Phosphorus Bonded Directly To Four Chalcogen Atoms, E.g., Phosphate, Etc. Patents (Class 524/127)
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Publication number: 20130078502Abstract: An injection molding composition includes specific amounts of a poly(arylene ether), a rubber-modified polystyrene, a bisphenol bis(diaryl phosphate), and a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene. The composition exhibits improved hydrolysis resistance and is useful for injection molding lead acid battery cases that exhibit improved hydrolysis resistance when employed use in hot, humid environments.Type: ApplicationFiled: September 28, 2011Publication date: March 28, 2013Inventor: Geoffrey Henry Riding
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FLAME-RETARDANT PC/ABS COMPOSITIONS HAVING GOOD IMPACT STRENGTH, FLOWABILITY AND CHEMICAL RESISTANCE
Publication number: 20130079443Abstract: The present invention relates to flame resistant moulding compositions comprising polycarbonates and graft polymers which, in addition to good flow properties, exhibit good (notched) impact strength and high chemical resistance with a UL94V-0 classification at 1.5 mm. These moulding compositions are particularly suitable for thin-walled housing parts in the electrical and electronics sector.Type: ApplicationFiled: September 26, 2012Publication date: March 28, 2013Applicant: Bayer Intellectual Property GmbHInventor: Bayer Intellectual Property GmbH -
Patent number: 8399546Abstract: A flame retardant thermoplastic composition having excellent physical properties that includes 20 to 90 wt. % of a polycarbonate resin; from 1 to 35 wt. % of an impact modifier; from 0.5 to 30 wt. % of a polysiloxane-polycarbonate copolymer including from 8 to 30 wt. % polydimethylsiloxane units or the equivalent molar amount of other diorganosiloxane units; from 0.5 to 20 wt. % of a phosphorus-containing flame retardant, and from 3 to 30 wt. % of metal fiber, each based on the total combined weight of the thermoplastic composition, exclusive of any filler. In one embodiment, a molded sample of the thermoplastic composition having a thickness of 3.0 mm (±10%) has an EMI shielding of at least 20 dB. In addition, a molded sample of the thermoplastic composition is capable of achieving UL94 V0 or V1 rating at a thickness of 1.5 mm (±10%). The compositions are useful in forming flame retardant articles having EMI shielding characteristics.Type: GrantFiled: January 4, 2007Date of Patent: March 19, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Gang Li, Thomas Ebeling, Monica M. Marugan, Zhaohui Qu, Srinivas Siripurapu, David Xiangping Zou
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Publication number: 20130059955Abstract: Halogen-free TPU compositions comprise in weight percent based on the weight of the composition: A. 1 to 99% thermoplastic polyurethane (TPU), B. 1 to 50% tris(2-butoxyethyl)phosphate (TBEP), C. 1 to 70% metal hydrate, and D. 1 to 70% organic phosphate ester other than tris(2-butoxyethyl)phosphate. These compositions exhibit better smoke suppression as compared with conventional organic phosphate flame retardant TPU compositions such as those based on resorcinol bis(diphenyl phosphate) (RDP) and bisphenol-A bis(diphenyl phosphate) (BPADP) in the absence of TBEP.Type: ApplicationFiled: June 3, 2010Publication date: March 7, 2013Inventors: Xiangyang Tai, Given Jing Chen, Yurong Cao, Li Qiang Fan
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Publication number: 20130053487Abstract: This disclosure relates generally to polycarbonate compositions whose hydrolysis products and residual monomer content, if any, exhibit little or no estradiol binding activity. Also disclosed are methods for making the disclosed polycarbonates and articles of manufacture comprising the disclosed polycarbonates.Type: ApplicationFiled: August 1, 2012Publication date: February 28, 2013Inventors: Robert R. Gallucci, James A. Mahood, Jean Francois Morizur, Steve Dimond
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Publication number: 20130053488Abstract: The present invention provides a flame retardant encapsulant composition. A composition includes 40-80 wt. % of an encapsulant comprising 60 to 80 parts by weight of hydrocarbon oil suspended in a cross-linked polymer matrix; and a liquid flame retardant. At least a portion of the liquid flame retardant can be present in the form of a dispersed liquid phase suspended in a continuous oil-rich phase that swells the cross-linked polymer matrix. In some exemplary embodiments, the oil-rich phase comprises less than 15% of the liquid flame retardant dissolved in the oil-rich phase.Type: ApplicationFiled: May 10, 2010Publication date: February 28, 2013Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Haohao Lin, Eumi Pyun, William V. Dower, Zhiqiang Gong, Zhiyong Xu
