At Least Two Tin Atoms Patents (Class 524/182)
  • Patent number: 8614268
    Abstract: This invention relates to the thermal stabilization of halogen-containing polymer compositions, more particularly, this invention relates to a poly(vinyl chloride) (PVC) or a chlorinated polyvinyl chloride (cPVC) composition comprising an alkyl tin stabilizer and at least one salt of a polymeric polyacid such as a polycarboxylic acid salt supported on a polymeric material.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: December 24, 2013
    Assignee: Rohm and Haas Company
    Inventors: Eric G. Lundquist, Jian-Yang Cho
  • Patent number: 7132467
    Abstract: Polyolefin mouldings that have excellent stability on permanent contact with chlorinated water comprise, as stabilizer, at least a compound selected from the group consisting of i) an epoxidized fatty acid having 3 to 22 carbon atoms or an aklyl ester thereof having 1 to 18 carbon atoms; and/or ii) an organotin compound; and/or iii) a compound containing at least one radical of the formula A or B.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: November 7, 2006
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Erich Kramer, Alfred Georges Oertli, Markus Grob
  • Patent number: 6919392
    Abstract: The heat and light stability imparted to vinyl halide polymers by metal compounds conventionally employed for this purpose is considerably improved by the presence of a mercapto ester such as 2-mercaptoethyl stearate. The esters can replace a substantial portion of the metal compound with no significant reduction in stability.
    Type: Grant
    Filed: April 20, 1992
    Date of Patent: July 19, 2005
    Assignee: Arkema Inc.
    Inventors: Jean-Yves Chenard, Jean-Claude Mendelsohn
  • Patent number: 6531533
    Abstract: Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O  (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.
    Type: Grant
    Filed: February 12, 1997
    Date of Patent: March 11, 2003
    Assignee: Crompton Vinyl Additives GmbH
    Inventors: Karl Josef Kuhn, Wolfgang Wehner, Rolf Drewes
  • Patent number: 6479070
    Abstract: Pinolenic acid can be used in the form of a food supplement, a pharmacentical composition or as part of a food composition as anti-inflammatory agent. The pinolenic acid used herefore suitably is applied as a natural product, or as a concentrate with more than 28 wt % pinolenic acid. The concentrates can be made by a process, wherein an enzymic hydrolysis on a glyceride material is performed.
    Type: Grant
    Filed: September 29, 2000
    Date of Patent: November 12, 2002
    Assignee: Unilever Patent Holdings
    Inventors: Frederick William Cain, Preyesh Parmar, Jonathan Richard Powell, Julia Sarah Rogers
  • Patent number: 6211269
    Abstract: Glass-fiber-reinforced ABS molding compounds containing up to 5% by weight of a tin-containing organic compound corresponding to formula (I) and/or (II) in which R1 and R2=C1-12 alkyl, R3, R4=C1-18 alkyl, R5=—(CH2)—n, —CH═CH—, —CH═CR1—, X=H, 1 equivalent of an alkali metal, preferably Na or K, ½ equivalent of an alkaline earth metal, preferably Mg or Ca, n=2-8.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: April 3, 2001
    Assignee: Bayer AG
    Inventors: Alfred Pischtschan, Herbert Eichenauer, Horst Peters
  • Patent number: 5670563
    Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymerb) at least one organotin compound andc) at least one phosphorus compound of formula(R.sub.7 S).sub.3 P.dbd.X.sub.nwherein the meaning of the individual substituents is as defined in the disclosure.
