Three Oxygen Atoms Are Directly Bonded To Three Nuclear Carbon Atoms Of The Nitrogen Ring, E.g., (iso) Cyanurate, Etc. Patents (Class 524/101)
  • Patent number: 5063263
    Abstract: Incorporation into polyacetal molding compositions stabilized for processing with a non-meltable polymer stabilizer of 0.01-1.00 weight percent of at least one meltable co-stabilizer, said co-stabilizer being a thermal stabilizer for polyacetal, and 0.02-1.0 weight percent of at least one primary antioxidant results in significantly improved long term stability, as evidenced by greater retention of physical properties over time, of such compositions.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: November 5, 1991
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Richard A. Hayes, Leonard E. R. Kosinski, Mark E. Wagman
  • Patent number: 5059647
    Abstract: A spandex fiber is provided with discoloration resistance by a synergistic combination of a hydroxyphenyl-1,3,5-triazine ultraviolet light absorber and N,N-dialkylsemicarbazide groups, the groups being attached to the ends of the spandex polymer or as a substituent of an additive.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: October 22, 1991
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Akitsugu Kawaguchi
  • Patent number: 5057564
    Abstract: The present invention relates to novel polymers which are adducts of an unsaturated hydrocarbon, wherein the novel polymers are produced by contacting cyclic carbonyl monomers with an unsaturated hydrocarbon to form novel cyclic carbonyl polymers having an Mn of about 500 to about 10.sup.7.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: October 15, 1991
    Assignee: Exxon Research and Engineering Company
    Inventor: Stanley J. Brois
  • Patent number: 5045577
    Abstract: The addition of hindered amines in combination with a phosphorus-III-ester to the polymerization of olefins on spherical Ziegler-Natta catalysts effects a thermo-oxidative stabilization of the prepared polymers. Phenolic antioxidants may be used additionally.
    Type: Grant
    Filed: June 21, 1989
    Date of Patent: September 3, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Paul Dubs
  • Patent number: 5045578
    Abstract: The invention relates to polymer mixtures which comprise a polyphenylene ether, a sterically hindered amine, an epoxy compound, and a salt of a fatty acid. The polymer mixtures according to the invention have a good stability against discoloring by light.
    Type: Grant
    Filed: October 13, 1988
    Date of Patent: September 3, 1991
    Assignee: General Electric Co.
    Inventors: Christianus A. A. Claesen, Hideo Koike
  • Patent number: 5037869
    Abstract: An improved process is disclosed for preparing flame retardant polyamide molding resins containing melamine cyanurate as a flame retarding agent which results in products with improved mechanical properties and good flame retarding properties. It comprises the addition of a glycol and a phthalate ester to the process wherein a polyamide, melamine or derivatives thereof and cyanuric acid are melt-blended in the presence of water.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: August 6, 1991
    Assignee: Monsanto Company
    Inventor: William E. Sprenkle, Jr.
  • Patent number: 5036125
    Abstract: Single-component diorganopolysiloxane compositions, stable in storage in the absence of atmospheric moisture and crosslinkable into elastomeric state in the presence of moisture, well adapted, e.g., as sealants and adhesives for the construction industry, contain (A) a diorganopolysiloxane polymer having silanol endgroups, (B) a ketiminoxysilane crosslinking agent, (C) a stabilizing amount of an isocyanurate of the formula: ##STR1## (D) an inorganic filler material, and (E) a metal curing catalyst.
    Type: Grant
    Filed: June 29, 1990
    Date of Patent: July 30, 1991
    Assignee: Rhone-Poulenc Chimie
    Inventor: Patrice Perrin
  • Patent number: 5036151
    Abstract: The invention relates to trimerized aliphatic isocyanates produced by special processes, to their use as mold release agents in thermoplastic aromatic polycarbonates and/or thermoplastic aromatic polyestercarbonates and/or thermoplastic aromatic polyesters, optionally using standard additives, to the readily demoldable molding compounds thus obtained on the basis of the thermoplastic polycarbonates, polyestercarbonates and/or polyesters and to processes for the production of these readily demoldable molding compounds.
    Type: Grant
    Filed: March 14, 1990
    Date of Patent: July 30, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Holger Ohst, Helmut-Martin Meier, Klaus Kircher
  • Patent number: 5032631
    Abstract: Polyester molding compositions include an effective amount of a triazine-based antioxidant and a benzophenone ultraviolet light absorber sufficient to achieve a clor difference, as calculated in CIELab units under illuminant "D-65" according to ASTM Standard D-2244, of less than about 10,0, when exposed in a Xenon arc weather-ometer operated according to SAE J1885 for 315 Kj/sq.m. The triazine-based antioxidant is of the formula: ##STR1## wherein R is a phenolic group attached to the triazine ring via a C1 to C5 alkyl or an ester substituent. Preferably, the triazine-based antioxidant is 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid triester with 1,3,5-tris-(2-hydroxyethyl)-s-triazine-2,4,6-(1H, 3H, 5H) trione. The benzophenone UV-absorber is of the general formula: ##STR2## where R' is hydrogen or an alkyl radical.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: July 16, 1991
    Assignee: Hoechst Celanese Corporation
    Inventors: Michael D. Golder, Bruce M. Mulholland
  • Patent number: 5030671
    Abstract: A composition containing a) a chlorine-containing polymer, b) at least one Me(II) carboxylate and/or Me(II) phenolate, wherein Me(II) represents Ba, Ca, Mg, Sr or Zn, and c) at least one compound of formula I ##STR1## wherein n is 1, 2, 3, 4 or 6 and, when n is 1, X is C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.20 -alkenyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.5 -C.sub.12 cycloalkyl substituted by C.sub.1 -C.sub.4 alkyl, phenyl, C.sub.7 -C.sub.9 phenylalkyl, phenyl substituted by from 1 to 3 radicals or C.sub.7 -C.sub.9 phenylalkyl substituted on the phenyl ring by from 1 to 3 radicals, the radicals being selected from the group consisting of C.sub.1 -C.sub.4 alkyl, chlorine, hydroxy, methoxy and ethoxy; when n is 2, X is C.sub.2 -C.sub.12 alkylene, C.sub.2 -C.sub.12 alkylene substituted by phenyl, or C.sub.2 -C.sub.12 alkylene interrupted by oxygen or sulfur atoms; when n is 3, X is, for example, C.sub.3 -C.sub.7 alkanetriyl; when n is 4, X is, for example, C.sub.4 .varies.C.sub.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: July 9, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Wolfgang Wehner, Gerd Abeler
  • Patent number: 5023283
    Abstract: Esters of N,N-bis(hydroxyethyl)hydroxylamines corresponding to the formula ##STR1## wherein R are various aliphatic and aromatic groups, and X is hydroxy or substituted carboxyethyl are effective in stabilizing various organic materials against oxidative, thermal and actinic degradation.
    Type: Grant
    Filed: April 25, 1989
    Date of Patent: June 11, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Raymond Seltzer
  • Patent number: 5015681
    Abstract: Thermoplastic molding materials contain, as essential components,(A) from 40 to 99.55% by weight of a thermoplastic polyamide,(B) from 0.45 to 15% by weight of a thermoplastic polyester elastomer,(C) from 0.05 to 1.99% by weight of melamine cyanurate and in addition(D) from 0 to 50% by weight of fibrous or particulate fillers or a mixture thereof.
    Type: Grant
    Filed: November 28, 1989
    Date of Patent: May 14, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Steiert, Walter Betz, Christoph Plachetta, Eckhard M. Koch
  • Patent number: 5013838
    Abstract: The present invention relates to a process for the production of an isocyanurate group-containing polyisocyanate by(a) partially reacting the isocyanate groups of an organic diisocyanate containing aliphatically and/or cycloaliphatically bound isocyanate groups in the presence of an ammonium or phosphonium fluoride trimerization catalyst,(b) introducing carbon dioxide into the reaction mixture at least periodically during the reaction and(c) terminating the reaction at the desired degree of conversion.The present invention also relates to the isocyanurate group-containing polyisocyanates obtained in accordance with this process.
    Type: Grant
    Filed: January 19, 1990
    Date of Patent: May 7, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hans-Joachim Scholl
  • Patent number: 5006587
    Abstract: A polypropylene composition which demonstrates good color stability and water carry-over properties comprises polypropylene containing a hindered amine light stabilizer and about 0.01 to about 0.5 wt. % of a fluoborate salt. Ammonium fluoborate, sodium fluoborate and potassium fluoborate are particularly useful.
