Abstract: Provided are a curable resin composition having high durability and adherence to a base material such as a metal, a molded composite member formed by coating the base material with the curable resin composition and performing resin molding, and a production method for the same. The curable resin composition contains a polyamide-based resin, a blocked polyisocyanate, and an epoxy compound, and the polyamide-based resin has an amino group concentration from 20 to 300 mmol/kg, and has a water absorption of 1 mass % or less determined by a water absorption test specified by ASTM D570. The polyamide-based resin has a C8-18 alkylene chain and has a melting point from 160 to 250° C. Per 1 mol of amino groups of the polyamide-based resin, a proportion of isocyanate groups of the blocked polyisocyanate is from 1.5 to 5 mol, and a proportion of epoxy groups of the epoxy compound is from 0.1 to 0.8 mol.

Abstract: Polyamide and amidoamine curing agents comprising a selectively modified amine. The selectively modified amine is formed by a substitution reaction between a polyamine and an epoxide, resulting in a multifunctional amine having a hydroxyl substituent. The curing agents are used to form epoxy resins having improved properties when cured.

Abstract: The present invention provides a rapid-hardening underground pipeline grouting repair polymer and a preparing method thereof for underground pipes. The rapid-hardening underground pipeline grouting repair polymer comprises the base resin and the hardener, weight ratio of which is 2:1-1:1. The base resin comprises 50 to 160 parts by weight of an isocyanate; 20 to 100 parts of a chlorophosphate mixture with a density over 1400 kg/m3; a parts by weight ratio of the isocyanate and chlorophosphate is 1:1-4:1. The hardener comprises 30 to 60 parts by weight of a chlorophosphate mixture with a density over 1400 kg/m3, 5 to 15 parts of a propyl formate, a methyl propionate or a mixture of a propyl formate and a methyl propionate, 15 to 55 parts of a polyol, 1 to 3 parts of a surfactant, 2 to 6 parts of a catalyst, 0 to 0.5 parts of water and 0 to 1 parts of a colorant.

Abstract: The present invention provides a curable aqueous composition comprising a (co)polymer and an epoxy crosslinker. The (co)polymer comprises, as (co)polymerized units, from 0.05% to 10% by dry weight, based on total monomers of the (co)polymer, ethylenically unsaturated acidic monomers having at least two carboxylic acid groups, and the epoxy crosslinker is an aliphatic compound having at least two reactive oxirane groups. It further provides a method for forming a treated substrate and a substrate formed by the method.

Abstract: The present invention relates to a process for preparing a polyurethane, comprising the reaction of a composition (Z1) at least comprising a compound (P1) reactive toward isocyanates, and a composition (Z2) at least comprising a polyisocyanate, wherein compound (P1) is obtained by the reaction of at least one polyepoxide with a compound (V1) selected from the group consisting of polyetheramines and polyetherols. The present invention further relates to polyurethanes obtained by such a process, and to the use of a polyurethane of the invention for coating of pipelines, as a “field joint” or of subsea equipment, for example “christmas trees”, for the offshore sector, and as a glass-syntactic polyurethane.

Abstract: A lost circulation material (LCM) composition for sealing a lost circulation zone in a wellbore is disclosed that includes from 50 weight percent to 97 weight percent epoxy resin and from 2 weight percent to 30 weight percent curing agent. The epoxy resin may include at least one of 2,3-epoxypropyl o-tolyl ether, alkyl glycidyl ethers having from 12 to 14 carbon atoms, bisphenol-A-epichlorohydrin epoxy resin, or a compound having formula (OC2H3)—CH2—O—R1—O—CH2—(C2H3O), where R1 is a linear or branched hydrocarbyl having from 4 to 24 carbon atoms. A method for isolating a lost circulation zone using the LCM compositions is also disclosed and includes introducing a spacer fluid to the lost circulation zone, introducing the LCM composition to the lost circulation zone, and curing the LCM composition in the lost circulation zone to isolate the lost circulation zone.

