Phosphorus Bonded Directly To Four Chalcogen Atoms, E.g., Phosphate, Etc. Patents (Class 524/127)
  • Patent number: 7132466
    Abstract: The invention relates to a compound of the general formula: Z1-O-[m(R1PO3),n(R2HPO3]Z2, represent a copolyphosphate, with m (R1PO3) units and n (R2HPO3) units; R3 represents an ammonium building block; R2 represents a 1,3,5-triazine building block; Z1 and Z2 represent ammonium or 1,3,5-triazine building blocks, to be chosen independently of each other; m and n represent whole numbers greater than or equal to 1; and m+n numbers greater than 3. The invention further relates to a method for the preparation of the above compound and to flame-retardant polymer compositions in which compounds with the above formula are applied as flame retardant, the use of the halogen-free compound in a coating composition and a substrate containing a coating formed from the coating composition that has been cured.
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: November 7, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Renier Henricus Maria Kierkels, Nicolaas Johanna Jozef Aelmans, Patricia Hubertina Cornelis Grolleman, Adrianus Wilhelmus Maria Braam
  • Patent number: 7122251
    Abstract: The resin composition for a platable substrate of the present invention comprises 100 parts by weight of a resin composition (C) comprising 10 to 60% by weight of a graft copolymer (A) prepared by graft polymerization of a rubbery polymer (A1) and a monomer component (A2) containing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) and 40 to 90% by weight of the other polymer (B) (provided that the total amount of the components (A) and (B) is 100% by weight), and 5 to 40 parts by weight of a phosphate ester flame retardant (D) having a molecular weight of more than 326 or 2 to 40 parts by weight of a red phosphorus flame retardant (D?). The resin composition for a platable substrate of the present invention is excellent in production stability such as moldability, dimensional stability, mechanical strength and plating properties, and is also environmentally friendly.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: October 17, 2006
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kouichi Tezuka, Seizo Fujii
  • Patent number: 7115677
    Abstract: A flame-retardant resin composition comprises 10 to 300 parts by weight of a flame retardant (B) and 1 to 200 parts by weight of an inorganic filler (C) (a glass fiber and/or a glass flake), relative to 100 parts by weight of a base resin (A). The flame retardant (B) comprises a polyphenylene oxide-series resin and/or a polyphenylene sulfide-series resin (B1), a phosphoric ester (B2), and a nitrogen-containing cyclic compound (B3) (for example, a polyphosphate of an amino group-containing triazine compound). The inorganic filler (C) has been treated with a surface-treatment agent or sizing agent containing a novolak epoxy resin. Such a resin composition is useful for obtaining a shaped article which has been inhibited from dripping and to which flame retardancy is highly imparted.
    Type: Grant
    Filed: November 28, 2002
    Date of Patent: October 3, 2006
    Assignee: Polyplastics Co., Ltd.
    Inventors: Hatsuhiko Harashina, Shinya Yamada
  • Patent number: 7094819
    Abstract: A flame retardant polytrimethylene terephthalate resin composition, comprising: 30 to 99 parts by weight of (A) a polytrimethylene terephthalate resin, and 1 to 70 parts by weight of at least one flame retardant selected from the group consisting of (B-1) phosphorus-containing flame retardant and (B-2) nitrogen-containing flame retardant, is disclosed. The composition has superior mechanical characteristics, chemical resistance, electrical characteristics, weatherability, heat aging resistance and hydrolysis resistance, and has superior moldability, good appearance with less warpage deformation when molded, and furthermore has superior flame retardance and does not generate highly corrosive hydrogen halide gas upon combustion.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: August 22, 2006
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Junko Kakegawa, Tomofumi Maekawa, Hideki Nakamura
  • Patent number: 7091267
    Abstract: Disclosed are resinous compositions with excellent balance of impact, heat, flow and environmental stress crack resistance, comprising (i) at least one aromatic polycarbonate, (ii) at least one low molecular weight hydrocarbon resin derived from petroleum C5–C9 feedstock and (iii) optionally a second thermoplastic resin which is not polycarbonate resin, (iv) optionally a rubber modified graft copolymer, and (v) optionally a polymeric or non-polymeric organic phosphorus species. Also disclosed is a method for the manufacture of the compositions and for the manufacture of articles thereof.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: August 15, 2006
    Assignee: General Electric Company
    Inventors: Robert W. Venderbosch, Sjef G. Berndsen, William A. Kernick, III
  • Patent number: 7084196
    Abstract: Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2?-alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: August 1, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Malisa V. Troutman, Ramanathan Ravichandran, Rangarajan Srinivsan, Roswell Easton King, Douglas Wayn Horsey
  • Patent number: 7067076
    Abstract: The invention is directed to a phosphonate composition having flame retardant properties. The phosphonate composition of the invention has the general formula: wherein R1 and R2 are independently C1–C4 alkyl, R3 is H or C1–C4 alkyl, and R4 is linear or branched C9–C22 alkyl, C9–C22 cycloalkyl, C9–C22 aryl or C9–C22 aralkyl and n=0 or 1. The invention is also directed to a method of producing the phosphonate composition having flame retardant properties.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: June 27, 2006
    Assignee: Rhodia Inc.
