Inversion To Form Water-in-oil System Patents (Class 523/337)
  • Patent number: 11935705
    Abstract: The present invention is related to a polymer dispersion comprising first conductive polymer particles having a positive Z-potential and second conductive polymer particles having a negative Z-potential, a method of forming the polymer dispersion, a method of making a capacitor comprising the polymer dispersion and a capacitor comprising the polymer dispersion.
    Type: Grant
    Filed: September 20, 2022
    Date of Patent: March 19, 2024
    Assignee: KEMET Electronics Corporation
    Inventors: Victor Andoralov, Vania Pais, Débora Sá, Rui A. Monteiro
  • Patent number: 11718783
    Abstract: The invention concerns a method for preparing a dispersion of a hydrophilic phase in a lipophilic phase, comprising:—a hydrophilic phase comprising at least one water-soluble (co)polymer, —a lipophilic phase, —at least one interface polymer consisting of at least one monomer of formula (I): Formula (I) in which, —R1, R2, R3 are separately a hydrogen atom, a methyl group, a carboxylate group and Z—X, —Z is chosen from the group comprising C(?O)—O; C(?O)—NH; O—C(?O); NH—C(?O)—NH; NH—C(?O)—O; and a saturated or unsaturated, substituted or unsubstituted carbon chain comprising 1 to 20 carbon atoms capable of comprising one or more heteroatoms chosen from nitrogen and oxygen, —X is a group chosen from the alkanolamides, sorbitan esters, ethoxylated sorbitan esters, glyceryl esters, and polyglycosides; and comprising a saturated or unsaturated, linear, branched or cyclic, optionally aromatic, hydrocarbon chain.
    Type: Grant
    Filed: December 12, 2018
    Date of Patent: August 8, 2023
    Assignee: SNF GROUP
    Inventors: Olivier Braun, Lionel Lauber
  • Patent number: 11274242
    Abstract: Compositions comprising an acrylamide polymer emulsion and a nonionic surfactant suitable for use as friction reducers for hydraulic fracturing are disclosed. The nonionic surfactants include aralkylated phenol ethoxylates, amine ethoxylates, amidoamine ethoxylates, linear or branched alcohol EO/PO alkoxylates, ethoxylated alcohols, alkylphenol ethoxylates, and EO-capped poly(oxypropylene) block copolymers. Improved hydraulic fracturing processes in which an acrylamide polymer emulsion is used as a friction reducer are also described. In these processes, the surfactant is included in the composition with the acrylamide polymer friction reducer, or it is introduced separately into the process. The performance of low-cost polyacrylamide friction reducers can be boosted with a small proportion of certain readily available nonionic surfactants.
    Type: Grant
    Filed: February 24, 2020
    Date of Patent: March 15, 2022
    Assignee: STEPAN COMPANY
    Inventors: Brian Seymour-Loya, Aaron Sanders, Dawn Friesen, Gregory P. Dado
  • Patent number: 11220606
    Abstract: A water-in-oil coating composition comprising a water phase emulsified in a non-aqueous liquid phase, wherein the non-aqueous phase comprises one or more binders including an autoxidizable binder, characterized in that the composition has a solids content in the range of from 5 to 50 wt % and a water content in the range of from 40 to 90 wt %, and wherein the value A defined by the sum of the mass-average molecular mass of the one or more binders divided by 1,400, 1.7 times the solids content, and the water content, is at most 130, wherein the mass-average molecular mass is expressed in gram/mole and the solids content and the water content are each expressed in wt % based on the total weight of the composition.
    Type: Grant
    Filed: July 25, 2019
    Date of Patent: January 11, 2022
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Gerard Antonie Van Ewijk, Diana Lucia Santangelo, Matthijs Solleveld
  • Patent number: 10836667
    Abstract: A method of dewatering sludge is provided herein. In some embodiments, the method includes introducing micronized dry water soluble polymer (DWSP) particles into a sludge, wherein the sludge includes water and solids; separating water of the sludge from solids of the sludge using the micronized DWSP particles; and collecting a wet solid including water and solids of the sludge, wherein a concentration of solids in the wet solid is higher than a concentration of solids in the sludge, wherein the micronized DWSP particles comprise a DWSP wherein the DWSP is selected from the group consisting of a dry anionic water soluble polymer, a dry cationic water soluble polymer, a dry nonionic water soluble polymer, and mixtures thereof, and wherein a mean particle size of the micronized DWSP particles ranges from about 100 to about 300 microns.
