Organic Nitrogen Compound Is Amine-aldehyde Condensation Product Patents (Class 523/416)
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Patent number: 11046809Abstract: The use of an amine of formula (I) as a component of a hardener for epoxy resins, hardeners for epoxy resins containing the amine of formula (I), and resultant epoxy resin compositions which can particularly be used as low-emission room-temperature-curing epoxy-resin coatings with high hardness and surface quality. The amine of formula (I) is low-odour and a very successful diluent for epoxy resin compositions. It is particularly obtained by reductive alkylation from 1,2-ethylenediamine or 1,2-propylenediamine and an aldehyde or ketone.Type: GrantFiled: September 16, 2016Date of Patent: June 29, 2021Assignee: SIKA TECHNOLOGY AGInventors: Edis Kasemi, Andreas Kramer, Ursula Stadelmann, Urs Burckhardt
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Patent number: 10985344Abstract: Flexible display devices, such as flexible cover lens films, are discussed and provided herein. The flexible cover lens film has good strength, elasticity, optical transmission, wear resistance, and thermostability. The cover lens film includes a hard coat layer with a thickness from about 5 ?m to 40 ?m, an impact absorption layer with a thickness from about 20 ?m to 110 ?m, and a substrate layer with a thickness from about 10 ?m to 175 ?m and is disposed between the hard coat layer and the impact absorption layer. By combining the hard coat layer and the impact resistant layer, the cover lens film is both flexible and strong with hardness from 6H to 9H.Type: GrantFiled: August 28, 2018Date of Patent: April 20, 2021Assignee: APPLIED MATERIALS, INC.Inventors: Manivannan Thothadri, Daniel Paul Forster, Robert F. Praino, Jr., Harvey You
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Patent number: 7993751Abstract: The present invention provides epoxy curing agent compositions comprising alkylated aminopropylated methylene-di-(cyclohexylamine) compounds. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: GrantFiled: August 6, 2008Date of Patent: August 9, 2011Assignee: Air Products and Chemicals, Inc.Inventors: Gamini Ananda Vedage, Williams Rene Raymond, Maw Lin Foo
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Patent number: 7868066Abstract: Aqueous dispersions and coatings comprising modified epoxy resins comprising the reaction product of rosin and a dienophile, further reacted with an epoxy resin, are disclosed.Type: GrantFiled: July 20, 2007Date of Patent: January 11, 2011Assignee: PPG Industries Ohio, Inc.Inventor: David Fenn
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Patent number: 7759436Abstract: Film-forming materials include nonionic metal coordinating structures. Nonionic metal coordinating structures can coordinate metals, such as metal catalysts and metal substrates. Example film-forming materials can be the product of a poly-functional epoxide and a nucleophilic ligand having a nonionic metal coordinating structure, or the product of a poly-functional alcohol and an electrophilic ligand having a nonionic metal coordinating structure.Type: GrantFiled: October 26, 2006Date of Patent: July 20, 2010Assignee: BASF Coatings GmbHInventors: Timothy S. December, Sergio Gonzalez, Günther Ott, Karl-Heinz Grosse-Brinkhaus
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Patent number: 7476444Abstract: A corrosion resistant, alkali resistant coating composition is disclosed. The composition comprises a binder comprising a reaction product of an epoxy-containing material and a phosphorus-containing material together with a curing agent. Aminoplasts, especially melamine-based aminoplasts, are particularly suitable curing agents. A source of silicon can optionally be included. The compositions also provide excellent adhesion and can be used with or without a weldable primer. The compositions are applied to and cured on a metal substrate.Type: GrantFiled: September 15, 2006Date of Patent: January 13, 2009Assignee: PPG Industries Ohio, Inc.Inventors: Michael J. Pawlik, Dennis W. Jones, Ralph C. Gray, Richard M Nugent, Jr., Yves Le Disert, Laurent Deronne
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Publication number: 20080188591Abstract: The present invention provides curing agent compositions comprising the reaction product of alkylated polyalkyleneamine compounds and polyalkylene polyether polyol modified polyepoxide resins. Amine-epoxy compositions and articles produced from these amine-epoxy compositions are also disclosed.Type: ApplicationFiled: February 7, 2007Publication date: August 7, 2008Inventors: Williams Rene Edouard Raymond, Gamini Ananda Vedage, Stephen Francis Monaghan, Michael Ian Cook, Susana R. Grote
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Patent number: 7345101Abstract: A corrosion resistant, alkali resistant coating composition is disclosed. The composition comprises a binder comprising a reaction product of an epoxy-containing material and a phosphorus-containing material together with a curing agent. Aminoplasts, especially melamine-based aminoplasts, are particularly suitable curing agents. A source of silicon can optionally be included. The compositions also provide excellent adhesion and can be used with or without a weldable primer. The compositions are applied to and cured on a metal substrate.Type: GrantFiled: February 2, 2006Date of Patent: March 18, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Michael J. Pawlik, Dennis W. Jones, Ralph C. Gray, Richard M. Nugent, Jr., Yves Le Disert, Laurent Deronne
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Patent number: 7342080Abstract: Polymerizable fluorinated polyethers are formed by Michael-type addition of a reactive fluorinated polyether to a poly(meth)acryl compound. The polymerizable fluorinated polyethers may be used to form composite articles.Type: GrantFiled: December 10, 2004Date of Patent: March 11, 2008Assignee: 3M Innovative Properties CompanyInventors: Zai-Ming Qiu, Thomas P. Klun, Naiyong Jing, William D. Coggio
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Patent number: 7288119Abstract: An improved method for dying leather with propylene glycol monomethyl ether (PGME) systems comprising adding polyacrylate resin base, C3 and C4 alcohols, and n-butyl acetate and negating the need for teflon dispersions, dibutyl phthalate, and improves the dye penetration, hastens the flash times, improve the dust free time, and improves the tape time.Type: GrantFiled: October 28, 2005Date of Patent: October 30, 2007Assignee: Automotive Technology, Inc.Inventors: Doug Slattery, Eric Waerkerle, Don Kamp
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Patent number: 7049354Abstract: The present invention provides a novel oxazolidone ring-containing epoxy resin suitable for use as a resin for a coated film having a structure of the formula: wherein R3 represents a residue excluding epoxy groups of diepoxide, X represents a residue excluding isocyanate groups of polyurethane diisocyanate, and n represents an integer of 1 to 5; and wherein X has a structure of the formula: wherein R1 represents a residue excluding isocyanate groups of diisocyanate, R2 represents a residue excluding hydroxyl groups of diol, and m represents an integer of 2 to 10.Type: GrantFiled: October 6, 2003Date of Patent: May 23, 2006Assignee: Nippon Paint Co., Ltd.Inventors: Shuhei Yamoto, Eiji Nakajima, Mitsuo Yamada
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Patent number: 7008980Abstract: Waterborne coating compositions, methods of applying such compositions, and substrates coated with such compositions are described. The compositions include an aqueous dispersion of a polyurethane resin, an epoxy resin, and a polyvinyl chloride resin. The compositions can also include an aminoplast such as a melamine, and one or more curing agents. Additionally, the compositions can include flatting agents, colored metallic and/or polymeric particles, hard particles, surfactants, rheology modifiers, defoamers, and coalescing aids. The coating composition can be applied to virtually any surface and cured using conventional heat curing techniques, whether or not there is a chemically embossed layer. However, it is advantageously used in surface coverings in combination with a chemically embossed layer. In one embodiment, the surface covering includes a chemically embossed layer and a cured top layer, which are both cured in a single heating step or plurality of heating steps.Type: GrantFiled: January 17, 2002Date of Patent: March 7, 2006Assignee: AWI Licensing CompanyInventor: Dong Tian
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Patent number: 7001435Abstract: An improved method for dyeing leather wit propylene glycol monomethyl ether (PGME) systems comprising adding polyacrylate resins base, C-3 and C-4 alcohols, and n-butyl acetate and negating the need for aqueous compositions, Teflon dispersions, dibutyl phthalate, and improves the dye penetration, hastens the flash times, improves the dust free time, and improves the tape time.Type: GrantFiled: April 28, 2003Date of Patent: February 21, 2006Assignee: Automotive Technology, Inc.Inventors: Doug Slattery, Eric Waerkerle, Don Kamp
