Abstract: The invention relates to plastisols which prevent a yellowing of top coats applied thereon, to a process for their preparation and to their use. The plastisols based on PVC or methacryl contain, in addition to basic adhesion promoters, aldehydes, ketones, their derivatives, oligomers or mixtures of same.

Abstract: A polymeric film has a polyester substrate layer and a cross-linked adherent layer of an acrylic resin and a phthalate ester. The adherent layer exhibits improved adhesion to the substrate and to a range of subsequently applied layers, such as inks, lacquers, and vinyl chloride polymers.

Abstract: Disclosed is a compatibilized carbon black useful in melt processing of plastic material. The carbon black is coated with a compatibilizing agent which enhances the dispersibility of the carbon black in a melt of the plastic material. Further disclosed are processes for making plastic foam structures with the compatibilized carbon black.

Abstract: In a one-part (one-pack) moisture-curing urethane adhesive comprising a urethane prepolymer having isocyanate groups (NCO) at the terminus, said urethane prepolymer being a reaction product of a polyol and an excess amount of a polyisocyanate, the improvement which comprises adding 0.01 to 5% by weight of a gelling agent based on the whole amount of the adhesive, and optionally adding a thermoplastic urethane multi-block copolymer resin and a thixotropic agent selected from the group consisting of a hydrophilic colloidal silica and a polysiloxane-polyoxyalkylene copolymer. The adhesive of the present invention can obviate float or slippage of glass in the adhesive application of window glass of automobiles.

Abstract: There is disclosed a core-shell polymer which comprises:(a) a core layer polymerized from a core forming monomer mainly comprising an aromatic monovinyl monomer; and(b) a shell layer polymerized from a shell forming monomer which comprises:(b1) 25-95% by weight of an aromatic monovinyl monomer as a first monomer;(b2) 5-40% by weight of at least one monomer selected from the group consisting of an .alpha., .beta.-ethylenically unsaturated carboxylic acid and a hydroxyalkyl ester of .alpha., .beta.-ethylenically unsaturated carboxylic acid as a second monomer; and(b3) 0-70% by weight of a third monomer which is other than the first and second monomers and is copolymerizable therewith,wherein the shell layer is contained in an amount of 5-70% by weight based on the core-shell polymer, and the core-shell polymer having a weight average particle size of 0.1-50 micrometers.There is further disclosed a plastisol which comprises the core-shell polymer dispersed in a liquid plasticizer.

Abstract: A thermoplastic elastomer composition comprising 100 parts by weight of a crystalline chlorinated polyethylene with a chlorination degree of from 20 to 45% and a heat of crystal fusion of from 5 to 35 cal/g as measured by a DSC method, obtained by chlorinating a polyethylene having a weight average molecular weight of from 100,000 to 750,000, from 1 to 100 parts by weight of a crystalline polyolefin and from 5 to 200 parts by weight of a plasticizer.

Abstract: A water-sealing sheet comprising a water-swelling resin obtained by kneading together 10 to 97% by weight of a non-water-swelling thermoplastic resin, preferably vinyl chloride resin, containing 80 to 200 parts by weight of a plasticizer based on 100 parts by weight of the non-waterswelling thermoplastic resin, and 3 to 90% by weight of a water-swelling urethane resin. The urethane resin is a prepolymer having isocyanate groups in which the content of terminal NCO groups amounts to 1 to 12%, preferably 2 to 7%, obtained by the reaction of polyisocyanate with at least one polyether polyol of the formulaR[(OR.sub.1)n OH]pwherein R is a polyhydric alcohol residue;(OR.sub.

