Phosphorus Bonded Directly To Three Chalcogen Atoms Only, E.g., Phosphite, Etc. Patents (Class 524/128)
  • Patent number: 5196477
    Abstract: Silicone compositions comprising an organopolysiloxane composition and an organic compound capable of coordination with metals are described. Since the organic compound is preferentially adsorbed on a metal surface, the composition is particularly suitable for use in electric or electronic parts to prevent contact failure. A more specific embodiment comprises a diorganopolysiloxane of the average unit formula, R.sub.a SiO.sub.(4-a)/2, wherein each R independently represents an unsubstituted or substituted monovalent hydrocarbon group, and a is a value of from 1.90 to 2.05, a filler, an alkoxysilane or its hydrolyzate, a silylation catalyst made of an organic silicon compound having at least one specific type of group, an organic tin compound, another organosilicon compound capable of reaction with an alcohol in order to stabilize the composition, and an organic compound capable of coordination with metals.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: March 23, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Yoshifumi Inoue, Kei Miyoshi
  • Patent number: 5194465
    Abstract: ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers with contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: March 16, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Gerhard Rytz, Werner Stauffer, Margot Clauss
  • Patent number: 5194468
    Abstract: A thermoplastic polyblend of high density polyethylene, polyethylene terephthalate, a polyester elastomer, and a mixture of two aromatic phosphites. The polyblend has greatly improved impact strength and low gasoline permeation properties.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: March 16, 1993
    Assignee: General Motors Corporation
    Inventors: Ismat A. Abu-Isa, Pamela M. Graham
  • Patent number: 5194572
    Abstract: A method of preparing polyester materials comprising polymerizing a mixture comprising a diol and a stabilized diester of a naphthalenedicarboxylic acid.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: March 16, 1993
    Assignee: Amoco Corporation
    Inventor: Allen B. Mossman
  • Patent number: 5185426
    Abstract: A continuous direct esterification and polycondensation process is disclosed for the production of polyester comprising units of ethylene terephthalate as the major repeating units by supplying a slurry of mainly terephthalic acid and ethylene glycol to bis(betahydroxyethyl) terephthalate or its oligomer so as to carry out esterification, followed by polycondensation whereby the resulting oligomer is kept under increasingly reduced pressure, characterized in that a stabilizing solution of an aliphatic diol containing a diethyl or tributhyl phosphite and a hindered phenolic phosphonate is added to the reaction mixture before the start of the polycondensation.
    Type: Grant
    Filed: February 20, 1992
    Date of Patent: February 9, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Johannes M. Verheijen, August M. Marien
  • Patent number: 5185392
    Abstract: A polyarylene sulfide resin composition useful for molded parts comprises (A) 100 parts by weight of a polyarylene sulfide, (B) 0.01 to 10 parts by weight of an organic bisphosphite of the formula: ##STR1## in which R.sub.1 and R.sub.2 are each an alkyl, an alkyl having at least one substituent, an aryl, an aryl having at least one substituent or an alkoxy, (C) 0 to 400 parts by weight of an inorganic filler and (D) 0.01 to 5 parts by weight of at least one alkoxy silane.
    Type: Grant
    Filed: December 26, 1990
    Date of Patent: February 9, 1993
    Assignee: Polyplastics Co., Inc.
    Inventors: Toshifumi Nonaka, Toshikatsu Nitoh, Andrew Auerbach
  • Patent number: 5164479
    Abstract: Disclosed are a material for extrusion molding comprising a styrene-based polymer having a high degree of syndiotactic configuration, a melt viscosity of 10.sup.3 to less than 10.sup.6 poise measured at 300.degree. C. and a shearing rate of 10/sec, and a crystallinity of 15% or more, a process for preparation of the said material and a process for preparation of a molding product therefrom.The molding product prepared according to the present invention has excellent properties such as heat resistance and chemical resistance.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: November 17, 1992
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Keisuke Funaki, Komei Yamasaki
  • Patent number: 5162405
    Abstract: The present invention comprises novel single-functional and mixtures of multi-functional oligomeric performance additive compounds having one or more components of Structure A R1 ? ? ##STR1## (The definitions of R, Z1, Z2, Z3, A1, A2, A3 and y are given in the Summary Section), their uses and polymeric compounds and compositions containing them which have enhanced oxidative stabilities, enhanced ultraviolet (UV) and light stabilites and/or enhanced flame retardance. An example is the bis sulfonic acid bispotassium salt reaction product from an oligomeric caprolactone diol (TONE.RTM. 260), 2-sulfobenzoic acid anhydride and potassium carbonate, and use of this product, at levels up to about 3.0%, in a general purpose bisphenol A polycarbonate resin, to enhance the fire resistance or flame retardance of the polycarbonate resin.
