Solid Polymer Derived From Ethylenic Reactants Only (includes In Situ Reactants From Plural 1,2-epoxides) Patents (Class 523/406)
- Polymer derived from ethylenic reactant only derived from reactant containing oxygen heterocycle (Class 523/410)
- Polymer derived from ethylenic reactants only derived from reactant containing nitrogen (Class 523/411)
- Polymer from ethylenic reactants only derived from reactant-containing carboxylic acid ester (Class 523/412)
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Patent number: 11149108Abstract: The present invention relates to formulations including a self-assembly monomer. In particular embodiments, the self-assembly monomer provides a thermoset having beneficial viscoelastic properties for printing methodologies. Methods of making and using such formulations are also provided.Type: GrantFiled: June 26, 2019Date of Patent: October 19, 2021Assignee: National Technology & Engineering Solutions of Sandia, LLCInventors: Kylie Manning, Mathias C. Celina, Adam Cook
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Patent number: 10190228Abstract: Copper electroplating baths and methods enable the plating of photoresist defined megafeatures at high current densities which have substantially uniform morphology and reduced nodule development. The copper electroplating baths include a mixture of heterocyclic nitrogen containing copolymers which provide megafeatures having a good % TIR and % WID balance.Type: GrantFiled: March 7, 2017Date of Patent: January 29, 2019Assignee: Rohm and Haas Electronic Materials LLCInventors: Matthew Thorseth, Rebecca Hazebrouck, Mark Scalisi, Zuhra Niazimbetova, Joanna Dziewiszek
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Patent number: 10118986Abstract: The disclosure relates to curable polyepoxysilane compounds and compositions, methods related to curing of such compounds via hydrolysis and/or condensation to form coatings on a substrate, and coated articles formed from the curable polyepoxysilane compounds. The polyepoxysilane compounds are silane-functional precursors and can be used as coatings (or pretreatments) on various substrates (e.g., metals such as aluminum) and provide a substantial improvement in corrosion resistance relative to other anti-corrosion coatings. The silane-functional precursors can be prepared by reaction of functional silanes (e.g., amino-functional silanes or other epoxide-reactive functionalized silanes) with epoxide-containing organic or hydrocarbon compounds and oligomers/polymers thereof (e.g., glycidyl-type ethers or other epoxide-/oxirane-functionalized hydrocarbon compounds), for example including hydrocarbons with one or more aromatic hydrocarbon groups (e.g., in an aromatic polyether).Type: GrantFiled: March 10, 2014Date of Patent: November 6, 2018Assignee: EASTERN MICHIGAN UNIVERSITYInventor: Vijaykumar M. Mannari
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Patent number: 10053594Abstract: The present invention includes coating compositions having a microgel, wherein the microgel is prepared from a carboxyl functional polymer and a hybrid crosslinker system, wherein the hybrid crosslinker system has a first crosslinker having an epoxy resin and a second crosslinker having a thermally active crosslinker.Type: GrantFiled: March 11, 2014Date of Patent: August 21, 2018Assignee: Akzo Nobel Coatings International B.V.Inventor: Gary Pierce Craun
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Patent number: 10041182Abstract: Reaction products of one or more amino acids and one or more epoxies are included in copper and copper alloy electroplating baths to provide good throwing power. Such reaction products may plate copper and copper alloys with good surface properties and good physical reliability.Type: GrantFiled: April 12, 2017Date of Patent: August 7, 2018Assignee: Rohm and Haas Electronic Materials LLCInventors: Zuhra I Niazimbetova, Maria Anna Rzeznik
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Patent number: 9975282Abstract: Described are: an active-energy-ray-curable composition (38) containing a phosphate ester compound of which an aqueous solution prepared by extracting with 50 mL of water per 1 g of the phosphate ester compound has a pH value of 6.5 to 7.5 at 25° C., wherein the value of (the concentration of phosphoric acid in the aqueous solution, expressed in mass ppm)×(the content of the phosphate ester compound in the active-energy-ray-curable composition, expressed in mass %) is 50 or less; and a process for producing a transparent film (40) which includes the active-energy-ray-curable composition (38) and in which a cured resin layer (44) having a fine uneven structure is formed on the surface of a base film (42).Type: GrantFiled: January 31, 2012Date of Patent: May 22, 2018Assignee: Mitsubishi Chemical CorporationInventors: Satoru Ozawa, Katsuhiro Kojima, Yusuke Nakai