    Type: Grant
    Filed: September 25, 1989
    Date of Patent: April 9, 1991
    Assignee: Amoco Corporation
    Inventor: Ivor R. Fielding
  • Patent number: 5006577
    Abstract: N-hydroxy-substituted hindered amine light stabilizers impart outstanding stabilization properties to ambient cured coatings based on a variety of resins, the stabilized coatings exhibiting improved durability, weatherability, and the like.
    Type: Grant
    Filed: October 19, 1988
    Date of Patent: April 9, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf A. Behrens, Andrew Mar
  • Patent number: 5000917
    Abstract: The corrosion tendencies of polymers of 4-methyl-1-pentene, when combined with tris-(3,5-ditert-butyl-4-hydroxybenzyl)isocyanurate and bis-(2,4-ditert-butyl)pentaerythritol, diphosphite are reduced. Optionally, metal stearates can be added to further reduce the polymer corrosion tendencies.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: March 19, 1991
    Assignee: Phillips Petroleum Company
    Inventor: Kenneth W. Willcox
  • Patent number: 4996244
    Abstract: Compounds having defined functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: February 26, 1991
    Assignee: General Electric Company
    Inventor: Roger W. Avakian
  • Patent number: 4996253
    Abstract: A polyoxymethylene composition which exhibits improved stability against the degradative effects of ultraviolet light includes a triazine-based antioxidant and UV stabilizers. One preferred composition of the invention includes, based upon the total weight of the composition, an oxymethylene copolymer, between 0.015 to about 0.4 weight percent of 2,4,6-triamino-sym-triazine (as a formaldehyde scavenger), between about 0.25 to about 1.0 weight percent of each of 2-2(hydroxy-5-t-octylphenyl) benzotriazole, and bis(2,2,6,6-tetramethyl-4-piperidinyl)sebacate as UV light stabilizers, and between about 0.25 to about 1.0 weight percent of 3,5-di-tert-butyl-4-hydroxyhydrocinnamic acid triester with 1,3,5-tris(2-hydroxy-ethyl)-s-triazine-2,4,6-(1H, 3H, 5H)-trione as an antioxidant. Due to their enchanced UV-light stability property, the compositions of the invention find particular utility as molded automobile components.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: February 26, 1991
    Assignee: Hoechst Celanese Corporation
    Inventor: Bruce M. Mulholland
  • Patent number: 4992548
    Abstract: The present invention is directed to catalysts obtained by mixing alkali fluorides with quaternary ammonium or phosphonium salts.The present invention is also directed to a process for the production of these catalysts by stirring alkali fluorides and quaternary ammonium or phosphonium salts in alcohol, separating any deposits formed, removing the alcohol and converting the catalyst into useful form by dilution in solvents or absorption onto support materials.Finally, the present invention is directed to the use of the new catalysts as trimerization catalysts for the production of polyisocyanates containing isocyanurate groups.
    Type: Grant
    Filed: August 8, 1989
    Date of Patent: February 12, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Joachim Scholl, Josef Pedain
  • Patent number: 4990578
    Abstract: Polyol-polycarbonates having a molecular weight comprising within the range from 750 to 2500, endowed with good rheologic characteristics and having a low glass transition temperature (Tg), are obtained by means of the reaction, under transesterification conditions, of(a) an organic carbonate;(b) a saturated alifatic .alpha.,.omega.-glycol; and(c) tris-(hydroxyethyl)-isocyanurate.These polyol-polycarbonates are useful as bases for paints in combination with polyisocyanates.Furthermore, the polyol-polycarbonates can be reacted with bicarboxy acids, or with cyclic anhydrides in order to yield the corresponding products with carboxy end groups which are useful as bases for paints in combination with melaminic or epoxy resins.
    Type: Grant
    Filed: June 19, 1989
    Date of Patent: February 5, 1991
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Alberto Greco, Gabriele Lugli
  • Patent number: 4983655
    Abstract: A plastisol composition comprising polyvinyl chloride as a main component, a plasticizer and a blocked compound of diisocyanate polymer with styrenated phenol as an adhesion-improver, and optionally a powdery curing agent having a melting point of 50.degree. to 150.degree. C. which is surface-treated, said composition having improved adhesion properties when gelated under low temperature conditions such as at 110.degree. to 130.degree. C. for 15 to 30 minutes and being useful as an adhesive, a sealant, or a coating agent, particularly as a sealant for the body of automobiles, and a novel blocked polyisocyanurate compound useful as an adhesion-improver for the above plastisol composition and also as an adhesive, a coating agent, a sealant, and an crosslinking agent for an active hydrogen-containing high molecular weight compound.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: January 8, 1991
    Assignee: Sunstar Giken Kabushiki Kaisha
    Inventors: Yoshihiro Nakata, Tadao Kunishige
  • Patent number: 4972014
    Abstract: Incorporation into polyacetal molding compositions stabilized with a non-meltable polymer stabilizer of 0.02-1.0 weight percent of at least one amide-containing phenolic antioxidant results in significantly improved long term stability, as evidenced by greater retention of physical properties over time, of such compositions.
    Type: Grant
    Filed: June 15, 1989
    Date of Patent: November 20, 1990
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Richard A. Hayes, Leonard E. R. Kosinski, Mark E. Wagman
  • Patent number: 4968736
    Abstract: The corrosion tendencies of polymers of 4-methyl-1-pentene, when combined with tris-(3,5-ditert-butyl-4-hydroxybenzyl)isocyanurate and bis-(2,4-ditert-butyl)pentaerythritol diphosphite are reduced. Optionally, metal stearates can be added to further reduce the polymer corrosion tendencies.
    Type: Grant
    Filed: August 23, 1988
    Date of Patent: November 6, 1990
    Inventor: Kenneth W. Willcox
  • Patent number: 4965301
    Abstract: In thermal stabilization of poly(.alpha.-olefin) fibers, such as a melt spun polypropylene, in which the poly(.alpha.-olefin) contains a hindered phenol, an organic phosphite, a hindered amine, and a metal salt of a fatty acid, the further inclusion of an alkali metal phosphate, such as sodium phosphate, results in improved thermal stability of the finished fiber.
    Type: Grant
    Filed: March 7, 1988
    Date of Patent: October 23, 1990
    Assignee: Phillips Petroleum Company
    Inventor: James C. Leininger
  • Patent number: 4945016
    Abstract: The present invention relates to an adhesive composition comprising 100 parts by weight of a polyester-polyurethane having an isocyanate group (--NCO) and 0.002-20 parts by weight of a halogenating agent, suitably used for the adhesion of polyolefin materials which are difficult to glue, such as car molding and base materials for electrostatic flocked products, the adhesion of trimming, the adhesion of rubber products and others.
    Type: Grant
    Filed: January 24, 1989
    Date of Patent: July 31, 1990
    Assignee: Toyoda Gosei Co., Ltd.
    Inventor: Tatsuya Murachi
  • Patent number: 4925938
    Abstract: Novel hindered hydroxyphenyl alkyl isocyanurates are provided which are useful as stabilizers of resins made from at least one ethylenically unsaturated monomer.
    Type: Grant
    Filed: December 20, 1988
    Date of Patent: May 15, 1990
    Assignee: ICI Americas Inc.
    Inventors: James P. Neilan, John F. Stephen
  • Patent number: 4902440
    Abstract: A UV-curable resin composition, which comprises blending urethane acrylate with tris(2-acryloxyethyl)isocyanurate, or with tris(2-acryloxyethyl)isocyanurate and with diacrylate, which composition has a low viscosity and a good drawing workability before curing and cures rapidly by ultraviolet radiation to give cured products having a high elastic modulus, a high elongation and a low water-absorption.
    Type: Grant
    Filed: July 20, 1987
    Date of Patent: February 20, 1990
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Hidekazu Takeyama, Yoshinobu Ohashi, Shuji Okagawa, Masayuki Nishimoto, Masao Nishimura
  • Patent number: 4898901
    Abstract: Long chain N-alkyl-alpha-alkyl nitrones represent particularly valuable process stabilizers for polyolefin compositions. The nitrone derived from the long chain alkyl mixture present in di(hydrogenated tallow)amine is especially useful for this purpose.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: February 6, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Stephen D. Pastor, Raymond Seltzer, Ambelal R. Patel
  • Patent number: 4888370
    Abstract: Flame-resistant, thermoplastic polyamide moulding materials which contain 0.01-4% by weight of polyphenylene oxides as flameproofing agent and which are prepared by mixing the components in the melt.