    Type: Grant
    Filed: March 22, 1991
    Date of Patent: November 10, 1992
    Assignee: ELF Atochem North America, Inc.
    Inventors: Ronald E. MacLeay, Jose Sanchez, Daryl L. Stein
  • Patent number: 5158992
    Abstract: Disclosed are olefin polymers in nonextruded, aspolymerized particle form having a regular, essentially symmetrical geometrical shape, which are stabilized by depositing on their surface a mixture which is either melted, or in which at least stabilizer (A) is in the liquid state, and which comprises the following stabilizers (percent by weight on the polymer):A) from 0.02% to 0.015% of one or more organic phosphites or phosphonites or mixtures thereof, which are liquid at room temperature or have melting point below 100.degree. C.;B) from 0.025% to 0.2% of one or more phenolic antioxidants with melting point from 45.degree. to 130.degree. C.; and, optionally, one or more of the following additional components:C) from 0.05% to 0.5% of one or more thioethers, or organic polysulfides or mixtures thereof;D) from 0.1% to 1.0% of one or more light stabilizers which are liquid at room temperature or have a melting point below 150.degree. C.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: October 27, 1992
    Assignee: HIMONT Incorporated
    Inventors: Giancarlo Caselli, Giuseppe Gorini
  • Patent number: 5141975
    Abstract: Hydrolytically stable phosphite compositions for melt flow and color stabilization of thermoplastics may be prepared from crude tetrahydroabietyl alcohol. The phosphites may be reacting said alcohol with an organophosphite, such as by transesterification. Other synthesis techniques may also be used.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: August 25, 1992
    Assignee: General Electric Company
    Inventor: William P. Enlow
  • Patent number: 5128397
    Abstract: Hot melt adhesive compositions stabilized against thermal degradation, discoloration, skin formation and substantial viscosity changes, said adhesives being based on ethylene-vinyl acetate copolymer and a hydrocarbon tackifying resin and containing a stabilizer system of a hindered phenol antioxidant, a phosphite costabilizer and an acid scavenger.
    Type: Grant
    Filed: May 9, 1991
    Date of Patent: July 7, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Douglas W. Horsey, Ambelal R. Patel
  • Patent number: 5106912
    Abstract: Disclosed is an antistatic thermoplastic resin composition comprised of (A) 100 wt.parts of a thermoplastic resin and (B) 0.1-40 wt.parts of a polymer comprising 20-100 wt. % of units an anionic monomer represented by the formula (I): ##STR1## wherein R.sub.1 is H or --CH.sub.3, A.sub.1 is ##STR2## in which n is 0, 1 or 2, ##STR3## in which B is an alkylene, arylene or aralkylene group which may have an ester bond, or ##STR4## in which B is as defined above and R.sub.6 is H or an alkyl group, or A.sub.1 is ##STR5## X is N or P, and R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently represent an alkyl, aryl or aralkyl group may have a substituent,and 80-0 wt. % of units of a copolymerizable vinyl or vinylidene monomer.