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Patent number: 9932684Abstract: Electroplating methods enable the plating of photoresist defined features which have substantially uniform morphology. The electroplating methods include copper electroplating baths with reaction products of ?-amino acids and bisepoxides to electroplate the photoresist defined features. Such features include pillars, bond pads and line space features.Type: GrantFiled: July 27, 2016Date of Patent: April 3, 2018Assignees: Rohm and Haas Electronic Materials LLC, Dow Global Technologies LLCInventors: Matthew Thorseth, Zuhra Niazimbetova, Yi Qin, Julia Woertink, Joanna Dziewiszek, Erik Reddington, Mark Lefebvre
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Patent number: 9080059Abstract: A coating composition comprising an advanced epoxy resin polymeric composition having the following chemical structure:(formula) I where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); R?1-R?4 are independently hydrogen, an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent, for example, a nitro, an isocyanate, or an alkyloxy group; additionally, any two of R?1-R?4 may form fused ring independently; and X is cycloalkylene group, including substituted cycloalkylene group, where the substituent groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halide, a cyano, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.Type: GrantFiled: September 13, 2011Date of Patent: July 14, 2015Assignee: Blue Cube IP LLCInventors: Xin Jin, Ray E. Drumright, Bernhard Kainz, Jerry E. White, Robert E. Hefner, Jr.
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Publication number: 20140242393Abstract: The invention provides materials and methods for forming coatings on substrates. The coatings are durable and resistant to damage from environmental, chemical, thermal, and/or radiative sources. In some embodiments, the coatings comprise bilayers of electrostatically charged materials. The bilayers are created by alternately applying solutions comprising water-soluble, electrostatically charged materials. Durability is imparted to the coatings by the formation of crosslinks that are formed within and between layers after deposition of the coatings.Type: ApplicationFiled: August 15, 2013Publication date: August 28, 2014Applicant: Svaya Nanotechnoligies, Inc.Inventors: David Olmeijer, J. Wallace Parce, Benjamin Wang, Kevin Krogman
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Patent number: 8409669Abstract: A method and system for the spray application of epoxy materials is provided. The system includes a dual walled tank structure as a reservoir for containing and preheating the epoxy materials in preparation for mixing and spray application. Each component of the epoxy material is preheated before the components are mixed. After preheating, the components are then mixed together and spray applied. The method and system of the present invention provides a high quality spray applied epoxy coating while reducing equipment down time and cleaning.Type: GrantFiled: November 7, 2008Date of Patent: April 2, 2013Inventors: Danny R. Warren, David Allan Smith
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Patent number: 8329067Abstract: A method of producing a color filter by using the ink jet system. The method includes a step of preparing a specific ink-jet ink for color filter, the ink containing a pigment, a pigment dispersing agent, a binder forming system and a solvent, a step of forming an R ink layer, a G ink layer and a B ink layer respectively by the ink jet system and a step of curing each of the ink layer to form an R pixel, a G pixel and a B pixel, which each have an average film thickness range from 1.5 ?m to 2.5 ?m and a film thickness distribution range from 1.0 ?m to 3.0 ?m, wherein the ratio of the total area of the regions having a film thickness of 1.5 ?m or less or 2.5 ?m or more in one pixel is 5% or less.Type: GrantFiled: April 2, 2007Date of Patent: December 11, 2012Assignee: Dai Nippon Printing Co., Ltd.Inventors: Tomonori Nishida, Hiroyuki Honda
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Publication number: 20120156382Abstract: The invention relates to a two-component composition consisting of a component A containing a polymer with a molecular weight of 250 to 5000 g/mol which has at least 2 epoxy groups per molecule, a component B containing a compound of the formula (I) R1-phenyl-(—O—R2)a where R1=H, C1 to C6-alkyl, a=1, 2, or 3, R2=—O—CH2—CHOH—CH2—NH—CH2-phenyl-CH2—NH2, wherein the epoxy/NH ratio of the components A to B is between 0.75:1 to 1.25:1.Type: ApplicationFiled: December 14, 2011Publication date: June 21, 2012Applicant: Henkel AG & Co, KGaAInventors: Holger Eichelmann, Michael Hoeltgen
