Metal Patents (Class 524/301)
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Patent number: 5656646Abstract: Mixtures of(I)polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and(II)(1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising(a) from 10 to 70% by weight of monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acids or the salts thereof and(b) from 30 to 90% by weight of monoethylenically unsaturated C.sub.3 -C.sub.10 -monocarboxylic acids and/or the salts thereof,(2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of(A) monoethylenically unsaturated C.sub.3 -C.sub.10 -carboxylic acids or the anhydrides and/or the salts thereof in the presence of(B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or(3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groupscontain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.Type: GrantFiled: May 22, 1995Date of Patent: August 12, 1997Assignee: BASF AktiengesellschaftInventors: Johannes Perner, Paul Diessel, Helmut Guembel, Walter Denzinger, Heinrich Hartmann, Matthias Kroner
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Patent number: 5624982Abstract: A stabilizer system for the suppression of yellowing in styrenic polymers, consisting essentially of a benzotriazole such as 2-(2'-hydroxy-3',5'-di-tert-amylphenyl)benzotriazole, a hydroxybenzocyanurate such as tris-(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate and a hindered amine light stabilizer selected from the group consisting of (i) bis (2,2,6,6,-tetramethyl-4-piperidinyl) sebacate; and (ii) bis-(1,2,2,6,6-pentamethyl-4-piperdinyl) ester of (3,5-di-tert-butyl-4-hydroxybenzyl)-butyl malonate. Additionally a dialkyl thiodipropionate and a zinc dialkyldithiocarbamate may be included in the stabilizer system.Type: GrantFiled: October 30, 1995Date of Patent: April 29, 1997Assignee: Bayer Antwerpen SA/NVInventors: Moh C. O. Chang, Chuan-Ju Chen, Allen R. Padwa
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Patent number: 5607729Abstract: A gel-free silica acrylate curable coating composition made from one or more of soluble salts, soaps, amines, nonionic and anion surfactants, acids or mixtures thereof, and a method for producing these compositions.Type: GrantFiled: February 26, 1996Date of Patent: March 4, 1997Assignee: General Electric CompanyInventor: George F. Medford
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Patent number: 5539034Abstract: A stable composition having a deodorizing action includes a sequenced polyetheresteramide polymer and an undecylenic acid or a lipid-soluble or water-soluble derivative thereof. Suitable derivatives include the C.sub.1 to C.sub.6 alkyl esters of undecylenic acid.Type: GrantFiled: June 5, 1995Date of Patent: July 23, 1996Assignee: ELF Atochem S.A.Inventors: Henri J. Caupin, Roland Leroux
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Patent number: 5536767Abstract: A zinc mercaptoacid ester of a polyhydric alcohol or ether, carboxylate, or ether-carboxylate thereof having at least one functional hydroxy group are improved heat stabilizers for halogen-containing polymer compositions. The phenomenon known as zinc burn during processing of such compositions is eliminated. Zinc bis-thioglycolates, zinc mercaptopropionates and zinc bis-mercaptosuccinates of glycols, glycerol, glycol ethers, glycol carboxylates, and glycerol carboyxlates exemplify the new class of heat stabilizers.Type: GrantFiled: March 10, 1995Date of Patent: July 16, 1996Assignee: Morton International, Inc.Inventors: George F. Beekman, Keith A. Mesch, Lionel R. Price
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Patent number: 5492948Abstract: A stabilizer system for the suppression of yellowing in styrenic polymers, consisting essentially of a benzotriazole such as 2-(2'-hydroxy-3',5'-di-tert-amylphenyl)benzotriazole, a hydroxybenzocyanurate such as tris-(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate and a condensation product of a N,N'-(2,2,6,6-tetramethylpiperidyl)-alkylenediamine and a 6-amino-2,4-dichloro-1,3,5-s-triazine such as the condensation product of N,N'-(2,2,6,6-tetramethylpiperidyl)hexamethylenediamine and 6-morpholino-2,4-dichloro-1,3,5-s-triazine. Additionally a dialkyl thiodipropionate and a zinc dialkyldithiocarbamate may be included in the stabilizer system.Type: GrantFiled: January 9, 1995Date of Patent: February 20, 1996Assignee: Monsanto CompanyInventors: Moh C. O. Chang, Chuan-Ju Chen, Allen R. Padwa
