Phosphorus Bonded Directly To Four Chalcogen Atoms, E.g., Phosphate, Etc. Patents (Class 524/127)
  • Patent number: 9416208
    Abstract: Provided are a method for producing an EVOH resin having sufficient long-run workability in melt molding and enabling prevention of coloring such as yellowing, an EVOH resin obtained by this method for production, and a laminate obtained from this resin. Additionally, a method for producing an ethylene-vinyl alcohol copolymer resin capable of efficiently drying while inhibiting deterioration of qualities is provided. The method for producing an ethylene-vinyl alcohol copolymer resin of the present invention includes a step of irradiation with an infrared ray for irradiating with an infrared ray an ethylene-vinyl alcohol copolymer or an ethylene-vinyl ester copolymer that is a precursor of the ethylene-vinyl alcohol copolymer.
    Type: Grant
    Filed: March 23, 2012
    Date of Patent: August 16, 2016
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenji Nakano, Kazutaka Ikeda
  • Patent number: 9334390
    Abstract: A resin composition includes a polylactic acid resin or cellulose resin, 0.07 phr to 8 phr of lignin, and 4 phr to 30 phr of an aromatic condensed phosphoric acid ester.
    Type: Grant
    Filed: March 29, 2013
    Date of Patent: May 10, 2016
    Assignee: FUJI XEROX CO., LTD.
    Inventors: Manabu Kawashima, Kenji Yao
  • Patent number: 9231335
    Abstract: A main object of the present invention is to provide a connection structure for a solar power generation module that has much better impact resistance at low temperature and flame retardancy even when made thinner and more compact. A connection structure for a solar power generation module according to the present invention is a connection structure for a solar power generation module, which links a solar power generation module with a cable for connecting to the solar power generation module, and includes a specific thermoplastic resin composition.
    Type: Grant
    Filed: February 13, 2012
    Date of Patent: January 5, 2016
    Assignee: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Tadayuki Ishii, Hiroaki Furukawa, Hiroyuki Kono
  • Patent number: 9187640
    Abstract: To provide a resin composition that has a high impact resistance, hardly causes peeling during molding, and is excellent in flame retardancy, heat resistance, and heat aging resistance for a long period. A resin composition containing (A) polyphenylene ether, (B) a hydrogenated block copolymer that is obtained by hydrogenating a block copolymer including a polystyrene block and a conjugated diene compound polymer block, and that has a weight average molecular weight of 100,000 to 500,000, and (C) an organic phosphorus-based flame retardant within a specified amount, wherein a value of the loss tangent (tan ?) peak height of the (B) component in a dynamic viscoelasticity spectrum obtained by measurement of the resin composition at a frequency of 10 Hz is in a specified range.
    Type: Grant
    Filed: June 20, 2012
    Date of Patent: November 17, 2015
    Assignee: ASAHI KASEI CHEMICALS CORPORATION
    Inventors: Hiroaki Furukawa, Tadayuki Ishii
  • Patent number: 9127142
    Abstract: A method for injection molding a thermoplastic composition that contains a polyarylene sulfide and an aromatic amide oligomer is provided. Due to the improved crystallization properties imparted by the oligomer, the present inventors have discovered that the thermoplastic composition can be molded at lower temperatures to still achieve the same degree of crystallization. In addition to minimizing the energy requirements for the molding operation, such low mold temperatures may be accomplished using heating mediums that are less corrosive and expensive than some conventional techniques.
    Type: Grant
    Filed: August 4, 2014
    Date of Patent: September 8, 2015
    Assignee: Ticona LLC
    Inventors: Rong Luo, Xinyu Zhao
  • Patent number: 9085683
    Abstract: A nucleating agent composition for increasing rigidity and toughness of polypropylene is provided. The nucleating agent composition comprises a carboxylate nucleating agent and a phosphate nucleating agent. The carboxylate nucleating agent is selected from the group consisting of sodium benzoate and hydroxyl aluminum para-tertiary butyl benzoate, and the phosphate nucleating agent is selected from any one of sodium 2,2?-methylene-di(4,6-di-t-butyl phenyl) phosphate and aluminum bis[2,2?-methylene-di(4,6-di-t-butylphenyl)] phosphate. The nucleating agent composition according to the present invention not only can significantly improve the bending modulus and thermal deformation temperature of polypropylene, but also can improve the impact strength of polypropylene.
    Type: Grant
    Filed: April 19, 2011
    Date of Patent: July 21, 2015
    Assignee: GCH Technology Co., Ltd.