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Publication number: 20120135243Abstract: To provide an aqueous dispersion of a resin wherein dispersed particles are stable with fine particle sizes and whereby bleeding out is suppressed, which is thus useful as e.g. a surface treating agent for a polyolefin substrate, an adhesive or a coating material. A resin dispersion having dispersed in water a polymer (C) having a hydrophilic polymer (B) bonded to a polyolefin (A) in a ratio of (A):(B)=100:5 to 100:500 (weight ratio); a method for producing the resin dispersion; and a coating material and a laminate, employing it.Type: ApplicationFiled: February 3, 2012Publication date: May 31, 2012Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Masato ONOE, Toshiya Seko, Yongwoo Shin, Yongjun Jang, Fumihiko Shimizu
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Publication number: 20120092413Abstract: A treatment solution used for ink-jet recording, including: polyallylamine contained in the treatment solution in an amount of 0.5% by weight to 10% by weight; polyamidepolyamine-epihalohydrin copolymer contained in the treatment solution in an amount of 0.3% by weight to 2% by weight; and water.Type: ApplicationFiled: October 14, 2011Publication date: April 19, 2012Applicant: BROTHER KOGYO KABUSHIKI KAISHAInventor: Eiji KAWAMURA
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Patent number: 8138240Abstract: Composition suitable for a powder coating composition comprising at least one resin and at least one dispersant wherein the dispersant is added during the resin synthesis or while the resin leaves the reactor.Type: GrantFiled: December 8, 2005Date of Patent: March 20, 2012Assignee: DSM IP Assets B.V.Inventors: Leendert J. Molhoek, Jurjen H. M. Bolks, Jochum Beetsma
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Patent number: 7714042Abstract: The present invention provides a coating composition for cans comprising 100 parts by mass of a neutralized acrylic resin-modified epoxy resin (A), and from 1 to 50 parts by mass of anionic polymer crosslinked fine particles (B), (A) and (B) being dispersed in an aqueous medium, wherein the anionic polymer fine particles (B) are polymer fine particles comprising a polymer having an acid value of from 10 to 120 mg KOH/g and being produced by polymerizing radically polymerizable unsaturated monomers comprising from 2 to 30% by mass of a carboxyl group-containing radically polymerizable unsaturated monomer (b1), from 2 to 30% by mass of a polyvinyl compound (b2) and from 40 to 96% by mass of other radically polymerizable unsaturated monomer (b3) in the presence of water.Type: GrantFiled: March 23, 2007Date of Patent: May 11, 2010Assignee: Kansai Paint Co., Ltd.Inventors: Masaaki Saika, Hideki Matsuda, Yuuichi Inada, Naoki Horike, Sumio Noda, Hideki Masuda, Keiichi Shimizu, Hiromi Harakawa
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Patent number: 7589158Abstract: The present invention relates to polymers polymerized sequentially or in stages and having varied functionality and/or monomer content as the polymerization progresses, as well as the methods for making these polymers. The polymers according to the invention can advantageously be present in aqueous emulsion or latex form and can advantageously be used in paint compositions.Type: GrantFiled: November 30, 2005Date of Patent: September 15, 2009Assignee: Columbia Insurance CompanyInventors: Yong Yang, Navin Tilara, Robert J. Sheerin, Dan Sayre
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Patent number: 7470730Abstract: An ink-jet ink composition for a color filter of the present invention comprises; (A) an epoxy compound having two or more epoxy groups, and (B) a carboxyl group block compound having two or more functional groups represented by the formula 1a or 1b, wherein R1, R2, R3, R1?, R2? and R3? each denote a hydrogen or an organic group having 1-18 carbon atoms, R4 and R5 each denote an organic group having 1-18 carbon atoms, Y1 and Y1? each denote an oxygen or a sulfur. R3 and R4 may be bonded with each other. The present invention further discloses a production method for the above-mentioned ink composition, and a production method for a color filter using the above-mentioned ink composition.Type: GrantFiled: June 12, 2002Date of Patent: December 30, 2008Assignees: Dai Nippon Printing Co., Ltd., NOF CorporationInventors: Tomonori Nishida, Masashi Nishiyama, Koji Sato, Shun Saito, Chihiro Imase