    Type: Grant
    Filed: September 11, 1990
    Date of Patent: April 21, 1992
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Naoki Yamamoto, Hiroki Hatakeyama
  • Patent number: 5086099
    Abstract: An inorganic filler-containing polyolefin composition which comprises100 parts by weight of a polyolefin,1-100 parts by weight of an inorganic filler,0.01-1.0 part by weight of a phenolic antioxidant represented by the general formula (I) shown below, andat least one compound selected from the group consisting of the compounds represented by the general formulas (II) to (IV) shown below, and optionally 0.01-1.0 part by weight of a sulfur antioxidant and/or 0.01-2.0 parts by weight of a light stabilizer. ##STR1## wherein R.sub.1 represents an alkyl group of 1-3 carbon atoms,R.sub.2 --CO--NH--(CH.sub.2).sub.n --HN--CO--R.sub.2 (II)wherein R.sub.2 represents an alkyl group or an alkenyl group of 5-21 carbon atoms, and n is an integer of 1 to 6.R.sub.3 --CONH.sub.2 (III)wherein R.sub.3 represents an alkyl group of an alkenyl group of 5-21 carbon atoms, ##STR2## wherein R.sub.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: February 4, 1992
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Yoshiharu Fukui, Kazuhisa Kuroda
  • Patent number: 5086100
    Abstract: An inorganic filler-containing polyolefin composition which comprises100 parts by weight of a polyolefin,1-100 parts by weight of an inorganic filler.0.01-1.0 part by weight of a phenolic antioxidant represented by the general formula (I) shown below, andat least one compound selected from the group consisting of the compounds represented by the general formulas (II) to (IV) shown below, and optionally 0.01-1.0 part by weight of a sulfur antioxidant and/or 0.01-2.0 parts by weight of a light stabilizer. ##STR1## wherein R.sub.1 represents an alkyl group of 1-3 carbon atoms,R.sub.2 --CO--NH--(CH.sub.2).sub.n --HN--CO--R.sub.2 (II)wherein R.sub.2 represents an alkyl group or an alkenyl group of 5-21 carbon atoms, and n is an integer of 1 to 6.R.sub.3 --CONH.sub.2 (III)wherein R.sub.3 represents an alkyl group or an alkenyl group of 5-21 carbon atoms. ##STR2## wherein R.sub.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: February 4, 1992
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Yoshiharu Fukui, Kazuhisa Kuroda
  • Patent number: 5071893
    Abstract: A halogen-containing thermoplastic resin composition comprising a halogen-containing thermoplastic resin (A), a metallic soap (B) and an ash- and alkali metal-lean ethylene-vinyl acetate copolymer hydrolysate (C) having an ethylene content of 20 to 75 mole percent, a degree of saponification not less than 50 mole percent, an ash content not exceeding 300 ppm and an alkali metal content not exceeding 200 ppm, the proportions of (B) and (C) based on 100 parts of weight by (A) being 0.1 to 5 parts by weight and 0.1 to 5 parts by weight, respectively. The composition may further include, in addition to (A), (B), and (C) mentioned above, at least one compound (D) selected from the group consisting of .beta.-diketone compounds, organic phosphorous esters and aminocarboxylic acid compounds, the proportion of (D) based on 100 parts by weight of (A) being 0.
    Type: Grant
    Filed: May 2, 1991
    Date of Patent: December 10, 1991
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hiroshi Takida, Takamasa Moriyama, Yoshimi Akamatu, Makoto Kunieda
  • Patent number: 5063265
    Abstract: Described herein are novel heat-stabilized poly(aryl ether ketone) compositions. Stability is imparted by blending a poly(aryl ether ketone) with an aromatic phosphorus compound and an organic acid having a dissociation constant within a well-defined range.
    Type: Grant
    Filed: January 3, 1990
    Date of Patent: November 5, 1991
    Assignee: Amoco Corporation
    Inventor: James E. Harris
  • Patent number: 5059645
    Abstract: Thermoplastic molding materials containa) from 20 to 80 parts by weight of a polyphenylene ether,b) from 1 to 20 parts by weight of a block copolymer of the general formula A--B--A' consisting of two polyvinylaromatic blocks A and A' and a partially hydrogenated rubber block B,c) from 0 to 70 parts by weight of a polyvinylaromatic andd) from 0 to 40 parts by weight of conventional additives, the sum of a) to d) being 100 parts by weight, wherethe mean molecular weights of A and A' differ by a factor of from 2 to 20,the shorter block A has a mean molecular weight of from 2,000 to 4,000 andthe blocks A and A' together account for from 35 to 50% by weight of b).
    Type: Grant
    Filed: May 2, 1990
    Date of Patent: October 22, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Bertram Ostermayer, Erhard Seiler, Daniel Wagner, Klaus Bronstert, Volker Ladenberger
  • Patent number: 5055509
    Abstract: A process for enhancing the compatibility of polyester and polyamide in blends by adding thereto an effective amount of an aryl phosphoryl azide compound as for example diphenyl phosphoryl azide, and thereafter heating the composition until the desired enhancement in compatibility is obtained as evidenced by a lower of the individual melting points of the polyester and polyamide in the blend.
    Type: Grant
    Filed: April 17, 1989
    Date of Patent: October 8, 1991
    Assignee: Allied-Signal Inc.
    Inventors: H. R. Bhattacharjee, Y. P. Khanna, R. Kumar, J. J. Belles, Jr.
  • Patent number: 5055508
    Abstract: The present invention relates to a polycarbonate resin composition comprising:100 parts by weight of a polycarbonate resin;(A) 00.5 to 1 part by weight of an ester of saturated fatty acid having 10 to 30 carbon atoms and monohydric or polyhydric alcohol having 2 to 30 carbon atoms;(B) 0.05 to 1 part by weight of paraffin wax, and(C) 0 to 0.001 part by weight as a phosphorus atom of at least one phosphorus compound selected from the group consisting of phosphorus acid and phosphorous acid esters, wherein the total amount of the components (A) and (B) is 0.1 to 1 part by weight.The present invention further relates to a polycarbonate resin composition comprising:100 parts by weight of a polycarbonate resin;(D) 0.05 to 1 part by weight of .beta.-long side chain alcohol/behenic acid ester or long chain aliphatic alcohol; and(E) 0 to 0.001 part by weight as a phosphorus atom of at least one phosphorus compound selected from the group consisting of phosphorous acid and phosphorus acid esters.
    Type: Grant
    Filed: March 9, 1989
    Date of Patent: October 8, 1991
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventor: Kazunari Ohtsubo
  • Patent number: 5045575
    Abstract: A method of improving the flowability and reducing voids in liquid synthetic thermosetting resins precursor compositions used to pot structures such as a honeycomb core or electronic parts and assemblies. Up to about 0.50 weight percent of a suitable titanate coupling agent is mixed with the liquid resin precursor, preferably in a vacuum or an inert atmosphere, any necessary hardener is added later to the premixed resin with the agent, then the resin is poured into a mold holding the structure to be potted. The titanate coupling agents have the general formula: ##STR1## where: R is an alkoxy, alkyl, alkenyl, alkynyl or aralkyl group having from 1 to about 30 carbon atoms or a substituted derivative thereof;M is zirconium or titanium; andR is independently an aryl, aralkyl, alkaryl, alkyl or alkeno group having from 1 to about 30 carbon atoms.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: September 3, 1991
    Assignee: General Dynamics Corporation, Convair division
    Inventor: Solomon M. Gabayson
  • Patent number: 5045579
    Abstract: The preparation and use of unique, environmentally benign, economical and selectively modified polynorbornene sponges are described as selective absorbents for hydrocarbons, their halogenated analogs and selected oxygenated derivatives thereof. The modified polynorbornene material contains organo-titanium phosphates or oligophosphates and is environmentally stable for extended periods, easy to use, efficient and absorbate-retentive. Exhausted product will not drip or exude absorbate under conventional landfill disposal conditions and will produce only minimal ash when incinerated.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: September 3, 1991
    Assignee: Liquid Waste Corporation
    Inventor: Gerald Sugerman
  • Patent number: 5028645
    Abstract: Di-(2,2,6,6-tetramethyl-4-piperidinyl) succinate and glutarate are very effective light stabilizers for thermoplastics, particularly for polyolefins.
    Type: Grant
    Filed: August 8, 1989
    Date of Patent: July 2, 1991
    Assignees: Ciba-Geigy Corp., Sankyo Company Ltd.
    Inventors: Francois Gugumus, Jean Rody
  • Patent number: 5023286
    Abstract: The present invention relates to polypropylene resin compositions that exhibit an improved smell over prior art polypropylene resin compositions and comprises a polypropylene resin containing an inorganic filler, at least one phenolic antioxidant, at least one phosphorus antioxidant, and fine powders comprising aggregates of intimately bonded particles comprising zinc oxide, titanium dioxide and water.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: June 11, 1991
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masaru Abe, Yoichi Kawai, Masami Maki, Katuo Wada
  • Patent number: 5015679
    Abstract: Polyolefin material having improved resistance to heat and discoloration comprising amount of a stabilizing composition said stabilizing composition comprising a relatively high molecular weight hindered amine compound and an organic phosphorus compound having relatively low hygroscopicity and a hydrotalcite.
