Metal Patents (Class 524/161)
  • Publication number: 20040143046
    Abstract: This invention is directed to formation of a creped nonwoven web. The creped web is formed in a creping process using a polymer emulsion binder formed in an alkylphenol ethoxylate-free surfactant system. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.
    Type: Application
    Filed: January 6, 2004
    Publication date: July 22, 2004
    Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
  • Patent number: 6753367
    Abstract: The present invention relates to flame retardant polycarbonate compositions with improved weathering performance, said compositions comprising one or more cyanoacrylic esters. The invention also relates to methods for improving the flame retardancy and weathering performances of polycarbonate compositions by incorporating cyanoacrylic ester(s). Finally, the invention further relates to articles manufactured from flame retardant polycarbonate compositions comprising cyanoacrylic ester(s).
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: June 22, 2004
    Assignee: General Electric Company
    Inventors: Johannes Martinus Dina Goossens, Hendrik Verhoogt
  • Patent number: 6740697
    Abstract: A flame retardant thermoplastic molding composition is disclosed. The composition contains an amorphous thermoplastic polymer, at least one flame retardant in the form of a fully or partially halogenated sulfonic acid salt and at least on alkaline earth metal sulfate and/or one oxide having an average particle size of up to 400 nm.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: May 25, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Axel Brenner, Walter Köhler, Martin Döbler
  • Patent number: 6727302
    Abstract: A transparent, fire resistant polycarbonate composition comprises polycarbonate, poly(methylphenylsiloxane) and a salt based flame retardant. These polycarbonate compositions can attain UL94 V0 ratings at 1.6 millimeter thickness, previously possible only with a halogenated fire retardant.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: April 27, 2004
    Assignee: General Electric Company
    Inventors: Johannes M. D. Goossens, Bart P. G. Hendrix, Walter van der Heijden, Christianus J. J. Maas, Hendrik Verhoogt
  • Patent number: 6624242
    Abstract: An aqueous dispersion of (a) 0.1-40% by wt. of a low molecular weight, low melting point, water-insoluble polymer in which the polymer particles have a size <10 microns, and (b) 0.001-30% by wt. of an anionic emulsifier.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: September 23, 2003
    Assignee: ISP Investments Inc.
    Inventors: James F. Curry, Kolazi S. Narayanan, Ronald H. Goehner, Jr., Domingo I. Jon, George B. Beestman
  • Patent number: 6608115
    Abstract: Polyvinyl chloride resin compositions and methods of preparation and use thereof for increasing the degree of whiteness in finished polyvinyl chloride foam. The resin compositions contain sulfur compounds selected from sulfonic acid derivatives, sulfinic acid derivatives, and mercapto acetic acid sodium salt, and optionally contain water soluble salts and/or t-butyl hydroperoxide.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: August 19, 2003
    Assignee: Occidental Chemical Corporation
    Inventors: Michael T. Moran, Thomas E. Moses, Sherry Rohn Clancy
  • Patent number: 6605659
    Abstract: A thermoplastic resin composition contains an aromatic carbonate resin, a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and a flame retarding amount of an alkali metal or alkaline earth metal salt of an alkylbenzenesulfonic acid flame retardant.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: August 12, 2003
    Assignee: General Electric Company
    Inventors: Kirk J. Blackburn, Robert R. Gallucci, Emil M. Georgiev
  • Patent number: 6602938
    Abstract: This invention is a flame resistant polycarbonate resin composition characterized by blending 0.01-2 weight parts of a silicone compound (B)) wherein a main chain has a branch structure and having an aromatic group in an organic substituent, 0.01-2 weight parts of an alkali metal salt of an aromatic sulfonic acid (C) represented by the following general formula 1 (hereafter, referred to as general formula 1), and 0.05-5 weight parts of a fiber-forming fluorine-containing polymer (D), relative to 100 parts of a polycarbonate resin (A): General formula 1: Am—R—(SO3M)n (wherein, R is a phenyl group, naphthyl group, or a phenyl group or naphthyl group substituted by A, where A is at least one type of substituent chosen from a group comprising a halogen atom, alkyl group, aryl group, vinyl group, alkoxy group, amino group, methyl ester group and ethyl ester group, and M is an alkali metal.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: August 5, 2003
    Assignees: Sumitomo Dow Ltd., NEC Corp.
