Abstract: Chrome-free aqueous size compositions containing quanternary salts reduce fuzz and fly in glass fiber gun roving. The roving particularly achieves a desirable ease and completeness of chopping in conventional chopping and spraying equipment for molding operations.

Abstract: A method for producing a high molecular weight aromatic polycarbonate composite material which comprisesa. coating the reinforcing material with a catalyst system which polymerizes aromatic cyclic carbonate oligomers to high molecular weight aromatic polycarbonate under appropriate conditions;b. contacting the catalyst system coated reinforcing material with a mixture of aromatic cyclic carbonate oligomers and;c. polymerizing the mixture of aromatic cyclic carbonate oligomers to high molecular weight aromatic polycarbonate.

Abstract: A glass fiber reinforced resin composition suitable as an injection molding material for automobile instrument panels. Essentially the resin composition is a blend of 55-77 wt % of a propylene-ethylene block copolymer at least partially modified by graft copolymerization with an unsaturated carboxylic acid or its derivative, 5-15 wt % of an ethylene-propylene rubber in which the content of ethylene is 60-85 wt % and 18-30 wt % of glass fiber having a filament diameter of 8-15 .mu.m. The melt flow index of the modified propylene-ethylene block copolymer and the Mooney viscosity of the ethylene-propylene rubber are strictly specified. The resin composition is pelletized from a melted state such that the glass fiber dispersed in the pellets is not smaller than 550 .mu.m and, preferably, not greater than 1100 .mu.m in mean filament length. This resin composition is good in moldability and provides instrument panels high in rigidity, in heat distortion resistance and also in impact resistance.

Abstract: Disclosed herein is a polypropylene-base resin composition obtained by heating at a temperature of 170.degree. C.-280.degree. C. a mixture containing a crystalline ethylene-propylene block copolymer having a specific composition, an ethylene-propylene copolymer rubber having a specific composition and viscosity, an inorganic filler having a specific particle size, and an organic peroxide, all in specified amounts. The thus-obtained polypropylene-base resin composition has high molding fluidity and are inexpensive and their moldings have excellent low-temperature impact resistance and paintability along with high stiffness. They are thus suitable for use in the production of large moldings such as automobile bumpers, fenders and body sidemembers.

Abstract: A novel inorganic filler-containing polyolefin resin composition exhibits high-level stiffness at a temperature in the vicinity of crystalline melting point of the matrix-forming polyolefin resin or even at a higher temperature. The composition comprises specified amounts of a matrix-forming polyolefin resin, a dispersion-phase-forming resin, and a fibrous or lamellate inorganic filler. In the composition, one end portion of an individual fiber or lamella of the fibrous of lamellate inorganic filler is embedded in the dispersion-phase-forming resin not uniformly miscible dispersed in the polyolefin resin and the other end portion of the individual fiber of lamella is also embedded in the dispersion-phase-forming resin located at a separate position, whereby the filler forms substantially a network structure via the dispersion-phase-forming resin.

Abstract: Disclosed is a glass fiber-reinforced composition, which comprises (A) 99-40 wt. % of a modified ethylene/propylene block copolymer having a polar monomer content of at least 0.05 wt. %, which is obtained by graft-modifying at least partially a crystalline ethylene/propylene block copolymer, in which the ethylene content is 3-15 wt. %, the melt flow rate is 0.1 to 70 g/10 min, the intrinsic viscosity of the portion soluble in p-xylene at normal temperature is 2.5-6 as measured in decalin at 135.degree. C. and the ethylene content of the portion insoluble in p-xylene at normal temperature is 1.5-10 wt. %, with a polar monomer and an organic peroxide in an extruder, (B) up to 20 wt. % of a polyolefin rubber, and (C) 1 to 45 wt. % of a surface-treated glass fiber. This composition gives a molded article having an excellent rigidity and impact resistance.

Abstract: Chrome-free aqueous size compositions containing quanternary salts reduce fuzz and fly in glass fiber gun roving. The roving particularly achieves a desirable ease and completeness of chopping in conventional chopping and spraying equipment for molding operations.

Abstract: This invention relates to fibre-reinforced or filled polyphenylene sulphide and to a process for the production thereof.

Abstract: A glass fiber reinforced resin composition is described, comprising the following components: (a) 30 to 98 parts by weight of a crystalline propylene polymer; (b) 2 to 30 parts by weight of a glass fiber having an average diameter of 10.mu. or less, the amount of a binder deposited being from 0.01 to 0.3% by weight; (c) 0 to 35 parts by weight of an ethylene-based rubber; (d) 0 to 30 parts by weight of at least one inorganic filler selected from talc, mica, calcium silicate and glass powder; and (e) 0 to 10 parts by weight per 100 parts by weight of the sum of the components (a) to (d) of a pigment comprising a coloring component and a dispersing component, the proportion of a coloring matter or matters having a Mohs hardness of 3.5 or more in the coloring component being less than 30% by weight. This composition is superior in high temperature stiffness, appearance, and pelletizability, and is satisfactory in an amount of warp of article or re-heating warp, and impact strength.

Abstract: Sound-insulating boards which are based on mineral fibers and thermoplastic binders and may or may not additionally contain fillers, flameproofing agents and water repellants contain, as the binder, from 4 to 20%, based on the weight of the mineral fibers, of polymers having a glass transition temperature of from 30.degree. to 80.degree. C. and consisting of not less than 60% by weight, based on the copolymer, of (meth)acrylates of 1 to 4 carbon atoms and as much as 40% by weight of acrylonitrile and/or styrene.

Abstract: Compositions of a vinylized epoxy resin, sized glass fibers and a complexing agent exhibit reduced fiber prominence upon curing with a metal composition than when employing no complexing agent.

Abstract: The shielding material of electromagnetic waves of the invention is formed f a polymeric material as the matrix and an inorganic powder, e.g. mica flakes, metallized on the surface of the particles with a metal, e.g. nickel, as the conductive dispersant in the matrix. The metallization of the inorganic powder is performed by chemical plating, preferably, after pretreatment with an organic compound having a functional group capable of capturing ions of a noble metal and then with a solution containing a noble metal, preferably, palladium. This pretreatment is effective to increase the firmness of bonding between the metallizing layer and the surface of the particles so that the shielding effect of the material is greatly improved.

Abstract: Conductive thermoplastic having high EMI shielding effectiveness comprise a thermoplastic condensation polymer and incorporated therein a synergistic combination of metal flake and conductive metal or metal coated fiber.

Abstract: A directly moldable resin composition for a composite plastic is disclosed, which comprises a predetermined amount of a mixture of pellets of a thermoplastic synthetic resin having an average size of 2.0 mm or larger and particles of a thermoplastic resin having an average size in a predetermined range, or particles of a thermoplastic resin alone having an average size of below 900 microns, and the balance of at least one filler such as particulate inorganic fillers or fibrous fillers. The particles of a thermoplastic resin should preferably be contained in an amount equal to or higher than 100% by volume of the at least one filler. When determined by a suspending tensile failure method at a tension speed of 2 mm/cm.sup.2, a particulate filler should preferably have an adhesion force in the range of below 4 g/cm.sup.2. Greater amounts of the mixture or the particles of thermoplastic resins can be used when the filler is treated on the surface thereof with organic compounds with a H.L.B.

Abstract: Under thermal aging conditions of reinforced polymeric materials, some reinforcements are not as effective as others in providing longevity for the fiber reinforced polymeric materials. A method is provided for incorporating an additional amount of antioxidant into the polymeric materials before the reinforcement is added to the polymeric materials or into an aqueous treating solution for the fibrous reinforcement. The antioxidant is of low volatility and good thermal resistance, and when added to the polymer directly is used in an amount greater than three parts per hundred parts of the polymer (PHR). When the antioxidant is added to the aqueous treating solution for treating the fibrous reinforcements, the antioxidant is in the form of an oil-in-water emulsion.

Abstract: Chrome-free aqueous sizing composition for glass fiber gun roving contains a mixture of emulsified film-forming polymers, titanium acetyl acetonate, silylated polyazamide, cationic lubricant and methacryloxypropylsilane.

Abstract: A polymer composite is produced by polymerizing an olefine monomer in the presence of a catalyst system obtained by treating a filler material with (a) an organic magnesium compound which contains halogen or (b) an organic magnesium compound and thereafter with a halogen-containing compound; and then with a transition metal compound, which is preferably titanium tetrachloride, adding an organic metal activator compound and continuing the polymerization to obtain a composite containing desired proportions of polymer and filler. The filler may be carbon, an aluminosilicate such as mica or talc, or glass-fibre. Homogeneous composites, in respect of the distribution of filler in various size fractions, can be obtained. Composites having good flow characteristics may be obtained. The composites may be formed directly into shaped articles by suitable shaping techniques. Alternatively, the composite may be blended with a polymeric material.

Abstract: A reinforced polymer composition comprising an epoxy resin matrix having intimately distributed therein, as the reinforcing component, a particulate or filamentary silicate or aluminosilicate mineral modified, prior to being admixed with matrix resin, by having a layer of an organic isocyanate chemically bonded to its surface by covalent bonding.

Abstract: An aqueous sizing composition with a cationic lubricant, amide compound, and water soluble or dispersible polyol which is used to produce wet chopped sized glass fiber strands. The sized wet or dried chopped glass fiber strands can be used to produce non-woven glass fiber strand mat, having good tensile strength, and good flexibility and reduced tendency for static generation. The wet chopped glass fiber strands also have good flowability in bulk handling apparatus.

Abstract: An aqueous sizing composition with a cationic lubricant, amide compound, and water soluble or dispersible polyol which is used to produce wet chopped sized glass fiber strands. The sized wet or dried chopped glass fiber strands can be used to produce non-woven glass fiber strand mat, having good tensile strength, and good flexibility and reduced tendency for static generation. The wet chopped glass fiber strands also have good flowability in bulk handling apparatus.

Abstract: An aqueous emulsion of a solid, water insoluble or limited water soluble organic peroxide is provided that has improved stability, dilutability and safety but still having an average particle size of 1.5 microns or less and a good particle size distribution. The emulsion has from about 10 weight percent of the emulsion of a solid peroxide selected from the group of hydroperoxides .alpha., -oxy and .alpha.-peroxy hydroperoxides, dialkyl peroxides, aldehyde and ketone peroxides, diacyl peroxides, peroxyesters, peroxy acids, peroxydicarbonates, monoperoxycarbonates and perketals.The emulsion also has a hydrocarbon solvent having a high kauri-butanol number if the organic peroxide has a substantial amount of aromaticity and a low kauri-butanol number if the organic peroxide has little or no aromaticity and one or more nonioic emulsifiers and at least about 20 weight percent of water.

Abstract: An aqueous emulsion of an organic peroxide that is liquid at a temperature of 20.degree. C. and that is insoluble or has limited solubility in water is provided that has improved shelf-stability, shear-stability and process stability and has good dilutability and has a particle size of around 1.5 microns or less. The emulsion has from about 1 weight percent of the emulsion to about 70 weight percent of the emulsion of an organic peroxide that is a liquid at 20.degree. C. and in particular that has a half-life exceeding 60 hours at 212.degree. F. (100.degree. C.) and 20 minutes at 300.degree. F. (149.degree. C.) The emulsion also has about 0.005 to about 15 weight percent of the emulsion of a nonionic emulsifier blend. The emulsifier blend has three emulsifiers selected from polyalkylene glycol ethers, dialkylaryl polyether alcohols, and polyoxy-propylene-polyoxyethylene condensates and the like nonionic emulsifiers having a particular HLB range for each of the three emulsifiers.

Abstract: An aqueous emulsion of an organic peroxide that is liquid at a temperature of 20.degree. C. and that is insoluble or has limited solubility in water is provided that has improved shelf-stability, shear-stability and process stability and has good dilutability and has a particle size of around 1.5 microns or less. The emulsion has from about 10 weight percent of the emulsion to about 70 weight percent of the emulsion of an organic peroxide that is a liquid at 20.degree. C. and in particular that has a half-life exceeding 60 hours at 212.degree. F. (100.degree. C.) and 20 minutes at 300.degree. F. (149.degree. C.). The emulsion also has about 0.005 to about 15 weight percent of the emulsion of a nonionic emulsifier blend. The emulsifier blend has three emulsifiers selected from polyalkylene glycol ethers, dialkylaryl polyether alcohols, and polyoxy-propylene-polyoxyethylene condensates and the like nonionic emulsifiers having a particular HLB range for each of the three emulsifiers.

Abstract: An aqueous alkaline dispersion of a rubbery graft or over polymerized copolymer of a diene and a vinyl pyridine on a polyacrylate seed (core or substrate), said acrylate polymer having a Tg of not above about -20.degree. C., desirably also containing a polybutadiene, and a water soluble, heat reactable phenolic resin, in certain amounts is useful in forming an adhesive for bonding glass fiber reinforcing elements or cords to rubber compounds or stocks. After dipping the glass fiber cord in the one-step adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing glass fiber cord is combined or laminated (calendered) with a curable rubber compound and the resulting assembly is cured to form a composite in which the glass fiber cord is bonded to the rubber by means of said adhesive.

Abstract: The invention provides dental materials in paste form consisting essentially of (a) 18 to 50% by weight of a polymerizable binder, (b) 20 to 65% by weight of a crosslinked bead polymer with an average particle size of 5 to 150 .mu.m and (c) 5 to 45% by weight of glass beads with an average particle size of 5 to 80 .mu.m. The pastes of the invention are outstandingly suitable as a dental filling material.

Abstract: A composite plastic material having improved shielding against electromagnetic interference is provided by injection molding a molding compound comprising elongated granules obtained by incorporating into a thermoplastic resin matrix metallized glass fibers together with carbon fibers.

Abstract: Glass fibers are treated with an aqueous treating composition having a lubricant and either a mixture of heat stable organic peroxide, vinyl-containing coupling agent and nonionic surfactant and optionally a film former such as polyvinylacetate or carboxylated compatible polymer film former like carboxylated polypropylene and an amino coupling agent. Other materials such as softeners, pigments and the like may be added to the aqueous treating composition. The treated glass fiber strands are used in the form of continuous glass strands or chopped strands or a mixture thereof to prepare glass fiber strand mat for use in reinforcing thermoplastic polymers. Thermoplastic polymers reinforced with mats made of the treated glass fiber strands of the present invention have improved stamping properties.

Abstract: A titanium dioxide pigment is provided for use in polymeric compositions comprising a pyrogenic titanium dioxide pigment which has been treated with an addition system comprising:(a) an organophosphate/alkanolamine addition product, and(b) a polyol.This invention provides for a novel method for treating a pyrogenic titanium dioxide pigment in order to reduce yellowing when such pigment is incorporated into a polymeric composition comprising adding to such pigment an addition system which comprises:(a) an organophosphate/alkanolamine addition product, and(b) a polyol.

Abstract: Coating compositions containing identifier particles are disclosed for the retrospective identification of articles. The compositions comprise a clear lacquer binder, visually-readable microparticles and reflective spotting particles. The reflective spotting particles facilitate location of the coating on the surface of the tagged article.

Abstract: This invention relates to polymer blends having improved hydrolytic stability which comprise, in admixture, (1) a linear aromatic polyester of monomer residues consisting essentially of residues of a dicarboxylic acid and a bisphenol, and (2) a SAN polymer.

Abstract: A radiation curable ink is provided which is convertible to a conductive coating when cured on the surface of a substrate. A particulated electrically conductive .[.metal containing.]. material is used in combination with an organic resin binder. Low temperature cure of the ink can be achieved with either actinic or ionizing radiation.