Two Or More Nitrogen Atoms Patents (Class 524/252)
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Patent number: 5319010Abstract: The instant invention pertains to viscous fluid coupling organopolysiloxane compositions comprised of (A) at least one organopolysiloxane fluid that has the general formula R.sup.1.sub.a R.sup.2.sub.b SiO.sub.[4-(a+b)]/2 wherein R.sup.1 is an alkyl group, R.sup.2 is an aryl group, a+b has the value of 1.95 to 2.05, and b/(a+b) has the value of 0.05 to 0.30; and (B) 0.01 to 5 weight parts by weight per 100 parts by weight of component (A) of a compound with the general formula ##STR1## wherein each R.sup.3 is independently selected from an alkyl group and C has the value of 0 to 2. The viscous fluid coupling organopolysiloxane compositions of the instant invention are capable of withstanding long-term use and under high-temperature, high-shear conditions with little increase or decrease in viscosity and almost no torque fluctuation.Type: GrantFiled: December 4, 1992Date of Patent: June 7, 1994Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Osamu Mitani, Ichiro Murakami
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Patent number: 5286785Abstract: Ethylene-carbon monoxide copolymer composition with improved thermal stability wherein the insoluble copolymer content after exposure to a temperature of 265.degree. C. during 5 minutes is at most 40 wt. % and use of the composition for the manufacture of objects, essentially consisting of ethylene-carbon monoxide copolymer. The composition preferably contains an inorganic compound reacting as a base upon contact with water.Type: GrantFiled: June 25, 1992Date of Patent: February 15, 1994Assignee: DSM N.V.Inventors: Pieter Gijsman, Daniel J. M. Tummers
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Patent number: 5284892Abstract: The present invention relates generally to compositions of polyalkylene imine ("PAI"), particularly polyethylene imine ("PEI") and polyolefin polymer (including copolymers and derivatives thereof); such compositions can be used in producing packaging films for oil containing foods, whereby the film is capable of scavenging unwanted aldehydes from the food product. The preferred compositions comprise a PAI substantially discontinuous phase and a olefinic polymer (including copolymers or derivatives thereof) substantially continuous phase in a weight ratio of PAI to olefinic polymer of about 0.001-30:100 which optionally also includes a binding agent.Type: GrantFiled: November 10, 1992Date of Patent: February 8, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Vincent Brodie, III, Donna L. Visioli
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Patent number: 5280060Abstract: A thermoplastic resin composition comprises:100 parts by weight of at least one polyamide resin, and0.01 to 20 parts by weight of at least one fluidity modifier selected from the group consisting of:Succinic anhydride,hexamethylenetetramine and1,12-diaminododecane.Type: GrantFiled: November 30, 1992Date of Patent: January 18, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Hiroomi Abe, Takeshi Fujii, Kiyoshi Mitsui
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Patent number: 5272196Abstract: A method is disclosed for increasing the surface energy of a surface of an organic polymeric material, particularly polyolefins. The method is comprised of blending from about 99.5% to about 90.0% by weight of the polymeric material with from about 0.5% to about 10.0% by weight of an amphiphile having the formula:RA(CHR.sup.2 [CH.sub.2 ].sub.n A.sup.1).sub.m R.sup.1where R and R.sup.1 are selected from the group consisting of the alkyl, aryl, alkylaryl, acyl and arylacyl derivatives of an aliphatic or aliphatic/aromatic mono-acid with a molecular weight of from about 150 to about 500 daltons, A and A.sup.1 are polar atoms or groups, R.sup.2 is selected from the group consisting of H, CH.sub.3 and C.sub.2 H.sub.5, n is from 0 to 3 and m is from 2 to 20.Type: GrantFiled: March 24, 1993Date of Patent: December 21, 1993Assignee: Arizona Chemical CompanyInventor: Eric S. Gardiner
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Patent number: 5256713Abstract: Glycoluril based amino resin powder coating compositions have improved flow out and viscosity characteristics when a rheology improving additive selected from alkali metal oxides, alkali metal hydroxides, alkali metal carbonates, alkaline earth metal carbonates, alkaline earth metal oxides, alkaline earth metal hydroxides, aluminum oxides, aluminum hydroxides, aluminum carbonates, zinc salts of long chain fatty acids, aluminum salts of long chain fatty acids, monoamines, dismines, or mixtures thereof are added.Type: GrantFiled: April 16, 1992Date of Patent: October 26, 1993Assignee: American Cyanamid CompanyInventors: William Jacobs, III, Donna A. Foster, Sami M. Sansur
