At Least One Sulfur Atom Patents (Class 524/179)
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Patent number: 8575250Abstract: This invention relates to the thermal stabilization of halogen-containing polymer compositions, more particularly, this invention relates to a poly(vinyl chloride) (PVC) or a chlorinated polyvinyl chloride (cPVC) composition comprising a methyl tin stabilizer and at least one salt of a polyacid material such as a polycarboxylic acid, a phosphoric acid, or a boric acid.Type: GrantFiled: March 26, 2010Date of Patent: November 5, 2013Assignee: Rohm and Haas CompanyInventors: Bahar Azimipour, Jian-Yang Cho, Eric G. Lundquist, Gene Norris
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Patent number: 8062709Abstract: A process for preparing polyurethane carpet backings uses a filled polyurethane-forming composition that contains a mixture of certain metal acetylacetonate and sulfur-containing organotin catalysts. The mixture of catalysts is particularly beneficial in instances where the composition is processed at temperatures of above 30 to about 500 C, as long pot life is provided together with a rapid thermally-induced cure.Type: GrantFiled: March 19, 2007Date of Patent: November 22, 2011Assignee: Dow Global Technologies LLCInventor: Randall C. Jenkines
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Publication number: 20110166268Abstract: The present invention relates to high purity monoalkyltin compounds, more specifically to alkyltin compound compositions containing monoalkyltin as major compound, and minor quantities of di- and/or trialkyltin compounds. The present invention also relates to the preparation processes of such high purity monoalkyltin compounds, as well as to the uses of said monoalkyltin compounds as chlorine-containing polymer-stabilisers, glass coating chemicals and catalysts, as well as articles comprising at least one polymer matrix and a high purity monoalkyltin compound.Type: ApplicationFiled: May 14, 2009Publication date: July 7, 2011Applicant: ARKEMA FRANCEInventors: Berth Jan Deelman, Jeroen J.M. de Pater, Evert J. Saman, Isabelle Tartarin
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Publication number: 20100267873Abstract: This invention relates to the thermal stabilization of halogen-containing polymer compositions, more particularly, this invention relates to a poly(vinyl chloride) (PVC) or a chlorinated polyvinyl chloride (cPVC) composition comprising a methyl tin stabilizer and at least one salt of a polyacid material such as a polycarboxylic acid, a phosphoric acid, or a boric acid.Type: ApplicationFiled: March 26, 2010Publication date: October 21, 2010Inventors: Bahar Azimipour, Jian-Yang Cho, Eric G. Lundquist, Gene Norris
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Publication number: 20100190902Abstract: Disclosed herein are compounds of the formula: (R)x—Sn—(R?)4-x wherein x is 1 or 2; R is alkyl of from 1 to 12 carbon atoms; and R? is a moiety selected from the group consisting of: and mixtures thereof, wherein y is 1, 2, 3, or 4; and z is 1, 2, 3, or 4, and processes for forming such compounds. The compounds are excellent stabilizers for halogen-containing resins, such as PVC.Type: ApplicationFiled: January 27, 2009Publication date: July 29, 2010Applicant: Chemtura CorporationInventor: Edward Krainer
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Patent number: 7479513Abstract: The method of at least one thermally expandable graphite intercalation compound, containing A) a least one metal halide of at least one of the elements Fe, Al, Sb, Zn, Y, Cr and Ni and B) at least one nitroalkane of the general formula CH3(CH2)nNO2, in which n is a whole number from 0 to 10, as well as its structural isomers or mixtures, as intumescing, fire-protection additive in polymer matrices for producing intumescing fire-protective seals for through holes, wall bushings and other openings in walls, floors and/or ceilings of buildings, as well as a method for preparing the thermally expandable graphite-intercalation compounds used.Type: GrantFiled: June 16, 2004Date of Patent: January 20, 2009Assignee: Hilti AktiengesellschaftInventors: Arne Reinheimer, Antje Wenzel, Herbert Muenzenberger
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Patent number: 7132467Abstract: Polyolefin mouldings that have excellent stability on permanent contact with chlorinated water comprise, as stabilizer, at least a compound selected from the group consisting of i) an epoxidized fatty acid having 3 to 22 carbon atoms or an aklyl ester thereof having 1 to 18 carbon atoms; and/or ii) an organotin compound; and/or iii) a compound containing at least one radical of the formula A or B.Type: GrantFiled: January 23, 2003Date of Patent: November 7, 2006Assignee: Ciba Specialty Chemicals Corp.Inventors: Erich Kramer, Alfred Georges Oertli, Markus Grob