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Patent number: 5420188Abstract: The present invention is directed to a mold release, a composition containing the mold release, and a process of using the mold release. The mold release comprises an internal mold release composition comprising(a) a zinc carboxylate containing from 8 to 24 carbon atoms per carboxylate group, and(b) a compatibilizer comprising an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may be substituted by ether groups, ester groups, amide groups or amidine groups and may also be terminated by isocyanate-reactive groups such as hydroxyl or amino groups, R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3, with the proviso that when R.sub.4 represents the group --NR.sub.2 R.sub.3, R.sub.1 can be hydrogen, and wherein R.sub.Type: GrantFiled: December 31, 1992Date of Patent: May 30, 1995Assignee: Miles Inc.Inventor: John E. Dewhurst
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Patent number: 5415895Abstract: A process for manufacturing a dry-to-touch coating having corrosion resistance and torque is provided. The process comprises the steps of adding PTFE to an oil, with the oil containing a amine soap, thoroughly mixing the PTFE into the oil, forming a homogenous dispersion of the PTFE in the oil, mixing a resin forming paint component, adding water to the mixed paint component, mixing the resin forming paint component and water with the oil, and adjusting the pH. The resin forming paint component comprises in the range of 40% to 70% of the coating, the water comprises in the range of 5% to 10% of the coating, and the oil and PTFE blend comprises in the range of 10% to 30% of the coating. Additionally, the PTFE when added to the oil preferably comprises in the range of 10% to 30% by weight. The process further involves the exposure of the resin, water, and oil mixture to a temperature of between 175.degree. to 250.degree. F. until it is dry-to-touch.Type: GrantFiled: June 25, 1993Date of Patent: May 16, 1995Assignee: Texo CorporationInventor: Edmund W. Kinkelaar
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Patent number: 5393808Abstract: A composition of matter especially for the formation and development of wear surfaces of decorative or aesthetic character is provided which comprehends a matrix and discrete reforcing elements embedded in the matrix. The matrix is resin-based with the resin being hydrogenated bis-phenol A which is mixed with a suitable low profile additive, a catalystic agent, a flame retardant, an extender, and a inhibitor while the reinforcer is constituted of glass fiber particles.Type: GrantFiled: June 9, 1994Date of Patent: February 28, 1995Assignee: The Swan CorporationInventors: Anthony Buonaura, John W. Moore
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Patent number: 5332772Abstract: The preparation of a zinc mercaptoacid ester by the reaction of zinc oxide with the mercaptoacid ester in a wax matrix provides an improved heat stabilizer for halogen-containing polymer compositions. The process obviates the necessity of isolating and transporting the normally very viscous zinc mercaptoacid esters. The zinc mercaptoacid ester/wax matrix is also an expedient medium for the preparation and utilization of calcium stearate as a lubricant in the heat stabilizer composition and the stabilized polymer composition containing it. A paraffin wax is the preferred matrix for the preparation and use of the heat stabilizer and lubricant.Type: GrantFiled: May 5, 1993Date of Patent: July 26, 1994Assignee: Morton International, Inc.Inventors: George F. Beekman, Lionel R. Price, Keith A. Mesch
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Patent number: 5283267Abstract: The polypropylene resin composition of the present invention comprises specific proportions of a crystalline ethylene-propylene block copolymer, an hydrogenated block copolymer, an amorphous ethylene-propylene copolymer, surface-treated talc, fibrous magnesium oxysulfate of granular form and a metal soap. This resin composition is well balanced in rigidity and impact resistance, has good mar resistance, and can be preferably used in large-sized parts for automobiles, particularly instrument panels for automobiles.Type: GrantFiled: December 21, 1990Date of Patent: February 1, 1994Assignee: Ube Industries, Ltd.Inventors: Takeyoshi Nishio, Norihisa Tamashima, Kouhei Ueno, Tomohiko Akagawa, Saburo Hinenoya, Shinji Katsui
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Patent number: 5248715Abstract: Liquid silicone compositions are described that cure to rubber which exhibits a unique combination of properties including low compression set and unprimed adhesion to a variety of substrates. The compositions include silicone polymers curable by hydrosilation reaction and specific combinations of adhesion promoting materials. Compositions containing aluminum chelates and epoxytrialkoxysilanes have been found particularly useful when adhesion to metal substrates is desired. When the compositions are desired to adhere to plastic materials, it is advantageous to include along with the aluminum chelate and epoxytrialkoxysilane, a tetraalkyltitanate, an alkylpolysilicate, and an acrylate or methacrylate compound.Type: GrantFiled: July 30, 1992Date of Patent: September 28, 1993Assignee: Dow Corning CorporationInventors: Thomas E. Gray, Michael E. Kunselman, Richard A. Palmer, William J. Schulz, Jr.
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Patent number: 5141977Abstract: Aqueous polymer composition for application to synthetic polymeric materials to improve wettability of same by polymer matrices and bond strength therebetween, which includes a polymer containing vinyl groups, in at least one and preferably two fluorocarbon surfactants and water. The composition also optionally, and preferably includes a copolymerizable surfactant and ethoxy silicone. Synthetic polymeric materials treated with the aqueous polymer composition are disclosed primarily as reinforcing materials in structural composites, either alone or in conjuction with other reinforcing materials. Composites utilizing the pretreated reinforcing materials are also included.Type: GrantFiled: May 2, 1989Date of Patent: August 25, 1992Assignee: ABCO Industries, Ltd.Inventors: James M. Self, Paul C. Fleischer
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Patent number: 5110892Abstract: Stirrable reactive polyurethane adhesive compositions are packaged in a single container by separating the reactive components with a disperable barrier layer so as to delay reaction until the entire adhesive composition is stirred together.Type: GrantFiled: December 18, 1990Date of Patent: May 5, 1992Assignee: National Starch and Chemical Investment Holding CorporationInventor: Malcolm Graham
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Patent number: 5055495Abstract: An improvement in the method for the foaming of polyvinylchloride resins by the use of a blowing agent and an activator therefor which uses as the activator a mixture of at least one organotin mercapto acid ester and a diorganotin oxide complex with an ester of an oxygen-containing acid.Type: GrantFiled: August 8, 1990Date of Patent: October 8, 1991Assignee: Witco CorporationInventors: Michael R. Croce, Stuart D. Brilliant
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Patent number: 4977193Abstract: An improvement in the method for the foaming of polyvinylchloride resins by the use of a blowing agent and an activator therefor which uses as the activator a mixture of at least one organotin mercapto acid ester and a diorganotin oxide complex with an ester of an oxygen-containing acid.Type: GrantFiled: May 4, 1990Date of Patent: December 11, 1990Assignee: Witco CorporationInventors: Michael R. Croce, Stuart D. Brilliant
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Patent number: 4839409Abstract: Compositions for stabilizing rigid (unplasticized) halogen-containing organic polymers against the deteriorative effects of heat, ultra-violet light and weathering comprise organotin or non-tin metal salt primary heat stabilizers in combination with esters of polyhydrocarbyl ether glycols.Type: GrantFiled: September 17, 1987Date of Patent: June 13, 1989Assignee: Morton Thiokol, Inc.Inventor: Gary M. Conroy
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Patent number: 4808649Abstract: Diorganopolysiloxanes having the formula: ##STR1## are especially useful for the stabilization of polyvinyl chloride-based polymers.Type: GrantFiled: August 12, 1987Date of Patent: February 28, 1989Assignee: Rhone-Poulenc ChimieInventors: Michel Gay, Edith Canivenc
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Patent number: 4792579Abstract: There is disclosed a stabilized oxymethylene copolymer composition comprising a blend of an oxymethylene copolymer and an alkaline earth metal salt of an ester of a tribasic inorganic acid of an organic carboxylic acid monoester of an alcohol having two or more hydroxyl groups, as the stabilizer.Type: GrantFiled: February 19, 1988Date of Patent: December 20, 1988Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Seinosuke Satoh, Minoru Hamada
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Patent number: 4788106Abstract: A curable composition comprising (A) a siloxane-polyester copolymer, (B) one or more solvents for the siloxane-polyester copolymer, (C) a silane having silicon-bonded alkoxy or alkoxy-alkoxy groups and a silicon-bonded substituent containing an epoxy group, (D) aluminium acetylacetonate and (E) a tetraalkyl titanate.The compositions are heat-curable and are useful for the formation of protective and decorative coatings on substrates such as metals and plastics.Type: GrantFiled: February 8, 1988Date of Patent: November 29, 1988Assignee: Dow Corning, Ltd.Inventor: Anthony G. Short
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Patent number: 4755549Abstract: A stabilizer system for stabilizing polyvinyl chloride molding compositions contains at least one zinc compound of the formulasR.sup.1 O--Zn--OR.sup.2 (I)R.sup.3 S--Zn--SR.sup.4 (II), orR.sup.5 O--Zn--SR.sup.6 (III)and one or more polyoxazolines or copolyoxazoline of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, and n are described herein. The stabilized molding compositions exhibit a good initial color, transparency and long-term stability.Type: GrantFiled: July 16, 1987Date of Patent: July 5, 1988Assignee: Huels AktiengesellschaftInventors: Bruno Kemper, Heimo Bieringer
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Patent number: 4749506Abstract: A microgel dispersion characterized by that an oil-soluble surface active agent is adsorbed or adhered onto a gel consisting of a fine particle substance and a polymer, and said gel is dispersed in a non-aqueous organic solvent.Type: GrantFiled: September 19, 1985Date of Patent: June 7, 1988Assignee: Ricoh Co., Ltd.Inventors: Ayao Kitahara, Kijiro Konno
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Patent number: 4696754Abstract: Compositions comprising a combination of a dihydrocarbyl ester of maleic acid and a metal salt of a monohydrocarbyl ester of maleic acid are useful as lubricant-stabilizers for halogen-containing organic polymers and provide unique lubricating-stabilizing characteristics to polymers stabilized therewith.Type: GrantFiled: August 11, 1986Date of Patent: September 29, 1987Assignee: Morton Thiokol, Inc.Inventors: Gary M. Conroy, Karl R. Wursthorn
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Patent number: 4670523Abstract: A magnet wire enamel having improved runnability and insulating properties is described comprising nylon containing 0.25% to 20% by weight titanium chelate. The nylon can be a sole coat, outermost coating, or bond coat.Type: GrantFiled: July 19, 1985Date of Patent: June 2, 1987Assignee: Essex Group, Inc.Inventor: Francois A. Lavallee
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Patent number: 4617334Abstract: Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic antimony compound or mixture of organic antimony compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and (3) a metal mercaptoalcohol or mixture of metal mercaptoalcohols. Also provided are polymer compositions containing said stabilizers, a process for stabilizing polymers, and articles of manufacture made from stabilized polymer compositions.Type: GrantFiled: September 24, 1984Date of Patent: October 14, 1986Assignee: Morton Thiokol, Inc.Inventors: Thomas G. Kugele, Keith A. Mesch, Karl R. Wursthorn