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Patent number: 5242684Abstract: An antimicrobial, low toxicity, non-irritating composition comprises a blend of several bis-quaternary ammonium compounds coprecipitated with a copolymer of vinylpyrrolidone and an acrylamido or vinyl quaternary ammonium monomer.Type: GrantFiled: October 25, 1991Date of Patent: September 7, 1993Assignee: ISP Investments Inc.Inventor: John J. Merianos
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Patent number: 5240976Abstract: Elastomers are very effectively stabilized against thermal and oxidative degradation at elevated temperatures with a blend of an N,N,N',N'-tetrasubstituted 1,4-diamino-2-butene, where the substituents are alkyl, cycloalkyl, aralkyl, aryl or mixtures thereof, in combination with a mercaptoimidazole of formula IV ##STR1## where E is hydrogen, alkyl, cycloalkyl, aryl or phenylalkyl.Type: GrantFiled: August 21, 1992Date of Patent: August 31, 1993Assignee: Ciba-Geigy CorporationInventors: Douglas W. Horsey, Ambelal R. Patel
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Patent number: 5229442Abstract: Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.Type: GrantFiled: March 6, 1992Date of Patent: July 20, 1993Assignee: Enichem Synthesis S.p.A.Inventors: Fabio Broussard, Carlo Busetto
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Patent number: 5229206Abstract: Adhesive composition comprising a blend consisting essentially of (1) an adhesive composition comprising a tacky pressure-sensitive adhesive, said adhesive preferably selected from rubber-based adhesives, e.g., the thermoplastic elastomers, and (2) a pressure-sensitive adhesive composition comprising a polymer having in its backbone at least a major portion by weight of polymerized monomeric acrylic or methacrylic acid ester of a non-tertiary alcohol having from 1 to 14 carbon atoms with the average number of carbon atoms being about 4 to about 12, and grafted to the backbone, polymeric moieties having a Tg greater than about 20.degree. C. and a weight average molecular weight above about 2,000. The pressure-sensitive adhesive of adhesive composition (1) has moieties, e.g., blocks or grafts, that associate with the polymeric moieties grafted to the backbone of the polymer of adhesive composition (2).Type: GrantFiled: June 30, 1992Date of Patent: July 20, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventor: James D. Groves
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Patent number: 5205971Abstract: Non-whiteware ceramic articles having an increased green strength are prepared from slip compositions containing a polyalkylene polyamine as an additive or a mixture of a polyalkylene polyamine and binder as an additive. An example of such an additive is tetraethylenepentamine or a mixture of tetraethylenepentamine and a styrene butadiene latex.Type: GrantFiled: October 2, 1990Date of Patent: April 27, 1993Assignee: The Dow Chemical CompanyInventors: Alan P. Croft, Brian D. Koblinski
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Patent number: 5151459Abstract: N,N,N',N'-Tetrasubstituted 1,4-diamino-2-butynes or N,N-disubstituted propargylamines where the substituents are alkyl, cycloalkyl, phenylalkyl, aryl or mixtures thereof provide effective antioxidant protection to lubricants and/or synthetic polymers.Type: GrantFiled: May 16, 1991Date of Patent: September 29, 1992Assignee: Ciba-Geigy CorporationInventors: Joseph E. Babiarz, Werner Rutsch
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Patent number: 5132348Abstract: A tread rubber composition for high-speed running tires comprises a particular halogenated modified styrene-butadiene copolymer having p-halomethylbenzoyl group as a starting rubber and contains particular amounts of carbon black, process oil and diamine, and has excellent heat resistance and wear resistance.Type: GrantFiled: June 28, 1990Date of Patent: July 21, 1992Assignee: Bridgestone CorporationInventors: Tadashi Saito, Joji Yatsunami, Ichiro Wada, Toshiki Takizawa
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Patent number: 5116895Abstract: Polyamines having at least two amine groups are incorporated into a polymer system comprising an anionic surfactant and a polymer having at least one anionic pendant group. The resulting polymer system typically exhibits at least one improved physical property.Type: GrantFiled: July 15, 1991Date of Patent: May 26, 1992Assignee: Union Oil Company of CaliforniaInventor: Gaylen M. Knutson
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Patent number: 5063264Abstract: A first crystalline polyolefin composition is provided, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I): ##STR1## wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar.sub.1 and Ar.sub.2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium.Type: GrantFiled: August 20, 1990Date of Patent: November 5, 1991Assignee: Chisso CorporationInventor: Hirokazu Nakajima
