Two Or More Carboxylic Acid Or Derivative Groups Patents (Class 524/321)
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Patent number: 5300549Abstract: A method for the nucleation of polyolefins containing residual polymerization catalyst by blending the polyolefins with at least one aliphatic dicarboxylic acid containing from about 4 to about 21 carbon atoms and at least one aliphatic monocarboxylic acid containing from about 8 to about 24 carbon atoms in a weight ratio between about 4:1 and about 1:4. Also a composition comprising at least one aliphatic dicarboxylic acid containing from about 4 to about 21 carbon atoms and at least one aliphatic monocarboxylic acid containing from about 8 to about 24 carbon atoms. The polyolefin product of the nucleation can be molded into shaped articles.Type: GrantFiled: April 11, 1991Date of Patent: April 5, 1994Assignee: Witco CorporationInventors: James J. Ward, Thomas E. Breuer
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Patent number: 5296522Abstract: Carboxylic acids of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 independently of one another are each hydrogen, hydroxyl, carboxyl or C.sub.1 -C.sub.6 -alkyl and x, y and z independently of one another are each 0 or an integer of from 1 to 6, and/or their anhydrides can permanently suppress the formation of water trees in electrical medium and high voltage cables which contain electrically insulating and/or electrically semiconductive layers based on ethylene homopolymers and/or copolymers, even when the relevant layers contain water-soluble basic salts. Accordingly, polymeric mixtures based on ethylene homopolymers and/or copolymers which contain the above-mentioned carboxylic acids I and/or their anhydrides are very useful for the production of electrically insulating and electrically semiconductive layers as used in electrical medium and high voltage cables.Type: GrantFiled: May 8, 1992Date of Patent: March 22, 1994Assignee: BASF AktiengesellschaftInventors: Heinz Vogt, Ingolf Hennig, Johannes Schlag, Thomas Muehlenbernd
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Patent number: 5292789Abstract: A polyphenylene sulfide/polyphenylene ether composition is provided, which has excellent dimensional stability and impact resistance, as well as good heat resistance, rigidity and surface appearance. The composition also includes certain polyamide resins, hydrogenated conjugated diene/aromatic monovinyl block copolymers, modified polyolefins, compatibilizer agents, and inorganic fillers.Type: GrantFiled: May 15, 1992Date of Patent: March 8, 1994Assignee: GE Plastics Japan, Ltd.Inventors: Hiromi Ishida, Hidekazu Kabaya
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Patent number: 5254614Abstract: This invention provides a polycarbonate resin composition for optical use and an optical disc substrate manufactured therefrom. Polycarbonate resin is mixed with at least one kind of carboxylic acid selected from aliphatic carboxylic acids having 1 to 10 carbon atoms in which hydrogen atoms of aliphatic group may be substituted by hydroxyl groups; or aromatic carboxylic acids in which hydrogen atoms of the aromatic ring may be substituted by low alkyl groups, hydroxyl groups, or halogen atoms.The amount of the carboxylic acids is 5 to 1000 ppm based on the polycarbonate resin.Type: GrantFiled: May 22, 1991Date of Patent: October 19, 1993Assignee: Mitsubishi Kasei CorporationInventors: Yoshitomi Urabe, Hironori Hayashida, Yoshiaki Ohtani
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Patent number: 5248717Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.Type: GrantFiled: December 31, 1991Date of Patent: September 28, 1993Assignee: The Sherwin-Williams CompanyInventor: John Mathai
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Patent number: 5244954Abstract: Moulding thermoplastic compositions, endowed with improved mould release characteristics, comprising:A) an impact resistant vinyl aromatic copolymer consisting of an ethylenically unsaturated nitrile, a vinyl aromatic monomer and a rubber;B) an engineering polymer; andC) an effective amount of a release agent constituted by a synergistic mixture of an ester of a C.sub.16 -C.sub.18 acid with glycerol and an ester of a saturated aliphatic C.sub.10 -C.sub.20 acid with a C.sub.4 -C.sub.6 aliphatic alcohol.The physical-mechanical properties of the compositions at high moulding temperatures can be improved by addition of an effective amount of a bis(alkyl-phenyl)pentaerythritol diphosphite.The compositions can, furthermore, contain in addition a grafted polymer consisting of an elastomeric core having a Tg lower than 10.degree. C. and containing vinyl monomer chains grafted thereon.Type: GrantFiled: December 19, 1991Date of Patent: September 14, 1993Assignee: ECP Enichem Polimeri S.r.l.Inventors: Gian C. Fasulo, Francesco Mori, Dario Ghidoni
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Patent number: 5231126Abstract: This invention relates to obtaining beta crystalline Phase isotactic polypropylene with high purity and thermal stability simply by melt-crystallization in the presence of a two component beta nucleating agent. The two component beta-nucleating agent is formed by mixing 0.0001-1 weight % of dibasic acid with 0.001-1 weight % oxide, hydroxide or acid salt of a Group IIA metal. Such beta phase polypropylene can be used for the production of high impact strength molding extrusion shapes, microporous film and microporous hollow fiber.Type: GrantFiled: February 9, 1989Date of Patent: July 27, 1993Inventors: Guan-yi Shi, Jing-yun Zhang, Hesheng Jing
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Patent number: 5219912Abstract: An emulsified alkenylsuccinic acid sizing agent having a solid content of not less than 25% by weight is disclosed, which comprises a composition having not less than 25 parts by weight of alkenylsuccinic acid derived from the reaction product of a branched internal olefin of 12-18 carbon atoms with maleic anhydride, and being dispersed in water with an anionic polymer type dispersant or with an anionic polymer type dispersant and an emulsifier.Type: GrantFiled: July 10, 1991Date of Patent: June 15, 1993Assignee: Mitsubishi Oil Co., Ltd.Inventors: Yoshio Takahashi, Junji Okazaki, Hideto Umekawa, Toshihiro Tahara
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Patent number: 5196469Abstract: A semi-aqueous ethylene-vinyl alcohol coating composition that is a stable, homogeneous solution which is capable of being easily applied to a substrate to form a multi-layer structure at room temperature, by spray, rod, gravure, or other mechanical means. Upon evaporation of the volatile components, this coating solution leaves a clear, homogeneous film comprising EVOH. The film resists degradation and discoloration during the lifetime of the structure, and upon incineration or recycling does not evolve harmful acids into the environment.Type: GrantFiled: March 28, 1991Date of Patent: March 23, 1993Assignee: Mica CorporationInventors: Virginia P. Cushing, Daniel Siegel
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Patent number: 5177134Abstract: A tacking agent is provided for use in temporarily adhering electronic components and providing fluxing properties for soldering electronic assemblies. The tacking agent comprises a fluxing agent and a tackifier. The fluxing agent is composed of one or more carboxylic acids having the formula ##STR1## where R is an alkyl group containing from 1 to 6 carbon atoms, R' is selected from the group consisting of hydrogen and hydroxyl, and R" is selected from the group consisting of hydrogen, hydroxyl and carboxyl. The tackifier comprises one or more alcohols, aromatic hydrocarbon solvents, aliphatic hydrocarbon solvents, or polymers. The tacking agent is deposited onto a printed circuit board or other substrate, the electronic components are placed into the deposited tacking agent and soldered. During solder reflow the fluxing agent provides fluxing action for the soldering process, and the tackifier volatilizes, leaving little or no residue on the printed circuit board.Type: GrantFiled: December 3, 1990Date of Patent: January 5, 1993Assignee: Motorola, Inc.Inventors: William B. Mullen, III, Anthony B. Suppelsa, Robert W. Pennisi
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Patent number: 5169891Abstract: Coating compositions based on ethylene vinyl acetate polymers have improved compatibility with solvents (especially with aliphatic hydrocarbon solvents) hydrocarbon oils, and mineral waxes by blending the EVA with a fatty acid and heating at or above the melting point of the EVA. Furthermore the resultant blends are much more easily emulsified in the presence of cations than blends which have not been processed with the fatty acids. Typically the starting material for the improved product of this invention is a composition comprising a blend of an EVA polymer and a fatty acid which is miscible in all proportions with mineral spirits at 25.degree. C. or forms a solution at a level 5% of fatty acid in mineral spirits, such as coconut or palm fatty acids.Type: GrantFiled: April 19, 1991Date of Patent: December 8, 1992Inventor: Nicholas Brown