    Type: Grant
    Filed: September 7, 1988
    Date of Patent: December 19, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Thomas Joswig, Karsten Idel, Heinz-Josef Fullmann, Friedemann Muller
  • Patent number: 4885326
    Abstract: A synthetic resin composition comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic alkylphosphite compound of 2,2'-alkylidene-bisphenol (I) and 0.001 to 10 parts by weight of beta-(3,5-dialkyl-4-hydroxyphenyl)-propionic acid ester (II) and is stabilized to light and heat.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: December 5, 1989
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Tohru Haruna, Kazunori Nishikawa, Mitsuhiro Hamajima
  • Patent number: 4880854
    Abstract: Compounds having defined triazine functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.
    Type: Grant
    Filed: December 22, 1987
    Date of Patent: November 14, 1989
    Assignee: General Electric Company
    Inventor: Roger W. Avakian
  • Patent number: 4879141
    Abstract: The present invention includes:(i) a method for making a coated particulate comprising the steps ofheating until liquid a polyolefin wax;fluidizing with a hot gas, additive particles selected from the group comprising an antioxidant, a processing stabilizer, an acid acceptor, and mixtures thereof;spraying the liquid polyolefin wax on the heated fluidized additive particles; andmaintaining the fluidized additive particles at a temperature which is sufficient to prevent the formation of fibers and adequate to form discrete substantially coated additive particles;(ii) a coated particulate made by the above process; and(iii) a process for providing in-reactor stabilization of a polyolefin during a polymerization reaction, using the coated additives prepared by the above described method.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: November 7, 1989
    Assignee: Shell Oil Company
    Inventor: Ananda M. Chatterjee
  • Patent number: 4877825
    Abstract: The invention relates to elasthane fibers which are protected against harmful environmental influences, particularly sunlight and combustion gases, by a synergistic stabilizer combination of(a) highly alkylated, phenolic antioxidants corresponding to the following formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are C.sub.1 -C.sub.3 alkyl radicals, in addition to which R.sup.3 may be C.sub.4 -C.sub.6 alkyl radicalsand(b) oligomeric, (cyclo)aliphatic phosphorous acid esters (oligomeric phosphites) obtained by reaction of pentaerythritol, perhydrobisphenol A and, optionally, a mono- alcohol with monomeric trialkyl or triaryl phosphites.
    Type: Grant
    Filed: March 10, 1989
    Date of Patent: October 31, 1989
    Assignee: Bayer Akteingesellschaft
    Inventors: Michael Kausch, Hans-Josef Buysch, Hans Schroer, Carlhans Suling
  • Patent number: 4873279
    Abstract: A resinous composition comprising:(i) at least one copolyester-carbonate resin;(ii) at least one polyester resin; and(iii) a minor amount of a mixture of at least one polyol and at least one epoxide.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: October 10, 1989
    Assignee: General Electric Company
    Inventor: Linda H. Nelson
  • Patent number: 4866114
    Abstract: Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials contain, as essential components,(A) from 10 to 90% by weight of component (A), which consists of(A.sub.1) from 70 to 99% by weight of a modified polyphenylene ether,(A.sub.2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of component (A), and(B) from 90 to 10% by weight of component (B), which consists of(B.sub.1) from 80 to 99% by weight of one or more polyamides and(B.sub.2) from 1 to 20% by weight of one or more compounds containing a bound triazine radical and from the group consisting of cyanuric acid and its derivatives.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: September 12, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Christof Taubitz, Hermann Gausepohl, Klaus Boehlke
  • Patent number: 4863982
    Abstract: Compounds of the formula I ##STR1## R.sup.4 is C.sub.5 -C.sub.7 -cycloalkyl which can be substituted by C.sub.1 -C.sub.4 -alkyl, and R.sup.5 to R.sup.9 are independently of one another C.sub.1 -C.sub.18 alkyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.5 -C.sub.7 -cycloalkyl, phenyl, benzyl or allyl, are suitable for stabilizing organic material against thermal, oxidative and/or actinic degradation.