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Patent number: 5034444Abstract: A rheological additive for non-aqueous coating compositions is disclosed. The additive may be the reaction product of an alkoxylated aliphatic nitrogen-containing compound, an aliphatic diamine or mixtures thereof, and an organic polycarboxylic anhydride or acid, an alkanediol polyepoxide ether, or mixtures thereof. The additive provides excellent anti-sag and storage stability properties, particularly for high solids coating compositions, without causing a significant increase in viscosity. Also disclosed are coating compositions containing the additive.Type: GrantFiled: June 18, 1990Date of Patent: July 23, 1991Assignee: Rheox, Inc.Inventors: Han B. Yun, Alan Smith
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Patent number: 5021513Abstract: Curable compositions comprise(A) a polyglycidyl ether of a polyhydric phenol,(B) a polyglycidyl ether of a polyhydric alcohol,(C) a nitrogen-containing latent hardener for epoxide resins and(D) as cure accelerator dispersed as a powder in the composition, a solid solution of a polymeric phenol with an aliphatic polyamine having two or more amine groups, each of the amine groups being tertiary and at least two of the amine groups being dimethylamino groups.Type: GrantFiled: October 4, 1990Date of Patent: June 4, 1991Assignee: Ciba-Geigy CorporationInventor: Madan M. Bagga
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Patent number: 4935165Abstract: The poor electrical conduction at an electrical switch contact caused by organopolysiloxane gas can be prevented by providing that a nitrogenous base gas be simultaneously present with the organopolysiloxane gas. Nitrogeneous base gases can be aliphatic amines or aromatic amines.Type: GrantFiled: October 30, 1987Date of Patent: June 19, 1990Assignee: Toray Silicone Company, Ltd.Inventors: Hiroyuki Asai, Katsutoshi Mine, Hiroshi Matsuoka
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Patent number: 4868235Abstract: A thermoplastic material containing, based in each case on the molding material comprising A and B,A from 30 to 80% be weight of one or more polycarbonates andB from 70 to 20% by weight of a blend of two different components B.sub.1 and B.sub.2, each of which consists of one or more graft copolymers b.sub.11 and b.sub.21 and each of which consists of one or more copolymers (hard matrix) b.sub.12 and b.sub.22, respectively, the graft copolymer b.sub.11 being prepared in emulsion and the graft copolymer b.sub.21 being prepared by another method.Type: GrantFiled: October 21, 1988Date of Patent: September 19, 1989Assignee: BASF AktiengesellschaftInventors: Klaus Muehlbach, Michael Portugall, Karl Ruppmich, Erhard Seiler, Hermann Brandt
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Patent number: 4857593Abstract: A process for enhancing the fabrication of thermoplastic polymers entailing the addition of from 0.01 to 1 part, per hundred parts of thermoplastic polymer, of a processing aid, said processing aid comprising a processing additive, such as a silicone or a polyol, and a processing adjuvant, such as a phosphate.Type: GrantFiled: March 8, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Pak S. Leung, Errol D. Goddard, Fred H. Ancker
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Patent number: 4849501Abstract: A composition for the application of a planar polyimide coating having a glass transition temperature above 300.degree. C. comprises a solution in an anhydrous, aprotic solvent of an aromatic diamine and a dialkyldihydrogen pyromellitate which is more than 90% meta isomer.Type: GrantFiled: April 19, 1988Date of Patent: July 18, 1989Assignee: International Business Machines CorporationInventors: Richard D. Diller, deceased, Anthony F. Arnold, Ying Ying Cheng, Patricia M. Cotts, Donald C. Hofer, Mahmoud Khojasteh, Elwood H. Macy, Prabodh R. Shah, Willi Volksen
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Patent number: 4829114Abstract: A composition comprises (a) a carboxylic acid compound which contains at least three carbon atoms and (b) an amine such as an ethoxylated amine. The composition may be obtained by conventional powder blending or melt blending techniques. The compositions can be incorporated into an olefin polymer to give a polymer composition which has an increased crystallization temperature and/or improved optical properties.Type: GrantFiled: October 30, 1987Date of Patent: May 9, 1989Assignee: Imperial Chemical Industries PLCInventors: Jean-Paul Trotoir, Colin Bath
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Patent number: 4810737Abstract: An improved process is provided for dry spinning spandex filaments which contain titanium dioxide pigment particles and a polymeric tertiary amine stabilizer. An organic base, such as ethylene diamine or diethyl amine, is added to the polymer solution before the titanium dioxide or the polymeric amine stabilizer is added to the solution. Improved spinning continuity and product yield are obtained.Type: GrantFiled: November 16, 1987Date of Patent: March 7, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: Wilton H. Dickerson
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Patent number: 4801642Abstract: Small amounts, typically from about 0.001 to about 0.05 percent by weight, of certain aliphatic and cycloaliphatic mono-, di- and triamines have been shown to retard the heat-induced discoloration to materials prepared by curing unfilled organosiloxane compositions comprising a specified class of vinyl-substituted polyorganosiloxanes, an organohydrogensiloxane and a platinum-containing hydrosilation catalyst. Preferred amines will also function as platinum catalyst inhibitors, and impart long term storage stability to these curable organosiloxane compositions when packaged in a single container.Type: GrantFiled: December 28, 1987Date of Patent: January 31, 1989Assignee: Dow Corning CorporationInventors: Gloria Janik, Manuello Buentello, III
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Patent number: 4730016Abstract: Disclosed herein is a resin composition obtained by mixing an olefin-base resin, which has in turn been obtained by partially neutralizing a free carboxyl group in a random copolymer of an .alpha.-olefin and an .alpha.,.beta.-ethylenically-unsaturated monocarboxylic or dicarboxylic acid, with a volatile rust preventive in a specific amount or more. The resin composition has excellent rust preventive properties and can hence be used advantageously as a wrapping material for metal products.Type: GrantFiled: April 14, 1986Date of Patent: March 8, 1988Assignee: Aicerro Chemical Company LimitedInventors: Akira Fujii, Yasuhisa Isobe, Kenichi Hashiudo
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Patent number: 4709009Abstract: A method for the production of reformed p-vinylphenol polymers which are lightened in color comprising treating a p-vinylphenol polymer under heating at about 150.degree. C. to about 350.degree. C. in the presence of an amine, and if optionally, in the additional presence of an acid compound and/or a reducing agent, and if necessary, in the additional presence of an inert solvent.Type: GrantFiled: June 3, 1985Date of Patent: November 24, 1987Assignee: Maruzen Petrochemical Co., Ltd.Inventors: Hiroshi Fujiwara, Tadashi Matsumoto, Masaaki Sekiya
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Patent number: 4613636Abstract: A peroxide-curable fluoroelastomer composition which can be readily removed from a mold cavity without tearing which comprises a fluoroelastomer whose interpolymerized units consist essentially of units of tetrafluoroethylene, units of perfluoroalkyl perfluorovinyl ether, units of a bromine-containing olefin and, optionally, units of ethylene, and from about 0.05-2 parts per 100 parts fluoroelastomer of an N,N,N',N'-tetrasubstituted 1,8-diaminonaphthalene having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently alkyl groups of 1-6 carbon atoms, phenyl or benzyl, R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 can be joined to form a 5- or 6-membered heterocyclic ring in which a carbon atom can be replaced by an oxygen or a sulfur atom, R.sub.1 and R.sub.3 and/or R.sub.2 and R.sub.Type: GrantFiled: July 12, 1985Date of Patent: September 23, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Leo Ojakaar
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Patent number: 4613639Abstract: Plastisols and organosols which have a long shelf life at room temperature, are based on a mixture of a finely divided synthetic resin with a plasticizer and may or may not contain additional pigments, fillers, volatile organic solvents and other assistants are prepared by a process in which an inert or reactive protective colloid or emulsifier, or a mixture of these, is added to a dispersion of a finely divided synthetic resin in a plasticizer, the dispersion as such not having a long shelf life at room temperature.These plastisols can be used as coating materials, sealants and adhesives.Type: GrantFiled: October 24, 1985Date of Patent: September 23, 1986Assignee: BASF AktiengesellschaftInventors: Rainer Blum, Rolf Osterloh
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Patent number: 4609699Abstract: This invention relates to polyarylene sulphides (PPS) produced in known manner from optionally substituted halogen benzenes and aromatic polyhalogen compounds, optionally in combination with other polymers, fillers and/or reinforcing fibres, which contain certain N-containing organic bases for reducing the elimination levels of acidic, corrosion-producing volatile constituents and for improving the flow properties thereof.Type: GrantFiled: October 22, 1984Date of Patent: September 2, 1986Assignee: Bayer AktiengesellschaftInventors: Rolf-Volker Meyer, Klaus Reinking, Karsten-Josef Idel, Rolf Dhein
