Metal Patents (Class 524/161)
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Publication number: 20040143046Abstract: This invention is directed to formation of a creped nonwoven web. The creped web is formed in a creping process using a polymer emulsion binder formed in an alkylphenol ethoxylate-free surfactant system. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.Type: ApplicationFiled: January 6, 2004Publication date: July 22, 2004Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Patent number: 6753367Abstract: The present invention relates to flame retardant polycarbonate compositions with improved weathering performance, said compositions comprising one or more cyanoacrylic esters. The invention also relates to methods for improving the flame retardancy and weathering performances of polycarbonate compositions by incorporating cyanoacrylic ester(s). Finally, the invention further relates to articles manufactured from flame retardant polycarbonate compositions comprising cyanoacrylic ester(s).Type: GrantFiled: August 20, 2001Date of Patent: June 22, 2004Assignee: General Electric CompanyInventors: Johannes Martinus Dina Goossens, Hendrik Verhoogt
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Patent number: 6740697Abstract: A flame retardant thermoplastic molding composition is disclosed. The composition contains an amorphous thermoplastic polymer, at least one flame retardant in the form of a fully or partially halogenated sulfonic acid salt and at least on alkaline earth metal sulfate and/or one oxide having an average particle size of up to 400 nm.Type: GrantFiled: August 17, 2001Date of Patent: May 25, 2004Assignee: Bayer AktiengesellschaftInventors: Axel Brenner, Walter Köhler, Martin Döbler
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Patent number: 6727302Abstract: A transparent, fire resistant polycarbonate composition comprises polycarbonate, poly(methylphenylsiloxane) and a salt based flame retardant. These polycarbonate compositions can attain UL94 V0 ratings at 1.6 millimeter thickness, previously possible only with a halogenated fire retardant.Type: GrantFiled: April 3, 2001Date of Patent: April 27, 2004Assignee: General Electric CompanyInventors: Johannes M. D. Goossens, Bart P. G. Hendrix, Walter van der Heijden, Christianus J. J. Maas, Hendrik Verhoogt
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Patent number: 6624242Abstract: An aqueous dispersion of (a) 0.1-40% by wt. of a low molecular weight, low melting point, water-insoluble polymer in which the polymer particles have a size <10 microns, and (b) 0.001-30% by wt. of an anionic emulsifier.Type: GrantFiled: August 8, 2001Date of Patent: September 23, 2003Assignee: ISP Investments Inc.Inventors: James F. Curry, Kolazi S. Narayanan, Ronald H. Goehner, Jr., Domingo I. Jon, George B. Beestman
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Patent number: 6608115Abstract: Polyvinyl chloride resin compositions and methods of preparation and use thereof for increasing the degree of whiteness in finished polyvinyl chloride foam. The resin compositions contain sulfur compounds selected from sulfonic acid derivatives, sulfinic acid derivatives, and mercapto acetic acid sodium salt, and optionally contain water soluble salts and/or t-butyl hydroperoxide.Type: GrantFiled: January 21, 2003Date of Patent: August 19, 2003Assignee: Occidental Chemical CorporationInventors: Michael T. Moran, Thomas E. Moses, Sherry Rohn Clancy
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Patent number: 6605659Abstract: A thermoplastic resin composition contains an aromatic carbonate resin, a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and a flame retarding amount of an alkali metal or alkaline earth metal salt of an alkylbenzenesulfonic acid flame retardant.Type: GrantFiled: December 20, 2000Date of Patent: August 12, 2003Assignee: General Electric CompanyInventors: Kirk J. Blackburn, Robert R. Gallucci, Emil M. Georgiev