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Patent number: 7268182Abstract: A coating composition comprising a film forming binder of a. at least one polymer that has pendant groups, such as, hydroxyl, carboxyl, glycidyl, amine, amide, silane and mixtures thereof that are reactive with a crosslinking component and the polymer has a glass transition temperature (Tg) of 10 to 80° C.; b. a polytrimethylene ether diol having a Mn (number average molecular weight) of 500 to 5,000; and c. a crosslinking component, such as, organic polyisocyanates, melamine formaldehydes, alkylated melamine formaldehydes, benzoquanamine formaldehyde, urea formaldehyde, polyepoxides, silane resin and any mixtures thereof; wherein the coating composition can be used as a clear coating composition and can contain pigments and may be used as a pigmented top coating, a pigmented base coating, a primer or primer surfacer coating and is useful for coating automobile and truck bodies and parts, industrial equipment, appliances and exterior structures.Type: GrantFiled: March 19, 2004Date of Patent: September 11, 2007Assignee: E. I. du Pont de Nemours & CompanyInventors: Hari Babu Sunkara, Patricia Mary Ellen Sormani, James William O'Neil, Joseph V. Kurian
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Patent number: 7235602Abstract: The invention relates to polymerizable preparations that contain: (a) 1 to 80% by weight of an epoxide or of a mixture of epoxides of the general formula (I), wherein n and m independently are 1, 2, 3, or 4, and wherein the molar mass of the epoxide or the average molar mass of the mixture of epoxides is 360 to 3000 g/mole, (b) 0 to 80% by weight of an epoxide or of a mixture of epoxides that are different from (a), (c) 3 to 85% by weight of fillers, (d) 0.01 to 25% by weight of initiators, retarders and/or accelerators, (e) 0 to 25% by weight of adjuvants, the percentages relating to the overall weight of the individual preparation.Type: GrantFiled: February 13, 2002Date of Patent: June 26, 2007Assignee: 3M ESPE AGInventors: Thomas Klettke, Karsten Dede
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Patent number: 7223803Abstract: An activated, substantially water soluble poly(ethylene glycol) is provided having of a linear or branched poly(ethylene glycol) backbone and at least one terminus linked to the backbone through a hydrolytically stable linkage, wherein the terminus is branched and has proximal reactive groups. The free reactive groups are capable of reacting with active moieties in a biologically active agent such as a protein or peptide thus forming conjugates between the activated poly(ethylene glycol) and the biologically active agent.Type: GrantFiled: December 21, 2005Date of Patent: May 29, 2007Assignee: Nektar Therapeutics AL, CorporationInventors: J. Milton Harris, Antoni Kozlowski
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Patent number: 7208145Abstract: Polymeric reagents comprising a polymer attached, either directly or through one or more atoms to a ketone or a related functional group such as ketone hydrate, thione, monothiohydrate, dithiohydrate, hemiketal, monothiohemiketal, dithiohemiketal, ketal, or dithioketal are provided. The polymeric reagents are useful for, among other things, forming polymer-active agent conjugates. Related methods, compositions, preparations, and so forth are also provided.Type: GrantFiled: December 31, 2003Date of Patent: April 24, 2007Assignee: Nektar Therapeutics AL, CorporationInventors: Samuel P. McManus, Antoni Kozlowski, Xiaoming Shen, Daniel C. Cook
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Patent number: 7193010Abstract: An aqueous resin composition satisfying the following criteria (I)–(III). (I) The aqueous resin composition contains (a) an aqueous dispersion of a polyurethane resin obtained from a macromolecular polyol, organic polyisocyanate, chain extending agent and 2,2-dimethylolbutanoic acid, and, if required, (b) an aqueous dispersion of an acrylic resin. (II) When the resin comprising this aqueous resin composition contains mainly a polyurethane resin, the inherent viscosity (?inh) of the polyurethane resin measured at a concentration of 0.5 g/dL in dimethylformamide solution is in the range of 0.2–0.7 dL/g. After this aqueous resin composition is dried, the elastic modulus at 25° C. of the film obtained by heat treatment at 80° C. for 8 hours is in the range of 8.0×106–5.0×108 Pa, and the elastic modulus at 80° C. is 8.0×107 Pa or less.Type: GrantFiled: September 29, 2003Date of Patent: March 20, 2007Assignee: Kuraray Co., Ltd.Inventors: Mitsuru Kato, Yukitoshi Higashinaka