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Patent number: 4607071Abstract: Improvement of a process for spin-dyeing acid-modified polymers or copolymers of acrylonitrile in which cationic quaternary dyestuffs are added to the spinning mass and spun according to the wet-spinning procedure. The improvement is characterized by using dyestuffs characterized by a migration factor M of 20 or less than 20, by a combination index K of less than 2.5 and a cation weight of more than 310. Migration factor M and combination index K are known values in the dyestuff field or can be determined. The dyestuff to be used according to the invention can belong to the most different classes of dyestuffs; they fix rapidly on the polymer, and thus they do not color, or color only to a minor extent, the coagulation, stretching and washing baths although they are soluble in water and aqueous solutions of these baths.Type: GrantFiled: May 15, 1985Date of Patent: August 19, 1986Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Reinhard Mohr, Kurt Hohmann
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Patent number: 4602052Abstract: A rubber composition containing carbon black as a reinforcing filler and a quaternary ammonium salt as a coupling agent and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 22, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4565843Abstract: This invention relates to new wire lacquers based on hydantoin group-containing polymers.Type: GrantFiled: December 18, 1984Date of Patent: January 21, 1986Assignee: Bayer AktiengesellschaftInventor: Willi Dunwald
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Patent number: 4369273Abstract: A stabilizing composition consisting of substituted alpha- or beta-naphthindoles, benzoylated or not benzoylated, and combined with organic polyimines such as those of formula 1 of the formulae sheet, in which R is alkyl or dialkyl, ethoxylated alkylmercaptans with 2.varies.8 ethoxy groups and (metal) halides of barium, calcium, lithium, zinc or aluminum, have a strong thermostabilizing effect on chlorine containing thermoplastics, especially on polyvinyl chloride, both homo-M and S polymers thereof, and on polyvinylidene chloride.Type: GrantFiled: August 22, 1980Date of Patent: January 18, 1983Assignee: Nautamix B.V.Inventor: Martinus A. Snel
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Patent number: 4347332Abstract: A blend of nylon and ethylene vinyl alcohol copolymer is provided which is suitable for conversion into films having desirable levels of strength and toughness, and good oxygen barrier properties. In addition, the blend exhibits enhanced adhesive qualities, as compared to films of EVOH copolymer per se, thus better adapting it for use in multilayer films. Methods for fabricating the resin blend into bare and composite films are also provided.Type: GrantFiled: April 1, 1981Date of Patent: August 31, 1982Assignee: American Can CompanyInventors: Thomas W. Odorzynski, Jack E. Knott, II
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Patent number: 4321190Abstract: This invention relates to particular polyolefin compositions which contain, as stabilizers against UV-light radiations, open-chain amine compounds which are hindered in the alpha-position by alkyl radicals, said amine compounds corresponding to the following general formula: ##STR1## wherein R', R", R"', R.sup.IV, R.sup.V and R.sup.VI which can be equal or different, are radicals of aliphatic hydrocarbons with a number of C-atoms variable from 1 to 20, or can be hydrogen atoms, n is an integer variable from 2 to 12, and n' is an integer comprised between 1 and 15.Type: GrantFiled: December 5, 1980Date of Patent: March 23, 1982Assignee: Anic S.p.A.Inventors: Silvestro Costanzi, Francesco Tessarolo, Adriano Ballabio, Tito Salvatori
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Patent number: RE34524Abstract: A composition for the application of a planar polymide coating having a glass transition temperature above 300.degree. C. comprises a solution in an anhydrous, aprotic solvent of .Iadd.the reaction product .Iaddend.of an aromatic diamine and a .[.dialkyldihydrogen.]. .Iadd.dialkyl .Iaddend.pyromellitate .Iadd.diacyl chloride .Iaddend.which .[.is more than.]. .Iadd.comprises about .Iaddend.90% .Iadd.or more .Iaddend.meta isomer.Type: GrantFiled: July 18, 1991Date of Patent: January 25, 1994Assignee: International Business Machines CorporationInventors: Richard D. Diller, deceased, Anthony F. Arnold, Ying Y. Cheng, Patricia M. Cotts, Donald C. Hofer, Mahmoud M. Khojasteh, Elwood H. Macy, Prabodh R. Shah, Willi Volksen