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Patent number: 6602938Abstract: This invention is a flame resistant polycarbonate resin composition characterized by blending 0.01-2 weight parts of a silicone compound (B)) wherein a main chain has a branch structure and having an aromatic group in an organic substituent, 0.01-2 weight parts of an alkali metal salt of an aromatic sulfonic acid (C) represented by the following general formula 1 (hereafter, referred to as general formula 1), and 0.05-5 weight parts of a fiber-forming fluorine-containing polymer (D), relative to 100 parts of a polycarbonate resin (A): General formula 1: Am—R—(SO3M)n (wherein, R is a phenyl group, naphthyl group, or a phenyl group or naphthyl group substituted by A, where A is at least one type of substituent chosen from a group comprising a halogen atom, alkyl group, aryl group, vinyl group, alkoxy group, amino group, methyl ester group and ethyl ester group, and M is an alkali metal.Type: GrantFiled: October 11, 2001Date of Patent: August 5, 2003Assignees: Sumitomo Dow Ltd., NEC Corp.Inventors: Masatoshi Iji, Shin Serizawa, Satoshi Umeyama, Tadashi Shinomiya, Ichiro Sato
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Publication number: 20030114561Abstract: This invention is directed an alkylphenol ethoxylate-free surfactant system for preparation of polymer emulsions. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Applicant: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20030065072Abstract: The invention relates to a process to make stabilized PVC wherein use is made of at least one compound of the formula 1Type: ApplicationFiled: August 6, 2002Publication date: April 3, 2003Inventors: Daniel Stephan Van Es, Jacco Van Haveren, Augustinus Emmanuel Frissen, Johannes Cornelis Van Der Kolk, Gerard Hubert Frans Schmets, Hendrik Willem Huisman, Heather Blue Harvey
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Patent number: 6518357Abstract: A flame retardant polycarbonate composition includes (A) at least one polycarbonate and (B) a silsesquioxane flame retardant. The flame retardant polycarbonate composition can be made by providing a polycarbonate and incorporating a flame retardant amount of a silsesquioxane into the polycarbonate. An article can be molded from the composition.Type: GrantFiled: October 4, 2000Date of Patent: February 11, 2003Assignee: General Electric CompanyInventors: Padmavathy Rajagopalan, John Robert Campbell, Larry Neil Lewis
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Patent number: 6489042Abstract: An electronic circuit device comprising at least one substrate having a photoimageable covercoat, comprising at least 95 weight percent of at least one epoxy-modified aromatic vinyl-conjugated diene block copolymer and a catalyst comprising an onium salt selected from a triarylsulfonium salt and a diaryliodonium salt, wherein the covercoat is formed by solvent coating or extrusion and then heat laminated onto at least a portion of the substrate.Type: GrantFiled: October 18, 2001Date of Patent: December 3, 2002Assignee: 3M Innovative Properties CompanyInventors: Ronald L. Imken, Robert S. Clough
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Patent number: 6476099Abstract: A joint compound composition comprising a filler, a binder and a hydrocarbon substituted sulfate, sulfonate, sulfuric acid or sulfonic acid is disclosed. The composition of the present invention produces a joint compound that shrinks less and is resistant to cracking and cratering.Type: GrantFiled: November 28, 2000Date of Patent: November 5, 2002Assignee: United States Gypsum CompanyInventors: Scott D. Cimaglio, Frank A. Wawrzos, Charles J. Miller
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Publication number: 20020120043Abstract: The invention concerns well dispersible powders on the basis of carboxylated copolymers containing butadiene made of styrene and/or acrylonitrile, whose films taken from redispersion show good tensile strength. According to the invention, the latices are sprayed with mixtures of spraying aids consisting of 1 to 15 weight % of a salt of the alkylated di-phenyl-ether-di-sulphonic acid, caseinate and/or N-alkyl sulphosuccinamide and/or with 1 to 20 weight % of a di- or tetra sodium or potassium salt of an addition product from N-alkyl sulphosuccinamates with maleic acid mixed together with polyvinyl alcohol. The dispersions can be used especially in the construction industry and they offer an alternative to copolymers on the basis of polyvinyl acetates and acrylates.Type: ApplicationFiled: September 24, 1998Publication date: August 29, 2002Inventors: BERND ROTHENHAUSSER, VOLKER KIESEL, HARTMUT KUHN, DOMINIK ELSASSER
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Publication number: 20020120044Abstract: A thermoplastic resin composition contains an aromatic carbonate resin, a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and a flame retarding amount of an alkali metal or alkaline earth metal salt of an alkylbenzenesulfonic acid flame retardant.Type: ApplicationFiled: December 20, 2000Publication date: August 29, 2002Applicant: General Electric CompanyInventors: Kirk J. Blackburn, Robert R. Gallucci, Emil M. Georgiev
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Publication number: 20020115762Abstract: The polycarbonate resin composition having good reflectance and impact strength according to the present invention comprises (A) about 100 parts by weight of a thermoplastic polycarbonate resin as a base resin, (B) about 2-20 parts by weight of titanium dioxide, (C) about 0.01-5 parts by weight of at least one sulfone sulfonate salt, and optionally (D) about 0-30 parts by weight of an impact modifier and optionally (E) about 0-30 parts by weight of a vinyl copolymer, and optionally (F) about 0-1.0 parts by weight of a stilbene-bisbenzoxazole derivative.Type: ApplicationFiled: December 21, 2001Publication date: August 22, 2002Applicant: CHEIL INDUSTRIES, INC.Inventors: Han-Soo Chung, Hee-Goo Yea
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Patent number: 6423367Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: July 27, 2001Date of Patent: July 23, 2002Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Patent number: 6342550Abstract: The purpose of the present invention is to provide a flame-retardant polycarbonate resin composition which contains phosphorus-free flame-retardant(s), has an excellent impact resistance, an excellent heat resistance as well as an excellent moldability, and can satisfy a severe flammability level. According to the present invention, there is provided a flame-retardant polycarbonate resin composition which comprises (A) 100 parts by weight of an aromatic polycarbonate resin, (B) 0.01-5 parts by weight of an organic sulfonic acid metal salt, (C) 0.01-5 parts by weight of a fluorinated polyolefin, (D) 0.2-20 parts by weight of a diene-containing multi-layered polymer, and wherein the content of a phosphorus-containing flame-retardant is less than 0.5 parts by weight.Type: GrantFiled: November 15, 1999Date of Patent: January 29, 2002Assignee: Mitsubishi Engineering Plastics CorporationInventors: Kazuhiko Ishii, Ken Shimomai
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Patent number: 6329450Abstract: The present invention relates to a blend of polymeric materials comprising; (A) of from about 1 to about 80 percent by weight (based on the combined weights of Components A and B) of at least one substantially random interpolymer; wherein said interpolymer; (1) contains of from about 0.5 to about 50 mole percent of polymer units derived from; a) at least one vinyl or vinylidene aromatic monomer, or b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 50 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a melt index (I2) of from about 0.01 to about 100 g/10 min; and (4) has a molecular weight distribution (Mw/Mn) of from about 1.Type: GrantFiled: March 2, 1999Date of Patent: December 11, 2001Assignee: The Dow Chemical CompanyInventors: Samuel A. Ogoe, Charles F. Diehl, Leo A. Novak, Wendy D. Hoenig, Shaofu Wu, Donna C. Scott
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Publication number: 20010049430Abstract: A water slurry process is used to prepare a prepreg and to manufacture articles from macrocyclic polyester oligomers. In one embodiment, a process for preparing a water suspension of macrocyclic polyester oligomers includes the steps of contacting a macrocyclic polyester oligomer and a polymerization catalyst with water and a surfactant, and mixing the macrocyclic polyester oligomer and polymerization catalyst with water and the surfactant thereby forming a suspension. In another embodiment, a process for impregnating macrocyclic polyester oligomers for polymerization includes the steps of providing a suspension of a macrocyclic polyester oligomer and a polymerization catalyst in water, applying the suspension to a base material, drying to remove water from the suspension, and pressing the dried suspension to a desired form. In yet another embodiment, a composition of macrocyclic polyester oligomer includes a macrocyclic polyester oligomer, a polymerization catalyst, and water.Type: ApplicationFiled: January 4, 2001Publication date: December 6, 2001Inventors: Steven J. Winckler, Tohru Takekoshi