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Patent number: 8383709Abstract: The present invention relates to flame-resistant moulding compositions of polycarbonates and graft polymers which, in addition to good flow properties, have very good mechanical properties and a particularly good, trouble-free surface. These moulding compositions are suitable in particular for injection moulding uses for mouldings with thin wall thicknesses and high-gloss surfaces. The thermoplastic moulding compositions according to the invention comprise A) 65.0 to 82.0 parts by wt. of at least one aromatic polycarbonate, B) 4.0 to 11.0 parts by wt. of at least one graft polymer, C) 14.0 to 24.0 parts by wt. of at least one phosphorus-containing flameproofing agent, wherein the sum of the parts by weight of components A to C adds up to 100 parts by weight and the total content of the polymer which is formed from the grafting monomers or is added in the free form and is not bonded chemically to the graft base is less than 2.0 wt. %, based on the total moulding composition.Type: GrantFiled: April 21, 2011Date of Patent: February 26, 2013Assignee: Bayer Materialscience AGInventors: Thomas Eckel, Burkhard Thuermer, Vera Taschner, Dieter Wittmann
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Patent number: 8378012Abstract: A flame retardant composition is provided which contains at least one phosphate ester containing at least one acidic substance resulting from the process of its manufacture, at least one acidity-reducing hydrotalcite and, optionally, at least one acidity-reducing oxetane. The flame retardant composition is especially useful for addition to resins that are susceptible to hydrolytic degradation such as polyesters and polycarbonates, and to resin blends (alloys) containing one or more of such resins, e.g., a blend of polycarbonate and acrylonitrile butadiene-styrene terpolymer.Type: GrantFiled: November 7, 2006Date of Patent: February 19, 2013Assignee: ICL-IP America Inc.Inventors: Paul Y. Moy, Leslie Bright
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Patent number: 8367754Abstract: A flameproof thermoplastic resin composition comprises (A) 100 parts by weight of a thermoplastic resin; (B) about 1 to about 40 parts by weight of a sublimational filler; and (C) about 1 to about 30 parts by weight of a flame retardant. The thermoplastic resin composition can solve the problems of high specific gravity and deterioration of flame retardancy caused by adding a conventional filler.Type: GrantFiled: June 28, 2010Date of Patent: February 5, 2013Assignee: Cheil Industries Inc.Inventors: Seon Ae Lee, Sang Hyun Hong, Kyung Hoon Shin, Jin Seong Lee, Seong Ho Kong
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Publication number: 20130030096Abstract: A poly(arylene ether) composition includes a styrenic polymer, a flame retardant comprising an organophosphate ester, and a poly(arylene ether)-polysiloxane block copolymer reaction product. The poly(arylene ether)-polysiloxane block copolymer reaction product includes a poly(arylene ether)-polysiloxane block copolymer and a poly(arylene ether) homopolymer. The composition is useful for forming molded articles, including photovoltaic junction boxes and connectors. The composition exhibits stiffness and a good balance of flame retardancy, impact strength, flow, and heat resistance.Type: ApplicationFiled: July 25, 2011Publication date: January 31, 2013Inventor: Christian Lietzau
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Publication number: 20130030093Abstract: Halogen-free, flame-retardant thermoplastic polyester elastomer (TPE-E) compositions that include at least one thermoplastic polyester elastomer, at least one low-melting, phosphorus-based flame retardant having a melting temperature no higher than 150° C., and a blend of solid intumescent flame retardants comprising a phosphorus-based, organic salt flame retardant and a nitrogen-based organic flame retardant are provided. The presence of the low-melting, phosphorus-based flame retardant renders the compositions more resistant to scratch-whitening.Type: ApplicationFiled: March 26, 2010Publication date: January 31, 2013Inventors: Given Jing Chen, Fangming Tony Gu, Yurong Cao, David H. Guo, Xiaoxiong Shawn Miao
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Patent number: 8357441Abstract: The present invention is an ignition resistant carbonate polymer composition, a method to make said composition and fabricated articles made therefrom. The ignition resistant carbonate polymer composition comprises: (i) an aromatic polycarbonate or an aromatic polyester carbonate, (ii) a graft polymer, (iii) optionally one or more thermoplastic vinyl (co)polymer, (iv) optionally one or more thermoplastic polyester polymer, (v) an aromatic phosphate compound, and (vi) a mixture of a fibril forming polytetrafluoroethylene polymer and a fluorothermoplast.Type: GrantFiled: July 29, 2009Date of Patent: January 22, 2013Assignee: Styron Europe GmbHInventors: Claude T. Van Nuffel, Pascal Lakeman, Jozef Van Dun, Giacomo Parisi, Mike J. Hale
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Publication number: 20130018115Abstract: Provided is a method for recovering a polycarbonate resin from a discarded optical disk and/or a recovered optical disk, which has a polycarbonate resin substrate. The following process steps (I) and (II) are applied to a chemically treated product, which is obtained by crushing a discarded optical disk and/or a recovered optical disk, and chemically treating the resulting crushed product. Process step (I): a step containing (a) removing a magnetic metal foreign matter with a magnet, and (b) identifying a colored foreign matter with an optical camera, and removing the colored foreign matter. Process step (II): a step containing detecting the presence of a metal foreign matter with a metal foreign matter detector, and removing a resin containing the metal foreign matter.Type: ApplicationFiled: December 24, 2010Publication date: January 17, 2013Applicants: PANAC INDUSTRIES, INC., IDEMITSU KOSAN CO., LTD.Inventors: Toshio Isozaki, Kenichi Mitsuhashi, Nobuyuki Ito
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Publication number: 20130011639Abstract: Disclosed is a metallic pigment composition that can be used in coating compositions or ink compositions, specifically, in water-based coatings and water-based inks, and exhibits superior coating material storage stability. When formed into a coating material, the metallic pigment composition has superior performance for photoluminescence, concealment, flip-flop color and other properties, and does not change the color of dyes or organic pigments. The metallic pigment composition contains: at least one organic molybdenum compound; a hydrolysate of a compound containing silicon and/or a condensate thereof; and metal particles.Type: ApplicationFiled: March 29, 2011Publication date: January 10, 2013Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Kazuko Nakajima, Kaoru Ueyanagi
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Patent number: 8349926Abstract: The present invention relates to scratch-resistant, impact-resistant polycarbonate (PC) compositions and moulding compositions which have good mechanical properties and a high resistance to chemicals coupled with good flameproofing properties, and show improved flow properties during processing. The present invention furthermore relates to a process for the preparation of the compositions and their use for the production of shaped articles, in particular housings of flat screen apparatuses.Type: GrantFiled: December 16, 2010Date of Patent: January 8, 2013Assignee: Bayer Materialscience AGInventors: Thomas Eckel, Vera Taschner, Achim Feldermann, Burkhard Thuermer
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Patent number: 8349927Abstract: The present invention relates to scratch-resistant, impact-resistant polycarbonate (PC) compositions and molding compositions which have good mechanical properties as well as high resistance to chemicals, to a process for their preparation, and to their use in the production of molded articles, in particular of casings for flat screen devices.Type: GrantFiled: December 16, 2010Date of Patent: January 8, 2013Assignee: Bayer Materialscience AGInventors: Thomas Eckel, Vera Taschner, Achim Feldermann, Burkhard Thuermer
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Patent number: 8344051Abstract: The present invention relates to flameproofed, impact-modified, scratch-resistant polycarbonate (PC) compositions and molding compositions with surface-modified, calcined kaolin as filler, which have good mechanical properties, good flowability and high chemical resistance. Furthermore, the present application relates to the use of the compositions for the production of moldings.Type: GrantFiled: December 16, 2010Date of Patent: January 1, 2013Assignee: Bayer MaterialScience AGInventors: Thomas Eckel, Vera Taschner, Achim Feldermann, Burkhard Thuermer, Dieter Wittmann
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Patent number: 8329791Abstract: The present invention provides phosphonate compounds represented by Chemical Formula 1. In addition, the invention provides flame retardant styrene resin compositions comprising (A) styrene resin, (B) polyphenylene ether resin, and (C) the phosphonate compound. The flame retardant styrene resin compositions according to the invention: can provide protection against fire, exhibit improved impact strength, and can be environment-friendly.Type: GrantFiled: June 22, 2011Date of Patent: December 11, 2012Assignee: Cheil Industries Inc.Inventors: Beom Jun Joo, Man Suk Kim, Woo Joong Kim, Seon Ae Lee, Byun Kun Lee, Myoung Jun Kim