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Patent number: 7101932Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotrialylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.Type: GrantFiled: December 2, 2003Date of Patent: September 5, 2006Assignee: Nektar Therapeutics Al, CorporationInventor: Antoni Kozlowski
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Patent number: 7094826Abstract: An aqueous coating composition comprising a crosslinkable water-dispersible hyperbranched macromolecule(s) wherein the composition when drying has an open time of at least 20 minutes, a wet edge time of at least 10 minutes, a tack free time ?15 hours, a dust free time ?5 hours and an equilibrium viscosity of ?5,000 Pa·s at any solids content when drying in the range of from 20 to 55% by weight using any shear rate in the range of from 9±0.5 to 90±5 s?1 and at 23±2° C.Type: GrantFiled: October 11, 2001Date of Patent: August 22, 2006Assignee: DSM IP Assets B.V.Inventors: Emilio Martin, Gerardus Cornelis Overbeek, Pablo Steenwinkel, Ronald Tennebroek
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Patent number: 7008996Abstract: A water-dispersed powder slurry coating comprises: (A) a particulate comprising (a1) a resin having an active hydrogen; (B) a reactive surfactant having an optionally blocked isocyanate group and/or an epoxy group; and an aqueous medium in which the particulate and the reactive surfactant are contained. The powder slurry coating can provide a film excellent in water resistance and strength. The powder slurry coating can be baked at a lower temperature and provide a film excellent in resistance to acid rain.Type: GrantFiled: March 24, 2003Date of Patent: March 7, 2006Assignees: Sanyo Chemical Industries, Ltd., Toyota Jidosha Kabushiki KaishaInventors: Takeshi Furuta, Yasuhiro Shindo, Takafumi Horiie, Reiko Suwaki, Yoshiko Kobayashi
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Patent number: 7008980Abstract: Waterborne coating compositions, methods of applying such compositions, and substrates coated with such compositions are described. The compositions include an aqueous dispersion of a polyurethane resin, an epoxy resin, and a polyvinyl chloride resin. The compositions can also include an aminoplast such as a melamine, and one or more curing agents. Additionally, the compositions can include flatting agents, colored metallic and/or polymeric particles, hard particles, surfactants, rheology modifiers, defoamers, and coalescing aids. The coating composition can be applied to virtually any surface and cured using conventional heat curing techniques, whether or not there is a chemically embossed layer. However, it is advantageously used in surface coverings in combination with a chemically embossed layer. In one embodiment, the surface covering includes a chemically embossed layer and a cured top layer, which are both cured in a single heating step or plurality of heating steps.Type: GrantFiled: January 17, 2002Date of Patent: March 7, 2006Assignee: AWI Licensing CompanyInventor: Dong Tian
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Patent number: 6921577Abstract: A water-based metal surface treatment agent for the surface treatment of metals including aluminum products such as pre-coated aluminum sheets gives excellent coating film adhesion, flexibility and acid resistance. The water-based metal surface treatment agent contains the following components (1) to (3): (1) A copolymer, containing in a side chain, a diketene or ketoester capable of switching between keto and enol tautomeric forms, and containing at least one hydrophilic side chain containing a cationic group, an anionic group, or a nonionic group; (2) An epoxy resin modified with a phosphoric acid type compound; and (3) A water-soluble curing agent.Type: GrantFiled: February 19, 2002Date of Patent: July 26, 2005Assignee: Nikko Materials Co., Ltd.Inventors: Takashi Ouchi, Katsuyuki Tsuchida, Masashi Kumagai
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Patent number: 6919305Abstract: Solid laundry detergents, dishwashing detergents and cleaners which are obtained by mixing gemini surfactants of the formula (I), R1CH(OH)CHR3(OCH2CH2)nOCHR4CH(OH)R2??(I) in which R1 and R2,independently of one another, are linear or branched alkyl and/or alkenyl radicals having 4 to 22 carbon atoms, R3 and R4, independent of one another, each represents a hydrogen or an alk(en)yl radical having from 1 to 22 carbon atoms and n is a number from 5 to 400, with inorganic or organic carriers.Type: GrantFiled: January 28, 2004Date of Patent: July 19, 2005Assignee: Cognis Deutschland GmbH & Co. KGInventors: Ditmar Kischkel, Manfred Weuthen, Michael Elsner
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Patent number: 6805141Abstract: A rinse agent composition containing: (a) a gemini surfactant corresponding to formula I: R—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R (I) wherein R is a linear or branched alkyl and/or alkenyl radical having from about 4 to 22 carbon atoms, and x is a number from about 5 to 90; and (b) a fatty alcohol alkoxylate corresponding to formula II: R1O[CH2(CH3)CHO]q(CH2CH2O)rH (II) wherein R1 is a linear or branched alkyl and/or alkenyl group having from about 4 to 22 carbon atoms, and q is a number up to about 10, and r is a number from about 1 to 50, and wherein (a) and (b) are present in the composition in a ratio by weight of from about 1:1 to 4:1.Type: GrantFiled: December 12, 2002Date of Patent: October 19, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Michael Elsner, Ditmar Kischke, Manfred Weuthen
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Patent number: 6797687Abstract: Mixtures comprising: (a) a gemini surfactant of the formula (I) R1—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R (I) wherein each of R and R1 is a linear or branched alkyl and/or alkenyl group having from 4 to 22 carbon atoms and x is a number from about 5 to about 400; (b) polyethylene glycol are useful as components in laundry detergents, dishwashing detergents and cleaners and for improving the wetting behavior on various surfaces.Type: GrantFiled: August 7, 2002Date of Patent: September 28, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Ditmar Kischkel, Hans-Christian Raths, Manfred Weuthen, Michael Elsner
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Patent number: 6794041Abstract: Low VOC aqueous coatings having excellent wetting ability are disclosed. The compositions comprise a film-forming resin in conjunction with an additive comprising a carboxylic acid, an amine, and an alcohol. Methods for making and using these compositions are also disclosed, as are the additives themselves.Type: GrantFiled: November 5, 2002Date of Patent: September 21, 2004Assignee: PPG Industries Ohio, Inc.Inventor: Robert L. McVay
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Patent number: 6794345Abstract: The invention relates to gemini surfactants, optionally in combination with ingredients customary in dishwashing detergents and cleaners, optionally with further nonionic surfactants and anionic surfactants, and to the use of such gemini surfactants for improving the wetting behavior and the compatibility with plastics, for the simplified preparation of solid cleaners and as foam-suppressing surfactant in rinse aid formulations.Type: GrantFiled: May 6, 2002Date of Patent: September 21, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Michael Elsner, Manfred Weuthen, Hans-Christian Raths
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Patent number: 6777384Abstract: The invention relates to gemini surfactants, optionally in combination with ingredients customary in laundry detergents, dishwashing detergents and cleaners, optionally with further nonionic surfactants and anionic surfactants, and to the use of such gemini surfactants for improving the wetting behavior and the compatibility with plastics, for the simplified preparation of solid cleaners and as foam-suppressing surfactant in rinse aid formulations.Type: GrantFiled: May 6, 2002Date of Patent: August 17, 2004Assignee: Cognis Deutschland GmbH & Co., KGInventors: Hans-Christian Raths, Manfred Weuthen, Michael Elsner
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Publication number: 20040059025Abstract: An activated, substantially water soluble poly(ethylene glycol) is provided having of a linear or branched poly(ethylene glycol) backbone and at least one terminus linked to the backbone through a hydrolytically stable linkage, wherein the terminus is branched and has proximal reactive groups. The free reactive groups are capable of reacting with active moieties in a biologically active agent such as a protein or peptide thus forming conjugates between the activated poly(ethylene glycol) and the biologically active agent.Type: ApplicationFiled: September 23, 2003Publication date: March 25, 2004Inventors: J. Milton Harris, Antoni Kozlowski
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Patent number: 6710125Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotriazolylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.Type: GrantFiled: February 6, 2002Date of Patent: March 23, 2004Assignee: Nektar Therapeutics AL, CorporationInventor: Antoni Kozlowski