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Patent number: 6322624Abstract: The reaction product of at least one polyanhydride and at least one amine is disclosed. A phase change ink composition and a phase change ink containing the polyanhydride/amine adduct are also disclosed.Type: GrantFiled: February 12, 1999Date of Patent: November 27, 2001Assignee: Xerox CorporationInventors: Donald R. Titterington, Jeffery H. Banning, Clifford R. King
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Patent number: 6310124Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.Type: GrantFiled: November 25, 1998Date of Patent: October 30, 2001Assignee: Cytec Technology, Corp.Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
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Patent number: 6294270Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.Type: GrantFiled: December 23, 1998Date of Patent: September 25, 2001Assignee: 3M Innovative Properties CompanyInventor: Robert Steven Clough
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Patent number: 6284823Abstract: Acrylic resin compositions having excellent antistaticity, good appearance and superior optical properties made by blending (A) 100 parts by weight of an acrylic resin; (B) a phosphonium sulfonate consisted of organic sulfonate anion and organic phosphonium cation; (C) a lithium benzenesulfonate; and (D) 0.05 to 2.0 parts by weight of a fatty acid ester and/or amide, wherein (B)/(C) is 2/8 to 8/2 by weight and (B) plus (C) is 0.2 to 2.5 parts by weight.Type: GrantFiled: July 8, 1998Date of Patent: September 4, 2001Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yukio Kokuzawa, Kazunobu Sato
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Publication number: 20010009942Abstract: A suspending agent-containing slurry is disclosed which comprises a dispersant and a particulate suspending agent having a particle size distribution in which the particle diameter at weight-cumulative 95%, from the minimum particle size, is 1 &mgr;m or smaller. A method for efficiently producing the suspending agent-containing slurry is also disclosed. A process for suspension polymerization by use of the suspending agent-containing slurry is further disclosed. The slurry not only has such an excellent suspending ability in suspension polymerization that it enables the production of vinyl polymer beads having a narrow bead size distribution, but also is capable of retaining this ability over long and of exhibiting the same ability even when it has a high concentration. The suspension polymerization process enables vinyl polymer beads having a narrow bead size distribution to be produced efficiently due to the use of the slurry.Type: ApplicationFiled: October 16, 1998Publication date: July 26, 2001Inventors: MITSUSHI MURATA, TSUNENORI TAKAHASHI, YUKIO KATO
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Patent number: 6235821Abstract: The invention provides thermoplastic resin compositions for purging which comprise a thermoplastic resin and a methyl methacrylate/styrene copolymer incorporated therein. According to the invention, thermoplastic resin compositions for purging molding machines, which have an excellent cleaning ability, can be obtained.Type: GrantFiled: December 8, 1999Date of Patent: May 22, 2001Assignee: Chisso CorporationInventor: Takanori Saito
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Patent number: 6232381Abstract: The process of this invention can be utilized to stabilize tin-coupled rubbery polymers. This process involves adding a chelating diamine or a sodium alkoxide to the rubbery polymer after the tin coupling has been carried out. This invention more specifically discloses a process for improving the stability of a tin-coupled rubbery polymer which comprises adding a sodium alkoxide to the tin-coupled rubbery polymer subsequent to the time at which the tin-coupled rubbery polymer is coupled. Sodium alkoxide is a representative example of a sodium alkoxide that can be used to stabilize the tin-coupled rubbery polymer.Type: GrantFiled: July 30, 1999Date of Patent: May 15, 2001Assignee: The Goodyear Tire & Rubber CompanyInventors: Wen-Liang Hsu, Adel Farhan Halasa