Abstract: Provided is an epoxy resin composition including an epoxy resin and a curing agent, in which the epoxy resin contains a multimeric compound having at least one selected from the group consisting of a structural unit represented by the following Formula (IA) and a structural unit represented by the following Formula (IB), the multimeric compound contains a dimeric compound containing two structural units represented by the following Formula (II) in one molecule, and a ratio of the dimeric compound is from 15% by mass to 28% by mass with respect to the epoxy resin as a whole.

Abstract: In one aspect, inks for use with a 3D printer are described herein. In some embodiments, an ink described herein comprises a cyclic carbonate monomer and an amine monomer. Further, in some instances, an ink described herein also comprises an ethylenically unsaturated monomer such as a (meth)acrylate. Additionally, an ink described herein, in some cases, further comprises a colorant, such as a molecular dye, a particulate inorganic pigment, or a particulate organic colorant. An ink described herein may also comprise one or more additives selected from the group consisting of inhibitors, stabilizing agents, photoinitiators, and photosensitizers.

Abstract: In one aspect, inks for use with a 3D printer are described herein. In some embodiments, an ink described herein comprises a cyclic carbonate monomer and an amine monomer. Further, in some instances, an ink described herein also comprises an ethylenically unsaturated monomer such as a (meth)acrylate. Additionally, an ink described herein, in some cases, further comprises a colorant, such as a molecular dye, a particulate inorganic pigment, or a particulate organic colorant. An ink described herein may also comprise one or more additives selected from the group consisting of inhibitors, stabilizing agents, photoinitiators, and photosensitizers.

Abstract: The present invention relates to waterborne curing compositions for electrodeposition and radiation curing and processes to obtain such compositions. The compositions are characterized in that an ethylenically unsaturated compound (b), is dispersed in an aqueous solution by an at least partially neutralized (meth)acrylic modified amine epoxy adduct. The compositions of the invention are particularly suitable for coating metallic materials and temperature sensitive materials such as electrically conductive plastic materials.

Abstract: The present invention relates to an aqueous radiation curable composition comprising: (I) at least one ethylenically unsaturated compound (A), and (II) at least one emulsifier (B) comprising alternating polyalkylene oxide segments, wherein said emulsifier optionally bears one or more groups selected from alkyl groups, aryl groups hydroxyl groups and/or ethylenically unsaturated groups, and wherein said emulsifier (B) has an HLB value of at least 4.5, preferably at least 7. The compositions of the invention are particularly suited for the manufacture of sprayable eco-friendly hardcoats, but they are also suitable for the making of inks, overprint varnishes and adhesives, alone or in combination with e.g. a water-borne polymer dispersion.

Abstract: The invention provides polymer particles useful in a variety of applications, including coating applications such as packaging coatings. The polymer particles preferably have a volume-averaged particle size of less than 40 microns, more preferably less than 20 microns. In preferred embodiments, the polymer particles are precipitated particles, more preferably precipitated polyester particles, which are optionally free of low-molecular weight surfactant.

Abstract: A method for coating an uncoated or precoated metallic or plastics substrate by (a) applying an aqueous coating composition (W) whose constituents are free or substantially free from blocked isocyanate groups, which comprises an aqueous dispersion of an epoxide-amine adduct, and which comprises either no crosslinking agent or one or more nonblocked polyisocyanate crosslinking agents, to the substrate, (b) optionally applying one or more further coating compositions, and (c) curing the coating composition (W) and, where appropriate, the further coating composition(s) at temperatures of below 90° C.

Abstract: The present invention relates to sizing compositions, glass fibers at least partially coated with sizing compositions, and glass fiber reinforced composite materials. In one embodiment, a sizing composition comprises at least one maleic anhydride copolymer, at least one coupling agent, and a reaction product of an alkoxylated amine and a polycarboxylic acid, which is further reacted with an epoxy compound.

Abstract: The present invention relates to aqueous-based primer composition, comprising at least one thermosetting, self-emulsifying epoxy resin composition; at least one thermosetting, non-self-emulsifying resin composition; water; and at least one curative.