Abstract: An acrylic resin plastisol composition that forms coatings or molded articles having excellent anticreep property. The plastisol composition maintains excellent fluidity required for the coating and molding even after preserved for extended periods of time and further exhibits excellent gelation property upon heating, enabling the obtained coating or the molded article to exhibit excellent resistance against the relaxation of stress. The plastisol composition comprises a dispersing medium composed chiefly of a plasticizer and acrylic resin grains dispersed in said dispersing medium, wherein said acrylic resin grains have a functional group selected from the group consisting of carboxyl group, hydroxyl group, epoxy group, methylol group and etherified methylol group, and said dispersing medium contains a crosslinking agent that has reactivity to said functional group in a state of being at least partly solubilized in said dispersing medium.

Abstract: A molding compound is disclosed which is useful in producing inorganic sintered moldings, which contains, in addition to an inorganic powder, a binder system containing a thermoplastically processable, partially crystalline polyester and an additional low molecular weight compound which may react with the polyester. A process is disclosed for preparing a sintered molding by injection molding of the molding compound, removal of the binder system, and sintering.

Abstract: A denture base lining material to be used upon mixing a liquid component and a powder component is disclosed, characterized in that the liquid component comprises a phthalic ester-based plasticizer and containing from 5 to 15% by weight of ethyl alcohol and from 5 to 20% by weight of a liquid paraffin or squalane alone or a mixed solution thereof, and the powder component comprises a powder comprising any one of the following powders (a), (b), or (c), or a mixture of two or more thereof: (a) an ethyl methacrylate polymer powder containing from 1 to 5% by weight of a phthalic ester-based plasticizer; (b) a copolymer powder represented by the following formula: ##STR1## wherein n/(m+n) is from 0.15 to 0.55, and containing from 0.5 to 2% by weight of a phthalic ester-based plasticizer; and (c) a mixed powder comprising a polyethyl methacrylate powder having a copolymer powder represented by the following formula mixed therewith: ##STR2## wherein n/(m+n) is from 0.45 to 0.76.

Abstract: A modified vinyl chloride resin composition prepared by adding 1 to 10 parts by dry weight of glue or gelatin to 100 parts by weight of vinyl chloride resin compound shows improved physical properties such as improved cracking resistance when used as the sole of shoes, improved adhesion properties for leather, cold cracking resistance as electric wirecoating material, improved vibration damping properties as vibration-preventing member, and non-slipping properties as power-carrying belt material, and is useful as molding composition for making footwear, coating composition with good cold resistance, belt composition with non-slipping properties, and resin material for preventing vibration having excellent vibration-damping properties.

Abstract: Stereoregular polystyrenes can be combined with a plasticizer to make a non-PVC plastisol with physical properties comparable to PVC-based plastisols.

Abstract: A thermoplastic elastomer composition comprising 100 parts by weight of a vinyl chloride resin, from 20 to 300 parts by weight of a nitrile rubber, from 25 to 200 parts by weight of a plasticizer, from 10 to 200 parts by weight of a filler and a curing agent for the rubber, and being meltable by a roll set at a temperature of 190.degree. C.

Abstract: A functional film-forming paste composition is disclosed, comprising (a) at least one metal-containing organic compound and at least one of (b) an acrylic resin, (c) an unsaturated fatty acid, and (d) an organic acid ester or phosphoric ester, the components (a) to (d) being dissolved in an organic solvent. The paste composition can be calcined at a low temperature, undergoes no change with time, can be printed by any printing method, exhibits good adhesion to a substrate, and gives a film free from unevenness in thickness and from defects such as cracks and pinholes.

Abstract: Copolymers of styrene and sodium styrene sulfonate can be combined with a plasticizer to make a non-PVC plastisol sealant for containers.

Abstract: A blood bag comprises a plastic polyvinyl chloride formulation in which the polyvinyl chloride formulation contains from 5 to 30 percent by weight of a first plasticizer material which is essentially nonextractable by blood plasma stored in the bag up to 35 days at about 4.degree. C.; and from 10 to 25 percent by weight of a second plasticizer which is significantly extracted by blood plasma stored in the bag up to 35 days at about 4.degree. C.