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Patent number: 6180702Abstract: A thermoplastic molding composition comprising polycarbonate resin and additive, positive, amounts of stabilizer and salt is disclosed. The composition is characterized by its freedom from splay and by its improved flame retardance. The stabilizer of the invention is a physical mixture of poly(alkyl methacrylate) with fluorinated polyolefin, and the salt is an alkali metal or alkaline earth metal salt of perfluoroalkane sulfonic acid, aromatic sulfimide, or aromatic sulfonic acid.Type: GrantFiled: August 9, 1999Date of Patent: January 30, 2001Assignee: Bayer CorporationInventors: James Y. J. Chung, Sivaram Krishnan, Winfried G. Paul
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Patent number: 6177511Abstract: Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.Type: GrantFiled: January 25, 1999Date of Patent: January 23, 2001Assignee: Wacker-Chemie GmbHInventors: Jochen Dauth, Bernward Deubzer, Robert Schröck, Petra Gratzl
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Patent number: 6150443Abstract: Provided are a flame-retardant polycarbonate resin composition capable of being formed into moldings having good impact resistance, high strength and good thermal stability that are intrinsic to polycarbonate resins and having good antistatic properties and good flame retardancy, and also injection moldings of the composition. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 50 to 100% by weight of a polycarbonate resin and (B) from 0 to 50% by weight of a styrenic resin, from 1 to 50 parts by weight of (C) a flame retardant, and from 0.1 to 5 parts by weight of (D) an anionic antistatic agent, and has a sodium sulfate content of at most 0.05% by weight. Optionally, the composition may contain (F) a fluoro-olefinic resin, (G) a rubber-like elastomer, and (H) an inorganic filler.Type: GrantFiled: August 9, 1999Date of Patent: November 21, 2000Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Akio Nodera, Naoki Mitsuta
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Patent number: 6121351Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymers during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.Type: GrantFiled: August 7, 1997Date of Patent: September 19, 2000Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Wayne Payton Pruett, Kay Hunt Shackelford, Samuel David Hilbert
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Patent number: 6037055Abstract: New copolyester composition that provides excellent filament spinning and mill/yarn processing of staple fiber into fabrics having combination of excellent pilling performance as well as aesthetics and tactility ("hand"). Preferred fibers have non-round cross-sections, especially multi-grooved and scalloped-oval cross-sections that provide fabrics having outstanding comfort qualities of moisture-management, dryness and comfort, as well as minimal pilling.Type: GrantFiled: September 8, 1998Date of Patent: March 14, 2000Assignee: E. I. du Pont de Nemours and CompanyInventors: Arun Pal Aneja, Frederick Karl Mallon, Adrian Charles Snyder
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Patent number: 6031036Abstract: Disclosed are aromatic brominated polycarbonate/polyester carbonate/silicone polyimide compositions having improved flame resistance and reduced drippage and heat release rate, comprising by weight:(A) from about 20 to about 77 parts of an aromatic brominated polycarbonate resin;(B) from about 20 to about 77 parts of a polyester carbonate resin;(C) from about 0.5 to about 10 parts of a silicone-polyimide resin;(D) from about 0 to about 25 parts of an aromatic polycarbonate having a molecular weight of from about 40,000 to about 90,000; the sum of (A)-(D) being 100 parts by weight;(E) from about 0.05 to about 2.0 parts of a metal salt of a halogenated monomeric or polymeric aromatic sulfonic acid or mixtures thereof, wherein the metal salt is selected from the group consisting of alkali metal salts, alkaline earth metal salts, and mixtures of the metal salts; and(F) from about 0.1 to about 5.0 parts by weight of filler or a pigment.Type: GrantFiled: December 10, 1993Date of Patent: February 29, 2000Assignee: General Electric CompanyInventors: Niles Richard Rosenquist, Angelika Howard Clark
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Patent number: 6013708Abstract: Compositions of precipitated cationic polymers containing mixtures of certain salts as well as processes for making and using the same are disclosed.Type: GrantFiled: October 3, 1996Date of Patent: January 11, 2000Assignee: Cytec Technology Corp.Inventors: Joseph J. Mallon, Raymond S. Farinato, Louis Rosati, John J. Freeman, Jr.
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Patent number: 5985966Abstract: An aqueous emulsion of fluorine-containing polymer according to the present invention contains an emulsion stabilizer represented by the formula:R--Ph--O--(CH.sub.2 CH.sub.2 O).sub.n --CH.sub.2 CH.sub.2 --SO.sub.3 M(Ph is a phenyl radical; R is an alkyl radical having 8-12 carbon atoms; n is a number of 1-6; and M is Na, K or NH.sub.4). The resulting emulsion has excellent mechanical stabilities and thermal stabilities as well as decreased possibility of causing ground water contamination.Type: GrantFiled: February 16, 1996Date of Patent: November 16, 1999Assignee: Du Pont - Mitsui Fluorochemicals Co., Ltd.Inventors: Masatsune Ogura, Shizuo Chiba
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Patent number: 5936007Abstract: The present invention provides polycarbonate moulding compositions containing polycarbonates, stabilisers of the general formula (I)R.sub.1 --X--(CHR.sub.4).sub.n --Y--R.sub.2and optionally polypropylene glycols.The present invention also provides use of these moulding compositions for preparing items for medical applications.Type: GrantFiled: July 14, 1998Date of Patent: August 10, 1999Assignee: Bayer AGInventors: Wolfgang Ebert, Ralf Hufen, Heidemarie Pantke, Klaus Berg
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Patent number: 5919854Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.Type: GrantFiled: October 3, 1996Date of Patent: July 6, 1999Assignee: Cytec Technology Corp.Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
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Patent number: 5882780Abstract: Elastic polyester fibers having a high anti-cohesive property (separability) include (A) a polyester elastomer and (B) 0.2 to 10%, based on the weight of the elastomer, of an anti-cohesive agent including (a) at least one alkali metal salt of organic sulfonic acid of the formula: R.sup.1 --S0.sub.3 M, wherein R.sup.1 =C.sub.5-25 hydrocarbon group, M=alkali metal, and (b) at least one compound of the formulae (2)-(6): R.sup.2 --X.sub.p --CH.sub.2 CH.sub.2 OH (2), R.sup.3 --COO--CH.sub.2 CH(OH)CH.sub.2 OH (3), R.sup.4 --COO--(CH.sub.2 CH.sub.2 O).sub.m --H (4), R.sup.5 --O--(CH.sub.2 CH.sub.2 O).sub.n H (5) and R.sup.6 --CONHCH.sub.2 CH.sub.2 NHCO--R.sup.7 (6), wherein R.sup.2 -R.sup.7 =C.sub.5-25 hydrocarbon group, X=--CONY or ##STR1## group, p=0 or 1, m, n=5 to 50.Type: GrantFiled: July 3, 1997Date of Patent: March 16, 1999Assignee: Teijin LimitedInventors: Yasuo Yamamura, Mikio Tashiro, Yasuyuki Yamazaki, Takeshi Honjou, Nobuyuki Yamamoto, Michihiro Yamada
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Patent number: 5847030Abstract: A process for the preparation of polymer latex particles by conducting a pre-reaction emulsification with monomer, polar comonomer, water, surfactant, chain transfer agent, and initiator; and which pre-reaction emulsification is effected at a low temperature of from about 3.degree. C. to about 35.degree. C., for example, and thereafter, effecting emulsion polymerization by heating the aforementioned emulsified mixture in a reactor at a temperature of from about 25.degree. C. to about 125.degree. C. The aforementioned reactor contents are retained at this temperature, that is 25.degree. C. to 125.degree. C. for an effective time period. Thereafter, the reaction mixture is cooled.Type: GrantFiled: August 2, 1996Date of Patent: December 8, 1998Assignee: Xerox CorporationInventors: Hadi K. Mahabadi, Grazyna E. Kmiecik-Lawrynowicz, T. Hwee Ng
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Patent number: 5840789Abstract: The present invention relates to aqueous compositions having pH of less than or equal to about 11 and which contain a thickening amount of an acrylate-based rheology modifier, which modifier contains an emulsion which is prepared by single-stage emulsion polymerization of a C.sub.2 -C.sub.6 alkyl ester of acrylic acid and/or a C.sub.1 -C.sub.6 alkyl ester of methacrylic acid, a monomer chosen from a vinyl-substituted heterocyclic compound containing at least one of a nitrogen or sulfur atom, (meth)acrylamide, a mono- or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylate, a mono or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylamide, and optionally cross-linking monomers and/or associative monomers, in the presence of water, a first surfactant, a free-radical initiator and an alcohol selected from C.sub.2 -C.sub.Type: GrantFiled: August 13, 1997Date of Patent: November 24, 1998Assignee: National Starch and Chemical Investment Holding CorporationInventors: Daniel W. Verstrat, Milagros C. Barron
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Patent number: 5789471Abstract: A polyvinyl chloride (PVC) composition includes an active fluorescence or phosfluorescence inducing agent which causes the composition to emit a brighter or hotter appearing light, as compared to conventional PVC compositions, when exposed to white light. In one form, the PVC composition includes barium diphenylaminesulfonate as an additive in a clear or transparent composition and light passing through the composition appears to be hotter than the impinging light. In another form, the additive is barium carbonate and the PVC includes a tinting agent to induce a colored glow when exposed to white light. In all forms, the fluorescence or phosfluorescence inducing agent is selected from a class of materials having the characteristics of creating a compound having an outer electron shell which will permit an electron shift between shells when exposed to light.Type: GrantFiled: April 14, 1997Date of Patent: August 4, 1998Assignee: Super Vision International, Inc.Inventor: Jack Caruso
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Patent number: 5786424Abstract: A blend of polycarbonate and a homogeneously branched, linear ethylene polymer, which blend has a desirable balance of impact resistance and toughness properties.Type: GrantFiled: February 6, 1997Date of Patent: July 28, 1998Assignee: The Dow Chemical CompanyInventors: Frank M. Hofmeister, Morgan M. Hughes, Hani Farah, Steve R. Ellebracht
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Patent number: 5760113Abstract: A floor polish composition comprising an aqueous emulsion which comprises as a copolymer having an average particle size of from 0.05 to 0.10 .mu.m and having a glass transition temperature of from 30.degree. to 50.degree. C. which is obtainable by polymerization of (A) to (C) described below in the presence of an alkylbenzenesulfonate containing an alkyl group having 10 to 16 carbon atoms in an amount of 0.5 to 2.5 parts by weight per 100 parts by weight of the total amount of (A) to (C):(A): 30 to 50% by weight of an aromatic vinyl compound,(B): 30 to 60% by weight of a (meth)acrylate, and(C): 10 to 20 % by weight of an .alpha., .beta.-ethylenically unsaturated carboxylic acid.Type: GrantFiled: September 30, 1996Date of Patent: June 2, 1998Assignee: Sumitomo Chemical Company, LimitedInventors: Tatsuo Mitsutake, Yuuzi Yoshii
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Patent number: 5760112Abstract: A water-borne autodepositing coating composition that has a pH of 1.6 to 5 and contains as essential components a water-dispersible or water-soluble organic coating-forming resin, a liquid dispersion of carbon black, acid, and oxidizing agent, and that may contain metal ions as an optional component, has an excellent storage stability and produces a strongly adherent and highly corrosion-resistant coating when the liquid dispersion of carbon black is an aqueous dispersion in which carbon black is dispersed using as a dispersant a naphthalenesulfonate-formaldehyde condensate.Type: GrantFiled: August 23, 1996Date of Patent: June 2, 1998Assignee: Henkel CorporationInventors: Mutsumi Hirota, Takumi Honda, Norifumi Hatano, Shoichi Sangenya, Shunjiro Saiki
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Patent number: 5747570Abstract: Water-absorbing resin compositions obtained by adding a water-soluble thiol compound in the process of drying or pulverizing a hydrogel of a water-absorbing resin which is obtained by polymerizing a water-soluble monomer having a polymerizable unsaturated group optionally with a polysaccharide, in the presence of a crosslinking agent and water. Composition of the present invention are highly efficient in water absorption and safe for having extremely low amounts of residual monomer and water-soluble component.Type: GrantFiled: October 4, 1995Date of Patent: May 5, 1998Assignee: Sanyo Chemical Industries, Ltd.Inventors: Masashi Date, Keiji Tanaka, Tsuyoshi Yuki, Kenjiro Tsubota, Satoshi Tamabuchi
