Oxygen Atom Other Than As Part Of A Cooh Or Derivative Group Patents (Class 524/320)
  • Patent number: 5444113
    Abstract: Disclosed are products made of degradable materials which include a hydrolytically degradable polymer. The degradable materials can be internally or externally modified. The internally modified polymer composition has polymers modified by the use of comonomers having a relatively high molecular weight. The externally modified polymer composition includes a modifier, wherein the modifier is compatible with the polymer and the modifier is nontoxic, nonvolatile and nonfugitive. The various degradable materials include films, fibers, extruded and molded products, laminates, foams, powders, nonwovens, adhesives and coatings. The disclosed materials are particularly useful for the production of a variety of products in high volumes which are suitable for recycling after use or which are discarded into the environment in large volumes.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: August 22, 1995
    Assignee: Ecopol, LLC
    Inventors: Richard G. Sinclair, Edward S. Lipinsky, James D. Browning, Donald Bigg, Thomas A. Rogers
  • Patent number: 5430090
    Abstract: The invention relates to a polyvinyl acetate resin composition comprising a hydrophilic polyvinyl acetate resin rendered soluble or dispersible in water by partial saponification or introduction of hydrophilic groups (A), a hydroxy fatty acid compound of not less than 6 carbon atoms (B) and a plasticizer (C).
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: July 4, 1995
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yoshihiko Miyamoto, Masahiro Saitoh
  • Patent number: 5424346
    Abstract: The biodegradable polymer comprises polymerized lactic acid units of the structure: ##STR1## where n is an integer between 450 and 10,000 and the alpha carbon is a mixture of L- and D-configurations with a preponderance of either D- or L-units, wherein the polymer is suitable for replacement of polystyrene; the biodegradable composition also comprises blends of a physical mixture of polymerized lactic acid units of the formula I, where n is an integer between 450 and 10,000 and the alpha carbon is a mixture of L- and D-configurations with a preponderance of either D- or L-units, and a homopolymer of poly(D-lactic acid) or poly(L-lactic acid), and plasticizers that provide unique properties when intimately dispersed.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: June 13, 1995
    Assignee: Ecopol, LLC
    Inventor: Richard G. Sinclair
  • Patent number: 5420181
    Abstract: Thermoplastic molding compositions containingA) ABS-type resin,B) aromatic polycarbonate resins,C) a compound bearing several carboxyl groups or mixtures thereof and optionallyD) further polymer resins,characterized in that an ABS resin with at least one basically acting additive is used as component A, component C is selected from compounds having a molecular weight of from 150 to 260 having at least two carboxyl groups (--COOH) in the molecule, and the weight ratio of basically acting additive in A: carboxyl groups in C is from 5:1 to 1:1.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: May 30, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Eichenauer, Karl-Heinz Ott, Alfred Pischtschan, Edgar Leitz, Karl-Erwin Piejko
  • Patent number: 5420185
    Abstract: A bow-tie tree resistant electrical insulating composition comprises 100 parts by weight of at least one polymer selected from polyolefins and ethylene copolymers, 0.005-1.0 part by weight of a metal salt of a fatty acid containing a hydroxyl group in the molecule, and 0.005-1.0 part by weight of a fatty acid or a derivative thereof.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: May 30, 1995
    Assignee: Hitachi Cable Ltd.
    Inventors: Kiyoshi Watanabe, Takanori Yamazaki, Hideki Yagyu, Mamoru Kanaoka, Katsutoshi Hanawa, Chuki Ikeda
  • Patent number: 5403872
    Abstract: A solid correction material for covering writing or drawing errors on paper is disclosed. The correction material may be formed into a stick and housed in hollow body and is composed of: (a) 5-40 wt % of a thermoplastic synthetic resin, preferably a homo- or copolymer based on (meth)acrylic compounds; (b) 10-70 wt % of a pigment, preferably a titanium dioxide pigment; (c) 5-20 wt % of a mono- or polyvalent alcohol, preferably glycerin being preferred; (d) 5-30 wt % of carrier mixture composed of (i) a fatty acid with 12 to 32 carbon atoms or a salt of a fatty acid, with stearate being preferred, and (ii) at least one member selected from the group consisting of a polyolefin and an ester wax, possibly 5 to 15 wt % water; and (e) 0 to 10 wt % of conventional additives, such as defoaming agents, dyes, aroma substances, and preservatives. The correction material is solid at room temperature and has a viscosity between about 100 and about 150 cPa.s at 90.degree. C.