Abstract: The present invention relates to an aqueous radiation curable composition comprising: (I) at least one ethylenically unsaturated compound (A), and (II) at least one emulsifier (B) comprising alternating polyalkylene oxide segments, wherein said emulsifier optionally bears one or more groups selected from alkyl groups, aryl groups hydroxyl groups and/or ethylenically unsaturated groups, and wherein said emulsifier (B) has an HLB value of at least 4.5, preferably at least 7. The compositions of the invention are particularly suited for the manufacture of sprayable eco-friendly hardcoats, but they are also suitable for the making of inks, overprint varnishes and adhesives, alone or in combination with e.g. a water-borne polymer dispersion.

Abstract: An inexpensive chromate-free black metal sheet not containing the high environmental load hexavalent chromium and extremely excellent in finish (coloring power and concealing power including worked parts), moisture resistance, corrosion resistance, formability, scratch resistance, chemical resistance, etc. The present invention is a chromate-free black-coated metal plate characterized by comprising a metal sheet on at least one surface of which is formed a black coating (?), containing a polyester resin (A1) containing sulfonic acid groups cured by a curing agent (B) and carbon black (C), of a thickness of 2 to 10 ?m.

Abstract: Compositions and methods for forming surfactants, aqueous dispersions, and curing agents are provided. In one aspect, the invention relates to improved epoxy functional surfactants prepared by reaction of an epoxy composition and an amidoamine composition formed from a blend of acid-terminated polyoxyalkylene polyols. The improved epoxy functional surfactants may be reacted with an excess of epoxy composition and water to result in an aqueous dispersion. The amidoamine composition may be a reaction mixture of a diamine compound and an acid terminated polyoxyalkylene composition formed from two or more polyoxyalkylene polyol compounds. The epoxy functional surfactant may be reacted with amine compounds to form a compound suitable as a curing agent.

Abstract: Compositions and methods for forming surfactants, aqueous dispersions, and curing agents are provided. In one aspect, the invention relates to improved epoxy functional surfactants prepared by reaction of an epoxy composition and an amidoamine composition formed from a blend of acid-terminated polyoxyalkylene polyols. The improved epoxy functional surfactants may be reacted with an excess of epoxy composition and water to result in an aqueous dispersion. The amidoamine composition may be a reaction mixture of a diamine compound and an acid terminated polyoxyalkylene composition formed from two or more polyoxyalkylene polyol compounds. The epoxy functional surfactant may be reacted with amine compounds to form a compound suitable as a curing agent.

Abstract: A coating/sealant system that includes a coating and a sealant deposited over at least a portion of the coating, in which the coating includes a reaction product formed from reactants comprising a phosphated epoxy resin and a curing agent, and the sealant includes a sulfur-containing polymer.

Abstract: An aqueous epoxy resin system AB is described comprising an aqueously dispersed epoxy resin A having, on the average, at least one epoxy group per molecule, and a water-soluble or water-dispersible curing agent B which comprises the reaction product of an amine B1 having at least one primary and/or at least one secondary amino group, an adduct B2 of a polyalkylene ether polyol B21 and an epoxide component B22, and an aromatic compound B3 having at least one acidic group selected from the group consisting of hydroxyl and carboxyl groups, which system can be applied by rolling, spraying or brushing to provide corrosion protection on base metals.

Abstract: Pressure sensitive adhesives produced from naturally occurring fats and oils are described. Also described are methods of producing the pressure sensitive adhesives. Generally, one or more naturally occurring fats or oils are epoxidized, and then reacted with certain alcohols or amines to thereby obtain the noted pressure sensitive adhesives.