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Patent number: 6984674Abstract: A curable coating composition is disclosed comprising a resinous binder comprising (a) a reaction product of an epoxy-containing polymer with a compound containing phosphorus acid groups, the reaction product having reactive functional groups, and (b) a curing agent having functional groups reactive with the functional groups of (a). An electroconductive pigment is dispersed in (a) such that the weight ratio of the electroconductive pigment to (a) plus (b) is within the range of 0.5 to 9.0:1. When the curable coating composition is deposited and cured on a metal substrate, the cured coating is weldable.Type: GrantFiled: March 18, 2004Date of Patent: January 10, 2006Assignee: PPG Industries Ohio, Inc.Inventors: Ralph C. Gray, Ellor James Van Buskirk, Michael J. Pawlik, Richard M. Nugent, Jr., Dennis W. Jones, Kathleen M. Coldren, Steven D. Perrine, James E. Jones
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Patent number: 6911490Abstract: Aqueous curing agents for epoxy resin dispersions comprising mixtures, adducts and/or salts of partly esterified organic phosphoric acids A1 or partly esterified phosphonic acids A2 with organic amines B selected from the group consisting of epoxide-amine adducts B1, Mannich bases B2, polyaminoamides B3, and condensation products B4 of diamines or polyamines B42 with di- or polyhydroxyaromatics B41, their preparation and a method of use comprising mixing thereof with aqueous epoxy resin dispersions in particular for coating metals as corrosion protectionType: GrantFiled: November 15, 2002Date of Patent: June 28, 2005Assignee: Solutia Austria GmbHInventors: Roland Feola, Willibald Paar, Johann Gmoser
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Publication number: 20040176502Abstract: A water-soluble composition including a water soluble polyamine adduct which is a reaction product of: (a) an alkoxy group modified polyepoxide resin containing an average of at least 1.5 epoxide groups per molecule; and (b) a Mannich base polyamine. The Mannich base polyamine is a reaction product of a polyamine containing at least two amino groups with a N-Mannich condensate prepared from a reaction of a phenolic compound, an aldehyde, and a secondary amine wherein the secondary amine of the N-Mannich condensate is replaced by one of the at least two amino groups of the polyamine, and wherein the ratio of the Mannich base polyamine to the alkoxy group modified polyepoxide resin contains an excess of an active amine hydrogen relative to epoxide groups so that the water soluble polyamine adduct has an amine hydrogen equivalent weight of at most 1000 based on solids content.Type: ApplicationFiled: March 4, 2003Publication date: September 9, 2004Inventors: William R. Raymond, Michael Cook
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Patent number: 6713587Abstract: The present invention relates to an electrodepositable coating composition having a resinous phase dispersed in an aqueous medium. The resinous phase includes (a) an ungelled, active hydrogen-containing, ionic salt group-containing resin; and (b) a curing agent reactive with the active hydrogens of the resin (a). The resinous phase has a covalently bonded halogen content based on total weight of resin solids present in the resinous phase such that when the composition is electrodeposited and cured, the cured film passes flame resistance testing in accordance with IPC-TM-650, and has a dielectric constant of less than or equal to 3.50. The invention also is directed to a method for forming a dielectric coating on an electroconductive substrate using the electrodepositable coating composition, as well as to a substrate coated with the electrodepositable composition.Type: GrantFiled: June 27, 2002Date of Patent: March 30, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Gregory J. McCollum, Thomas C. Moriarity, Kevin C. Olson, Michael G. Sandala, Alan E. Wang, Craig A. Wilson, Steven R. Zawacky
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Patent number: 6670041Abstract: Water-dilutable binders which are self-crosslinking at room temperature, comprising reaction products ABF with epoxy-amine adducts A and formaldehyde resin formers B selected from phenols B1, (substituted) ureas B2, melamine B3, guanamines B4, and mixtures of said resin formers, with formaldehyde F or compounds which give off formaldehyde under the reaction conditions, may be formulated, following at least partial neutralization, to give aqueous coating materials which give coatings affording outstanding corrosion protection.Type: GrantFiled: November 2, 2001Date of Patent: December 30, 2003Assignee: Solutia Austria GmbHInventors: Willibald Paar, Roland Feola, Johann Gmoser, Michael Gobec
