Polymer Derived From Ethylenic Reactant Only Derived From Reactant Containing Oxygen Heterocycle Patents (Class 523/410)
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Patent number: 4477609Abstract: An improved, stabilized container coating composition of an amine solubilized hydrosol resin solution of:(a) an acrylic-poly(vinyl acetal) co-resin having a number average molecular weight above 10,000 and a glass transition temperature of -20.degree. C. to +60.degree. C.;(b) an epoxy resin having a molecular weight of 300 to 8,000; and on the average 2 or less than 2 epoxy groups per molecule; and(c) an aminoplast, a phenolplast resin, or combination thereof.Type: GrantFiled: July 20, 1983Date of Patent: October 16, 1984Assignee: Inmont CorporationInventors: Patrick F. Aluotto, Paul A. Drees, Charles A. Soucek
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Patent number: 4454264Abstract: Paint coating material capable of cathodic deposition based on a vehicle mixture that has been made water-thinnable with acid and optionally customary additives, wherein said vehicle contains in combination(A) from 50 to 90% by weight of a polymer and/or polycondensate containing tertiary amino-groups and OH groups and having amine and hydroxy numbers of from 30 to 170 and 30 to 300 respectively;(B) from 5 to 40% by weight of a fully blocked polyisocyanate which is stable in the aqueous phase and becomes reactive again under the influence of heat, after dissociation of the blocking group; and(C) from 0 to 30% by weight of polymer and/or polycondensate containing primary and/or secondary OH- and/or amino-groups.Type: GrantFiled: July 2, 1981Date of Patent: June 12, 1984Assignee: Herberts Gesellschaft mit beschrankter HaftungInventors: Hans-Peter Patzschke, Armin Gobel
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Patent number: 4446259Abstract: A coating composition having a liquid carrier and a binder of a blend ofa. an acrylic polymer containing glycidyl groups andb. a crosslinkable polysiloxane having attached to the silicone atoms of its backbone alkyl groups, phenyl groups and hydroxyl groups;optionally, a fluorocarbon polymer can be added to the composition;the composition cures at ambient temperatures and provides a finish that is durable, weatherable and heat resistant and is particularly useful for coating pipes, tanks, vessels and stacks of plants and refineries that are subjected to weathering, chemicals and heat.Type: GrantFiled: September 30, 1982Date of Patent: May 1, 1984Assignee: E. I. Du Pont de Nemours and CompanyInventor: Joseph A. Vasta
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Patent number: 4435529Abstract: Novel compositions of matter comprising a reaction product of a tannin and epoxy material are hereby provided. The novel reaction products can be dispersed in an aqueous or solvent medium for use as a treating or coating composition which imparts excellent corrosion resistance to metals and exhibits excellent substrate and intercoat adhesion.Type: GrantFiled: February 11, 1982Date of Patent: March 6, 1984Assignee: PPG Industries, Inc.Inventors: Alan J. Kaylo, Nicholas T. Castellucci
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Patent number: 4427804Abstract: A monosecondary amine containing blocked primary amine groups is provided by reacting a monosecondary amine containing at least one primary amine group (such as diethylene triamine) with a ketone which is hindered to prevent reaction with secondary amino hydrogen atom (such as methyl isobutyl ketone) while removing water. This product disperses in water with the aid of a solubilizing acid to provide a solution which will emulsify a liquid polymer dispersed therein. The water hydrolyzes the blocked primary amine groups to restore reactivity. This product can also be reacted with 1,2-oxirane or isocyanate-functional polymers to provide products which are dispersible in water with a solubilizing acid. These dispersions will electrodeposit at the cathode.Type: GrantFiled: March 1, 1982Date of Patent: January 24, 1984Assignee: DeSoto, Inc.Inventors: Anthony J. Tortorello, Mary A. Kinsella
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Patent number: 4423168Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two beta-amido ester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.Type: GrantFiled: July 29, 1981Date of Patent: December 27, 1983Assignee: PPG Industries, Inc.Inventor: Joseph T. Valko
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Patent number: 4423169Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two beta- and/or gamma-ester ester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.Type: GrantFiled: July 29, 1981Date of Patent: December 27, 1983Assignee: PPG Industries, Inc.Inventor: Joseph T. Valko
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Patent number: 4423167Abstract: Coating compositions comprising a polymeric polyol with a polyester crosslinking agent having at least two beta-alkoxyester groups per molecule are disclosed. The compositions, when applied to a substrate and cured in the presence of a transesterification catalyst, give solvent-resistant coatings.Type: GrantFiled: July 29, 1981Date of Patent: December 27, 1983Assignee: PPG Industries, Inc.Inventor: Joseph T. Valko
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Patent number: 4421569Abstract: Polymeric coatings are provided on steel pipes to protect the same against corrosion. Monomers and prepolymers are permanently adhered to the surface of steel pipes by graft polymerization to form a barrier which keeps out moisture, oxygen and other corrosive gases from the steel substrate. The monomers and prepolymers are chosen to provide a low moisture vapor transmission rate and oxygen permeability.Type: GrantFiled: May 7, 1982Date of Patent: December 20, 1983Assignee: Sharon Tube Corp.Inventors: Michael Dichter, Carl Horowitz
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Patent number: 4415700Abstract: Hydrophilic latex particles consisting of a homo- or co-polymer of monomers which are sparingly soluble in water, which hydrophilic latex particles can be prepared by emulsion polymerization in the presence of a water-soluble, radical-forming initiator but without an addition of an emulsifier, stabilizer or wetting agent. A process for the preparation of these hydrophilic latex particles, wherein a monomer which is sparingly soluble in water or several monomers which are sparingly soluble in water are dispersed in water and, with the exclusion of oxygen, for example in an inert atmosphere, are homo- or co-polymerized by emulsion polymerization in the presence of a water-soluble, radical-forming initiator but without any addition of an emulsifier, stabilizer or wetting agent.A diagnostic agent containing these hydrophilic latex particles as carrier and biologically and/or immunologically active substances covalently bound to this carrier either directly or via a coupling agent as a bridge.Type: GrantFiled: December 16, 1981Date of Patent: November 15, 1983Assignees: Boehringer Mannheim GmbH, Tschechoslowakische Academie der WissenschaftenInventors: Hans-Georg Batz, Paul Tanswell, Manfred Baier, Karel Bouchal, Jaroslav Kalal, Frantisek Svec, Eva Zurkova
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Patent number: 4410645Abstract: Sized glass fibers are provided that enables the production of sized glass fibers having improved filamentization. When these sized glass fibers are used for reinforcing polymeric materials the reinforced polymeric materials having good mechanical properties such as tensile strength and compaction without fuzz, fly or static properties of the strands. The reinforced polymeric materials and other improvements of the present invention eminate from the use of an interaction product of an epoxidized polar thermoplastic copolymer and an amino organo silane coupling agent in an aqueous sizing composition that also contains a predominant amount of a cross-linkable film former. The aqueous sizing composition has one or more cross-linkable film formers, one or more organo silane coupling agents and about 2 to about 12 weight percent of an interaction product of an unhydrolyzed or partially hydrolyzed amino organo silane coupling agent and an epoxidized polar thermoplastic copolymer.Type: GrantFiled: March 29, 1982Date of Patent: October 18, 1983Assignee: PPG Industries, Inc.Inventors: Balbhadra Das, L. Dow Moore
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Patent number: 4360632Abstract: This invention relates to an improvement in a process for producing a latex containing dispersed polymer. The improvement in the process for polymerizing a reaction mixture of vinyl monomer, stabilizer, oxidizing agent and reducing agent comprises using a water-soluble ketone bisulfite as the reducing agent, either alone or with other reducing agents, the ketone having from 3 to 8 carbon atoms in the structure. During the polymerization, the ketone bisulfite is maintained in stoichiometric excess of the oxidizing agent. Vinyl acetate-ethylene copolymers are some of the preferred polymer systems produced.Type: GrantFiled: October 23, 1981Date of Patent: November 23, 1982Assignee: Air Products and Chemicals, Inc.Inventors: Robert K. Pinschmidt, Jr., Finn L. Marten
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Patent number: 4338233Abstract: An aqueous sizing composition, method of preparing same and sized glass fibers are provided that enables the production of sized glass fibers having improved filamentization. The aqueous sizing composition has one or more cross-linkable film formers, one or more organo silane coupling agents and about 2 to about 12 weight percent of an interaction product of an unhydrolyzed or partially hydrolyzed amino organo silane coupling agent and an epoxidized polar thermoplastic copolymer. The epoxy copolymer has about 2 to about 12 parts of monomer with epoxy functionality per 100 parts of copolymer. Also the epoxy copolymer has a glass transition temperature (Tg) of from -10.degree. C. to about 70.degree. C. The unhydrolyzed or partially hydrolyzed amino silane coupling agent is contacted with the epoxidized copolymer, where the copolymer has a percent solids in the range of about 15 to about 60 weight percent.Type: GrantFiled: June 15, 1981Date of Patent: July 6, 1982Assignee: PPG Industries, Inc.Inventors: Balbhadra Das, L. Dow Moore
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Patent number: 4333865Abstract: Aqueous emulsions and a process for producing aqueous emulsions useful in air drying and stoving paints with improved stability over long periods are described. Fatty acid esters carrying ether-like bound polyethyleneglycol radicals are reacted with conventional alkyd resin raw materials to provide an alkyd resin intermediate which is esterified with an acidic vinyl copolymer carrying methacrylic acid and oil fatty acid radicals. The excellent stability characteristics of the products, despite the relatively low content of polyglycol of from 3 to 8%, is believed due to the substantially unsaponifiable linkage of the stabilizing groups to the resin molecule.Type: GrantFiled: November 10, 1980Date of Patent: June 8, 1982Assignee: Vianova Kunstharz, A.G.Inventor: Bertram Zuckert
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Patent number: 4328144Abstract: Room temperature curable latices can be produced by copolymerizing ketimine derivative ethylenically unsaturated monomers with conventional ethylenically unsaturated monomers in an emulsion process at a controlled pH greater than about 7.2 to produce a coagulum-free latex containing blocked amine (--NH.sub.2) groups. In use, the pH of the latex can be adjusted to acidic below 7 to generate unblocked reactive amino groups which can be cured or cross-linked at about room temperature with water-dispersed polymers such as epoxy, double bond or isothiocyanate containing polymers.Type: GrantFiled: March 17, 1980Date of Patent: May 4, 1982Assignee: SCM CorporationInventor: James T. K. Woo