    Inventors: Shiming Wo, Dwight Shamblee
  • Patent number: 7067567
    Abstract: A thermoplastic molding composition having improved flammability rating and mechanical properties is disclosed. The composition contains aromatic polycarbonate having a weight-average molecular weight Mw?25,000 g/mol., polyalkylene terephthalate, graft (co)polymer characterized in that its grafted phase includes structural units derived from acrylate monomers, an oligomeric organic phosphoric acid ester, and an optional fluorinated polyolefin. In a preferred embodiment the graft (co)polymer is characterized in its core-shell morphology.
    Type: Grant
    Filed: July 25, 2003
    Date of Patent: June 27, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel
  • Patent number: 7056973
    Abstract: A high flow polyphenylene ether resin composition comprises a blend of at least two polyphenylene ether resins, a first resin having an intrinsic viscosity of at least 0.3 dl/g, and a second resin having an intrinsic viscosity of less than 0.17 dl/g and preferably having a particle size of at least about 100 ?m. Fiber reinforced and flame retarded compositions exhibit high HDT values.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: June 6, 2006
    Assignee: General Electric
    Inventor: Nirajkumar Patel
  • Patent number: 7045555
    Abstract: A regenerated resin composition comprising (I) a molded article pulverized material (Component A) that satisfies conditions (1) that the molded article pulverized material is a pulverized material of a molded article having an aromatic polycarbonate resin content of 30 to 98% by weight, (2) that the pulverized material has a viscosity average molecular weight of 17,000 to 30,000, and (3) that the pulverized material has a wet heat retention ratio of at least 60%, and (II) an aromatic polycarbonate resin (Component B). According to the present invention, there is provided a regenerated resin composition that comprises a pulverized material from a molded article made of an aromatic polycarbonate resin and that is excellent in the property of retaining physical properties for a long period of time and excellent in mechanical strength.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: May 16, 2006
    Assignee: Teijin Chemicals Ltd.
    Inventor: Makoto Takagi
  • Patent number: 7030180
    Abstract: A polycarbonate composition containing inorganic material with an anisotropic particle geometry and with an iron content of less than about 100 ppm is disclosed. The composition is suitable for producing molded articles exhibiting improved mechanical properties both at ambient and low temperatures.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: April 18, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Holger Warth, Dieter Wittmann
  • Patent number: 7019057
    Abstract: A flame retardant, thermoplastic molding composition is disclosed. The composition contains A) at least one of aromatic polycarbonate and polyester carbonate, B) polyalkyl (alkyl)acrylate, C) a graft polymer the molecular structure of which is substantially free of units derived from styrene, butadiene and acrylonitrile, D) at least one organic phosphoric acid ester, E) an optional anti-drip agent, and F) optionally at least one polymer additive. The composition is characterized in its good property profile especially weld line strength, resistance to chemicals, elongation at break, thermal stability and melt flowability.
    Type: Grant
    Filed: February 2, 2004
    Date of Patent: March 28, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel
  • Patent number: 7019056
    Abstract: An oligophosphate of general formula is disclosed. The oligophosphate is suitable as a flame retardant for thermoplastic molding compositions that exhibit a good flame-retardant effect, improved dimensional stability under the effect of heat, a good level of toughness and excellent flowability.
    Type: Grant
    Filed: January 4, 2002
    Date of Patent: March 28, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Käthe Baumann, Thomas Eckel, Michael Zobel, Jörn Stölting, Dieter Wittmann
  • Patent number: 7001944
    Abstract: A mineral-filled, impact-resistant thermoplastic molding composition is disclosed. The composition contains at least one resin selected from the group consisting of polycarbonate and polyester carbonate B) impact resistance modifier, and C) wollastonite having carbon content greater than 0.1% relative to the weight of the wollastonite as determined by elemental analysis. Exhibiting high modulus of elasticity and a good toughness, in particular also at low temperatures, the composition is suitable for car body external applications.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: February 21, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Marc Vathauer, Andreas Seidel, Detlev Joachimi, Dieter Wittmann
  • Patent number: 6956073
    Abstract: A flame-retardant resin composition comprising (A)(1) a resin component containing an aromatic polycarbonate resin and a styrene-containing resin or (2) a resin component containing a polyphenylene ether resin and a polystyrene, and (B) a flame retardant that is a phosphoric ester of the following formula (I), wherein each of R1, R2, R3 and R4 is independently an aryl group having 6 to 12 carbon atoms, each of R5 and R6 is independently methyl or a hydrogen atom, each of R7 and R8 is methyl, m1 and m2 are 0 or integers of 1 or 2, each of a, b, c and d is independently 0 or 1, and n is 0 or an integer of 1 or 5.
    Type: Grant
    Filed: November 21, 2002
    Date of Patent: October 18, 2005
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Makoto Takagi, Tetsuya Aibara
  • Patent number: 6956072
    Abstract: To provide a resin composition, in which a liquid crystal polymer is made into fiber in a molded article to exhibit an extremely high reinforcing effect which has not been available yet, and from which a molded article having an excellent mechanical strength can be manufactured in a stable manner. That is, a thermoplastic resin composition, wherein 100 parts by weight in total consisting of 99-50 parts by weight of a thermoplastic polyester resin (A) not forming an anisotropic molten phase and 1-50 parts by weight of a liquid crystal polymer (B) capable of forming an anisotropic molten phase is blended with 0.001-2.
    Type: Grant
    Filed: July 12, 2000
    Date of Patent: October 18, 2005
    Assignee: Polyplastics Co., Ltd.
    Inventors: Keiichi Kanaka, Toshio Shiwaku, Mineo Ohtake
  • Patent number: 6949596
    Abstract: A flame resistant anti-electrostatic polycarbonate composition that is chlorine- and bromine-free is disclosed. Good melt flowability and low tendency to juicing, coupled with its good mechanical and thermal properties make the composition especially suitable for injection molding. The composition finds use in the production of a variety of molded articles.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: September 27, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Michael Zobel, Dieter Wittmann, Manfred Dietrich
  • Patent number: 6943212
    Abstract: The present invention provides a deproteinized natural rubber latex wherein coagulation of a rubber component does not occur when the concentration of calcium ions (Ca2+) is 0.01 mol/L or less and coagulation of the rubber component occurs when the concentration of Ca2+ is 0.1 mol/L or more; a method of preparing the deproteinized natural rubber latex, which comprises adding a protease and two or more surfactants having different coagulation properties to calcium ions (Ca2+) to a natural rubber latex and maturing the natural rubber latex; a rubber product using the deproteinized natural rubber latex; and a proteolytic agent comprising a protease and two or more surfactants.
    Type: Grant
    Filed: February 26, 2002
    Date of Patent: September 13, 2005
    Assignees: Sumitomo Rubber Industries, Ltd., Kao Corporation
    Inventors: Naoya Ichikawa, Yoshiaki Miyamoto
  • Patent number: 6939905
    Abstract: A molding composition characterized by its improved processability and flame resistance, suitable especially for extrusion is disclosed. The composition that contains polycarbonate, an impact modifier and a halogen-free phosphous-containing flameproofing agent features flame resistance of V-0 in the UL 94 V fire behavior test at wall thickness ?1.5 mm and a melt viscosity, measured at 260° C.
    Type: Grant
    Filed: February 21, 2001
    Date of Patent: September 6, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Bernd Keller, Dieter Wittmann
  • Patent number: 6936647
    Abstract: The present invention relates to novel crosslinked bead polymers having an average particle size of 1 to 1000 ?m containing specific, halogen-free phosphorus compounds including triphenyl phosphate as the halogen-free phosphorus compound, and to a process for the production of these bead polymers and to the use thereof as flame retardants in thermoplastics.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: August 30, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Podszun, Andreas Seidel, Thomas Eckel, Dieter Wittmann, Kamelia Karlou-Eyrisch
  • Patent number: 6921785
    Abstract: Disclosed are flame retardant resinous compositions comprising (i) at least one aromatic polycarbonate, (ii) at least one a rubber modified graft copolymer, (iii) at least one silyl borate ester, (iv) at least one organophosphorus compound, and (v) at least one fluoropolymer additive. The compositions exhibit improved surface properties in molded parts.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: July 26, 2005
    Assignee: General Electric Company
    Inventors: John Robert Campbell, Thomas Miebach
  • Patent number: 6914090
    Abstract: An impact resistant, flame-resistant thermoplastic molding composition suitable for making thin-wall housing parts is disclosed. The composition contains A) 50 to 90 parts by weight of at least one a member selected from the group consisting of polycarbonate and polyester carbonate, B) 5 to 20 parts by weight of rubber-modified vinyl (co)polymer C) 2 to 15 parts by weight of at least one low-volatility, halogen-free flameproofing agent, D) 0.1 to 6 parts by weight of a silicate mineral, and optional E) fluorinated polyolefin, and F) conventional polymer additive wherein the total sum of the parts by weight of the components A) to F) is 100, and wherein the rubber content of the composition referred to the weight of the composition is 2 to 6 wt.-%.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: July 5, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Dieter Wittmann
  • Patent number: 6906124
    Abstract: A translucent thermoplastic molding composition containing polycarbonate, phosphorous compound and a fluorinated polyolefin is disclosed. Characterized in its excellent flame proofing, optical properties and resistance to chemicals the composition is suitable for making articles that in the course of use come in contact with solvents lubricants and cleaning compositions.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: June 14, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Torsten Derr, Thomas Eckel, Michael Zobel, Dieter Wittmann, Andreas Seidel
  • Patent number: 6906123
    Abstract: A flameproof thermoplastic resin composition substantially free of phenolic resin, red phosphorous and silicone resin comprises (A) about 40-95 parts by weight of a rubber modified styrene-containing graft copolymer resin, (B) about 5-60 parts by weight of polyphenylene ether resin; (C) about 5-30 parts by weight of aromatic phosphoric acid ester per 100 part by weight of (A) and (B) wherein the styrene-containing copolymer chains in rubber modified styrene-containing resin (A) comprise (i) about 5-20% by weight having an acrylonitrile fractionation content of 0-9% by weight (ii) about 10-40% by weight having an acrylonitrile fractionation content of 9-20% by weight and (iii) about 40-80% by weight having an acrylonitrile fractionation content of not less than 20% by weight acrylonitrile and the sum of (i), (ii), and (iii) is 100% by weight of the total weight of styrene-containing copolymer chains in rubber modified styrene-containing resin (A).
    Type: Grant
    Filed: January 17, 2002
    Date of Patent: June 14, 2005
    Assignee: Cheil Industries Inc.
    Inventors: Sang-Hyun Hong, Yong-Hae Kweon, Bok-Nam Jang, Young-Kil Chang, Gyu-Cheol Lee
  • Patent number: 6893680
    Abstract: The invention relates to a coating composition demonstrating improved adhesion and method for improving adhesion of a coating composition to metal. The coating and method of the invention provide improved adhesion of a coating when coating is applied directly over metal substrates, especially untreated metal substrates such as galvanized steel, unsanded aluminum and unsanded cold-rolled steel.
    Type: Grant
    Filed: May 2, 2003
    Date of Patent: May 17, 2005
    Assignee: BASF Corporation
    Inventor: David L. Newton
  • Patent number: 6890979
    Abstract: A thermoplastic molding composition having improved mechanical properties is disclosed. The composition contains (A) aromatic polycarbonate and/or polyester carbonate (B) at least one graft rubber, obtained by emulsion polymerization of styrene and acrylonitrile in the presence of at least two rubber latices of type (B1) and (B2) where (B1) has a particle diameter d50 of ?350 nm, a particle size distribution range of 30 nm to 100 nm, and a gel content of 70 wt. %, and (B2) has a particle diameter of ?350 nm, a particle size distribution range of 50 nm to 500 nm, and a gel content of ?70 wt. %, and the difference in the average particle diameter of B1 and B2 is ?50 nm, (C) an optional copolymer of styrene and or acrylonitrile and for methyl methacrylate and/or N-substituted maleinimide, and optionally (D) flame retardant as well as optionally conventional additives.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: May 10, 2005
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Thomas Eckel, Holger Warth, Dieter Wittmann
  • Patent number: 6849676
    Abstract: Inorganic salts are generated in the production process of metal salts, such as sulfonates, sulfates and phosphates. When such metal salts containing inorganic salts are added as an antistatic agent to a polymer for producing polyurethane fiber, the inorganic salts cause fiber breakage or pack choking in fiber extrusion process. In addition, such antistatic agents are highly hygroscopic and contain trace of water. When such an antistatic agent is added to the material for polymerizing polyurethane, the alcohol and water in the agent react with isocyanate to result in lowered degree of polymerization and generation of oligomer. Such polyurethane polymer is spun into fiber of low elongation and tenacity. The material for polyurethane elastic fibers of the present invention comprises a mixture of 5 to 95 weight percent of at least one of the above-mentioned antistatic agents and 95 to 5 weight percent of a isocyanate-free starting material for elastic fibers, and eliminates the above troubles.
    Type: Grant
    Filed: January 8, 1999
    Date of Patent: February 1, 2005
    Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.
    Inventors: Michihiro Shibano, Yoji Mizuhiro, Masayoshi Yamanaka
  • Patent number: 6846853
    Abstract: A calcium phosphate bone graft material comprising an amorphous calcium phosphate glassy phase of from about 30 to about 100 volume % is obtained by plasma spraying calcium phosphate-containing powder onto a target to produce a deposited layer and removing the deposited layer from the target to provide the calcium phosphate bone graft material.
    Type: Grant
    Filed: July 16, 2002
    Date of Patent: January 25, 2005
    Assignee: Osteotech, Inc.
    Inventor: Lawrence A. Shimp
  • Patent number: 6846866
    Abstract: The invention provides polyurethane containing a) a first additive comprising at least one mono-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; b) a second additive selected from the group consisting of i) condensation polymers of p-cresol and divinyl benzene and ii) compounds comprising at least one unsymmetrically di-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; and c) an inorganic chlorine-resist additive. The polyurethane of the invention exhibits improved resistance to degradation by chlorine and by atmospheric fumes.
    Type: Grant
    Filed: June 3, 2002
    Date of Patent: January 25, 2005
    Assignee: Invista North America S.a.r.L.
    Inventors: Nathan E. Houser, Gordon W. Selling
  • Patent number: 6838497
    Abstract: The present invention relates to a flame retardant thermoplastic resin composition that comprises (A) about 40 to 95 parts by weight of a rubber modified styrene-containing resin, (B) about 5 to 60 parts by weight of polyphenylene ether resin, (C) about 2 to 30 parts by weight of a styrene-containing copolymer resin having about 5 to 18 % by weight of acrylonitrile in the copolymer per 100 parts by weight of the sum of (A) and (B), (D) about 0.5 to 20 parts by weight of an oxaphospholane compound per 100 parts by weight of the sum of (A) and (B), and (E) about 0 to 30 parts by weight of a phosphoric acid ester compound per 100 parts by weight of the sum of (A) and (B).
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: January 4, 2005
    Assignee: Cheil Industries Inc.
    Inventors: Sang-Hyun Hong, Bok-Nam Jang, Young-Kil Chang, Sung-Hee Ahn, Jae-Ho Yang
  • Patent number: 6838503
    Abstract: A resin composition useful for wire and cable covering material is formed by compounding a phosphate ester retardant, boron phosphate, and zinc borate hydrate with a polyphenylene ether group resin or a combination of a polyphenylene ether group resin and an aromatic vinyl group resin, in a specific ratio.
    Type: Grant
    Filed: June 28, 2002
    Date of Patent: January 4, 2005
    Assignee: General Electric Compa
    Inventors: Ming Yin, Takuro Kitamura, Atsuo Oshiro, Kenichi Ishiwa, Kazunari Kosaka, Hiroshi Kubo
  • Patent number: 6833397
    Abstract: Disclosed is a method for producing a flame retardant polycarbonate resin composition by using a screw extruder, which comprises extruding a resin component (mainly comprising a polycarbonate) and an organic phosphorus compound having an acid value of not more than 0.1 mg KOH/g while kneading, wherein the temperature of the resin component in the extruder is not higher than 300° C., and the residence time of the resin component in the extruder is not more than 40 seconds.
    Type: Grant
    Filed: September 7, 2001
    Date of Patent: December 21, 2004
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Akira Miyamoto, Kazuhiro Shibuya, Hiroshi Hachiya, Chung Neng Wu, Wen-Yi Su
  • Patent number: 6828366
    Abstract: A thermoplastic molding composition characterized by its excellent flame retardance, chemical resistance and thermal stability is disclosed. The compostion that contains polycarbonate, an impact modifier and a flame retardant corresponding to in which R1, R2, R3 and R4 independently of one another denote C1-C8-alkyl, C6-C10-aryl or C7-C12-aralkyl, n is 0 or 1, q is 0, 1, 2, 3, or 4, N is 0.1 and 30, R5 and R6 independently denote C1-C4-alkyl, and Y denotes C1-C7-alkylidene, C1-C7-alkylene, C5-C12-cycloalkylene, C5-C12-cycloalkylidene, —O—, —S—, —SO—, SO2 or —CO—, is further characterized in that is contains ≦0.1% fluorine, in relation to its weight.
    Type: Grant
    Filed: September 3, 2002
    Date of Patent: December 7, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Andreas Seidel, Thomas Eckel, Bernd Keller, Dieter Wittmann
  • Patent number: 6825280
    Abstract: Disclosed are a propylene polymer composition possessing excellent balance among rigidity and low warpage, resistance to deterioration caused by thermal oxidation during processing, weathering resistance, antistatic properties, and low bleeding properties, and a propylene resin composition which can easily produce molded products having excellent balance between rigidity and impact resistance (particularly low-temperature impact resistance) or heat resistance. The propylene polymer composition and the propylene resin composition comprise a propylene block copolymer consisting essentially of the following blocks (a) and (b) and having a melt flow rate of 0.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: November 30, 2004
    Assignee: Japan Polychem Corporation
    Inventors: Yu Hayakawa, Tsuyoshi Ogasawara, Yuuji Fujita, Masao Sakaizawa, Kimiho Kosegaki, Toshihiko Sugano, Takao Tayano, Toru Suzuki, Yasuo Maruyama, Osamu Shibata, Takao Usami
  • Patent number: 6825251
    Abstract: A unique treatment for pigments is provided. This treatment, which uses certain organo-acid phosphate molecules, imparts improved physical and chemical qualities including lacing resistance, improved dispersion and decreased chemical reactivity when these treated pigments are incorporated into polymeric matrices.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: November 30, 2004
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert J. Kostelnik
  • Patent number: 6822038
    Abstract: An aqueous coating material comprising A) at least one polyester that is water-soluble or water-dispersible, B) at least one polyurethane acrylate that is water-soluble or water-dispersible, C) at least one amino resin that is itself water-soluble or water-dispersible or is water-soluble or water-dispersible in the presence of the polyester and the polyurethane acrylate, D) at least one of a color pigment, an effect pigment, a color and effect pigment, and a filler, and E) optionally at least one polyisocyanate. Also, processes for preparing and using the aqueous coating material.
    Type: Grant
    Filed: February 26, 2002
    Date of Patent: November 23, 2004
    Assignee: BASF Coatings AC
    Inventors: Lutz-Werner Gross, Ludwig Moorkamp, Heinz-Ulrich Grumpe, Ulrich Poth
  • Patent number: 6822025
    Abstract: A flame retardant thermoplastic resin composition comprises a thermoplastic resin comprising a polyphenylene ether resin, a high impact polystyrene resin or an acrylontrile-butadiene-styrene resin; an organo phosphate compound in an amount less than or equal to about 20 parts by weight for every 100 parts by weight of the thermoplastic resin; and a polyhydric alcohol compound in an amount of about 0.5 to about 5.0 parts for every 100 parts by weight of the thermoplastic resin. A method for the manufacture of the thermoplastic resin composition is also disclosed. The thermoplastic resin composition exhibits high flow characteristics and improved impact strength while providing effective flame retardance.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: November 23, 2004
    Assignee: General Electric Company
    Inventors: Chandra S. Bajgur, Sumi dummyname, Gaurav Mediratta, Radhakrishna Arakali
  • Patent number: 6822026
    Abstract: The present invention relates to a flame-retardant polypropylene resin composition comprising (A) polypropylene resin 20-60% by weight, (B) polyphenylene ether-based resin 1-50% by weight, (C) hydrogenated block copolymer of a vinylaromatic compound and conjugated diene, which mainly is based on vinylaromatic compound, 0.1-15% by weight, (D) aromatic phosphoric ester in phenol strucure 1-20% by weight, (E) polyammonium phosphate 1-20% by weight, and (F) pentaerythritol-based flame retardant auxiliary agent 0.1-13% by weight. The weight ratio of the aromatic phosphoric ester in phenol structure to the polyammonium phosphate is preferably 0.2-5.0. The composition has advanced flame-retardant and heat-resistant property, and processing property.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: November 23, 2004
    Assignee: Sansung General Chemicals Co.
    Inventors: In Sik Jung, Jong Soo Hong, Man Seang Her, Won Beum Jung
  • Publication number: 20040229983
    Abstract: A composition substantially free of elastomers (plasticizers), which is a crystalline polypropylene homopolymer, modified by mixing with an ethylene octene copolymer plastomer and containing an exfoliated inorganic nanocomposite and a coupling agent which is a polyolefin polymer grafted to maleic anhydride is described. The composition is adapted to be used with pigments to make finished molded products which have an appearance of paint covered by a clear coat and which are scratch resistant.
    Type: Application
    Filed: May 14, 2003
    Publication date: November 18, 2004
    Inventor: Kris W. Winowiecki
  • Patent number: 6815489
    Abstract: The invention relates to a method for preparing a composition for coating, wherein a layered, inorganic filler is subjected to an ion exchange with a modifier, which modifier comprises at least two ionic groups, which groups are separated from each other by at least four atoms, and wherein the modified filer, together with a polymer, is dispersed in a diluent.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: November 9, 2004
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Hartmut Rudolf Fischer, Lawrence Fabian Batenburg, Harmen Anne Meinema, Marinus Pieter Hogerheide, Cornelis Hermanus Arnoldus Rentrop
  • Patent number: 6815476
    Abstract: A flame retardant moldable thermoplastic resin composition consisting of a thermoplastic resin and a flame retardant consisting of a combination of a low molecular weight phosphate having a molecular weight of about 500 to about 2000 and a high molecular weight phosphate having a molecular weight of about 2300 to about 11,000 and to articles molded therewith. The composition has a high heat deflection temperature, good impact resistance, excellent flame retardancy and good flow for easier processing.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: November 9, 2004
    Assignee: General Electric Company
    Inventors: Qamar Bhatia, Robert Howe
  • Patent number: 6815477
    Abstract: The purpose of the present invention is to provide a flame-retardant polyamide resin composition which neither causes environment pollution nor liberates toxic combustion gases, exhibits good flame-retardancy even if an inorganic filler is compounded with the polyamide-based resin, and hardly stains the mold during molding. Provision of a flame-retardant polyamide resin composition comprising (A) 20 to 89 wt.-% of a polyamide-base resin consisting of a polyamide resin obtained from xylylene diamine and an &agr;,&ohgr;-straight-chain aliphatic dibasic acid, (B) 1 to 30 wt.-% of a salt of polyphosphoric acid and melamine, and (C) 10 to 50 wt.-% of inorganic filler; and of electrical parts employing the composition.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: November 9, 2004
    Assignee: EC-Showa Denko K.K.
    Inventors: Toshihiro Arai, Tadashi Takeda, Katsuo Kobori, Osamu Hamazoe
  • Publication number: 20040209983
    Abstract: A waterborne, soft feeling coating composition and a substrate coated with the composition. The coating composition comprises an aqueous solvent, a resin, and an alcohol alkoxylate surfactant. The invention is also directed to a process of making the waterborne coating composition of the invention, and a process of coating a substrate with the waterborne coating composition.
    Type: Application
    Filed: May 7, 2004
    Publication date: October 21, 2004
    Inventors: Murray A. Ruggiero, Harold W. Chubb, Diane J. Burt
  • Patent number: 6800678
    Abstract: Polyolefins, especially polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of a selected hindered amine substituted by an alkoxy, cycloalkoxy or hydroxyalkoxy moiety and a selected organic or inorganic brominated and/or phosphorus containing flame retardant, such as ammonium polyphosphate or decabromodiphenyl oxide wherein the amount of organic or inorganic flame retardant required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when the hindered amine is not present.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Douglas Wayne Horsey, Stephen Mark Andrews, Leonard Harris Davis, Darrell David Dyas, Jr., Robert Leo Gray, Anunay Gupta, Bruce Vincent Hein, Joseph Stephen Puglisi, Ramanathan Ravichandran, Paul Shields, Rangarajan Srinivasan
  • Publication number: 20040192815
    Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrenic-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.
    Type: Application
    Filed: December 29, 2003
    Publication date: September 30, 2004
    Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
  • Publication number: 20040186208
    Abstract: Flame resistant, laser weldable polyester resin compositions comprising melt-mixed blends of polyester, phosphorus containing flame retardant, phenolic polymer, and acrylic polymer and articles made therefrom. The compositions may optionally further comprise inorganic reinforcing agents.
    Type: Application
    Filed: December 4, 2003
    Publication date: September 23, 2004
    Inventors: Hiroyuki Sumi, Toshikazu Kobayashi
  • Patent number: 6794039
    Abstract: A flame retardant resin coating which comprises a flame retardant base resin and a transparent resin top layer. The base resin is selected from the group consisting of polyester, polyether, epoxy, polyurethane, and acrylic acrylates, melamine acrylates, and silicone (meth)acrylates and comprises color pigments and flame retardant additives. The base resin further comprises color pigments and at least one flame retardant additive ranging from about 2.5 to about 50% by weight, based on the weight of base resin. The flame retardant additive is preferably selected from the group consisting of melamine polyphosphates, melamine pyrophosphates, ammonium polyphosphates, and mixtures thereof. Furthermore, the transparent resin comprises at least one sterically hindered amine.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: September 21, 2004
    Assignee: Trespa International, B.V.
    Inventor: Robert Huusken
  • Publication number: 20040180998
    Abstract: The present invention relates to hydrophilic polymeric compositions for making a liquid impermeable moisture vapour permeable structure, for example by forming the composition into a layer or coating onto a suitable substrate for example a microporous film and to composite structures comprising the compositions. The hydrophilic polymeric compositions of the present invention do not solidify at room temperature, but remain viscous or “creamy”. This prevents layers made from the hydrophilic polymeric composition of the present invention from settling as a film so that delamination of a composite structure comprising the hydrophilic polymeric composition coated into a layer onto a suitable substrate is avoided. The hydrophilic polymeric compositions of he present invention can find a variety of applications wherein liquid imperviousness and moisture vapour permeability are desirable.
    Type: Application
    Filed: December 19, 2003
    Publication date: September 16, 2004
    Applicant: The Procter & Gamble Company
    Inventors: Denis Alfred Gonzales, Pietro Lunetto, Calum MacBeath, Enrico Spina
  • Patent number: 6790887
    Abstract: Disclosed is an aromatic polycarbonate resin composition comprising a resin component (A) selected from the group consisting of an aromatic polycarbonate and a resin mixture of an aromatic polycarbonate and at least one organic polymer resin other than an aromatic polycarbonate, wherein the resin mixture has an aromatic polycarbonate content of 50% by weight or more, and at least one aromatic group-containing silicone compound (B), wherein the at least one aromatic group-containing silicone compound (B) comprises a monomer, a polymer or a mixture thereof, which is represented by at least one formula selected from the group consisting of the following formulae (1) and (2): wherein the component (B) contains the aromatic group in an amount of 5 to 100 mole %, based on the total molar amount of R1, R2, R3 and R4, wherein each of R1 and R2 represents a hydrogen atom or a C1-C20 hydrocarbon group, and each of R3 and R4 represents a hydrogen atom, a C1-C20 hydrocarbon group or a metal-containing g
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: September 14, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventor: Hajime Nishihara
  • Patent number: 6787584
    Abstract: Curable compositions comprising degradable macromonomers having one or more terminal acrylate or methacrylate functionality, a curing composition, a filler composition comprising bioactive particles of bioactive glass, bioactive glass-ceramics, calcium phosphates, calcium apatites, or mixtures thereof and optionally one or more polymerizable acrylate or methacrylate comonomers. Degradable macromonomers are manufactured from cyclic monomers with compounds having acrylate or methacrylate functionality. Depending on their use, the degradable macromonomer compositions further comprise one or more organic or inorganic fillers, including a calcium-based compound and/or a radiopacity-imparting agent. The compositions are particularly suitable for root canal sealants, implants, bone cements, and pulp capping materials.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: September 7, 2004
    Assignee: Pentron Corporation
    Inventors: Weitao Jia, Shuhua Jin