Abstract: An oligomeric phosphate or mixture of oligomeric phosphates having the general formula (I) wherein R1, R2, R3 and R4 each independently is aryl or alkaryl and n has an average value of from about 1.0 to about 2.0 and resin compositions containing the same.

Abstract: A flame-retardant thermoplastic elastomer compound is disclosed having polyphenylene ether, a hydrogenated styrene block copolymer, at least one solid non-halogenated phosphorus containing flame retardant, and a nucleated olefinic polymer. The compound has a before-aging tensile elongation of >200% and an after-aging tensile elongation residual of at least 75%, according to the UL 62 test, which makes it useful as an insulation layer, a jacketing layer, or both for protected electrical lines such as alternating current wire and cable products, accessory cables, and variety of injection molded electrical or electronic parts.

Abstract: Fibrous basic magnesium sulfate-containing pellets comprising an olefin polymer and fibrous basic magnesium sulfate in a weight ratio of 80:20 to 20:80 and further comprising a nucleating agent in an amount of 0.3 to 8 weight parts based on 100 weight parts of the olefin polymer and in an amount of 0.2 to 4 weight parts based on 100 weight parts of the fibrous basic magnesium sulfate are favorably employable for producing molded fibrous basic magnesium sulfate-containing propylene polymer products which show high flexural modulus, high flexural strength and high yield strength in tension as well as excellent thermal stability.

Abstract: There is provided herein a process for purifying bisphosphate comprising solvating a molten bisphosphate in a mixture of water and water miscible solvent; cooling the solution over a period and to a temperature that provides for crystallization of solid product; increasing the pH of the solution prior to, and/or during, and/or after the initiation of crystallization, and/or after crystallization, by the addition of a base; and after crystallization is complete, separating solid product from the solution; washing the separated solid product in the same and/or different mixture of water and water miscible solvent; and, washing the solid product which has been washed in the mixture with water.

Abstract: There is provided herein a flame retardant additive composition comprising: a. at least one aromatic bisphosphate b. at least one metal phosphonate; and, c. at least one nitrogen-rich compound. There is also provided a thermoplastic polymer composition, containing thermoplastic polymer, e.g., thermoplastic polyester and the flame retardant additive composition; a method of making said flame retardant additive composition; and an article, e.g., an electronic component, containing the thermoplastic polymer composition.

Abstract: Provided are an organic solvent dispersion of titanium oxide containing at least titanium oxide fine particles each having an average primary particle diameter of 3 nm or more to 50 nm or less; a titanate-based surface treatment agent formed of a compound represented by the following general formula (1): (R1O)m—Ti—Xn ??(1) where R1 represents a methyl, ethyl, or isopropyl group; X represents —O—SO2—R2 or —O—P(OH)O—O—PHO—O—R2; R2 represents an alkyl or aryl group having 1 to 16 carbon atoms; m represents a numerical value of 1 or more to 3 or less, and n represents a numerical value of 1 or more to 3 or less, provided that m+n=4; a polyether-based dispersant; and an alcohol-based solvent, and an optical material containing the organic solvent dispersion of titanium oxide and a resin.

Abstract: Provided is a film or sheet composed of a resin composition that includes a poly lactic acid (A), an acidic functional group-modified olefinic polymer (B) including an acidic functional group and having an acid value of 10 to 70 mg KOH/g and a weight average molecular weight of 10,000 to 80,000, a tetrafluoroethylene polymer (C), and an aromatic-condensed phosphoric acid ester-containing flame retardant (D) including a compound of General Formula (I) and in which the aromatic-condensed phosphoric acid ester-containing flame retardant (D) is included in an amount of 10 to 80 parts by weight based on 100 parts by weight of the poly lactic acid (A), and a method for manufacturing the film or sheet by melt film formation. Each sign in Formula is as described in the specification.

Abstract: Disclosed herein is a scratch-resistant polycarbonate resin composition, the resin composition comprising: (A) about 100 parts by weight of a polycarbonate resin; (B) about 1 to about 30 parts by weight of a phosphate eater compound represented by the following Formula (II) or a combination thereof: and (C) about 0.1 to about 30 parts by weight of a halogen substituted polycarbonate oligomer represented by the following Formula (III): wherein R1, R2, R4 and R5 are each independently C6-20 aryl or C1-10 alkyl-substituted C6-20 aryl, R3 is C6-30 aryl or C1-10 alkyl-substituted C6-30 aryl derivative, m represents a number average degree of polymerization, and the average of m is 0 to 3; wherein each X is independently fluorine, chlorine or bromine, each Y is independently hydrogen, C1-8 alkyl, fluorine, chlorine or bromine, n is an integer of 1 to 10, and 1 is an integer of 1 to 3.

Abstract: A phosphorus flame-retardant composition characterized in that it comprises an aromatic diphosphate compound represented by the general formula (I): wherein R1 and R2 are, the same or different, a lower alkyl group, R3 and R4 are, the same or different, a hydrogen atom or a lower alkyl group, Y is a bonding arm, a —CH2—, —C(CH3)2—, —S—, —SO2?, —O—, —CO— or —N?N— group, k is 0 or 1, and m is an integer from 0 to 4, and it contains, as an impurity, a phosphorus compound having a hydroxyphenyl group represented by the general formula (II): wherein R1, R2, R3, R4, Y, k and m are as defined in the general formula (I), the content of the phosphorus compound being 1% by area or less as determined by gel permeation chromatography (GPC).

Abstract: The present invention relates to flame-resistant moulding compositions of polycarbonates and graft polymers which, in addition to good flow properties, have very good mechanical properties and a particularly good, trouble-free surface. These moulding compositions are suitable in particular for injection moulding uses for mouldings with thin wall thicknesses and high-gloss surfaces. The thermoplastic moulding compositions according to the invention comprise A) 65.0 to 82.0 parts by wt. of at least one aromatic polycarbonate, B) 4.0 to 11.0 parts by wt. of at least one graft polymer, C) 14.0 to 24.0 parts by wt. of at least one phosphorus-containing flameproofing agent, wherein the sum of the parts by weight of components A to C adds up to 100 parts by weight and the total content of the polymer which is formed from the grafting monomers or is added in the free form and is not bonded chemically to the graft base is less than 2.0 wt. %, based on the total moulding composition.

Abstract: The present invention provides a thermoplastic resin composition containing 100 parts by mass of a mixture of a thermoplastic resin (A) and carbon nanotubes (B), the mixture comprising the component (A) in an amount of 20 to 99.95 mass % and the component (B) in an amount of 0.05 to 20 mass %; a flame retardant (C) in an amount of 0.05 to 30 parts by mass; and a polyfluoroolefin resin in an amount of 0 to 2 parts by mass. The flame retardant is preferably a phosphorus compound, and the thermoplastic resin preferably contains, as a component, an aromatic polycarbonate-polyorganosiloxane copolymer.

Abstract: The present invention provides phosphonate compounds represented by Chemical Formula 1. In addition, the invention provides flame retardant styrene resin compositions comprising (A) styrene resin, (B) polyphenylene ether resin, and (C) the phosphonate compound. The flame retardant styrene resin compositions according to the invention: can provide protection against fire, exhibit improved impact strength, and can be environment-friendly.

Abstract: A particle including: at least one selected from an ionic liquid that has, as an organic cation, one selected from cyclic amidine ion-based organic cations, pyridinium-based organic cations, ammonium-based organic cations, sulfonium-based organic cations, and phosphonium-based organic cations, or a liquid phosphate ester; and a polymer compound that serves as a base material, a resin composition including the particle and a resin molded article including the resin composition are provided.

Abstract: The present invention relates to a halogen-free or substantially halogen-free flame-retardant composition comprising a blend of (i) at least one of each highly charring polymer (ii) at least one low volatility phosphate ester, and (iii) at least one compound which splits off a high volatility phosphorus-containing fragment. The invention also relates to a flame retarded thermoplastic composition wherein the flame retardant composition is blended with at least one thermoplastic resin (iv), preferable a polystyrene resin. The invention also relates to a process for manufacturing a flame retardant composition and a thermoplastic composition containing the same.

Abstract: A thermoplastic polycarbonate composition includes, based on the total weight of the thermoplastic polycarbonate composition: 15 to less than 40 wt. % of a reinforcing mineral filler; and greater than 60 to 85 wt. % of a polymer component, including, based on the weight of the polymer component, 68 to 99.9 wt. % of an aromatic polycarbonate, 0.1 to 2 wt. % of a fluorinated polymer, optionally, 0.1 to 25 wt. % of an impact modifier; and optionally, 0.1 to 5 wt. % of an additive composition including an antioxidant, a mold release agent, and a stabilizer; wherein a molded sample of the thermoplastic polycarbonate composition has no drips when measured in accordance with NF P 92-505 at a thickness of 3.0 mm.

Abstract: Clays and organoclays which are treated with resorcinol diphosphate and/or bisphenol diphosphate as general nanoparticle particle dispersants and replacements for quaternary amines. The two compounds are used as self activating and self dispersing nanoparticles by localizing themselves on the particle surface in a polymer matrix and acting as a nanoparticle dispersants in general, as well as resulting in exfoliation of clays. The exfoliate clays may be used in polymers in lieu of other organic treatments.

Abstract: The thermoplastic resin composition of the present invention comprises: about 100 parts by weight of a base resin comprising (A) about 5 to about 40% by weight of a rubber modified aromatic vinyl based copolymer resin, (B) about 30 to about 90% by weight of a polycarbonate resin, and (C) about 1 to about 50% by weight of a noncrystalline polyester resin; and (D) about 5 to about 30 parts by weight of an aromatic phosphate ester based compound.

Abstract: Polyglycolic acid and polylactic acid having a weight-average molecular weight of at most 50,000 are melt-kneaded in the presence of a thermal stabilizer to obtain a polyglycolic acid-based aliphatic polyester composition. The aliphatic polyester composition alleviates the too fast crystallizability of polyglycolic acid which has been problematic in forming or molding of polyglycolic acid alone or in combination with another thermoplastic resin, thus showing a crystallization speed which has been lowered and can be controlled in a wide range.

Abstract: One subject of the present invention is a method for preparing a composite preferably containing 10 to 50% by weight of nanotubes, comprising: (a) the introduction, into a mixer, of nanotubes and at least one thermoplastic polymer, such as a homopolyamide or copolyamide, a polycarbonate, SBM or a PEG; (b) the melting of the thermoplastic polymer; and (c) the mixing of the molten thermoplastic polymer and the nanotubes, provided that aplasticizer is introduced upstream of, or in, the melting zone of the polymer. The invention also relates to the composite thus obtained and to its use in the manufacture of a composite product.

Abstract: Polycarbonate compositions are disclosed. The compositions comprise an optional polycarbonate polymer (A); a polycarbonate-polysiloxane copolymer (B); a phosphorous-containing flame retardant (C); and a reinforcing agent (D). The resulting compositions have an improved combination of properties, particularly Vicat softening temperature and high flame retardance in thin walls.

Abstract: A thermoplastic elastomer (TPE) is disclosed which is flame retardant and essentially halogen-free. The TPE is a copolyester (COPE). Two essentially halogen-free flame retardants (HFFRs) are used: organo-phosphinates and melamine polyphosphate. The compound is useful for wire and cable insulation.

Abstract: The invention relates to ductile two-component moulding parts which are resistant to stress cracking and warping under the influence of chemicals, i.e. dimensionally stable two-component moulding parts.

Abstract: Provided is a thermoplastic polycarbonate resin composition. The resin composition contains (A) 83 to 93% by weight of a polycarbonate resin, (B) 6 to 17% by weight of aromatic phosphate, and (C) 0.08 to 0.3% by weight of fluoroolefin. The resin composition exhibits excellent infrared transmissivity and flame retardancy.

Abstract: Improved flame retardant polytrimethylene terephthalate compositions are provided by including a bis(diphenyl phosphate) flame retardant additive.

Abstract: The present invention relates to a flame retardant rubber-modified styrene resin composition having excellent flame resistance for dripping without containing halogens and phenylene ether, which comprises A) 100 weight part of a rubber-modified polystyrene; B) 1˜10 weight part of a phosphoric ester compound; and C) 0.1˜10 weight part of an aliphatic amide compound. The flame retardant rubber-modified styrene resin composition of the present invention has flame resistance at the level of UL-94 V-2 and excellent impact resistance, heat resistance and fluidity.

Abstract: Improved flame retardant polytrimethylene terephthalate compositions are provided by including a bis(diphenyl phosphate) flame retardant additive.

Abstract: A thermoplastic molding composition characterized by its flame retardance and impact strength is disclosed. The composition contains (A) linear aromatic (co)polycarbonate, (B) a graft (co)polymer having core-shell morphology, the shell containing polymerized alkyl(meth)acrylate and the core containing interpenetrated and inseparable polyorganosiloxane and poly(meth)alkyl acrylate components, (C) a phosphorous-containing flame retardant compound, (D) fluorinated polyolefin and (E) a boron compound, and optionally SAN. The composition is further characterized in that it contains no polyalkylene terephthalate.

Abstract: The present invention relates to scratch-resistant, impact-resistant polycarbonate (PC) compositions and moulding compositions which have good mechanical properties as well as high resistance to chemicals, to a process for their preparation, and to their use in the production of moulded articles, in particular of casings for flat screen devices.

Abstract: The present invention relates to flameproofed, impact-modified, scratch-resistant polycarbonate (PC) compositions and moulding compositions with surface-modified, calcined kaolin as filler, which have good mechanical properties, good flowability and high chemical resistance. Furthermore, the present application relates to the use of the compositions for the production of mouldings.

Abstract: The present invention relates to scratch-resistant, impact-resistant polycarbonate (PC) compositions and moulding compositions which have good mechanical properties and a high resistance to chemicals coupled with good flameproofing properties, and show improved flow properties during processing. The present invention furthermore relates to a process for the preparation of the compositions and their use for the production of shaped articles, in particular housings of flat screen apparatuses.

Abstract: An organic-inorganic composite particle containing an inorganic particle having a plurality of polymer particles attached to the inorganic particle and a polymer layer encapsulating the attached polymer particles. A process is provided for the organic-inorganic composite particle. The organic-inorganic composite particle is useful in the preparation of dried coatings that have improved hiding, whiteness, or gloss.

Abstract: The present invention is an ignition resistant carbonate polymer composition, a method to make said composition and fabricated articles made therefrom. The ignition resistant carbonate polymer composition comprises: (i) an aromatic polycarbonate or an aromatic polyester carbonate, (ii) a graft polymer, (iii) optionally one or more thermoplastic vinyl (co)polymer, (iv) optionally one or more thermoplastic polyester polymer, (v) an aromatic phosphate compound, and (vi) a mixture of a fibril forming polytetrafluoroethylene polymer and a fluorothermoplast.

Abstract: A polycarbonate resin composition is provided. The composition comprises (A) 50 to 90% by weight of a polycarbonate resin, (B) 5 to 30% by weight of a polymethyl methacrylate resin, (C) 5 to 20% by weight of a phosphate compound, (D) 0.01 to 2% by weight of a metal sulfonate as an organic salt, and (E) 0.05 to 2% by weight of a fluorinated olefin. The composition is highly flame retardant and scratch resistant.

Abstract: The disclosure relates to impact-modified polycarbonate compositions and moulding compositions comprising A) aromatic polycarbonate or aromatic polyester carbonate or mixtures of these, B) a mixture containing Ba) at least one graft polymer prepared in emulsion polymerization and Bb) at least one carboxylate salt, wherein this mixture, suspended as a 10 wt. % strength suspension in distilled water, has a pH of >7, C) at least one acidic phosphorus compound with at least one P—OH functionality, which are distinguished compared with the prior art by an improved combination of stability to hydrolysis and heat stability, and which are suitable for production of injection-moulded components which have a good toughness at low temperatures and—even with critical processing conditions (high processing temperatures)—still have a good resistance to stress cracking under the influence of chemicals.

Abstract: A method is disclosed concerning discovering how the use of an additive in a polyolefin compound affects the weatherability of that compound. Applying that technique, a weatherable polyolefin nanocomposite is disclosed, which contains UV stabilizers that filter wavelengths in a range influenced by presence of organoclay in the nanocomposite.

Abstract: Fluoroalkyl phosphates containing a tertiary carbon and a nonfluorinated chain are useful as surfactants and additives. The f can be used to alter a surface property of a medium and to provide resistance to blocking, open time extension, or oil repellency to a substrate.

Abstract: A resin composition for a shell mold which reduces smoke generation upon molding of a casting mold and maintains a crumbility and a casting mold strength of a phenolic resin, and resin coated sand by the use thereof are provided. The resin composition for the shell mold includes the phenolic resin and an aromatic condensed phosphate ester. The phenolic resin is used as a binder of the resin coated sand used for producing a main mold and a core for shell mold casting of cast iron, cast steel, aluminum, and the like. The aromatic condensed phosphate ester is very effective as a crumbling agent for improving the crumbility of the casting mold after casting.

Abstract: The present invention provides compositions that enable excellent hardness in coating applications, the compositions containing one or more copolymer having as copolymerized units one or more acrylic monomer with a phosphorus acid-functional group, a polymeric side chain containing multi-acid functional groups, a salt thereof, or a combination thereof, one or more polyurethane dispersion made from a high molecular weight polyol, and one or more coalescent having a normal boiling point of 190° C. or higher. The compositions may be ambient curable.

Abstract: The present invention relates to a flame-retardant, optically clear thermoplastic molding composition. The composition contains a A) about 60 pbw to about 97 pbw of a polycarbonate, B) about 1 pbw to about 20 pbw of bromine-substituted oligocarbonate, C) about 1 pbw to about 20 pbw of a phosphorus-containing compound and D) about 0.01 pbw to about 1 pbw of at least one alkali or alkaline-earth salt of perfluoroalkane sulfonic acid and optionally E) about 0.01 to about 1 pbw of a phosphite antioxidant/stabilizer. In accordance with UL-94 standard the flame-retardant, optically clear thermoplastic molding composition is rated 5VA at 3.00 mm and V-0 at 2.3 mm, more preferably V-0 at 1.5 mm according to UL-94.

Abstract: The present invention generally relates to a resin composition, a cured resin, a sheet-like cured resin, a laminated body, a prepreg, electronic parts, single and multilayer circuit boards comprising a cyanate ester polymer and condensed phosphate ester, for use in single and multilayer circuit boards that are especially useful in the high-frequency range of above 100 MHz.

Abstract: The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer consisting of a trunk and on average at least one polyamide graft, wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine-terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise a mixture: 50 to 70 wt. % of polyamide block copolymer, 25 to 35 wt. % of a flame-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, about 2 wt. % of zeolite, or hydrotalcitemolecular sieves.

Abstract: A simple and economical process for the preparation of polyphosphates of organic bases consists of reacting a mixture of phosphorus pentoxide and at least one organic nitrogen base with at least one compound which releases water accompanied by decomposition under the prevailing conditions in such a molar ratio that upon decomposition of the water-releasing compound at most essentially 2 mol. water are produced per mol. phosphorus pentoxide. Thus-prepared polyphosphates are particularly suitable as flame-protection agents for plastics.

Abstract: Novel polyester composition comprising a polyester, wherein said polyester comprises structural units derived from substituted or unsubstituted diacid or diester, a substituted or unsubstituted diol; a phosphorus containing compound and at least one selected from a stabilizer and an organic compound comprising at least one functional group is been disclosed. In addition methods for the preparation of the polyester composition and articles derived from said composition is disclosed.

Abstract: A flameproof thermoplastic resin composition comprises (A) 100 parts by weight of a thermoplastic resin; (B) about 1 to about 40 parts by weight of a sublimational filler; and (C) about 1 to about 30 parts by weight of a flame retardant. The thermoplastic resin composition can solve the problems of high specific gravity and deterioration of flame retardancy caused by adding a conventional filler.

Abstract: An oligomeric phosphate or mixture of oligomeric phosphates having the general formula (I) wherein R1, R2, R3 and R4 each independently is aryl or alkaryl and n has an average value of from about 1.0 to about 2.0 and resin compositions containing the same.

Abstract: A thermoplastic molding composition that features improved thermal stability and a relatively low maximum rate of decomposition in the event of fire is disclosed. The composition contains an aromatic polycarbonate and/or polyester carbonate, and a modified layered compound, the modification with organic polymer by means of a solvent-free melt process. Optional additional components include an impact modifier, a thermoplastic (co)copolymer, and a phosphorus compound.

Abstract: The present disclosure relates to an impact-modified polycarbonate composition which comprise a first graft polymer containing silicone/acrylate composite rubber as the graft base, wherein the content of silicone rubber is 65-95 wt.% (based on the graft base), a second graft polymer containing a diene rubber, and phosphorus-containing flameproofing agent, the use of the polycarbonate compositions for the production of shaped articles and the shaped articles themselves. The compositions and moulding compositions according to the disclosure have an optimum combination of good flameproofing at thin wall thicknesses, good resistance to chemicals and hydrolysis and low melt viscosity.

Abstract: Disclosed herein is a thermoplastic composition comprising: a polycarbonate; an impact modifier; a polycarbonate-polysiloxane copolymer; a poly(arylene ether)-polysiloxane copolymer; and an organophosphate in an amount of 2 to 20 weight percent based on the combined weight of polycarbonate, impact modifier, polycarbonate-polysiloxane copolymer, and poly(arylene ether)-polysiloxane copolymer, wherein the composition has a notched Izod impact strength of greater than or equal to 4 kilojoules per square meter (kJ/m2) as determined according to ISO 180/A, a melt viscosity rate of less than or equal to 130 Pascal seconds (Pa·s) as determined according to ISO11443 at 1500 s?1 and 280° C., and a UL94 rating of V1 or better at 0.8 millimeter thickness.

Abstract: A thermally expandable vinyl chloride resin composition is provided. It includes (A) 100 parts by mass of a vinyl chloride resin, (B) 5 to 200 parts by mass of an inorganic filler, (C) 10 to 300 parts by mass of a thermally expandable graphite, (D) 0.1 to 10 parts by mass of a fluororesin, and (E) 10 to 300 parts by mass of a phosphorus compound. The composition exhibits favorable thermal expansion properties and favorable shape retention following thermal expansion upon exposure to high temperatures.

Abstract: A thermoplastic molding composition that features good mechanical properties as well as processability is disclosed. The composition that contains aromatic polycarbonate and/or aromatic polyester carbonate, rubber-modified graft polymer and a plurality of hollow ceramic beads is suitable for making molded articles characterized by good ESC behavior and flammability rating.