Phosphorus Bonded Directly To Three Chalcogen Atoms Only, E.g., Phosphite, Etc. Patents (Class 524/128)
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Patent number: 6284822Abstract: Disclosed is a film or sheet of a polypropylene resin composition comprising the following components (A), (B) and (C): (A) 100 parts by weight of a polypropylene resin, (B) from 0.001 to 1 part by weight of a phenolic antioxidant such as 1,3,5-tris(4-t-butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate or the like, and (C) from 0.05 to 5 parts by weight of a hindered amine-based light stabilizer. Provided are filmy or sheet moldings of the polypropylene resin composition which color little even when stored indoors at relatively high temperatures; and also the polypropylene resin composition for the moldings.Type: GrantFiled: April 23, 1999Date of Patent: September 4, 2001Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Satoshi Tamura, Yutaka Azuma
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Publication number: 20010014708Abstract: A method of producing a thermotropic liquid crystalline copolyester having an extremely small amount of out-gases comprising the steps of: (1) charging in a reactor 5-100 mol % of aromatic hydroxycarboxylic acid, 0-47.5 mol % of aromatic dicarboxylic acid and 0-47.5 mol % of aromatic diol, so that the sum of mol % of each material is 100 mol % and the mol % of aromatic dicarboxylic acid and that of aromatic diol are substantially equal; (2) adding acetic anhydride of an amount which satisfies the formula, (B−C)/A≧1.04, “A” representing the total molar number of the hydroxy group in a reaction system, “B” representing the molar number of acetic anhydride to be added, and “C” representing the molar number of water present in the reaction system prior to addition of acetic anhydride; (3) acetylation; (4) melt polymerization; and (5) solid-phase polymerization.Type: ApplicationFiled: March 15, 2001Publication date: August 16, 2001Applicant: NIPPON PETROCHEMICAL CO., LTD.Inventors: Satoshi Murouchi, Yoshikuni Yamada, Toshitaka Kobayashi
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Patent number: 6268419Abstract: A method of producing a thermotropic liquid crystalline copolyester having an extremely small amount of out-gases comprising the steps of: (1) charging in a reactor 5-100 mol % of aromatic hydroxycarboxylic acid, 0-47.5 mol % of aromatic dicarboxylic acid and 0-47.5 mol % of aromatic diol, so that the sum of mol % of each material is 100 mol % and the mol % of aromatic dicarboxylic acid and that of aromatic diol are substantially equal; (2) adding acetic anhydride of an amount which satisfies the formula, (B−C)/A≧1.04, “A” representing the total molar number of the hydroxy group in a reaction system, “B” representing the molar number of acetic anhydride to be added, and “C” representing the molar number of water present in the reaction system prior to addition of acetic anhydride; (3) acetylation; (4) melt polymerization; and (5) solid-phase polymerization.Type: GrantFiled: March 29, 2000Date of Patent: July 31, 2001Assignee: Nippon Petrochemical Co., LTDInventors: Satoshi Murouchi, Yoshikuni Yamada, Toshitaka Kobayashi
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Patent number: 6251972Abstract: Single-material recycled thermoplastics from commercial and industrial waste can be stabilized against thermal oxidative degradation by adding a combination of a sterically hindered phenol with an organic phosphite or phosphonite and an inorganic compound from the series consisting of metal oxides, hydroxides and carbonates.Type: GrantFiled: March 21, 1995Date of Patent: June 26, 2001Assignee: Ciba Specialty Chemicals Corp.Inventors: Kurt Hoffmann, Heinz Herbst, Rudolf Pfaendner, Franciszek Sitek
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Patent number: 6225385Abstract: The present invention relates to a stabilizer mixture prepared by partially condensing PCl3 with 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide, where the phosphorus content is from 2 to 4% by weight and the content of 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide is from 0.5 to 50% by weight. The stabilizer mixture has very good solubility in organic solvents and in the polymer and has very good stabilizing action.Type: GrantFiled: March 19, 1999Date of Patent: May 1, 2001Assignee: Clariant GmbHInventors: Thomas Stährfeldt, Alexander Lichtblau, Gerhard Pfahler, Karl Gaa
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Patent number: 6218454Abstract: An acid-resistant, thermoplastic resin composition which is nonpoisonous and non-halogen and has an acid-resistance for a long period of time, the acid-resistant, thermoplastic resin composition containing a thermoplastic resin, 30 to 70% by weight of magnesium hydroxide which has a specific surface area of 20 m2/g or less and an average secondary particle diameter of 0.2 to 5.0 &mgr;m and is surface-treated with at least one surface-treating agent selected from a water-soluble silane-coupling agent, a phosphoric acid ester, a higher fatty acid or its alkali metal salt, and 1 to 20% by weight of a reaction type compatibilizing agent.Type: GrantFiled: October 15, 1998Date of Patent: April 17, 2001Assignee: Kyowa Chemical Industry Co., Ltd.Inventors: Tsutomu Nosu, Tomoko Tachifuji, Wataru Hiraishi
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Patent number: 6211501Abstract: Low-odor microwaveable mineral-filled polypropylene food contact articles are disclosed. The articles are prepared by low temperature processing and typically include odor-suppressing basic organic or inorganic compounds. Preferably, the articles are substantially free from C8 and C9 organic ketones associated with undesirable odors. Further improvements to the articles include crack-resistant embodiments with synergistic amounts of polyethylene and titanium dioxide.Type: GrantFiled: June 11, 1999Date of Patent: April 3, 2001Assignee: Fort James CorporationInventors: Donald C. McCarthy, Ronald L. Cochran, II, Mark B. Littlejohn, Cristian M. Neculescu, Robert Patterson, Anthony J. Swiontek
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Patent number: 6211500Abstract: Low-odor microwaveable polypropylene/mica food contact articles are disclosed. The articles are prepared by low temperature processing and typically include odor-suppressing basic organic or inorganic compounds. Preferably, the articles are substantially free from C8 and C9 organic ketones associated with undesirable odors. Further improvements to the articles include crack-resistant embodiments with synergistic amounts of polyethylene and titanium dioxide.Type: GrantFiled: March 12, 1999Date of Patent: April 3, 2001Assignee: Fort James CorporationInventors: Ronald L. Cochran, II, Mark B. Littlejohn, Donald C. McCarthy, Cristian M. Neculescu, Robert Patterson, Anthony J. Swiontek
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Patent number: 6191246Abstract: The invention provides a polymer which is a polymerization product obtained by polymerizing at least ethylene, 1-pentene and 1-hexene; and a process for producing a polymer by reacting at least ethylene, 1-pentene and 1-hexene in a reaction zone at a pressure between atmospheric and 60 kg/cm3 and at a temperature between 30° C. and 120° C., in the presence of a catalyst system. The invention also provides a polymer composition which comprises a terpolymer of ethylene, 1-pentene and 1-hexene, a phenolic stabilizer component, a metal salt of a higher aliphatic acid, and, optionally, at least one organic phosphite stabilizer.Type: GrantFiled: January 12, 1998Date of Patent: February 20, 2001Assignee: Sasol Technology (Proprietary) LimitedInventors: Dawid Johannes Joubert, Ignatius Hendrik Potgieter, Ioan Tincul, Peter Loggenberg
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Patent number: 6187848Abstract: A polyester molding composition reinforced with fiber glass or other silica based filler which has color stability at relatively high temperatures and comprises (a) from 40 to 97 weight percent of a polyester resin; (b) from about 3 to about 60 weight percent fibrous glass or silica based filler or mixture; (c) less than about 5 percent by weight additional ingredients which include a combination of stabilizers consisting essentially of an acidic quencher, a thioester and a phosphonite and (d) optionally from 2 to 30 weight percent of a flame retarding composition.Type: GrantFiled: February 20, 1998Date of Patent: February 13, 2001Assignee: General Electric CompanyInventors: Matthew R. Pixton, Robert R. Gallucci, James M. Finan
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Patent number: 6180700Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.Type: GrantFiled: February 6, 1998Date of Patent: January 30, 2001Assignee: General Electric CompanyInventor: James A. Mahood
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Olefin polymer composition having low smoke generation and fiber, film and fabric prepared therefrom
Patent number: 6172153Abstract: A polymer composition and fiber, film and fabric prepared therefrom. The composition contains (i) an acid neutralizing agent other than a metallic salt of a saturated or unsaturated fatty acid, (ii) a processing aid comprising a metallic salt of a saturated or unsaturated fatty acid, the metallic salt of a saturated or unsaturated being present in a maximum amount of 200 ppm, a stabilizer system containing (a) a phosphite selected from the group consisting of 2,2′,2″-nitrilo[triethyl-tris(3,3′,5,5′-tetra-tert.butyl-1, 1-biphenyl-2,2′-diyl)phosphite] and tris(2,4-di-tert-butylphenyl) phosphite; and (b) a N,N-dialkylhydroxylamine. Also disclosed is a method for preparing a polyolefin fiber, film or fabric which includes (A) incorporating the above additives into an olefin polymer, thereby producing a stabilized polyolefin polymer; and (B) extruding the stabilized olefin polymer through a die, thereby producing a olefin polymer fiber or film.Type: GrantFiled: June 12, 1998Date of Patent: January 9, 2001Assignee: Montell North America Inc.Inventor: Michael E. Starsinic -