    Type: Grant
    Filed: July 17, 1995
    Date of Patent: September 23, 1997
    Assignee: Ciba-Specialty Chemicals Corporation
    Inventors: Horst Zinke, Johannes Kaufhold
  • Patent number: 5567751
    Abstract: Disclosed are homogeneous liquid stabilizer for polyvinyl chloride formulations and which exhibit a reduced tendency to form precipitates, comprising an aromatic ether alcohol, an alkyl or dialkyl phenol, and an admixture of alkyl tin compounds including butyltin alkyl mercaptides, butyltin hydroxyethyl mercaptides and compounds which are dibutyltin sulfides and/or monobutyltin sulfides.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: October 22, 1996
    Assignee: Witco Corporation
    Inventor: Samuel Hoch
  • Patent number: 5527842
    Abstract: Disclosed are liquid stabilizer compositions useful in polyvinyl chloride formulations and which exhibit a reduced tendency to form precipitates on standing, comprising one or more aromatic ether alcohols of the formula (1)Ar--O--(CH.sub.2 CH(X)O).sub.n H (1)wherein Ar is aryl, X is --H or --CH.sub.3, and n is 1 to 5, and one or more thioglycolates of the formula (2)(R.sup.1).sub.a Sn(--SCH.sub.2 COOR.sup.2).sub.4-a (2)wherein R.sup.1 is C.sub.1-4 alkyl, a is 1-2, and R.sup.2 is C.sub.7-16 alkyl.
    Type: Grant
    Filed: March 10, 1995
    Date of Patent: June 18, 1996
    Assignee: Witco Corporation
    Inventor: Samuel Hoch
  • Patent number: 5414035
    Abstract: The present invention provides an external lubricant composition for calendered vinyl polymer. The external lubricant provides rigid vinyl polymer compositions having improved plate out resistance, clarity, release, and stability. The external lubricant comprises an effective amount for lubricating vinyl polymer of polyethylene having a Brookfield viscosity at a temperature of 150.degree. C. of greater than about 85,000 centipoises and an acid number as determined by standardized titration of KOH of between about 5 and about 9.Sheets of the calendered vinyl polymer are used for blister packs and credit cards.
    Type: Grant
    Filed: July 1, 1994
    Date of Patent: May 9, 1995
    Assignee: AlliedSignal Inc.
    Inventors: Robert Lindner, Vincent Clarke
  • Patent number: 5369177
    Abstract: Thermoplastic molding materials containA) from 40 to 99.69% by weight of a polyoxymethylene homo- or copolymer,B) from 0.1 to 2% by weight of at least one stabilizer selected from the group consisting of benzotriazole derivatives or benzophenone derivatives or aromatic benzoate derivatives,C) from 0.1 to 2% by weight of at least one sterically hindered amino compound,D) from 0.005 to 2% by weight of a polyamide,E) from 0 to 2% by weight of an epoxy-containing compound,F) from 0 to 50% by weight of a toughened polymer andG) from 0 to 50% by weight of a fibrous or particulate filler or of a mixture thereof.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: November 29, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Sabine Kielhorn-Bayer, Hartmut Zeiner, Heiner Goerrissen, Dietrich Saenger
  • Patent number: 5252645
    Abstract: A halogen-containing resin composition containing 100 parts by weight of a halogen-containing resin, 0.01 to 10 parts by weight of a hydrotalcite, 0.01 to 10 parts by weight of a perchloric acid ion-containing hydrotalcite, and 0.01 to 5 parts by weight of at least one member selected from a .beta.-diketone compound, an organic acid metal salt and an organic tin compound, the resin composition being thermally stabilized against heat treatment and sun light and being improved in antistatic properties.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: October 12, 1993
    Assignee: Kyowa Chemical Industry Co., Ltd.
    Inventors: Tsutomu Nosu, Yoshiyuki Nagae
  • Patent number: 5236981
    Abstract: The present invention relates to new stabilized compositions based on halogenated polymer and more specifically on chlorinated polymer. It relates more particularly to stabilized compositions based on chlorinated polymer, which are characterized in that they contain:a) an effective quantity of at least one lead compound or of at least one organostannic compound, andb) an effective quantity of at least one essentially amorphous basic aluminum magnesium carbonate denoted by the formula (I):(MgO).sub.y.Al.sub.2 O.sub.3.(CO.sub.2).sub.x.(H.sub.2 O).sub.z (I).