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Patent number: 6653369Abstract: Water dilutable amine curing agents for aqueous epoxy resin dispersions, comprising a combination of an epoxide-amine adduct with an emulsifier, the epoxide-amine adduct being obtainable by reacting a polyepoxide with a reaction product of an amine and an epoxide component or an amine and subsequent reaction with an epoxide component, the amount of amine being chosen such that the number of nitrogen-attached hydrogen atoms the number of epoxide groups by a factor of from 2 to 10, and the emulsifier being obtainable by reacting diepoxides or polyepoxides with compounds that are at least difunctional with respect to epoxides, optionally with compounds D that are monofunctional with respect to epoxides, and with amines G which contain at least one tertiary and at least one primary or at least two secondary amino group(s).Type: GrantFiled: May 6, 2002Date of Patent: November 25, 2003Assignee: Solutia Austria GmbHInventors: Martin Gerlitz, Thomas Fischer, Andreas Gollner, Manfred Gogg, Elfriede Prucher, Heike Schneeberger, Josef Wenzl
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Patent number: 6596817Abstract: Low molar mass polyester polyols having a weight average molar mass Mw of up to 3500 g/mol, hydroxyl numbers of from 80 to 280 mg/g and acid numbers of from 5 to 40 mg/g, comprising structural units derived from aliphatic monocyclic or polycyclic compounds containing at least two hydroxyl and/or epoxide groups and at least one heteroatom, aliphatic acyclic or cyclic polyhydroxy compounds containing three or more hydroxyl groups per molecule, linear or branched aliphatic dihydroxy compounds and aliphatic cyclic polycarboxylic acids, alone or in a mixture with low molar mass acrylate copolymers, may be processed to give coating materials which dry rapidly, and result in defect-free surfaces.Type: GrantFiled: June 15, 2001Date of Patent: July 22, 2003Assignee: Solutia Austria GmbHInventors: Ulrich Epple, Ulrike Kuttler, Adolf Labenbacher
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Patent number: 6479151Abstract: The present invention provides a water borne two-component cross-linkable composition based on an aqueous dispersion of an at least partially neutralized amino-functional epoxy derived polymer and a compound comprising at least two acetoacetate groups or acetoacetamide groups or a combination of the two groups. This composition provides coatings with high gloss, good water and solvent borne resistance, and high hardness. This composition also provides adhesives with high adhesion power.Type: GrantFiled: April 12, 2001Date of Patent: November 12, 2002Assignee: Akzo Nobel, N.V.Inventors: Roelof Buter, Tom Van't Veer, Josephina Johanna Hendrika Maria Schlief, Petrus Johannes Arnoldus Geurink
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Patent number: 6462124Abstract: A base-neutralized, water-diluted coating comprises (A) a polyhydroxyl-functional resin of an acrylate resin or an oil-free polyester containing urethane groups, (B) an amino resin partially etherified with an alcohol, (C) a basic neutralizing agent, (D) water, and (E) a water-insoluble crosslinking catalyst of a strong organic or inorganic acid such as p-toluenesulfonic acid blocked with a monoepoxide, diepoxide or lactone.Type: GrantFiled: March 16, 2001Date of Patent: October 8, 2002Assignee: Solutia Austria GmbHInventors: Werner Wilfinger, Ingo Kriessmann, Friedrich Herrmann, Angelika Boehme
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Patent number: 6410635Abstract: Provided are curable coating compositions comprised of any of a variety of film-forming polymers containing reactive functional groups, a curing agent containing functional groups which are reactive with the functional groups of the polymer, and an exfoliated silicate material derived from a layered silicate which has been exfoliated with a polymer which is compatible with both the film-forming polymer and the curing agent. The inclusion of the exfoliated silicate material enhances coating properties such as adhesion, appearance, crater resistance, and rheology control.Type: GrantFiled: February 22, 1999Date of Patent: June 25, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Alan J. Kaylo, Richard F. Karabin, Tie Lan, Michael G. Sandala
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Patent number: 6387506Abstract: A resin composition for paper-coating, which comprises (A) a cross-linked amine compound which is a reaction product of (a) an aliphatic amine, (b) a glycidyl compound having at least two glycidyl groups in the molecule and (c) a compound selected from &agr;,&bgr;-unsaturated carbonyl compounds, &agr;,&bgr;-unsaturated nitrile compounds and &agr;-halocarboxylic acid groups; and (B) at least one selected from a group consisting of (B1) non-polymer nonvolatile substances and (B2) polyhydric alcohols, is provided, and the resin composition for paper-coating can realize high quality of coated paper by being mixed with a pigment and an aqueous binder and being coated on paper, which does not cause generation of formaldehyde and which does not tend to produce disadvantages such as thickening and deterioration in flowing property, and for paper using the resin composition and a coated paper produced by using the coating composition are also provided.Type: GrantFiled: November 26, 1999Date of Patent: May 14, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Akira Kawamura, Akira Tanikawa, Toshiyuki Hasegawa, Yutaka Shibata, Toshishige Hamaguchi
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Patent number: 6342580Abstract: A process for obtaining aminopolyamide-epichlorohydrin resins with a 1,3-dichloro-2-propanol content which is undetectable by ordinary means of vapor-phase chromatography. The process consists of passing the products resulting from the successive condensation of aminopolyamides and epichlorohydrin through two columns of activated carbon. In this way, aqueous resins are obtained which are free of toxic products, and which are particularly valuable as wet strength additives in the manufacture of papers for medical, cosmetic or food contact uses.Type: GrantFiled: February 2, 2000Date of Patent: January 29, 2002Assignee: AtofinaInventors: Henri Laurent, Thierry Dreyfus, Chantal Poulet, Serge Quillet
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Patent number: 6309707Abstract: The present invention relates to a coating composition comprising at least three components, characterized in that component (I) contains as binder at least one acrylate copolymer which is dissolved or dispersed in organic solvent and has a number-average molecular weight of between 1000 and 30,000, an OH number of from 40 to 200 and an acid number of from 5 to 150 and/or polyester resin having a number-average molecular weight of between 1000 and 30,000, an OH number of from 30 to 250 and an acid number of from 5 to 150 and/or polyurethane resin having a number-average molecular weight of between 1000 and 30,000, an OH number of from 20 to 200 and an acid number of from 5 to 150, and, if desired, a further binder, the binder components being selected such that a 50% strength solution of the binder in ethoxyethyl propionate has a viscosity at 23° C. of ≦2.Type: GrantFiled: December 20, 1996Date of Patent: October 30, 2001Assignee: BASF Coatings AGInventors: Bernd Mayer, Uwe Meisenburg, Egbert Nienhaus
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Patent number: 6294645Abstract: The invention relates to resin systems useful for imparting dry-strength to paper without substantially increasing the paper's wet-strength wherein the resin system comprises a cationic component and an anionic component. The invention also relates to the process for incorporating these resin systems into paper and the paper produced containing the resin systems.Type: GrantFiled: July 25, 1997Date of Patent: September 25, 2001Assignee: Hercules IncorporatedInventors: Anthony J. Allen, Elliott Echt, William W. Maslanka, Jeffrey C. Peters
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Patent number: 6255364Abstract: A crosslinkable waterborne dispersion of an epoxidized polydiene block polymer composition which comprises: (a) 10 to 65% w of a polydiene block polymer containing at least five olefinic epoxy groups per molecule which are sterically hindered, (b) 0.2 to 25% w of a compatible aminoplast, (c) 0.1 to 10% w of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. The invention also describes a water-continuous process and an inversion processes for making such dispersions.Type: GrantFiled: February 16, 1995Date of Patent: July 3, 2001Assignee: Shell Oil CompanyInventors: David John St. Clair, James Robert Erickson
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Patent number: 6248810Abstract: A crosslinkble waterborne dispersion useful as a coating on metal substrates of an epoxidized polydiene block polymer composition which comprises: (a) 10 to 65% by weight of a polydiene block polymer containing at least five olefinic epoxy groups per molecule which are sterically hindered, (b) 0.2 to 25% by weight of a compatible aminoplast, (c) 0.1 to 10% by weight of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. A water-continuous process and an inversion process for making a dispersion are also described.Type: GrantFiled: February 16, 1995Date of Patent: June 19, 2001Assignee: Shell Oil CompanyInventors: David John St. Clair, James Robert Erickson
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Patent number: 6228907Abstract: Two component water-based coatings, inks, adhesives and sealants prepared by reacting enhanced molecular weight epoxy emulsions with amine curatives.Type: GrantFiled: January 26, 2000Date of Patent: May 8, 2001Assignee: Air Products and Chemicals, Inc.Inventors: Lowell O. Cummings, Patrick A. Terrizzi, Norman A. Gac
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Patent number: 6204332Abstract: A water-dilutable coating after base neutralization comprises a polyhydroxyl-functional resin including a condensation resin such as a polyester or alkyd resin, and/or a polyhydroxyl-functional addition resin such as an acrylate resin or the reaction product of a carboxyl-functional acrylate resin and a hydroxyl-functional acrylate resin, and/or an emulsion copolymer, an at least partially monoalcohol-etherified amino resin, and a strong organic or inorganic acid crosslinking catalyst non-ionically blocked with a monoepoxide, a diepoxide or a lactone.Type: GrantFiled: May 18, 1998Date of Patent: March 20, 2001Assignee: Vianova Resins AGInventors: Werner Wilfinger, Ingo Kriessmann, Friedrich Herrmann, Angelika Boehme
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Patent number: 6121350Abstract: One component water-based coatings, inks, adhesives and sealants comprising enhanced molecular weight epoxy emulsions and inactivated amines.Type: GrantFiled: March 17, 1997Date of Patent: September 19, 2000Assignee: Air Products and Chemicals, Inc.Inventors: Lowell O. Cummings, Patrick A. Terrizzi, Norman A. Gac
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Patent number: 6063840Abstract: Two component water-based coatings, inks, adhesives and sealants prepared by reacting enhanced molecular weight epoxy emulsions with amine curatives.Type: GrantFiled: June 12, 1998Date of Patent: May 16, 2000Assignee: Air Products and Chemicals, Inc.Inventors: Lowell O. Cummings, Patrick A. Terrizzi, Norman A. Gac
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Patent number: 5908912Abstract: An electrodepositable coating composition is provided comprising (a) an active hydrogen-containing, cationic salt group-containing resin electrodepositable on a cathode; (b) a curing agent for transurethanation, transamidation or transesterification curing like at least a partially capped polyisocyanate curing agent; and (c) a catalytic mixture of bismuth and an amino acid or amino acid precursor. Optionally, an auxiliary acid may be present to increase the effectiveness of the amino acid in the mixture with bismuth.Type: GrantFiled: June 3, 1997Date of Patent: June 1, 1999Assignee: PPG Industries Ohio, Inc.Inventors: Raphael O. Kollah, Matthew S. Scott, Gregory J. McCollum, Joseph A. Bethoski
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Patent number: 5894071Abstract: Two-component adhesive-, sealing- or coating compositions are being described which are separately packed, and comprise the component A and the component D, whereby the component A is curing as soon as it gets in touch with water or the component D which contains the curing agent for the component A.The component D can be, or a component B containing an ingredient which is curing at the contact of water, or, possibly, at the contact with the component A, orthe component D can also be a mixture of solid matter and a volatile ingredient which is causing the cross-linking of the component A.The advantage of the novel two-component systems is that the component D is working as a curing agent for the component A, however, a surplus thereof is, or self-curing, or it does not leave a nuissance residue in the cured composition.Type: GrantFiled: December 6, 1996Date of Patent: April 13, 1999Assignee: Sika AG, vorm. Kaspar Winkler & Co.Inventors: Peter Merz, Norman E. Blank, Hans-Peter Tschan, Reinhard Ernst Wappmann, Lutz Zabel
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Patent number: 5888655Abstract: A composite coating is described. The composite comprises a substrate; one or more primer coating layers disposed on the substrate; and at least one topcoat layer disposed on the outermost primer coating layer. The outermost primer coating layer is obtained by reaction of a primer composition that includes a novolac resin having at least one carbamate group and an aminoplast resin.Type: GrantFiled: June 30, 1997Date of Patent: March 30, 1999Assignee: BASF CorporationInventors: Paul J. Harris, Gregory G. Menovcik
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Patent number: 5854314Abstract: A crosslinkable waterborne dispersion of a hydroxy functional polydiene polymer composition which comprises: (a) 10 to 65% w of a hydroxy functional polydiene polymer, (b) 0.2 to 25% w of a compatible amino resin, (c) 0.1 to 10% w of a surfactant which is nonionic or anionic and has a volatile cation, and (d) the balance water. The invention also describes a water-continuous process and an inversion processes for making such dispersions.Type: GrantFiled: October 2, 1997Date of Patent: December 29, 1998Assignee: Shell Oil CompanyInventors: David John St. Clair, James Robert Erickson