Patent number: 6140398Abstract: A novel composition of matter comprising the reaction product of a phosphoryl compound, a salicylic acid derivative, and an organic compound containing two groups having hydroxyl functionality is provided. This composition has utility as a fire retardant chemical.Type: GrantFiled: July 7, 1999Date of Patent: October 31, 2000Assignee: Rhodia Inc.Inventor: Johnson D. Koola
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Patent number: 6136902Abstract: To provide a polyacetal resin composition having an excellent corrosion inhibiting effect on metals, particularly reduced in the adverse effect on magnetic tapes or the like, and suitable for use in producing component parts of a magnetic tape cassette such as a reel hub or tape guide, 100 parts by weight of a polyacetal resin (A) is blended with 0.05 to 5 parts by weight of an antioxidant (B), 0.001 to 5 parts by weight of a specified nitrogen-containing compound (C), and 0.001 to 3 parts by weight of a boric acid compound.Type: GrantFiled: June 18, 1997Date of Patent: October 24, 2000Assignee: Polyplastics Co., Ltd.Inventors: Yoshihito Fukasawa, Sachio Anada
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Patent number: 6133403Abstract: Disclosed are acid hardenable phenolic resin compositions and novolac compositions modified with about 5 to about 15% by weight of at least one reactive diluent selected from the group consisting of benzylic alcohol, benzylic ether, ethylene glycol, 1,3-butylene glycol, monoallyl or methylallyl ethers of poly(methylol) alkanes, monoallyl ether of glycerine, allyl or methallyl glycidyl ether, N-acylated arylamine, N-acylated naphthylamine, N-substituted arylsulfonamide, and N-substituted arylamine. The reactive diluent can be used to improve impact resistance and flexibility of the acid hardenable phenolic resin. Preferably, the methods for modifying mix life of acid hardenable phenolic resin by use of aryl phosphite and benzylic alcohol, and methods for modifying novolac resins, as well as methods for making the present compositions and products, such as coiled filament pipe and laminate panels, employing the compositions are also disclosed.Type: GrantFiled: October 7, 1998Date of Patent: October 17, 2000Assignee: Borden Chemical, Inc.Inventor: Arthur H. Gerber
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Patent number: 6107375Abstract: A thermoplastic composition featuring an improved resistance to hydrolysis is disclosed. The composition comprises (i) thermoplastic polycarbonate resin (ii) about 0.01 to 3 percent of a compound selected from the group consisting of phosphite and phosphonite and (iii) an additive amount of an oligomer or polymer the structure of which features at least one pendant cyclic iminoether group per molecular chain. The additive amount is that which is sufficient to improve the resistance of the polycarbonate resin to hydrolysis.Type: GrantFiled: October 8, 1998Date of Patent: August 22, 2000Assignee: Bayer CorporationInventors: Sivaram Krishnan, James B. Johnson, Donald K. Booher
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Patent number: 6093757Abstract: A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.Type: GrantFiled: November 24, 1997Date of Patent: July 25, 2000Assignee: Midwest Research InstituteInventor: Fu-Jann Pern
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Patent number: 6066695Abstract: A thermoplastic synthetic resin, especially high-density polyethylene, has its diffusion coefficient especially for hydrocarbons, reduced by the addition of 2 to 8% by weight of an additive consisting essentially of at least one phenoxy and/or epoxy resin, and at least one further component selected from the group which consists of at least one radical forming agent and at least one graft coploymerization catalyst, and optional quantities of an antioxidant selected from the group which consists of at least one phenolic antioxidant, at least one phosphitic antioxidant and mixtures thereof, at least one organosilane ester, at least one UV stabilizer, at least one antistatic composition, and polypropylene.Type: GrantFiled: August 25, 1998Date of Patent: May 23, 2000Assignee: Roth Werke GmbHInventors: Manfred Roth, Jurgen Dreier