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Patent number: 5166237Abstract: A novel thermoplastic composition having improved paint adhesion strength comprising,A) from about 5 to 95 weight % of a6t least one polyphenylene ether.B) from about 95 to 5 weight % of at least one polyamide,C) paint adhesion improving amount of at least one paint adhesion improver selected from the class consisting of(1) homopolymers or copolymers of unsaturated nitrile compounds and(2) homopolymers or copolymers of alkyl (meth)acrylate, excluding an ethylene alkylacrylate copolymer having about 50 weight % or higher of ethylene,D) from about 0.01 to 30 parts by weight of at least one compatibilizer, based on 100 by weight of the total of the polyphenylene either and polyamide.Type: GrantFiled: February 20, 1990Date of Patent: November 24, 1992Assignee: Sumitomo Chemical Company, Ltd.Inventors: Hiroomi Abe, Taichi Nishio, Takashi Sanada, Noriyasu Kagawa
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Patent number: 5162403Abstract: Premoulding materials having long-term controllable B-stage characteristic, comprising phenol resins, optionally with reagents, additives and adjuvants, are characterized in that they contain hydraulic binder and/or its components as well as an agent that reduces the alkalinity and optionally the content of free metal ions. For its preparation, 1 part by wt. phenol resin is mixed with less than 4 parts by wt. of a hydraulic binder and/or its components as well as less than 0.2 equivalent parts by weight of the agent. The phenol resin premoulding materials according to the invention thicken quickly to a desired B-stage, are capable of maintaining the attained plateau, and thus allow the manufacture of heat-curable composites of desired rheology and reactivity.Type: GrantFiled: August 2, 1990Date of Patent: November 10, 1992Assignee: Reichhold Chemie Ges.m.b.H.Inventor: I. Thomas Fucik
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Patent number: 5115067Abstract: Disclosed is a molecularly oriented molded body of an ultra-high-molecular-weight ethylene/.alpha.-olefin copolymer having an intrinsic viscosity (.eta.) of at least 5 dl/g and such a content of an .alpha.-olefin having at least 3 carbon atoms that the number of molecules of the .alpha.-olefin is 0.1 to 15 on the average per 1000 carbon atoms, wherein the molded body shows at least two crystal fusion endothermic peaks when the measurement is conducted in the restraint state by using a differential scanning calorimeter, the molded body has at least one crystal fusion endothermic peak (Tp) at a temperature higher by at least 20.degree. C. than the inherent crystal fusion temperature (Tm) of the ultra-high-molecular-weight ethylene/.alpha.-olefin copolymer determined as the main fusion endothermic peak at the time of the second elevation of the temperature, and the quantity of heat based on said crystal fusion endothermic peak (Tp) is at least 15% based on the total fusion heat quantity.Type: GrantFiled: April 4, 1990Date of Patent: May 19, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Akinori Toyota
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Patent number: 5107069Abstract: Described are heat-activatable promoters for treating the surfaces of metals or synthetic materials (plastics) prior to bonding, containingfrom 0.1 to 10% by weight of a carbonyl compound having at least one activated double bond,from 5 to 30% by weight of a polymer having functional groups,from 0 to 10% by weight of further auxiliary materials, as well asone or more organic solvent(s) to make 100% by weight.The invention further relates to a process for producing the heat-activatable adhesion promoter and the use thereof for the surface treatment of polymer fibers.Type: GrantFiled: October 27, 1989Date of Patent: April 21, 1992Inventors: Jurgen Wichelhaus, Johannes Andres, Serge Rebouillat, Werner Gruber
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Patent number: 5106897Abstract: A method for improving the low temperature impact strength of a thermoplastic polyblend of PETG and SAN which method comprises incorporating therein an effective amount of a dispersant selected from the group consisting of mono- and di-carboxylic acids containing 6 to 36 carbon atoms; alkali and alkaline-earth metal salts and amides of such acids; and aliphatic alcohols containing 6 to 36 carbon atoms.Type: GrantFiled: February 20, 1990Date of Patent: April 21, 1992Assignee: Monsanto CompanyInventors: James Y. Chen, Donald B. Baldridge
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Patent number: 5104923Abstract: A non-polymerizable polycarboxylate imparts greater wet strength to nonwovens bound by an emulsion polymer containing a polymerizable cross-linker.Type: GrantFiled: March 31, 1989Date of Patent: April 14, 1992Assignee: Union Oil Company of CaliforniaInventors: Paul J. Steinwand, Dennis P. Stack
