Three Oxygen Atoms Are Directly Bonded To Three Nuclear Carbon Atoms Of The Nitrogen Ring, E.g., (iso) Cyanurate, Etc. Patents (Class 524/101)
  • Patent number: 5356964
    Abstract: A polyolefin composition comprising a polyolefin, and the following components:(A) a phenolic compound such as 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl) isocyanurate;(B) an acrylate compound represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl of 1 to 5 carbon atoms, R.sup.2 is an alkyl of 1 to 8 carbon atoms, R.sup.3 is hydrogen or an alkyl of 1 to 8 carbon atoms, and R.sup.4 is hydrogen or methyl;(C) an organic phosphorous compound such as bis(2,6-di-t-butyl-4-methylphenyl) pentaerythritol diphosphite; and(D) a hindered piperidine compound such as poly[{6-(1,1,3,3-tetramethylbutyl)imino-1,3,5-triazin-2,4-diyl}{(2,2,6,6-t etramethyl-4-piperidyl)imino}hexamethylene{(2,2,6,6-tetramethyl-4-piperidyl )imino}]. This composition is stable against thermal processing, thermal oxidation, light oxidation and discoloration, and it is especially useful for fibers and films.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: October 18, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tamaki Ishii, Shinichi Yachigo, Fumitoshi Kojima, Kanako Ida
  • Patent number: 5356983
    Abstract: Small particles of ammonium dihydrogen phosphate, diammonium hydrogen phosphate, or a mixture thereof provide a higher Limiting Oxygen Index ("LOI") to polyolefin compositions containing the small particles than do larger particles of the same substance. In many instances, improvement in one or more other properties, such as for example, processability, appearance, UL-94 rating, tensile strength, tensile modulus, and/or elongation at break is also obtained.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: October 18, 1994
    Assignee: PPG Industries, Inc.
    Inventors: Bhima R. Vijayendran, Seetha Eswarakrishnan, Carol L. Knox
  • Patent number: 5350785
    Abstract: Stabilized chlorine-containing polymer compositions comprising a chlorine-containing polymer and a stabilizer mixture comprising:a) at least one cyclic or non-cyclic, sterically hindered amine,b) at least one organic zinc compound and/or inorganic zinc compound from the series consisting of carbonates, chlorides, sulfates, oxides, hydroxides, basic oxides and mixed oxides, andc) at least one compound from the series consisting of the crystalline alkali metal/alkaline earth metal aluminosilicates, and, if desired,d) at least one 1,3-diketone and/ore) at least one organic or inorganic calcium compound.Polymer compositions of this type are preferably employed for slush mould and crash pad applications.
    Type: Grant
    Filed: May 6, 1993
    Date of Patent: September 27, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans J. Sander, Olaf-Rene Hartmann, Hermann O. Wirth, Wolfgang Wehner
  • Patent number: 5346944
    Abstract: A polyolefin resin composition for a film which consists essentially of a mixture of 100 parts by weight of a polyolefin resin with (a) 0.01-3.0 parts by weight of an antiblocking agent, the surface OH group content of which is 200 .mu.mol/g or less. The resin composition may further contain (b) 0.05-2.0 parts by weight of an antistatic agent consisting of (A) a glycerine fatty acid ester and (B) an alkyldiethanolamide in a weight ratio of A/B of 50/50-95/5 for antistatic film or (c) 0.05-3.0 parts by weight of at least one member selected from the group consisting of polyhydric alcohol fatty acid esters, alkylene oxide adducts of polyhydric alcohol fatty acid esters and higher alcohol-alkylene oxide adducts as an antifogging agent, or (d) 0.01-3.0 parts by weight of a phenol type antioxidant and (e) 0.01-0.2 part by weight of a phosphorous type antioxidant for forming a stabilized film.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: September 13, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Haruo Hayashida, Ryoichi Nomura, Satoru Koyama
  • Patent number: 5342867
    Abstract: The present invention provides an adhesive composition comprising a polyurethane resin and, as adhesion promoter, a compound of formula I: ##STR1## in which Z is an organic radical which is derived from an aliphatic aromatic or heterocyclic polyisocyanate containing m+n isocyanate groups; m is a value greater than or equal to 1; n is a value greater than or equal to 0; m+n is a value greater than or equal to 2; Y is 0 or S; X is 0, S or N--C.sub.1 -C.sub.4 alkyl; R.sub.1 is C.sub.1 -C.sub.8 alkylene; R.sub.2 is C.sub.1 -C.sub.4 alkyl or two groups R.sub.2 together for m a C.sub.1 -C.sub.4 alkylene residue; R.sub.3 is C.sub.1 -C.sub.4 alkyl or phenyl; and q is a value from 0 to 2.