    Type: Grant
    Filed: June 1, 1989
    Date of Patent: May 14, 1991
    Assignee: Tonen Sekiyukagagaku K.K.
    Inventor: Tooru Matumura
  • Patent number: 5010123
    Abstract: Stabilizers for chlorine-containing olefin polymers containing Ca complexes of 1,3-diketones, hydrocarbon waxes and esters and/or partial esters of saturated, straight-chain C.sub.12 -C.sub.34 monocarboxylic acids, in conjunction with zinc salts of saturated, straight-chain C.sub.8 -C.sub.22 monocarboxylic acids and esters of phosphorous acid, provide the polymers with excellent properties in regard to processibility and temperature stability.
    Type: Grant
    Filed: April 4, 1989
    Date of Patent: April 23, 1991
    Assignee: Neynaber Chemie GmbH
    Inventors: Kurt Worschech, Peter Wedl, Erwin Fleischer, Frido Loeffelholz, Manfred Jaeckel
  • Patent number: 5008312
    Abstract: Bislactams of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are each C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 form a tetra- or pentamethylene radical, and R.sup.5 is hydrogen, carbonyl-C.sub.1 -C.sub.8 -alkyl, benzoyl, C.sub.1 -C.sub.8 -alkyl, C.sub.7 -C.sub.10 -phenylalkyl, the phenyl nucleus being unsubstituted or substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkyoxy, fluorine, chlorine or bromine radicals, or is C.sub.1 -C.sub.3 -cyanoalkyl, C.sub.2 -C.sub.4 -hydroxyalkyl or C.sub.2 - or C.sub.3 -aminoalkyl, and the acid addition salts and hydrates of these compounds.The compounds (I) are stabilizers for organic materials.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumueller, Peter Neumann, Hubert Trauth
  • Patent number: 5006578
    Abstract: A composition for temporary protection paint, containing alkali-soluble resin and an ester phosphite compound.
    Type: Grant
    Filed: March 23, 1990
    Date of Patent: April 9, 1991
    Assignees: Dainippon Ink and Chemicals, Inc., Yushiro Chemical Industry Co., Ltd.
    Inventors: Tsuyoshi Masuda, Hiromiti Tomihari, Masaki Muto, Naohito Saito
  • Patent number: 4994508
    Abstract: A composition comprising,(a) 1 to 99 parts by weight of a specific hydrogenated product of a block copolymer having at least one polymer block composed mainly of a vinyl aromatic compound and at least one polymer block composed mainly of a conjugated diene compound, a modified product which comprises said product modified with an .alpha.,.beta.-unsaturated carboxylic acid or a derivative thereof, or a mixture of said product and said modified product, wherein the content of the vinyl aromatic compound prior to hydrogenation is 5 to 95% by weight and a content of vinyl linkages [V] prior to hydrogenation which originated from the conjugated diene compound is 10 to 80%, said product satisfying the following conditions;(1) the hydrogenated ratio [A] of the total of aliphatic double bonds which originated from the conjugated diene compound is not lower than 5% and lower than 50%, and[B]/[V].sup.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: February 19, 1991
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Toshinori Shiraki, Yasuo Hattori
  • Patent number: 4985479
    Abstract: A stabilized polyolefin composition having improved weathering resistance is provided, whereby the following four components are incorporated into a polyolefin:(A) a hindered piperidine compound having a molecular weight of more than 750, such as poly-{[6-morpholino-1,3,5-triazine-2,4-diyl][2,2,6,6-tetramethyl-4-piperid yl)imino]hexamethylene[2,2,6,6-tetramethyl-4-piperidyl)imino]},(B) a hindered piperidine compound having a molecular weight of less than 500, such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate,(C) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate, and(D) a phosphorus-containing compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite.
    Type: Grant
    Filed: March 28, 1989
    Date of Patent: January 15, 1991
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Hideo Nagasaki, Shinichi Yachigo, Takeshi Takata, Hiroki Yamamoto, Yukoh Takahashi
  • Patent number: 4980114
    Abstract: Disclosed herein are stretched poly(arylene thioether) block copolymer films and a production processes thereof, said block copolymer film comprising a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 100 parts by weight of at least one other thermoplastic resin, and (C) up to 15 parts by weight of at least one filler.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: December 25, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4975479
    Abstract: Disclosed herein are melt-stable thermoplastic resin compositions comprising (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) --400 parts by weight of at least one of thermoplastic resins, and (C) 0-400 parts by weight of at least one filler per 100 parts by weight of the resin components. At least either one of Component (B) and Component (C) is contained in a proportion of at least 0.1 part by weight per 100 parts by weight of Component (A). The poly(arylene thioether) block copolymer alternately comprise at least one poly(arylene thioether-ketone) block having predominant recurring units of the formula ##STR1## wherein the --CO-- and --S-- are in the para position to each other and at least one poly(arylene thioether) block having predominant recurring units of the formula ##STR2## Also disclosed are compositions obtained by stabilizing by the melt-stable thermoplastic resin compositions with a basic compound and products molded or formed product from these compositions.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: December 4, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4962143
    Abstract: Disclosed herein are poly(arylene thioether) block copolymer fibers formed by melt-spinning a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 50 parts by weight of at least one other thermoplastic resin and (C) up to 10 parts by weight of at least one filler.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: October 9, 1990
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4960555
    Abstract: Disclosed herein are poly(arylene thioether) block copolymer fibers formed by melt-spinning a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 50 parts by weight of at least one other thermoplastic resin and (C) up to 10 parts by weight of at least one filler.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: October 2, 1990
    Assignee: Kureha Kagaku Kogho K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4960806
    Abstract: Disclosed herein are stretched poly(arylene thioether) block copolymer films and production processes thereof, said block copolymer film comprising a thermoplastic material composed of (A) 100 parts by weight of a particular poly(arylene thioether) block copolymer, (B) up to 100 parts by weight of at least one other thermoplastic resin, and (C) up to 15 parts by weight of at least one filler.
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: October 2, 1990
    Assignee: Kureha Kagaku Kagyo K.K.
    Inventors: Yoshikatsu Satake, Shinji Yamamoto, Takashi Kaneko, Masahito Tada, Ken Kashiwadate, Toshiya Mizuno, Hiroyuki Endo, Takayuki Katto, Zenya Shiiki
  • Patent number: 4933011
    Abstract: An antimicrobial solution of a microbiologically active organo sulfonyl ethylene, isoindole dicarboximide or zinc hydroxypyridine thionate dissolved in an organo phosphorus compound selected from the group consisting of organophosphites and organophosphonates.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: June 12, 1990
    Assignee: Morton Thiokol, Inc.
    Inventor: Nuno M. Rei
  • Patent number: 4925890
    Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicon or a polyol, and a processing adjuvant, such as a phosphate.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: May 15, 1990
    Assignee: Union Carbide Chemicals and Plastics Company Inc.
    Inventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
  • Patent number: 4912198
    Abstract: Cyclic carbonate oligomers are stabilized according to the present invention by admixing a composition containing cyclic carbonate oligomers with an amount of an organic phosphite sufficient to substantially prevent premature polymerization of the oligomers.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: March 27, 1990
    Assignee: General Electric Company
    Inventor: Luca P. Fontana
  • Patent number: 4857593
    Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicone or a polyol, and a processing adjuvant, such as a phosphate.
    Type: Grant
    Filed: March 8, 1988
    Date of Patent: August 15, 1989
    Assignee: Union Carbide Corporation
    Inventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
  • Patent number: 4829113
    Abstract: An aromatic polyester composition comprising an aromatic polyester derived from terephthalic acid and/or isothalic acid and a bisphenol and a stabilizer chosen from P-containing organic esters, O, S, or F-containing organic compounds or their mixtures.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: May 9, 1989
    Assignee: Celanese Corporation
    Inventor: Jerold C. Rosenfeld
  • Patent number: 4824885
    Abstract: Stabilizers for organic polymers, consisting of one or more phosphorus-containing compounds of the family of alkyl- and/or phenyl-phosphites, alkyl- and/or phenyl-phosphonites, alkyl- and/or phenyl-diphosphonites, are directly added to the reaction mixture during the (co)polymerization of .alpha.-olefins or of mixtures thereof with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized, and show a thermo-oxidative resistance higher than that of the same polymeric compositions to which the same antioxidants have been added by a traditional route.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: April 25, 1989
    Assignee: Enichem Sintesi S.p.A.
    Inventors: Ambrogio Magni, Erik Bersanetti
  • Patent number: 4762873
    Abstract: A polycarbonate resin composition comprising a blended mixture of(A) 100 parts by weight of a polycarbonate resin having a viscosity average molecular weight of from about 13,000 to about 18,000,(B) 0.01 to 0.1 part by weight of a partial ester of a monobasic fatty acid having 10 to 22 carbon atoms with a polyhydric alcohol having 2 to 10 carbon atoms,(C) 0.001 to 0.01 part by weight of trimethyl phosphate, and(D) 0.00001 to 0.002 part by weight, calculated as phosphorus atoms, of a phosphite ester having 9 to 60 carbon atoms.
    Type: Grant
    Filed: June 12, 1986
    Date of Patent: August 9, 1988
    Assignee: Teijin Chemicals, Ltd.
    Inventors: Masayoshi Miyauchi, Osamu Ohara
  • Patent number: 4742099
    Abstract: A new polyimide film which contains 30 to 800 ppm of titanium based on the weight of the film, and a process for producing a new polyimide film which comprises introducing an organic titanium compound substance into the film-forming polyimide resin prior to the casting step. This process enables one to control the film surface forming process and improve directly the adhesive properties of the film.
    Type: Grant
    Filed: December 1, 1986
    Date of Patent: May 3, 1988
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Hirosaku Nagano, Junji Takase, Hideki Kawai, Hitoshi Nojiri, Tsuneo Yamamoto
  • Patent number: 4739000
    Abstract: An aromatic tetraphosphite suitable for use as an antioxidant for organic materials. The aromatic tetraphosphite has the formula: ##STR1## wherein R, R.sup.1 and R.sup.2 are independently selected from the group consisting of hydrogen and straight chain, branched and cyclic alkyl groups having from 1 to about 18 carbon atoms with the provision that at least two of the R, R.sup.1 and R.sup.2 groups are alkyl groups.
    Type: Grant
    Filed: July 22, 1986
    Date of Patent: April 19, 1988
    Assignee: Ethyl Corporation
    Inventor: Lester P. J. Burton
  • Patent number: 4724247
    Abstract: An aromatic diphosphite as a antioxidant for organic materials. The aromatic diphosphite has the formula: ##STR1## wherein each R is independently selected from the group consisting of hydrogen and methyl; and R.sup.1, R.sup.2 and R.sup.3 are each independently selected from the group consisting of hydrogen and straight chain and branched alkyl groups having from 1 to about 18 carbon atoms with the proviso that at least two of said R.sup.1, R.sup.2, and R.sup.3 are alkyl groups having at least three carbon atoms.
    Type: Grant
    Filed: July 18, 1986
    Date of Patent: February 9, 1988
    Assignee: Ethyl Corporation
    Inventors: Lester P. J. Burton, Kestutis A. Keblys, Ronald L. Shubkin
  • Patent number: 4710317
    Abstract: A flame retardant polyolefin resin composition which, when molded, affords a molded product having highly flame retardant properties, no dripping properties, a smooth surface and an excellent appearance and superior resistances to heavy metal deterioration, heat deterioration and weather is provided, which composition consists of (A) 5-60% by weight of a halogen-containing flame retardant, (B) 100-10% by weight of antimony trioxide based on the weight of the halogen-containing flame retardant, (C) 0.5-15% by weight of a crosslinking agent, (D) 0.05-5% by weight of a specified thiophosphite, and (E) the balance % by weight of a polyolefin resin, the total of the quantities of (A), (B), (C), (D) and (E) being 100% by weight. If necessary, a processing aid may be further added to the above flame retardant polyolefin resin composition.
    Type: Grant
    Filed: May 20, 1986
    Date of Patent: December 1, 1987
    Assignee: Chisso Corporation
    Inventors: Nobuchika Tabata, Shohji Fukumitsu
  • Patent number: 4684679
    Abstract: Polyacetal resin compositions are provided having improved light stability and comprising an alkylidene bis(benzotriazolyl phenol) having the formula: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about eleven carbon atoms;R.sub.2 is selected from the group consisting of alkyl having from one to about twelve carbon atoms; and arylalkyl having from seven to about eighteen carbon atoms; andX is selected from the group consisting of hydrogen; halogen; alkyl having from one to about twelve carbon atoms; aryl alkyl having from seven to about eighteen carbon atoms; alkoxy having from one to about twelve carbon atoms; phenoxy; arylalkoxy having from seven to about eighteen carbon atoms; and phenyl.
    Type: Grant
    Filed: January 6, 1986
    Date of Patent: August 4, 1987
    Assignee: Adeka Argus Chemical Co., Ltd.
    Inventors: Naohiro Kubota, Atsushi Nishimura
  • Patent number: 4668722
    Abstract: New hindered piperidinoalcohol 1,1,1-trioxyalkanes are disclosed. In the 1,1,1-trioxyalkanes, at least on 1,1,1-trioxyalkane group is linked to the residue of an alcohol linked to the 4-position of a 2,2,6,6-tetraalkylpiperidine compound having 12 to 75 carbon atoms. For each 1,1,1-trioxalkane group, there are 1 to 3 tetraalkylpiperidine groups. The alkyl groups linked to the piperidine ring have from one to five carbon atoms each. The fourth substituent on the carbon atom of the 1,1,1-trioxyalkane is a hydrogen atom or an aliphatic group having one to five carbon atoms.The disclosed 1,1,1-trioxyalkanes protect a variety of synthetic resins against the deteriorative effects of exposure to actinic light.Stabilizer compositions comprising a disclosed 1,1,1-trioxyalkane and a known polymer stabilizer, as well as synthetic resin compositions stabilized with such stabilizer compositions, are also disclosed.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: May 26, 1987
    Inventor: Gerry P. Mack
  • Patent number: 4663374
    Abstract: A flame-resisting polycarbonate resin composition is disclosed, comprising (a) 100 parts by weight of an aromatic polycarbonate resin comprising (i) a copolymer of a halogenated 4,4'-dihydroxydiphenylalkane and a non-halogenated 4,4'-dihydroxydiphenylalkane or (ii) the copolymer (i) or a homopolymer of the non-halogenated 4,4'-dihydroxydiphenylalkane having incorporated therein a homo-oligomer of the halogenated 4,4'-dihydroxydiphenylalkane and/or a co-oligomer of the halogenated 4,4'-dihydroxydiphenylalkane and the non-halogenated 4,4'-dihydroxydiphenylalkane, (b) 0.001 to 5.0 parts by weight of an organic potassium phosphate, (c) 0.001 to 0.5 parts by weight of an phosphorous ester compound, and (d) 0 to 0.5 part by weight of an organosilicone compound. The resin composition has an improved viscosity characteristic and is, therefore, prevented from dripping during combustion, and does not suffer change in hue or reduction in molecular weight during molding.
    Type: Grant
    Filed: January 14, 1985
    Date of Patent: May 5, 1987
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Nobuharu Sonoda
  • Patent number: 4639481
    Abstract: Thermoplastic molding compositions which comprise (a) a poly(C.sub.2-6 alkylene terephthalate) resin and a major proportion of (b) an aromatic polycarbonate resin with (c) a polyolefin resin or an olefin copolymer, provide molded articles of improved impact resistance. In preferred embodiments, articles molded from the compositions possess improved impact resistance, lower specific gravity, good tensile strength, and improved resistance to distortion at elevated temperatures under load.
    Type: Grant
    Filed: April 9, 1985
    Date of Patent: January 27, 1987
    Assignee: General Electric Company
    Inventor: Harold F. Giles, Jr.
  • Patent number: H506
    Abstract: Disclosed is a resinous composition having excellent discoloration, processability, heat resistancy and durability comprising,A. 100 parts by weight of an aromatic polyester having the general formulae (I) and (II) ##STR1## B. 0.01 to 5 parts by weight of a phosphoric compound, and C. 0.01 to 0.1 part by weight of a carboxylic acid metal salt. Also disclosed is a process for producing shaped articles, the improvement which comprises adding the additives stepwise to the aromatic polyester.
    Type: Grant
    Filed: April 17, 1987
    Date of Patent: August 2, 1988
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masashiro Asada, Junji Takase