarbon radicals containing 1 to 12 carbon atoms or from carbonyls, and R10 being chosen from hydrocarbon radicals whose main chain has from 1 to 6 carbon atoms. The glass yarns according to the invention are particularly suitable for reinforcing organic materials, the yarns and composites obtained resisting in a corrosive medium.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: October 2, 2007
    Assignee: Saint-Gobain Vetrotex France S.A.
    Inventors: Eric Dallies, Patrick Moireau
  • Patent number: 7169463
    Abstract: An aqueous glass fiber sizing composition that includes a polymeric film forming component, at least one silane coupling agent, and one or more lubricants is provided. The polymeric film forming component of the sizing composition includes a silanated polyvinyl acetate, an epoxidized polyvinyl acetate, and a modified epoxy emulsion. In preferred embodiments, the film formers are present in the sizing composition in ratios of 70:25:5, 50:25:25, or 63:18:18 of silanated polyvinyl acetate, epoxidized polyvinyl acetate, and modified epoxy emulsion respectively. Fibers sized with the sizing composition in a sheet molding compound process have improved wet-out characteristics.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: January 30, 2007
    Assignee: Owens Corning Fiberglas Technology, Inc.
    Inventors: Steven E. Baker, Jeffrey L. Antle, Donald R. Holman
  • Patent number: 7160944
    Abstract: A process for making an aqueous emulsion of polyolefin employs a functionalized emulsification facilitating compound. The aqueous emulsion can be used to prepare a hybrid polyolefin-polyurethane dispersion useful, inter alia, as an adhesion-promoting coating for polymers such as the polyolefins.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: January 9, 2007
    Assignee: Crompton Corporation
    Inventors: Ibrahim Bechara, Pavel Ilmenev, Oleg Tselnik
  • Patent number: 7122585
    Abstract: Coating powders with enhanced electrostatic attraction to low conductivity substrates such as engineered wood are disclosed. The addition of conductive fillers to low temperature cure coating powder compositions improves the coating of difficult to coat substrates such as raised panel cabinet doors. Low temperature cure coating powders containing conductive additives can be applied to preheated engineered wood substrates. Also disclosed are methods for forming a powder coating on a low conductivity substrate.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: October 17, 2006
    Assignee: Rohm and Haas Company
    Inventors: Edward G. Nicholl, Joseph J. Kozlowski
  • Patent number: 7115677
    Abstract: A flame-retardant resin composition comprises 10 to 300 parts by weight of a flame retardant (B) and 1 to 200 parts by weight of an inorganic filler (C) (a glass fiber and/or a glass flake), relative to 100 parts by weight of a base resin (A). The flame retardant (B) comprises a polyphenylene oxide-series resin and/or a polyphenylene sulfide-series resin (B1), a phosphoric ester (B2), and a nitrogen-containing cyclic compound (B3) (for example, a polyphosphate of an amino group-containing triazine compound). The inorganic filler (C) has been treated with a surface-treatment agent or sizing agent containing a novolak epoxy resin. Such a resin composition is useful for obtaining a shaped article which has been inhibited from dripping and to which flame retardancy is highly imparted.
    Type: Grant
    Filed: November 28, 2002
    Date of Patent: October 3, 2006
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Patent number: 7091258
    Abstract: Particulate composite material with an average particle size of 20 to 50 ?m and a maximum content of particles with a size of <10 ?m of 10 wt.-% and its use for the preparation of dental materials.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: August 15, 2006
    Assignee: Ivoclar Vivadent AG
    Inventors: Roland Neubert, Karin Vogel, Ulrich Salz, Volker Rheinberger
  • Patent number: 7087302
    Abstract: The present invention relates to a sizing composition for use on glass fibers which are used to reinforce plastic resins used in the formation of fiber-reinforced plastics (FRPs). The sizing composition comprises a copolymer formed from at least one functional monomer that is selected from the group consisting of hydroxy, phenyl and alkoxylated functional groups. The glass fibers sized with the sizing composition of the invention have excellent computability with resins used in forming FRPs, as seen by a low level of white glass.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: August 8, 2006
    Assignee: Celanese International Corporation
    Inventors: Charles R. Key, Rajeev Farwaha
  • Patent number: 7026377
    Abstract: A process for producing a fiber-reinforced molded article and the resulting article such as a cantilevered battery tray. In the process, thermoplastic material in its solid state having a melt flow index above 25 g/10 minutes is fed into a suitable processing machine simultaneous with the addition of reinforcing fibers having a length of at least 0.375 inch or greater and sized with a material such as polyurethane, polyurea, and isocyanate derivatives thereof. The introduced materials are subjected to orientational agitation such that the reinforcing fibers are filamentized in an essentially homogeneous dispersion throughout the solid polymeric material. Once filamentization and dispersion are achieved, the resulting admixture is subjected to knead melting operations for an interval sufficient to achieve melting of the polymeric material introduced into a suitable plasticizing apparatus where the introduced material can be subjected to suitable knead melting operations.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: April 11, 2006
    Assignee: Mayco Plastics
    Inventor: Frank Grant
  • Patent number: 6890968
    Abstract: A dental composite having high filler loading and low shrinkage thereby providing good strength and marginal integrity. Through the use of prepolymerized filler particles in combination with a structural filler and a nanofiller, the composite exhibits very low shrinkage and is useful in stress bearing restorations and in cosmetic restorations. The structural filler used is ground to a mean particle size of less than 0.5 ?m and the nanofiller has discrete particles of a mean particle size less than 100 nm to improve handling and mechanical characteristics. The prepolymerized filler particles also allow for less viscosity and better handling characteristics of the composite.
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: May 10, 2005
    Assignee: Kerr Corporation
    Inventors: Christos Angeletakis, Minh-Dang Son Nguyen, Alvin I. Kobashigawa
  • Patent number: 6855440
    Abstract: A construction product made from an extrudable composition formed into various shapes for use in deck-building systems and other applications is disclosed. The extrudable composition prepared from polyethylene polymeric compounds, such as HDPE, and mixed with a mineral such as fiberglass, mineral wool or sand, along with a pigment, has sufficient strength and other advantageous properties to be useful for those construction applications.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: February 15, 2005
    Inventor: Paul Bracegirdle
  • Publication number: 20040266916
    Abstract: A flame-retardant resin composition comprises 10 to 300 parts by weight of a flame retardant (B) and 1 to 200 parts by weight of an inorganic filler (C) (a glass fiber and/or a glass flake), relative to 100 parts by weight of a base resin (A). The flame retardant (B) comprises a polyphenylene oxide-series resin and/or a polyphenylene sulfide-series resin (B1), a phosphoric ester (B2), and a nitrogen-containing cyclic compound (B3) (for example, a polyphosphate of an amino group-containing triazine compound). The inorganic filler (C) has been treated with a surface-treatment agent or sizing agent containing a novolak epoxy resin. Such a resin composition is useful for obtaining a shaped article which has been inhibited from dripping and to which flame retardancy is highly imparted.
    Type: Application
    Filed: May 20, 2004
    Publication date: December 30, 2004
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Patent number: 6822020
    Abstract: Modified silica fillers are prepared by contacting silica with blends or mixtures containing diorganodihalosilanes and tetrahalosilanes in weight ratios of 1:0.1 to 1:2, respectively. While dialkyldichlorosilanes and tetrahalosilanes such as dimethyldichlorosilane and silicon tetrachloride, respectively, are most preferred, the blends or mixtures may also comprise compositions containing other silanes such as mercaptopropyltriethoxysilane.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: November 23, 2004
    Assignee: Dow Corning Corporation
    Inventor: Anthony Revis
  • Patent number: 6737157
    Abstract: The present invention provides a coating type reinforcement composition of sheet metal which can be applied under warming for ensuring satisfactory levels of tensile rigidity and resistance to dent of a thin sheet metal mainly due to weight reduction of an automobile body, or for collision safety, and which improve a bending strength and a rigidity of the sheet metal without causing a distortion to the sheet metal. The coating type reinforcement composition of sheet metal according to the present invention comprises a liquid epoxy resin, a latent curing agent and an inorganic filler having an aspect ratio (L/D) of 5 or higher, an amount of the inorganic filler contained being 20 to 50% by weight and the composition being a viscous preparation with a high viscosity.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: May 18, 2004
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Masaki Ukai, Yutaka Sugiura, Mutsuhisa Miyamoto
  • Patent number: 6645620
    Abstract: The invention concerns a material based on halogenated thermoplastic resin, comprising long fibers, characterized in that at least one long fiber is in close contact with a polymer based on alkyl (meth)acrylate. The invention also concerns the methods for making such a material and its uses.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: November 11, 2003
    Assignee: Atofina
    Inventors: Carole Dupuy, Philippe Renouard, Régis Jacquemet
  • Patent number: 6646027
    Abstract: The invention relates to a thermoplastic resin with improved impact strength comprising a) a thermoplastic polyether sulfone resin and b) glass fibers treated with a polyolefin wax. The polyolefin wax may be polyethylene wax, polypropylene wax, polyethylene-propylene wax, or polyethylene-butylene wax. The polyethersulfone resin glass blend has high modulus and improved impact strength.
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: November 11, 2003
    Assignee: General Electric Company
    Inventor: Robert R. Gallucci
  • Patent number: 6620861
    Abstract: There are provided an inorganic filler, multi-functional filler, an organic compound filler, a modified filler, and a dental coloring filler suitable in use as a filler in a dental composition, compositions having a resin matrix of an organic polymer material, as well as a process for producing the same. Disclosed are an inorganic filler which comprises an inorganic fine particle, wherein the surface of the inorganic fine particle is covered with polysiloxane. Also disclosed is a multi-functional filler which comprises an inorganic fine particle containing an acid reactive element, wherein a cement reactive phase is formed on the surface of the inorganic fine particle, and the cement reactive phase is further covered with polysiloxane. Also disclosed is an organic compound filler which comprises an organic-inorganic polymer particle or an organic polymer particle, wherein the surface of the organic-inorganic polymer particle or an organic polymer particle is covered with an inorganic film.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: September 16, 2003
    Assignee: Kabushiki Kaisha Shofu
    Inventors: Toshiyuki Nakatuka, Yasuhisa Yasuda, Katsuya Kimoto, Mitsuharu Mizuno, Noriyuki Negoro
  • Patent number: 6613812
    Abstract: A dental composition is provided comprising (a) a part A comprising fluoroaluminosilicate glass that has been surface treated with agents selected from the group consisting of silane, silanol and combinations thereof, and at least one fatty acid, dimer thereof, or trimer thereof; and (b) a part B comprising at least one polyacid. The composition further comprises resin that can be curable or non-curable and at least one initiator. The composition exhibits adhesion to dentin, and the treated FAS glass contained therein does not settle out with time.
    Type: Grant
    Filed: January 3, 2001
    Date of Patent: September 2, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Hoa T. Bui, Brant U. Kolb, Sumita B. Mitra
  • Patent number: 6602932
    Abstract: Nanoparticle composites and nanocapsules for guest encapsulation and methods for synthesizing same. One synthesis method includes providing a nanoparticle template; and forming a shell on the nanoparticle template by polymerizing a monomer on the nanoparticle template to form a nanoparticle composite defined by the shell and the nanoparticle template. Another synthesis method includes providing a nanoparticle template; forming a shell on the nanoparticle template by polymerizing a monomer on the nanoparticle template; and dissolving the nanoparticle template to thereby form a hollow nanocapsule defined by the shell. Another synthesis method includes providing a nanoparticle template carrying a guest molecule; and forming a shell on the nanoparticle template by polymerizing a monomer on the nanoparticle template to thereby encapsulate the guest molecule.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: August 5, 2003
    Assignee: North Carolina State University
    Inventors: Daniel L. Feldheim, Stella M. Marinakos, David A. Shultz
  • Patent number: 6602933
    Abstract: In-organic fillers are modified by in-situ co-polymerization of vinyl silane and another vinyl monomer. Vinyl silane couples with the filler by Si—O bonds. The remaining vinyl groups on the surface of the treated fillers then co-polymerize with the other vinyl monomer. The modified in-organic fillers treated by the in-situ co-polymerization are subsequently used to fill the polymer matrix. Tensile and impact strength of filler-reinforced polymer composites are improved remarkably.
    Type: Grant
    Filed: October 5, 2001
    Date of Patent: August 5, 2003
    Assignee: The Hong Kong Polytechnic University
    Inventors: Chak Yin Tang, Xiao-lin Xie
  • Patent number: 6593420
    Abstract: A resin binder composition useful in the manufacture of fiber glass articles is described. The resin binder is formulated to exhibit increased stress tolerance (flexibility) and to enable the manufacture of fiber glass products with less dusting with minimal compromise of physical strength characteristics.
    Type: Grant
    Filed: August 10, 2000
    Date of Patent: July 15, 2003
    Assignee: Knauf Fiber Glass GmbH
    Inventor: Clarence Henry Helbing
  • Patent number: 6586517
    Abstract: The present invention provides a long fiber-reinforced polypropylene resin composition for a molded article which is improved in all of a mechanical strength, a rigidity and an impact resistance and excellent as well in a durability, in which the long fiber-reinforced polypropylene resin composition comprises a long fiber-reinforced propylene polymer composition comprising a propylene polymer modified with unsaturated carboxylic acid or an anhydride thereof and having an isotactic pentad ratio of 96% or more and a melt flow rate of 100 to 500 g/10 min, an alkaline earth metal compound, and a glass fiber; and a propylene-ethylene copolymer composition comprising a propylene-ethylene copolymer having a melt flow rate of 10 to 60 g/10 min and a nucleating agent.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: July 1, 2003
    Assignees: Mazda Motor Corporation, Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Koichi Saito, Toshimori Nakai, Takahiro Tochioka
  • Publication number: 20030092821
    Abstract: A storage stable aqueous dispersion useful in preparing sizing compositions for glass fibers contains a normally solid nucleating agent, a nonionic surfactant, and a base. The nucleating agent is a mixture of an aliphatic monocarboxylic acid and an aliphatic dicarboxylic acid. Also disclosed are the process of making the dispersion, and the use of the sized glass fibers in glass fiber reinforced polyolefin composites having improved mechanical properties such as tensile strength, flexural strength, and notched and unnotched IZOD.
    Type: Application
    Filed: November 21, 2001
    Publication date: May 15, 2003
    Inventor: Bing-Lin Chen
  • Patent number: 6544445
    Abstract: A fire-resistant composite substrate for use in making structural openings fire-resistant, the substrate containing: (a) elastically compressible particles; (b) at least one heat-activated expanding agent; (c) at least one heat-activated binder; and (d) a diisocyanate adhesive.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: April 8, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Robert Graf, Maria-Elisabeth Kaiser
  • Patent number: 6541541
    Abstract: An aqueous resin composition comprising a polyepoxy compound represented by formula (I): wherein n represents a number of from 0.1 to 20; Z represents a single bond, an alkylidene group having 1 to 4 carbon atoms or a sulfone group; and X represents a hydrogen atom or a glycidyl group, provided that at least 10% of nX's represent a glycidyl group, and water.
    Type: Grant
    Filed: September 18, 2001
    Date of Patent: April 1, 2003
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Kiyoshi Masamune, Naohiro Fujita, Ryo Ogawa, Koji Akimoto
  • Patent number: 6521693
    Abstract: Provided is a long fiber-reinforced polypropylene resin composition which provides a molded article excellent in a mechanical strength and an impact resistance and having a small anisotropy in a strength, so that it can suitably be used even for uses in medium-sized to large-sized molded articles. The long fiber-reinforced polypropylene resin composition comprises 40 to 85% by weight of (A) a long fiber-reinforced propylene homopolymer pellet shown below and 15 to 60% by weight of (B) a propylene base block copolymer resin having the MFR of 50 g/10 min or less: (A): a long fiber-reinforced propylene homopolymer pellet comprising, (A1): 20 to 64.9% by weight of a modified propylene homopolymer obtained by modifying a propylene homopolymer with unsaturated carboxylic acid or an anhydride thereof or a mixture of the above modified propylene homopolymer and an unmodified propylene homopolymer, wherein an MFR is 60 g/10 min or more, (A2): 0.
    Type: Grant
    Filed: February 28, 2001
    Date of Patent: February 18, 2003
    Assignees: Chisso Corporation, Chisso Petrochemical Corporation
    Inventors: Koichi Saito, Toshimori Nakai, Nobukazu Atsumi, Hitoshi Kuramochi