    Type: Grant
    Filed: August 14, 2018
    Date of Patent: November 17, 2020
    Assignee: Water Mark Technologies, Inc.
    Inventors: Phillip B. Reilly, Jr., Kimberly S. Logsdon, Phillip B. Reilly, III
  • Patent number: 10209171
    Abstract: The present invention includes a method and an apparatus for determining the viscosity of a fluid. The apparatus comprising that includes a microchannel connected to a glass capillary in fluid communication with the microchannel, a digital camera positioned with respect to the glass capillary to capture two or more images of a fluidic slug as a fluid travels within the glass capillary, and a processor communicably coupled to the digital camera that determines a viscosity of the fluid based on the two or more digital images.
    Type: Grant
    Filed: December 9, 2014
    Date of Patent: February 19, 2019
    Assignee: Texas Tech University System
    Inventors: Siva A. Vanapalli, Deepak E. Solomon
  • Patent number: 8668915
    Abstract: Process for the preparation of a an inverse latex including from 20% to 70% by weight and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the polyelectrolyte is a copolymer of 2-acrylamido-2-methylpropanesulfonic acid partially or totally salified with acrylamide and optionally one or more monomers chosen from monomers containing a partially or totally salified weak acid function and/or from neutral monomers other than acrylamide, the production process including the control of the pH in the initial aqueous phase; Cosmetic, dermopharmaceutical or pharmaceutical composition including the inverse latex directly obtained by the process.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: March 11, 2014
    Assignees: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC, Scott Bader Company Limited
    Inventors: Olivier Braun, Paul Mallo, Audrey Bonnardel, Francois Guy
  • Patent number: 8512684
    Abstract: Process for the preparation of a composition including an oil phase, an aqueous phase, at least one emulsifying system of water-in-oil (W/O) type, optionally at least one emulsifying system of oil-in-water (O/W) type, in the form of an inverse latex including from 20% to 70% by weight and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the polyelectrolyte is a copolymer of 2-acrylamido-2-methylpropanesulfonic acid partially or totally salified with acrylamide and optionally one or more monomers chosen from monomers containing a partially or totally salified weak acid function and/or from neutral monomers other than acrylamide, the production process being characterized in that the preparation of the aqueous phase includes the dissolution in the aqueous medium of solid 2-acrylamido-2-methyl propanesulfonic acid before neutralization. Cosmetic, dermopharmaceutical or pharmaceutical composition including the inverse latex directly obtained by the process.
    Type: Grant
    Filed: October 15, 2008
    Date of Patent: August 20, 2013
    Assignees: Societe d'Exploitation de Produits pour les Industries Chimiques SEPPIC, Scott Bader Company Limited
    Inventors: Paul Mallo, Olivier Braun, Francois Guy, Audrey Bonnardel
  • Patent number: 8163838
    Abstract: A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 ?m, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: April 24, 2012
    Assignee: Kraton Polymers US LLC
    Inventors: Adrie A. Van Der Huizen, Marc S. Sonderman, Arwin W. Van Der Waal, Wouter De Jong, Anton Nicolai
  • Publication number: 20110245374
    Abstract: W/O/W multiple emulsions are disclosed having improved stability against coalescence and phase separation. When a silicone MQ resin is incorporated in the oil phase, a multiple emulsion can be easily made without stringent requirements on other emulsifiers used in the system.
    Type: Application
    Filed: December 3, 2009
    Publication date: October 6, 2011
    Applicant: DOW CORNING CORPORATION
    Inventors: Kathleen Barnes, Glenn Gordon
  • Publication number: 20100233108
    Abstract: Process for the preparation of a composition including an oil phase, an aqueous phase, at least one emulsifying system of water-in-oil (W/O) type, optionally at least one emulsifying system of oil-in-water (O/W) type, in the form of an inverse latex including from 20% to 70% by weight and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the polyelectrolyte is a copolymer of 2-acrylamido-2-methylpropanesulfonic acid partially or totally salified with acrylamide and optionally one or more monomers chosen from monomers containing a partially or totally salified weak acid function and/or from neutral monomers other than acrylamide, the production process being characterized in that the preparation of the aqueous phase includes the dissolution in the aqueous medium of solid 2-acrylamido-2-methyl propanesulfonic acid before neutralization. Cosmetic, dermopharmaceutical or pharmaceutical composition including the inverse latex directly obtained by the process.