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Publication number: 20120301766Abstract: Provided a polycarbonate resin composition excellent in flame resistance, impact resistance, and color fastness. A polycarbonate resin composition containing, per 100 parts by mass of polycarbonate resin (A), 0.001 to 30 parts by mass of flame retardant (B), 0.001 to 1 part by mass of fluoropolymer (C), and 0.5 to 10 parts by mass of graft copolymer (D) obtainable by graft-copolymerizing a diene-based rubber with a (meth)acrylate ester compound, the graft copolymer (D) having (i) a sulfur content of 100 to 1500 ppm, and (ii) an average particle size of 70 to 240 nm.Type: ApplicationFiled: November 15, 2011Publication date: November 29, 2012Inventors: Toshiki Monden, Yutaka Shiraishi
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Publication number: 20120282490Abstract: Ethyleneamine polyphosphates are good flame retardants. Use of non viscous phase enables making modified ethyleneamine polyphosphate of enhanced thermal stability and greatly reduced waste stream. Addition of fillers such as fumed silica unexpectedly improve the flame retardance. Organic phosphates improve compatibility.Type: ApplicationFiled: October 19, 2010Publication date: November 8, 2012Inventor: Robert Valentine Kasowski
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Patent number: 8299149Abstract: There is provided herein a process for purifying bisphosphate comprising solvating a molten bisphosphate in a mixture of water and water miscible solvent; cooling the solution over a period and to a temperature that provides for crystallization of solid product; increasing the pH of the solution prior to, and/or during, and/or after the initiation of crystallization, and/or after crystallization, by the addition of a base; and after crystallization is complete, separating solid product from the solution; washing the separated solid product in the same and/or different mixture of water and water miscible solvent; and, washing the solid product which has been washed in the mixture with water.Type: GrantFiled: December 21, 2009Date of Patent: October 30, 2012Assignee: ICL-IP America Inc.Inventors: Joseph Zilberman, Dorit Canfi, Andrew Gregor, Andrew Piotrowski
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Patent number: 8283397Abstract: The present invention provides a resin-coated metal pigment capable of achieving both of water resistance of a water base paint and chemical resistance of a film at a high level, and a water base paint using the resin-coated metal pigment. The present invention provides a method for producing a resin-coated metal pigment including an adsorption step of bringing a solution or a dispersion liquid of a phosphate ester component (A) into contact with a metal pigment to prepare a phosphate ester adsorbing metal pigment, a slurry preparation step of preparing a slurry for polymerization obtained by dissolving a polymerization component (B) therein, and a coating step of polymerizing the polymerization component (B) to form a resin coating layer on the surface of the phosphate ester adsorbing metal pigment; a resin-coated metal pigment obtained by the method; and a water base paint using the resin-coated metal pigment.Type: GrantFiled: October 11, 2006Date of Patent: October 9, 2012Assignee: Toyo Aluminium Kabushiki KaishaInventors: Wataru Terao, Yasushi Takano, Shunichi Setoguchi
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Publication number: 20120244359Abstract: The present invention relates to compositions containing flame retardant polycarbonate, which are suitable for producing flame-resistant milk-white coloured plates.Type: ApplicationFiled: November 3, 2010Publication date: September 27, 2012Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Alexander Meyer, Berit Krauter, Claus Rüdiger, Ulrich Blaschke, Peter Schwarz
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Publication number: 20120231278Abstract: The present invention relates to compositions which contain flame-retardant polycarbonate and are suitable for the production of flame-resistant and milky-white sheets.Type: ApplicationFiled: November 3, 2010Publication date: September 13, 2012Applicant: Bayer Intellectual Property GmbHInventors: Ulrich Blaschke, Alexander Meyer, Claus Rüdiger, Berit Krauter