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Patent number: 4547542Abstract: This invention relates to unique and novel compositions based on chemically combining a sulfonated polymer and an amine terminated polylactone composition. The resulting amine neutralized sulfonated polymer compositions have a variety of uses including those as diverse as adhesive agents, thermoplastic elastomers, additive uses wherein these materials can be utilized to compatibilize two different polymers which are normally incompatible. These compositions can also be blended with fillers and/or oils when the sulfonated polymer is elastomeric. The materials display thermoplastic character.Type: GrantFiled: December 23, 1983Date of Patent: October 15, 1985Assignee: Exxon Research and Engineering Co.Inventors: Robert D. Lundberg, Warren A. Thaler
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Patent number: 4515916Abstract: Compositions are provided which are effective for stabilizing halogen containing polymers against the deteriorative effects of heat. These stabilizer compositions comprise (1) at least one zinc mercaptoester, (2) at least one basic inorganic alkali or alkaline earth metal compound, and, optionally, (3) at least one substituted dihydropyridine.Type: GrantFiled: February 6, 1984Date of Patent: May 7, 1985Assignee: Morton Thiokol Inc.Inventor: Kenneth R. Molt
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Patent number: 4440674Abstract: A vinyl halide resin stabilizer composition which essentially contains:(a) an antimony organic sulfur-containing compound, for example, antimony mercaptoacid esters, antimony alkyl mercaptides, and the like,(b) an alkaline earth metal salt of a carboxylic acid, such as calcium stearate, and(c) an alkali metal carbonate, such as sodium carbonate.These compositions synergistically contribute to the dynamic processing stability of vinyl halide resin compositions. Rigid polyvinyl chloride compositions are stabilized against dynamic processing conditions of heat and shearing forces.Type: GrantFiled: August 8, 1980Date of Patent: April 3, 1984Assignee: Dart Industries Inc.Inventors: Dale J. Dieckmann, Charles W. Fletcher
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Patent number: 4432821Abstract: The present invention is directed to a brazing material for joining graphite structures that can be used at temperatures up to about 2800.degree. C. The brazing material formed of a paste-like composition of hafnium carbide and uranium oxide with a thermosetting resin. The uranium oxide is converted to uranium dicarbide during the brazing operation and then the hafnium carbide and uranium dicarbide form a liquid phase at a temperature about 2600.degree. C. with the uranium diffusing and vaporizing from the joint area as the temperature is increased to about 2800.degree. C. so as to provide a brazed joint consisting essentially of hafnium carbide. This brazing temperature for hafnium carbide is considerably less than the eutectic temperature of hafnium carbide of about 3150.degree. C.Type: GrantFiled: August 10, 1982Date of Patent: February 21, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: Albert J. Taylor, Norman L. Dykes
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Patent number: 4430471Abstract: The malodor in polymers based on thiodiethanol and elastomers produced therefrom is reduced by the incorporation of various metal salts of Group IB, IIB or VIII of the Periodic Table therein.Type: GrantFiled: May 24, 1982Date of Patent: February 7, 1984Assignee: American Cyanamid CompanyInventors: Richard B. Toothill, Ignazio S. Megna, Ajit K. Chaudhuri
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Patent number: 4394325Abstract: Provided are organic antimony compound compositions comprising (a) at least one organic antimony compound having at least one antimony-sulfur-carbon (i.e. Sb-S-C) linkage and as a stabilizer therefor, (b) elemental sulfur. Also provided are stabilized organic polymer compositions comprising a halogen containing polymer and said organic antimony compound-elemental sulfur compositions.Type: GrantFiled: November 27, 1981Date of Patent: July 19, 1983Assignee: Carstab CorporationInventors: Robert E. Bresser, Sidney S. White, Jr., Arthur F. Koeniger
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Patent number: 4391757Abstract: In accordance with this invention there are provided organic antimony stabilizer compositions effective in stabilizing halogen containing organic polymers against the deteriorative effects of heat comprising (1) at least one organic antimony compound having at least one antimony to sulfur to carbon (i.e. Sb-S-C) linkage, (2) elemental sulfur, and (3) at least one 2-mercaptocarboxylic acid. Said 2-mercaptocarboxylic acid and elemental sulfur also serve to provide hydrolytic and UV light stability to the antimony compound per se. Also provided are stabilized organic polymer compositions comprising a halogen containing polymer and said organic antimony stabilizer composition.Type: GrantFiled: November 27, 1981Date of Patent: July 5, 1983Assignee: Carstab CorporationInventors: Thomas G. Kugele, Dennis W. Gilmore
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Patent number: 4380597Abstract: A stabilized thermoplastic composition comprised of polyvinyl chloride or mixed polymers containing mainly vinyl chloride units together with stabilizers and other conventional additives employed in thermoplastic compositions, which have as major stabilizer component, a content of 0.02 to 5 parts by weight of aliphatic polyhydroxyl compounds containing 4 to 6 OH-groups per 100 parts by weight of polymer. These polyhydroxyl compounds should contain at least one carboxyl and/or carbonyl group and/or double bond. Suitable compounds are gluconic acid, glucuronic acid, ketogluconic acid, ascorbic acid or the alkali metal salts or alkaline earth salts of the mentioned acids.Other conventional processing additives may be present. The invention concerns also a process for the manufacture of pipes, profiles, foils, hollow parts by hot forming, with the use of the mentioned additives, and the additional use of paraffin, free fatty acid, epoxidized soybean oil or higher molecular weight ester wax.Type: GrantFiled: October 21, 1981Date of Patent: April 19, 1983Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Werner Erwied, Bernd Wegemund
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Patent number: 4367304Abstract: Compounds of the formula I, II, III or IV ##STR1## wherein X is halogen, OH, --OR.sup.1, --OOCR.sup.2, --OOC--R.sup.4 --COOR.sup.3 or --N(R.sup.5)(R.sup.6), or the two X groups together form a group --O--R.sup.9 --O-- or --OOC--R.sup.9 --COO--, Y has one of the meanings given for X, or it is --NHR.sup.5, --NHNH.sub.2 or --NHNH-phenyl, Z has one of the meanings given for X, or is --SR, and R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.9 and R' are organic radicals having the meanings defined hereinbelow, are thermal stabilizers for chlorine-containing thermoplastics particularly for PVC. Their effect can be further intensified by the addition of co-stabilizers.Type: GrantFiled: November 4, 1980Date of Patent: January 4, 1983Assignee: Ciba-Geigy CorporationInventors: Klaus-Peter Michaelis, Wolfgang Wehner, Holger Andreas, Horst Muller
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Patent number: 4350655Abstract: There is disclosed a novel process for the cold stretching at high stretch tension and at low stretch ratios of a film of a blend of synthetic orientable thermoplastic polymer and at least 50 weight percent of a coated inorganic filler selected from the group consisting of calcium carbonate, clays and titanium oxide and coated with a fatty acid ester of silicon and titanium to form a highly porous thermoplastic film (i.e. 10,000 to 100,000 surface ruptures/mm.sup.2) exhibiting paper-like properties.Type: GrantFiled: June 25, 1980Date of Patent: September 21, 1982Assignee: Biax FiberfilmInventor: William H. Hoge
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Patent number: 4336168Abstract: Shelf-stable liquid antimony stabilizer compositions for vinyl halide resin compositions comprise a liquid antimony organic sulfur- and/or oxygen-containing compound, such as antimony tris-(isooctyl thioglycolate), and a stabilizing amount of an acidic organic compound that may be a mercaptoacid ester, mercaptan, mercaptoacid, mercaptoalcohol, monocarboxylic acid, or a mixture thereof.Type: GrantFiled: April 28, 1980Date of Patent: June 22, 1982Assignee: Tenneco Chemicals, Inc.Inventors: Samuel Hoch, Mario Q. Ceprini