    Inventors: Masatoshi Iji, Shin Serizawa, Satoshi Umeyama, Tadashi Shinomiya, Ichiro Sato
  • Publication number: 20030114561
    Abstract: This invention is directed an alkylphenol ethoxylate-free surfactant system for preparation of polymer emulsions. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.
    Type: Application
    Filed: December 19, 2001
    Publication date: June 19, 2003
    Applicant: Air Products Polymers, L.P.
    Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
  • Publication number: 20030065072
    Abstract: The invention relates to a process to make stabilized PVC wherein use is made of at least one compound of the formula 1
    Type: Application
    Filed: August 6, 2002
    Publication date: April 3, 2003
    Inventors: Daniel Stephan Van Es, Jacco Van Haveren, Augustinus Emmanuel Frissen, Johannes Cornelis Van Der Kolk, Gerard Hubert Frans Schmets, Hendrik Willem Huisman, Heather Blue Harvey
  • Patent number: 6518357
    Abstract: A flame retardant polycarbonate composition includes (A) at least one polycarbonate and (B) a silsesquioxane flame retardant. The flame retardant polycarbonate composition can be made by providing a polycarbonate and incorporating a flame retardant amount of a silsesquioxane into the polycarbonate. An article can be molded from the composition.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: February 11, 2003
    Assignee: General Electric Company
    Inventors: Padmavathy Rajagopalan, John Robert Campbell, Larry Neil Lewis
  • Patent number: 6489042
    Abstract: An electronic circuit device comprising at least one substrate having a photoimageable covercoat, comprising at least 95 weight percent of at least one epoxy-modified aromatic vinyl-conjugated diene block copolymer and a catalyst comprising an onium salt selected from a triarylsulfonium salt and a diaryliodonium salt, wherein the covercoat is formed by solvent coating or extrusion and then heat laminated onto at least a portion of the substrate.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: December 3, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Ronald L. Imken, Robert S. Clough
  • Patent number: 6476099
    Abstract: A joint compound composition comprising a filler, a binder and a hydrocarbon substituted sulfate, sulfonate, sulfuric acid or sulfonic acid is disclosed. The composition of the present invention produces a joint compound that shrinks less and is resistant to cracking and cratering.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: November 5, 2002
    Assignee: United States Gypsum Company
    Inventors: Scott D. Cimaglio, Frank A. Wawrzos, Charles J. Miller
  • Publication number: 20020120043
    Abstract: The invention concerns well dispersible powders on the basis of carboxylated copolymers containing butadiene made of styrene and/or acrylonitrile, whose films taken from redispersion show good tensile strength. According to the invention, the latices are sprayed with mixtures of spraying aids consisting of 1 to 15 weight % of a salt of the alkylated di-phenyl-ether-di-sulphonic acid, caseinate and/or N-alkyl sulphosuccinamide and/or with 1 to 20 weight % of a di- or tetra sodium or potassium salt of an addition product from N-alkyl sulphosuccinamates with maleic acid mixed together with polyvinyl alcohol. The dispersions can be used especially in the construction industry and they offer an alternative to copolymers on the basis of polyvinyl acetates and acrylates.
    Type: Application
    Filed: September 24, 1998
    Publication date: August 29, 2002
    Inventors: BERND ROTHENHAUSSER, VOLKER KIESEL, HARTMUT KUHN, DOMINIK ELSASSER
  • Publication number: 20020120044
    Abstract: A thermoplastic resin composition contains an aromatic carbonate resin, a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and a flame retarding amount of an alkali metal or alkaline earth metal salt of an alkylbenzenesulfonic acid flame retardant.
    Type: Application
    Filed: December 20, 2000
    Publication date: August 29, 2002
    Applicant: General Electric Company
    Inventors: Kirk J. Blackburn, Robert R. Gallucci, Emil M. Georgiev
  • Publication number: 20020115762
    Abstract: The polycarbonate resin composition having good reflectance and impact strength according to the present invention comprises (A) about 100 parts by weight of a thermoplastic polycarbonate resin as a base resin, (B) about 2-20 parts by weight of titanium dioxide, (C) about 0.01-5 parts by weight of at least one sulfone sulfonate salt, and optionally (D) about 0-30 parts by weight of an impact modifier and optionally (E) about 0-30 parts by weight of a vinyl copolymer, and optionally (F) about 0-1.0 parts by weight of a stilbene-bisbenzoxazole derivative.
    Type: Application
    Filed: December 21, 2001
    Publication date: August 22, 2002
    Applicant: CHEIL INDUSTRIES, INC.
    Inventors: Han-Soo Chung, Hee-Goo Yea
  • Patent number: 6423367
    Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: July 23, 2002
    Assignee: 3M Innovative Properties Company
    Inventor: Robert Steven Clough
  • Patent number: 6342550
    Abstract: The purpose of the present invention is to provide a flame-retardant polycarbonate resin composition which contains phosphorus-free flame-retardant(s), has an excellent impact resistance, an excellent heat resistance as well as an excellent moldability, and can satisfy a severe flammability level. According to the present invention, there is provided a flame-retardant polycarbonate resin composition which comprises (A) 100 parts by weight of an aromatic polycarbonate resin, (B) 0.01-5 parts by weight of an organic sulfonic acid metal salt, (C) 0.01-5 parts by weight of a fluorinated polyolefin, (D) 0.2-20 parts by weight of a diene-containing multi-layered polymer, and wherein the content of a phosphorus-containing flame-retardant is less than 0.5 parts by weight.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: January 29, 2002
    Assignee: Mitsubishi Engineering Plastics Corporation
    Inventors: Kazuhiko Ishii, Ken Shimomai
  • Patent number: 6329450
    Abstract: The present invention relates to a blend of polymeric materials comprising; (A) of from about 1 to about 80 percent by weight (based on the combined weights of Components A and B) of at least one substantially random interpolymer; wherein said interpolymer; (1) contains of from about 0.5 to about 50 mole percent of polymer units derived from; a) at least one vinyl or vinylidene aromatic monomer, or b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or c) a combination of at least one vinyl or vinylidene aromatic monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer; (2) contains of from about 50 to about 99.5 mole percent of polymer units derived from at least one aliphatic &agr;-olefin having from 2 to 20 carbon atoms; (3) has a melt index (I2) of from about 0.01 to about 100 g/10 min; and (4) has a molecular weight distribution (Mw/Mn) of from about 1.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: December 11, 2001
    Assignee: The Dow Chemical Company
    Inventors: Samuel A. Ogoe, Charles F. Diehl, Leo A. Novak, Wendy D. Hoenig, Shaofu Wu, Donna C. Scott
  • Publication number: 20010049430
    Abstract: A water slurry process is used to prepare a prepreg and to manufacture articles from macrocyclic polyester oligomers. In one embodiment, a process for preparing a water suspension of macrocyclic polyester oligomers includes the steps of contacting a macrocyclic polyester oligomer and a polymerization catalyst with water and a surfactant, and mixing the macrocyclic polyester oligomer and polymerization catalyst with water and the surfactant thereby forming a suspension. In another embodiment, a process for impregnating macrocyclic polyester oligomers for polymerization includes the steps of providing a suspension of a macrocyclic polyester oligomer and a polymerization catalyst in water, applying the suspension to a base material, drying to remove water from the suspension, and pressing the dried suspension to a desired form. In yet another embodiment, a composition of macrocyclic polyester oligomer includes a macrocyclic polyester oligomer, a polymerization catalyst, and water.
    Type: Application
    Filed: January 4, 2001
    Publication date: December 6, 2001
    Inventors: Steven J. Winckler, Tohru Takekoshi
  • Patent number: 6322624
    Abstract: The reaction product of at least one polyanhydride and at least one amine is disclosed. A phase change ink composition and a phase change ink containing the polyanhydride/amine adduct are also disclosed.