    Type: Grant
    Filed: December 16, 1993
    Date of Patent: April 4, 1995
    Assignee: Kores Holding Zug AG
    Inventor: Peter Koreska
  • Patent number: 5395889
    Abstract: Glycidyl (meth)-acrylate polymer and an organic acid, phosphoric acid, phosphorous acid, hypophosphoric acid and/or a compound other than an organic acid containing one or more functional groups selected from among carboxyl, amino, hydroxyl, acid anhydride and thiol groups added to an aromatic polycarbonate resin composition, decrease the luster of the composition without compromising the properties of the composition.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: March 7, 1995
    Assignee: GE Plastics Japan
    Inventors: Tomohide Fujiguchi, Hideyuki Itoi, Akihiro Saito
  • Patent number: 5384349
    Abstract: A block copolymer comprising about 5 weight percent to about 95 weight percent monovinylarene monomer, about 95 to about 5 weight percent butadiene, and an effective amount of a thermal stabilizing agent selected from the group consisting of ascorbic acid, citric acid, disodium citrate, and mixtures thereof is provided. A process for stabilizing conjugated diene/monovinylarene block copolymer and articles prepared from such copolymers are also provided.
    Type: Grant
    Filed: December 6, 1993
    Date of Patent: January 24, 1995
    Assignee: Phillips Petroleum Company
    Inventors: William J. Trepka, Nathan E. Stacy, George A. Moczygemba
  • Patent number: 5378747
    Abstract: An ethylene polymer composition is provided that comprises:(a) bis(2,4-di-tert-butylphenyl) pentaerythritol diphosphite, in an amount that is from about 0.0001 to less than 0.30 weight percent; and(b) at least one color stabilization compound selected from the group consisting of:(1) a carboxylic acid compound;(2) an alcohol compound; and(3) a hydroxycarboxylic acid compound;in an amount from about 0.0001 to about 1 weight percent;wherein said weight percents are based on the weight of said ethylene polymer composition.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: January 3, 1995
    Assignee: Phillips Petroleum Company
    Inventors: Paritosh K. Das, Kenneth W. Willcox
  • Patent number: 5358992
    Abstract: In accordance with the present invention, there is provided a novel composition for attaching a semiconductor device to a substrate. The invention composition comprises liquid polycyanate ester monomer, electrically conductive filler rendered substantially free of catalytically active metal ions and a curing catalyst. Treatment of filler to render it free of catalytically active metal ions significantly extends the pot life of the composition.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: October 25, 1994
    Assignee: Quantum Materials, Inc.
    Inventors: Stephen M. Dershem, Deborah L. Derfelt, Dennis B. Patterson
  • Patent number: 5350790
    Abstract: This invention provides a polycarbonate resin composition for optical use and an optical disc substrate manufactured therefrom. Polycarbonate resin is mixed with at least one kind of carboxylic acid selected from aliphatic carboxylic acids having 1 to 10 carbon atoms in which hydrogen atoms of aliphatic group may be substituted by hydroxyl groups; or aromatic carboxylic acids in which hydrogen atoms of the aromatic ring may be substituted by low alkyl groups, hydroxyl groups, or halogen atoms.The amount of the carboxylic acids is 5 to 1000 ppm based on the polycarbonate resin.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: September 27, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshitomi Urabe, Hironori Hayashida, Yoshiaki Ohtani
  • Patent number: 5350783
    Abstract: Thermoplastic polymer product of a thermoplastic material including a thermoplastic polymer and polymeric composting promoting agent selected from the group consisting of nonmetallic metal complexing agents, nonoxidizing-metal metal complexing agents, and mixtures thereof, in a composting effective amount to convert in the presence of oxidizing metal compounds to an active oxidant to thermally degrade the thermoplastic polymer of the thermoplastic material under composting conditions to a low molecular weight material with enhanced biodegradability, the nonmetallic metal complexing agents and the nonoxidizing-metal metal complexing agents being neither photoactivators nor prooxidants.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: September 27, 1994
    Assignee: Biolan Corporation
    Inventor: Murray H. Reich
  • Patent number: 5296522
    Abstract: Carboxylic acids of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 independently of one another are each hydrogen, hydroxyl, carboxyl or C.sub.1 -C.sub.6 -alkyl and x, y and z independently of one another are each 0 or an integer of from 1 to 6, and/or their anhydrides can permanently suppress the formation of water trees in electrical medium and high voltage cables which contain electrically insulating and/or electrically semiconductive layers based on ethylene homopolymers and/or copolymers, even when the relevant layers contain water-soluble basic salts. Accordingly, polymeric mixtures based on ethylene homopolymers and/or copolymers which contain the above-mentioned carboxylic acids I and/or their anhydrides are very useful for the production of electrically insulating and electrically semiconductive layers as used in electrical medium and high voltage cables.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: March 22, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Vogt, Ingolf Hennig, Johannes Schlag, Thomas Muehlenbernd
  • Patent number: 5292789
    Abstract: A polyphenylene sulfide/polyphenylene ether composition is provided, which has excellent dimensional stability and impact resistance, as well as good heat resistance, rigidity and surface appearance. The composition also includes certain polyamide resins, hydrogenated conjugated diene/aromatic monovinyl block copolymers, modified polyolefins, compatibilizer agents, and inorganic fillers.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: March 8, 1994
    Assignee: GE Plastics Japan, Ltd.
    Inventors: Hiromi Ishida, Hidekazu Kabaya
  • Patent number: 5270372
    Abstract: Food packaging-use formed articles including at least one layer of a 3 to 90 microns thickness which comprises a composition consisting of (A) polyvinyl alcohol resin having a degree of saponification of 60 to 95 mole % (A) and (B) a hydroxy containing compound falling within the range of from 3 weight parts of (B) to 100 weight parts of (A) to the saturated solubility of (B) in (A) and having a carbon dioxide/oxygen solubility ratio (SCO.sub.2 /SO.sub.2) of 30 or higher.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: December 14, 1993
    Assignee: Kureha Chemical Industry Co., Ltd.
    Inventors: Kazuhiko Hirose, Nobuyuki Hisazumi, Shinichiro Funabashi, Hiroyuki Ohba, Hideaki Tanaka
  • Patent number: 5254614
    Abstract: This invention provides a polycarbonate resin composition for optical use and an optical disc substrate manufactured therefrom. Polycarbonate resin is mixed with at least one kind of carboxylic acid selected from aliphatic carboxylic acids having 1 to 10 carbon atoms in which hydrogen atoms of aliphatic group may be substituted by hydroxyl groups; or aromatic carboxylic acids in which hydrogen atoms of the aromatic ring may be substituted by low alkyl groups, hydroxyl groups, or halogen atoms.The amount of the carboxylic acids is 5 to 1000 ppm based on the polycarbonate resin.
    Type: Grant
    Filed: May 22, 1991
    Date of Patent: October 19, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshitomi Urabe, Hironori Hayashida, Yoshiaki Ohtani
  • Patent number: 5252642
    Abstract: An environmentally degradable composition comprises blends of a physical mixture of a poly(lactic acid), comprising about 1 to 99 weight percent of the composition, and an elastomeric blend compatible polymer, such as a segmented polyester, that provides improved impact resistance to the poly(lactic acid) and is discrete and intimately bound; plasticizer is added to the blend that is selected from the group consisting of lactide monomer, lactic acid oligomer, lactic acid, and mixtures thereof. Other plasticizer that may be added includes one or more derivatives of an oligomer of lactic acid, its esters and copolymer.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: October 12, 1993
    Assignee: BioPak Technology, Ltd.
    Inventors: Richard G. Sinclair, Joseph Preston
  • Patent number: 5231161
    Abstract: Macrocyclic poly(alkylene dicarboxylate) oligomers are prepared in high yield by the reaction of a dicarboxylic acid chloride such as terephthaloyl chloride with at least one bis(hydroxyalkyl) ester such as bis(4-hydroxybutyl) terephthalate, in the presence of a highly unhindered amine or a mixture thereof with at least one other tertiary amine such as triethylamine, in a substantially inert organic solvent such as methylene, chlorobenzene or a mixture thereof. The concentration of the reagents in the reaction mixture are at least 0.08M.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: July 27, 1993
    Assignee: General Electric Company
    Inventors: Daniel J. Brunelle, John B. McDermott
  • Patent number: 5218027
    Abstract: A fire-retardant thermoplastic compound that can be used as compounded or further enhanced through chemical cross linkage. The compound is manufactured from a composition of a copolymer or terpolymer with a carboxylic acid comonomer and optionally a low modulus polymer and a synthetic hydrocarbon elastomer with or without a graft of ethylenically unsaturated carboxylic acid or anhydride. A fire retardant additive comprising a group I, group II or group III metal oxide hydrate with the proviso that at least 1% by weight of the composition is in the form of an organopolysiloxane. The compound may be used for sheet or wire extrusion and action for injection or compression molding.
    Type: Grant
    Filed: May 20, 1991
    Date of Patent: June 8, 1993
    Assignee: Motrile Industries, Ltd.
    Inventors: Philip J. Smith, Jacques Mortimer
  • Patent number: 5216070
    Abstract: A method for forming a water-in-oil emulsion of a water-soluble polymer by emulsion polymerization of the corresponding monomer in the presence of an initiator and an emulsifier which is a polysiloxane polyalkylene polyether copolymer. The polymerization of acidic monomer can be carried out without complete neutralization of the monomer beforehand and without adverse effects on the emulsion stability. The water-in-oil product emulsion is easily inverted to a stable oil-in-water emulsion.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: June 1, 1993
    Assignee: ISP Investments Inc.
    Inventors: Krystyna Plochocka, Jui-Chang Chuang
  • Patent number: 5216050
    Abstract: An environmentally degradable composition comprising blends of a physical mixture of poly(lactic acid), and a polymer selected from the group consisting of poly(ethylene terephthalate), a polymer or copolymer of styrene, ethylene, propylene, vinyl chloride, vinyl acetate, alkyl methacrylate, alkyl acrylate, and physical mixtures thereof; plasticized with D-lactic acid, L-lactic acid, racemic D,L-lactic acid, D-lactide, L-lactide, meso D,L-lactide, racemic, D,L-lactide, oligomers of lactic acid, oligomers of lactide, derivatives of oligomers of lactic acid, or various mixtures thereof.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: June 1, 1993
    Assignee: BioPak Technology, Ltd.
    Inventor: Richard G. Sinclair
  • Patent number: 5214083
    Abstract: Blends of polyphenylene sulfides, polyphenylene ethers and certain polyamides are made more compatible by incorporating in the polymeric blend either citric, malic or agaricic acid or one of their derivatives, trimellitic anhydride acid chloride, oxazolinyl or epoxy-containing ethylenically unsaturated compounds, or oxazolinyl or epoxy-containing polymers.
    Type: Grant
    Filed: August 15, 1991
    Date of Patent: May 25, 1993
    Assignee: General Electric Company
    Inventors: Tetsuji Kodaira, Hiromi Ishida, Hidekazu Kabaya
  • Patent number: 5214049
    Abstract: The present invention provides a resin composition which is excellent in balance of mechanical properties and processability, solvent resistance and chemical resistance. This composition comprises:(a) a polyphenylene ether resin,(b) a thermoplastic polyester resin, and(c) a compound represented by the formula:(HO)mR.sup.1 (COOR.sup.2)nwherein R.sup.1 represents a straight or branched chain saturated aliphatic hydrocarbon group of 2-20 carbon atoms, R.sup.2 represents a hydrogen atom or an alkyl or aryl group of 1-20 carbon atoms and R.sup.1 and R.sup.2 may be identical or different and m and n each represents an integer of 1 or more or a derivative thereof.This composition may further contain a rubber-like polymer.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: May 25, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takashi Maruyama, Yukio Mizuno
  • Patent number: 5180765
    Abstract: Environmentally biodegradable compositions of poly(lactic acid) plasticized with lactic acid, D-lactide, L-lactide, meso D,L-lactide, racemic D,L-lactide, oligomers of lactic acid, oligomers of lactide, derivatives of oligomers of lactic acid, or various mixtures thereof; the compositions are suitable replacements of thermoplastic polymer compositions; the compositions are useful for pliable films and other packaging applications conventionally served by polyethylene and other nondegradable thermoplastics; homopolymers or copolymers of D-lactic acid, L-lactic acid, D-lactide, L-lactide, meso D,L-lactide, and/or racemic D,L-lactide having properties similar to other known polymers may be prepared by varying the ratios of monomer and polymerization conditions, the amount and type of plasticizer in the polymer and process conditions; additives and subsequent treatment are also used to modify properties.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: January 19, 1993
    Assignee: BioPak Technology, Ltd.
    Inventor: Richard G. Sinclair
  • Patent number: 5177134
    Abstract: A tacking agent is provided for use in temporarily adhering electronic components and providing fluxing properties for soldering electronic assemblies. The tacking agent comprises a fluxing agent and a tackifier. The fluxing agent is composed of one or more carboxylic acids having the formula ##STR1## where R is an alkyl group containing from 1 to 6 carbon atoms, R' is selected from the group consisting of hydrogen and hydroxyl, and R" is selected from the group consisting of hydrogen, hydroxyl and carboxyl. The tackifier comprises one or more alcohols, aromatic hydrocarbon solvents, aliphatic hydrocarbon solvents, or polymers. The tacking agent is deposited onto a printed circuit board or other substrate, the electronic components are placed into the deposited tacking agent and soldered. During solder reflow the fluxing agent provides fluxing action for the soldering process, and the tackifier volatilizes, leaving little or no residue on the printed circuit board.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: January 5, 1993
    Assignee: Motorola, Inc.
    Inventors: William B. Mullen, III, Anthony B. Suppelsa, Robert W. Pennisi
  • Patent number: 5143961
    Abstract: Normally water insoluble hot melt adhesive compositions containing structural polymers such as A-B-A block copolymers, butyl rubbers, polyesters, ethylene vinyl acetates, ethylene acrylic acid polymers can be made sensitive to the action of water using an effective water sensitizing amount of a polyalkyloxazoline polymer in the hot melt adhesive. The polyalkyloxazoline polymer can be incorporated into a single phase adhesive composition with the structural polymer using an effective amount of a hydroxyl or carboxylic acid compound.
    Type: Grant
    Filed: December 21, 1989
    Date of Patent: September 1, 1992
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Steven L. Scholl, Eugene R. Simmons, Keith C. Knutson, William L. Bunnelle
  • Patent number: 5137955
    Abstract: A propylene polymer film is described which is composed of a composition comprising 100 parts by weight of a propylene polymer, 0.01 to 0.5 part by weight of a fine spherical silica particle and 0.3 to 5.0 parts by weight of hydroxy-fatty acid glyceride. A laminate film including a layer comprised of the above composition is also described. The film has an excellent transparency, gloss, slipperiness and adhesiveness, as well as a good adaptability to vacuum deposition.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: August 11, 1992
    Assignee: Toray Industries, Inc.
    Inventors: Katsuhiro Tsuchiya, Kenji Takuwa, Katsuya Ogawa
  • Patent number: 5137956
    Abstract: A solid film prelube composition for metals contacting food and beverages which comprises:______________________________________ Ingredients % by Weight ______________________________________ A. As a primary lubricant, 75-95 a C14-C22 fatty acid B. As a plasticizer-supplemental 5-25 lubricant, butyl stearate C. As a film former, an ethylene 0.5-2 acrylic acid copolymer D.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: August 11, 1992
    Assignee: Nalco Chemical Company
    Inventor: Robert L. Trivett
  • Patent number: 5089165
    Abstract: Novel water-dispersed compositions are prepared containing (1) 100 parts by weight of an amine-containing polymer, (2) at least 25 parts by weight of a solvent which is soluble in both water and organics and has a boiling point above about 100.degree. C., (3) at least about 0.8 equivalent of an organic acid having a pk.sub.a value of less than 5, and (4) from about 50 to about 750 parts by weight of water. The compositions are useful as a component in water-borne resin systems such as epoxies and polyesters.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: February 18, 1992
    Assignee: The BFGoodrich Company
    Inventor: Carl S. Nichols
  • Patent number: 5045580
    Abstract: A thermoplastic polyester resin composition exhibiting improved antistatic properties including a thermoplastic polyester resin, between about 0.02 to about 10 wt. %, based on the total weight of the composition, of a sulfonate-type anionic antistatic agent, and between about 0.005 to about 10 wt. %, based on the total weight of the composition, of one or more compounds selected from organophosphorus compounds, and organic chelating agents.
    Type: Grant
    Filed: November 30, 1989
    Date of Patent: September 3, 1991
    Assignee: Polyplastics Co., Ltd.
    Inventor: Hiroshi Kitamura
  • Patent number: 5023290
    Abstract: Disclosed are waterproofing agent primer compositions which can be applied to wet and dry structures and methods of waterproofing structures made of waterpenetrable construction materials which can be used on wet and dry structures. The primer compositions include a C.sub.8 -C.sub.18 fatty acid, a natural or synthetic rubber, a resin, and an organic solvent.
    Type: Grant
    Filed: September 12, 1988
    Date of Patent: June 11, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: James M. Gaidis
  • Patent number: 5021490
    Abstract: An internally plasticized polyvinyl halide composition is prepared by polymerizing a vinyl halide in the presence of a reactive polyester plasticizer having terminal groups copolymerizable therewith. The reactive polyester acts as an internal plasticizer for the polyvinyl halide composition and is not readily extactable therefrom.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: June 4, 1991
    Assignee: The B. F. Goodrich Company
    Inventors: Josef C. Vyvoda, James T. Harvilchuck
  • Patent number: 4988461
    Abstract: Novel water-dispersed compositions are prepared containing (1) 100 parts by weight of an amine-containing polymer, (2) at least 25 parts by weight of a solvent which is soluble in both water and organics and has a boiling point above about 100.degree. C., (3) at least about 0.8 equivalent of an organic acid having a pk.sub.a value of less than 5, and (4) from about 50 to about 750 parts by weight of water. The compositions are useful as a component in water-borne resin systems such as epoxies and polyesters.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: January 29, 1991
    Assignee: The BFGoodrich Company
    Inventor: Carl S. Nichols
  • Patent number: 4973620
    Abstract: A composition and method for treating fibers is based on a mixture of an organopolysiloxane having at least one amino-substituted hydrocarbon radical directly bonded to a silicon atom and a carboxylic acid containing at least one ethylene oxide unit. The carboxylic acid reacts with the amino radicals to reduce yellowing and oxidation of the fiber treatment. The composition and method provide non-yellowing fibers and a treatment agent that does not gel during use, such as when exposed to carbon dioxide and/or used to treat carbon fibers.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: November 27, 1990
    Assignee: Toray Silicone Company, Ltd.
    Inventors: Isao Ona, Masaru Ozaki, Hidetoshi Kurusu
  • Patent number: 4966933
    Abstract: A propylene polymer film is described which is composed of a composition including 100 parts by weight of a propylene polymer, 0.01 to 0.5 parts by weight of a fine powder of a crosslinked silicone resin and 0.3 to 3.0 parts by weight of a hydroxy-fatty acid glyceride. A laminate film including a layer comprised of the above composition is also described. The film has an excellent transparency, gloss, slipperiness and adhesiveness, as well as a good adaptability to vacuum deposition.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: October 30, 1990
    Assignee: Toray Industries, Inc.
    Inventors: Ken-ichi Kawakami, Masatsugi Murakami, Kenji Takuwa
  • Patent number: 4944802
    Abstract: Magnetic inks useful for the production of magnetic recording products are disclosed. The present magnetic inks contain ferromagnetic barium ferrite particles dispersed in a flexible polymer medium.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: July 31, 1990
    Assignee: Omni Quest Corporation
    Inventors: Mark S. Chagnon, John R. Ferris
  • Patent number: 4889879
    Abstract: Coherent thermoplastic aggregates with very high content of pulverized mineral materials, composed of the said materials, of polyolefin polymers and/or copolymers, and possibly also of various familiar adjuvants, characterized by the fact that, in order for them to have both a volumetric mass close to or at most equal to the theoretical volumetric mass of the pulverized mineral substances entering into their composition and an excellent compatibility with redispersion polymers, the polymers and/or copolymers entering into the composition of the said aggregates in presence of a fluidizing agent are chosen within the group of thermoplastics with melting and/or softening point at least equal to 60.degree. C. and index of fluidity at least 50 (measured according to the standard ASTM D 1238) of the polyolefin type, other than those containing a polar monomer.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 26, 1989
    Assignee: Pluess Staufer AG
    Inventors: Henry Seinera, Patricia Luberne, Claude Stock, Patrick Trouve
  • Patent number: 4882227
    Abstract: There is provided an electric conductive resin composition formed into a pellet, which includes an electric conductive filler comprising electric conductive fibers and a low-melting point metal, and being coated on the surface thereof with a thermoplastic resin. Flux and/or a phosphorus-based antioxidant may be added to the filler. There is also provided an electromagnetic wave shielding molded product prepared by using the electric conductive resin composition mentioned above, wherein the electric conductive fibers dispersed within the molded product are fixed each other through the low-melting point metal.
    Type: Grant
    Filed: March 9, 1988
    Date of Patent: November 21, 1989
    Assignee: Toshiba Chemical Corporation
    Inventors: Hidehiro Iwase, Keiichi Habata
  • Patent number: 4863987
    Abstract: A deodorizing coating formulation is composed of a white or substantially colorless deodorizing agent, a binder resin and a liquid medium. The deodorizing agent may preferably be composed of 10-90 parts by weight of a zinc compound and 90-10 parts by weight of an aliphatic polycarboxylic acid, aromatic polycarboxylic acid, acidic polymer or a sulfate of aluminum, or a salt thereof. A deodorizing sheet can be obtained by coating and/or impregnating a base sheet with the deodorizing coating formulation and then drying the resulting base sheet. The deodorizing sheet can shield a flavor or odor from external flavors or odors while maintaining air permeability, it is suitable for wrapping foods having strong flavors or odors.
    Type: Grant
    Filed: November 10, 1986
    Date of Patent: September 5, 1989
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Akira Hoshino, Mikio Saji, Shigeaki Fujii
  • Patent number: 4855348
    Abstract: A storage stable water-based paint comprising a solid silicone resin and an ammonium salt of a drying oil modified acrylic copolymer provide a coating for barbecue grills and other appliances that are subjected to temperatures as high as 1300.degree. F. A smooth and continuous coating remains on the metal after burning off of the acrylic resin and firing of the metal at 1300.degree. F. The paint is redispersible and may be drawn down to 1.5 mils after storage at 120.degree. F. for more than 3 months when the pH is at least about 8.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: August 8, 1989
    Assignee: DAP Inc.
    Inventor: Hartzel G. Strader
  • Patent number: 4822836
    Abstract: Novel compatibilized polyphenylene ether-polyamide compositions are provided by this invention, comprising polyphenylene ether resin, polyamide resin, a compatibilizing agent, and a melt flow-improving compound. The compatibilizing agent may be selected from a wide variety of materials, such as saturated aliphatic polycarboxylic acids or derivatives thereof; various silane compounds; and functionalized polyphenylene ethers. A specific example of a compatibilizer is citric acid. Specific examples of melt flow-improving compounds are stearic acid, oleic acid, and linolenic acid.
    Type: Grant
    Filed: September 18, 1987
    Date of Patent: April 18, 1989
    Assignee: General Electric Company
    Inventor: Ronald J. Wroczynski
  • Patent number: 4785041
    Abstract: Thixotropic, silica-filled coating compositions wherein the curable film-forming material is an organosiloxane copolymer resin include a liquid polydiorganosiloxane containing hydroxyl-terminated polyoxypropylene units as the flow control agent. The compositions are particularly useful as screen printable passivation coatings for semiconductor devices.
    Type: Grant
    Filed: December 31, 1987
    Date of Patent: November 15, 1988
    Assignee: Dow Corning Corporation
    Inventors: Robert C. Antonen, Diane M. Rasch, David A. Sierawski, David J. Romenesko
  • Patent number: 4783395
    Abstract: The invention provides an organic solvent free, phosphate free, lithographic desensitizing composition which comprises:(a) from about 0.1% to about 20.0% by weight of the composition of a copolymer of polymethyl vinyl ether and maleic acid having the formula ##STR1## which has a molecular weight in an amount of from about 20,000 to about 70,000; and(b) from about 0.1% to about 20.0% by weight of the composition of a desensitizing component comprising one or more hydroxy carboxylic acids or salts; and(c) sufficient water to formulate a desensitizing composition; and(d) sufficient base to adjust the pH of the composition into the range of from about 6.5 to about 7.5.
    Type: Grant
    Filed: November 5, 1987
    Date of Patent: November 8, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: Shane Hsieh, Wayne A. Mitchell
  • Patent number: 4781948
    Abstract: An acidic water-based film-forming coating composition suitable for the protection of ferrous surfaces by application thereto and drying at ambient temperature wherein said composition contains at least one acid of defined formula, such as lactic or tartaric acid, which prevents or reduces general yellow/brown staining.
    Type: Grant
    Filed: June 5, 1986
    Date of Patent: November 1, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventor: David Caldwell
  • Patent number: 4737541
    Abstract: Thickened or gelled industrial formulations comprise, for example, an aqueous acid or base formulation thickened with a small amount of a water-soluble polymer comprising acrylamide, an ionic monomer and, optionally, a crosslinking monomer. The thickened formulations can be used as industrial or household cleaners, etc., and exhibit good viscosity stability and retention capability over time.
    Type: Grant
    Filed: August 12, 1986
    Date of Patent: April 12, 1988
    Assignee: The Dow Chemical Company
    Inventors: David L. Stavenger, James W. Sanner, Patricia L. Slaber
  • Patent number: 4728597
    Abstract: The invention provides an organic solvent free, phosphate free, lithographic desensitizing composition which comprises:(a) from about 0.1% to about 20.0% by weight of the composition of a copolymer of polymethyl vinyl ether and maleic acid having the formula ##STR1## which has a molecular weight in an amount of from about 20,000 to about 70,000; and(b) from about 0.1% to about 20.0% by weight of the composition of a desensitizing component comprising one or more hydroxy carboxylic acids or salts; and(c) sufficient water to formulate a desensitizing composition; and(d) sufficient base to adjust the pH of the composition into the range of from about 6.5 to about 7.5.
    Type: Grant
    Filed: February 17, 1987
    Date of Patent: March 1, 1988
    Assignee: Hoechst Celanese Corporation
    Inventors: Shane Hsieh, Wayne A. Mitchell
  • Patent number: 4714730
    Abstract: It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.1d).
    Type: Grant
    Filed: June 4, 1986
    Date of Patent: December 22, 1987
    Assignee: Illinois Tool Works Inc.
    Inventors: Paul C. Briggs, Donald E. Gosiewski
  • Patent number: 4686255
    Abstract: Stabilized polyvinyl chloride molding compositions contain, per 100 parts by weight of polymer, 0.02 to 5 parts by weight compounds of Formula I, ##STR1## in which R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms or an MOOC--CH.sub.2 group, n represents the numbers 0 and 1, and M represents sodium or potassium.Heat stabilizers which are metal soaps, aromatic metal carboxylates, metal phenolates and organotin compounds as well as crystalline sodium aluminosilicate are also incorporated.
    Type: Grant
    Filed: May 3, 1985
    Date of Patent: August 11, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Werner Erwied, Horst Upadek, Bernd Wegemund
  • Patent number: 4602058
    Abstract: The compatibility and thermal stability of blends of polyamides/carboxyl-containing ethylene polymers is improved by adding thereto an organic carboxylic acid compound, especially di-basic acids such as sebacic acid or tartaric acid. The blends may also contain free-radical scavengers and/or antioxidants. These blends are useful as heat-plasticized adhesives or bonding agents.
    Type: Grant
    Filed: July 2, 1984
    Date of Patent: July 22, 1986
    Assignee: The Dow Chemical Company
    Inventors: Stephen L. Graham, Laura A. Kelly
  • Patent number: 4504616
    Abstract: A neodymium-containing transparent resin comprising (A) a copolymer of (i) at least one monomer selected from the group consisting of alkyl methacrylates having alkyl groups of 1 to 4 carbon atoms and styrene with (ii) at least one copolymerizable unsaturated carboxylic acid or a salt thereof selected from the group consisting of acrylic acid, methacrylic acid and neodymium salts thereof and (B) at least one compound selected from the group consisting of saturated or unsaturated organic carboxylic acids substituted or unsubstituted with a hydroxyl group and having 6 to 21 carbon atoms, and neodymium salts thereof, which transparent resin is characterized by having a neodymium content in the range of 0.
    Type: Grant
    Filed: July 28, 1983
    Date of Patent: March 12, 1985
    Assignee: Kyowa Gas Chemical Industry Co., Ltd.
    Inventors: Hiroshi Uehara, Tohru Shimizu