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Patent number: 6683131Abstract: A water-based liquid treatment composition for metal surfaces comprises water, (A) dissolved, dispersed, or both dissolved and dispersed urethane resin, acrylic resin; or both urethane and acrylic resins; (B) dissolved, dispersed, or both dissolved and dispersed curing agent molecules; (C) dispersed silica powder; (D) dispersed oxidized polyethylene wax with an average particle size of 0.01 to 0.Type: GrantFiled: November 28, 2001Date of Patent: January 27, 2004Inventors: Yasuhiro Kinoshita, Keiichi Ueno, Takashi Koyama
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Patent number: 6666217Abstract: A cleaning composition containing a gemini surfactant corresponding to formula I: R—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R (I) wherein R is a linear or branched alkyl and/or alkenyl radical having from about 4 to 22 carbon atoms, and x is a number from about 5 to 90.Type: GrantFiled: May 3, 2002Date of Patent: December 23, 2003Assignee: Cognis Deutschland GmbH & Co. KGInventors: Michael Elsner, Manfred Weuthen, Hans-Christian Raths
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Patent number: 6653370Abstract: Water-dilutable, cationically stabilized epoxy resins ZYX are obtained by reacting, in the first stage, aromatic or aliphatic epoxide compounds Z with aliphatic amines Y to form epoxy-amine adducts ZY which are neutralized and then in aqueous dispersion are reacted in a second stage with a further epoxy resin X. The resins ZYX may be formulated without additional curatives to give aqueous coating materials which exhibit a good corrosion protection effect.Type: GrantFiled: November 2, 2001Date of Patent: November 25, 2003Assignee: Solutia Austria GmbHInventors: Willibald Paar, Roland Feola, Johann Gmoser, Maximilian Friedl
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Patent number: 6649729Abstract: Curable mixtures based on epoxy resins and amine hardeners, if required additionally using solvents, water, plasticisers, UV stabilisers, colourants, pigments, fillers, which mixtures contain as accelerator at least one compound of general formula (I), wherein R1, R2, R3, R4 are each independently of one another H or an unbranched or branched alkyl radical containing 1 to 15 carbon atoms, and n is 0 to 10.Type: GrantFiled: May 19, 2000Date of Patent: November 18, 2003Assignee: Vantico GmbH & Co. KGInventors: Wolfgang Scherzer, Jörg Volle
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Patent number: 6627682Abstract: The present invention is directed to fast reacting epoxy compositions employing select unidentate and chelated Ti(IV) and Sn(II) curing catalysts.Type: GrantFiled: August 29, 2000Date of Patent: September 30, 2003Assignee: Crompton CorporationInventors: Antonio Chaves, Eric R. Pohl, Frederick D. Osterholtz
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Patent number: 6627316Abstract: A resin composition, which is obtained by quaternary salt-formation reaction, in the presence of a tertiary amine, of a copolymer and an amine-modified epoxide resin. Also disclosed herein is a water-borne coating comprising the resin. The coating composition can form superior coating film in surface appearance, adhesion, fabrication, coating film hardness, yellowing resistance and retort resistance, and has good coatability, and low organic solvent content.Type: GrantFiled: March 27, 2001Date of Patent: September 30, 2003Assignee: Kansai Paint Co., Ltd.Inventors: Hiroyasu Matsuki, Reijirou Nishida, Tohru Iwamoto, Atsushi Shioda
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Patent number: 6624213Abstract: The invention provides polyepoxide-based adhesives containing cycloaliphatic-containing polyepoxide resin, aromatic polyepoxide resin, and 9,9-bis(3-methyl-4-aminophenyl)fluorene. The adhesives provide improved peel and shear strength.Type: GrantFiled: November 8, 2001Date of Patent: September 23, 2003Assignee: 3M Innovative Properties CompanyInventors: Clayton A. George, William J. Schultz, Wendy L. Thompson
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Patent number: 6624246Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotriazolylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.Type: GrantFiled: February 6, 2002Date of Patent: September 23, 2003Assignee: Shearwater CorporationInventor: Antoni Kozlowski