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: August 17, 1993
    Assignee: Rhone-Poulenc Chimie
    Inventors: Mireille Arfiche, Louis Carette, Pierre Pena Porta, Francois Pouenat
  • Patent number: 5229444
    Abstract: Antioxidant-containing polyolefin composition containing a polyolefin and an antioxidant compound having the general formula: ##STR1## wherein R, R', X and Y are the same or different and are selected from alkyl, phenyl, cyclohexyl, a mono or polyfunctional carboxylic acid ester, hydroxyalkyl, and aralkyl, which groups may be unsubstituted or substituted, linear or branched, or cyclic, and p indicates a degree of polymerization and is at least 2.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: July 20, 1993
    Assignee: Elf Atochem North America, Inc.
    Inventors: William L. Smith, Michel Foure', Dominique Ranceze, Pierre Tozzolino
  • Patent number: 5109046
    Abstract: This invention relates to heat and light stabilizer compositions for vinyl halide resin compositions comprising organotinthioalkanol compounds that are stabilized against gelation and precipitation, to methods of preparing the stabilizer compositions, and to stabilized vinyl halide resin compositions.
    Type: Grant
    Filed: February 28, 1991
    Date of Patent: April 28, 1992
    Assignee: Atochem North America, Inc.
    Inventors: William A. Larkin, Robert C. Ringwood, Matthew T. Stershic
  • Patent number: 5100946
    Abstract: The present invention comprises a stabilized halogen containing polymer, preferably poly(vinyl halide), and more preferably poly(vinyl chloride) composition. A preferred polymer composition is a rigid halogenated polymer such as rigid poly(vinyl chloride). The composition contains at least one metal salt selected from the group consisting of at least one carboxylic acid or derivative thereof having at least two carboxyl groups, at least one carboxyl group and at least one hydroxyl group, at least one carboxyl group and at least one mercaptan, and an aromatic carboxylic acid having at least one carboxyl group. The metal salt is most preferably disodium adipate.
    Type: Grant
    Filed: December 27, 1990
    Date of Patent: March 31, 1992
    Assignee: Atochem North America, Inc.
    Inventors: Paul L. K. Hung, William L. Smith, Daniel B. Dess, Sriram Seshadri
  • Patent number: 5030676
    Abstract: An improved unplasticized polyvinyl chloride composition for forming articles for exterior use such as house siding and window profiles includes a polymeric organic impact modifier, at least one thermal dehydrochlorination stabilizer, and an ultraviolet stabilization system. The ultraviolet stabilization system includes from about 0.2-15 parts by weight of the polyvinyl chloride resin of rutile titanium dioxide and less than about 5 parts by weight of the polyvinyl chloride resin of magnesium oxide. Inclusion of magnesium oxide in the unplasticized polyvinyl chloride composition permits the extrusion of ultraviolet resistant siding and window profiles including relatively low levels of titanium dioxide.
    Type: Grant
    Filed: July 14, 1989
    Date of Patent: July 9, 1991
    Assignee: Certainteed Corporation
    Inventor: J. Michael Wallen
  • Patent number: 4988751
    Abstract: Halogenated vinyl polymer compositions containing molybdenum smoke retardants and organotin compounds having an overall ratio of sulfur to tin of not more than 1.7 gram atoms of sulfur per gram atom of tin, typically from about 0.6 to about 1.7 and preferably from about 0.6 to about 0.9 gram atoms of sulfur per gram atom of tin.
    Type: Grant
    Filed: April 28, 1989
    Date of Patent: January 29, 1991
    Assignee: Witco Corporation
    Inventors: Scott R. Chambers, Michael R. Croce
  • Patent number: 4963594
    Abstract: Vinyl chloride based polymers are heat/color stabilized by formulating therewith a stabilizing amount of (i) at least one organozinc derivative, (ii) at least one organic derivative of a metal from Group IIa of the Periodic Table, and (iii) at least one thiomalic acid diester.
    Type: Grant
    Filed: July 21, 1989
    Date of Patent: October 16, 1990
    Assignee: Rhone-Poulenc Specialites Chimiques
    Inventor: Michel Gay
  • Patent number: 4962145
    Abstract: Partial esters of saturated, linear C.sub.22 -C.sub.34 -monocarboxylic acids with polyols containing at least 3 carbon atoms and at least 2 hydroxyl groups are provided. The partial esters contain on average at least 1 free hydroxyl group and are generally obtained as mixtures of partial esters of at least 2 of said C.sub.22 -C.sub.34 -monocaroxylic acids. Particularly contemplated are partial esters based on montanic acids. The partial esters exhibit excellent release effects and transparency properties when used as release agents for plastics based on PVC or PVC copolymers.
    Type: Grant
    Filed: December 9, 1988
    Date of Patent: October 9, 1990
    Assignee: Neynaber Chemie GmbH
    Inventors: Kurt Worschech, Erwin Fleischer, Peter Wedl, Frido Loeffelholz, Ernst-Udo Brand
  • Patent number: 4950704
    Abstract: Motor vehicle components are provided having an improved stability at moderate temperatures and shaped from polyvinyl chloride resin compositions, comprising a polyvinyl chloride resin, at least one heat stabilizer in a sufficient amount to impart heat processing stability, and a .beta.-diketone in a sufficient amount to provide, after forming, stability at moderate temperatures not provided by any residual heat stabilizer, as well as polyvinyl chloride resin stabilizer compositions and polyvinyl chloride resin compositions containing such heat stabilizer compositions suitable for use in forming motor vehicle components, comprising at least one heat stabilizer and a .beta.-diketone.
    Type: Grant
    Filed: May 18, 1989
    Date of Patent: August 21, 1990
    Assignee: Argus Chemical Corporation
    Inventors: Michael A. Croce, Kook J. Bae, Stuart D. Brilliant
  • Patent number: 4810736
    Abstract: Compositions comprising the combination of an organotin mercaptide and a polyformal of a dithiodiglycol are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.
    Type: Grant
    Filed: December 7, 1987
    Date of Patent: March 7, 1989
    Assignee: Morton Thiokol, Inc.
    Inventor: Jeffrey R. Hyde
  • Patent number: 4786437
    Abstract: Unfavorable interaction is prevented between (a) electroconductive particle fillers and (b) organic resin binders of the type which are normally instable with respect to viscosity when aged in contact with said fillers. Moreover, electroconductivity degradation is also avoided. In a preferred mode of the invention, the particle surface is treated with a coating of an interfacial pacifying agent such as a tetravalent tin compound which both enhances the electroconductive performance of the particles and also is sufficiently compatible with the resin binder to migrate into the binder sufficiently to avoid undue gelling of the binder by particle-borne contamination or residues of such contamination.
    Type: Grant
    Filed: May 13, 1987
    Date of Patent: November 22, 1988
    Assignee: Ercon, Inc.
    Inventor: John E. Ehrreich
  • Patent number: 4704412
    Abstract: A high nitrile polymer composition resistant to gamma radiation comprising a high nitrile resin, a first stabilizer comprising at least one organotin compound selected from the group consisting of an organotin compound having the formulaR.sub.2 Sn(OOCCH.dbd.CHCOOR').sub.
    Type: Grant
    Filed: May 19, 1986
    Date of Patent: November 3, 1987
    Assignee: The Standard Oil Company
    Inventor: Joseph P. McCaul
  • Patent number: 4701486
    Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) a mono-organotin compound or mixture of mono-organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally (3) a diorganotin compound or mixture of diorganotin compounds. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.
    Type: Grant
    Filed: January 5, 1984
    Date of Patent: October 20, 1987
    Assignee: Morton Thiokol, Inc.
