Oxygen Atom Other Than As Part Of A Carboxylic Acid Or Ester Group Patents (Class 524/290)
  • Patent number: 6051639
    Abstract: A material of general formula I: ##STR1## where E=0 indicates a non-cyclic system, and E=1 indicates a cyclic system;G is R.sub.3 SiR.sub.1 R.sub.2 (O).sub.kR.sub.1, R.sub.2, R.sub.3 are independently selected from C.sub.1-16 alkyl which may be partly or fully halogenated, H and formula IA: ##STR2## wherein Y is a propylene group which may be partially halogenated with fluorine or chlorine and Y.sub.1 is independently selected from COO, OCO, O, S, CHOH, CHF, CO or CH.sub.2 ;Q and Q.sub.1 are independently selected from (CH.sub.2).sub.n wherein one or more non-adjacent methylenes may be replaced by O andn=0-20;Z and Z.sub.1 are independently selected from O, S, single covalent bond, COO or OCO; ##STR3## represents a mesogenic group and is given by the general structure II ##STR4## A, B, D are selected from the following rings: ##STR5## the above rings may be substituted with one or more of the following substituents in at least one of the available substitution positions: F, Cl, Br, CH.sub.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: April 18, 2000
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventors: Georg H Mehl, John W Goodby, Rachel P Tuffin, Kenneth J Toyne
  • Patent number: 6008304
    Abstract: An additive for masticating natural rubber comprising at least one compound selected from the group consisting of benzoic acids, naphthoic acids, dicarboxylic acids and compounds represented by Formula (IV): ##STR1## wherein m and n each represent an integer of 1 to 3; p represents an integer of 1 to 4; m+n+p=6; X is O, NR.sup.8 or (R.sup.9 O).sub.q ; R.sup.6 is a C.sub.1 .about.C.sub.24 alkyl, a C.sub.2 .about.C.sub.24 alkenyl, or a C.sub.6 .about.C.sub.24 aryl group; and R.sup.7 is H, OH, an alkyl, alkenyl or aryl group; R.sup.8 is H or a C.sub.1 .about.C.sub.24 alkyl group; R.sup.9 is a C.sub.1 .about.C.sub.4 alkyl group; q is an integer of 1 to 5, a mastication method and a natural rubber composition each of which uses the additive, and a pneumatic tire using the natural rubber composition.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: December 28, 1999
    Assignees: Bridgestone Corporation, KAO Corporation
    Inventors: Daisuke Nohara, Masaaki Tsuchihashi, Isao Nishi
  • Patent number: 5994415
    Abstract: The invention relates to compound antifoams comprising alkoxylated partial esters--using from 3 to 60 mol of propylene oxide with or without from 1 to 10 mol of styrene oxide and/or from 1 to 10 mol of butylene oxide--of oligoglycerols, obtainable by condensation of 2 to 20 glycerol molecules, with C.sub.8 to C.sub.22 fatty acids and inorganic or organic solids for defoaming polymer dispersions and aqueous coating systems.
    Type: Grant
    Filed: May 14, 1998
    Date of Patent: November 30, 1999
    Assignee: Th. Goldschmidt AG
    Inventors: Burghard Gruning, Petra Hinrichs, Michael Keup, Frank Konig, Stefan Silber, Roland Sucker, Ellen Wallhorn
  • Patent number: 5989794
    Abstract: Disclosed is a polyalkylene naphthalate film, preferably the homopolymer of naphthalene-2,6-dicarboxylic acid and ethylene glycol (PEN), comprising a UV absorbing compound of general formula Q--CO--CO--X (explained in the description) for quenching of the UV fluorescence at 429 nm. The polymeric film is preferably used as support for a photographic material, preferably a colour negative or colour reversal photographic material.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: November 23, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventor: August Marien
  • Patent number: 5965648
    Abstract: This invention relates to a polyester composition comprising a blend of:(A) 99.5 to 75 weight % of a copolyester having an inherent viscosity of 0.1 to 1.2 dL/g and having a melting point in excess of 250.degree. C., comprising:(a) one or more dicarboxylic acids, and(b) a glycol component comprising at least 80 mole % 1,4-cyclohexanedimethanol; and(B) 0.5 to 25 weight % of one or more polyalkylene ethers,wherein the weight percentages of all components in said blend total 100 weight %.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: October 12, 1999
    Assignee: Eastman Chemical Company
    Inventors: Andrew Edwin Brink, Sam Richard Turner, Gerald Timothy Keep
  • Patent number: 5922795
    Abstract: Acetylenic maleates, fumarates and related derivative compounds are new compositions of matter having the formula:R.sub.1 O.sub.2 CCH.dbd.CH--O.sub.2 R.sub.2wherein R.sub.1 may be an organic moiety containing at least two carbon atoms triply bonded one to the other as:--C.tbd.C--and R.sub.2 may be hydrogen, an organic moiety, or R.sub.1 ; suitable for use as liquid injection molding inhibitors either singly or in combination with themselves or other liquid injection molding inhibitors when used for the process of liquid injection molding curable compositions enabling an increase in the size of articles manufactured therefrom, which new compositions of matter cure into the polymerizable or curable resins thereby creating new compositions of matter as cured resins from which said articles of manufacture are produced.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: July 13, 1999
    Assignee: General Electric Company
    Inventors: Philip J. McDermott, Michael J. O'Brien, Edward M. Jeram
  • Patent number: 5856413
    Abstract: A thermoplastic molding composition comprising polycarbonate and a comples ester are disclosed. The ester which conforms to ##STR1## wherein p is an integer of 2 to 8, q is an integer of 7 to 13 and R and R' independently denote a C.sub.x H.sub.2x+1 -group, where x is an integer of 8 to 24, with the proviso that R is linear, was found to impart to the composition excellent mold filling and release properties.
    Type: Grant
    Filed: June 24, 1997
    Date of Patent: January 5, 1999
    Assignee: Bayer Corporation
    Inventors: John J. Charles, Charles E. Lundy, Robson Mafoti
  • Patent number: 5821292
    Abstract: The use of 3-arylacrylic esters I ##STR1## where Ar is an aryl radical which can additionally carry substituents,R.sup.1 is the residue of an n-hydric aliphatic polyol having up to 20 carbon atoms, where the carbon chain can be interrupted by up to 9 non-adjacent oxygen atoms, or of an n-hydric cyclo-aliphatic polyol having 5 to 20 carbon atoms in which ring carbon atoms can also be replaced by non-adjacent oxygen atoms,R.sup.2 and R.sup.3 are hydrogen or C.sub.1 --C.sub.4 -alkyl, andn is a number from l to 10,as stabilizers, in particular against the action of light, for non-living organic material.
    Type: Grant
    Filed: May 12, 1997
    Date of Patent: October 13, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumuller, Martin Holderbaum, Wolfgang Goetze, Jurgen Krockenberger, Hubert Trauth
  • Patent number: 5756569
    Abstract: This invention relates to an aqueous coating composition comprising a stable dispersion of resin particles and a coalescing agent wherein the coalescing agent is an alkyl 3-alkoxypropionate having the structure:R.sup.1 --OCH.sub.2 CH.sub.2 COO--R.sup.2wherein R.sup.1 and R.sup.2 are independently selected from the group consisting of an alkyl and a arylalkyl group wherein the sum of the carbon atoms of the alkyl and arylalkyl groups is 5 to 10, provided that R.sup.2 is not methyl.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: May 26, 1998
    Inventors: Bobby Carroll Carver, Glenn Clark Jones, Ronald Keith Litton, William Dell Nottingham, Alan Kent Wilson
  • Patent number: 5728760
    Abstract: A method of making flame retarded polyurethanes by including a bromobenzoate compound in the polyurethane mixture. Also disclosed is a method of making flame retarded polyvinyl chlorides, unsaturated polyesters and epoxy resins by incorporating a bromobenzoate compound into the polymer system. The bromobenzoate compounds of the invention may also be used as plasticizers for PVC and rubber.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: March 17, 1998
    Assignee: Great Lakes Chemical Corporation
    Inventors: Richard S. Rose, Bhabatosh Bhattacharya, Nicolai A. Favstritsky
  • Patent number: 5700857
    Abstract: A polyester resin composition made of a polyester resin containing a polyalkylene oxide soft segment component, a plasticizer, a crystallization promoter, and a brominated flame retardant is developed, said composition having good flame resistance and mechanical properties.
    Type: Grant
    Filed: June 25, 1996
    Date of Patent: December 23, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Atsushi Mukohyama
  • Patent number: 5624987
    Abstract: This invention relates to a polyester composition comprising a blend of:(A) 99.5 to 75 weight % of a copolyester having an inherent viscosity of 0.1 to 1.2 dL/g and having a melting point in excess of 250.degree. C., comprising:(a) one or more dicarboxylic acids, and(b) a glycol component comprising at least 80 mole % 1,4-cyclohexanedimethanol; and(B) 0.5 to 25 weight % of one or more polyalkylene ethers,wherein the weight percentages of all components in said blend total 100 weight %.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: April 29, 1997
    Inventors: Andrew E. Brink, Sam R. Turner, Gerald T. Keep
  • Patent number: 5616640
    Abstract: A golf ball employing a cover composition comprising an oxa acid compound having the formula ##STR1## wherein R is an organic moiety selected from the group consisting of alkyl, carbocyclic, and heterocyclic groups. Additionally, the present invention is directed towards a golf ball cover composition comprising a copolymer of at least two comonomers, the first comonomer comprising an oxa acid composition of Formula I, and the second comonomer is selected from the group consisting of polyurethanes, epoxy resins, polyethylenes, polyamides, polyesters, and a monomer having a carboxylic acid moiety or its corresponding ionomer. Golf balls employing the present cover compositions exhibit excellent spin characteristics as well as good shear resistance.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 1, 1997
    Assignees: Acushnet Company, E. I. Du Pont de Nemours & Co.
    Inventor: Kevin M. Harris
  • Patent number: 5527847
    Abstract: Plasticizers are homogeneously incorporated into finely divided solid polyamides by mechanically agitating a mixture of plasticizers and polyamides at temperatures of at least 80.degree. C. while the polyamide remains in the finely divided solid phase.
    Type: Grant
    Filed: January 13, 1994
    Date of Patent: June 18, 1996
    Assignee: Huels Aktiengesellschaft
    Inventors: Salih Mumcu, Weigand Kramer, Wolfgang Kriesten, Hans J. Panoch
  • Patent number: 5506289
    Abstract: Acetylenic maleates, fumarates and related derivative compounds are new compositions of matter having the formula:R.sub.1 O.sub.2 C--CH.dbd.CH--CO.sub.2 R.sub.2wherein R.sub.1 may be an organic moiety containing at least two carbon atoms triply bonded one to the other as:--C.tbd.C--and R.sub.2 may be hydrogen, an organic moiety, or R.sub.1 ; suitable for use as liquid injection molding inhibitors either singly or in combination with themselves or other liquid injection molding inhibitors when used for the process of liquid injection molding curable compositions enabling an increase in the size of articles manufactured therefrom, which new compositions of matter cure into the polymerizable or curable resins thereby creating new compositions of matter as cured resins from which said articles of manufacture are produced.
    Type: Grant
    Filed: July 23, 1993
    Date of Patent: April 9, 1996
    Inventors: Philip J. McDermott, Michael J. O'Brien, Edward M. Jeram
  • Patent number: 5506312
    Abstract: A polyketone is contacted with an organic peroxyacid in a reactive, oxidization, slurry process to produce a polyester polymer.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: April 9, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Palanisamy Arjunan
  • Patent number: 5486559
    Abstract: The invention relates to an optically non-linear active waveguiding material comprising an optically transparent polymer and a donor group and acceptor group-containing triphenylcarbinol as a dopant. Said dopants have a high hyperpolarizability and have a charge-transfer absorption band which is about the same as that of their corresponding compounds having only one donor-.pi.-acceptor unit. The triphenylcarbinols were found to display good solubility in polymers. Nitro-functionalized triphenylcarbinols are preferred because of their charge-transfer absorption band at a low wavelength (.lambda..sub.max at about 290 nm). Aldehyde-functionalized calix(4)arenes were also found to have this low wavelength charge-transfer absorption band (.lambda..sub.max at about 270 nm). Triphenyls comprising stilbene donor-.pi.-acceptor units are preferred because of their high hyperpolarizability.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: January 23, 1996
    Assignee: Akzo Nobel NV
    Inventors: Johannes F. J. Engbersen, Erik Kelderman, David N. Reinhoudt, Willem Verboom
  • Patent number: 5459184
    Abstract: Hot melt adhesives of this invention can comprise a water-soluble polyalkylenimine, an hydroxy substituted organic compound, and optimally a plasticizer, a tackifier, and other ingredients. The adhesives are water actuated, and can be water activated, cleaned by aqueous systems, or recycled in aqueous systems.
    Type: Grant
    Filed: April 2, 1985
    Date of Patent: October 17, 1995
    Assignee: H. B. Fuller Company
    Inventors: William L. Bunnelle, Keith C. Knutson, Robert Hume, III
  • Patent number: 5434208
    Abstract: The invention relates to an optically non-linear active waveguiding material comprising an optically transparent polymer and a non-linear optical dopant comprising more than one donor-.pi.-acceptor unit.Dopants comprising more than one donor-.pi.-acceptor unit, especially dopants in which the donor-.pi.-acceptor units are positioned in a cyclic group, have a high hyperpolarizability and a charge-transfer absorption band wavelength which is about the same as that of dopants with only one donor-.pi.-acceptor unit.Especially suitable dopants for use are calix(4)arenes. These are provided with acceptor groups at the upper rim and with donor groups at the lower rim. In addition to having excellent hyperpolarizability, these compounds were found to be readily soluble in host polymers, such as polymethylene (meth) acrylate and polystyrene.
    Type: Grant
    Filed: July 7, 1993
    Date of Patent: July 18, 1995
    Assignee: Akzo Nobel N.V.
    Inventors: Jan G. Batelaan, Johannes F. J. Engbersen, Erik Kelderman, David N. Reinhoudt, Willem Verboom
  • Patent number: 5405897
    Abstract: The present invention relates to a rubber stock containing 0.1 to 10.0 phr of phenoxyacetic acid. Addition of the phenoxyacetic acid to a rubber stock increases the low strain stiffness properties of the rubber stock and results in increased treadwear when the stock is used in tread stocks. The phenoxyacetic acid may also be used in a rubber stock as a methylene acceptor or resorcinol replacement. In addition, the phenoxyacetic acid functions as a silica coupling agent and provides lower viscosities for processing the rubber stock compared to rubber stocks containing conventional silane coupling agents.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: April 11, 1995
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thomas J. Segatta, Paul H. Sandstrom
  • Patent number: 5397825
    Abstract: An active filler composition utilizing scrap rubber, such as automobile tires, as a main or primary ingredient is used in the treatment, recycling, and manufacture of various rubber and plastic articles. A chemical plasticizer and binding agent is used in the production of the composition to plasticize, swell, and soften the scrap rubber. The filler composition is a homogeneous blend of from about 40 to 95 parts by weight of cured rubber particles and from about 5 to 60 parts by weight of the liquid plasticizer and binder. The active filler composition can be further compounded with materials such as polyethylene, polyethylene-terephthallate (PET), polyurethanes, urethanes, polyisocurates, polyacrylics, polyvinylchloride (PVC), and epoxies, to form a composite material for combining with still other materials to impart elastomeric properties.
    Type: Grant
    Filed: May 19, 1993
    Date of Patent: March 14, 1995
    Inventor: Neal Segrest
  • Patent number: 5312855
    Abstract: The adhesive organopolysiloxane composition contains a compound having two or more allyl ester groups in combination with an adhesion imparting agent of a silicon compound having at least one group selected from the group consisting of an alkoxy group and an epoxy containing hydrocarbon group and also having at least one silicon-bonded hydrogen atom. This composition is markedly improved in adhesion to various substrates and durability of the adhesion.
    Type: Grant
    Filed: February 1, 1993
    Date of Patent: May 17, 1994
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Takehide Okami
  • Patent number: 5279896
    Abstract: A vibration-damping pressure-sensitive adhesive composition containing a crosslinked structure of a copolymer comprising (A) from 75 to 92% by weight of a main monomer comprising an alkyl (meth)acrylate containing from 8 to 12 carbon atoms in the alkyl moiety thereof and (B) from 8 to 25% by weight of a carboxyl-containing monomer whose homopolymer has a glass transition temperature of 50.degree. C. or more, said crosslinked structure having a solvent-insoluble content of 80% by weight or more and a weight loss of 3% by weight or less on heating at 120.degree. C. for 240 hours, and said composition having a T-peel strength of 400 g/20 mm-width or more from a SUS plate and a loss factor of 0.05 or more at 60.degree. C. in the vicinity of 1 kHz as determined by a half-value width method. The composition exhibits satisfactory heat resistance against long-term use in high temperatures as well as satisfactory adhesion to various parts at room temperature.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: January 18, 1994
    Assignee: Nitto Denko Corporation
    Inventors: Yasuyuki Tokunaga, Yutaka Moroishi, Nobuharu Suzuki
  • Patent number: 5271866
    Abstract: A liquid-crystalline polymer composition comprising a ferroelectric liquid-crystalline polymer and a low molecular weight liquid-crystalline compound which exhibits smectic C phase or chiral smectic C phase. Such liquid-crystalline polymer compositions have not only excellent moldabilities such as ease of orientation, but also exhibit chiral smectic C phase at wide temperature range within room temperatures and exhibit high speed response to changes of external fields and high contrast ratios when they are used for optical display elements.
    Type: Grant
    Filed: May 21, 1991
    Date of Patent: December 21, 1993
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shunji Uchida, Kazuharu Morita, Kenji Hashimoto
  • Patent number: 5246999
    Abstract: There is disclosed thermoplastic polymeric compositions of polycarbonates, polyamides, polyacetals, and poly(2,6-dimethyl-1,4-phenylene oxides) and which contain in a minor amount sufficient to make the thermoplastic polymeric material easily releasable from a processing mold of fatty acid ester.
    Type: Grant
    Filed: May 13, 1991
    Date of Patent: September 21, 1993
    Assignees: Instytut Chemii Przemyskowej, Nauchno Issledovatelsjkij Institut Plasticheskich Mass Imeni G. S. Petrova
    Inventors: Zbigniew Wielgosz, Valentina Amerik, Dmitrij Bojko, Regina Jeziorska, Ewa Kowalska, Piotr Penczek, Ewgenij Riabow, Galina Szkarpejkina, Ewa Kicko-Walczak
  • Patent number: 5169890
    Abstract: The present invention relates to a thermoplastic hot melt adhesive comprising(a) a block copolymer, said block copolymer being prepared utilizing a bromide based coupling agent, said block copolymer comprising at least two monoalkenyl arene polymer end blocks A and at least one elastomeric conjugated diene polymer mid block B, and said block copolymer having about 8 to about 65 percent by weight of said monoalkenyl arene polymer block content, each polymer block A having an average molecular weight of between about 5,000 and about 125,000, and each polymer block B having an average molecular weight of between about 10,000 and about 300,000,(b) a polyisobutylene rubber,(c) a partially cross-linked polyisobutylene rubber(d) a compatible tackifying resin,(e) a phenolic antioxidant,(f) a non-reactive phenolic resin,(g) a fluorocarbon surface active agent, and(h) a petroleum derived wax.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: December 8, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rajan Eadara, Julie Szymborski, Irvin Jackson
  • Patent number: 5164436
    Abstract: Waxy esters of aromatic alcohols with long-chain carboxylic acids give lubricants and release agents for highly transparent thermoplastics which reduce the transparency of these plastics to a far lesser degree than the previously customary montan wax esters of aliphatic alcohols.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: November 17, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karl Maier, Gerd Hohner, Jan-Peter Piesold
  • Patent number: 5128397
    Abstract: Hot melt adhesive compositions stabilized against thermal degradation, discoloration, skin formation and substantial viscosity changes, said adhesives being based on ethylene-vinyl acetate copolymer and a hydrocarbon tackifying resin and containing a stabilizer system of a hindered phenol antioxidant, a phosphite costabilizer and an acid scavenger.
    Type: Grant
    Filed: May 9, 1991
    Date of Patent: July 7, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Douglas W. Horsey, Ambelal R. Patel
  • Patent number: 5071898
    Abstract: Composition containing a) a polymer containing chlorine and b) at least one compound of the formula I ##STR1## in which R.sub.1 is C.sub.1 -C.sub.10 alkyl, C.sub.2 -C.sub.10 hydroxyalkyl, phenyl, hydroxyphenyl, C.sub.7 -C.sub.10 phenylalkyl or C.sub.7 -C.sub.10 phenylalkyl which is substituted on the phenyl ring by an OH group, and R.sub.2 is C.sub.2 -C.sub.10 hydroxyalkyl, hydroxyphenyl or C.sub.7 -C.sub.10 phenylalkyl which is substituted on the phenyl ring by an OH group, subject to the condition that R.sub.2 is other than hydroxyphenyl if R.sub.1 is phenyl or hydroxyphenyl, and/or at least one compound of the formula I in which the OH groups present in the radicals R.sub.1 and R.sub.2 have been replaced by C.sub.2 -C.sub.12 alkanoyloxy.The compounds of the formula IA ##STR2## in which R is C.sub.1 -C.sub.10 alkyl, C.sub.2 -C.sub.10 hydroxyalkyl, phenyl, hydroxyphenyl, C.sub.7 -C.sub.10 phenylalkyl or C.sub.7 -C.sub.10 phenylalkyl which is substituted on the phenyl ring by an OH group, are novel.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: December 10, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Hans-Helmut Friedrich, Gerd Abeler
  • Patent number: 5064932
    Abstract: Novel poly(keto-esters) having carbonyl and oxycarbonyl units randomly combined with linking units derived from olefinic monomers to form an essentially straight-chain polymer backbone are provided. The poly(keto-esters) are produced by converting a portion of the carbonyl functionality of a polyketone to oxycarbonyl groups. The conversion is achieved by reacting the polyketone with an organic peroxyacid in an inert liquid medium at a temperature from -20.degree. C. to 150.degree. C.
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: November 12, 1991
    Assignee: Quantum Chemical Corporation
    Inventors: Biau-Hung Chang, Lester Y. Lee, Jack Kwiatek
  • Patent number: 5057565
    Abstract: This invention relates to a solid polyelectrolyte polymer film which comprises a polymer, a plasticizer for the polymer, an epoxidized vegetable oil, and an electrolyte.
    Type: Grant
    Filed: December 22, 1988
    Date of Patent: October 15, 1991
    Assignee: The Dow Chemical Company
    Inventors: Stephen A. Noding, Sanford A. Siegel
  • Patent number: 5028647
    Abstract: The present invention is a composition comprising a linear saturated polyester and from 0.5 to 30 percent by weight of thee polyester of at least one ester of an ethoxylated polyfunctional alcohol having a molecular weight of from 500 to about 1,500. The ester is of an ethoxylated aromatic alcohol and a carboxylic acid wherein the ethoxylated aromatic alcohol has the formulaHO (R O).sub.n --R.sup.1 --(OR).sub.n --OHwherein, R is the same or different hydrocarbon radical of from 2 to 4 carbon atoms, n can be the same or a different integer of from 2 to 15; and R.sup.1 is an aromatic radical preferably derived from an aromatic dialcohol, most preferably bisphenol A. The ethoxylated aromatic alcohol has greater than 20 carbon atoms. The acid is a carboxylic acid of from 1 to 25 and preferably 3 to 10 carbon atoms, and from 1 to 10 carboxyl groups. Preferably the acid has from 3 to 10 carbon atoms and one carboxyl group.
    Type: Grant
    Filed: March 13, 1989
    Date of Patent: July 2, 1991
    Assignees: Allied-Signal Inc., The C.P. Hall Company
    Inventors: John C. Haylock, Harold W. Tuller, Nicholas Vanderkooi, Jr.
  • Patent number: 5011877
    Abstract: Disclosed are copolyesters comprising an acid component of 4,4'-biphenyldicarboxylic acid and a glycol component comprising 1,4-cyclohexanedimethanol and 1,6-hexanediol. The copolyesters exhibit unusually high tensile strengths.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: April 30, 1991
    Assignee: Eastman Kodak Company
    Inventors: John C. Morris, Winston J. Jackson, Jr.
  • Patent number: 5011878
    Abstract: Disclosed are copolyesters comprising an acid component of 4,4'-biphenyldicarboxylic acid and a glycol component comprising 1,4-cyclohexanedimethanol and 1,4-butanediol. The copolyesters exhibit unusually high tensile strengths.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: April 30, 1991
    Assignee: Eastman Kodak Company
    Inventors: John C. Morris, Winston J. Jackson, Jr.
  • Patent number: 5011879
    Abstract: An engineering plastic composition with excellent flowability, heat stability, and desirable mechanical properties is provided. The composition comprises an engineering plastic material and at least one p-quaterphenyl derivative of specific formula.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: April 30, 1991
    Assignees: Sekisui Kagaku Kogyo Kabushiki Kaisha, Kabushiki Kaisha Sanko Kaihatsu Kagaku Kenkyusho
    Inventors: Toshio Uesaka, Akihiro Niki, Makoto Ohsuga, Toranosuke Saito, Hiroki Tsunomachi, Makoto Yamaguchi, Kazuo Doyama, Daishiro Kishimoto
  • Patent number: 5008313
    Abstract: An impact modifier for a thermoplastic resin is disclosed, which comprises (I) 100 parts by weight of a graft copolymer formed by graft-polymerizing (B) a monomer having a vinyl group in the molecule onto (A) a butadiene polymer and, incorporated therein, (II) 0.01 to 5 parts by weight of a thioether type heat stabilizer, (III) 0.01 to 5 parts by weight of a phosphite type heat stabilizer and (IV) 0.01 to 5 parts by weight of a phenol type heat stabilizer having a molecular eight of at least 500. A thermoplastic resin composition having this impact modifier incorporated therein exhibits a good heat discoloration resistance and heat deterioration resistance under high-temperature conditions, as well as an improved impact resistance.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: April 16, 1991
    Assignee: Mitsubishi Rayon Company, Ltd.
    Inventors: Kazuo Kishida, Kiyokazu Kitai, Masaaki Mohri
  • Patent number: 5002990
    Abstract: Quickly crystallizing polyester compositions containing as nucleating agent a compound having the formula: ##STR1## wherein: Me is an alkali metal or alkaline-earth metal;X is a group selected from --CH.sub.2 --, --CO--, --CH.sub.2 --CO--, and --CH(CH.sub.3)--CO);p is 0 or 1;Ar is a single or condensed aromatic ring, or Ar represents 2 or more aromatic nuclei linked either by a simple bond or by an --O--, --S--, --SO.sub.2 --, --SO--, --CO--, --CS--, or --NH-- group;R, R.sub.1, R.sub.2 may be, independently of each other, H, a linear or branched C.sub.1 -C.sub.6 alkyl radical, optionally substituted with halogen atoms or C.sub.1 -C.sub.6 alkoxy groups;Y is H or --CH.sub.3 ;m is 1 when Y is --CH.sub.3, or a number from 1 to 5 when Y.dbd.H;n is a number from 1 to 500; andZ is --H, a C.sub.1 -C.sub.18 alkyl, benzyl, allyl, glycidyl, acetyl, --CO--NH--R.sub.3 or --CO--NH--R.sub.4 --NCO group.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: March 26, 1991
    Assignee: Montefibre S.p.A.
    Inventors: Catia Bastioli, Vittorio Bellotti, Nello Gazzarata
  • Patent number: 4992504
    Abstract: Composition containing a chlorine-containing polymer and at least one compound of the formula IA ##STR1## in which R.sup.1 and R.sup.3 independently of one another are C.sub.1 -C.sub.12 alkyl, phenyl, phenyl which is substituted by one to three C.sub.1 -C.sub.12 alkyl groups, C.sub.7 -C.sub.10 phenylalkyl or C.sub.7 -C.sub.10 phenylalkyl which is substituted on the phenyl ring by one to three C.sub.1 -C.sub.12 alkyl groups and R.sup.1 is additionally --R.sup.2 --X--R.sup.3, R.sup.2' is C.sub.1 -C.sub.10 alkylene, R.sup.4 is hydrogen, C.sub.2 -C.sub.5 alkoxycarbonyl or C.sub.2 -C.sub.5 alkanoyl and X is oxygen or sulfur.Compounds of the formula IA in which R.sup.
    Type: Grant
    Filed: January 5, 1990
    Date of Patent: February 12, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Hermann O. Wirth, Hans-Helmut Friedrich
  • Patent number: 4973620
    Abstract: A composition and method for treating fibers is based on a mixture of an organopolysiloxane having at least one amino-substituted hydrocarbon radical directly bonded to a silicon atom and a carboxylic acid containing at least one ethylene oxide unit. The carboxylic acid reacts with the amino radicals to reduce yellowing and oxidation of the fiber treatment. The composition and method provide non-yellowing fibers and a treatment agent that does not gel during use, such as when exposed to carbon dioxide and/or used to treat carbon fibers.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: November 27, 1990
    Assignee: Toray Silicone Company, Ltd.
    Inventors: Isao Ona, Masaru Ozaki, Hidetoshi Kurusu
  • Patent number: 4963598
    Abstract: The invention relates to thermoplastic polycarbonate molding compositions which are rendered resistant to gamma-radiation by incorporating therewith about 0.1 to about 10 percent by weight of a stabilizing agent conforming to ##STR1## wherein R.sub.1 denotes a hydrogen atom or a C.sub.1 -C.sub.4 alkyl, R.sub.2 denotes a hydrogen atom, a C.sub.1 -C.sub.30 alkyl or acyl radical, silyl or pyranyl where said alkyl and acyl radicals may be either branched or linear, n is an integer of from 0 to 70, p is 0 or 1 and m is 1 to 4.
    Type: Grant
    Filed: January 18, 1989
    Date of Patent: October 16, 1990
    Assignee: Mobay Corporation
    Inventors: Sivaram Krishnan, Richard E. Keegan, Neil H. Nodelman, Charles E. Lundy
  • Patent number: 4957960
    Abstract: An encapsulating composition for electronic devices comprises a curable material such as a silicone resin and an ion scavenger compound selected from certain calixarene or oxacalixarene compounds in which at least half of the phenolic groups have been substituted by specific groups and certain silacrown compounds. Exemplary ion scavenger compounds include ##STR1## the tetraethyl acetate of 7, 13, 19, 25-tetra-tertbutyl-27, 28, 29, 30-tetrahydroxy-2,3-dihomo-3-oxacalix-4-arene and 1,1-dimethasila-17-crown-6.
    Type: Grant
    Filed: January 30, 1990
    Date of Patent: September 18, 1990
    Assignee: Loctite (Ireland) Ltd.
    Inventors: Stephen J. Harris, John G. Woods, John M. Rooney, Marueen G. MacManus, John Guthrie
  • Patent number: 4929711
    Abstract: A facile process for converting polyketones to polyesters is provided. The process involves reacting a polyketone, such as an ethylene-carbon monoxide copolymer, with an organic peroxyacid oxidizing agent in an inert liquid medium at a temperature from -20.degree. C. to 150.degree. C. to convert substantially all or only a portion of the keto functionality to ester moieties.
    Type: Grant
    Filed: October 4, 1989
    Date of Patent: May 29, 1990
    Assignee: Quantum Chemical Corporation
    Inventors: Biau-Hung Chang, Lester Y. Lee, Jack Kwiatek
  • Patent number: 4908399
    Abstract: An encapsulating composition for electronic devices comprises a curable material such as an epoxy resin and an ion scavenger compound selected from certain calixarene or oxycalixarene compounds in which at least half of the phenolic groups have been substituted by specific groups and certain silacrown compounds. Exemplary ion scavenger compounds include ##STR1## the tetraethyl acetate of 7, 13, 19, 25-tetra-tertbutyl-27, 28, 29, 30-tetrahydroxy-2,3-dihomo-3-oxacalix-4-arene and 1,1-dimethasila-17-crown-6.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: March 13, 1990
    Assignee: Loctite (Ireland) Ltd.
    Inventors: Stephen J. Harris, Maureen G. MacManus, John Guthrie
  • Patent number: 4889879
    Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 26, 1989
    Assignee: Pluess Staufer AG
    Inventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4882377
    Abstract: A pressure-adherent silicone elastomer composition comprising a homogeneous mixture of a silicone pressure sensitive adhesive composition, a crosslinkable silicone elastomer composition, and, optionally, a viscosity reducing agent. Specifically, the silicone pressure sensitive adhesive composition is a condensation product, having a plasticity of less than 200 mils, of a benzene-soluble resinous copolymer containing silicon-bonded hydroxyl radicals and consisting essentially of triorganosiloxy units of the formula R.sub.3 SiO.sub.1/2 and tetrafunctionalsiloxy units of the formula SiO.sub.4/2 in a ratio of about 0.6 to 0.9 triorganosiloxy units for each tetrafunctionalsiloxy unit present in the copolymer and a polydiorganosiloxane having a viscosity from 100 centipoise to 50,000 centipoise at 25.degree. C.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: November 21, 1989
    Assignee: Dow Corning Corporation
    Inventors: Randall P. Sweet, Patrick J. Miller, Virgil L. Metevia
  • Patent number: 4851462
    Abstract: A solvent based contact adhesive suitable for bonding cured EPDM membranes is disclosed. The adhesive includes a crosslinked halogenated butyl rubber, a low molecular weight, high softening point, thermoplastic aliphatic-type-based hydrocarbon resin and at least one organic solvent employed as a dispersion medium for the crosslinked halogenated butyl rubber and the resin. The disclosed adhesive exhibits superior heat aging and hot water immersion properties which are significant characteristics in roof applications.
    Type: Grant
    Filed: January 21, 1988
    Date of Patent: July 25, 1989
    Assignee: Uniroyal Plastics Company, Inc.
    Inventors: Chester T. Chmiel, David A. Young
  • Patent number: 4788240
    Abstract: Polyorganosiloxane compositions comprising:(A) a polyorganosiloxane having two or more of the following unit, in the molecule, represented by the formula: ##EQU1## wherein, R.sup.1 represents an alkenyl radical; R.sup.2 represents a substituted or unsubstituted monovalent hydrocarbon radical having no unsaturated aliphatic bond; a is an integer of 1 of 2; b is an integer of 0 to 2; and a+b is an integer of 1 to 3;(B) a polyorganohydrogensiloxane, having units represented by the formula: ##EQU2## wherein, R.sup.3 represents a substituted or unsubstituted monovalent hydrocarbon radical; c is an integer of 0 to 2; d is an integer of 1 or 2; and c+d is an integer of 1 to 3,and having at least three hydrogen atoms bonded to silicon atoms in a molecule, in an amount such that the number of the hydrogen atoms bonded to silicon atoms may be 0.5 to 4.0 per R.sup.
    Type: Grant
    Filed: May 28, 1986
    Date of Patent: November 29, 1988
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Tetsuo Fujimoto
  • Patent number: 4731404
    Abstract: The present invention is a composition comprising a linear saturated polyester and from 0.5 to 30 percent by weight of the polyester of at least one ester of a polyfunctional alcohol having a molecular weight of from 900 to about 1,500. The ester is of an alcohol and a carboxylic acid wherein the alcohol has the formulaR.sup.1 [(OR.sup.2).sub.n OH].sub.mwherein R.sup.1 is a hydrocarbon radical of from 3 to 10 carbon atoms, R.sup.2 is a hydrocarbon radical of from 2 to 4 carbon atoms, n can be the same or a different interger of from 2 to 15, m is an integer of from 3 to 6. The alcohol has greater than 20 carbon atoms. The acid is a carboxylic acid of from 1 to 25 and preferably 3 to 10 carbon atoms, and from 1 to 10 carboxyl groups. Preferably the acid has from 3 to 10 carbon atoms and one carboxyl group.
    Type: Grant
    Filed: August 25, 1986
    Date of Patent: March 15, 1988
    Assignee: Allied Corporation
    Inventors: John C. Haylock, Harold W. Tuller, John A. Bander
  • Patent number: 4608409
    Abstract: An ultraviolet curing liquid coating composition is disclosed which, when cured with ultraviolet light in the presence of an appropriate photoinitiator, provides buffer coatings for optical glass fiber having adequate strength at room or expected elevated temperature and stability at such elevated temperature, a high index of refraction above 1.48, and a low tensile modulus which remains low to resist microbending difficulties down to around -60.degree. C. This coating composition consists essentially of a linear polyacrylate-terminated polyurethane or polyurea oligomer having a room temperature tensile modulus of at least 100 psi., and a tensile modulus at -60.degree. C. which is less than 175,000 psi., when capped with 2-hydroxyethyl acrylate and cured with ultraviolet light, in admixture with a liquid acrylate-functional material which does not increase the low temperature hardness and which provides the liquidity needed for coating application.
    Type: Grant
    Filed: May 8, 1985
    Date of Patent: August 26, 1986
    Assignee: DeSoto, Inc.
    Inventors: Clive J. Coady, John J. Krajewski, Timothy E. Bishop
  • Patent number: 4588807
    Abstract: The present invention relates to new benzylidenemalonic or vinylogous benzylidenemalonic acid polyesters containing structural units of the formula (I) ##STR1## their preparation and their use for the UV stabilization of thermoplastics, preferably thermoplastic, aromatic polycarbonates, thermoplastic, aromatic polyesters or thermoplastic polymethylmethacrylates.
    Type: Grant
    Filed: October 17, 1984
    Date of Patent: May 13, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Thomas Scholl, Reinhard Preuss, Burkhard Lachmann, Hartmut Lower, Peter R. Muller