    Type: Grant
    Filed: July 6, 1988
    Date of Patent: September 5, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Werner Stegmann, Eduard Troxler, Peter Hofmann, Hans-Rudolf Meier, Paul Dubs
  • Patent number: 4853426
    Abstract: The present invention includes:(i) a method for making a coated particulate comprising the steps ofheating until liquid a polyolefin wax;fluidizing with a hot gas, additive particles selected from the group comprising an antioxidant, a processing stabilizer, an acid acceptor, and mixtures thereof;spraying the liquid polyolefin wax on the heated fluidized additive particles, andmaintaining the fluidized additive particles at a temperature which is sufficient to prevent the formation of fibers and adequate to form discrete substantially coated additive particles;(ii) a coated particulate made by the above process; and(iii) a process for providing in-reactor stabilization of a polyolefin during a polymerization reaction, using the coated additives prepared by the above described method.
    Type: Grant
    Filed: January 25, 1988
    Date of Patent: August 1, 1989
    Assignee: Shell Oil Company
    Inventor: Ananda M. Chatterjee
  • Patent number: 4829111
    Abstract: A stabilizer composition for synthetic resin is described comprising a piperazine derivative represented by the following formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an alkyl group having from 12 to 20 carbon atoms or a 2,2,6,6-tetramethyl-4-piperidyl group; R.sub.3 and R.sub.4 each represents a hydrogen atom or a methyl group; and n and m each represents 2 or 3.A synthetic resin composition is also described comprising polyolefin and the aforesaid piperazine derivative.
    Type: Grant
    Filed: February 2, 1988
    Date of Patent: May 9, 1989
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Kazuyuki Iida, Hiroyuki Omori, Akiyoshi Oonishi, Masami Takahashi
  • Patent number: 4826983
    Abstract: Novel hindered hydroxyphenyl alkyl isocyanurates are provided which are useful as stabilizers of resins made from at least one ethylenically unsaturated monomer.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: May 2, 1989
    Assignee: ICI Americas Inc.
    Inventors: James P. Neilan, John F. Stephen
  • Patent number: 4822833
    Abstract: Rigid polyvinyl chloride stabilized against the adverse effects of ultraviolet radiation by the addition thereto of effective amounts of 2,2,6,6-tetraalkylpiperidine compound and an organotin carboxylate thermal stabilizer, optionally with reduced amounts of titanium dioxide, organotin mercapto esters and/or organotin mercaptide thermal stabilizers.
    Type: Grant
    Filed: February 3, 1988
    Date of Patent: April 18, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean M. Zappia, Gerald A. Capocci
  • Patent number: 4820755
    Abstract: This invention provides polymers containing radiochromic hindered phenolic stabilizers which are characterized by including a blue compound which interacts with the hindered phenolic during irradiation to provide a color change indicative of sterility.
    Type: Grant
    Filed: August 18, 1987
    Date of Patent: April 11, 1989
    Assignee: American Cyanamid Company
    Inventor: Joseph R. Webster
  • Patent number: 4814103
    Abstract: The present invention is directed to the stabilization of a prepolymer based on methylene diphenyl isocyanate rich in the 2,4'-isomer. It was surprisingly found that the color stability, viscosity and aging characteristics of the prepolymer are improved markedly upon the incorporation therewith of a combination of a certain epoxide compound and a hindered phenol.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: March 21, 1989
    Assignee: Mobay Corporation
    Inventors: Terry A. Potter, Richard S. Pantone, Russell P. Carter, Jr.
  • Patent number: 4812500
    Abstract: An improved polyolefin pipe or wire and coating composition having improved resistance to deterioration in the presence of chlorinated and nonchlorinated water and having improved resistance to temperatures in the range of about 0.degree. C., as well as in cool water consisting of a blend of:(a) about 93 to about 99.5 percent by weight of an isotactic poly-1-butene polymer;(b) about 0.05 to about 0.50 percent by weight of a hindered amine UV stabilizer;(c) about 0.05 to about 1.1 by weight of a hindered phenolic thermal stabilizer having a molecular weight above 530;(d) about zero to about 0.5 percent by weight of a nucleating agent;(e) about zero to about 4 percent by weight of a pigment;(f) about zero to about 3.0 percent by weight of a filler; and(g) up to about 3.0 percent by weight of a chelating agent.