    Inventor: Wen-lin Zhao
  • Patent number: 9073293
    Abstract: An object of the present invention is to provide an EVOH-containing resin composition which has superior appearance characteristics and long-run workability in melt molding and enables occurrence of yellowing etc., in melt molding to be inhibited particularly, even in melt molding at high temperatures of, for example, no less than 260° C. Further provided is a multilayered structure molded from the composition. The present invention provides a resin composition containing (A) an ethylene-vinyl alcohol copolymer, (B) a carboxylic acid and/or a carboxylate ion, and (C) a metal ion, wherein the component (B) includes (B2) a multivalent carboxylic acid and/or a multivalent carboxylate ion, and the molar ratio (B2/C) of the multivalent carboxylic acid and the multivalent carboxylate ion (B2) to the metal ion (C) is 0.002 or greater and 2 or less.
    Type: Grant
    Filed: March 23, 2011
    Date of Patent: July 7, 2015
    Assignee: KURARAY CO., LTD.
    Inventors: Yoshikazu Yamasaki, Yasuhiro Nonaka, Kazuyuki Somemiya
  • Patent number: 9056978
    Abstract: A non-halogen flame retardant and high rigidity polycarbonate resin composition is disclosed. The non-halogen flame retardant and high rigidity polycarbonate resin composition has excellent flame retardancy and rigidity by overcoming a conventional problem such as poor rigidity occurred, upon adding a flame retardant agent in polycarbonate resin composition reinforced with a glass fiber having improved rigidity such as flexibility and surface smoothness etc., imposed by the use of the glass fiber. The polycarbonate resin composition has excellent fluidity, appearance surface quality and flexibility, together with high impact resistance and toughness, and also flame retardancy.
    Type: Grant
    Filed: January 29, 2013
    Date of Patent: June 16, 2015
    Assignee: LG Chem, Ltd.
    Inventors: Sun Mo Son, Ryul Lee, Sung Ho Lee, Sung Tae Ahn, Su Kyoung Lee, Jong Wan Kim
  • Publication number: 20150141560
    Abstract: Provided is a thermoplastic resin composition having high flame resistance and high fluidity during injection molding, and improved impact resistance in a molded article. A method for producing a thermoplastic resin composition, the method including the step (1) of obtaining a polyester resin mixture by melt-kneading 50 to 80 parts by weight of crystalline polyester resin and 20 to 50 parts by weight of amorphous polyester resin with an extruder, and the step (2) of mixing the polyester resin mixture, a polycarbonate resin, a flame retardant, a dripping inhibitor and a toughening agent, wherein the cylinder temperature of the extruder is 250 to 280° C.
    Type: Application
    Filed: November 13, 2014
    Publication date: May 21, 2015
    Inventors: Yiqiang YU, Masashi Mamino, Ryuji Kitani
  • Patent number: 9034959
    Abstract: A polycarbonate resin composition includes: (D) about 1 to about 10 parts by weight of a silicon-based resin; (E) about 1 to about 10 parts by weight of a core-shell graft copolymer; and (F) about 1 to about 20 parts by weight of a flame retardant, with respect to about 100 parts by weight of a base resin including: (A) about 70 to about 90 wt % of a polycarbonate resin; (B) about 9 to about 25 wt % of a polysiloxane-polycarbonate copolymer; and (C) about 1 to about 10 wt % of an aromatic vinyl-based graft copolymer. The polycarbonate resin composition can have improved releaseability and external appearance, and excellent impact strength and coloring.
    Type: Grant
    Filed: June 24, 2013
    Date of Patent: May 19, 2015
    Assignee: Cheil Industries Inc.
    Inventors: Kyuong-Sik Chin, Jong-Tae Yoon, Seung-Shik Shin
  • Patent number: 9034958
    Abstract: A polymer complex is disclosed which is the reaction product of one or more polymers having a terminal or pendant hydroxyl group, or a terminal or pendent carboxyl group, or combinations thereof, with at least one metal complex and one alkyl phosphate. This polymer complex acts as an adhesion promotion agent as well as a viscosity stabilizer when formulated in a printing ink or coating.
    Type: Grant
    Filed: November 16, 2004
    Date of Patent: May 19, 2015
    Assignee: Sun Chemical Corporation
    Inventors: Mark Andreas Mielke, Mathew Charles Mathew, William P. Keaveney, Richard John Czarnecki, William Ford Wilson, Mark John Lindsey, Ralph Francis Arcurio
  • Patent number: 9023922
    Abstract: Disclosed herein is a flame retardant composition comprising a polycarbonate; a polylactide; and a flame retardant; where the flame retardant is a phenoxyphosphazene, a di- or polyfunctional aromatic phosphorus-containing compound, or a combination comprising at least one of the foregoing flame retardants. Disclosed herein is a method comprising blending a polycarbonate, a polylactide and a flame retardant to form a flame retardant composition; where the flame retardant is a phenoxyphosphazene, a di- or polyfunctional aromatic phosphorus-containing compound, or a combination comprising at least one of the foregoing flame retardants.
    Type: Grant
    Filed: May 22, 2013
    Date of Patent: May 5, 2015
    Assignee: SABIC Global Technologies B.V.
    Inventors: Wei Zhao, Vikram Daga, Amit Kulkarni
  • Publication number: 20150111041
    Abstract: Provided is a resin composition capable of achieving a higher plating property. The resin composition comprises, relative to 100 parts by weight of a resin component comprising 30 to 100% by weight of a polycarbonate resin and 70% by weight or less of a styrene-based resin, 10 to 100 parts by weight of a glass filler and 2 to 20 parts by weight of a laser direct structuring additive, wherein the laser direct structuring additive comprises a metal oxide particle comprising titanium oxide coated with a composition comprising tin as a main component and antimony.
    Type: Application
    Filed: September 12, 2013
    Publication date: April 23, 2015
    Inventors: Atsushi Motegi, Hiroyoshi Maruyama
  • Patent number: 9012547
    Abstract: In various embodiments, provided are novel curable silicone compositions; films and adhesives comprising one or more cured products of said compositions, the films and adhesives exhibiting properties of mechanical flexibility and low flammability. Additionally, the films and adhesives may exhibit one or more of high transparency, low haze, and high refractive index.
    Type: Grant
    Filed: October 31, 2011
    Date of Patent: April 21, 2015
    Assignee: Dow Corning Corporation
    Inventors: Marilyn P. Shope, Bizhong Zhu
  • Publication number: 20150104599
    Abstract: A thermoplastic composition includes a poly(carbonate-arylate ester); and an organophosphorus compound in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after four minutes (Ds-4) of less than or equal to 300 determined according to ISO 5659-2 on a 3 mm thick plaque and a maximum average rate of heat release emission (MAHRE) of less than or equal to 90 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.
    Type: Application
    Filed: December 18, 2014
    Publication date: April 16, 2015
    Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
  • Patent number: 8993506
    Abstract: A hydrophilized article includes (a) a substrate having a hydrophobic surface, and (b) a hydrophilizing layer disposed on at least a portion of the hydrophobic surface of the substrate. said layer comprising an organophosphorus material or a vinyl alcohol material, or a mixture of an organophosphorus material and a vinyl alcohol material.
    Type: Grant
    Filed: June 12, 2007
    Date of Patent: March 31, 2015
    Assignee: Rhodia Operations
    Inventors: Tobias Johannes Fütterer, Robert Lee Reierson, Jean-Christophe Castaing
  • Publication number: 20150076413
    Abstract: An intermediate transfer member that contains a mixture of a polyimide, an optional conductive component, and a perfluoropolyether phosphate.
    Type: Application
    Filed: September 15, 2013
    Publication date: March 19, 2015
    Applicant: Xerox Corporation
    Inventors: Jin Wu, Kyle B. Tallman, Qi Ying Li, Lin Ma
  • Publication number: 20150080508
    Abstract: Thermal barrier mixtures and method of making the thermal barrier mixtures are described herein. The thermal barrier mixtures may be used to make thermal barrier coatings. Thermal barrier mixture may include halloysite and one or more silicon compounds.
    Type: Application
    Filed: April 22, 2013
    Publication date: March 19, 2015
    Inventors: Charles J. Neef, John Lee Massingill, JR., Clois E. Powell
  • Patent number: 8969447
    Abstract: A thermoplastic composition includes a poly(carbonate-arylate ester); and an organophosphorus compound in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after four minutes (Ds-4) of less than or equal to 300 determined according to ISO 5659-2 on a 3 mm thick plaque and a maximum average rate of heat release emission (MAHRE) of less than or equal to 90 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: March 3, 2015
    Assignee: Sabic Global Technologies B.V.
    Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
  • Patent number: 8969448
    Abstract: The present invention relates to moulding compositions of polycarbonates and graft polymers and optionally further additives and components, which have, in addition to a high resistance to chemicals, a good resistance to heat, in particular a low tendency towards yellowing and a low tendency towards degradation when exposed to heat. In a particular, flameproofed embodiment, the after-burn time in a UL94 classification is furthermore reduced.
    Type: Grant
    Filed: April 22, 2013
    Date of Patent: March 3, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Thomas Eckel, Andreas Seidel, Martin Haussler, Burkhard Thuermer
  • Publication number: 20150051328
    Abstract: An alkyl phosphinate polymer having a formula R1 is a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tertiary butyl, n-amyl group, isoamyl, n-hexyl, isohexyl, hydroxymethyl, or alkoxy; R2 is a methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tertiary butyl, n-amyl group, isoamyl, n-hexyl, isohexyl, hydroxymethyl, or alkoxy; Re is an alkali metal, alkaline earth metal, transition metal, poor metal, metalloid, lanthanide element, or protonated nitrogen base; x=1/m, m is the valence of Re; u is the degree of polymerization in a range of from 1 to 6. Glare use in a flame-retardant composition, and flame-retardant polymer molding composition which comprises the alkyl phosphinate polymer.
    Type: Application
    Filed: October 31, 2014
    Publication date: February 19, 2015
    Inventors: Jinbiao YE, Xiangdong Xu
  • Patent number: 8957141
    Abstract: A non-halogen flame retardant thermoplastic polyurethane composition containing: a) an organic non-halogenated flame retardant package which contains non-reacted components, i) an organic phosphate compound which is melamine free, ii) a mixture of an organic phosphate in combination with an organic phosphoric acid; and iii) a zinc oxide, b) a stabilizer, c) optionally inorganic flame retardant components, and d) optionally non-flame retardant additives, resulting in a TPU composition with excellent tensile strength and improved high flame performance and low smoke properties.
    Type: Grant
    Filed: August 24, 2011
    Date of Patent: February 17, 2015
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventor: Chetan M. Makadia
  • Publication number: 20150044461
    Abstract: There is provided a material for molding including: carbon fiber bundles which are easily impregnated including carbon fibers and at least one impregnation aid in an amount of 3 to 15 parts by mass based on 100 parts by mass of the carbon fibers, the at least one impregnation aid satisfying specific requirements; and a polycarbonate is adhered thereto in an amount of 50 to 2000 parts by mass.
    Type: Application
    Filed: March 12, 2013
    Publication date: February 12, 2015
    Applicant: TEIJIN LIMITED
    Inventors: Hodaka Yokomizo, Takeshi Matsuda, Takashi Ito, Ikko Furukawa
  • Patent number: 8937125
    Abstract: A reinforced poly(phenylene ether)-polysiloxane block copolymer composition includes specific amounts of a poly(phenylene ether)-polysiloxane block copolymer reaction product, a flame retardant, and a reinforcing filler. The composition exhibits a desirable balance of flame retardancy, heat resistance, and stiffness relative to a corresponding poly(phenylene ether) composition, and it is useful to fabricate articles including fuser holders for electrophotographic copiers.
    Type: Grant
    Filed: May 6, 2014
    Date of Patent: January 20, 2015
    Assignee: SABIC Global Technologies B.V.
    Inventors: Christian Lietzau, Sho Sato
  • Patent number: 8937141
    Abstract: The present invention provides curable compositions comprising non-Sn organo-metal catalysts that accelerate the condensation curing of moisture curable silicones/non-silicones. In particular, the present invention provides Mn(III) complexes that are particularly suitable as replacements for organotin for sealant and RTV formulations. The Mn(III) complexes are comparable or superior to organotin such as DBTDL, superior to Mn(II) compounds, and exhibit certain behavior in the presence of components that allow for tuning or adjusting the cure characteristics of the present compositions and provide good adhesion and storage stability.
    Type: Grant
    Filed: September 8, 2011
    Date of Patent: January 20, 2015
    Assignee: Momentive Performance Materials Inc.
    Inventors: Sumi, Edward J. Nesakumar, Anantharaman Dhanabalan, Shahid Murtuza, Shayne J. Landon
  • Patent number: 8933155
    Abstract: A reinforced poly(phenylene ether)-polysiloxane block copolymer composition includes specific amounts of a poly(phenylene ether)-polysiloxane block copolymer reaction product, a flame retardant, and a reinforcing filler. The composition exhibits a desirable balance of flame retardancy, heat resistance, and stiffness relative to a corresponding poly(phenylene ether) composition, and it is useful to fabricate articles including fuser holders for electrophotographic copiers.
    Type: Grant
    Filed: May 6, 2014
    Date of Patent: January 13, 2015
    Assignee: SABIC Global Technologies B.V.
    Inventors: Christian Lietzau, Sho Sato
  • Patent number: 8933153
    Abstract: The present invention relates to impact-modified polycarbonate molding compositions, the use thereof for producing shaped bodies and moldings, as well as shaped bodies and molding produced therefrom themselves. Compositions of the present invention comprise mixtures of graft polymers prepared in the emulsion polymerization process and in the bulk, solution and/or suspension polymerization process having a defined grafted particle size distribution. Compositions of the present invention, on the one hand are suitable for producing, over a wide processing window, (i.e. also at high processing temperatures), non-lacquered components having a high gloss surface, and on the other hand, are also capable of precise imaging of fine-grained or surface-etched mold surfaces.