    Type: Application
    Filed: October 15, 2008
    Publication date: September 16, 2010
    Applicant: SCOTT BADER COMPANY LIMITED
    Inventors: Paul Mallo, Olivier Braun, Francois Guy, Audrey Bonnardel
  • Patent number: 7745514
    Abstract: Disclosed are tinted, abrasion resistant coating compositions comprising polymer-enclosed color-imparting particles. Also disclosed are methods for making such a composition and substrates at least partially coated with a hard coat deposited from such a composition.
    Type: Grant
    Filed: December 7, 2006
    Date of Patent: June 29, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shan Cheng, Dennis L. Faler, W. David Polk
  • Publication number: 20100063180
    Abstract: Fire protection and/or fire fighting additives including a water-swellable polymer, a water immiscible phase, an emulsifier, an inverter, and a remainder water are disclosed. The water-swellable polymer is acrylamide-free and crosslinked and may be prepared by inverse phase polymerization. Such fire protection and/or fire fighting additives and fire protection and/or fire fighting compositions made using the additives exhibit exceptionally low corrosion properties. For example, when contacted with any one of a 2024-T3 aluminum alloy, 4130 steel, yellow brass, or AZ31B magnesium alloy, the corrosion rate is less than about 5 mils/yr for the fire protection and/or fire fighting additives.
    Type: Application
    Filed: September 5, 2008
    Publication date: March 11, 2010
    Inventors: Seungkoo Kang, Detlef Tholmann
  • Publication number: 20090029168
    Abstract: Water-swellable compositions, dispersions and polymer microparticles for their preparation as well as their manufactures and uses are described.
    Type: Application
    Filed: April 5, 2006
    Publication date: January 29, 2009
    Inventors: Martin Peter Butters, Malcolm Skinner, Beatrix Loehner, Ian Biggin
  • Patent number: 7351755
    Abstract: In a method of producing an oil-in-water type emulsion containing an internally crosslinked fine resin particle, the fine resin particle is encapsulated in an emulsion particle having an average particle diameter of 0.02 to 0.3 ?m. The method includes a step of undergoing phase transition from a water-in-oil type emulsion (Y) which includes a resin (A) having a cationic group or an anionic group, an acid or a base (B) neutralizing 20 to 150 mole percent of the cationic group or the anionic group in the resin (A), an internally crosslinked fine resin particle (C), having an average particle diameter of 0.01 to 0.2 ?m, dispersed in an oil phase and an aqueous medium (D) to an oil-in-water type emulsion (Z) by adding the aqueous medium (D) further to the water-in-oil type emulsion (Y).
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: April 1, 2008
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hitoshi Hori, Yasuhiro Hayashi, Seiko Inoue, legal representative, Hisaichi Muramoto, Tsuyoshi Inoue
  • Patent number: 7323507
    Abstract: Dispersion concentrates are claimed which consist of: I) 10-80% by weight of a crosslinked copolymer obtained by polymerization of 1 to 50% by weight of a cyclic N-vinylcarboxamide and 49.99 to 98.99 by weight of acryloyldimethyltauric acid, II) 20-90% by weight of a phase selected from the group consisting of an emulsifier, an oil phase, and mixtures thereof, and III) up to 30% weight water based on the total weight of the stable dispersion concentrate. The stable dispersion concentrate is useful in preparing cosmetic, pharmaceutical, and dermatological compositions.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: January 29, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Löffler, Roman Morschhäuser, Livio Caribé Da Rocha
  • Patent number: 7015279
    Abstract: A composition and method for a linear or crosslinked cationic polyelectrolyte, involving copolymerization of at least one cationic monomer with at least one neutral monomer and at least one nonionic surfactant monomer.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: March 21, 2006
    Assignee: Société d'Exploitation de Produits pour les Industries Chimiques (SEPPIC)
    Inventors: Olivier Braun, Paul Mallo, Hervé Rolland
  • Patent number: 6916864
    Abstract: The present invention refers to a high internal phase polyelectrolyte emulsions which are useful for the manufacture of superabsorbent polymers having two phases: i) a continuous oil phase and the ii) a dispersed aqueous phase containing the aqueous monomer solution prior to polymerization and the polyelectrolyte in water-soluble, or water-swellable or very slightly crosslinked form after polymerization, wherein the polymerization occurs in the dispersed aqueous phase and wherein the dispersed aqueous phase contains a high concentration of polyelectrolyte. The present invention also refers to a process for preparing such emulsions and for inverting these emulsions so as to form films or other patterns of the superabsorbent polymer. Absorbent structures containing SAP films or other patterns prepared by the present invention are also contemplated.