    Type: Grant
    Filed: February 12, 1999
    Date of Patent: November 27, 2001
    Assignee: Xerox Corporation
    Inventors: Donald R. Titterington, Jeffery H. Banning, Clifford R. King
  • Patent number: 6310124
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: October 30, 2001
    Assignee: Cytec Technology, Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 6294270
    Abstract: An electronic circuit device comprises a resin composition including 90 to 100 weight percent of a curable epoxy-modified aromatic vinyl-conjugated diene block copolymer, optionally up to 10 weight percent of an epoxy resin, and an effective amount of an epoxy curative, the weight percent of the copolymer and epoxy resin being based on the weight of the epoxy bearing material exclusive of curative. The resin composition can be used as an electronic adhesive, covercoat, or encapsulant. The electronic circuit device exhibits superior heat and moisture insensitivity, including the absence of voiding and delamination of the cured resin compostion from its substrate under conditions of 85° C. and 85% relative humidity for 168 hours followed by a temperature of 220° C. for 10 to 40 seconds.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: September 25, 2001
    Assignee: 3M Innovative Properties Company
    Inventor: Robert Steven Clough
  • Patent number: 6284823
    Abstract: Acrylic resin compositions having excellent antistaticity, good appearance and superior optical properties made by blending (A) 100 parts by weight of an acrylic resin; (B) a phosphonium sulfonate consisted of organic sulfonate anion and organic phosphonium cation; (C) a lithium benzenesulfonate; and (D) 0.05 to 2.0 parts by weight of a fatty acid ester and/or amide, wherein (B)/(C) is 2/8 to 8/2 by weight and (B) plus (C) is 0.2 to 2.5 parts by weight.
    Type: Grant
    Filed: July 8, 1998
    Date of Patent: September 4, 2001
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yukio Kokuzawa, Kazunobu Sato
  • Publication number: 20010009942
    Abstract: A suspending agent-containing slurry is disclosed which comprises a dispersant and a particulate suspending agent having a particle size distribution in which the particle diameter at weight-cumulative 95%, from the minimum particle size, is 1 &mgr;m or smaller. A method for efficiently producing the suspending agent-containing slurry is also disclosed. A process for suspension polymerization by use of the suspending agent-containing slurry is further disclosed. The slurry not only has such an excellent suspending ability in suspension polymerization that it enables the production of vinyl polymer beads having a narrow bead size distribution, but also is capable of retaining this ability over long and of exhibiting the same ability even when it has a high concentration. The suspension polymerization process enables vinyl polymer beads having a narrow bead size distribution to be produced efficiently due to the use of the slurry.
    Type: Application
    Filed: October 16, 1998
    Publication date: July 26, 2001
    Inventors: MITSUSHI MURATA, TSUNENORI TAKAHASHI, YUKIO KATO
  • Patent number: 6235821
    Abstract: The invention provides thermoplastic resin compositions for purging which comprise a thermoplastic resin and a methyl methacrylate/styrene copolymer incorporated therein. According to the invention, thermoplastic resin compositions for purging molding machines, which have an excellent cleaning ability, can be obtained.
    Type: Grant
    Filed: December 8, 1999
    Date of Patent: May 22, 2001
    Assignee: Chisso Corporation
    Inventor: Takanori Saito
  • Patent number: 6232381
    Abstract: The process of this invention can be utilized to stabilize tin-coupled rubbery polymers. This process involves adding a chelating diamine or a sodium alkoxide to the rubbery polymer after the tin coupling has been carried out. This invention more specifically discloses a process for improving the stability of a tin-coupled rubbery polymer which comprises adding a sodium alkoxide to the tin-coupled rubbery polymer subsequent to the time at which the tin-coupled rubbery polymer is coupled. Sodium alkoxide is a representative example of a sodium alkoxide that can be used to stabilize the tin-coupled rubbery polymer.
    Type: Grant
    Filed: July 30, 1999
    Date of Patent: May 15, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Wen-Liang Hsu, Adel Farhan Halasa
  • Patent number: 6180702
    Abstract: A thermoplastic molding composition comprising polycarbonate resin and additive, positive, amounts of stabilizer and salt is disclosed. The composition is characterized by its freedom from splay and by its improved flame retardance. The stabilizer of the invention is a physical mixture of poly(alkyl methacrylate) with fluorinated polyolefin, and the salt is an alkali metal or alkaline earth metal salt of perfluoroalkane sulfonic acid, aromatic sulfimide, or aromatic sulfonic acid.
    Type: Grant
    Filed: August 9, 1999
    Date of Patent: January 30, 2001
    Assignee: Bayer Corporation
    Inventors: James Y. J. Chung, Sivaram Krishnan, Winfried G. Paul
  • Patent number: 6177511
    Abstract: Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.