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Patent number: 5100930Abstract: Disclosed herein is a food container of a resin composition composed of a polyolefin and an inorganic filler, said resin composition containing (i) a phenolic antioxidant and (ii) a slip agent and/or antistatic agent, said phenolic antioxidant being at least one kind selected from .beta.-(4-hydroxy-3-t-butyl-5-alkylphenyl)propionic acid esters, hindered phenols having an isocyanuric acid ester, 1,3,5-tris(3,5-di-t-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, specific phenol compounds, and 6-hydroxychroman compounds. The food container has a low level of offensive odors and discoloration.Type: GrantFiled: June 28, 1990Date of Patent: March 31, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshiharu Fukui, Kazuhisa Kuroda
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Patent number: 5063265Abstract: Described herein are novel heat-stabilized poly(aryl ether ketone) compositions. Stability is imparted by blending a poly(aryl ether ketone) with an aromatic phosphorus compound and an organic acid having a dissociation constant within a well-defined range.Type: GrantFiled: January 3, 1990Date of Patent: November 5, 1991Assignee: Amoco CorporationInventor: James E. Harris
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Patent number: 5059644Abstract: Polyacetal compositions containing 0.05 to 5 weight percent of an oxo-piperazinyl-triazine hindered amine light stabilizer wherein the hindered N.sup.4 atom in the piperazinone ring of the stabilizer is alkylated with a metyl, ethyl, or propyl group, said compositions being relatively stable upon exposure to UV light. A polyacetal composition containing a specific oxo-piperazinyl-triazine hindered amine light stabilizer wherein the hindered N.sup.4 atom is not alkylated is shown to be relatively stable upon exposure to UV light. Both compositions possess stability during melt processing and do not significantly lose physical properties upon exposure to heat and light.Type: GrantFiled: March 19, 1990Date of Patent: October 22, 1991Assignee: E. I. du Pont de Nemours and CompanyInventor: Leonard E. R. Kosinski
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Patent number: 5008319Abstract: Homogeneous compositions of a solid, water soluble organic acid, e.g., glutaric acid, and a solid cationic ester-based copolymer flocculant are resistant to mechanical segregation and stratification caused by agitation. The compositions are prepared by coating the polymeric flocculant with the organic acid. The compositions are useful in sludge dewatering, water treatment, paper processing and waste water treatment.Type: GrantFiled: February 1, 1990Date of Patent: April 16, 1991Assignee: Polypure, Inc.Inventors: Ronald E. Highsmith, Eric H. Larson
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Patent number: 4959405Abstract: It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.ld).Type: GrantFiled: June 2, 1989Date of Patent: September 25, 1990Assignee: Illinois Tool Works, Inc.Inventors: Paul C. Briggs, Donald E. Gosiewski
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Patent number: 4957954Abstract: Polyvinyl chloride resin stabilizer compositions are provided, comprising a 2,2,6,6-tetramethyl piperidinyl compound and an ammonium or metal perchlorate; and also stabilized polyvinyl chloride resin compositions containing such stabilizers, and optionally including a plasticizer, and particularly as molded articles with polyurethane foam backing.Type: GrantFiled: January 25, 1989Date of Patent: September 18, 1990Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Shunichi Iizuka, Yoshiyuki Sakamaki, Noriyuki Shimoyama
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Patent number: 4943609Abstract: A curable rubber bladder stock containing esters of ricinoleic acid or derivatives thereof has reduced viscosity as compared to stocks containing castor oil. The rubber stocks of the present invention generally retain a very high percentage of the initial cure tensile strength and have improved modulus as compared to castor oil, both upon initial cure and upon aging. Lower viscosity and higher modulus of the rubber stocks of the present invention readily permit the production of thinner bladders. The bladders can fit within an article such as a tire during vulcanization of the tire as in an automatic vulcanizing press. Thinner bladders effect a greater heat rate and result in shorter cure times for articles such as tires. The esters of ricinoleic acid and derivatives thereof have the formula ##STR1## where R is H or ##STR2## where R.sup.1 is an aliphatic, preferably an alkyl, having from 1 to 12 carbon atoms, desirably from 1 to 4 carbon atoms, and preferably 1 carbon atom, i.e., methyl, and R.sup.Type: GrantFiled: April 17, 1989Date of Patent: July 24, 1990Assignee: The Uniroyal Goodrich Tire CompanyInventor: Terrence M. Stuhldreher