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Patent number: 8258216Abstract: The present invention generally relates to a resin composition, a cured resin, a sheet-like cured resin, a laminated body, a prepreg, electronic parts, single and multilayer circuit boards comprising a cyanate ester polymer and condensed phosphate ester, for use in single and multilayer circuit boards that are especially useful in the high-frequency range of above 100 MHz.Type: GrantFiled: August 27, 2010Date of Patent: September 4, 2012Assignee: Park Electrochemical CorporationInventors: Wei Qiang, Ke Wang, Doug Leys, Greg Almen
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Publication number: 20120213982Abstract: The invention relates to flame resistant polycarbonate plates characterised in that the flame-proof properties thereof are maintained even after long exposure to weathering.Type: ApplicationFiled: November 3, 2010Publication date: August 23, 2012Applicant: Bayer Intellectual Property GmbHInventors: Alexander Meyer, Berit Krauter, Claus Rüdiger, Ulrich Blaschke, Peter Schwarz
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Publication number: 20120208936Abstract: The invention relates to polycarbonate compositions and copolycarbonate compositions with improved melt stability, the preparation thereof and the use thereof for the production of mouldings and mouldings obtainable therefrom, wherein the compositions contain a polycarbonate or copolycarbonate containing bisphenol A, and at least one phosphorus compound of the formulae (1) and (2), wherein R1 and R2 independently of each other and among one another are chosen from the group which includes branched alkyl radicals, aryl radicals and substituted aryl radicals.Type: ApplicationFiled: September 17, 2010Publication date: August 16, 2012Inventors: Rolf Wehrmann, Helmut Werner Heuer
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Patent number: 8242197Abstract: The present disclosure pertains to a blend of aromatic polycarbonate and polylactic acid, the method for preparing the same and the use thereof. In the present invention a transesterification catalyst is added during the preparing process with regard to the blend of aromatic polycarbonate and polylactic acid to improve the compatibility of the components in the blend. The blend of aromatic polycarbonate and polylactic acid is provided with the good mechanical properties, thermal processibility and flame retardance properties, and can be widely applied to mechanical product or parts, electronic equipments and/or parts, construction material and/or commodities.Type: GrantFiled: September 8, 2009Date of Patent: August 14, 2012Assignee: Bayer Materialscience AGInventors: Holger Warth, Sichong Chen, Yuzhong Wang, Yanyan Wang, Hongchao Li
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Publication number: 20120202034Abstract: Provided herein are branched polycarbonate resin compositions that withstand discoloration and increased melt viscosity when exposed to elevated temperatures. These compositions are useful in the manufacture of various shaped, formed and/or molded articles.Type: ApplicationFiled: February 3, 2011Publication date: August 9, 2012Inventors: Jean-Francois Morizur, Yaming Niu, Thomas Evans
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Publication number: 20120202061Abstract: Flame retardant compositions that include a thermoplastic polyurethane, a metal hydrate flame retardant and a phosphorus-based flame retardant are provided. The compositions are characterized by good flame retardant properties, as well as high insulation resistance.Type: ApplicationFiled: October 28, 2009Publication date: August 9, 2012Inventors: Lan Lu, Given Jing Chen, Xiaowei Wilson Yan, Bin Li, Weiming Wayne Ma
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Patent number: 8222329Abstract: Disclosed herein is a symmetric cyclic phosphonate compound represented by the following Formula 1, a method of preparing the same and a flame retardant styrenic resin composition including the same: wherein R1 and R2 are each independently hydrogen, C1-C6 alkyl or C6-C20 aryl. The styrene resin composition employing the symmetric cyclic phosphonate compound exhibits good flame retardancy and impact strength, does not release halide gas during preparation or combustion of the resin composition, and thus is environmentally friendly.Type: GrantFiled: February 5, 2010Date of Patent: July 17, 2012Assignee: Cheil Industries Inc.Inventors: Beom Jun Joo, Sang Hyen Hong, Min Soo Lee, Byun Kun Lee
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Patent number: 8222331Abstract: An injection molded article, such as a washing machine top, exhibiting an improved balance of heat resistance, ductility, and absence of molding-related defects is formed from a poly(arylene ether)-block copolymer composition. The composition includes specific amounts of a poly(arylene ether) having particular molecular weight characteristics, a hydrogenated block copolymer, and an organophosphate ester flame retardant.Type: GrantFiled: December 14, 2010Date of Patent: July 17, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventor: Geoffrey H. Riding
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Patent number: 8217101Abstract: A thermoplastic molding composition characterized by its flame retardance is disclosed. The composition contains A) aromatic poly(ester) carbonate having a weight-average molecular weight of at least 25,000, B) (co)polyester and C) graft (co)polymer having a core-shell morphology, comprising a grafted shell that contains polymerized alkyl(meth)acrylate and a composite rubber core that contains interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate where the weight ratio of polyorganosiloxane/poly(meth)alkylacrylate/grafted shell is 70-90/5-15/5-15, D) phosphorus-containing compound, E) fluorinated polyolefin and F) boron compound having average particle diameter of 2 to 10 microns.Type: GrantFiled: March 2, 2007Date of Patent: July 10, 2012Assignee: Bayer MaterialScience LLCInventor: Xiangyang Li
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Publication number: 20120172504Abstract: A thermoplastic resin composition includes a polycarbonate resin/impact modifier system, a polystyrene resin having a predetermined molecular weight, and a phosphorus flame retardant. The impact modifier includes a particular rubber particle size and is formed of particular monomers. The composition can exhibit improved flame retardancy, impact resistance, fluidity, and appearance.Type: ApplicationFiled: December 29, 2011Publication date: July 5, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Kyuong Sik CHIN, Seung Shik SHIN, Yun Ku NAM, Hwan Seok PARK
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Publication number: 20120165444Abstract: Disclosed herein is a phosphorus compound represented by Formula 1: wherein each R is the same or different and is independently hydrogen, C1-C6 alkyl or C6-C12 aryl.Type: ApplicationFiled: October 12, 2011Publication date: June 28, 2012Applicant: CHEIL INDUSTRIES INC.Inventors: Min Soo LEE, Im Hyuck BAE, Seon Ae LEE, Sang Hyun HONG, Chang Hong KO, Beom Jun JOO, Jin Hwan KIM, Ik Hyun YU, Thi Hai VO, Thanh Kieu GIANG, Thi Thuy Hang NGUYEN
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Publication number: 20120149815Abstract: Embodiments in accordance with the present invention provide polymers for forming layers/films useful in the manufacture of a variety of types of optoelectronic displays. Such embodiments also provide compositions of such polymers for forming such layers/films where the formed layers/films have high transparency over the visible light spectrum.Type: ApplicationFiled: December 9, 2011Publication date: June 14, 2012Applicants: Promerus LLC, Sumitomo Bakelite Co., Ltd.Inventors: Osamu Onishi, Larry F. Rhodes, Nobuo Tagashira
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Patent number: 8193261Abstract: Disclosed herein is a composition for preparing a halogen-free flame retarding masterbatch with low phosphorous content. The flame retarding masterbatch includes a phosphorus-containing flame retardant in an amount of about 0.1-6 wt %, a sulfur-containing flame retardant in an amount of about 0.1-5 wt %, a tertiary or quaternary ammonium salt having tri- or tetra-functional groups in an amount of about 0.1-5 wt %, a thermoplastic polymer in an amount of about 79-99.6 wt %, and a dispersing agent in an amount of about 0.1-5 wt % in the composition.Type: GrantFiled: December 28, 2009Date of Patent: June 5, 2012Assignee: Taiwan Textile Research InstituteInventors: Sheng-Jen Lin, Hsi-Wen Chang, Nai-Yun Liang, Wei-Peng Lin, Ying-Hsiu Hsiao
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Publication number: 20120132457Abstract: The present disclosure provides a composition which includes a thermoplastic elastomer and a flame retardant composed of a metal hydrate and an oligomeric phosphate ester. The weight ratio of metal hydrate to oligomeric phosphate ester is greater than 1.45:1. The composition may be a component of an article such as a coated wire or a coated cable, with the composition present in the coating.Type: ApplicationFiled: July 31, 2009Publication date: May 31, 2012Inventors: Xiang Y. Tai, Wei G. Yao, Yu D. Qi, Given J. Chen, Robert F. Eaton
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Publication number: 20120123007Abstract: There is provided herein a styrenic polymer composition comprising a styrenic polymer and a flame retardant effective amount of a mixture comprising (a) at least one brominated flame retardant; and, (b) at least one solid phosphate ester that has a melting temperature of at least 80 degrees Celsius.Type: ApplicationFiled: February 18, 2010Publication date: May 17, 2012Inventors: Smadar Hini, Michael Peled, Gideon Shikolsky, Grigory I. Titelman, Yoav-Bar Yaakov, Joseph Zilberman, Sergei V. Leychik
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Publication number: 20120121877Abstract: There is provided herein a polyolefin composition comprising a polyolefin and a flame retardant effective amount of a solid phosphate ester of the general formula (1): wherein n has an average value of from about 1.0 to about 2.0 and X is a divalent arylene moiety bonded to both of the oxygen atoms of any one of hydroquinone, resorcinol, 4,4?-biphenol, bisphenol S, or bisphenol F, and wherein the phosphate ester is in the absence of halogen. There is also provided a method of making the polyolefin composition. This fire retardant polyolefin composition is particularly useful in polypropylene fiber and films and foams.Type: ApplicationFiled: March 1, 2010Publication date: May 17, 2012Inventors: Sergei V. Levchik, Gerald R. Alessio, Pierre Georlette
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Patent number: 8178603Abstract: The present disclosure relates to an impact-modified polycarbonate composition which comprise a first graft polymer containing silicone/acrylate composite rubber as the graft base, wherein the content of silicone rubber is 65-95 wt. % (based on the graft base), a second graft polymer containing a diene rubber, and phosphorus-containing flameproofing agent, the use of the polycarbonate compositions for the production of shaped articles and the shaped articles themselves. The compositions and molding compositions according to the disclosure have an optimum combination of good flameproofing at thin wall thicknesses, good resistance to chemicals and hydrolysis and low melt viscosity.Type: GrantFiled: December 18, 2009Date of Patent: May 15, 2012Assignee: Bayer MaterialScience AGInventors: Thomas Eckel, Vera Taschner, Achim Feldermann, Eckhard Wenz
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Patent number: 8167957Abstract: An agent and method for treating biodegradable synthetic yarns fabricated from a polymer comprising lactic acid as a main component, which enable improved lubricity, cohesion, etc. to be so imparted to the biodegradable synthetic yarns that the yarns can be prevented from fuzzing and breaking at every step from spinning to down-stream step, especially at a false twisting step and improved in terms of bulkiness, providing yarns having improved mechanical properties in a stable manner. The agent of the invention comprises 0.1 to 30 weight % of a specific functional agent, and a lubricant and a surfactant in the total amount of 70 weight % or greater, and has a friction coefficient in the range of 0.04 to 0.35.Type: GrantFiled: September 13, 2010Date of Patent: May 1, 2012Assignee: Takemoto Yushi Kabushiki KaishaInventor: Hiroshi Yamakita
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Patent number: 8168707Abstract: A thermoplastic composition comprises, based on the total weight of the composition: 51-90 wt % of a polyester, 10-49 wt % of an ABS impact modifier; 0 to 20 wt % of a multifunctional epoxy compound; 0-40 wt % of a filler; 0-2 wt % of a fibrillated fluoropolymer; and from more than 0 to 5 wt % of a stabilizer composition. An article blow molded or injection molded from the composition has a multi-axial impact total energy from 40-100 Joules at ?30° C.; a ductility of more than 90%, a permeability of more than 0 to less than or equal to 1.5 g/m2-day, measured after exposure Fuel C vapor for 20 weeks at 40° C.; an MVR of 1-20 cc/10 min; a flexural modulus of greater than 1300 MPa; and retains at least 75% of its initial tensile elongation at break after exposure to Fuel E85 for 28 days at 70° C.Type: GrantFiled: August 7, 2008Date of Patent: May 1, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Parminder Agarwal, Donald Howard Ellington, Robert Russell Gallucci, Josephus Gerardus M. van Gisbergen, Vishvajit Chandrakant Juikar, Ihab Odeh, Sathish Kumar Ranganathan, Kenneth Frederick Miller, Veeraraghavan Srinivasan
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Publication number: 20120088870Abstract: Use of an talc being coated with an organo-metallic compound in a polymer composition to accomplish a headspace emission of all volatiles together of said polymer composition of equal or below 120 ?g/g.Type: ApplicationFiled: June 16, 2010Publication date: April 12, 2012Applicant: BOREALIS AGInventors: Juliane Braun, Johannes Wilfschwenger
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Patent number: 8153710Abstract: A method is disclosed concerning discovering how the use of an additive in a polyolefin compound affects the weatherability of that compound, Applying that technique, a weatherable polyolefin nanocomposite is disclosed, which contains UV stabilizers that filter wavelengths in a range influenced by presence of organoclay in the nanocomposite.Type: GrantFiled: March 28, 2011Date of Patent: April 10, 2012Assignees: Polyone Corporation, Amcol International CorporationInventors: David A. Jarus, Guoqiang Qian
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Publication number: 20120074617Abstract: Battery box comprising compositions containing A) 70.0 to 90.0 parts by weight of linear and/or branched aromatic polycarbonate and/or aromatic polyester carbonate, B) 6.0 to 15.0 parts by weight of at least one graft polymer, C) 2.0 to 15.0 parts by weight of one or more phosphorus compounds, D) 0 to 3.0 parts by weight of antidripping agents, E) 0 to 3.0 parts by weight of thermoplastic vinyl (co)polymer (E.1) and/or polyalkylene terephthalate (E.2), and F) 0 to 20.0 parts by weight of further additives, wherein the compositions are optionally free from rubber-free polyalkyl(alkyl)acrylate.Type: ApplicationFiled: September 22, 2011Publication date: March 29, 2012Applicant: BAYER MATERIALSCIENCE AGInventors: Thomas ECKEL, Ulrich GROSSER, Claus RÜDIGER, Achim FELDERMANN, Dieter WITTMANN
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Publication number: 20120074036Abstract: The present invention relates to battery boxes comprising flame-retardant compositions comprising A) linear and/or branched aromatic polycarbonate and/or aromatic polyester carbonate, B) at least one graft polymer, C) one or more phosphorus compounds, D) optionally one or more antidripping agents, optionally E) thermoplastic vinyl (co)polymer (E.1) and/or polyalkylene terephthalate (E.2), and F) optionally one or more further additives, wherein the composition is preferably free from rubber-free polyalkyl(alkyl)acrylate.Type: ApplicationFiled: September 22, 2011Publication date: March 29, 2012Applicant: BAYER MATERIALSCIENCE AGInventors: Thomas ECKEL, Ulrich GROSSER, Claus RÜDIGER, Achim FELDERMANN
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Patent number: 8138245Abstract: The invention relates to a halogen free flame retardant polyester composition suitable for use as a molding composition for making lampholders, comprising (A) a polymeric material consisting for at least 50 wt. %, relative to the total weight of the polymeric material, of a thermoplastic polyester; (B) a flame retardant system in an amount of 11-35 wt. %, relative to the total weight of (A), (B) and (C), and consists of: melamine cyanurate, and optionally one or more of the following flame retardant components: another phosphorus-free nitrogen based organic flame retardant compound, a phosphorus containing flame retardant excluding elementary phosphorus, in an amount of less than 1 wt. %, relative to the total weight of (A), (B) and (C); an inorganic flame retardant synergist, and an organic flame retardant synergist (C) a fibrous reinforcing agent in an amount of 5-35 wt. %, relative to the total weight of (A), (B) and (C); and (D) a mould release agent in an amount of at least 0.01 wt.Type: GrantFiled: April 2, 2007Date of Patent: March 20, 2012Assignee: DSM IP Assets B.V.Inventors: Ronald M. A. M. Schellekens, Robert H. C. Janssen, Theodorus J. G. Zwartkruis, Franciscus Vehmendahl Van
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Publication number: 20120065307Abstract: Color-stable, halogen-free, flame retardant composition comprise, based on the weight of the composition: A. 10-95 weight percent of a thermoplastic polyurethane polymer; B. 3-50 weight percent of a phosphorus-based flame retardant; and 0.1-10 weight percent of a low molecular weight epoxide additive other than a novolak polymer or an olefin-based polymer comprising an epoxy group.Type: ApplicationFiled: June 3, 2010Publication date: March 15, 2012Inventors: Jeffrey M. Cogen, Given J. Chen, Xiang Y. Tai, Geoffrey D. Brown
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Patent number: 8129456Abstract: Flame retardant compositions that are halogen-free or substantially halogen-free are disclosed. In certain examples, the compositions comprise a halogen-free or substantially halogen-free epoxide and one or more phosphorated compounds. In some examples, the phosphorated compound comprises an average particle size less than 10 microns. In other examples, the phosphorated compound provides a surface area of 78.5 ?m2 to about 1965 ?m2. Prepregs, laminates, molded articles and printed circuit boards using the compositions are also disclosed.Type: GrantFiled: November 8, 2005Date of Patent: March 6, 2012Assignee: Isola USA Corp.Inventors: David Bedner, William D. Varnell