    Type: Grant
    Filed: September 30, 1993
    Date of Patent: August 30, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Glen R. Ryan, Steven A. Allen, David A. Taylor
  • Patent number: 5328948
    Abstract: A composition comprising a halopolymer, such as an ethylene/chlorotrifluoroethylene copolymer, an effective stabilizing amount of an ionomer, and an effective stabilizing amount of a compound such as a phosphite of an organic polyhydric phenol; a thioester; a phosphite; or a hindered phenolic antioxidant. Preferred ionomers are metal salts of ethylene-acrylic acid copolymers, and metal salts of sulfonated polystyrenes. The stabilized halopolymers have improved resistance to thermal degradation and suffer less discoloration when subjected to high melt processing or extrusion molding temperatures.
    Type: Grant
    Filed: September 23, 1992
    Date of Patent: July 12, 1994
    Assignee: Ausimont, U.S.A., Inc.
    Inventors: Chii-Shu Chen, L. Lawrence Chapoy
  • Patent number: 5326805
    Abstract: A flame-retardant plastic molding composition of improved stability comprises50 to 85% by weight, based on the total amount of the molding composition, of an olefin polymer and15 to 50% by weight, based on the total amount of the molding composition, of a flameproofing system comprising 80 to 50% by weight of an ammonium polyphosphate of the formula (NH.sub.4 PO.sub.3).sub.n, in which n is a number from 200 to 1000 (=component A) and50 to 20% by weight of a reaction product of tris(2-hydroxyethyl) isocyanurate (THEIC) of the formula ##STR1## with an aromatic polycarboxylic acid of the formulaAr(COOH).sub.m(=component B).As a result of the flameproofing system to be employed according to the invention, not only is the processing temperature of the plastics molding composition increased, but the water-solubility of components of the molding composition after processing is reduced significantly.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: July 5, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Martin Sicken, Wolfgang Wanzke
  • Patent number: 5326793
    Abstract: The tensile strength and flexural strength of glass fiber reinforced aromatic polycarbonate resin/poly(butylene terephthalate) resin blends is improved by employing a glass fiber reinforcing agent treated with a sizing agent selected from epoxy functional cyanurates and isocyanurates. The reinforced blends are useful for making molded articles.
    Type: Grant
    Filed: August 10, 1990
    Date of Patent: July 5, 1994
    Assignee: General Electric Company
    Inventors: Robert R. Gallucci, Kelvin T. Okamoto
  • Patent number: 5308902
    Abstract: Biphosphites of formula I ##STR1## wherein m is 0, 1 or 2,n is 1 to 4 or 6,R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different, and A is the radical of an at least n-hydric alcohol or phenol, which radical is attached to the P atom or atoms through the alcoholic or phenolic O atom or atoms, obtainable by reacting a compound of formula II ##STR2## wherein m is 0, 1 or 2, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different and R.sub.2 ' is phenyl, C.sub.1 -C.sub.12 alkylphenyl or C.sub.1 -C.sub.4 alkyl, with a polyether polyol or polyether/ester polyol, the hydroxy functions of said polyether polyol or polyether/ester polyol being partially or completely esterified with the ##STR3## are suitable for use as stabilizers, especially processing stabilizers, for organic polymers, preferably PVC resins, high density polyethylene and propylene.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: May 3, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Holger Andreas, Alfred Renner, Horst Zinke
  • Patent number: 5302497
    Abstract: Compounds of the formula ##STR1## wherein R.sub.o, is hydrogen or alkylene-COOR where R is alkyl or hydroxyalkyl, R.sub.1 is hydrogen, alkyl, hydroxyalkyl, alkenyl or acyl, R.sub.2 and R.sub.3 are independently hydrogen, alkyl, alkenyl or alkoxy, R.sub.6 is hydrogen or alkyl, and X is --CH.sub.2 --, --NH--, --S-- or --O--, are suitable as UV absorbers for use in photosensitive organic materials in combination with a sterically hindered amine or hydroxyphenylbenzotriazole derivative.