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Patent number: 4939187Abstract: A pattern material for making foundry patterns for use in investment casting process, comprising urea, polyvinyl alcohol and a substance, said substance being capable of forming an eutectic mixture with polyvinyl alcohol to reduce the melting temperature of urea.Type: GrantFiled: November 22, 1988Date of Patent: July 3, 1990Inventor: Tadao Fujita
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Patent number: 4900617Abstract: This invention relates to compositions for forming opaque, abrasion-removable masks on substrates. The compositions, which include a texture modifying amount of solid or hollow microspheres, have enabled depression or embossing of the surface of the printed substrates to be obscured so that they cannot be seen by the naked eye. The compositions can be based on plastisols, pigmented polymer solution, or pigmented aqueous emulsions. The invention further provides substrates, for example lottery tickets, having abrasion-removable masks formed from compositions of the invention.Type: GrantFiled: April 14, 1988Date of Patent: February 13, 1990Assignee: Sericol Group LimitedInventor: Jonathan H. Smith
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Patent number: 4871793Abstract: Polyphenylene sulfide resin compositions are provided having improved light stability and comprising an alkylidene bis(benzotriazolyl phenol) having the formula: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about eleven carbon atoms;R.sub.2 is selected from the group consisting of alkyl having from one to about twelve carbon atoms; and arylalkyl having from seven to about eighteen carbon atoms; andX is selected from the group consisting of hydrogen; halogen; alkyl having from one to about twelve carbon atoms; aryl alkyl having from seven to about eighteen carbon atoms; alkoxy having from one to about twelve carbon atoms; phenoxy; arylalkoxy having from seven to about eighteen carbon atoms; and phenyl.Type: GrantFiled: January 21, 1987Date of Patent: October 3, 1989Inventors: Yutaka Nakahara, Atsushi Nishimura, Toshio Nakajima
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Patent number: 4863987Abstract: A deodorizing coating formulation is composed of a white or substantially colorless deodorizing agent, a binder resin and a liquid medium. The deodorizing agent may preferably be composed of 10-90 parts by weight of a zinc compound and 90-10 parts by weight of an aliphatic polycarboxylic acid, aromatic polycarboxylic acid, acidic polymer or a sulfate of aluminum, or a salt thereof. A deodorizing sheet can be obtained by coating and/or impregnating a base sheet with the deodorizing coating formulation and then drying the resulting base sheet. The deodorizing sheet can shield a flavor or odor from external flavors or odors while maintaining air permeability, it is suitable for wrapping foods having strong flavors or odors.Type: GrantFiled: November 10, 1986Date of Patent: September 5, 1989Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.Inventors: Akira Hoshino, Mikio Saji, Shigeaki Fujii
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Patent number: 4857570Abstract: The melting point and the apparent degree of crystallinity of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon are stabilized against undue lowering by intimately mixing with the polymer a succinic anhydride or hydrolysis product thereof.Type: GrantFiled: May 24, 1988Date of Patent: August 15, 1989Assignee: Shell Oil CompanyInventor: Edgar J. Smutny
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Patent number: 4828744Abstract: Conventional polyvinyl alcohol envelopes will not readily dissolve in wash water which has a significant borate concentration and a pH frequently encountered in wash liquors. Herein, such films are rendered sufficiently soluble in such solutions. In the preferred embodiment this is done by utilizing a polyvinyl alcohol film wherein at least a portion of the polyvinyl alcohol has a number average molecular weight below about 50,000, or a polyvinyl alcohol film containing a polyhydroxy compound having a binding constant with borate of at least about 800M.sup.-2, or utilizing a polyvinyl alcohol film having an acid having an acid dissociation constant of 10.sup.-9 M or larger; or a polyvinyl alcohol film containing mixtures thereof.Type: GrantFiled: November 26, 1986Date of Patent: May 9, 1989Assignee: The Clorox CompanyInventors: Edward J. Kaufmann, Barry A. Sudbury