Abstract: The present invention is a method for preparing an emulsion resin composition for a cationic electrodeposition paint, which reduces or eliminates time for desolvation. The emulsion resin composition for cationic electrodeposition paint includes a cationic epoxy resin and a blocked isocyanate curing agent. The method features the steps of: (1) a step of mixing water and the cationic resin to form a W/O emulsion, (2) a step of mixing the blocked isocyanate curing agent and the W/O emulsion to form a curing agent-containing W/O emulsion, and (3) a step of mixing water and the curing agent-containing W/O emulsion to form an O/W emulsion, via a phase inversion point from W/O emulsion to O/W emulsion. The method features a solid concentration by mass Xw/o (%) of the curing agent-containing W/O emulsion and a solid content by mass Xtra (%) at the phase inversion point from W/O emulsion to O/W emulsion satisfying a relation of Xw/o?Xtra>3%.

Abstract: This invention relates to a coating composition comprising (A) 100 weight parts of at least one epoxy resin; (B) 40 to 900 weight parts of at least one alkoxy-containing aminofunctional silicone resin; (C) up to 50 weight parts of at least one organic hardener; (D) up to 100 weight parts of at least one epoxyfunctional silicone resin; and (E) up to 10 weight parts of at least one cure accelerator, provided the alkoxy-containing aminofunctional silicone resin (B) has a total alkoxy content ranging from 26 to 80 mol percent per mole of silicon (Si) in the alkoxy-containing aminofunctional silicone resin. Methods for preparing the above-described composition and for treating substrates are also disclosed.

Abstract: The present invention deals with a flexible printed wiring board in the form of a printed wiring board wherein the conductive elements are fully encapsulated by an epoxy adhesive comprising a novel aromatic di-isoimide chemical compound. The conductive elements are thereby protected. The flexible printed wiring board is readily cured at a temperature in the range of 100 to 250° C. However, before curing, by virtue of the latent cure feature of the epoxy adhesive, the adhesive component of the printed wiring board has an extended shelf life, and avoids premature curing during processing.

Abstract: Compositions and methods for forming surfactants, aqueous dispersions, and curing agents are provided. In one aspect, the invention relates to improved epoxy functional surfactants prepared by reaction of an epoxy composition and an amidoamine composition formed from a blend of acid-terminated polyoxyalkylene polyols. The improved epoxy functional surfactants may be reacted with an excess of epoxy composition and water to result in an aqueous dispersion. The amidoamone composition may be a reaction mixture of a diamine compound and an acid terminated polyoxyalkylene composition formed from two or more polyoxyalkylene polyol compounds. The epoxy functional surfactant may be reacted with amine compounds to form a compound suitable as a curing agent.

Abstract: The present invention deals with a laminate useful for forming fully encapsulated flexible printed wiring boards. The laminate comprises a dielectric substrate coated with a curable composition comprising an epoxy and a novel aromatic di-isoimide chemical compound. The curable composition provides the benefit of thermal latency, improving shelf-life, and reducing premature curing during processing. Fully encapsulated printed wiring boards are also disclosed.

Abstract: Embodiments of the present disclosure include a method of destabilizing a crude oil-water emulsion that includes adding to the crude oil-water emulsion a demulsifier obtained by an alkoxylation reaction of an aminated epoxy adduct, the aminated epoxy adduct obtained by a reaction of an epoxy resin and an amine. In one or more embodiments, the alkoxylation reaction includes reacting C2 to C4 alkylene oxides with the aminated epoxy adduct.

Abstract: Crosslinked lactone/alkylene oxide polymers are useful as demulsifiers to break emulsions, e.g. water-in-oil and oil-in-water emulsions, particularly oilfield emulsions. These polymers are random or block polymers made from addition reactions of a hydroxyl- and/or amine-containing base compound with at least one lactone monomer and at least one alkylene oxide monomer. The polymers may be crosslinked with multifunctional epoxides, multifunctional carboxylic acids, and/or multifunctional anhydrides. The crosslinked polymers may be optionally capped by reaction with monofunctional monomers such as mono-epoxides and/or monofunctional carboxylic acids. The crosslinked polymers are also suitable as oilfield paraffin inhibitors and dispersants.

Abstract: The invention is a radiation curable coating composition containing epoxyacrylate formed by ring opening reaction between (meth)acrylic acid and a self-dispersing epoxy resin in an aqueous system.

Abstract: The present invention provides curing agent compositions comprising the reaction product of polyalkyleneamine compounds and polyalkylene polyether polyol modified polyepoxide resins. Amine-epoxy compositions and thick layer compositions produced from these amine-epoxy compositions are also disclosed.

Abstract: Disclosed is a low VOC coating additive employing a water-dispersible polymer, a water insoluble plasticizer, cyclohexanedimethanol, and optionally an amphiphilic component. The additive can be added to a coating to improve at least one performance characteristics of the coating, such as, wet-edge time, open time, scrub resistance, wet adhesion, and water resistance.

Abstract: The invention relates to a composition containing a polyepoxide with polyether lateral chains and pendant hydrocarbyl groups. The invention further relates to a composition containing a particulate solid, an organic or aqueous medium, and a polyepoxide with polyether lateral chains and pendant hydrocarbyl groups. The invention further relates to novel compounds, and the use of the polyepoxide with polyether lateral chains and pendant hydrocarbyl groups as a dispersant.

Abstract: A pigment dispersing resin is disclosed along with pigment dispersion, electrodepositable coating compositions using the pigment dispersing resin, and methods for applying the electrodepositable coating composition. The pigment dispersing resin consists essentially of the carboxylic acid salt of an aminated bisphenol epoxy resin and an alkoxylated styrenated phenol. Pigment dispersions made from the dispersing resin are especially useful for forming low or no volatile organic content electrocoating baths.

Abstract: Disclosed herein are resinous dispersions suitable for use in an electrodepositable coating composition. The resinous dispersions include: (a) an epoxy-amine adduct formed as the reaction product of reactants comprising (i) an epoxy-containing compound having at least one active hydroxyl group; and (ii) an amine-containing compound having a primary and a tertiary amine group; (b) an acid; (c) a second epoxy-containing compound; and (d) water. The resinous dispersion may be introduced into cationic electrodepositable coating compositions. Coated substrates formed with such cationic electrodepositable coating compositions may achieve 60° gloss readings of 3 or less at conventional film builds.

Abstract: A process including the polymerization of a reactive diluent, which is present in an aqueous dispersion that further includes an epoxy-amine material, is disclosed. The resulting composition is useful as a coating composition.

Abstract: A coating layer prepared from an aqueous electrodeposition coating composition comprising an electrodepositable binder, the binder comprising a sulfo or sulfamyl group-containing resin, provides corrosion protection to a metallic substrate.

Abstract: The present invention provides curing agent compositions comprising the reaction product of alkylated polyalkyleneamine compounds and polyalkylene polyether polyol modified polyepoxide resins. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.

Abstract: Curable, aqueous epoxy resin composition, comprising a) an epoxy compound, b) an aminic curing agent which is an aqueous solution of a product from the reaction between i) an adduct between a polyamine and a liquid glycidyl ether which is not a glycidyl ether of a polyalkylene glycol, and ii) an epoxidized polyalkylene glycol, and c) from 0.5 to 15 wt.-%, based on the sum of the components b) and c), of a compound of the general formula (I) whereby R1=—H or —C4H9, and x=1, 2, 3 or 4, providing due to the presence of component c) an adjustable and recognizable end of pot life during application, for example coating, adhesive, as flooring, casting, tooling or encapsulating.

Abstract: Pressure sensitive adhesives produced from naturally occurring fats and oils are described. Also described are methods of producing the pressure sensitive adhesives. Generally, one or more naturally occurring fats or oils are epoxidized, and then reacted with certain alcohols or amines to thereby obtain the noted pressure sensitive adhesives.

Abstract: Lactone/alkylene oxide polymers are useful as demulsifiers to break emulsions, e.g. water-in-oil and oil-in-water emulsions, particularly oilfield emulsions. These polymers are random or block polymer made from addition reactions of a hydroxyl- and/or amine-containing base compound with at least one lactone monomer and at least one alkylene oxide monomer.