    Type: Grant
    Filed: May 18, 2004
    Date of Patent: July 12, 2005
    Assignee: Dow Global Technologies Inc.
    Inventors: Herbert A. Gartner, Steven W. Mork, Heike Herr, Reed A. Shick, John Klier, Christopher J. Tucker
  • Patent number: 6835783
    Abstract: The present invention refers to a high internal phase polyclectrolyte emulsions which are useful for the manufacture of superabsorbent polymers having two phases: i) a continuous oil phase and the ii) a dispersed aqueous phase containing the aqueous monomer solution prior to polymerization and the polyelectrolyte in water-soluble, or water-swellable or very slightly crosslinked form after polymerization, wherein the polymerization occurs in the dispersed aqueous phase and wherein the dispersed aqueous phase contains a high concentration of polyclectrolyte. The present invention also refers to a process for preparing such emulsions and for inverting these emulsions so as to form films or other patterns of the superabsorbent polymer. Absorbent structures containing SAP films or other patterns prepared by the present invention are also contemplated.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: December 28, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Herbert A. Gartner, Steven W. Mork, Heike Herr, Reed A. Shick, John Klier, Christopher J. Tucker
  • Publication number: 20040214961
    Abstract: The present invention refers to a high internal phase polyelectrolyte emulsions which are useful for the manufacture of superabsorbent polymers having two phases: i) a continuous oil phase and the ii) a dispersed aqueous phase containing the aqueous monomer solution prior to polymerization and the polyelectrolyte in water-soluble, or water-swellable or very slightly crosslinked form after polymerization, wherein the polymerization occurs in the dispersed aqueous phase and wherein the dispersed aqueous phase contains a high concentration of polyelectrolyte.
    Type: Application
    Filed: May 18, 2004
    Publication date: October 28, 2004
    Inventors: Herbert A. Gartner, Steven W. Mork, Heike Herr, Reed A. Shick, John Klier, Christopher J. Tucker
  • Publication number: 20020082375
    Abstract: A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product.
    Type: Application
    Filed: October 29, 2001
    Publication date: June 27, 2002
    Inventors: Kevin M. Andrist, John E. Blasko, Glenn C. Calhoun, Frederick C. Hansen, Dean R. Hellwig, Kurt A. Hessenius, Steven M. Hurley, D. Sunil Jayasuriya, Matthew G. Lee, Stephen J. Maccani, H. Thomas Mills, Gregory R. Peterson, Paul E. Sandvick, Dennis M. Wilson, John P. Wiruth
  • Patent number: 6410616
    Abstract: The present invention provides a process in which no surfactant is used, or even if the surfactant is used the amount thereof is as small as possible, thus stably obtaining a suspension to carry out a crosslinking reaction. A production process for a crosslinked polymer particle, comprising the steps of: forming a suspension in which liquid drops of a first phase are dispersed in a second phase by stirring both phases in the presence of an inorganic particle, wherein the first phase includes a high-molecular compound and a crosslinking agent, and wherein the first phase and the second phase are insoluble in each other, and wherein the affinity of the inorganic particle for water is different from that of the high-molecular compound; and carrying out a crosslinking reaction. Furthermore, an approximately spherical crosslinked polymer particle, which is free from a surfactant.
    Type: Grant
    Filed: April 7, 1999
    Date of Patent: June 25, 2002
    Assignee: Nippon Shokubai Co., LTD
    Inventors: Nobuyuki Harada, Masatoshi Nakamura, Shigenori Kirimura, Yoshifumi Adachi
  • Patent number: 6372204
    Abstract: A thickener comprises a water-in-oil reverse emulsion and a copolymer having moieties derived (i) from a monounsaturated monocarboxylic acid monomer containing from 3 to 5 carbon atoms, the monocarboxylic acid either being in free form or in the form of an inorganic salt, and (ii) from a monoacrylamide monomer. The copolymer is in solution in the aqueous phase constituting the emulsion, the oil phase of this emulsion consisting of a mixture of at least one volatile oil and at least one non-volatile oil. The weight ratio between the volatile oil and the non-volatile oil is between 90/10 and 10/90. The oil phase represents from 10 to 60% by weight of the whole. Water represents from 30 to 70% by weight of the whole. The copolymer represents from 10 to 30% by weight of the whole and a surfactant represents from 5 to 20% by weight of the whole.
    Type: Grant
    Filed: April 25, 2000
    Date of Patent: April 16, 2002
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques, S.E.P.P.I.C.
    Inventors: Nelly Michel-Lecocu, Chantal Amalric
  • Patent number: 6136305
    Abstract: A thickener comprises a water-in-oil reverse emulsion and a copolymer having moieties derived (i) from a monounsaturated monocarboxylic acid monomer containing from 3 to 5 carbon atoms, the monocarboxylic acid either being in free form or in the form of an inorganic salt, and (ii) from a monoacrylamide monomer. The copolymer is in solution in the aqueous phase constituting the emulsion, the oil phase of this emulsion consisting of a mixture of at least one volatile oil and at least one non-volatile oil. The weight ratio between the volatile oil and the non-volatile oil is between 90/10 and 10/90. The oil phase represents from 10 to 60% by weight of the whole. Water represents from 30 to 70% by weight of the whole. The copolymer represents from 10 to 30% by weight of the whole and a surfactant represents from 5 to 20% by weight of the whole.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: October 24, 2000
    Assignee: Societe d'Exploitation de Produits pour les Industries Chimiques, S.E.P.P.I.C.
    Inventors: Nelly Michel-Lecocu, Chantal Amalric
  • Patent number: 6096806
    Abstract: Epoxy resins, particularly those based on bisphenol A, can constitute the principal film forming polymer component of a storage stable autodepositable composition wherein the particle size distribution of all the film forming polymers in the composition satisfies certain criteria of size distribution, and an accelerator component which is an acid, oxidizing agent or complexing agent is present in amount sufficient to provide an oxidation-reduction potential at least 100 mV more oxidizing than a standard hydrogen electrode. Such dispersions can conveniently be prepared using a two stage process in which a solution of the film forming polymers is emulsified into water to form a preliminary dispersion and this preliminary dispersion is subjected to at least one particle size refinement stage in which the preliminary dispersion is forced through a narrow aperture.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: August 1, 2000
    Assignee: Henkel Corporation
    Inventors: Brian L. Mueller, Elizabeth J. Siebert
  • Patent number: 5928656
    Abstract: A thickener for products for topical application such as personal care products for application to the skin or hair, or topically administrable pharmaceutical preparations, comprises a water-in-oil emulsion containing polymeric material, at least 98% of which polymeric material is soluble in the aqueous phase. The polymeric material comprises units derived from (a) acrylamide, (b) 2-acrylamido-2-methylpropane-sulphonic acid (AMPS) and (c) a polyfunctional monomer, present in an amount of from 0.12 to 2 milliequivalents per mol of total monomer units. At least some of the AMPS units are in the form of a neutral salt such that the aqueous phase of the water in oil emulsion has a pH of at least 5.5.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: July 27, 1999
    Assignee: Scott Bader Company Limited
    Inventors: Arshad-Ul-Hag Chaudhry, Roman J Mikolajewicz
  • Patent number: 5908896
    Abstract: Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: June 1, 1999
    Assignee: The Regents of the University of California
    Inventors: Steven T. Mayer, Fung-Ming Kong, Richard W. Pekala, James L. Kaschmitter
  • Patent number: 5902842
    Abstract: A temperature sensitive material and method of preparing the same includes an oil-in-water emulsion in which the emulsifier type and content are controlled, as are the freezing point of the oil phase, the freezing point of the water phase, the oil-to-water ratio and the particle size of the oil phase and to which additives are introduced in the water phase, selected from the group consisting of a salt, glycerol and urea such that the material undergoes an irreversible optical change when subjected to a temperature above the reveal temperature of the emulsion.
    Type: Grant
    Filed: March 25, 1997
    Date of Patent: May 11, 1999
    Assignee: Sealed Air (NZ) Limited
    Inventors: Simon Neville Balderson, Robert John Whitwood
  • Patent number: 5880214
    Abstract: An emulsion ink for stencil printing is disclosed which enlarges the selection region of a body to be printed on, improves the handling property and adds a building-up feeling and a brilliance to the printed letters and others by developing the drying property, sticking tendency and preservation stability of the ink. The emulsion ink for stencil printing is characterized by using an oil-in-water type resin emulsion as a water phase in the water-in-oil type emulsion ink consisting of an oil phase and a water phase, and it is further characterized in that the minimum film-making temperature for the oil-in-water type resin emulsion described above is 40.degree. C. or less and its compound ratio is 2-45 wt.% as a reduced solid basis of the total amount of the avaiable emulsion ink.