Abstract: A new process for preparing a separation membrane from aminated polysulfone resin or blends of aminated polysulfone-blended materials which utilizes an organic additive having a low or negligible water-solubility (instead of conventional water-soluble organics, polymers, or inorganic salts) in the casting solution. The resulting membrane exhibits high water-permeability and is capable of being formed at a high production rate when using a wet casting machine.

Abstract: A pressure sensitive adhesive composition which can be applied by hot melt techniques to one surface and adhered to a second surface by contact at ambient temperature, to thereby bond the two surfaces together. The adhesive composition is made of certain ethylene/n-butyl acrylate copolymers together with tackifier and optionally, plasticizer.

Abstract: Seals for automotive body applications (such as, windows, hoods, trunks and doors) and building applications (such as, window glazing gaskets and weather strips) should be dimensional stable, provide low compression set, and offer outstanding sealing characteristics over a broad temperature range. They must be capable of sealing out noise, wind and water, while providing long-term ultraviolet light resistance.

Abstract: A light anti-chipping coating consisting of vinyl chloride plastic sol is manufactured by employing a hollow filler as a small portion of the overall filler component. Doing so permits weight reduction without deteriorating the anti-chipping property of the light anti-chipping coating.

Abstract: A fluororubber-containing powder coating composition comprising a fluororubber, an adhesion-preventing material and optionally a cross-linking agent, which composition has an particle size of 10 to 2,000 .mu.m and an apparent density of at least 0.2 g/cc, which provides a homogeneous smooth coated film having no or only a small amount of bubbles.

Abstract: A article of manufacture and composition for preventing a tear, hole or run in hosiery from expanding, wherein the composition comprises:(a) nitrocellulose,(b) resin,(c) dioctylphthalate, and(d) a solvent or solvent mixture.

Abstract: A coating composition and a method of coating with said composition, with the composition comprising a coating especially suited for sealing metal joints and metal roofs that comprises from about 10% to about 20% of a thermoplastic resin, from about 1.5% to about 3% of a plasticizer, from about 10% to about 20% of a synthetic thermo-plastic rubber, and from about 5% to about 20% of a free flowing silica-alumina glass ceramic filler.

Abstract: The subject of this invention is acrylic polymer plastisol compositions, wherein the acrylic polymer component of the plastisol composition is a single-stage methyl methacrylate copolymer derived from methyl methacrylate and a comonomer component comprising isobutyl methacrylate and optionally other comonomer(s). The selection of isobutyl methacrylate as a comonomer with the methyl methacrylate results in good compatibility with a wide range of plasticizers and without undue softness in the resulting plastisol.

Abstract: Compositions, with controlled and programmed hardening, to record mucodynamic dental impressions, characterized in that they comprise:______________________________________ Polyvinyl acetate (PVAc) 50-85% by weight C.sub.3 to C.sub.6 aliphatic ketones 2-25% by weight C.sub.3 to C.sub.8 aliphatic esters 1-25% by weight C.sub.2 to C.sub.10 aliphatic alcohols 1-25% by weight and/or aliphatic ethers Non-toxic, non-aromatic 0.5-10% by weight plasticizing oils selected from the group consisting of dioctyl adipate, glycerol triacetate and polyglycols Non-toxic and non-extractable 0-2% by weight black, yellow, red or white organic pigments or a combination thereof ______________________________________and is free of any gel-forming components, peroxide-based catalysts, aromatic compounds and incompatible plasticizers.

Abstract: This composition comprises a mixture of 20 to 70 parts by weight of polynorbornene, crosslinked or uncrosslinked, 80 to 30 parts by weight of a polymer based on vinyl chloride and of at least one plasticiser customary for polynorbornene and the polymer based on vinyl chloride in an amount sufficient for reducing the glass-transition temperature of polynorbornene down to the range of rubbers. To prepare the thermoplastic composition comprising crosslinked polynorbornene, a mixture of polynorbornene, a polymer based on vinyl chloride, a plasticiser customary for polynorbornene and the polymer based on vinyl chloride and a crosslinking system is kneaded at a temperature sufficiently high and during a period sufficiently long for crosslinking polynorbornene.Applications: Manufacture of flexible tubes, seals for the construction and automobile industries, protective bellows for the automobile industry, injection-moulded articles, such as solid wheels for the toy industry, and the like.

Abstract: Disclosed is a polyvinyl chloride resin powder composition for rotational molding, which is prepared by dry-blending a plasticizer and a stabilizer with a polyvinyl chloride resin followed by incorporating from 0.1 to 5 parts by weight, to 100 parts by weight of the polyvinyl chloride resin, of a finely divided polyvinyl chloride resin having a viscosity average polymerization degree of from 2000 to 5000 into the resulting dry blend. Also disclosed is a method of producing a molded article by subjecting the composition to rotational molding. The composition has good powder flowability for rotational molding, and the molded article from the composition is free from pin holes and blocks on the surface thereof.

Abstract: Method for patterning organic polymer layers comprising the sequential steps:A. Applying to a substrate an unpatterned layer of acidic polymer dissolved in a plasticizer,B. Applying to the unpatterned layer a second patterned layer which is a liquid solution of organic base dissolved in a volatile solvent;C. Heating the patterned layer to effect removal of the volatile solvent from the layer and diffusion of the second layer plasticizer and organic base into the underlying areas of the acidic polymer layer; andD. Washing the layers with aqueous solution to effect solubilization of the acidic polymer underlying the patterned areas and removal therefrom of the solubilized polymer and plasticizers.

Abstract: An acrylic ester copolymer plastisol composition comprises (A) copolymer particles comprising, as the major components thereof, (a) 98 to 50 weight % of an alkyl acrylate unit having an alkyl group of 1 to 8 carbon atoms and/or an alkyl methacrylate unit having an alkyl group of 1 to 8 carbon atoms and (b) 2 to 50 weight % of a diene monomer unit, (B) a plasticizer and, optionally, (C) a vulcanizing agent. Another acrylic ester copolymer plastisol composition comprises (A) copolymer particles comprising an ionic crosslinked copolymer prepared by ionic crosslinking of a copolymer comprising, as the major components thereof, (a) 97 to 50 weight % of an alkyl acrylate unit having an alkyl group of 1 to 8 carbon atoms and/or an alkyl methacrylate unit having an alkyl group of 1 to 8 carbon atoms, (b) 2 to 40 weight % of a diene monomer unit and (c) 1 to 20 weight % of a radical polymerizable unsaturated carboxylic acid unit of 3 to 8 carbon atoms having a carboxyl group and (B) a plasticizer.

Abstract: Molding compositions having high rates of crystallization and suitable for being molded at a temperature of the mold not higher than 100.degree. C. to produce molded articles having an optimal combination of mechanical, physical, thermal properties and of surface appearance, comprising: a linear saturated polyester (A); a salt of a mono- or poly-carboxylic acid (B); an ionomer copolymer containing side carboxylic groups at least partially salified (C), and a solid inert inorganic substance (D) having a particle size not higher than 5 micrometers. Said compositions may be reinforced by reinforcing materials, preferably by glass fibers.

Abstract: An adhesion promoting composition for use on polyolefin substrates which is formulated with a chlorinated polyolefin in a water-based emulsion.

Abstract: A thermoplastic elastomer composition comprising, as the main blend components, 100 parts by weight of a crystalline chlorinated polyethylene with a chlorination degree of from 20 to 45% and a heat of crystal fusion of from 5 to 35 cal/g as measured by a DSC method and from 10 to 75 parts by weight of a plasticizer.

Abstract: In order to provide a filler for degradable plastics which can simplify the stages for producing a degradable plastic, give effective plastic-degradability, and stabilize the quality of the plastic article, the filler is used as a carrier substance and effective biodegradable and/or photodegradable components are adsorbed on the surfaces of the filler particles via a surface treating agent.

Abstract: A coating formulation for secure bonding attachment to surfaces of resilient or flexible articles, including plastic foam articles and comprising a highly adherent and coherent water-based film forming mixture for coating the surface of flexible foam articles. The working solution of the coating preferably has a formulation containing:ComponentAcrylic emulsion;Plasticizer;Coalescing agent;Polyacrylate thickener/rheology modifier;Defoamer;Surfactant;Ammonium hydroxide; andWater.The working solution is applied to the surfaces of the article being treated and the water solvent which is present evaporates at a significantly rapid rate in the ambient to form a thick coating having a substantially dry outer surface. The film remains securely bonded to the article even though flexed and otherwise roughly treated.

Abstract: A quick drying liquid electrical tape formulation having good shelf life. The formulation forms a durable vinyl coating or film on wires, junctions and objects. The formulation is comprised of at least about 10% of a vinyl material effective to achieve the durable vinyl coating. The formulation further includes a thixotropic agent to add body, and a plasticizer to impart flexibility to the vinyl coating. The vinyl material, thixotropic agent and plasticizer are admixed with solvents comprising at least one drying agent. The formulation further including a stabilizing agent and at least one solvent, such that the thixotropic agent and plasticizer enable the application of a satisfactory coating using the formulation.

Abstract: A vinyl chloride resin plastisol can be prepared without the shearing action mixing conventionally required for mixing a resin and plasticizer, merely by immersing in a conventional plasticizer, aggregates in the form of a dry power and having an average diameter of 80 to 700 .mu.m of vinyl chloride resin particles; using a spray drying apparatus to form aggregates having an average diameter in the range from 80 to 700 .mu.m or by adding an organic fluid which is barely soluble in water and does not dissolve or swell the vinyl chloride resin to the aqueous dispersion of the vinyl chloride particles, followed by drying the aggregates thus formed at a temperature of 70.degree. C.or below.

Abstract: Chlorinated polyethylene mastic adhesive compositions, and process for the production of such compositions, formed from chlorinated polyethylene and a compatible plasticizer. These mastic compositions are useful for bonding and sealing together membranes, particularly chlorinated polyethylene membranes, at ambient conditions without application of heat. The ability to form seals of high peel strength in roofing applications without the use of heat is of particular importance. In another embodiment however, cross linking agents can be incorporated within the recipe, and seals of even greater peel strength obtained. Heat is required in the sealing operation in this instance to produce cross linking of the polymer. One thus has the choice of forming adhesives of high peel strength for roofing applications without any necessity of using heat; or, alternatively, to form adhesives of even greater peel strength with the use of heat.

Abstract: An expandable, powder coating composition is disclosed which includes (a) a thermoplastic resin containing a hydroxyl group-containing polymer, (b) a cross-linking agent containing a polyisocyanate compound which is capable crosslinking the thermoplastic resin, (c) a blowing agent, and (d) a mixture of a solid plasticizer such as triphenyl phosphate and a liquid plasticizer such as dioctyl phthalate.

Abstract: Yellowing-resistant, overpaintable plastisol compositions based on vinyl chloride homo- or copolymers which contain optical brighteners and, preferably, strongly acid ion exchangers. They are especially suitable for overpaintable sealers, coatings, and adhesives, and find particular application in automobile body construction.

Abstract: Provided are novel blocked polyisocyanurates to be suitably used as an adhesiveness providing agent, coating material, sealant and crosslinking agent for polymers containing active hydrogens. Also provided are polyvinyl chloride plastisol compositions comprising a polyvinyl chloride resin, the above blocked polyisocyanurate as an adhesiveness providing agent, plasticizer and a specific agent for accelerating dissociation of the blocked polyisocyanurate. These compositions have excellent properties such as high adhesiveness even cured at low temperatures and resistance to yellowing, and are suitably used particularly as sealants for car body.

Abstract: Process for the production of a plasticized polyvinyl butyral particularly used for gluing a base onto glazings. The polyvinyl butyral is obtained by the reaction of a butyric aldehyde with a polyvinyl alcohol, demonstrating a level of hydrolysis greater than 95%, and a viscosity greater than 50 cP, in the presence of an acid catalyst and an emulsifier, the quantity of butyric aldehyde being such that the level of hydroxylation of the polyvinyl butyral obtained is between 22 and 26%.

Abstract: Thioxotropic Fuller's earth clay minerals which are structurally double silica chains linked together through oxygen to form double-ribbed sheets held by aluminum and/or magnesium in octahedral coordination in an amphibole chain are vacuum dried and admixed with a stabilizing fluid, e.g., silicone fluid, to result in new, low moisture content thixotropic agents. The mineral products thus produced are superior thixotropes when compounded in plastics such as plastisols, adhesive sealants, coatings and other organic binder systems which are heat set or heat cured or moisture cured, and compliance coatings.The methods involve reducing the moisture content of Fuller's earth clay, e.g., attapulgite, by (1) heating it under vacuum at an elevated temperature, preferably between 100.degree. C. and 300.degree. C., or (2) heating it at an elevated temperature, preferably between 100.degree. C. and 350.degree. C.

Abstract: A polyvinyl chloride-free plastisol comprisesa) 5 to 50% by weight of a methyl methacrylate-homopolymer or coplymerb) 10 to 50% by weight of a plasticiser,c) 20 to 70% by weight of a fillerd) 2 to 30% by weight of a blocked poly isocyanate, ande) 0.2 to 5% by weight of a polyamine. The plastisol is particularly useful for sealing spot welded joints in, for example, motor vehicle manufacture.

Abstract: Normally water insoluble hot melt adhesive compositions containing structural polymers such as A-B-A block copolymers, butyl rubbers, polyesters, ethylene vinyl acetates, ethylene acrylic acid polymers can be made sensitive to the action of water using an effective water sensitizing amount of a polyalkyloxazoline polymer in the hot melt adhesive. The polyalkyloxazoline polymer can be incorporated into a single phase adhesive composition with the structural polymer using an effective amount of a hydroxyl or carboxylic acid compound.

Abstract: A strippable coating composition is shown for use as a temporary protective coating on a variety of substrates. The composition includes a water based polymeric emulsion which is dispersed in an aqueous carrier to form a stable emulsion. Release aids are incorporated in the composition which allow the protective coating to be removed by peeling or washing off with water.

Abstract: Sheet for safety glazings made of: a) polyvinyl butyral internally plasticized by the presence in the polymer of C.sub.7 to C.sub.15 aliphatic aldehyde groups and b) an external plasticizer in amount sufficient to provide a sheet glass transition temperature of about 25.degree. to 30.degree. C.

Abstract: Disclosed is a viscosity index improver in the form of a high-concentration non-aqueous dispersion of a low-viscosity olefinic polymer and a method of preparing the same.

Abstract: Interpenetrating network polymers (IPN's) are made by admixing polyols, polyisocyanate, and a poly(vinylchloride) plastisol, followed by heating to complete the cure. The resulting polyurethane/poly(vinylchloride) IPN has superior properties as sealant, especially for automotive parts.

Abstract: Disclosed is an anti-stat which is effective in polyvinyl chloride polymeric parts to dissipate charge phenomena occurring at a surface thereof. The anti-stat comprises an ethoxylated fat-forming alcohol and a dibasic acid-capped fat-forming alcohol which is incorporated in an effective amount in the polyvinyl chloride polymeric material.

Abstract: A plasticized polyurethane gel system comprising the reaction product of an isocyanate compound and a polyol in the presence of a plasticizer compound having a total solubility parameter of .[.between about 8.3 and 8.9 or.]. between about 9.1 and 9.7.