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Patent number: 4816508Abstract: The present invention is directed to an admixture, comprising:(A) a cationic acrylate or methacrylate polymer and(B) 0.1 to 5.0%, by weight, based on the weight of said polymer, of an acidic buffering compound.The present invention is also directed to a method for improving the stability of cationic acrylate polymers, comprising adding 0.1 to 5.0%, by weight, based on the weight of the polymer, of an acidic buffering compound.Type: GrantFiled: April 18, 1988Date of Patent: March 28, 1989Assignee: Calgon CorporationInventor: Shih-Ruey T. Chen
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Patent number: 4812498Abstract: Polycarbonate resin compositions are provided having improved light stability and comprising an alkylidene bis(benzotriazolyl phenol)having the formula: ##STR1## wherein: R.sub.1 is selected from the group consisting of hydrogen and alkyl having from one to about eleven carbon atoms;R.sub.2 is selected from the group consisting of alkyl having from one to about twelve carbon atoms; and arylalkyl having from seven to about eighteen carbon atoms; andX is selected from the group consisting of hydrogen; halogen; alkyl having from one to about twelve carbon atoms; aryl alkyl having from seven to about eighteen carbon atoms; alkoxy having from one to about twelve carbon atoms; phenoxy; arylalkoxy having from seven to about eighteen carbon atoms; and phenyl.Type: GrantFiled: December 22, 1986Date of Patent: March 14, 1989Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Yutaka Nakahara, Atsushi Nishimura, Toshio Nakajima
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Patent number: 4801639Abstract: A flame-retardant olefinic resin composition comprising(A) 100 parts by weight of a mixed resin consisting of an olefinic resin and a silane-grafted polymer obtained by grafting a silane to said olefinic resin,(B) 50 to 300 parts by weight of a hydrated metal compound, and(C) 0.1 to 30 parts by weight of a dicarboxylic acid or dicarboxylic acid anhydride derivative.Type: GrantFiled: July 9, 1987Date of Patent: January 31, 1989Assignee: Sumitomo Bakelite Company LimitedInventors: Kazuo Hoshi, Yasuo Nakagawa
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Patent number: 4798836Abstract: Bis-(2,2,6,6-tetramethyl-piperidyl)diimides are provided, having the formula: ##STR1## in which R is selected from the group consisting of hydrogen; oxyl; alkyl and alkenyl having from one to about eighteen carbon atoms; epoxy and hydroxyalkyl having from two to about eight carbon atoms; acyl having from two to about eight carbon atoms; and phenalkyl having from seven to about twelve carbon atoms; and Z is a tetravalent aliphatic or cycloaliphatic hydrocarbon group having from two to about eighteen carbon atoms; and stabilizer and synthetic polymer compositions containing such diimides having improved resistance to deterioration when exposed to light.Type: GrantFiled: October 26, 1987Date of Patent: January 17, 1989Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Motonobu Minagawa, Yutaka Nakahara, Bunji Hirai, Kazuo Sugibuchi
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Patent number: 4781948Abstract: An acidic water-based film-forming coating composition suitable for the protection of ferrous surfaces by application thereto and drying at ambient temperature wherein said composition contains at least one acid of defined formula, such as lactic or tartaric acid, which prevents or reduces general yellow/brown staining.Type: GrantFiled: June 5, 1986Date of Patent: November 1, 1988Assignee: Imperial Chemical Industries PLCInventor: David Caldwell
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Patent number: 4767669Abstract: Quick setting, nonaqueous melt size compositions suitable for application as a melt to textile yarns, and for later removal by solvent or aqueous means, include substantially equal amounts of an 80/20 ethylene/acrylic acid copolymer and a wax such as hydrogenated tallow intimately blended with a smaller amount of sebacic acid or dodecanedioic acid together with an amount of a nonionic surfactant to facilitate size removal.Type: GrantFiled: April 21, 1987Date of Patent: August 30, 1988Assignee: Burlington Industries, Inc.Inventors: Delano M. Conklin, John H. Hansen, Norbert W. Burske, Robert C. Malpass
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Patent number: 4753971Abstract: Peroxide vulcanizable chlorinated polyethylene compositions can, after being press cured at a temperature of 204.degree. Centigrade for a period of ten minutes, withstand ozone-induced cracking for a period of 168 hours or more when elongated 60% and exposed to 200 parts of ozone per hundred million parts of air at a temperature of 400.degree. Centigrade.Type: GrantFiled: July 10, 1987Date of Patent: June 28, 1988Assignee: The Dow Chemical CompanyInventors: William H. Davis, Jr., Raymond L. Laakso, Jr., Michael E. Price