    Type: Grant
    Filed: September 26, 1997
    Date of Patent: March 9, 1999
    Assignee: Riso Kagaku Corporation
    Inventor: Sadanao Okuda
  • Patent number: 5811485
    Abstract: The present invention relates to an adhesive kit comprising two packs and a method of manufacture of an adhesive composition therefrom. The kit comprises, in a first pack a water-continuous polymer emulsion and in a second pack a non-alkali activated inverse emulsion of a high molecular weight water soluble synthetic polymer. The method of manufacture of the adhesive requires mixing for short periods with hand stirring. The adhesive composition formed is particularly, but not exclusively useful as an adhesive for hanging wallpaper.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: September 22, 1998
    Assignee: Polycell Products Ltd.
    Inventors: Ronald Scott Charnock, Derrick Frederick Deamer, James Duncan Holloway
  • Patent number: 5624996
    Abstract: Disclosed is a dispersion of fine particles of modified polyethylene, which comprises a hydrocarbon organic solvent and fine particles of an ethylene polymer or ethylene polymer composition dispersed in the solvent, wherein the ethylene polymer or ethylene polymer composition has an acid value of 0.3 to 75 mg-KOH/g as a whole and a crystallinity of at least 45% as determined by the X-ray diffractometry and has an average dispersed particle size of 0.3 to 20 .mu.m and a concentration of 15 to 60% by weight.
    Type: Grant
    Filed: May 31, 1995
    Date of Patent: April 29, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Akio Morinaga, Takeo Kigami, Kunihiko Yorihiro, Toshihiko Okada
  • Patent number: 5508341
    Abstract: Organic aerogel microspheres which can be used in capacitors, batteries, thermal insulation, adsorption/filtration media, and chromatographic packings, having diameters ranging from about 1 micron to about 3 mm. The microspheres can be pyrolyzed to form carbon aerogel microspheres. This method involves stirring the aqueous organic phase in mineral oil at elevated temperature until the dispersed organic phase polymerizes and forms nonsticky gel spheres. The size of the microspheres depends on the collision rate of the liquid droplets and the reaction rate of the monomers from which the aqueous solution is formed. The collision rate is governed by the volume ratio of the aqueous solution to the mineral oil and the shear rate, while the reaction rate is governed by the chemical formulation and the curing temperature.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: April 16, 1996
    Assignee: Regents of the University of California
    Inventors: Steven T. Mayer, Fung-Ming Kong, Richard W. Pekala, James L. Kaschmitter
  • Patent number: 5504129
    Abstract: The specification discloses an aqueous dispersion for coatings consisting essentially of water and a water dispersible component, wherein the water dispersible component is provided by reacting maleic anhydride with a rosin ester to provide a maleated rosin ester, adding wax and preferably also an ethylene vinyl acetate copolymer to the maleated rosin ester, and adding a tertiary amino alcohol to the mixture to yield the water dispersible component as a reaction product thereof. When used in a coating formulation for paper, clay and/or latex may be added to the formulation. In one preferred embodiment, the dispersion is applied as a coating to paper to enhance toner adhesion to the surface of the paper while also providing a relatively low friction surface.
    Type: Grant
    Filed: December 8, 1993
    Date of Patent: April 2, 1996
    Assignees: International Paper Company, Arizona Chemical Company
    Inventors: Gary F. Dandreaux, John T. Geoghegan, Long S. Wang, Lori S. Slovik, John H. Hung
  • Patent number: 5380771
    Abstract: Acrylic polymer aqueous dispersions and a method of making such dispersions are described.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: January 10, 1995
    Assignee: Cargill Incorporated
    Inventor: Joseph L. Nothnagel
  • Patent number: 5356988
    Abstract: Aqueous dispersions of amine and ammonia salts of acrylic polymers having an acid value of from about 15 to about 100 and less than 2 weight percent organic solvent and a method of making such dispersions are described.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: October 18, 1994
    Assignee: Cargill, Incorporated
    Inventor: Joseph L. Nothnagel
  • Patent number: 5319019
    Abstract: Aqueous dispersions of an ammonia salt of an acrylic polymer and a method of making such dispersions are described.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: June 7, 1994
    Assignee: Cargill Incorporated
    Inventor: Joseph L. Nothnagel
  • Patent number: 5258425
    Abstract: A solvent-free adhesive formulation and a method for producing the adhesive is disclosed, the method involving dissolving resin in a heated oil and adding a surfactant thereto for dispersion purposes. Water is added to the resultant mixture to form an emulsion. A caustic agent is added to stabilize the emulsion and latex and thickener are added to the emulsion at ambient temperature. A stable, solvent-free adhesive is produced having superior bond strength and aging characteristics.