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Patent number: 6846861Abstract: A pleasant fragrance is imparted to the stabilizatiin of a halogen-containing polymer by the use of an organotin mercaptoalkyl heptanoate, and, optionally, up to about 50%, on an equivalents basis, of a sulfide thereof as the stabilizer. A mixture of the heptanoate with up to about 80% by weight of the mixture of a second carboxylate having from 8 to 20 carbon atoms in the carboxylate moiety may be used in place of the heptanoate.Type: GrantFiled: September 29, 2001Date of Patent: January 25, 2005Assignee: Rohm and Haas CompanyInventors: Bruce C. Herzig, Gary M. Conroy, Paul B. Adams, Michael E. Skladani, Gene K. Norris
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Patent number: 6617376Abstract: A flexible wood composition comprising at least one cellulosic filler and a material selected from the group consisting of thermoplastic elastomers and melt-processible rubbers. Additionally, the composition may include other ingredients including, but not limited to, a stabilizer, a lubricant, and a fatty acid. The composition can be used to make a variety of components such as flooring, gaskets, stair treads, weather stripping, hinges, sound absorption components, trim, seals, grips, surface treatment for various surfaces, bumpers, toys, buttons, and tubing.Type: GrantFiled: March 30, 2001Date of Patent: September 9, 2003Assignee: Crane Plastics Company LLCInventor: Arthur F. Korney, Jr.
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Publication number: 20030166752Abstract: The present invention relates to a halogen containing polymer compound containing a modified zeolite stabilizer. The modified zeolite stabilizer has a small particle diameter, narrow particle size distribution and less than 10 weight percent water. The modified zeolite stabilizer is formed by shock annealing, coating or a combination of the two methods.Type: ApplicationFiled: March 7, 2003Publication date: September 4, 2003Applicant: Noveon IP Holdings Corp.Inventors: Robert E. Detterman, Nancy A. Hamerly, Carole A. Lepilleur, Anthony M. Mazany, David L. Milenius, Arthur L. Backman
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Publication number: 20030134946Abstract: Disclosed is a rubber composition for forming a core of a solid golf ball, the composition containing a base rubber (A); a filler (B); an organic peroxide (C); and a dry blend and/or a solvent slurry blend (D) of an unsaturated carboxylic acid metallic salt and a metal-containing organic sulfur compound represented by the following formula (1): 1Type: ApplicationFiled: November 25, 2002Publication date: July 17, 2003Applicant: BRIDGESTONE SPORTS CO., LTD.Inventor: Nobuyuki Kataoka
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Patent number: 6531526Abstract: The present invention relates to a halogen containing polymer compound containing a modified zeolite stabilizer. The modified zeolite stabilizer has a small particle diameter, narrow particle size distribution and less than 10 weight percent water. The modified zeolite stabilizer is formed by shock annealing, coating or a combination of the two methods.Type: GrantFiled: March 9, 2000Date of Patent: March 11, 2003Assignee: Noveon IP Holdings Corp.Inventors: Robert E. Detterman, Nancy A. Hamerly, Carole A. Lepilleur, Anthony M. Mazany, David L. Milenius, Arthur L. Backman
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Patent number: 6531533Abstract: Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.Type: GrantFiled: February 12, 1997Date of Patent: March 11, 2003Assignee: Crompton Vinyl Additives GmbHInventors: Karl Josef Kuhn, Wolfgang Wehner, Rolf Drewes
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Publication number: 20020035179Abstract: A pleasant fance is imparted to the stabiliztim of a halogencontamng polymer by the use of an organotin mercaptoalkyl heptanoate, and, optionally, up to about 50%, on an equivalents basis, of a sulfide thereof as the stabilizer. A mitre of the heptanoate with up to about 80% by weight of the mire of a second carboxylate having from 8 to 20 carbon atoms in the carboxylate moiety may be used in place of the heptanoate.Type: ApplicationFiled: September 29, 2001Publication date: March 21, 2002Applicant: Morton International, Inc.Inventors: Bruce C. Herzig, Gary M. Conroy, Paul B. Adams, Michael E. Skladani, Gene K. Norris
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Patent number: 6326435Abstract: The polyester resin composition of the present invention comprises (A) a thermoplastic polyester resin, (B) an olefinic polymer modified with at least one member selected from the group consisting of an unsaturated carboxylic acid and its derivative, and (C) an aliphatic ester having a molecular weight of 400 to 1,000. The polyester resin of the present invention may comprises: (D) a flame retardant, (E) an inorganic flame retardant auxiliary, and others. The thermoplastic polyester resin composition is useful for the fabrication of sliding members (particularly, gears). Polyester resin compositions with improved dimensional accuracy and sliding properties and shaped articles formed therefrom can be obtained from the resin composition of the present invention.Type: GrantFiled: November 3, 2000Date of Patent: December 4, 2001Assignee: Polyplastics Co., Ltd.Inventors: Katsunori Takayama, Kazuhito Kobayashi
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Patent number: 6306209Abstract: A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant is hydrophilic, while at least a portion of each pendent polymeric segment is hydrophobic.Type: GrantFiled: December 16, 1999Date of Patent: October 23, 2001Assignee: PPG Industries Ohio, inc.Inventors: Brian E. Woodworth, Gregory J. McCollum, James B. O'Dwyer, Simion Coca
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Patent number: 5539055Abstract: An antistatic nonflammable resin composition comprising: (A) 30 to about 80 weight percent a styrene resin; (B) 70 to about 20 weight percent of a vinyl chloride resin; (C) 0.5 to about 5 weight parts based on (A)+(B) of at least one antistatic agent selected from the group consisting of alkyl sulfonates and alkyl benzene sulfonates; and (D) 0.1 to about 5 weight parts based on (A)+(B) of at least one organic tin stabilizer containing sulfur. Molded articles from said composition possess a good appearance, excellent antistatic property and dust-repellency on the surface thereof.Type: GrantFiled: February 15, 1995Date of Patent: July 23, 1996Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Kenji Nishimoto, Yoshihiko Hashimoto
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Patent number: 5304589Abstract: Oxidatively stabilized polyolefin polymers containing an antioxidant are made more resistant to loss of antioxidant by converting at least some of the antioxidant comprising a polymer of dicyclopentadiene and a phenolic compound into a form non extractable with cyclohexane. The conversion is preferably by reaction in the melt phase in the presence of a radical initiator. Addition of organotin esters, sulphides, oxides or thioethers reduces the color.Type: GrantFiled: January 18, 1991Date of Patent: April 19, 1994Assignee: BP Chemicals LimitedInventors: Neil S. Davidson, Hilda A. Leiper, Colette A. A. Di Murro, Kenneth Wilkinson
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Patent number: 5118741Abstract: Such food packing materials as heat shrinkable films or such formed containers for food as bottles are manufatured by forming resin compositions of the following compostions: (a) 100 weight parts of vinyl chloride based resin obtained by adding 0.005 to 0.5 weight parts of partially saponified polyvinyl alcohol, degree of saponification 20-55 mol %, means degree of polymerization 150-600, to 100 weight parts of loaded vinyl chloride monomer or a mixture of vinyl based monomer with vinyl chloride as main, during suspension-polymerizing in an aqueous medium under the existence of 0.03-0.08 weight parts of partially saponified polyvinyl alcohol, degree of saponification 65-80 mol %, means degree of polymerization 600-1000, or else in slurry after completion of the suspension-polymerizing: (b) 0.3 to 5 weight parts of non-toxic stabilizer for food which is a liquid composite stabilizer; and (c) 4 to 15 weigth parts of butadiene-styrene based copolymer resin.Type: GrantFiled: September 5, 1991Date of Patent: June 2, 1992Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tadashi Amano, Shigehiro Hoshida
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Patent number: 4910244Abstract: A storage stable adhesive for PVC plastics, particularly post-chlorinated PVC plastics, containing a basic mixture of 5 to 30% by weight post-chlorinated PVC and 95 to 70% by weight of an organic solvent, a stabilizer combination of effective quantities of organotin compounds and alkali metal carbonates from the group consisting of ammonium, lithium, sodium and potassium carbonates and also standard additives, such as impact modifiers, antioxidants and UV stabilizers can be included in the basic mixture. The composition has improved stability when stored in tin plated steel containers.Type: GrantFiled: November 7, 1988Date of Patent: March 20, 1990Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hans R. Dierdorf, Juergen Wegner
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Patent number: 4871590Abstract: A thixotropic hot-melt adhesive contains reactive silane groups and is still viscous and plastically moldable after cooling. It contains a mixture ofat least one thermoplastic material, andat least one thixotropic agent,wherein silane groups are contained either in the thermoplastic material itself or in at least one added silane-based binder.Type: GrantFiled: November 6, 1987Date of Patent: October 3, 1989Assignee: Sika AG, vorm. Kaspar Winkler & Co.Inventors: Peter W. Merz, Lutz-Dieter Zabel
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Patent number: 4839409Abstract: Compositions for stabilizing rigid (unplasticized) halogen-containing organic polymers against the deteriorative effects of heat, ultra-violet light and weathering comprise organotin or non-tin metal salt primary heat stabilizers in combination with esters of polyhydrocarbyl ether glycols.Type: GrantFiled: September 17, 1987Date of Patent: June 13, 1989Assignee: Morton Thiokol, Inc.Inventor: Gary M. Conroy
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Patent number: 4786437Abstract: Unfavorable interaction is prevented between (a) electroconductive particle fillers and (b) organic resin binders of the type which are normally instable with respect to viscosity when aged in contact with said fillers. Moreover, electroconductivity degradation is also avoided. In a preferred mode of the invention, the particle surface is treated with a coating of an interfacial pacifying agent such as a tetravalent tin compound which both enhances the electroconductive performance of the particles and also is sufficiently compatible with the resin binder to migrate into the binder sufficiently to avoid undue gelling of the binder by particle-borne contamination or residues of such contamination.Type: GrantFiled: May 13, 1987Date of Patent: November 22, 1988Assignee: Ercon, Inc.Inventor: John E. Ehrreich
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Patent number: 4764539Abstract: A combination of materials is disclosed which imparts superior fire retardant properties to organic polymers and the gaseous by-products of those polymers. The combination is made up of an organo phosphate plasticizer, aluminum hydroxide or alumina hydrate, antimony trioxide, a borate, a brominated hydrocarbon and a chlorinated paraffin.Type: GrantFiled: November 24, 1987Date of Patent: August 16, 1988Assignee: Norton CompanyInventor: Michel Ladang
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Patent number: 4732573Abstract: Dye salts of a mono- or polycationic dye where the anion conforms to a general formula (1) or (2)[Me (XCN).sub.4 ].sup.2(-) (1)[Me (SCN).sub.6 ].sup.n(-) (2)in whichMe in the formula (1) is the divalent zinc cation, the divalent iron cation, the divalent cobalt cation, the divalent tin cation or the divalent copper cation, andMe in the formula (2) stands for the divalent iron cation, the divalent nickel cation or the trivalent iron cation,X stands for an oxygen or sulfur atom andn depending on the valency of the corresponding metal cation, denotes the number 4 or 3.The novel dye salts can be obtained for example from aqueous solution or suspension by reacting the corresponding cationic dye which has a customary anion with a metal cation Me donor compound and an alkali metal thiocyanate or cyanate, alkaline earth metal thiocyanate or cyanate or ammonium thiocyanate or cyanate. They are used in particular in the spin-dyeing of acid-modified polyacrylonitrile and copolymers thereof.Type: GrantFiled: December 23, 1986Date of Patent: March 22, 1988Assignee: Hoechst AktiengesellschaftInventors: Kurt Hohmann, Peter Mischke, Wolfgang Teige
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Patent number: 4683082Abstract: Unfavorable interaction is prevented between (a) electroconductive particle fillers and (b) organic resin binders of the type which are normally instable with respect to viscosity when aged in contact with said fillers. Moreover, electroconductivity degradation is also avoided. In a preferred mode of the invention, the particle surface is treated with a coating of an interfacial pacifying agent such as a tetravalent tin compound which both enhances the electroconductive performance of the particles and also is sufficiently compatible with the resin binder to migrate into the binder sufficiently to avoid undue gelling of the binder by particle-borne contamination or residues of such contamination.Type: GrantFiled: March 27, 1985Date of Patent: July 28, 1987Assignee: Ercon, Inc.Inventor: John E. Ehrreich