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Patent number: 6596519Abstract: The present invention provides a modifying agent for resins for paints or resins for inks, containing fatty acids obtained by the enzymatic decomposition of vegetable oils or fats, the resins for paints or resins for inks modified with the modifying agent, and a paint or ink composition containing the resin for the paint or resin for the ink. The paint or ink composition of the present invention has electrodeposition potential or UV curing property and is excellent in the appearance of the paint film, finishing sharpness and adhesion.Type: GrantFiled: June 20, 2001Date of Patent: July 22, 2003Assignee: The Nisshin Oil Mills, Ltd.Inventors: Masaaki Takayanagi, Akiko Iguchi, Naoki Gotou, Kinya Tsuchiya
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Patent number: 6576689Abstract: A water based coating composition prepared by reacting an epoxy resin (A) having a bisphenol A skeletal structure and a carboxyl group-containing acrylic resin (B) in the presence of an amine compound to form an acrylic-modified epoxy resin (C), and neutralizing, and dispersing the acrylic-modified epoxy resin (C) into an aqueous medium, an amount of a quaternary ammonium salt in the acrylic-modified epoxy resin (C) being in the range of 3.0×10−4 mol or less per one gram of the resin.Type: GrantFiled: October 17, 2001Date of Patent: June 10, 2003Assignee: Kansai Paint Co., Ltd.Inventors: Sumio Noda, Reijiro Nishida, Makoto Asakura, Masaki Murase
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Patent number: 6541543Abstract: An activated, substantially water soluble poly(ethylene glycol) is provided having of a linear or branched poly(ethylene glycol) backbone and at least one terminus linked to the backbone through a hydrolytically stable linkage, wherein the terminus is branched and has proximal reactive groups. The free reactive groups are capable of reacting with active moieties in a biologically active agent such as a protein or peptide thus forming conjugates between the activated poly(ethylene glycol) and the biologically active agent.Type: GrantFiled: November 5, 2001Date of Patent: April 1, 2003Assignee: Shearwater CorporationInventors: J. Milton Harris, Antoni Kozlowski
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Patent number: 6541562Abstract: An aqueous paint composition comprising: (i) an aqueous dispersion obtained by neutralizing with a neutralizing agent a hydrolytic condensation reaction product of (a) 100 parts by weight of an organosilane of the formula (1) R1nSi(OR2)4-n, wherein R1 is a C1-8 organic group, R2 is a C1-5 alkyl group, and n is 1 or 2, and/or its partially hydrolyzed condensate, with (b) from 5 to 200 parts by weight of a silyl group-containing vinyl resin having hydrolyzable silyl groups or silyl groups having silicon atoms bonded to hydroxyl groups and having an acid value of from 20 to 150 mgKOH/g, and adding water thereto, (ii) an amino group-containing alkoxysilane compound, and (iii) an epoxy group-containing compound.Type: GrantFiled: October 3, 2000Date of Patent: April 1, 2003Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Ryuichi Aoki, Tadashi Hatakeyama, Hiroharu Sasaki, Kazuyoshi Tsuneta
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Patent number: 6534177Abstract: Crosslinkable polymer compositions are provided which can be in the form of a polymer powder which is redispersible in water or as an aqueous dispersion. The polymer composition is composed of A) a copolymer of one or more comonomers of vinyl esters of straight-chain or branched alkanecarboxylic acids having 1 to 18 C atoms, acrylates or methacrylates of branched or straight-chain alcohols having 1 to 15 C atoms, dienes, olefins, vinylaromatics and vinyl halides, and of from 0.1 to 10% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated comonomers containing epoxide groups, and B) one or more non-copolymerizable compounds having at least two epoxide groups. The invention furthermore relates to a process for the preparation of the crosslinkable polymer compositions and their use in chemical products for the construction industry.Type: GrantFiled: January 25, 2001Date of Patent: March 18, 2003Assignee: Wacker-Chemie GmbHInventors: Klaus Kohlhammer, Klaus Adler, Herbert Eck, Hermann Lutz
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Method of making an aqueous dispersion of particles comprising an epoxy material for use in coatings
Patent number: 6525115Abstract: The present invention relates to a method of making an aqueous dispersion of particles comprising epoxy-functional and acid-functional materials. Coating compositions made from such a dispersion can be used to protect various substrates, including imaging layers, so that the coated product resists fingerprints, common stains, and spills.Type: GrantFiled: December 5, 2000Date of Patent: February 25, 2003Assignee: Eastman Kodak CompanyInventors: Yongcai Wang, Kurt M. Schroeder, James L. Bello, Kevin M. O'Connor