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Patent number: 5721299Abstract: Electrically conductive and abrasion resistant polymeric compositions, methods of fabrication thereof and uses thereof are described. Admixtures of abrasion resistant materials and electrically conductive polymeric materials are formed. Many of these admixtures are light transmitting and can be used as an abrasion resistant light transmitting electrostatic discharge layers. The light transmitting discharge layer is useful as a surface coating for visual displays such as CRT screens to avoid electrostatic accumulation of dust and scratching.Type: GrantFiled: February 9, 1994Date of Patent: February 24, 1998Assignee: International Business Machines CorporationInventors: Marie Angelopoulos, Ali Afzali-Ardakani, Jack A. Dickerson, Thomas B. Pillsbury, Karl J. Puttlitz, Jane M. Shaw, Jeffrey D. Gelorme
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Patent number: 5714534Abstract: A resin composition having excellent antistatic properties is provided which comprises (A) 100 parts by weight of a styrene resin, (B) 3 to 35 parts by weight of a polyethylene oxide, (C) 0.1 to 10 parts by weight of a styrene-acrylonitrile-hydroxyalkyl acrylate copolymer and/or a styrene-acrylonitrile-hydroxyalkyl methacrylate copolymer, (D) 4 to 100 parts by weight of a (meth)acrylic ester polymer, and/or an oxide selected from the group consisting of titanium oxide, zinc oxide and magnesium oxide, the oxide being present in an amount of 0.7 to 5 parts by weight per 100 parts by weight of the combined amount of components (A) and (B), and (E) a surface-active agent comprising a specified sulfonic acid salt or alkylsulfuric acid salt, the surface-active agent being present in an amount of 0.4 to 5 parts by weight per 100 parts by weight of the combined amount of components (A), (B), (C) and (D). This resin composition can be used for general household articles including, for example, wardrobe cases.Type: GrantFiled: October 5, 1995Date of Patent: February 3, 1998Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Nobumoto Kojima, Kouzo Ichikawa, Hideo Amemiya, Shinji Okajima, Takayoshi Sekido, Mitsuyoshi Kato
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Patent number: 5712334Abstract: Disclosed are a lactone-modified polyvinyl alcohol and a process for the preparation thereof, a polymer composition, a permanently anti-electrostatic resin composition, a lactone-modified resin having hydroxyl groups, and a process for the preparation thereof. The lactone-modified polyvinyl alcohol can be used in wide fields owing to the capability of freely adjusting the water solubility, such as water-soluble, gradually water-soluble, low water-soluble, and water-insoluble by a degree modified by lactone compounds, and owing to possessing properties both of PVA and lactones. Furthermore, the lactone-modified polyvinyl alcohol has properties such as being plasticizers or softening agents, and as a result, there can be provided a polymer composition having excellent properties by mixing with a hydrophilic polymer or polar polymer.Type: GrantFiled: December 26, 1996Date of Patent: January 27, 1998Assignee: Daicel Chemical Industries, Ltd.Inventors: Kazushi Watanabe, Takaaki Fujiwa, Tomohisa Isobe, Hiroshi Sagane
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Patent number: 5698618Abstract: A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.Type: GrantFiled: July 18, 1996Date of Patent: December 16, 1997Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Takashi Kamikubo, Tadashi Itabashi, Masami Kuwahara
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Patent number: 5696187Abstract: A methyl methacrylate-styrene copolymer resin composition in the form of an optical sheet which comprises: (A) 100 parts by weight of a methyl methacrylate-styrene copolymer resin having a weight ratio of methyl methacrylate units to styrene units of 75:25 to 50:50, (B) 0.5 to 5 parts by weight of a lithium sulfonate having a C.sub.8 -C.sub.16 alkyl group, and (C) 0.3 to 1.5 parts by weight of glass beads, as a light diffuser. The methyl methacrylate-styrene copolymer resin composition in the form of an optical sheet of the present invention has excellent antistatic properties and appearance properties. By using the lithium sulfonate in the form of a solution, excellent light diffusion properties (without impaired dispersion properties), excellent total light transmittance and desired coloring properties can be obtained, and hence desirable optical properties and desirable physical properties and dimensional stability can be obtained.Type: GrantFiled: August 31, 1995Date of Patent: December 9, 1997Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yukio Kokuzawa, Yoshio Imae, Kazunobu Sato