    Type: Grant
    Filed: September 30, 1987
    Date of Patent: March 14, 1989
    Assignee: Shell Oil Company
    Inventor: Earl E. Hayden
  • Patent number: 4812501
    Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: March 14, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
  • Patent number: 4793972
    Abstract: The corrosion tendencies of polymers of 4-methyl-1-pentene, when combined with tris-(3,5-ditert-butyl-4-hydroxybenzyl)isocyanurate and bis(2,4-ditert-butyl)pentaerythritol diphosphite are reduced. Optionally, metal stearates and/or poly[[6-[(1,1,3,3-tetramethylbutyl)amino]-5-triazine-2,4-diyl][2,2,6,6-tet ramethyl-4-piperidyl)imino]hexamethylene[2,2,6,6-tetramethyl-4-piperidyl)im ino]] can be added to further reduce the polymer corrosion tendencies.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: December 27, 1988
    Assignee: Phillips Petroleum Company
    Inventor: Kenneth W. Willcox
  • Patent number: 4789698
    Abstract: Polyamide moulding materials which have been reinforced with unsized glass fibres and to which a flame-proof finish has been imparted by means of melamine or melamine cyanurate and which have a high glow wire resistance.
    Type: Grant
    Filed: March 9, 1987
    Date of Patent: December 6, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinz Bonten, Werner Nielinger, Dietrich Michael, Harald Selbeck, Rolf-Volker Meyer
  • Patent number: 4786673
    Abstract: Flame retarded polyamides and methods for their preparation, the polyamides being obtained by anionic polymerization of lactams or by the hydrolytic polycondensation of monomers in the presence of chain terminators, the flame resistance being conferred by incorporating into the molten polyamide a mixture of melamine cyanurate and a polyol having at least four hydroxy groups.
    Type: Grant
    Filed: January 26, 1988
    Date of Patent: November 22, 1988
    Assignee: Atochem
    Inventors: Genevieve Morival, Catherine Hervy
  • Patent number: 4785035
    Abstract: A curing composition comprising a silane functional acrylic polymer component and a silane functional oligomer component. The polymer component is a co-polymer of functional silyl group-containing units derived from monomers of Formula:CH.sub.2 .dbd.CR.sup.1 CO.sub.2 (CH.sub.2).sub.a LThe oligomer component is of formulaE(GKL).sub.6in which E is derived from a multifunctional isocyanate oligomer, G is of general formula:--[O(CH.sub.2).sub.5 CO].sub.C [O(CH.sub.2).sub.d OCO(CH.sub.2).sub.2 ]--and K is of general formula:--[NR.sup.5 (CH.sub.2).sub.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: November 15, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventors: August L. L. Palluel, Stephen P. Davis, Angela C. Fletcher
  • Patent number: 4777212
    Abstract: The present invention relates to thermoplastic moulding compositions comprising polydiorganosiloxane-polycarbonate block copolymers, copolymers of styrene and maleic anhydrides, graft polymers and, where appropriate, further customary additives and a process for preparing these moulding compositions.
    Type: Grant
    Filed: November 21, 1986
    Date of Patent: October 11, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Jurgen Kress, Winfried Paul, Horst Peters, Christian Lindner, Josef Buekers
  • Patent number: 4769406
    Abstract: A hot melt adhesive suitable for bonding plastic, metal, and glass together has been developed by blending together into a homogenous mixture 10 to 20 weight percent of ethylene/vinyl acetate/acid functional terpolymer resin of low acid number, 15 to 50 weight percent of ethylene/vinyl acetate/acrylic acid terpolymer resin of high acid number and 30 to 60 weight percent of tackifying resins based on alpha-methylstyrene, rosin, or a terpene resin. Additionally, suitable antioxidants and surfactants are added to control the aging and application of the composition.
    Type: Grant
    Filed: March 2, 1987
    Date of Patent: September 6, 1988
    Assignee: Essex Specialty Products, Inc.
    Inventor: Robert J. Keithley