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Patent number: 4734446Abstract: Polymeric compositions comprised of particularly disclosed oil-soluble polymers and specific oil-soluble acrylate polymerization products are disclosed. The oil-soluble polymer (A) is a polymer selected from the group consisting of a non-aromatic mono-olefin having at least three carbon atoms, and a copolymer of the non-aromatic mono-olefin with an aromatic monoolefin, the polymer having a number average molecular weight of about 500 to about 100,000. The oil-soluble acrylate polymerization product (B) is at least one ester of the formula CH.sub.2 .dbd.C(X)--COOR wherein X is hydrogen or an alkyl or aryl group, and R is a monovalent hydrocarbyl group containing at least four carbon atoms, or an ether derivative of said hydrocarbyl group. The components (A) and (B) are preferably present in a weight ratio of (A):(B) of about 20:1 to about 1:10.Type: GrantFiled: October 27, 1986Date of Patent: March 29, 1988Assignee: The Lubrizol CorporationInventor: Craig D. Tipton
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Patent number: 4714725Abstract: Solutions of sulphonated polyaryletherketones in a solvent mixture of at least three liquids or low melting solids which are non-solvents or poor solvents for the polymer, can be used to produce asymmetric semi-permeable membranes. The polymer may be a polymer of(Ph.sup.1 --O--Ph.sup.2 --O--Ph.sup.1 --CO)and optionally(Ph.sup.1 --O--Ph.sup.1 --CO)and(Ph.sup.1 --O--Ph.sup.1 --O--Ph.sup.1 --CO)wherein Ph.sup.1 and Ph.sup.2 are respectively unsulphonated and sulphonated phenylene residues. The components of the solvent mixture have specified solubility parameters. A suitable solvent mixture is one formed from water, 1,4-dioxane and acetonitrile.Type: GrantFiled: April 6, 1987Date of Patent: December 22, 1987Assignee: Imperial Chemical Industries PLCInventors: Brian N. Hendy, John W. Smith
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Patent number: 4714730Abstract: It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.1d).Type: GrantFiled: June 4, 1986Date of Patent: December 22, 1987Assignee: Illinois Tool Works Inc.Inventors: Paul C. Briggs, Donald E. Gosiewski
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Patent number: 4690958Abstract: The inclusion of a substantially saturated dicarboxylic acid, anhydride or ester substituted with at least one hydrogen and carbon containing group of at least 30 carbon atoms and optionally an acidic C.sub.2 and/or C.sub.3 olefin polymer or copolymer of molecular weight 500 to 30,000 having an acid number from 30 to 300 wt. % of a resin in a resin based hot melt road marking formulation containing aggregate gives a formulation of improved colour and melt viscosity.Type: GrantFiled: February 21, 1986Date of Patent: September 1, 1987Assignee: Exxon Chemical Patents Inc.Inventors: Olivier H. V. Lacoste, Alain De Regel, Hidenori Fujiwara, Raymond C. C. Yap
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Patent number: 4690959Abstract: Compositions which are particularly useful as coupling agents and primers for polyolefin composites. The compositions comprise fumaric acid and diaminefunctional silanes in mole ratios from 1.0 to 1.4 in nonreactive solvent, particularly water. These compositions are particularly effective in polyethylene composite materials.Type: GrantFiled: May 9, 1986Date of Patent: September 1, 1987Assignee: Dow Corning CorporationInventor: Edwin P. Plueddemann
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Patent number: 4670490Abstract: A vinyl chloride resin composition with a yield stress of 1 to 5 g/mm.sup.2, composed of(A) 100 parts by weight of a vinyl chloride resin containing 0 to about 20% by weight of a comonomer,(B) about 10 to about 80 parts by weight, per 100 parts by weight of the resin (A), of (B-1) a liquid polyester plasticizer having a number average molecular weight (Mn) of not less than about 1,500 and 0 to about 10 parts by weight, per 100 parts by weight of the resin (A), of (B-2) a plasticizer for the resin (A), which is other than said plasticizer (B-1), and(C) about 0.2 to about 200% by weight, based on the total weight of said plasticizers (B-1) and (B-2), of a low-molecular-weight acrylic or methacrylic resin having a number average molecular weight (Mn) of about 1,500 to about 50,000 and being solid at 23.degree. C.Type: GrantFiled: March 19, 1984Date of Patent: June 2, 1987Assignee: Nippon Carbide Kogyo Kabushiki KaishaInventors: Tatsuro Yoshida, Hidematsu Shimasaki, Takahisa Minamizono, Katsura Ochi