    Inventors: Robert E. Bresser, Karl R. Wursthorn
  • Patent number: 4683082
    Abstract: Unfavorable interaction is prevented between (a) electroconductive particle fillers and (b) organic resin binders of the type which are normally instable with respect to viscosity when aged in contact with said fillers. Moreover, electroconductivity degradation is also avoided. In a preferred mode of the invention, the particle surface is treated with a coating of an interfacial pacifying agent such as a tetravalent tin compound which both enhances the electroconductive performance of the particles and also is sufficiently compatible with the resin binder to migrate into the binder sufficiently to avoid undue gelling of the binder by particle-borne contamination or residues of such contamination.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: July 28, 1987
    Assignee: Ercon, Inc.
    Inventor: John E. Ehrreich
  • Patent number: 4681907
    Abstract: Compositions comprising an organotin mercaptide, organotin sulfide, organotin carboxylate or mixtures thereof and a diester of an ethylenically unsaturated dicarboxylic acid having one carboxyl group on each carbon atom of the ethenylene group are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: July 21, 1987
    Assignee: Morton Thiokol, Inc.
    Inventors: Keith A. Mesch, Gary M. Conroy
  • Patent number: 4617334
    Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic antimony compound or mixture of organic antimony compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and (3) a metal mercaptoalcohol or mixture of metal mercaptoalcohols. Also provided are polymer compositions containing said stabilizers, a process for stabilizing polymers, and articles of manufacture made from stabilized polymer compositions.
    Type: Grant
    Filed: September 24, 1984
    Date of Patent: October 14, 1986
    Assignee: Morton Thiokol, Inc.
    Inventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn
  • Patent number: 4593059
    Abstract: Compositions comprising an organotin mercaptide, organotin sulfide or mixtures thereof; a diester of an ethylenically unsaturated dicarboxylic acid having one carboxyl group on each carbon atom of the ethenylene group; and, optionally, an organotin carboxylate are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.
    Type: Grant
    Filed: November 20, 1984
    Date of Patent: June 3, 1986
    Assignee: Morton Thiokol, Inc.
    Inventors: Keith A. Mesch, Gary M. Conroy
  • Patent number: 4576984
    Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) a mono-organotin compound or mixture of mono-organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally (3) a diorganotin compound or mixture of diorganotin compounds. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.
    Type: Grant
    Filed: January 10, 1984
    Date of Patent: March 18, 1986
    Assignee: Morton Thiokol, Inc.
    Inventors: Robert E. Bresser, Keith A. Mesch, Karl R. Wursthorn
  • Patent number: 4517117
    Abstract: An improved conductive molding composition for the preparation of high density capacitance electronic discs is disclosed. The disclosed compositions are improved by the replacement of most or all of the conventionally used stabilizer ingredient with a tin mercapto ester or alkyl mercaptide represented by the formulae ##STR1## wherein R is a straight-chain alkyl radical having 4 to 8 carbon atoms; R.sub.1 is selected from --S-CH.sub.2 -COOR.sub.3 and --S-R.sub.3 ;R.sub.2 is R or R.sub.1 ; andR.sub.3 is a straight-chain alkyl radical having from 8 to 18 carbon atoms.
    Type: Grant
    Filed: June 20, 1984
    Date of Patent: May 14, 1985
    Assignee: RCA Corporation
    Inventors: Mohamed E. Labib, Chin C. Wang
  • Patent number: 4360619
    Abstract: This invention relates to stabilizer compositions for polymers comprising (1) an organotin compound, or mixture of organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally, (3) a halogen-containing tin compound or mixture of halogen-containing tin compounds, said stabilizers having a total halogen content of about 0.1% to about 10% by weight based on the weight of the stabilizer composition. This invention also relates to polymer compositions containing said stabilizers, to a process for stabilizing polymer by adding thereto said stabilizers, and to articles of manufacture, e.g. pipe, comprising a polymer and said stabilizers.
    Type: Grant
    Filed: February 26, 1981
    Date of Patent: November 23, 1982
    Assignee: Carstab Corporation
    Inventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn