At Least Two Tin Atoms Patents (Class 524/182)
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Patent number: 8614268Abstract: This invention relates to the thermal stabilization of halogen-containing polymer compositions, more particularly, this invention relates to a poly(vinyl chloride) (PVC) or a chlorinated polyvinyl chloride (cPVC) composition comprising an alkyl tin stabilizer and at least one salt of a polymeric polyacid such as a polycarboxylic acid salt supported on a polymeric material.Type: GrantFiled: March 26, 2010Date of Patent: December 24, 2013Assignee: Rohm and Haas CompanyInventors: Eric G. Lundquist, Jian-Yang Cho
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Patent number: 7132467Abstract: Polyolefin mouldings that have excellent stability on permanent contact with chlorinated water comprise, as stabilizer, at least a compound selected from the group consisting of i) an epoxidized fatty acid having 3 to 22 carbon atoms or an aklyl ester thereof having 1 to 18 carbon atoms; and/or ii) an organotin compound; and/or iii) a compound containing at least one radical of the formula A or B.Type: GrantFiled: January 23, 2003Date of Patent: November 7, 2006Assignee: Ciba Specialty Chemicals Corp.Inventors: Erich Kramer, Alfred Georges Oertli, Markus Grob
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Patent number: 6919392Abstract: The heat and light stability imparted to vinyl halide polymers by metal compounds conventionally employed for this purpose is considerably improved by the presence of a mercapto ester such as 2-mercaptoethyl stearate. The esters can replace a substantial portion of the metal compound with no significant reduction in stability.Type: GrantFiled: April 20, 1992Date of Patent: July 19, 2005Assignee: Arkema Inc.Inventors: Jean-Yves Chenard, Jean-Claude Mendelsohn
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Patent number: 6531533Abstract: Halogen-containing polymers or the recyclates thereof are stabilized by the addition of (a) a halogen-containing polymer or a recyclate thereof; (b) at least one zeolite in the form of sodium, potasssium and/or lithium, in particular at least one zeolite of formula M2O.Al2O3.x SiO2.y H2O (I), wherein M is Na, K or Li, x is 2 to 12, and y is 1 to 15, with the exception of zeolite A, Na12Al12Si12O48.27 H2O and clinoptilolite Na6Al6Si30O72.2 H2O, (c) at least one organic zinc, aluminium or rare earth compound, and/or (d) at least one organotin compound, as described in more detail in claim 1.Type: GrantFiled: February 12, 1997Date of Patent: March 11, 2003Assignee: Crompton Vinyl Additives GmbHInventors: Karl Josef Kuhn, Wolfgang Wehner, Rolf Drewes
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Patent number: 6479070Abstract: Pinolenic acid can be used in the form of a food supplement, a pharmacentical composition or as part of a food composition as anti-inflammatory agent. The pinolenic acid used herefore suitably is applied as a natural product, or as a concentrate with more than 28 wt % pinolenic acid. The concentrates can be made by a process, wherein an enzymic hydrolysis on a glyceride material is performed.Type: GrantFiled: September 29, 2000Date of Patent: November 12, 2002Assignee: Unilever Patent HoldingsInventors: Frederick William Cain, Preyesh Parmar, Jonathan Richard Powell, Julia Sarah Rogers
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Patent number: 6211269Abstract: Glass-fiber-reinforced ABS molding compounds containing up to 5% by weight of a tin-containing organic compound corresponding to formula (I) and/or (II) in which R1 and R2=C1-12 alkyl, R3, R4=C1-18 alkyl, R5=—(CH2)—n, —CH═CH—, —CH═CR1—, X=H, 1 equivalent of an alkali metal, preferably Na or K, ½ equivalent of an alkaline earth metal, preferably Mg or Ca, n=2-8.Type: GrantFiled: October 23, 1998Date of Patent: April 3, 2001Assignee: Bayer AGInventors: Alfred Pischtschan, Herbert Eichenauer, Horst Peters
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Patent number: 5670563Abstract: The invention relates to compositions comprisinga) a chlorine-containing polymerb) at least one organotin compound andc) at least one phosphorus compound of formula(R.sub.7 S).sub.3 P.dbd.X.sub.nwherein the meaning of the individual substituents is as defined in the disclosure.Type: GrantFiled: July 17, 1995Date of Patent: September 23, 1997Assignee: Ciba-Specialty Chemicals CorporationInventors: Horst Zinke, Johannes Kaufhold
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Patent number: 5567751Abstract: Disclosed are homogeneous liquid stabilizer for polyvinyl chloride formulations and which exhibit a reduced tendency to form precipitates, comprising an aromatic ether alcohol, an alkyl or dialkyl phenol, and an admixture of alkyl tin compounds including butyltin alkyl mercaptides, butyltin hydroxyethyl mercaptides and compounds which are dibutyltin sulfides and/or monobutyltin sulfides.Type: GrantFiled: June 1, 1995Date of Patent: October 22, 1996Assignee: Witco CorporationInventor: Samuel Hoch
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Patent number: 5527842Abstract: Disclosed are liquid stabilizer compositions useful in polyvinyl chloride formulations and which exhibit a reduced tendency to form precipitates on standing, comprising one or more aromatic ether alcohols of the formula (1)Ar--O--(CH.sub.2 CH(X)O).sub.n H (1)wherein Ar is aryl, X is --H or --CH.sub.3, and n is 1 to 5, and one or more thioglycolates of the formula (2)(R.sup.1).sub.a Sn(--SCH.sub.2 COOR.sup.2).sub.4-a (2)wherein R.sup.1 is C.sub.1-4 alkyl, a is 1-2, and R.sup.2 is C.sub.7-16 alkyl.Type: GrantFiled: March 10, 1995Date of Patent: June 18, 1996Assignee: Witco CorporationInventor: Samuel Hoch
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Patent number: 5414035Abstract: The present invention provides an external lubricant composition for calendered vinyl polymer. The external lubricant provides rigid vinyl polymer compositions having improved plate out resistance, clarity, release, and stability. The external lubricant comprises an effective amount for lubricating vinyl polymer of polyethylene having a Brookfield viscosity at a temperature of 150.degree. C. of greater than about 85,000 centipoises and an acid number as determined by standardized titration of KOH of between about 5 and about 9.Sheets of the calendered vinyl polymer are used for blister packs and credit cards.Type: GrantFiled: July 1, 1994Date of Patent: May 9, 1995Assignee: AlliedSignal Inc.Inventors: Robert Lindner, Vincent Clarke
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Patent number: 5369177Abstract: Thermoplastic molding materials containA) from 40 to 99.69% by weight of a polyoxymethylene homo- or copolymer,B) from 0.1 to 2% by weight of at least one stabilizer selected from the group consisting of benzotriazole derivatives or benzophenone derivatives or aromatic benzoate derivatives,C) from 0.1 to 2% by weight of at least one sterically hindered amino compound,D) from 0.005 to 2% by weight of a polyamide,E) from 0 to 2% by weight of an epoxy-containing compound,F) from 0 to 50% by weight of a toughened polymer andG) from 0 to 50% by weight of a fibrous or particulate filler or of a mixture thereof.Type: GrantFiled: August 30, 1993Date of Patent: November 29, 1994Assignee: BASF AktiengesellschaftInventors: Sabine Kielhorn-Bayer, Hartmut Zeiner, Heiner Goerrissen, Dietrich Saenger
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Patent number: 5252645Abstract: A halogen-containing resin composition containing 100 parts by weight of a halogen-containing resin, 0.01 to 10 parts by weight of a hydrotalcite, 0.01 to 10 parts by weight of a perchloric acid ion-containing hydrotalcite, and 0.01 to 5 parts by weight of at least one member selected from a .beta.-diketone compound, an organic acid metal salt and an organic tin compound, the resin composition being thermally stabilized against heat treatment and sun light and being improved in antistatic properties.Type: GrantFiled: December 4, 1991Date of Patent: October 12, 1993Assignee: Kyowa Chemical Industry Co., Ltd.Inventors: Tsutomu Nosu, Yoshiyuki Nagae
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Patent number: 5236981Abstract: The present invention relates to new stabilized compositions based on halogenated polymer and more specifically on chlorinated polymer. It relates more particularly to stabilized compositions based on chlorinated polymer, which are characterized in that they contain:a) an effective quantity of at least one lead compound or of at least one organostannic compound, andb) an effective quantity of at least one essentially amorphous basic aluminum magnesium carbonate denoted by the formula (I):(MgO).sub.y.Al.sub.2 O.sub.3.(CO.sub.2).sub.x.(H.sub.2 O).sub.z (I).Type: GrantFiled: April 9, 1992Date of Patent: August 17, 1993Assignee: Rhone-Poulenc ChimieInventors: Mireille Arfiche, Louis Carette, Pierre Pena Porta, Francois Pouenat
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Patent number: 5229444Abstract: Antioxidant-containing polyolefin composition containing a polyolefin and an antioxidant compound having the general formula: ##STR1## wherein R, R', X and Y are the same or different and are selected from alkyl, phenyl, cyclohexyl, a mono or polyfunctional carboxylic acid ester, hydroxyalkyl, and aralkyl, which groups may be unsubstituted or substituted, linear or branched, or cyclic, and p indicates a degree of polymerization and is at least 2.Type: GrantFiled: August 15, 1991Date of Patent: July 20, 1993Assignee: Elf Atochem North America, Inc.Inventors: William L. Smith, Michel Foure', Dominique Ranceze, Pierre Tozzolino
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Patent number: 5109046Abstract: This invention relates to heat and light stabilizer compositions for vinyl halide resin compositions comprising organotinthioalkanol compounds that are stabilized against gelation and precipitation, to methods of preparing the stabilizer compositions, and to stabilized vinyl halide resin compositions.Type: GrantFiled: February 28, 1991Date of Patent: April 28, 1992Assignee: Atochem North America, Inc.Inventors: William A. Larkin, Robert C. Ringwood, Matthew T. Stershic
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Patent number: 5100946Abstract: The present invention comprises a stabilized halogen containing polymer, preferably poly(vinyl halide), and more preferably poly(vinyl chloride) composition. A preferred polymer composition is a rigid halogenated polymer such as rigid poly(vinyl chloride). The composition contains at least one metal salt selected from the group consisting of at least one carboxylic acid or derivative thereof having at least two carboxyl groups, at least one carboxyl group and at least one hydroxyl group, at least one carboxyl group and at least one mercaptan, and an aromatic carboxylic acid having at least one carboxyl group. The metal salt is most preferably disodium adipate.Type: GrantFiled: December 27, 1990Date of Patent: March 31, 1992Assignee: Atochem North America, Inc.Inventors: Paul L. K. Hung, William L. Smith, Daniel B. Dess, Sriram Seshadri
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Patent number: 5030676Abstract: An improved unplasticized polyvinyl chloride composition for forming articles for exterior use such as house siding and window profiles includes a polymeric organic impact modifier, at least one thermal dehydrochlorination stabilizer, and an ultraviolet stabilization system. The ultraviolet stabilization system includes from about 0.2-15 parts by weight of the polyvinyl chloride resin of rutile titanium dioxide and less than about 5 parts by weight of the polyvinyl chloride resin of magnesium oxide. Inclusion of magnesium oxide in the unplasticized polyvinyl chloride composition permits the extrusion of ultraviolet resistant siding and window profiles including relatively low levels of titanium dioxide.Type: GrantFiled: July 14, 1989Date of Patent: July 9, 1991Assignee: Certainteed CorporationInventor: J. Michael Wallen
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Patent number: 4988751Abstract: Halogenated vinyl polymer compositions containing molybdenum smoke retardants and organotin compounds having an overall ratio of sulfur to tin of not more than 1.7 gram atoms of sulfur per gram atom of tin, typically from about 0.6 to about 1.7 and preferably from about 0.6 to about 0.9 gram atoms of sulfur per gram atom of tin.Type: GrantFiled: April 28, 1989Date of Patent: January 29, 1991Assignee: Witco CorporationInventors: Scott R. Chambers, Michael R. Croce
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Patent number: 4963594Abstract: Vinyl chloride based polymers are heat/color stabilized by formulating therewith a stabilizing amount of (i) at least one organozinc derivative, (ii) at least one organic derivative of a metal from Group IIa of the Periodic Table, and (iii) at least one thiomalic acid diester.Type: GrantFiled: July 21, 1989Date of Patent: October 16, 1990Assignee: Rhone-Poulenc Specialites ChimiquesInventor: Michel Gay
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Patent number: 4962145Abstract: Partial esters of saturated, linear C.sub.22 -C.sub.34 -monocarboxylic acids with polyols containing at least 3 carbon atoms and at least 2 hydroxyl groups are provided. The partial esters contain on average at least 1 free hydroxyl group and are generally obtained as mixtures of partial esters of at least 2 of said C.sub.22 -C.sub.34 -monocaroxylic acids. Particularly contemplated are partial esters based on montanic acids. The partial esters exhibit excellent release effects and transparency properties when used as release agents for plastics based on PVC or PVC copolymers.Type: GrantFiled: December 9, 1988Date of Patent: October 9, 1990Assignee: Neynaber Chemie GmbHInventors: Kurt Worschech, Erwin Fleischer, Peter Wedl, Frido Loeffelholz, Ernst-Udo Brand
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Patent number: 4950704Abstract: Motor vehicle components are provided having an improved stability at moderate temperatures and shaped from polyvinyl chloride resin compositions, comprising a polyvinyl chloride resin, at least one heat stabilizer in a sufficient amount to impart heat processing stability, and a .beta.-diketone in a sufficient amount to provide, after forming, stability at moderate temperatures not provided by any residual heat stabilizer, as well as polyvinyl chloride resin stabilizer compositions and polyvinyl chloride resin compositions containing such heat stabilizer compositions suitable for use in forming motor vehicle components, comprising at least one heat stabilizer and a .beta.-diketone.Type: GrantFiled: May 18, 1989Date of Patent: August 21, 1990Assignee: Argus Chemical CorporationInventors: Michael A. Croce, Kook J. Bae, Stuart D. Brilliant
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Patent number: 4810736Abstract: Compositions comprising the combination of an organotin mercaptide and a polyformal of a dithiodiglycol are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.Type: GrantFiled: December 7, 1987Date of Patent: March 7, 1989Assignee: Morton Thiokol, Inc.Inventor: Jeffrey R. Hyde
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Patent number: 4786437Abstract: Unfavorable interaction is prevented between (a) electroconductive particle fillers and (b) organic resin binders of the type which are normally instable with respect to viscosity when aged in contact with said fillers. Moreover, electroconductivity degradation is also avoided. In a preferred mode of the invention, the particle surface is treated with a coating of an interfacial pacifying agent such as a tetravalent tin compound which both enhances the electroconductive performance of the particles and also is sufficiently compatible with the resin binder to migrate into the binder sufficiently to avoid undue gelling of the binder by particle-borne contamination or residues of such contamination.Type: GrantFiled: May 13, 1987Date of Patent: November 22, 1988Assignee: Ercon, Inc.Inventor: John E. Ehrreich
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Patent number: 4704412Abstract: A high nitrile polymer composition resistant to gamma radiation comprising a high nitrile resin, a first stabilizer comprising at least one organotin compound selected from the group consisting of an organotin compound having the formulaR.sub.2 Sn(OOCCH.dbd.CHCOOR').sub.Type: GrantFiled: May 19, 1986Date of Patent: November 3, 1987Assignee: The Standard Oil CompanyInventor: Joseph P. McCaul
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Patent number: 4701486Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) a mono-organotin compound or mixture of mono-organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally (3) a diorganotin compound or mixture of diorganotin compounds. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.Type: GrantFiled: January 5, 1984Date of Patent: October 20, 1987Assignee: Morton Thiokol, Inc.Inventors: Robert E. Bresser, Karl R. Wursthorn
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Patent number: 4683082Abstract: Unfavorable interaction is prevented between (a) electroconductive particle fillers and (b) organic resin binders of the type which are normally instable with respect to viscosity when aged in contact with said fillers. Moreover, electroconductivity degradation is also avoided. In a preferred mode of the invention, the particle surface is treated with a coating of an interfacial pacifying agent such as a tetravalent tin compound which both enhances the electroconductive performance of the particles and also is sufficiently compatible with the resin binder to migrate into the binder sufficiently to avoid undue gelling of the binder by particle-borne contamination or residues of such contamination.Type: GrantFiled: March 27, 1985Date of Patent: July 28, 1987Assignee: Ercon, Inc.Inventor: John E. Ehrreich
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Patent number: 4681907Abstract: Compositions comprising an organotin mercaptide, organotin sulfide, organotin carboxylate or mixtures thereof and a diester of an ethylenically unsaturated dicarboxylic acid having one carboxyl group on each carbon atom of the ethenylene group are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.Type: GrantFiled: September 20, 1985Date of Patent: July 21, 1987Assignee: Morton Thiokol, Inc.Inventors: Keith A. Mesch, Gary M. Conroy
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Patent number: 4617334Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic antimony compound or mixture of organic antimony compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and (3) a metal mercaptoalcohol or mixture of metal mercaptoalcohols. Also provided are polymer compositions containing said stabilizers, a process for stabilizing polymers, and articles of manufacture made from stabilized polymer compositions.Type: GrantFiled: September 24, 1984Date of Patent: October 14, 1986Assignee: Morton Thiokol, Inc.Inventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn
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Patent number: 4593059Abstract: Compositions comprising an organotin mercaptide, organotin sulfide or mixtures thereof; a diester of an ethylenically unsaturated dicarboxylic acid having one carboxyl group on each carbon atom of the ethenylene group; and, optionally, an organotin carboxylate are useful for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering.Type: GrantFiled: November 20, 1984Date of Patent: June 3, 1986Assignee: Morton Thiokol, Inc.Inventors: Keith A. Mesch, Gary M. Conroy
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Patent number: 4576984Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) a mono-organotin compound or mixture of mono-organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally (3) a diorganotin compound or mixture of diorganotin compounds. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.Type: GrantFiled: January 10, 1984Date of Patent: March 18, 1986Assignee: Morton Thiokol, Inc.Inventors: Robert E. Bresser, Keith A. Mesch, Karl R. Wursthorn
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Patent number: 4517117Abstract: An improved conductive molding composition for the preparation of high density capacitance electronic discs is disclosed. The disclosed compositions are improved by the replacement of most or all of the conventionally used stabilizer ingredient with a tin mercapto ester or alkyl mercaptide represented by the formulae ##STR1## wherein R is a straight-chain alkyl radical having 4 to 8 carbon atoms; R.sub.1 is selected from --S-CH.sub.2 -COOR.sub.3 and --S-R.sub.3 ;R.sub.2 is R or R.sub.1 ; andR.sub.3 is a straight-chain alkyl radical having from 8 to 18 carbon atoms.Type: GrantFiled: June 20, 1984Date of Patent: May 14, 1985Assignee: RCA CorporationInventors: Mohamed E. Labib, Chin C. Wang
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Patent number: 4360619Abstract: This invention relates to stabilizer compositions for polymers comprising (1) an organotin compound, or mixture of organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally, (3) a halogen-containing tin compound or mixture of halogen-containing tin compounds, said stabilizers having a total halogen content of about 0.1% to about 10% by weight based on the weight of the stabilizer composition. This invention also relates to polymer compositions containing said stabilizers, to a process for stabilizing polymer by adding thereto said stabilizers, and to articles of manufacture, e.g. pipe, comprising a polymer and said stabilizers.Type: GrantFiled: February 26, 1981Date of Patent: November 23, 1982Assignee: Carstab CorporationInventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn