Abstract: Polyester-based films contain certain copolyesters (A) and polyester plasticizers (B). The copolyesters (A) may be selected from those in which the force required to stretch a film of the copolyester (A) by itself, from 2× to 5×, increases by less than 200%. The polyester plasticizers (B) have a weight-average molecular weight of 900 to 12,000 g/mol, and contain (i) a diol component comprising residues of diols having 2 to 8 carbon atoms, and (ii) a diacid component comprising residues of dicarboxylic acids having 4 to 12 carbon atoms. These polyester-based films are particularly useful for preparing ultra-thin LCD or OLED polarizers, because they can be stretched very thin with a high stretch ratio at lower temperatures.

Abstract: The present invention provides a rubber composition for treads, containing: a rubber component including an isoprene-based rubber and polybutadiene rubber; silica; carbon black; a terpene-based resin; and a water-soluble fine particle and/or a foaming agent, the terpene-based resin having a softening point of 70-150° C., an ?-pinene unit content of 65-100% by mass, and a ?-pinene unit content of 0-35% by mass, the rubber component including, based on 100% by mass thereof, 20-80% by mass of the isoprene-based rubber and 20-80% by mass of the polybutadiene rubber, with a combined amount of the isoprene-based rubber and the polybutadiene rubber of 90% by mass or more, the rubber composition containing, per 100 parts by mass of the rubber component, 20-200 parts by mass of the silica, 0.1-50 parts by mass of the carbon black, and 0.1-50 parts by mass of the terpene-based resin.

Abstract: The invention relates to blends containing polymers of vinylidene fluoride, having low ductile-brittle transition temperatures and having excellent low temperature impact properties while maintaining the positive aspects of unmodified vinylidene fluoride-containing polymers. The blends of this invention are produced by adding a core-shell impact modifier (CSIM) comprised of a polysiloxane core and a shell compatible with vinylidene fluoride-containing polymer. The blends are further characterized by the presence of a heterogeneous copolymer composition comprised of two or more distinct phases and/or at least one flame and smoke suppressant. The preparation of these new blends can be done by conventional thermoplastic compounding techniques such as twin screw compounding; alternatively, the CSIM can be introduced earlier, such as in the latex.

Abstract: Tripentyl esters of trimellitic acid, especially mixtures of triisopentyl esters of trimellitic acid comprising isomeric pentyl radicals in which more than 5 mol % of the isomeric pentyl radicals incorporated in the ester mixture are branched, have good compatibility with PVC and PVC-containing polymers and simultaneously exhibit a lesser tendency to migrate.

Abstract: This disclosure provides a process for producing vinylidene dimer derivatives by subjecting one or more vinylidene dimers and one or more carbonyl-containing compounds to a carbonyl-ene reaction, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure also provides a process for producing vinylidene dimer derivatives by reacting one or more vinylidene dimers with one or more carbonyl-containing compounds, optionally in the presence of a catalyst, to produce one or more vinylidene dimer derived alcohols. This disclosure further provides vinylidene dimer derivatives (e.g., vinylidene dimer derived alcohols and esters) produced by these processes. This disclosure still further provides for hydrogenating/reacting the vinylidene dimer derived alcohols with acids or anhydrides to produce vinylidene dimer derived esters.

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

Abstract: The present invention relates to polyester polyols made from aromatic polyacid sources such as thermoplastic polyesters. The polyols can be made by heating a thermoplastic polyester such as virgin polyethylene terephthalate, recycled polyethylene terephthalate, or mixtures thereof, with a glycol to give a digested intermediate which is then reacted with a digestible polymer, which can be obtained from various recycle waste streams. The polyester polyols comprise a glycol-digested polyacid source and a further digestible polymer. The polyester polyols provide a sustainable alternative to petrochemical or biochemical based polyester polyols.

Abstract: A thermosetting powder coating material includes a thermosetting resin, a thermosetting agent, and metal salt containing an alkyl group having 5 to 20 carbon atoms.

Abstract: Provided is a polybutylene terephthalate resin composition having excellent mold releasability, measurement stability and hydrolysis resistance, and exhibiting minimal discoloration under high-temperature conditions. The polybutylene terephthalate resin composition contains: (A) a polybutylene terephthalate resin, (B) a higher fatty acid ester of pentaerythritol, and (C) a low-molecular weight polyethylene having a number-average molecular weight of 3,000 to 7,000. It is preferable that the component (B) is pentaerythritol tetrastearate, and that the component (C) is a low-molecular weight polyethylene having a number-average molecular weight of 4,500 to 5,500.

Abstract: A formulation for the preparation of a wiping blade element for a vehicle windscreen wiper blade is disclosed. The formulation has an elastomer material based on chloroprene rubber in which plasticizing additives are incorporated, where the plasticizing additives include a combination of at least a first additive, the pour point of which is less than ?50° C., and at least a second additive, the pour point of which is greater than ?50° C. The first additive is octyl sebacate in a proportion of 4 phr and the second is a naphthalic oil plasticizer or a C18-C30 tricarboxylic ester in a proportion of 10 phr.

Abstract: Described is a solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer component composed of (A1) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of 15° C. to 100° C., and (A2) at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of ?100° C. to ?20° C.; (B) a crosslinker component comprising at least one crosslinking agent having functional groups that are reactive toward OH groups; and also (C) at least one polyamide; and (D) at least one urea compound, which is an adduct of a polyisocyanate and methoxypropylamine. Also described is a process for preparing the solvent-containing clearcoat coating composition, to the use of the solvent-containing clearcoat coating composition and a clearcoat which has been produced using the clearcoat coating composition.

Abstract: Plasticizing system which can be used in particular for the plasticizing of a tire diene elastomer composition containing, in combination: a plasticizing hydrocarbon resin, the glass transition temperature of which is greater than 0° C.; and a tri- or pyromellitate ester corresponding to the formula (I): in which the R radicals, which are identical or different, represent a hydrocarbon radical and the R? radical represents hydrogen or COOR group. Also, a rubber composition incorporating the plasticizing system and the use of such a composition for the manufacture of a tire or tire semi-finished product made of rubber, in particular of a tire tread, exhibiting an improved wear resistance without having a detrimental affect on its wet grip.

Abstract: Compositions of biobased polymer blends of polymers and a polyhydroxyalkanoate copolymer are described. In certain embodiments, the copolymer is a multiphase copolymer blend having one phase a glass transition temperature of about ?5° C. to about ?50° C. Methods of making the compositions of the invention are also described. Also articles, films and laminates made from the compositions are described.

Abstract: The present invention relates to a polymer composition including a transparent thermoplastic plastic, an inorganic infrared absorber, also referred to as IR absorber hereinbelow, optionally an inorganic nano-scale pigment, and the combination of at least one organic coloring agent of a specific structure, and to the preparation and use of the polymer compositions according to the invention and to products produced therefrom.

Abstract: A solvent-less liquid ethylene propylene diene rubber compound and a solvent-less liquid ethylene propylene rubber compound are provided. The compounds can include a liquid ethylene propylene diene or a liquid ethylene propylene mixed with a filler system, a plasticizer, and a cross-linking agent to form the compound. The compound can have a viscosity ranging from 150,000 centipoises to 750,000 centipoises at a temperature of 23 degrees Celsius, allowing the compound to be liquid injection moldable. The compound can contain substantially no solvent.

Abstract: The present invention provides a resin composition for flooring characterized in that it comprises a PLA resin, a plasticizer, and an acrylate oligomer. Also, the present invention provides a method for manufacturing flooring, comprising the step of processing flooring which includes a sheet-like molded body of the resin composition and manufacturing the sheet-like molded body by processing the resin composition through extrusion or calendaring methods.

Abstract: The present invention relates to a process for the preparation of compositions comprising vinyl aromatic copolymers prepared by the emulsion polymerisation process and having salt inclusions resulting from their preparation, which compositions are distinguished by an improved surface quality after storage under warm moist conditions and in that respect are suitable for the production of molded bodies having a class A surface.

Abstract: Fibrous insulation products have an aqueous binder composition that includes a carbohydrate and a crosslinking agent. In exemplary embodiments, the carbohydrate-based binder composition may also include a catalyst, a coupling agent, a process aid, a crosslinking density enhancer, an extender, a moisture resistant agent, a deducting oil, a colorant, a corrosion inhibitor, a surfactant, a pH adjuster, and combinations thereof. The carbohydrate may be natural in origin and derived from renewable resources. Additionally, the carbohydrate polymer may have a dextrose equivalent (DE) number from 2 to 20. In at least one exemplary embodiment, the carbohydrate is a water-soluble polysaccharide such as dextrin or maltodextrin and the crosslinking agent is citric acid. Advantageously, the carbohydrates have a low viscosity and cure at moderate temperatures. The environmentally friendly, formaldehyde-free binder may be used in the formation of insulation materials and non-woven chopped strand mats.

Abstract: The present invention provides an aqueous dispersion type adhesive which is excellent in adhesion and is accurately ejected through a nozzle without fouling the nozzle when the adhesive is applied by a nozzle coater, and a paper product obtainable by applying the aqueous dispersion type adhesive. An aqueous dispersion type adhesive including an ethylene-vinyl acetate based modified emulsion and a plasticizer, the plasticizer containing an acetyl group-containing compound, is excellent in adhesive strength and does not cause fouling of a nozzle when the adhesive is ejected through the nozzle of a nozzle coater. When the acetyl group-containing compound contains triacetin, adhesion between a paper and a metal foil is improved, and thus fouling of a nozzle is less likely to occur. Moreover, when the ethylene-vinyl acetate based modified emulsion contains a modification having a carboxyl group attached thereto, fouling of a nozzle is much less likely to occur, preferably.

Abstract: Disclosed herein are blended thermoplastic compositions comprising at least one polycarbonate polymer, at least one polyester polymer, and at least one reinforcing filler. The thermal blended polycarbonate compositions can optionally further comprise at least one polycarbonate-polysiloxane copolymer, at least one impact modifier polymer, and/or at least one flame retardant. The resulting compositions can be used in the manufacture of articles requiring materials with high modulus and high flowability, while retaining good impact strength. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Abstract: An adhesive composition is provided that is water-insoluble yet water-absorbent, i.e., capable of absorbing up to 15 wt. % water or more. The composition in composed of a film-forming hydrophilic polymer with at least one linear segment having a plurality of recurring polar groups along the polymer backbone, a complementary multifunctional polymer with a plurality of recurring functional groups that noncovalently bind to the polar groups on the film-forming polymer, and plasticizer. A method for manufacturing the adhesive composition is provided as well.

Abstract: The invention relates to a plastic material comprising a composition Z comprising the components A, B, C and D, the component A being a polyester, the component B being a polyamide, the component C being a transition metal catalyst, the component D being an organic compound selected from the group consisting of paraffins, vegetable oils, polyalkylene glycols, esters of polyols, alkoxylates, and mixtures of these substances.

Abstract: The present invention provides a biodegradable resin composition which is modified through a thermally initiated cross linking reaction and comprising a PLA resin, a thermal initiator, and a cross linked monomer. Also, the present invention provides an eco-friendly biodegradable sheet manufactured by extruding the biodegradable resin composition or by processing the biodegradable resin composition using a calendaring method.

Abstract: Provided herein are compounds of the formula: in which n is an integer equal to or greater than 1; m is an integer equal to or greater than 1; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R1, R3, and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein at least one of R1, R2, R3, or R4 is sulfurized or epoxidized. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.

Abstract: A process for the preparation of a compound can have the formula wherein R1, R2 and R3 are independently selected from hydrogen and acyl groups, wherein at least one of R1, R2 and R3 is a branched chain long acyl group of the formula wherein n is from 9 to 21 and m is 2n, and wherein p is from 0 to 4, wherein the other of R1, R2 and R3 are selected from short acyl groups of the formula wherein q is from 0 to 4; the process comprising the steps of: (1) providing an unsaturated compound having the formula (2) if at least one of R1, R2 and R3 is hydrogen, optionally acylating the compound; and (3a) (i) hydroxylating the unsaturated long acyl group and (ii) acylating the hydroxy long acyl group, or (3b) reacting the unsaturated long acyl group with a carboxylic acid.

Abstract: A composition has been made for biopolyester films, preferably polylactic acid (PLA) films, having a low coefficient of friction for improved sliding properties, while maintaining a low haze value for good transparency. The composition, made from a masterbatch of specific additives, produces a film that achieves a haze of two percent or less (measured by ASTM D1003) and a dynamic coefficient of friction of 0.35 or less (measured by ASTM D1894-01).

Abstract: Provided herein are poly-capped estolides, including those of the Formula IV in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 2; R1 is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Hydroxy estolides are also described herein, which may be suitable end products, or serve as intermediates to provide poly-capped estolides. Also provided are compositions containing poly-capped estolides and methods of making both said poly-capped estolides and compositions thereof.

Abstract: Tetraesters of a C4-C5 aliphatic tetracarboxylic acid and OXO-alcohols and plasticized compositions containing said tetraesters are provided.

Abstract: The present invention is directed to a series of citrate ester emulsifiers that are effective in making water in oil (regular emulsions) and oil in water (invert emulsions). In addition to being outstanding emulsifiers, these emulsifiers provide unique solubility, liquidity and outstanding feel when applied to the skin, making them highly desirable in cosmetic emulsions.

Abstract: The invention relates to glass fiber reinforced polycarbonate compositions and molding compositions of the present investor and distinguished by high rigidity, high flowabillty, high processing stability, good chemical resistance and good aging resistance vis-à-vis the effects of light and heat compared with the prior art. The present invention also relates to the use of the compositions for the production of shaded articles and to shaped articles comprising the compositions according to the invention.

Abstract: Provided are processes for making, and processes for using triglycerides as plasticizers.

Abstract: The invention relates to rubber compositions, and their use, including composites of such rubber compositions containing wire reinforcement and tires having a component comprised of such rubber composition or composite.

Abstract: A water based polymeric dispersion for PSA adhesive preparation for transdermal system comprising: a) an aqueous dispersion of a polymer of an acrylate and/or a methacrylate ester, b) a plasticizer c) a shrinkage reducing agent able to reduce the shrinkage of the water PSA dispersion when spread onto a surface to width values lower than 20 mm after 3 minutes rest.

Abstract: The invention provides enclosure adhesives, methods of using the adhesives to bond for enclosing a multilayer structure and to articles of manufacture comprising the adhesives. The multilayer structure is a laminant of at least one composite film and at least one Kraft paper substrates. It has been discovered that an adhesive that comprises (a) a mixture of 1:1 to 5:2 of a metallocene catalyzed polyolefin copolymer with a density greater than or equal to 0.880 g/cm3 to a metallocene catalyzed polyolefin copolymer with a density less than 0.880 g/cm3; (b) a compatible tackifier; and (c) a compatible wax, has high adhesion to both Kraft and composite film with low blocking properties.

Abstract: The present invention is directed toward a play composition including a polymeric binder and oil. In an embodiment, the binder is a hydrogenated triblock copolymer including styrene. The oil is a mineral oil. The composition may further include a plasticizer, a release agent, and one or more fillers.

Abstract: Disclosed are oligomeric phosphonates including oligophosphonates, random or block co-oligo(phosphonate ester)s and co-oligo(phosphonate carbonate)s produced using a condensation process terminated with hydroxyl, epoxy, vinyl, vinyl ester, isopropenyl, isocyanate groups, and the like. These materials can be used as a reactive additive to other polymers, oligomers or monomer mixtures to impart flame resistance without diminishing melt processability which is important in the fabrication of polymers for many applications.

Abstract: Novel carboxylic acid polyesters, and mixtures thereof, are useful as plasticizers such as for polyvinylchloride compositions. These polyesters and the other components of the mixtures are prepared from bio-renewable sources.

Abstract: Provided herein are compounds of the formula: in which n is an integer equal to or greater than 1; m is an integer equal to or greater than 1; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R1, R3, and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched, wherein at least one of R1, R2, R3, or R4 is sulfurized or epoxidized. Also provided are compositions containing the compounds and methods of making both the compounds and compositions thereof.

Abstract: One or more embodiments contained herein disclose an adhesive for printed circuit board (PCB) applications. The improved adhesive may comprise a benzoxazine resin and a polyester plasticizer.

Abstract: The present invention relates to a radiation curable composition comprising (a) from 1 to 99% by weight of a (meth)acrylated natural oil which is the reaction product of an unsaturated natural oil with an unsaturated anhydride and a hydroxyl functional (meth)acrylate, and (b) from 1 to 99% by weight of a (meth)acrylated oligomer and/or monomer, and optionally an inert resin and/or filler, as well as their use for making inks and coatings.

Abstract: Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.

Abstract: The present invention relates to a process for the preparation of compositions comprising vinyl aromatic copolymers prepared by the emulsion polymerisation process and having salt inclusions resulting from their preparation, which compositions are distinguished by an improved surface quality after storage under warm moist conditions and in that respect are suitable for the production of moulded bodies having a class A surface.

Abstract: A silicone rubber composition comprising (A) an organopolysiloxane composition of the organic peroxide cure or addition reaction cure type, (B) a normally solid organic compound having at least two ester bonds per molecule, and (C) particulate aluminum hydroxide having an average particle size of up to 20 ?m is suited for use as high-voltage electric insulator since it maintains insulating properties for a long term in outdoor service and has acid resistance and a long lifetime even in polluted areas.

Abstract: The present disclosure relates to methods of preparation of compounds resulting from the reaction of levulinic esters and epoxidized unsaturated fatty acid esters. The compounds are useful as renewable biomass-based plasticizers for a variety of polymers. Mono-, di- and tri-ketal adducts formed in a reaction between alkyl esters of levulinate and epoxidized unsaturated fatty acid esters derived from vegetable oils are also disclosed.

Abstract: A composition includes estolide esters of vegetable oil fatty acid alkyl esters where the vegetable oil has an unsaturation greater than 90 IV. The fatty acid alkyl esters include unsaturated and saturated fatty acid alkyl esters, and each unsaturated fatty acid alkyl ester has greater than one estolide ester functionality.

Abstract: The invention is directed to an oxygen scavenging additive system for polymers, said additive system comprising an oxidisable polymer, a transition metal catalyst and a fatty acid ester of trimethylolpropane, wherein the fatty acid is a C6 to C18 fatty acid having a linear or branched chain, to polyester compositions containing said additive and to containers, or preforms for containers, prepared from said polyester composition.

Abstract: Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.

Abstract: The present invention provides an effect pigment comprising: (a) substrate optionally coated with metal oxide; and (b) triacetin. The present effect pigment may be used in cosmetics, plastics, security markings, inks, coatings including solvent and water borne automotive paint systems, and unsaturated polyester buttons.

Abstract: Continuous process for preparation of polyalkylene arylates A) comprising highly branched or hyperbranched polymers B) and, if appropriate, comprising lubricants C), by esterifying or transesterifying an aromatic dicarboxylic acid or its ester or ester-forming derivatives, with a molar excess of an aliphatic dihydroxy compound, and polycondensing the resultant transesterification or esterification product, which comprises, on achievement of at least 80% of the desired viscosity number, adding component B) and also, if appropriate, C) to the polymer melt, and, if appropriate, post-condensing the melt and then discharging, cooling, and pelletizing it, and also using, as component B), at least one highly branched or hyperbranched polycarbonate B1) with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or at least one highly branched or hyperbranched polyester B2) of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these.

Abstract: A curable composition contains (A) a polyorganosiloxane base polymer having an average per molecule of at least two aliphatically unsaturated organic groups, optionally (B) a crosslinker having an average per molecule of at least two silicon bonded hydrogen atoms, (C) a catalyst, (D) a thermally conductive filler, and (E) an organic plasticizer. The composition can cure to form a thermally conductive silicone gel or rubber. The thermally conductive silicone rubber is useful as a thermal interface material, in both TIM1 and TIM2 applications. The curable composition may be wet dispensed and then cured in situ in an (opto)electronic device, or the curable composition may be cured to form a pad with or without a support before installation in an (opto)electronic device.