    Type: Grant
    Filed: March 28, 2013
    Date of Patent: January 13, 2015
    Assignee: Bayer Intellectual Property
    Inventor: Andreas Seidel
  • Patent number: 8933154
    Abstract: A flame retardant thermoplastic resin composition and a molded article including the same are provided. The flame retardant thermoplastic resin composition includes: (A) a thermoplastic resin; (B) a flame retardant; and (C) a filler, wherein the (C) filler has an oil absorption rate of about 0.1 ml/100 g to about 10 ml/100 g as measured in accordance with ASTM D281. With the filler having a certain range of oil absorption, the flame retardant thermoplastic resin composition can exhibit excellent stiffness and/or flame retardancy.
    Type: Grant
    Filed: June 24, 2013
    Date of Patent: January 13, 2015
    Assignee: Cheil Industries Inc.
    Inventor: Ki Uk Kim
  • Publication number: 20150011688
    Abstract: The present disclosure relates to blended thermoplastic compositions comprising at least one polycarbonate component, at least one reinforcing filler, at least one phosphorus-containing flame retardant component. The resulting thermoplastic composition can be used in the manufacture of articles requiring materials with improved flame retardancy and optical properties such as light transmittance, while retaining required modulus and impact properties.
    Type: Application
    Filed: June 27, 2014
    Publication date: January 8, 2015
    Inventors: Narong An, Hiromi Ishida, Hiroshi Iida, Pei Sun, Dake Shen
  • Patent number: 8927654
    Abstract: Provided are a water-treating agent which includes a specific nonionic polymer and a phosphorus compound and can exhibit the ability to inhibit the deposition of silica-based scale under wide ranges of water quality conditions and temperature conditions; and a method of treating water. The inhibitor for silica-based scale includes a nonionic polymer and a phosphorus compound, the nonionic polymer being: a polymer formed by the reaction of an unsaturated double bond and including units derived from at least one monomer selected from the group consisting of (meth)acrylamide, N-substituted (meth)acrylamide and N-vinyl lactam; and/or one or more polymers having an ether group and selected from the group consisting of alkyl alcohol/polyalkylene oxide adducts, aliphatic monocarboxylic acid/polyalkylene oxide adducts, and polyvinyl alcohol/polyalkylene oxide adducts.
    Type: Grant
    Filed: January 14, 2010
    Date of Patent: January 6, 2015
    Assignee: Kurita Water Industries Ltd.
    Inventor: Ikuko Nishida
  • Publication number: 20150005422
    Abstract: Disclosed herein are a thermoplastic resin composition and a molded article produced therefrom. The thermoplastic resin composition includes a thermoplastic resin, an inorganic filler, and a maleic anhydride (MAH)-grafted rubber, and has a coefficient of linear expansion from about 20×10?6 cm/cm° C. to about 35×10?6 cm/cm° C., as measured in accordance with ASTM D696. The thermoplastic resin composition can exhibit low shrinkage, excellent impact resistance and excellent flexural modulus and can have a good balance therebetween.
    Type: Application
    Filed: June 19, 2014
    Publication date: January 1, 2015
    Inventors: Dong In HA, Dong Min PARK, Seung Shik SHIN, Kyuong Sik CHIN
  • Patent number: 8920929
    Abstract: The present disclosure provides a flexible, halogen-free, flame retardant composition. The composition includes from about 25 wt % to about 95 wt % of a thermoplastic polyurethane (TPU); from about 5 wt % to about 50 wt % of an olefin block copolymer (OBC); and from about 30 wt % to about 70 wt % of a flame retardant. The flame retardant is selected from resorcinol bis(diphenyl 5 phosphate) (RDP), bis diphenyl phosphate (BDP), bisphenol-A bis(diphenyl phosphate) (BPADP), aluminum trihydrate (ATH), a nitrogen/phosphorus-based halogen-free flame retardant, epoxidized novolac resin, and combinations thereof. The composition requires no compatibilizer for the TPU and OBC. The composition finds application in wire and cable structures.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: December 30, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Given Jing Chen, Wilson Xiao Wei Yan, Bin Li, Lan Lu, Weiming Wayne Ma, Lotus Hua Huang, David Hong Fei Guo
  • Patent number: 8916632
    Abstract: A flame retardant thermoplastic resin composition includes: (A) about 60% by weight (wt %) to about 90 wt % of a polycarbonate resin including a first polycarbonate having a weight average molecular weight from about 30,000 g/mol to about 50,000 g/mol and a second polycarbonate having a weight average molecular weight from about 5,000 g/mol to about 20,000 g/mol; (B) about 10 wt % to about 40 wt % of an aromatic vinyl resin having a fogging index (FI) of about 0.8 or less as calculated by Equation 1 defined in the specification; (C) about 1 part by weight to about 20 parts by weight of an impact modifier based on about 100 parts by weight of (A)+(B); and (D) about 5 parts by weight to about 30 parts by weight of a flame retardant based on about 100 parts by weight of (A)+(B.
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: December 23, 2014
    Assignee: Cheil Industries Inc.
    Inventors: Dong Kil Choi, Su Hak Bae, Jung Hun Lee, Dong Min Park, Seung Shik Shin, Min Jung Joo
  • Patent number: 8916631
    Abstract: Provided is a film or sheet composed of a resin composition that includes a poly lactic acid (A), an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000, a tetrafluoroethylene polymer (C), and an aromatic-condensed phosphoric acid ester-containing flame retardant (D) including a compound of General Formula (I) and in which the aromatic-condensed phosphoric acid ester-containing flame retardant (D) is included in an amount of 10 to 80 parts by weight based on 100 parts by weight of the poly lactic acid (A), and a method for manufacturing the film or sheet by melt film formation. Each sign in Formula is as described in the specification.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: December 23, 2014
    Assignee: Nitto Denko Corporation
    Inventors: Shigeki Ishiguro, Hiroki Senda
  • Publication number: 20140370213
    Abstract: Interior aircraft components comprise a thermoplastic composition comprising: a first polymer comprising bisphenol A carbonate units and monoaryl arylate units, or a second polymer comprising bisphenol A carbonate units, monoaryl arylate units, and siloxane units, or a combination comprising at least one of the foregoing polymers; and an organophosphorus compound; wherein a sample of the thermoplastic composition has: an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, an E662 smoke test DsMax value of less than 200, a flame time of less than 15 seconds, a burn length of less than 6 inches, and a drip extinguishing time of less than 5 seconds, an energy in multiaxial impact of 100 J or more and a ductility in multiaxial impact of 100%.
    Type: Application
    Filed: June 12, 2013
    Publication date: December 18, 2014
    Inventors: Mark Adrianus Johannes van der Mee, Paul Dean Sybert, Robert Dirk van de Grampel, Roland Sebastian Assink
  • Patent number: 8912260
    Abstract: A composition that includes at least one silane-functional polymer P and 20 to 60% by weight of aluminum hydroxide or magnesium hydroxide or mixture thereof, is disclosed. The composition has a viscosity of 500 to 20,000 mPa·s measured according to DIN 53018 at a temperature of 20° C. The composition is suitable as a liquid membrane and has very good flammability properties, i.e., it is difficult to ignite and is self-extinguishing.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: December 16, 2014
    Assignee: Sika Technology AG
    Inventors: Thomas Pusel, Raphael Teysseire, Willi Tenisch, Susanne Strauss, Barbara Jucker, Carsten Zilg
  • Patent number: 8912261
    Abstract: The present invention is directed to a process for preparing halogen-free melt-filtered polymer compositions, compositions prepared by the process, as well as articles derived therefrom. The process comprises filtering the melted composition through a filter to remove particulate impurities that are 0.5 mm2 in size or larger. The composition comprises: (a) 60 to 90 percent by weight of a poly(phenylene ether); (b) 3 to 23 percent by weight of a styrenic polymer; (c) 5-11 percent by weight of a halogen-free flame retardant comprising at least one organic phosphate flame retardant, wherein the composition has: (i) a melt viscosity of 620 Pa·s or less as measured according at 280° C. and 1500 s?1; and (ii) a heat deflection temperature that is 135° C. or more as measured according to ASTM D648 on 6.4 mm thick bars at 1.82 MPa.
    Type: Grant
    Filed: June 22, 2012
    Date of Patent: December 16, 2014
    Assignee: SABIC Global Technologies B.V.
    Inventor: Norihiro Takamura
  • Publication number: 20140364547
    Abstract: The present invention provides a polyester resin composition including, a polyester resin (A) including a dicarboxylic acid unit and a diol unit, 1 to 60 mol % of the diol unit being a diol unit having a cyclic acetal skeleton; a phosphorus compound (B) represented by the following general formula (1); and a basic compound (C), wherein, based on 100 parts by weight of the polyester resin (A), the phosphorus compound (B) is in an amount of 0.005 to 2 parts by weight and the basic compound (C) is in an amount of 0 to 2 parts by weight, and a method for producing the polyester resin composition: (wherein R1, R2, R3 and R4 each independently represent an aryl group, X represents a divalent group derived from an aromatic dihydroxy compound having 6 to 15 carbon atoms, and n is an integer of 1 to 5.
    Type: Application
    Filed: August 27, 2012
    Publication date: December 11, 2014
    Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.
    Inventors: Atsuko Iwasaki, Kazunobu Sato
  • Patent number: 8901215
    Abstract: A resin composition includes a polylactic acid, a solid flame retardant that has at least one functional group selected from the group consisting of a phosphate group, a sulfate group, and a sulfite group in a structure, a bifunctional compound that has a carbodiimide group, and a crystal nucleating agent.
    Type: Grant
    Filed: April 24, 2012
    Date of Patent: December 2, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Masaya Ikuno
  • Publication number: 20140349119
    Abstract: A polycarbonate resin composition according to the present invention comprises: (A) a polycarbonate; (B) a polycarbonate containing a non-phenyl group; (c) a rubber-modified aromatic vinyl graft copolymer; and (D) an aromatic phosphoric acid ester. The polycarbonate resin composition has superior physical balance by being flame retardant, shock resistant, low temperature shock resistant, and chemical resistant.
    Type: Application
    Filed: December 21, 2011
    Publication date: November 27, 2014
    Inventors: Jong Chan Hur, O Sung Kwon, Jun Ho Chi, Hyuck Man Kwon, Chang Heon Lee
  • Publication number: 20140335298
    Abstract: This disclosure relates to thermoplastic compositions comprising a polycarbonate copolymer, the polycarbonate copolymer comprising first repeating carbonate units and second repeating units selected from carbonate units that are different from the first carbonate units, polysiloxane units, and a combination comprising at least one of the foregoing unit; and an organophosphorus flame retardant in an amount effective to provide 0.1 to 1.0 wt % phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after 4 minutes (Ds-4) of less than or equal to 600 determined according to ISO 5659-2 on a 3 mm thick plaque, and a material heat release of less than or equal to 160 kW/m2 determined according to ISO 5660-1 on a 3 mm thick plaque.
    Type: Application
    Filed: July 29, 2014
    Publication date: November 13, 2014
    Inventors: Mark Adrianus Johannes van der Mee, Robert Dirk van de Grampel, Roland Sebastian Assink, Paul Dean Sybert
  • Patent number: 8883893
    Abstract: The present invention relates to a flame retardant plexifilamentary film-fibril strand comprising at least one polyolefin and at least one flame retardant selected from the group consisting of: phosphate esters, phosphonate esters, phosphinate esters, polyphosphazines, nitrogen-containing polyphosphates, hindered amines and mixtures thereof. The present invention also relates to flame retardant sheet made from the flame retardant plexifilamentary film-fibril strands. The sheet can be made into a flame retardant building substrate, garment, banner, light reflector and cover.
    Type: Grant
    Filed: April 17, 2012
    Date of Patent: November 11, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Sabine Gabriel, Lakshmi Krishnamurthy, Mieczyslaw (Michel) Stachnik, Mark Gary Weinberg
  • Publication number: 20140326162
    Abstract: Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density ?300 measured according to ISO 5659-2, and a MAHRE ?90 kW/m2 measured according to ISO 5660-1, a multiaxial impact energy ?100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.
    Type: Application
    Filed: May 1, 2013
    Publication date: November 6, 2014
    Inventors: Mark Adrianus Johannes van der Mee, Roland Sebastian Assink, Robert Dirk van de Grampel, Paul Dean Sybert
  • Publication number: 20140326163
    Abstract: Interior railway components (seat covers and claddings) comprise a thermoplastic composition comprising: a first polymer comprising bisphenol A carbonate units and monoaryl arylate units, or a second polymer comprising bisphenol A carbonate units, monoaryl arylate units, and siloxane units, or a combination comprising at least one of the foregoing polymers; and an organophosphorus compound; wherein a sample of the thermoplastic composition has: a smoke density after 4 minutes (Ds-4) of equal to or less than 300, an integral of the smoke density as a function of time up to 4 minutes (VOF4) of equal to or less than 600, a maximum average heat release (MAHRE) of equal to or less than 90 kW/m2, and a ductility in multiaxial impact of 100%.
    Type: Application
    Filed: May 1, 2013
    Publication date: November 6, 2014
    Inventors: Mark Adrianus Johannes van der Mee, Roland Sebastian Assink, Robert Dirk van de Grampel, Paul Dean Sybert
  • Publication number: 20140323606
    Abstract: The invention relates to thermoplastic moulding compositions comprising A) between 55 to 98% in weight of at least one vinyl aromatic copolymer modified with a particulate graft rubber, B) between 1 to 44% in weight of a flame retardant comprising B1) an expandable graphite, B2) a flame-retardant compound comprising phosphorus, and B3) a fluorine-containing polymer, C) between 1 to 20% in weight of a non-particulate-forming rubber comprising polar groups, and D) between 0 to 40% in weight of additional additives, where the weight percentages are respectively based on the total weight of components A) to D), and said percentages add up to a total of 100% in weight, and the polybutadiene content is between 0 to 11I % in weight.
    Type: Application
    Filed: December 15, 2011
    Publication date: October 30, 2014
    Applicant: BASF SE
    Inventors: Matthias Mueller, Norbert Guentherberg, Guenter Kehr, Norbert Niessner
  • Publication number: 20140323625
    Abstract: The flame retardant thermoplastic resin composition includes about 100 parts by weight of a polycarbonate resin; about 5 parts by weight to about 30 parts by weight of a rubber modified aromatic vinyl-based copolymer resin; about 10 parts by weight to about 30 parts by weight of an aromatic phosphoric acid ester compound; and about 5 parts by weight to about 100 parts by weight of fillers including wollastonite and talc, wherein a weight ratio of wollastonite to talc ranges from about 1:about 0.1 to about 1:about 0.5. In the flame retardant thermoplastic resin composition, wollastonite and talc are present in a specific ratio, which can provide excellent properties in terms of stiffness such as flexural modulus and bending characteristics, and flame retardancy.
    Type: Application
    Filed: September 29, 2013
    Publication date: October 30, 2014
    Applicant: Cheil Industries Inc.
    Inventors: Pil Ho KIM, Ki Uk KIM, Ji Yea KIM, Seung Shik SHIN, Dong Kil CHOI, Dong Hoon HAN
  • Patent number: 8871833
    Abstract: Provided is a metallic-pigment composition which is usable in coating compositions or ink compositions, in particular, in water-based coating compositions or aqueous inks, and which gives coating compositions having excellent storage stability. The metallic-pigment composition gives a coating film having excellent performances with respect to brightness, hiding properties, flip-flop feeling, etc., causes no colorant or organic-pigment discoloration, and has excellent adhesion and chemical resistance. The metallic-pigment composition comprises one or more mixed-coordination-type heteropolyanion compounds, a hydrolyzate of a silicon compound and/or a condensate thereof, and metal particles.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: October 28, 2014
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Kazuko Nakajima, Kaoru Ueyanagi
  • Patent number: 8865808
    Abstract: Halogen-free TPU compositions comprise in weight percent based on the weight of the composition: A. 1 to 99% thermoplastic polyurethane (TPU), B. 1 to 50% tris(2-butoxyethyl)phosphate (TBEP), C. 1 to 70% metal hydrate, and D. 1 to 70% organic phosphate ester other than tris(2-butoxyethyl)phosphate. These compositions exhibit better smoke suppression as compared with conventional organic phosphate flame retardant TPU compositions such as those based on resorcinol bis(diphenyl phosphate) (RDP) and bisphenol-A bis(diphenyl phosphate) (BPADP) in the absence of TBEP.
    Type: Grant
    Filed: June 3, 2010
    Date of Patent: October 21, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Xiangyang Tai, Given Jing Chen, Yurong Cao, Li Qiang Fan
  • Publication number: 20140303296
    Abstract: A thermoplastic resin composition having good balance among impact resistance, flame retardancy, heat resistance and flowability all of which are required for thin molded articles high-dimensionally. The flame retardant resin composition comprises 100 parts by weight of a resin component comprising (A) a polycarbonate resin and (B) a polycarbonate-polydiorganosiloxane copolymer resin obtained by copolymerizing a dihydric phenol with a hydroxyaryl-terminated polydiorganosiloxane, (C) 3 to 35 parts by weight of an organic phosphorus-based flame retardant or 0.005 to 5 parts by weight of an organic metal salt-based flame retardant, (D) 0.1 to 30 parts by weight of a silicate mineral and (E) 0.1 to 3 parts by weight of a dripping inhibitor, and, if necessary, (F) 3 to 45 parts by weight of a styrene resin wherein the polydiorganosiloxane content of the component (B) in the composition is 0.2 to 0.6 wt %.
    Type: Application
    Filed: November 27, 2012
    Publication date: October 9, 2014
    Inventors: Yasunori Inazawa, Masashi Ishida
  • Patent number: 8841367
    Abstract: Disclosed herein is a flame retardant composition comprising a polycarbonate; 5 to 10 weight percent of a polysiloxane-polycarbonate copolymer; where the polysiloxane-polycarbonate copolymer comprises an amount of greater than 10 weigh percent of the polysiloxane and where the molecular weight of the polysiloxane-polycarbonate copolymer is greater than or equal to 25,000 grams per mole; 5 to 20 weight percent of a branched polycarbonate; 5 to 60 weight percent of a reinforcing filler; and 1 to 15 weight percent of a flame retarding compound.
    Type: Grant
    Filed: May 24, 2013
    Date of Patent: September 23, 2014
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Yun Zheng, Yunan Cheng, Shijie Song