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Patent number: 6057016Abstract: Polyester resins with a low formaldehyde content, to which an antioxidant acting as free-radical scavenger is added, containing less than 150 ppb of formaldehyde and having a formaldehyde generation rate of less than 15 ppb/min at 290.degree. C.Type: GrantFiled: March 15, 1999Date of Patent: May 2, 2000Assignee: Sinco Ricerche S.p.A.Inventors: Hussein Al Ghatta, Antonio Pinto
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Patent number: 6022628Abstract: A polymer composition having improved balanced mechanical and optical properties comprising (i) a random copolymer comprising from about 0.8% to about 20% by weight of butene-1 and from about 80% to about 99.2% by weight of propylene, and (2) from about 0%-0.35% by weight of polymer composition of a synthetic amorphous silica antiblock agent.Type: GrantFiled: August 11, 1997Date of Patent: February 8, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Ananda Mohan Chatterjee, Randolph Neil Campbell
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Patent number: 6010760Abstract: A thermoplastic resin composition comprising a thermoplastic resin (A) not forming an anisotropic melt phase and a liquid crystal polymer (B) capable of forming an anisotropic melt phase, an injection molding method thereof and an injection molded article capable of providing a thin molded article having excellent mechanical strength. A thermoplastic resin composition (C) comprises 99 to 50 wt. % of the thermoplastic resin (A) and 1 to 50 wt. % of the liquid crystal polymer (B). The liquid crystal polymer (B) is microscopically dispersed in an island form in the matrix phase of the thermoplastic resin (A) so that when the composition (C) is heat-treated at a temperature not lower than the melting point of the liquid crystal polymer (B) under a non-load state and is then cooled, the liquid crystal polymer (B) has a weight average particle diameter within the range of 10 to 40 micrometers and at least 80 wt. % thereof has a particle diameter within the range of 0.5 to 60 micrometers.Type: GrantFiled: June 17, 1997Date of Patent: January 4, 2000Assignee: Polyplastics Co., Ltd.Inventors: Hirotaka Miyazaki, Tomoyuki Aketa, Haruji Murakami, Takayuki Ishikawa, Kazuhito Kobayashi, Ayako Migita
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Patent number: 5980777Abstract: A liquid crystalline resin which comprises at least one kind of liquid crystalline polymer selected from liquid crystalline polyester and liquid crystalline polyester amide, both forming an anisotropic molten phase, and an inorganic phosphorus compound, said liquid crystalline resin having an absorbance of 0.5 or less at 380 nm when measured over an optical path length of 10 mm in a 0.5 wt % solution in a 1:1 mixed solvent of pentafluorophenol and chloroform (by weight). It is useful as engineering plastics because of improved color, heat resistance, and hydrolytic resistance.Type: GrantFiled: December 24, 1997Date of Patent: November 9, 1999Assignee: Toray Industries, Inc.Inventors: Hideyuki Umetsu, Yoshiki Makabe, Toshihide Inoue
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Patent number: 5969015Abstract: Compositions, comprising (i) a halogen-containing polymeric material, and(ii) at least one phosphite of formula I ##STR1## wherein n is a number from 1 to 6,R is a divalent linking group of formulae as defined herein as well as of novel compounds of formula I and their use as stabilisers.Type: GrantFiled: September 10, 1997Date of Patent: October 19, 1999Assignee: Witco Vinyl Additives GmbHInventors: Horst Zinke, Karl Josef Kuhn, Wolfgang Wehner
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Patent number: 5948833Abstract: A water-borne road marking paint composition which includes a chelating agent capable of chelating iron ions to form a substantially colorless complex is provided. A road marking produced from the traffic paint of the present invention substantially reduces or prevents yellowing of white road marking from iron and iron compound debris strewn on the road surfaces. A method of reducing or preventing yellowing of a newly-applied road marking on a road surface of a water-borne road marking paint is also disclosed. The method comprises incorporating in the water-borne road marking paint a chelating agent capable of chelating iron ions to form a substantially colorless complex. Further reduction of yellowing of the road marking is observed when a pigment dispersant is incorporated in the water-borne road marking paint.Type: GrantFiled: May 19, 1997Date of Patent: September 7, 1999Assignee: Rohm and Haas CompanyInventors: Josef Hans Jilek, Angelo Sanfilippo, Donald Craig Schall, Andrew Paul Trapani
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Patent number: 5929148Abstract: The present invention provides polyhexamethylene adipamide fibers significantly excellent in thermal yellowing resistance, and a process for producing the same. The improved polyhexamethylene adipamide fibers have adaptability to fibers for clothing which adaptability is comparable to that of poly-.epsilon.-capramide fibers and polyester fibers. The improved polyhexamethylene adipamide fibers can be obtained by either (1) melt spinning a polyhexamethylene adipamide simultaneously containing 2,4-bis(alkylthio)-6-(3,5 -dialkyl-4-hydroxyanilino)-1,3,5-triazine and a compound selected from the group consisting of phosphorous acid, hypophosphorous acid and derivatives of these acids, or (2) melt spinning the fibers having the sum of an amino end group concentration (?--NH.sub.2)!) and a carboxyl end group concentration (?--COOH!) of 70 to 200 meq/kg, satisfying the condition: ?--COOH!.ltoreq.60 meq/kg, and containing from 0.005 to 0.Type: GrantFiled: November 25, 1996Date of Patent: July 27, 1999Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Katsuya Shimizu, Hiroshi Tomiyama
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Patent number: 5922828Abstract: A novel process to produce polyethylene terephthalate (PET) using a specific catalyst stabilizer system is described. The catalyst stabilizer system is specific for producing PET wherein the polycondensation catalyst is a titanium and the stabilizer possesses an irreversible oxidation potential of at least +2.0 volts versus SCE. The novel process results in PET having acceptable color and low acetaldehyde content.Type: GrantFiled: August 13, 1997Date of Patent: July 13, 1999Assignee: Hoechst Celanese Corp.Inventor: David Anthony Schiraldi
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Patent number: 5919848Abstract: Disclosed are magnetic polyester compositions comprising a thermoplastic polyester polymer, certain epoxy-containing ethylene polymers, an aromatic phosphite compound, and elemental or magnetite iron.Type: GrantFiled: September 25, 1998Date of Patent: July 6, 1999Assignee: Eastman Chemical CompanyInventors: Larry Allen Minnick, Thomas Joseph Pecorini
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Patent number: 5916938Abstract: The present invention relates to a solution of a polyacrylate resin in one or more organic solvents, containing one or more phosphites, characterized in that the solution contains from 0.05 to 1.0% by weight, based on the solids content of the acrylate resin solution, of one or more phosphites and in that the phosphite has been added, either partially or entirely, after the polymerization reaction, at a temperature below the polymerization temperature.The present invention further relates to coating compositions which contain these polyacrylate resin solutions, their use in processes for producing a multilayer protective and/or decorative coating on a substrate surface, and the use of the coating compositions in the automotive refinishing sector.Type: GrantFiled: January 15, 1997Date of Patent: June 29, 1999Assignee: BASF Coatings AGInventors: Michael Brunnemann, Heinz-Peter Rink, Harald Borgholte, Werner-Alfons Jung, Peter Hoffmann
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Patent number: 5912289Abstract: Disclosed is a thermally stable aromatic polycarbonate composition comprising an aromatic polycarbonate, which is substantially free of a chlorine-containing compound, and a thermal stabilizer, the aromatic polycarbonate comprising a plurality of aromatic polycarbonate chains, each comprising recurring aromatic carbonate units and having a terminal aryl carbonate group and a terminal hydroxyl group, wherein each recurring unit has a divalent aromatic or pyridylene group comprising one or more divalent constituent aromatic or pyridylene groups, and wherein the plurality of aromatic polycarbonate chains collectively contain at least one constituent aromatic or pyridylene group substituted with at least one methyl group in an amount of 0.0001 or less in terms of the molar ratio of the methyl group substituted constituent group or groups relative to all constituent groups in the aromatic polycarbonate chains.Type: GrantFiled: January 24, 1997Date of Patent: June 15, 1999Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Kyosuke Komiya, Hiroshi Hachiya
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Patent number: 5897959Abstract: A biaxially extended polyester film which comprises a polyester resin having ethylene A biaxially oriented polyester film comprises a polyester resin having ethylene terephthalate and ethylene isophthalate repeating units in a weight ratio of 90:10 to 75:25; 0.02 to 0.06 weight % of an organic phosphite or phosphate ester; and 0.01 to 0.05 weight % of a hindered phenol compound, wherein the film possesses good thermal stability, processability, and thermal adhesive strength to a metal surface and is useful in forming the inner laminate layer of a metal container.Type: GrantFiled: November 20, 1996Date of Patent: April 27, 1999Assignee: SKC LimitedInventors: Sang-Il Kim, Byoung-Ho Cho
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Patent number: 5889099Abstract: A thermoplastic resin composition improved in terms of prevention of mold contamination, comprising the following components (A) to (G):component (A): 55 to 75% by weight of a propylene-ethylene block copolymer including a propylene homopolymer moiety having a melt flow rate of 15 to 50 g/10 min. and an isotactic pentad fraction of at least 0.97, said block copolymer having a melt flow rate of 10 to 30 g/10 min. and an ethylene content of 2 to 6% by weight,component (B): 0 to 10% by weight of an ethylene-propylene copolymer rubber having a melting temperature of 30.degree. to 60.degree. C. and a melt flow rate of 0.2 to 2 g/10 min.,component (C): 5 to 15% by weight of an ethylene-.alpha.-olefin copolymer rubber having a melting temperature of 60.degree. to 100.degree. C. and a melt flow rate of 0.3 to 2 g/10 min.,component (D): 15 to 25% by weight of a talc having an average particle diameter of up to 5 .mu.m and a specific surface area of at least 3.5 m.sup.Type: GrantFiled: February 21, 1997Date of Patent: March 30, 1999Assignees: Japan Polychem Corporation, Toyota Jidosha Kabushiki KaishaInventors: Takayuki Nagai, Toshio Niimi, Yukihito Zanka, Ikuo Tsutsumi, Hiroki Sato
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Patent number: 5883168Abstract: A profiled element for use as a wiping strip in a motor vehicle screen wiper is made of rubber or an elastomer, and has a coating formed by applying a solution to the profiled element. The solution comprises a powder of graphite for example, which is dispersed in a resin, and the solution includes a proofing agent for making the coating impermeable.Type: GrantFiled: June 13, 1997Date of Patent: March 16, 1999Assignee: Valeo Systemes D'EssuyageInventor: Michel Oulie
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Patent number: 5877242Abstract: A molding material comprises styrene/butadiene block copolymers obtainable by anionic polymerization and from 0.01 to 1% by weight, based on the polymer, of .alpha.-tocopherol.Type: GrantFiled: August 14, 1997Date of Patent: March 2, 1999Assignee: BASF AktiengesellschaftInventors: Norbert Niessner, Wolfgang Loth, Konrad Knoll, Norbert Guntherberg, Paul Naegele, Hubert Trauth, Jurgen Pohrt
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Patent number: 5877260Abstract: A thermoplastic synthetic resin, especially high-density polyethylene, has its diffusion coefficient especially for hydrocarbons, reduced by the addition of 2 to 8% by weight of an additive consisting essentially of at least one phenoxy resin, and at least one further component selected from the group which consists of at least one radical forming agent and at least one graft coploymerization catalyst, and optional quantities of an antioxidant selected from the group which consists of at least one phenolic antioxidant, at least one phosphitic antioxidant and mixtures thereof, at least one organosilane ester, at least one UV stabilizer, at least one antistatic composition, and polypropylene.Type: GrantFiled: May 8, 1997Date of Patent: March 2, 1999Assignee: Roth Werke GmbHInventors: Manfred Roth, Jurgen Dreier
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Patent number: 5874494Abstract: Phosphites which are useful as a deterioration inhibitor for organic material and are represented by the following formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group;R.sup.3 represents hydrogen atom or an alkyl group;R.sup.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group, or the two R.sup.4 together form a direct bond, a group represented by --S-- or an optionally substituted methylene group;A represents an alkylene group;W represents a group represented by --O-- or a group represented by --NR.sup.7wherein R.sup.7 represents a hydrogen atom, an alkyl group, etc.;B represents an alkylene group;and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other one represents hydrogen atom or an alkyl group.Type: GrantFiled: August 26, 1997Date of Patent: February 23, 1999Assignee: Sumitomo Chemical Company, LimitedInventors: Naoki Inui, Taketoshi Kikuchi, Kanako Fukuda, Takashi Sanada
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Patent number: 5852086Abstract: An antigel agent composed of four types of antioxidants that allows polyamides to be blended with acrylonitrile/butadiene polymers with minimum generation of gels and yields a blend which can be extruded or sheeted to give a uniformed shaped product, for example, sheets and molded articles and is essentially free of plugging the screens of extruder used to extrude hose tube or sheet.Type: GrantFiled: September 30, 1996Date of Patent: December 22, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: James Walter Horvath, Faith Michelle Howard
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Patent number: 5852085Abstract: Disclosed are transparent blends of a polyetherimide, at least one resin selected from the group consisting of polycarbonate resins, poly(ester-carbonate) resins, and polyarylate resins, and an effective amount of a catalyst to provide transparency to the blends. In addition to being transparent, the blends have good ductility as well as high flexural and tensile properties. The yellowness index of the compositions can be improved with the addition of a phosphite.Type: GrantFiled: December 31, 1996Date of Patent: December 22, 1998Assignee: General Electric CompanyInventors: Sterling Bruce Brown, Stephen Michael Copper, Brenda A. Giles
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Patent number: 5847057Abstract: The invention relates to heat-curable coating compounds containing a carboxyl-functional polyester produced by a condensation reaction from aliphatic and/or cycloaliphatic and/or aromatic polycarboxylic acids and anhydrides, a .beta.-hydroxyalkylamide and special stabilizers.Type: GrantFiled: October 30, 1997Date of Patent: December 8, 1998Assignee: EMS--Inventa AGInventors: Andreas Kaplan, Manfred Wenzler
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Patent number: 5843339Abstract: Phosphites represented by the general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.4 and R.sup.5 independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, an alkylcycloalkyl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms or a phenyl group; R.sup.3 and R.sup.6 independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; X.sub.1 is a dihydric alcohol residue, wherein HO--X.sub.1 --OH defines the corresponding dihydric alcohol from which residue X.sub.1, is obtained; and X.sub.2 is a direct bond or an alkylene group having 1 to 8 carbon atoms; and the phosphites are useful as stabilizers for organic materials.Type: GrantFiled: October 1, 1996Date of Patent: December 1, 1998Assignee: Sumitomo Chemical Company, LimitedInventors: Kanako Fukuda, Naoki Inui
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Patent number: 5833886Abstract: The thermostability of an aromatic polyphosphate composition an be improved by the addition of an effective amount of a hydroxy-terminated aromatic polyphosphate composition for such.Type: GrantFiled: September 17, 1997Date of Patent: November 10, 1998Assignee: Akzo Nobel NVInventors: Sophia Dashevsky, Danielle A. Bright
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Patent number: 5811478Abstract: Molding compositions comprising certain epoxy compounds, at least one antioxidant, an unsaturated thermosetting resin and an olefinically unsaturated monomer are disclosed. The disclosed compositions can provide enhanced yellowing resistance to articles molded from the compositions, particularly when the molding compositions contain white pigment. Processes from molding articles having enhanced yellowing resistance are also disclosed.Type: GrantFiled: December 23, 1996Date of Patent: September 22, 1998Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Gary Charles Rex, Kenneth Earl Atkins
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Patent number: 5773498Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.Type: GrantFiled: December 31, 1996Date of Patent: June 30, 1998Assignee: General Electric CompanyInventor: James A. Mahood
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Patent number: 5741838Abstract: This invention relates to halogen-free flame retardant thermoplastic moulding compounds prepared from polycarbonate and graft polymer, which may contain thermoplastic copolymer and/or polyalkylene terephthalate, wherein the flame retardant used is polyphenylene oxide combined with phosphorus compounds.Type: GrantFiled: August 9, 1995Date of Patent: April 21, 1998Assignee: Bayer AGInventors: Karl Fuhr, Thomas Eckel, Dieter Wittmann, Heinrich Alberts
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Patent number: 5736599Abstract: A diphosphite is provided derived from phosphorous trihalide, tetra alkyl hindered bisphenol, and a neoalkyl diol. The phosphites exhibit improved stability and are useful as thermal oxidative stabilizers for thermoplastic compositions.Type: GrantFiled: December 31, 1996Date of Patent: April 7, 1998Assignee: General Electric CompanyInventor: James A. Mahood
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Patent number: 5717014Abstract: A polyphenylene ether resin composition containing the following Components (A) to (D) according at the following formulation ratio.(A) 50 to 99.5 parts by weight of a polyphenylene ether(B) 0.5 to 50 parts by weight of a partially hydrogenated aromatic alkenyl compound-conjugated diene block copolymer having a hydroxy group and based on 100 parts by weight of the above resin composition,(C) 0 to 950 parts by weight of a thermoplastic resin and(D) 0 to 10 parts by weight of a phosphorous acid triester.Type: GrantFiled: November 25, 1996Date of Patent: February 10, 1998Assignee: Mitsubishi Chemical CorporationInventors: Ichiro Ohkawachi, Kiyoji Takagi, Koji Nishida
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Patent number: 5714527Abstract: A water-borne road marking paint composition which includes a chelating agent capable of chelating iron ions to form a substantially colorless complex is provided. A road marking produced from the traffic paint of the present invention substantially reduces or prevents yellowing of white road marking from iron and iron compound debris strewn on the road surfaces. A method of reducing or preventing yellowing of a newly-applied road marking on a road surface of a water-borne road marking paint is also disclosed. The method comprises incorporating in the water-borne road marking paint a chelating agent capable of chelating iron ions to form a substantially colorless complex. Further reduction of yellowing of the road marking is observed when a pigment dispersant is incorporated in the water-borne road marking paint.Type: GrantFiled: June 4, 1996Date of Patent: February 3, 1998Assignee: Rohm and Haas CompanyInventors: Josef Hans Jilek, Angelo Sanfilippo, Donald Craig Schall, Andrew Paul Trapani
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Patent number: 5703150Abstract: Phosphonite and phosphonate compounds ##STR1## wherein X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are each independently a group of the formula ##STR2## wherein R is a hydrogen atom or a methyl group, p is 0 or 1, q is independently 0 or 1 with regard to each repeat unit, and m is an integer of 2 to 10, a stabilizer for organic materials comprising said compound and a stabilized organic material comprising said compound. The compound of the present invention is less volatile at high temperatures. The use of the compound of the present invention as a stabilizer for organic materials affords an extremely useful organic material which is superior in heat stability and free of degradation caused by oxidation. The compound of the present invention has excellent compatibility with the above-mentioned organic materials and hardly migrate from the organic materials.Type: GrantFiled: December 27, 1995Date of Patent: December 30, 1997Assignee: Yoshitomi Pharmaceutical Industries, Ltd.Inventors: Tetsuji Ike, Takeshi Inoue, Yoshihiro Ozaki
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Patent number: 5698621Abstract: There is disclosed a printable self-clinging flexible film containing a polymerized PVC-based resin, a primary plasticizer and a stabilizer. The film exhibits high tackiness and surface tension, and printing ink may be applied directly to the surface of the film. Compositions for forming the film, and related methods are also disclosed.Type: GrantFiled: April 7, 1995Date of Patent: December 16, 1997Assignees: Achilles USA, Inc., Achilles CorporationInventors: Bach T. Nguyen, Tomiki Matsumoto, Toshihiro Katagiri
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Patent number: 5695869Abstract: Melt-blown microfiber webs are prepared from polyarylene sulfide polymers, particularly polyphenylene sulfide. A small amount of a phosphite or phosphonite compound is added to the extruder feedstock. The additive essentially eliminates spurious polymer particle formation at the extruder die openings, even over sustained production periods. The polyarylene sulfide microfiber webs so produced are thus essentially free of spurious particulates, and the web defects which may be caused by such particulates.Type: GrantFiled: August 21, 1995Date of Patent: December 9, 1997Assignee: Hoechst Celanese CorporationInventors: Andrew Bernard Auerbach, Warren Stephen Harmon
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Patent number: 5679288Abstract: The disclosure teaches a blend of a predominant amount of a polyphosphate flame retardant and an effective amount of a liquid crystalline additive for viscosity reduction and compatibilization when blended with a thermoplastic polymer, as compared to use of just the polyphosphate flame retardant alone. The polyphosphate can comprise resorcinol bis(diphenyl phosphate) and/or its higher oligomers. The liquid can be a liquid crystalline segmented block copolymer or a liquid crystalline oligomer.Type: GrantFiled: June 27, 1996Date of Patent: October 21, 1997Assignee: Akzo Nobel nvInventors: Ki-Soo Kim, Sophia Dashevsky, Alan Aaronson, Johst Herman Burk