    Type: Grant
    Filed: January 25, 1999
    Date of Patent: January 23, 2001
    Assignee: Wacker-Chemie GmbH
    Inventors: Jochen Dauth, Bernward Deubzer, Robert Schröck, Petra Gratzl
  • Patent number: 6150443
    Abstract: Provided are a flame-retardant polycarbonate resin composition capable of being formed into moldings having good impact resistance, high strength and good thermal stability that are intrinsic to polycarbonate resins and having good antistatic properties and good flame retardancy, and also injection moldings of the composition. The composition comprises 100 parts by weight of a resin or resin mixture of (A) from 50 to 100% by weight of a polycarbonate resin and (B) from 0 to 50% by weight of a styrenic resin, from 1 to 50 parts by weight of (C) a flame retardant, and from 0.1 to 5 parts by weight of (D) an anionic antistatic agent, and has a sodium sulfate content of at most 0.05% by weight. Optionally, the composition may contain (F) a fluoro-olefinic resin, (G) a rubber-like elastomer, and (H) an inorganic filler.
    Type: Grant
    Filed: August 9, 1999
    Date of Patent: November 21, 2000
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Akio Nodera, Naoki Mitsuta
  • Patent number: 6121351
    Abstract: Thermoplastic compositions containing certain anthraquinone polysulfonamide colorants incorporated therein as toners or colorants. The anthraquinone colorant moieties which are incorporated into the polymer chain of the polysulfonamide colorants are not leachable, sublimable or extractable and do not exude from the thermoplastic compositions. The anthraquinone polysulfonamide colorants may be added to the thermoplastic polymers during production or melt blended with the polymer by conventional techniques to produce transparent thermoplastic compositions useful for a variety of end uses where nonmigrating or nonextractable colorants are needed.
    Type: Grant
    Filed: August 7, 1997
    Date of Patent: September 19, 2000
    Assignee: Eastman Chemical Company
    Inventors: Max Allen Weaver, Wayne Payton Pruett, Kay Hunt Shackelford, Samuel David Hilbert
  • Patent number: 6037055
    Abstract: New copolyester composition that provides excellent filament spinning and mill/yarn processing of staple fiber into fabrics having combination of excellent pilling performance as well as aesthetics and tactility ("hand"). Preferred fibers have non-round cross-sections, especially multi-grooved and scalloped-oval cross-sections that provide fabrics having outstanding comfort qualities of moisture-management, dryness and comfort, as well as minimal pilling.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: March 14, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Arun Pal Aneja, Frederick Karl Mallon, Adrian Charles Snyder
  • Patent number: 6031036
    Abstract: Disclosed are aromatic brominated polycarbonate/polyester carbonate/silicone polyimide compositions having improved flame resistance and reduced drippage and heat release rate, comprising by weight:(A) from about 20 to about 77 parts of an aromatic brominated polycarbonate resin;(B) from about 20 to about 77 parts of a polyester carbonate resin;(C) from about 0.5 to about 10 parts of a silicone-polyimide resin;(D) from about 0 to about 25 parts of an aromatic polycarbonate having a molecular weight of from about 40,000 to about 90,000; the sum of (A)-(D) being 100 parts by weight;(E) from about 0.05 to about 2.0 parts of a metal salt of a halogenated monomeric or polymeric aromatic sulfonic acid or mixtures thereof, wherein the metal salt is selected from the group consisting of alkali metal salts, alkaline earth metal salts, and mixtures of the metal salts; and(F) from about 0.1 to about 5.0 parts by weight of filler or a pigment.
    Type: Grant
    Filed: December 10, 1993
    Date of Patent: February 29, 2000
    Assignee: General Electric Company
    Inventors: Niles Richard Rosenquist, Angelika Howard Clark
  • Patent number: 6013708
    Abstract: Compositions of precipitated cationic polymers containing mixtures of certain salts as well as processes for making and using the same are disclosed.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: January 11, 2000
    Assignee: Cytec Technology Corp.
    Inventors: Joseph J. Mallon, Raymond S. Farinato, Louis Rosati, John J. Freeman, Jr.