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Patent number: 5739185Abstract: The present invention provides a cationic electrodepositable coating composition comprising:?I! a polyurethane-modified epoxy resin-amine adduct obtained by a reaction of:(A) a polyurethane compound having one terminal isocyanate group in the molecule, obtained by a reaction of (a) a polyhydroxy compound having a number-average molecular weight of 50-8,000, (b) a polyisocyanate compound, and (c) a compound having one active hydrogen atom in the molecule,(B) a bisphenol type epoxy resin having at least two epoxy groups in the molecule, and(C) an active-hydrogen-containing amine compound, and ?II! a nonionic film-forming resin.Type: GrantFiled: August 16, 1995Date of Patent: April 14, 1998Assignee: Kansai Paint Co., Ltd.Inventors: Hidehiko Haneishi, Masanobu Kudoh, Koji Kamikado
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Patent number: 5612143Abstract: One component water-based coatings, inks, adhesives and sealants comprising enhanced molecular weight epoxy emulsions and inactivated amines.Type: GrantFiled: June 9, 1995Date of Patent: March 18, 1997Assignee: Adhesive Coatings Co.Inventors: Lowell O. Cummings, Patrick A. Terrizzi, Norman Gac
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Patent number: 5460889Abstract: A coating composition comprises an alkyd resin based topcoat and a water dilutable coating comprising an epoxy resin-modified polyester binder which is water-dilutable upon base neutralization of the free carboxyl groups and is prepared by the reaction of (A) a polyester containing (cyclo)aliphatic groups having at least six carbon atoms derived from (a.sub.1) a polycarboxylic acid with at least three carboxyl groups and/or (a.sub.2) a polyol with at least one carboxyl group, (a.sub.3) a polycarboxylic acid with two carboxyl groups and (a.sub.4) a polyol; and (B) a bisphenol epoxide resin.Type: GrantFiled: January 10, 1995Date of Patent: October 24, 1995Assignee: BASF AktiengesellschaftInventors: Lutz-Werner Gross, Ulrich Poth, Dieter Hille, Klaus Weidemeier
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Patent number: 5441996Abstract: One component water-based coatings, inks, adhesives and sealants comprising enhanced molecular weight epoxy emulsions and inactivated amines.Type: GrantFiled: January 21, 1994Date of Patent: August 15, 1995Assignee: Adhesive Coatings Co.Inventors: Lowell O. Cummings, Patrick A. Terrizzi, Norman Gac
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Patent number: 5438083Abstract: A colloidal particle dispersion is disclosed, comprising mainly (1) a fumed silica or fumed aluminum silicate, (2) a colloidizing agent (aid) which is at least one compound selected from the group consisting of a phosphoric acid compound, a molybdic acid compound, a boric acid compound, and a silicic acid compound, and (3) water, and a method for preparing the same is disclosed. Further, a water-based coating composition is disclosed, which comprises a water-based coating composition and incorporated therein a colloidal particle dispersion comprising mainly (1) fumed silica or fumed aluminum silicate, (2) a colloidizing agent (aid) which is at least one compound selected from the group consisting of a phosphoric acid compound, a molybdic acid compound, a boric acid compound, and a silicic acid compound, and (3) water, and a method for preparing the same is disclosed. Furthermore, the coating method with which the above water-based coating composition on a metal substrate is disclosed.Type: GrantFiled: January 21, 1994Date of Patent: August 1, 1995Assignee: Nippon Paint Co., Ltd.Inventors: Masaaki Takimoto, Minao Izumi, Hisataka Yamamoto
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Patent number: 5409972Abstract: This invention relates to a process for the preparation of self-crosslinking cationic paint binders which can be diluted with water after protonation and are based on modified aminoalkylation products of phenols; to the binders prepared by this process and to their use for formulating water-dilutable paints, in particular electrodeposition paints which can be deposited cathodically. The process is characterized in that an aminoalkylation product of a phenol containing at least one secondary amino group is reacted with epoxide compounds, and after temperature treatment, the reaction product is reacted with partly blocked isocyanate compounds. The process permits the use of blocking agents which allow stoving temperatures in the range of 130 to 150.degree. C.Type: GrantFiled: May 7, 1992Date of Patent: April 25, 1995Assignee: Vianova Kunstharz, A.G.Inventors: Roland Feola, Willibald Paar, Georg Pampouchidis, Johann Gmoser, Helmut Honig
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Patent number: 5389435Abstract: The present invention is a flame retardant composite material comprising a laminate of (A) a glass scrim coated with an inorganic filler and an epoxy resin and (B) a structural composite of graphite fibers and an epoxy resin.Type: GrantFiled: May 20, 1993Date of Patent: February 14, 1995Assignee: ICI Composites Inc.Inventor: Hugh A. Yap
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Patent number: 5386000Abstract: Described is a flexible adhesive formulation for bonding a semiconductor device to a flexible substrate and a flexible card containing a semiconductor device which can be processed in a computer.Type: GrantFiled: December 3, 1993Date of Patent: January 31, 1995Assignee: Johnson Matthey Inc.Inventor: My N. Nguyen
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Patent number: 5384386Abstract: Synthetic resins are based on products which are obtainable by reactingA) epoxy-carrying resins based ona.sub.1) polyhydric phenols anda.sub.2) at least one compound selected from the group consisting of.alpha..sub.1) polyoxyalkylenepolyols,.alpha..sub.2) polyoxyalkylenepolyepoxides,.alpha..sub.3) polyoxyalkylenepolyamines and.alpha..sub.4) polyhydric aliphatic alcohols and,if desired,a.sub.3) phenolic compounds which react monofunctionally toward epoxides,B) monocarboxylic acids of 5 to 30 carbon atoms,C) amines which contain at least one primary and one tertiary amino group andD) formaldehyde-donating compounds.Type: GrantFiled: March 8, 1994Date of Patent: January 24, 1995Assignee: BASF Lacke & Farben AGInventors: Klaus Huemke, Gerhard Hoffmann
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Patent number: 5380565Abstract: A substrate is spray coated with a composition containing an epoxy resin-modified polyester binder which is water-dilutable upon base neutralization of the free carboxyl groups and is prepared via the reaction of A) a polyester containing (cyclo)aliphatic groups having at least six carbon atoms derived from (a.sub.1) a polycarboxylic acid with at least three carboxyl groups and/or (a.sub.2) a polyol with at least one carboxyl group, and (a.sub.3) a polycarboxylic acid with two carboxyl groups and (a.sub.4) a polyol; and (B) a bisphenol epoxy resin.Type: GrantFiled: October 5, 1993Date of Patent: January 10, 1995Assignee: BASF L+F AktiengesellschaftInventors: Lutz-Werner Gross, Ulrich Poth, Dieter Hille, Klaus Weidemeier
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Patent number: 5356959Abstract: Epoxy resins obtainable by reactingA) a polyfunctional epoxide, which carries on average 1.5 to 2.5 epoxy groups per molecule and has an epoxide equivalent weight of from 100 to 2000, with based on 1 mol of epoxy groupsB) from 0.1 to 0.5 mol of an alkylphenol, the alkyl groups of which carry from 6 to 20 carbon atoms, andC) from 1 to 100 mmol of a polyoxyalkylenediol obtained from 1,2-propylene oxide, or of a copolymer obtained from 1,2-propylene oxide and other alkylene oxides, which has an average molecular weight of from 200 to 5000 and, on average, from 1 to 4 sulfonic acid groups bonded to methyl groups per molecule, and alsoD) from 0.2 to 0.3 mol of a diol, which isd1) a phenolic diol and/ord2) a polyoxyalkylenediol which has an average molecular weight of from 200 to 5000,with the proviso that the reaction product has an epoxide equivalent weight of from 1000 to 5000, can be converted to pigment resins suitable for electrodeposition coating and pigment pastes can then be prepared from said resins.Type: GrantFiled: July 27, 1993Date of Patent: October 18, 1994Assignee: BASF Lacke & Farben AktiengesellschaftInventors: Klaus Huemke, Christian Sinn
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Patent number: 5298538Abstract: Plasticizing resins, aqueous dispersions of cationic resins, and methods of making the same for use in cathodic electrodeposition are disclosed. The resins are formed from reacting a polyoxyalkylenepolyamine, a phenol, and a formaldehyde. The reactants may further include a block building unit derived from a polyepoxide. When used in combination with other conventional electrodepositable resins, deposited films with improved mechanical properties and descreased tendency toward cratering are obtained.Type: GrantFiled: April 11, 1990Date of Patent: March 29, 1994Assignee: BASF CorporationInventors: Klaus Cibura, Yali F. Hallock, John A. Gilbert, John D. McGee
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Patent number: RE34766Abstract: A laminating and coating adhesive based on an aqueous dispersion of(1) a copolymer of a vinyl ester, and/or an acrylic acid ester, and/or a further monomer and an ethylenically-unsaturated functional group-containing monomer having from 3 to 18 carbon atoms and hydroxy and carbonyl groups as functional groups, such as a monocarboxylic acid or dicarboxylic acid and/or N-methylol-(meth)-acrylamide,(2) an epoxy compound, and(3) an amine hardener.The adhesive gives a laminate bond with especially high resistance to peeling even in the case of thermal stress and/or in the presence of water.Type: GrantFiled: May 6, 1991Date of Patent: October 25, 1994Assignee: Wacker-Chemie GmbHInventors: Ekkehard Merz, Robert Singer