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Patent number: 4609701Abstract: Blends of (a) a vinyl chloride polymer having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25.degree. C. falling within the range of about 1.50 to about 1.85; (b) a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride in which the relative proportions of said compound and said anhydride fall within the range of about 91 to about 70 weight percent of said compound and about 9 to about 30 weight percent of said anhydride; and (c) a tin-containing stabilizer and an impact modifier for vinyl chloride polymers. These blends contain 60 to 40 weight percent of (a) and 40 to 60 weight percent of (b) and have an Izod impact strength (ASTM D 256, Method A) of at least 0.5 foot pound per inch; a heat deflection temperature (ASTM D 648) at 66 psi of at least 75.degree. C.; and a dynamic thermal stability of at least 10 minutes.Type: GrantFiled: February 4, 1985Date of Patent: September 2, 1986Assignee: Ethyl CorporationInventors: Jesse D. Jones, Edwin D. Hornbaker
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Patent number: 4590232Abstract: A postchlorinated polyvinyl chloride composition having high processability for preparing molded products of outstanding properties comprises postchlorinated polyvinyl chloride and a copolymer of methyl methacrylate and a styrene monomer blended with the chloride. The composition has good thermal fluidity with good releasability from metal surface in processing and gives molded products of a high softening point and outstanding transparency.Type: GrantFiled: March 11, 1985Date of Patent: May 20, 1986Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Yoshihisa Tsubokura, Sumio Yamamoto, Eiji Aoishi, Tamio Fujita
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Patent number: 4517117Abstract: An improved conductive molding composition for the preparation of high density capacitance electronic discs is disclosed. The disclosed compositions are improved by the replacement of most or all of the conventionally used stabilizer ingredient with a tin mercapto ester or alkyl mercaptide represented by the formulae ##STR1## wherein R is a straight-chain alkyl radical having 4 to 8 carbon atoms; R.sub.1 is selected from --S-CH.sub.2 -COOR.sub.3 and --S-R.sub.3 ;R.sub.2 is R or R.sub.1 ; andR.sub.3 is a straight-chain alkyl radical having from 8 to 18 carbon atoms.Type: GrantFiled: June 20, 1984Date of Patent: May 14, 1985Assignee: RCA CorporationInventors: Mohamed E. Labib, Chin C. Wang
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Patent number: 4513108Abstract: A thermoplastic molding composition having high Izod Impact and heat deflection temperature is disclosed. This composition contains in intimate admixture: a vinyl chloride polymer; a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride; as a first impact modifier, chlorinated polyethylene resin; and as a second impact modifier either a MBS impact modifier, an ABS impact modifier, a MABS impact modifier or a mixture thereof. This copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride can be rubber modified.Type: GrantFiled: May 16, 1983Date of Patent: April 23, 1985Assignee: Ethyl CorporationInventor: Jesse D. Jones
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Patent number: 4510280Abstract: Blends of (a) a vinyl chloride polymer having a relative viscosity as measured at a concentration of 1 gram per 100 grams of cyclohexanone at 25.degree. C. falling within the range of about 1.50 to about 1.85; (b) a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride in which the relative proportions of said compound and said anhydride fall within the range of about 91 to about 70 weight percent of said compound and about 9 to about 30 weight percent of said anhydride; and (c) a tin-containing stabilizer and an impact modifier for vinyl chloride polymers. These blends contain 60 to 40 weight percent of (a) and 40 to 60 weight percent of (b) and have an Izod impact strength (ASTM D 256, Method A) of at least 0.5 foot pound per inch; a heat deflection temperature (ASTM D 648) at 66 psi of at least 75.degree. C.; and a dynamic thermal stability of at least 10 minutes.Type: GrantFiled: November 24, 1980Date of Patent: April 9, 1985Assignee: Ethyl CorporationInventors: Jesse D. Jones, Edwin D. Hornbaker
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Patent number: 4506049Abstract: A thermoplastic molding composition having good gloss and physical properties is disclosed. This composition contains in intimate admixture: a vinyl chloride polymer; a copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride; a styrene-maleic anhydride copolymer having a number average molecular weight within the range of from about 1000 to about 8000; and an alkyl diphenyl phosphite. The copolymer of a vinyl aromatic compound and an .alpha.,.beta.-unsaturated cyclic anhydride can be rubber modified.Type: GrantFiled: May 16, 1983Date of Patent: March 19, 1985Assignee: Ethyl CorporationInventors: Warren B. Mueller, Jesse D. Jones