Abstract: An aqueous epoxy resin system AB is described comprising an aqueously dispersed epoxy resin A having, on the average, at least one epoxy group per molecule, and a water-soluble or water-dispersible curing agent B which comprises the reaction product of an amine B1 having at least one primary and/or at least one secondary amino group, an adduct B2 of a polyalkylene ether polyol B21 and an epoxide component B22, and an aromatic compound B3 having at least one acidic group selected from the group consisting of hydroxyl and carboxyl groups, which system can be applied by rolling, spraying or brushing to provide corrosion protection on base metals.

Abstract: The present invention provides epoxy curing agent compositions comprising alkylated aminopropylated methylene-di-(cyclohexylamine) compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.

Abstract: A method for producing reactive fine particles, includes: admixing at least one latent curing agent selected from the group consisting of a urea derivative, an imidazole, a dicyaniamide (DICY), a mixture of any one or more thereof, and a precursor thereof, in a solvent to form a clear solution; spraying the clear solution onto at least one inorganic inert particle selected from the group consisting of a metal oxide, a mineral filler, a natural filler, and a mixture of any one or more thereof, the at least one inorganic inert particle having a specific surface area in the range of about 10 to about 50 m2/g; and removing the solvent to form reactive fine particles that includes a core of inert material coated by a coating layer that includes the at least one latent curing agent.

Abstract: A process including the polymerization of a reactive diluent, which is present in an aqueous dispersion that further includes an epoxy-amine material, is disclosed. The resulting composition is useful as a coating composition.

Abstract: Aqueous dispersions and coatings comprising modified epoxy resins comprising the reaction product of rosin and a dienophile, further reacted with an epoxy resin, are disclosed.

Abstract: A pigmented granular pigmented coating feedstock is prepared by melting a resin, which can be a solid resin based on polymerizable ethylenically unsaturated monomer or epoxy based resin, and a solid or viscous curing agent, blending the molten mass, and cooling to form a solid. The solid blend of resin and curing agent is ground to produce a granular feedstock. The feedstock is readily storable or shippable to a location for coating preparation. Alternatively a solid coating can be ground after shipping. An aqueous coating is made by dispersing the feedstock in water and mixing to form a dispersion. A salting agent and at least one additive can be added to form an aqueous coating composition. An article can be coated with the dispersion, for example, by electrodeposition.

Abstract: A hyperdispersant for use in a fluorocarbon coating composition is disclosed. The fluorocarbon coating composition generally comprises a fluorocarbon resin, a binder resin, a cross-linking agent, and the hyperdispersant. The hyperdispersant comprises the reaction product of a polyglycidyl oligomer and at least one amino compound. The polyglycidyl oligomer comprises a carbon chain having from 1 to 25 carbon atoms with at least one of an internal ether linkage and an internal ester linkage and comprises a plurality of epoxy groups. The at least one amino compound has a cyclic, heterocyclic, alkyl, or heteroalkyl structure substituted with at least one primary or secondary amine group for reacting with and opening at least one of the epoxy groups.

Abstract: A pigment dispersing resin is disclosed along with pigment dispersion, electrodepositable coating compositions using the pigment dispersing resin, and methods for applying the electrodepositable coating composition. The pigment dispersing resin consists essentially of the carboxylic acid salt of an aminated bisphenol epoxy resin and an alkoxylated styrenated phenol. Pigment dispersions made from the dispersing resin are especially useful for forming low or no volatile organic content electrocoating baths.

Abstract: A granular coating feedstock is prepared by melting a resin, which can be a solid, polymerizable, ethylenically unsaturated monomer or epoxy-based resin, and a solid or viscous curing agent, blending the molten mass, and cooling to form a solid. The solid blend of resin and agent is ground to produce a granular coating feedstock. The feedstock is readily storable or shippable to a location for coating preparation. Alternatively the feedstock can be ground after shipping. An aqueous coating composition is made by dispersing the feedstock in water and mixing to form a dispersion. A salting agent and at least one additive can be added to form an aqueous coating composition. An article can be coated with the dispersion, for example, by electrodeposition.