  • Patent number: 5985966
    Abstract: An aqueous emulsion of fluorine-containing polymer according to the present invention contains an emulsion stabilizer represented by the formula:R--Ph--O--(CH.sub.2 CH.sub.2 O).sub.n --CH.sub.2 CH.sub.2 --SO.sub.3 M(Ph is a phenyl radical; R is an alkyl radical having 8-12 carbon atoms; n is a number of 1-6; and M is Na, K or NH.sub.4). The resulting emulsion has excellent mechanical stabilities and thermal stabilities as well as decreased possibility of causing ground water contamination.
    Type: Grant
    Filed: February 16, 1996
    Date of Patent: November 16, 1999
    Assignee: Du Pont - Mitsui Fluorochemicals Co., Ltd.
    Inventors: Masatsune Ogura, Shizuo Chiba
  • Patent number: 5936007
    Abstract: The present invention provides polycarbonate moulding compositions containing polycarbonates, stabilisers of the general formula (I)R.sub.1 --X--(CHR.sub.4).sub.n --Y--R.sub.2and optionally polypropylene glycols.The present invention also provides use of these moulding compositions for preparing items for medical applications.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: August 10, 1999
    Assignee: Bayer AG
    Inventors: Wolfgang Ebert, Ralf Hufen, Heidemarie Pantke, Klaus Berg
  • Patent number: 5919854
    Abstract: Aqueous dispersions of cationic water-soluble polymers are provided, as well as processes for making and methods of using the same.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: July 6, 1999
    Assignee: Cytec Technology Corp.
    Inventors: Sun-Yi Huang, Louis Rosati, Joseph J. Kozakiewicz
  • Patent number: 5882780
    Abstract: Elastic polyester fibers having a high anti-cohesive property (separability) include (A) a polyester elastomer and (B) 0.2 to 10%, based on the weight of the elastomer, of an anti-cohesive agent including (a) at least one alkali metal salt of organic sulfonic acid of the formula: R.sup.1 --S0.sub.3 M, wherein R.sup.1 =C.sub.5-25 hydrocarbon group, M=alkali metal, and (b) at least one compound of the formulae (2)-(6): R.sup.2 --X.sub.p --CH.sub.2 CH.sub.2 OH (2), R.sup.3 --COO--CH.sub.2 CH(OH)CH.sub.2 OH (3), R.sup.4 --COO--(CH.sub.2 CH.sub.2 O).sub.m --H (4), R.sup.5 --O--(CH.sub.2 CH.sub.2 O).sub.n H (5) and R.sup.6 --CONHCH.sub.2 CH.sub.2 NHCO--R.sup.7 (6), wherein R.sup.2 -R.sup.7 =C.sub.5-25 hydrocarbon group, X=--CONY or ##STR1## group, p=0 or 1, m, n=5 to 50.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: March 16, 1999
    Assignee: Teijin Limited
    Inventors: Yasuo Yamamura, Mikio Tashiro, Yasuyuki Yamazaki, Takeshi Honjou, Nobuyuki Yamamoto, Michihiro Yamada
  • Patent number: 5847030
    Abstract: A process for the preparation of polymer latex particles by conducting a pre-reaction emulsification with monomer, polar comonomer, water, surfactant, chain transfer agent, and initiator; and which pre-reaction emulsification is effected at a low temperature of from about 3.degree. C. to about 35.degree. C., for example, and thereafter, effecting emulsion polymerization by heating the aforementioned emulsified mixture in a reactor at a temperature of from about 25.degree. C. to about 125.degree. C. The aforementioned reactor contents are retained at this temperature, that is 25.degree. C. to 125.degree. C. for an effective time period. Thereafter, the reaction mixture is cooled.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: December 8, 1998
    Assignee: Xerox Corporation
    Inventors: Hadi K. Mahabadi, Grazyna E. Kmiecik-Lawrynowicz, T. Hwee Ng
  • Patent number: 5840789
    Abstract: The present invention relates to aqueous compositions having pH of less than or equal to about 11 and which contain a thickening amount of an acrylate-based rheology modifier, which modifier contains an emulsion which is prepared by single-stage emulsion polymerization of a C.sub.2 -C.sub.6 alkyl ester of acrylic acid and/or a C.sub.1 -C.sub.6 alkyl ester of methacrylic acid, a monomer chosen from a vinyl-substituted heterocyclic compound containing at least one of a nitrogen or sulfur atom, (meth)acrylamide, a mono- or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylate, a mono or di-(C.sub.1 -C.sub.4)alkylamino (C.sub.1 -C.sub.4)alkyl (meth)acrylamide, and optionally cross-linking monomers and/or associative monomers, in the presence of water, a first surfactant, a free-radical initiator and an alcohol selected from C.sub.2 -C.sub.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: November 24, 1998
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Daniel W. Verstrat, Milagros C. Barron
  • Patent number: 5789471
    Abstract: A polyvinyl chloride (PVC) composition includes an active fluorescence or phosfluorescence inducing agent which causes the composition to emit a brighter or hotter appearing light, as compared to conventional PVC compositions, when exposed to white light. In one form, the PVC composition includes barium diphenylaminesulfonate as an additive in a clear or transparent composition and light passing through the composition appears to be hotter than the impinging light. In another form, the additive is barium carbonate and the PVC includes a tinting agent to induce a colored glow when exposed to white light. In all forms, the fluorescence or phosfluorescence inducing agent is selected from a class of materials having the characteristics of creating a compound having an outer electron shell which will permit an electron shift between shells when exposed to light.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: August 4, 1998
    Assignee: Super Vision International, Inc.