    Type: Grant
    Filed: August 19, 1992
    Date of Patent: April 12, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Godwin Berner, Andreas Valet
  • Patent number: 5286775
    Abstract: A halogen-free composition comprising 100 parts of polyolefin resin grafted with from about 1 to about 10 parts maleic anhydride; from about 0.1 part to about 10 parts of a free radical catalyst therefor, from about 0.5 part to about 10 parts of an antioxidant, and from about 5 parts to about 500 parts of at least one ammonium polyphosphate containing flame retardant.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: February 15, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Pradip K. Bandyopadhyay
  • Patent number: 5238980
    Abstract: A stereoregular, branched-mono-lolefin polymer composition that has reduced corrosion tendencies is provided. This polymer composition comprises:(a) a stereoregular, branched-mono-1-olefin polymer;(b) tris(3,5-di-t-butyl-40hydroxybenzyl)isocyanurate;(c) poly[[6-[(1,1,3,3-tetramethylbutyl)amino]-s-triazine-2,-4-diyl][(2,2,6,6-t etramethyl-4-piperidyl)imino]hexamethylene-[(2,2,6,6-tetramethyl-4-piperidy l)imino]]; and(d) a hydrocarbylsulfide.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: August 24, 1993
    Assignee: Phillips Petroleum Company
    Inventor: Kenneth W. Willcox
  • Patent number: 5238979
    Abstract: Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and R.sub.6 is hydrogen or alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.
    Type: Grant
    Filed: March 12, 1990
    Date of Patent: August 24, 1993
    Assignee: Asahi Denka Kogyo K.K.
    Inventors: Tohru Haruna, Kazunori Nishikawa
  • Patent number: 5227416
    Abstract: When tris(2-hydroxyethyl) isocyanurate and a long chain amine are employed together in intumescent flame retardant compositions, tris(2-hydroxyethyl) isocyanurate bloom is substantially reduced or even eliminated, and yet the flame retardant effectiveness of the tris(2-hydroxyethyl) isocyanurate is substantially retained.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: July 13, 1993
    Assignee: PPG Industries, Inc.
    Inventors: Carol L. Knox, Suresh B. Damle
  • Patent number: 5221743
    Abstract: This invention relates to a process for preparing a trimer by the steps of: (a) cyclotrimerizing a polyisocyanate in the presence a polymer-bound trimerization catalyst by contacting said polyisocyanate with said catalyst at a temperature of between about 20.degree. and about 135.degree. C. in a reaction to form an isocyanurate-containing cyclotrimerized isocyanate wherein a portion of the isocyanate moieties comprising said polyisocyanate are converted to isocyanurate groups, and (b) separating said catalyst from said cyclotrimerized isocyanate in order to stop said reaction after a desired amount of isocyanate moieties in said polyisocyanate have been converted to isocyanurate moieties.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: June 22, 1993
    Assignee: Olin Corporation
    Inventors: Stephen L. Goldstein, Curtis P. Smith
  • Patent number: 5210120
    Abstract: Polymeric compositions endowed with high self-extinguishing characteristics o flame, based on thermoplastic polymers or polymers having elastomeric properties, especially olefin polymers and copolymers, comprising:a) from 89 to 40 parts by weight of a thermoplastic polymer or of a polymer having elastomeric properties;b) from 8 to 33 parts by weight of one or more phosphates and/or phosphonates of ammonium or of amine;c) from 3 to 27 parts by weight of one or more oligomeric compounds derived from the 2,4-diamino-6-hydroxy-1,3,5-triazine, having the general formula (I): ##STR1##
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: May 11, 1993
    Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e Technologica
    Inventors: Roberto Cipolli, Enrico Masarati, Gilberto Nucida, Roberto Oriani, Mario Pirozzi
  • Patent number: 5208334
    Abstract: The present invention is directed to a process for the production of a polyisocyanate composition having an NCO content of 10 to 47% by weight and a viscosity of less than 2,500 mPa.s, wherein the viscosity is determined from a mixture containing less than 1% by weight of the starting organic diisocyanate, and containing isocyanurate and allophanate groups in a molar ratio of monoisocyanurates to monoallophanates of 10:1 to 1:5 bya) catalytically trimerizing a portion of the isocyanate groups of an organic diisocyanate having (cyclo)aliphatically bound isocyanate groupsb) adding 0.01 to 0.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: May 4, 1993
    Assignee: Miles Inc.