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Patent number: 4639483Abstract: A gelled dielectric encapsulant material and process therefor for use in reenterable and nonreenterable communication cable splices as well as applications relating to encapsulation of electronic components comprises a plasticizer which does not stress crack polycarbonate, an aliphatic or aromatic carboxylic acid, and a basic oxide or hydroxide.Type: GrantFiled: May 9, 1985Date of Patent: January 27, 1987Assignee: Minnesota Mining and Manufacturing CompanyInventors: James E. Billigmeier, James D. Groves, Harwick A. Haugen, Richard J. Pokorny
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Patent number: 4611017Abstract: The oxidative, process, and/or color stability of carboxyl-containing ethylene interpolymers is improved by incorporating therein at least one aromatic bis(organophosphorus) compound, with or without a hindered phenol antioxidant and/or a dicarboxylic acid.Type: GrantFiled: December 7, 1984Date of Patent: September 9, 1986Assignee: The Dow Chemical CompanyInventors: Osborne K. McKinney, David P. Flores
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Patent number: 4605596Abstract: An additive for coating compositions which is a blend of(A) 20-50% by weight of a polyisocyanate of one of the following formulas: ##STR1## where R.sup.1 is (CH.sub.2).sub.6, (B) 1-15% by weight of an ester of a polyalkylene glycol alkyl alkylate, an alkyl phthalate or an alkyl aromatic phthalate(C) 1-10% by weight of a blend of ultraviolet light stabilizers and(D) 25-78% by weight of organic solvent; the additive can be added to acrylic lacquers, nitrocellulose lacquers, acrylic-alkyd enamels and acrylic polyurethane enamels to provide flexible finishes for flexible substrates used in automobile and truck bodies.Type: GrantFiled: December 19, 1983Date of Patent: August 12, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Grant C. Fry
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Patent number: 4602058Abstract: The compatibility and thermal stability of blends of polyamides/carboxyl-containing ethylene polymers is improved by adding thereto an organic carboxylic acid compound, especially di-basic acids such as sebacic acid or tartaric acid. The blends may also contain free-radical scavengers and/or antioxidants. These blends are useful as heat-plasticized adhesives or bonding agents.Type: GrantFiled: July 2, 1984Date of Patent: July 22, 1986Assignee: The Dow Chemical CompanyInventors: Stephen L. Graham, Laura A. Kelly
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Patent number: 4594378Abstract: Polymeric compositions are described which comprise a mixture of(A) at least one oil-soluble polymer which is a homopolymer of a non-aromatic monoolefin or a copolymer of said non-aromatic monoolefin with an aromatic monoolefin, and(B-1) at least one nitrogen-containing ester of a carboxy-containing interpolymer, and/or(B-2) at least one oil-soluble acrylate polymerization product of at least one acrylate ester, or a mixture of one or more of (B-1) and (B-2). The polymeric compositions of the invention also may contain(C) an effective amount of at least one viscosity-reducing liquid organic diluent such as a naphthenic oil or an alkylated aromatic material.Type: GrantFiled: March 25, 1985Date of Patent: June 10, 1986Assignee: The Lubrizol CorporationInventors: Craig D. Tipton, Kent B. Grover
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Patent number: 4594367Abstract: An antistatic polymer blend composition and articles made therefrom are disclosed. The composition comprises, based on parts by weight: (a) polyvinyl chloride: 100 parts; (b) carboxylated nitrile terpolymer: 30-40 parts; (c) nonionic antistatic agent: 5-8 parts; (d) metallic stabilizers: 2-5 parts; (e) epoxidized oil: 5-10 parts; (f) primary plasticizer: 50-90 parts; and (g) lubricant: 1-2 parts. A method of protection against the effects or build up of antistatic electricity employing articles made from the composition of the present invention is also disclosed.Type: GrantFiled: April 1, 1985Date of Patent: June 10, 1986Assignee: Bata LimitedInventors: Geissel Francis A., William W. Alexander, John Rys-Sikora
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Patent number: 4569958Abstract: An elastomeric composition whose scorch is inhibited comprises [I] a halogen-containing elastomer, [II] a di- or tri-thiol-s-triazine compound and [III] at least one polycarboxylic acid compound selected from the group consisting of (A) a polycarboxylic acid having at least two carboxyl groups capable of forming an acid anhydride group in the molecule and (B) a halogen-substituted polycarboxylic acid anhydride.Type: GrantFiled: July 2, 1985Date of Patent: February 11, 1986Assignee: Nippon Zeon Co LtdInventors: Akio Maeda, Mitsuyoshi Aonuma, Masahiko Muranishi