    Inventor: Jack Caruso
  • Patent number: 5786424
    Abstract: A blend of polycarbonate and a homogeneously branched, linear ethylene polymer, which blend has a desirable balance of impact resistance and toughness properties.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: July 28, 1998
    Assignee: The Dow Chemical Company
    Inventors: Frank M. Hofmeister, Morgan M. Hughes, Hani Farah, Steve R. Ellebracht
  • Patent number: 5760113
    Abstract: A floor polish composition comprising an aqueous emulsion which comprises as a copolymer having an average particle size of from 0.05 to 0.10 .mu.m and having a glass transition temperature of from 30.degree. to 50.degree. C. which is obtainable by polymerization of (A) to (C) described below in the presence of an alkylbenzenesulfonate containing an alkyl group having 10 to 16 carbon atoms in an amount of 0.5 to 2.5 parts by weight per 100 parts by weight of the total amount of (A) to (C):(A): 30 to 50% by weight of an aromatic vinyl compound,(B): 30 to 60% by weight of a (meth)acrylate, and(C): 10 to 20 % by weight of an .alpha., .beta.-ethylenically unsaturated carboxylic acid.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: June 2, 1998
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tatsuo Mitsutake, Yuuzi Yoshii
  • Patent number: 5760112
    Abstract: A water-borne autodepositing coating composition that has a pH of 1.6 to 5 and contains as essential components a water-dispersible or water-soluble organic coating-forming resin, a liquid dispersion of carbon black, acid, and oxidizing agent, and that may contain metal ions as an optional component, has an excellent storage stability and produces a strongly adherent and highly corrosion-resistant coating when the liquid dispersion of carbon black is an aqueous dispersion in which carbon black is dispersed using as a dispersant a naphthalenesulfonate-formaldehyde condensate.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: June 2, 1998
    Assignee: Henkel Corporation
    Inventors: Mutsumi Hirota, Takumi Honda, Norifumi Hatano, Shoichi Sangenya, Shunjiro Saiki
  • Patent number: 5747570
    Abstract: Water-absorbing resin compositions obtained by adding a water-soluble thiol compound in the process of drying or pulverizing a hydrogel of a water-absorbing resin which is obtained by polymerizing a water-soluble monomer having a polymerizable unsaturated group optionally with a polysaccharide, in the presence of a crosslinking agent and water. Composition of the present invention are highly efficient in water absorption and safe for having extremely low amounts of residual monomer and water-soluble component.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: May 5, 1998
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Masashi Date, Keiji Tanaka, Tsuyoshi Yuki, Kenjiro Tsubota, Satoshi Tamabuchi
  • Patent number: 5721299
    Abstract: Electrically conductive and abrasion resistant polymeric compositions, methods of fabrication thereof and uses thereof are described. Admixtures of abrasion resistant materials and electrically conductive polymeric materials are formed. Many of these admixtures are light transmitting and can be used as an abrasion resistant light transmitting electrostatic discharge layers. The light transmitting discharge layer is useful as a surface coating for visual displays such as CRT screens to avoid electrostatic accumulation of dust and scratching.