    Type: Grant
    Filed: May 23, 1991
    Date of Patent: November 2, 1993
    Assignee: Capitol Adhesives, Inc.
    Inventor: Lisa M. Kirby
  • Patent number: 5236996
    Abstract: Stable aqueous dispersions of finely divided piperazine-containing polyamide resin particles and methods for the manufacture thereof are provided. Dispersions according to this invention find use in hot melt adhesives, coatings, inks, and the like.
    Type: Grant
    Filed: July 24, 1991
    Date of Patent: August 17, 1993
    Assignee: Union Camp Corporation
    Inventor: George A. Smith
  • Patent number: 5124376
    Abstract: A method of rapidly dissolving a water-soluble polymer into water. A water-in-oil latex having the polymer dispersed in the water phase thereof is added to the water. Phenol (C.sub.6 H.sub.5 OH) is added to the water in an amount sufficient to promote rapid inversion of the latex and release of the polymer into the water. When used in connection with certain latexes, phenol also functions to increase the viscosity of the water by as much as three times or more that achieved by complete inversion of the latex and release of the polymer into the water alone.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: June 23, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Earl Clark, Jr.
  • Patent number: 4977208
    Abstract: (A) Water-absorbent coating compositions comprising (1) a nonaqueous dispersion of a resin, or a solution of a resin, and (2) a water-in-oil type emulsion of a water-swellable polymer with an average particle size not greater than 10 .mu.m; and a process for coating the same which uses a proper primer. (B) Water-absorbent coating compositions which comprise 100 parts by weight (on dry basis) of a resinous solution and 10 to 150 parts by weight (on solid basis) of a dehydrated water-in-oil type emulsion of a water-swellable polymer with an average particle size not greater than 10 .mu.m and which gives coated film with an elongation not lower than 30%.
    Type: Grant
    Filed: May 16, 1989
    Date of Patent: December 11, 1990
    Assignee: Mitsui-Cyanamid, Ltd.
    Inventors: Yoshio Hosoya, Naotaka Watanabe, Isao Takagi, Atsuo Miyoshi
  • Patent number: 4942189
    Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; the admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken).
    Type: Grant
    Filed: July 31, 1989
    Date of Patent: July 17, 1990
    Assignee: Exxon Research and Engineering Company
    Inventors: Dennis G. Peiffer, Robert D. Lundberg, Ilan Duvdevani
  • Patent number: 4925884
    Abstract: The present invention relates to a process for the production of concentrated, water-soluble or water swellable emulsion polymers by the polymerization of at least one water-soluble monomer in a water-in-oil dispersion by means of polymerization initiators, preferably in presence of bi- or multi-function vinyl- or allyl compounds in which a water-in-oil dispersion of the starting monomers is polymerized while being stirred so that the heat of polymeriaation is eliminated by distillation removal of the water contained in the reaction mixture. The polymerisation temperature is preferably adjusted and controlled by means of the pressure in the system.
    Type: Grant
    Filed: February 13, 1987
    Date of Patent: May 15, 1990
    Assignee: Chemische Fabrik Stockhausen GmbH
    Inventors: Wolfgang Hubner, Otto Schroers
  • Patent number: 4753981
    Abstract: A water-in-oil emulsion polymerization process is provided for preparing water-in-oil latexes of water-soluble polymers of ethylenically unsaturated monomers. The process utilizes as a chain transfer agent a thiol having the formula HS-Y(Z).sub.x wherein Y is a hydrocarbyl radical having 2-5 carbons and a valence of x+1; Z is selected from the group consisting of --OH, --CO.sub.2 H and --CO.sub.2 R wherein R is an alkyl radical of 1-3 carbon atoms; x is an integer of 1 or 2 and wherein the total number of carbon atoms per molecule of the thiol is 2-7.
    Type: Grant
    Filed: April 1, 1987
    Date of Patent: June 28, 1988
    Assignee: Phillips Petroleum Company
    Inventor: Earl Clark, Jr.
  • Patent number: 4743648
    Abstract: Water-in-oil compositions having a continuous oil phase comprising a silicone and a hydrocarbon cleaning component, a discontinuous water phase, comprise as emulsifier an organopolysiloxane of the formulaZ(Me).sub.2 SiO[(Me).sub.2 SiO].sub.x [(Me)(R)SiO].sub.y [(Me)(QR')SiO].sub.z --Si(Me.sub.2)Zwhere Me denotes methyl, Q a polyoxyalkylene radical, R a C.sub.6 -C.sub.16 alkyl radical, R' an alkylene and Z a monovalent radical. The organopolysiloxane allows stability and easy emulsification of water into an oil phase comprising those silicones and hydrocarbons which are preferred in polishes.