    Inventors: Terry A. Potter, William E. Slack
  • Patent number: 5204393
    Abstract: An improved flame retardant polyolefin is disclosed which comprises a combination of ammonium polyphosphate; tris(2-hydroxyethyl) isocyanurate; and melamine cyanurate; and a selected silica in an amount from 0.5 percent to an amount equal to one-half the amount by weight of THEIC, wherein the selected silica meets defined surface area, particle size and absorption criteria.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: April 20, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Raymond W. Nalepa, Daniel J. Scharf
  • Patent number: 5204392
    Abstract: An improved flame reardant polyolefin is disclosed which comprises a combination of ammoniumm polyphosphate; tris(2-hydroxyethyl) isocyanurate; and a selected silica in an amount from 0.5 percent to an amount equal to one-half the amount by weight of THEIC, wherein the silica meets defined surface arera, particle size and absorption criteria.
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: April 20, 1993
    Assignee: Hoechst Celanese Corporation
    Inventors: Raymond W. Nalepa, Daniel J. Scharf
  • Patent number: 5200445
    Abstract: Polymeric compositions endowed with high characteristics of flame self-esguishing, based on thermoplastic polymers or showing elastomeric properties, especially olefin polymers and copolymers, comprising:a) from 89 to 40 parts by weight of a thermoplastic polymer or having elastomeric properties;b) from 8 to 33 parts b.w; of one or more phosphates and/or phosphonates of ammonium or of an amine;c) from 3 to 27 parts b.w.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: April 6, 1993
    Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Enrico Masarati, Gilberto Nucida, Mario Pirozzi, Roberto Oriani
  • Patent number: 5196465
    Abstract: The present invention relates to polymeric thermoplastic materials stabilized against thermal degradation by means of using one or more compounds of the formula (I) ##STR1## in which R.sub.1 is e.g. C.sub.1 -C.sub.4 alkyl or phenyl and n is e.g. 1 or 2 and, when n is 1, R.sub.2 is e.g. C.sub.1 -C.sub.4 alkyl, phenyl or cyclohexyl, and, when n is 2, R.sub.2 is e.g. C.sub.2 -C.sub.6 alkylene, methylenedicyclohexylene, a group ##STR2## methylphenylene or methylenediphenylene.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: March 23, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Roberto Scrima, Graziano Zagnoni, Valerio Borzatta
  • Patent number: 5194466
    Abstract: Piperidine-triazine compounds of the general formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 is e.g. 2,2,6,6-tetramethyl-4-piperidyloxy or 1,2,2,6,6-pentamethyl-4-piperidyloxy, m is e.g. 2, 3 or 4 and, if m is 2, R.sub.3 is e.g. a group of the formula (IIIc) or (IIIe) ##STR2## in which R.sub.10 and R.sub.12 which can be identical or different are e.g. hydrogen, cyclohexyl, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, R.sub.11 is e.g. C.sub.2 -C.sub.6 alkylene, R.sub.14 is e.g. hydrogen or methyl and p is e.g. 2, and, if m is 3 or 4, R.sub.3 is e.g. a group of the formula (IV) ##STR3## in which R.sub.15 and R.sub.19 which can be identical or different are e.g. hydrogen, 2,2,6,6-tetramethyl-4-piperidyl or 1,2,2,6,6-pentamethyl-4-piperidyl, R.sub.16, R.sub.17 and R.sub.18 which can be identical or different are e.g. C.sub.2 -C.sub.3 alkylene and q is e.g.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: March 16, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Valerio Borzatta, Franca Masina
  • Patent number: 5189085
    Abstract: Flameproof plastic which contains urea cyanurate as flame retardant.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: February 23, 1993
    Assignee: Chemie Linz Gesellschaft m.b.H.
    Inventor: Heinrich Horacek
  • Patent number: 5189087
    Abstract: Plastic compositions for the production of deep-drawn films have the following composition:______________________________________ Parts By Weight ______________________________________ Polyvinyl chloride 35-40 Acrylate rubber/PVC (1:1) 40-50 Plasticizer 5-10 Polystyrene/polyethylenebutylene 1-10 block copolymer Processing agent 4-5 ______________________________________The plastic film products from these materials have a high degree of strength and resistance to aging. Inhomogeneities and hard particles in the films are eliminated.
    Type: Grant
    Filed: July 12, 1988
    Date of Patent: February 23, 1993
    Assignee: J. H. Benecke GmbH
    Inventor: Artur Wildenau
  • Patent number: 5162406
    Abstract: A stabilized composition of matter comprises: (a) at least one block polymer comprising at least one non-elastomeric block and at least one polybutadiene block and (b) a stabilizing composition in an amount effective to improve heat or oxidative stability of the block polymer, said composition comprising (i) at least one hydroxyphenylalkylenyl isocyanurate and (ii) at least one polyphenylene diphosphonite. An alkylidene bisphenol is optionally added to achieve improved color stability.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: November 10, 1992
    Assignee: The Dow Chemical Company
    Inventors: Wendell W. Meyer, Grace Y. Lo
  • Patent number: 5155153
    Abstract: A stabilizing composition for thermoplastic organic polymers containing measured quantities of: (a) a sterically hindered phenol; (b) a triarylphosphite; and (c) a dialkylthiodipropionate. Stabilized polymer compositions are also described containing a thermoplastic organic polymer, in particular a polyolefin, and a stabilizing quantity of said stabilizing composition, which possess excellent characteristics in relation to their melt flow index and color when subjected to repeated extrusion and in relation to their long-term thermal stability.
    Type: Grant
    Filed: September 25, 1991
    Date of Patent: October 13, 1992
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Roberto Podesta, Giovanni Sandre
  • Patent number: 5153247
    Abstract: There is disclosed a polycarbonate composition which comprises having a melt flow rate of 5 to 50 g/10 min and composed of:(a) 30 to 65 parts by weight of a thermoplastic aromatic polycarbonate,(b) 70 to 35 parts by weight of glass fibers with an average diameter of 3 to 15 .mu.m, and(c) 0.01 to 15 parts by weight of at least one component selected from the group consisting of (c-1) to (c-3) shown below formulated therein based on 100 parts by weight of the total amount of (a) and (b):(c-1) 0.3 to 10 parts by weight of a brominated polystyrene with an average particle size of 0.1 to 50 .mu.m;(c-2) 0.3 to 10 parts by weight of zinc sulfide with an average particle size of 0.1 to 50 .mu.m; and(c-3) 0.01 to 5 parts by weight of a melamine-cyanuric acid adduct with an average particle size of 0.1 to 50 .mu.m.
    Type: Grant
    Filed: December 11, 1991
    Date of Patent: October 6, 1992
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Michiya Okamura, Hiroshi Yui, Takeshi Hatakeyama, Michio Ohmori, Kouich Sagisaka, Kazuyuki Hata, Katsuhiko Yamada, Kazuhide Hayama
  • Patent number: 5153246
    Abstract: An ethylenically unsaturated isocyanurate composition suitable for formulating SMC systems for the molding of structural automobile body parts requiring high levels of adhesion is prepared by blending the isocyanurate composition with a minor amount of a dicyclopentadiene terminated unsaturated polyester. These parts have excellent retention of physical properties when exposed to high temperature.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: October 6, 1992
    Assignee: Reichhold Chemicals, Inc.
    Inventors: Joseph B. Michaels, James J. Phipps, John W. Lauritzen
  • Patent number: 5147912
    Abstract: A two step method of preparing fire retardant thermoplastic polymer granules from fire retarding agents and thermoplastic polymers in a stationary granulating cylinder containing mixing elements mounted to a central rotating shaft which fluidizes and throws contained materials toward the center of the cylinder, forcing axial and radial flows simultaneously on the materials thereby forming granules. In the first step, a fire retarding agent is mixed with a fluid thermoplastic polymer at a temperature exceeding the solidification point of the polymer until a homogeneous mixture is formed. In the second stage, the mixture is solidified by cooling while the granulating cylinder continues to operate until the fire retardant agent is bound together in homogeneous granular form by a matrix of solid thermoplastic polymer. Suitable fire retarding agents include alumina, phosphates, borates, melamine, melamine cyanurate, metal cyanurates, and halogenated phenols.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: FR Polymers, Inc.
    Inventor: William P. Moore
  • Patent number: 5147910
    Abstract: Substituted 3H-1,3,2-oxazaphospholidines of formula I ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4 and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, James L. Hyun, Sai P. Shum, Raymond Seltzer
  • Patent number: 5147911
    Abstract: Compounds of formula I ##STR1## wherein n is 2-4, R.sub.1 is alkyl, cycloalkyl, phenylalkyl, phenyl or a radical of formula II ##STR2## R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, or R.sub.3 and R.sub.4 together are alkyl, R.sub.5 and R.sub.6 are independently hydrogen, alkyl, cycloalkyl or phenylalkyl, R.sub.7 is hydrogen, alkyl or a group of the formula --(CH.sub.2).sub.k COOR.sub.8, where k is 0-2 and R.sub.8 is hydrogen or alkyl, and T is an n-valent hydrocarbon radical which may be interrupted by heteroatoms, are useful stabilizers for substrates subject to the deleterious effects of oxygen, heat and/or actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Hofmann, Paul A. Odorisio, Glen T. Cunkle, Don Sabrsula
  • Patent number: 5147909
    Abstract: Substituted 1,3,2-benzoxazaphospholidines of formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen, alkyl, cycloalkyl, phenylalkyl or aryl, n is 1 to 4, and T is an n-valent aliphatic or aromatic hydrocarbon radical are effective in stabilizing organic materials against the deleterious effects of oxygen, heat and actinic radiation.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: September 15, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 5135974
    Abstract: A method of preparing fire retardant concentrates wherein a base soluble cyanurate is dissolved in base and mixed with a fluid thermoplastic polymer. An amino-s-triazine is then reacted in-situ with the solubulized cyanurate to precipitate very fine insoluble cyanurate-amino-s-triazine adduct evenly distributed in the polymer. The mixture is cooled below its solidification point, binding the film particles of the insoluble adduct together by a matrix of solid thermoplastic polymer. The solidified matrix bound adduct is comminuted to form particulate thermoplastic fire retardant concentrate. The fluid thermplastic polymer may be a melt or an aqueous dispersion of a stable polymer such as nylon, polyolefin, polycarbonate, polyester, polystyrene, and polybutadiene. The particulate granules may contain concentrations as high as 65 to 95 percent of the adducts produced from soluble cyanurates such as sodium isocyanurate, and base solubulized isocyanuric acid and chlorocyanuric acid.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: August 4, 1992
    Assignee: FR Polymers, Inc.
    Inventor: William P. Moore
  • Patent number: 5134181
    Abstract: A polyethylene stabilizer composition comprises:A) one or more compounds with piperidine groups of the formula (I) or (Ia) ##STR1## in which R is hydrogen, C.sub.1 -C.sub.4 -alkyl, allyl, benzyl, acetyl, acryloyl, 2-hydroxyethyl or 2-hydroxypropyl andB) one or more metal compounds such as oxides and hydroxides of Al, Mg and Zn and, if appropriate, one or more salts of Al, Ba, Ca, Mg, Sr and Zn with C.sub.1 -C.sub.22 -carboxylic acids.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: July 28, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Franca Masina
  • Patent number: 5132344
    Abstract: A stabilized polyethylene composition containing catalyst residues comprising at least one transition metal comprises (a) polyethylene, (b) 100 to 2000 ppm by weight based on the total weight of the composition of one or more antioxidants of the phenolic type and (c) 100 to less than 2000 ppm by weight, based on the total weight of the composition of zinc oxide but substantially no calcium stearate. The composition has improved color and improved resistance to coloration effects.
    Type: Grant
    Filed: April 30, 1991
    Date of Patent: July 21, 1992
    Assignee: BP Chemicals Limited
    Inventor: Jean-Baptiste Matteodo
  • Patent number: 5130402
    Abstract: Coating compositions, comprising (I) blocked urethane prepolymers, particularly those derived from tetramethyl-xylylene diisocyanate, and (II) curatives, such as polyether polyamines, oxyalkylene ethers of polyamines and ketimines of polyamine, are disclosed. Plastisol compositions, which comprise vinyl chloride polymers, plasticizers, and adhesion promoters, comprising (I) a blocked polyisocyanate, such blocked urethane prepolymers as above, or isocyanurate or biuret-containing blocked polyisocyanate, and (II) active amino group-containing mono- or poly-amide compounds, are also disclosed. These compositions are useful for coating metal surface to improve resistance to chipping.
    Type: Grant
    Filed: June 30, 1989
    Date of Patent: July 14, 1992
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Hajime Akiyama, Shunji Matsunaga, Yoshio Taguchi, Mitsuo Koseki, Takashi Takemoto
  • Patent number: 5128397
    Abstract: Hot melt adhesive compositions stabilized against thermal degradation, discoloration, skin formation and substantial viscosity changes, said adhesives being based on ethylene-vinyl acetate copolymer and a hydrocarbon tackifying resin and containing a stabilizer system of a hindered phenol antioxidant, a phosphite costabilizer and an acid scavenger.
    Type: Grant
    Filed: May 9, 1991
    Date of Patent: July 7, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Douglas W. Horsey, Ambelal R. Patel
  • Patent number: 5124378
    Abstract: N--OR.sub.1 substituted hindered amine light stabilizers impart outstanding stabilization properties to ambient cured coatings based on a variety of resins, the stabilized coatings exhibiting improved durability, weatherability, and the like.
    Type: Grant
    Filed: October 19, 1988
    Date of Patent: June 23, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Andrew Mar
  • Patent number: 5124388
    Abstract: Disclosed are films, containers and container liners comprising a copolyester having repeat units from terephthalic acid and 1,4-cyclohexanedimethanol, and a hindered phenolic antioxidant.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: June 23, 1992
    Assignee: Eastman Kodak Company
    Inventors: Wayne P. Pruett, Charles W. Ramsey, Sarah J. Webb, Joey C. Carico
  • Patent number: 5114996
    Abstract: Talc filled thermoplastic polyester compositions which have been modified by the addition of a butadiene-based impact modifier are stabilized against degradation by the addition thereto of a specific phosphorous compound.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: May 19, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Michael D. Golder, David K. Walker
  • Patent number: 5114995
    Abstract: Talc filled thermoplastic polyester compositions which have been modified by the addition of a butadiene-based impact modifier are stabilized against degradation by the addition thereto of a specific phosphorous compound.
    Type: Grant
    Filed: December 6, 1990
    Date of Patent: May 19, 1992
    Assignee: Hoechst Celanese Corp.
    Inventors: Michael D. Golder, David K. Walker
  • Patent number: 5112891
    Abstract: A polycarbonate resin composition improved in heat resistance by the addition of an organic cyclic phosphite represented by the general formula: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 9 carbon atoms; R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and R.sub.3 represents an alkyl group having 1 to 30 carbon atoms.
    Type: Grant
    Filed: August 28, 1990
    Date of Patent: May 12, 1992
    Assignee: Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Tohru Haruna, Masayuki Takahashi, Toshinori Yukino
  • Patent number: 5112890
    Abstract: N-OR.sub.1 substituted hindered amine light stabilizers impart outstanding stabilization properties to acid catalyzed thermoset coating compositions providing enhanced resistance against the deleterious effects of light, moisture or oxygen without inhibition of cure.
    Type: Grant
    Filed: October 19, 1988
    Date of Patent: May 12, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Roland A. E. Winter, Andrew Mar, Peter J. Schirmann, Raymond Seltzer, Roger F. Malherbe
  • Patent number: 5102929
    Abstract: The invention relates to mixtures of polyarylene sulphides, heterocyclic nitryoaryloxy compounds and optionally other additives. The mixtures are distinguished by good mechanical properties.
    Type: Grant
    Filed: March 11, 1991
    Date of Patent: April 7, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Walter Uerdingen, Klaus Kraft, Hans-Detlef Heinz, Wolfgang Wehnert
  • Patent number: 5100941
    Abstract: This invention concerns a polyolefin resin composition composed essentially of(A) a polyolefin resin,(B) an alkyl disulfide compound represented by formula [I]R.sup.1 --S--S--R.sup.2 [I]wherein R.sup.1 and R.sup.2 are the same or different and each denotes an alkyl group with 10 or more carbon atoms,(C) a triazine compound represented by formula [II] ##STR1## and/or a benzene compound represented by formula [III] ##STR2## According to this invention, there is provided the stabilized polyolefin resin composition that can resistant to heat ageing for a long period of time without discoloring.
    Type: Grant
    Filed: July 5, 1990
    Date of Patent: March 31, 1992
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hiromi Shigemoto, Keiji Kawamoto, Tetsuji Kasai
  • Patent number: 5100930
    Abstract: Disclosed herein is a food container of a resin composition composed of a polyolefin and an inorganic filler, said resin composition containing (i) a phenolic antioxidant and (ii) a slip agent and/or antistatic agent, said phenolic antioxidant being at least one kind selected from .beta.-(4-hydroxy-3-t-butyl-5-alkylphenyl)propionic acid esters, hindered phenols having an isocyanuric acid ester, 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, specific phenol compounds, and 6-hydroxychroman compounds. The food container has a low level of offensive odors and discoloration.
    Type: Grant
    Filed: June 28, 1990
    Date of Patent: March 31, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yoshiharu Fukui, Kazuhisa Kuroda
  • Patent number: 5086175
    Abstract: A polyisocyanate having an isocyanurate ring which is obtained by reacting a diisocyanate compound selected from the group consisting of alkylene, cycloalkylene and aralkylene diisocyanates with a monoalcohol of 10 to 50 carbon atoms in the presence of an isocyanuration catalyst, and removing of the unreacted diisocyanate compound from the reaction mixture, can be used in combination with various polyols, in the main, for the preparation of coatings, adhesives, architectural materials, molding materials, etc.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: February 4, 1992
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Ichiro Minato, Fumiaki Hirata, Tatsuya Nakashima
  • Patent number: 5073584
    Abstract: Proposed is a processing additive for halogen-containing polymers, in particular for polyvinyl chloride, with a content of a synthetic, crystalline, finely particulate alkali metal alumo silicate containing 13 to 25 percent by weight of bound water, which--in its anhydrous form--is of the composition (0.7-1.1) Me.sub.2 O.Al.sub.2 O.sub.3 .times.(1.3-2.4) SiO.sub.2, Me standing for an alkali metal, wherein the alkali metal alumo silicate is present in combination with at least one isocyanuric acid derivative of the formula ##STR1## wherein each n stands for an integer from 0 to 5, preferably from 0 to 3, each X represents H or a straight or branched alkyl group having 1 to 6 carbon atoms, preferably 1 or 2 carbon atoms, and each R is --OH or --COOH, and wherein the n's, X's and/or R's preferably have the same meaning, as well as halogen-containing polymers stabilized with use of this combination.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: December 17, 1991
    Assignee: Chemson Polymer-Additive Gesellschaft m.b.H.
    Inventors: Peter Meszaros, Peter Stern
  • Patent number: 5066460
    Abstract: The corrosion tendencies of polymers of 4-methyl-1-pentene, when combined with tris-(3,5-ditert-butyl-4-hydroxybenzyl)isocyanurate and bis-(2,4-ditert-butyl)pentaerythritol diphosphite are reduced. Optionally, metal stearates can be added to further reduce the polymer corrosion tendencies.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: November 19, 1991
    Assignee: Phillips Petroleum Company
    Inventor: Kenneth W. Willcox
  • Patent number: 5064883
    Abstract: N-hydroxy substituted hindered amine light stabilizers impart outstanding stabilization properties to acid catalyzed thermoset coating compositions with enhanced resistance against the deleterious effects of light, moisture or oxygen in the substantial absence of cure inhibition.
    Type: Grant
    Filed: October 19, 1988
    Date of Patent: November 12, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Roger F. Malherbe