    Type: Grant
    Filed: February 9, 1994
    Date of Patent: February 24, 1998
    Assignee: International Business Machines Corporation
    Inventors: Marie Angelopoulos, Ali Afzali-Ardakani, Jack A. Dickerson, Thomas B. Pillsbury, Karl J. Puttlitz, Jane M. Shaw, Jeffrey D. Gelorme
  • Patent number: 5714534
    Abstract: A resin composition having excellent antistatic properties is provided which comprises (A) 100 parts by weight of a styrene resin, (B) 3 to 35 parts by weight of a polyethylene oxide, (C) 0.1 to 10 parts by weight of a styrene-acrylonitrile-hydroxyalkyl acrylate copolymer and/or a styrene-acrylonitrile-hydroxyalkyl methacrylate copolymer, (D) 4 to 100 parts by weight of a (meth)acrylic ester polymer, and/or an oxide selected from the group consisting of titanium oxide, zinc oxide and magnesium oxide, the oxide being present in an amount of 0.7 to 5 parts by weight per 100 parts by weight of the combined amount of components (A) and (B), and (E) a surface-active agent comprising a specified sulfonic acid salt or alkylsulfuric acid salt, the surface-active agent being present in an amount of 0.4 to 5 parts by weight per 100 parts by weight of the combined amount of components (A), (B), (C) and (D). This resin composition can be used for general household articles including, for example, wardrobe cases.
    Type: Grant
    Filed: October 5, 1995
    Date of Patent: February 3, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Nobumoto Kojima, Kouzo Ichikawa, Hideo Amemiya, Shinji Okajima, Takayoshi Sekido, Mitsuyoshi Kato
  • Patent number: 5712334
    Abstract: Disclosed are a lactone-modified polyvinyl alcohol and a process for the preparation thereof, a polymer composition, a permanently anti-electrostatic resin composition, a lactone-modified resin having hydroxyl groups, and a process for the preparation thereof. The lactone-modified polyvinyl alcohol can be used in wide fields owing to the capability of freely adjusting the water solubility, such as water-soluble, gradually water-soluble, low water-soluble, and water-insoluble by a degree modified by lactone compounds, and owing to possessing properties both of PVA and lactones. Furthermore, the lactone-modified polyvinyl alcohol has properties such as being plasticizers or softening agents, and as a result, there can be provided a polymer composition having excellent properties by mixing with a hydrophilic polymer or polar polymer.
    Type: Grant
    Filed: December 26, 1996
    Date of Patent: January 27, 1998
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Kazushi Watanabe, Takaaki Fujiwa, Tomohisa Isobe, Hiroshi Sagane
  • Patent number: 5698618
    Abstract: A coating composition is formed from an acid-set coating varnish and a pigment composition. The pigment composition includes a specific organic dyestuff derivative and a specific basic-group-containing resin-type pigment dispersant. The coating composition excels in pigment dispersibility, nonflocculation properties, noncrystallizability and fluidity. When used as a coating, the coating composition has excellent color tone, gloss, hardness, weather resistance, and solvent resistance.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: December 16, 1997
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Takashi Kamikubo, Tadashi Itabashi, Masami Kuwahara
  • Patent number: 5696187
    Abstract: A methyl methacrylate-styrene copolymer resin composition in the form of an optical sheet which comprises: (A) 100 parts by weight of a methyl methacrylate-styrene copolymer resin having a weight ratio of methyl methacrylate units to styrene units of 75:25 to 50:50, (B) 0.5 to 5 parts by weight of a lithium sulfonate having a C.sub.8 -C.sub.16 alkyl group, and (C) 0.3 to 1.5 parts by weight of glass beads, as a light diffuser. The methyl methacrylate-styrene copolymer resin composition in the form of an optical sheet of the present invention has excellent antistatic properties and appearance properties. By using the lithium sulfonate in the form of a solution, excellent light diffusion properties (without impaired dispersion properties), excellent total light transmittance and desired coloring properties can be obtained, and hence desirable optical properties and desirable physical properties and dimensional stability can be obtained.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: December 9, 1997
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yukio Kokuzawa, Yoshio Imae, Kazunobu Sato