    Type: Grant
    Filed: April 24, 1986
    Date of Patent: May 10, 1988
    Assignee: Dow Corning, Ltd.
    Inventors: Michael P. L. Hill, Luc J. R. Vandamme
  • Patent number: 4739009
    Abstract: Bead polymers are prepared by reverse suspension polymerization by a process in which an aqueous solution of water-soluble ethylenically unsaturated monomers are polymerized in an aliphatic hydrocarbon using an inorganic suspending agent based on a modified finely divided mineral and, in addition, from 0.1 to 5% by weight, based on the monomers used, of a nonionic surfactant, in the presence of a polymerization initiator, with the formation of a water-in-oil polymer suspension.
    Type: Grant
    Filed: April 10, 1987
    Date of Patent: April 19, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Wilfried Heide, Heinrich Hartmann, Christos Vamvakaris
  • Patent number: 4698395
    Abstract: A process of purifying maleic anhydride graft polyolefin comprising the steps of adding an aqueous solution of alkali initial hydroxide to a solution of maleic anhydride graft polyolefin containing unreacted maleic anhydride which is dissolved in an organic solvent at a temperature from 80.degree. C. to 160.degree. C., thereby precipitating maleic anhydride graft polyolefin particles to make a W/O emulsion; stirring the W/O emulsion while maintaining the temperature at a same temperature as above for less than 2 hours, thereby selectively forming the alkali metal salt of unreacted maleic anhydride; adding the aqueous solution of alkali metal hydroxide to the W/O emulsion to convert the W/O emulsion into an O/W emulsion; separating the maleic anhydride draft polyolefin particles, and washing the maleic anhydride graft polyolefin particles with water.
    Type: Grant
    Filed: May 14, 1986
    Date of Patent: October 6, 1987
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Takayuki Inoue, Masafumi Hattori, Kazuhide Hayama, Riichiro Maruta
  • Patent number: 4650827
    Abstract: In an improved water-in-oil emulsion of the type which contains one or more finely divided water soluble vinyl addition polymers, one or more water soluble water-in-oil emulsifying agents, a hydrocarbon liquid and an aqueous phase, the improvement comprising an aqueous phase ranging from about 30% to about 50% by weight of the emulsion.
    Type: Grant
    Filed: November 2, 1983
    Date of Patent: March 17, 1987
    Assignee: Allied Corporation
    Inventors: Larry W. Becker, Benjamin Shultes, III
  • Patent number: 4647603
    Abstract: The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming two solvent systems of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent systems, a viscosity of both solvent systems being less than about 1,000 cps; dissolving an anionic polymer such as neutralized sulfonated polymer (water insoluble) in one of the solvent systems to form a first solution, and dissolving a cationic polymer such as a copolymer of vinyl pyridine, a concentration of the neutralized sulfonated polymer in the first solution being about 0.2 to about 10 weight percent, a concentration of the copolymer or vinyl pyridine in the second solution being about 0.
    Type: Grant
    Filed: June 26, 1985
    Date of Patent: March 3, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Robert D. Lundberg, Ilan Duvdevani, Dennis G. Peiffer
  • Patent number: 4639491
    Abstract: A dispersion for the water-in-oil suspension polymerization is stabilized by a stabilizer comprising a polymer having 70 to 99 mole percent of a lipophilic, ethylenically unsaturated monomer units and 1 to 30 mole percent of ethylenically unsaturated monomer units having a cationic group.
    Type: Grant
    Filed: December 12, 1985
    Date of Patent: January 27, 1987
    Assignee: Kao Corporation
    Inventors: Akihiro Kondo, Rikio Tsushima, Yuzo Sumida
  • Patent number: 4619967
    Abstract: Multi-modal emulsions comprise a continuous oil phase and a discontinuous aqueous phase having two or more droplet size distributions and comprising a water-soluble polymer. Such emulsions are prepared by subjecting portions of the emulsion to varying rates of shear during emulsion formation. The multi-modal emulsions can have high polymer solids, reduced oil content, low bulk viscosity and high stability.
    Type: Grant
    Filed: November 2, 1984
    Date of Patent: October 28, 1986
    Assignee: The Dow Chemical Company
    Inventors: Richard R. Emerson, Do I. Lee, James P. Easterly