Ketone Or Ketene Dnrm, I.e., C(c=o)c Or C=c=o Patents (Class 524/356)
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Patent number: 5939478Abstract: The viscosity of a solvent is modified by thickening the solvent with a silicone latex. A silicone latex having a plurality of crosslinked polysiloxane particles is first prepared by mixing the siloxane polymer, a surfactant, and water; emulsifying the mixture to a gel phase; diluting the emulsion with water; adding a cure package (i.e., a catalyst, a crosslinker, or both, or a self catalytic crosslinker); and then without removing the water from the latex and after the particles of siloxane polymer in the latex have been cured, mixing the latex and solvent to thicken the solvent, forming viscous liquids, gels, and pastes. Water in the latex thickened solvent composition can be stabilized by adding a silicone polyether during mixing of the latex and the solvent.Type: GrantFiled: November 13, 1997Date of Patent: August 17, 1999Assignee: Dow Corning CorporationInventors: James Anderson Beck, Vicky Sue Cobb, Cassie Emelia Cuthbert, Eric Jude Joffre, Virginia Kay O'Neil, Burt Michael Wrolson
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Patent number: 5936027Abstract: A jet ink composition for use with textiles which comprises a pigment dispersed with an ethyl cellulose resin, a silicone resin, a phenolic resin, and at least one non-aqueous solvent in which the pigment dispersion, silicone resin, and phenolic resin are dissolved. The printed images formed therefrom are readable even when applied to darkly-dyed textiles.Type: GrantFiled: December 19, 1995Date of Patent: August 10, 1999Assignee: Videojet Systems International, Inc.Inventors: Peter Zahrobsky, Bruce Lent
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Patent number: 5929150Abstract: A polyketone solution is prepared by the dissolution of alternating aliphatic polyketone in a solution of ZnX.sub.2. X can be Cl, Br, or I. At a given temperature, these solvents completely dissolve polyketone when aqueous or organic solutions are made from particular concentrations.Type: GrantFiled: August 4, 1998Date of Patent: July 27, 1999Assignee: Shell Oil CompanyInventor: Carlton Edwin Ash
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Patent number: 5902872Abstract: A resin for coating formation which comprises a polyarylate comprising 2,2-bis(3-methyl-4-hydroxyphenyl)propane units and a divalent carboxylic acid component comprising 10 to 90 mol % of terephthalic acid units and 90 to 10 mol % of isophthalic acid units, having an inherent viscosity measured in 1,1,2,2-tetrachloroethane at a concentration of 1 g/dl at 25.degree. C. of 0.85 or more, and having a carboxyl value of 20 mol/ton or less. Also disclosed is a process for producing the resin by interfacial polymerization, using a quaternary ammonium salt or a quaternary phosphonium salt having at least 3 alkyl groups each having at least 3 carbon atoms as a catalyst.Type: GrantFiled: May 28, 1998Date of Patent: May 11, 1999Assignee: Unitika, Ltd.Inventors: Souichiro Kishimoto, Takamasa Ohwaki, Shinya Takagi, Tomohiro Hamada, Akihiko Hasegawa
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Patent number: 5902847Abstract: A coating composition prepared by mixing an organic solvent based coating composition with (1) a silicone compound having organofunctional group and hydrolyzable group in one molecule and containing a specified silicon structural unit, or (2) a silicone compound consisting of a partial cohydrolysis.cndot.condensation product of a silane mixture of alkoxysilane compound containing at least one organofunctional group selected from the group consisting of (meth)acryloyl group, vinyl group, haloalkyl group, amino group, epoxy group and mercapto group with tetraalkoxysilane compound.Type: GrantFiled: July 30, 1996Date of Patent: May 11, 1999Assignee: Kansai Paint Co., Ltd.Inventors: Junpei Yanagi, Haruo Furuse, Kazuhiko Ohnishi, Masaaki Yamaya, Masahiro Yoshizawa
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Patent number: 5891573Abstract: A method is disclosed for providing a friable polytetrafluoroethylene (PTFE) product that has particles of a desired size which are flowable and do not tend to agglomerate. To achieve this result, the PTFE starting material is handled at a temperature below 66.degree. F., and preferably below 55.degree. F., before irradiating. The PTFE starting material may be mixed with a wetting agent before irradiating to provide a product that has enhanced dispersibility. The source of radiation may include electron beam radiation, nuclear radiation, or radiation from a cobalt-60 (CO.sub.60) source.Type: GrantFiled: August 8, 1997Date of Patent: April 6, 1999Assignee: Shamrock Chemicals CorporationInventors: Nicholas W. Neuberg, George Poszmik, Manshi Sui
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Patent number: 5883139Abstract: A process involving (a) homogeneously dispersing tetrathiodipropionic acid in a recycled rubber having an individual particle size no greater than 420 microns, (b) mixing the treated recycled rubber with unvulcanized rubber and (c) vulcanizing the rubber mixture.Type: GrantFiled: February 20, 1998Date of Patent: March 16, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, George Frank Balogh, Raymond Dean McQuate
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Patent number: 5880210Abstract: Silicone gels are made by reacting an .tbd.Si--H containing polysiloxane with an alpha-olefin and an alpha, omega-diene. The reaction is conducted in the presence of a platinum catalyst and in the presence of a low molecular weight silicone oil. First, an .tbd.Si--H containing polysiloxane is grafted by long chain alkyl groups from the alpha-olefin onto the .tbd.Si--H containing polysiloxane, and then crosslinked with double bonds in the alpha, omega-diene, in the presence of the low molecular weight silicone oil. The formed silicone gel can then be crumbled into a silicone powder using mechanical force. When additional amounts of the low molecular weight silicone oil are added to the gel, and the silicone oil and the gel are subjected to shear force, a silicone paste can be formed.Type: GrantFiled: April 1, 1997Date of Patent: March 9, 1999Assignee: Dow Corning CorporationInventors: William James Schulz, Jr., Shizhong Zhang
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Patent number: 5877259Abstract: A heat-sealable adhesive for dissimilar substrates is disclosed comprising an organic solvent suspension of a graft copolymer of an A-B-A terblock copolymeric rubber, olefin copolymer and olefin terpolymer. Processing conditions are improved over known adhesive preparation conditions.Type: GrantFiled: October 14, 1997Date of Patent: March 2, 1999Assignee: Sun Chemical CorporationInventors: Albert A. Kveglis, Robert J. Catena, Joseph M. Laquidara, Stavros Staveris
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Patent number: 5859103Abstract: The present invention relates to a low VOC solvent based adhesive comprising a mixture of at least two organic solvents and a thermoplastic resin having a flash point of at least 100.degree. F. when measured in accordance with ASTM D3828-87. The low VOC solvent based adhesive of the instant invention volatilizes at substantially reduced rates as compared to conventional solvent based adhesives. Furthermore, this novel low VOC solvent based adhesive is easy to apply, cost effective, cures within a reasonable time without the use of heat, ultraviolet light or other mechanical devices. In addition, the novel low VOC solvent based adhesive can be stored in containers other than the steel tins.Type: GrantFiled: June 4, 1997Date of Patent: January 12, 1999Assignee: B. F. Goodrich CompanyInventors: Carmen D. Congelio, Andrew M. Olah
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Patent number: 5852091Abstract: Disclosed is a solvent-based cement for bonding joints of polyvinyl chloride pipe and fittings. The cement of the composition contains at least about 10% by weight of a polyvinyl chloride resin, at least about 2% by weight of a solid alcohol having a melting point above at least about 20.degree. C., and at least about 10% by weight of a solvent or a mixture of solvents. There is also provided a method of joining two pieces of thermoplastic material, such a poly(vinyl chloride) piping and fittings, and the product piece having one or more joints formed thereby.Type: GrantFiled: October 4, 1996Date of Patent: December 22, 1998Assignee: BASF CorporationInventors: Mark W. Waldrop, William C. Walsh
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Patent number: 5852088Abstract: The present invention provides for amorphous, nanoporous, catalytic metal-containing ceramic material having a surface area in excess of 70 m.sup.2 /gm and characterized by a high content of open microporous cell structure wherein the micropores have a mean width of less than 20 Angstroms and wherein said microporous structure comprises a volume of greater than about 0.03 cm.sup.3 /gm of the ceramic. The invention also provides for a preceramic composite intermediate composition comprising a mixture of a ceramic precursor and from about 0.5 up to about 65 wt % of an organometallic compound containing a metal of Group IB, II, III, IV, IV, V, VIB, VIIA or VIII of the Periodic Table, including rare earth metals, whose pyrolysis product in ammonia or an inert atmosphere at temperatures of up to less than about 1100.degree. C. gives rise to the nanoporous catalytic ceramics of the invention.Type: GrantFiled: December 27, 1995Date of Patent: December 22, 1998Assignee: Exxon Research and Engineering CompanyInventors: John P. Dismukes, Jack Wayne Johnson, John Stewart Bradley
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Patent number: 5846663Abstract: A sizing agent for paper that is a 2-oxetanone ketene multimer which is not solid at 35.degree. C., particularly a multimer mixture in which at least 25 weight percent of the hydrocarbon substituents contain irregularities such as branched alkyl groups or linear or branched alkenyl groups. Paper surface sized with the 2-oxetanone ketene multimer sizing agent and the method of surface sizing paper are also disclosed.Type: GrantFiled: February 16, 1996Date of Patent: December 8, 1998Assignee: Hercules IncorporatedInventors: Clement L. Brungardt, Richard J. Riehle, Jian Jian Zhang
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Patent number: 5834553Abstract: A dampproofing composition comprising from about 25 to about 80 parts by weight of a polymer based component, from about 15 to about 70 parts by weight of a solvent, and from about 5 to about 60 parts by weight of a processing oil, to total about 100 parts by weight, wherein the solvent produces a substantially homogeneous solution.Type: GrantFiled: April 9, 1997Date of Patent: November 10, 1998Inventors: Michael G. Roberts, Sr., Michael G. Roberts, Jr.
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Patent number: 5821314Abstract: This invention provides a thermosetting composition comprising (A) a compound (A-1) containing an epoxy group or groups and a reactive silicon group or groups as essential functional group components in the same molecule, or a mixture (A-2) of an epoxy group-containing compound and a reactive silicon group-containing compound, and (B) an organotin catalyst, a thermosetting composition comprising (A) a compound (A-3) containing (i) an epoxy group or groups, (ii) a reactive silicon group or groups and (iii) a hydroxyl group or groups and/or a carboxyl group or groups as essential functional group components in the same molecule, or a mixture (A-4) of at least two types of compounds, each compound containing at least one member selected from the class consisting of functional group components (i) to (iii), and all of the functional group components (i) to (iii) being present in said mixture, and (B) an organotin catalyst; and methods of forming a finish coat using these thermosetting compositions.Type: GrantFiled: December 13, 1996Date of Patent: October 13, 1998Assignee: Kansai Paint Company, LimitedInventors: Satoshi Ikushima, Yasumasa Okumura, Osamu Isozaki, Minoru Tsunoda
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Patent number: 5773531Abstract: A modified acrylic urethane prepolymer composition and an unsaturated polyester resin composition to which the prepolymer has been added. The prepolymer composition includes an acrylic urethane prepolymer prepared by the reaction of diisocyanate, like MDI, with an hydroxyl-containing acrylate monomer, such as a pentaerythritol triacrylate, which prepolymer composition may contain a styrene monomer and an inhibitor, such as benzoquinone, to retard the reaction of the prepolymer and styrene monomer prior to the addition of the prepolymer composition into the polyester resin composition. The employment of the modified urethane prepolymer composition provides for the reduction in the amount of styrene monomer used in the unsaturated resin composition and also provides for improved chemical and physical properties of the cured, unsaturated resin composition, such as a reduction in glass roll-out when the resin composition is employed with fiberglass.Type: GrantFiled: August 29, 1997Date of Patent: June 30, 1998Assignee: Hehr International Inc.Inventor: Stuart B. Smith
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Patent number: 5756559Abstract: A composition and method of treating a dental tooth surface and adhering a restorative material to the treated dental tooth surface is provided. A liquid composition is applied to at least the portion of the tooth to form a treated surface. The composition includes at least 50 percent by weight of a volatile organic solvent, at least 15 percent by weight of one or more polymerizable acrylate compounds and an effective amount of a photoinitiator. At least a portion of the polymerizable compounds are multifunctional polymerizable compounds having at least three acrylate moieties. The polymerizable compounds are substantially soluble in the solvent. The composition is adapted to form a polymeric material which is adapted to adhere to dentin with a bond strength of at least 12 Mpa. Restorative material is then adhered to the treated surface with a bond strength of at least about 12 MPa.Type: GrantFiled: April 4, 1996Date of Patent: May 26, 1998Assignee: Dentsply Research & DevelopmentInventors: Gordon Blackwell, Chin-Teh Huang
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Patent number: 5717013Abstract: A polypropylene resin composition comprising (a) 100 parts by weight of a propylene polymer having an isotactic pentad fraction of 96% or more which is determined by .sup.13 C-NMR, (b) 0.01-5 parts by weight of at least one alkali salt selected from the group consisting of alkali carboxylates, alkali .beta.-diketonates and alkali salts of .beta.-ketacetate, (c) 0.01-5 parts by weight of an organophosphoric compound, and (d) 0.01-0.5 parts by weight of a lithium aluminum compound. The organophosphoric compound is represented by the following formula (I): ##STR1## wherein R.sub.1 is hydrogen or an alkyl group having 1 to 4 carbon atoms, each of R.sub.2 and R.sub.3 is independently hydrogen or an alkyl group having 1 to 12 carbon atoms, M is a metal atom of an element selected from the group consisting of Group III, IV, XIII and XIV elements of the Periodic Table, and X is --OH when M is a metal atom of an element of Group III or XIII of the Periodic Table or X is .dbd.O or (--OH).sub.Type: GrantFiled: August 22, 1996Date of Patent: February 10, 1998Assignee: Tonen Chemical CorporationInventors: Kenji Ichiyanagi, Masayuki Yamazaki
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Patent number: 5714567Abstract: An improved process for the preparation of aromatic polyesters, whereby dialkyl esters of aromatic dicarboxylic acids are melt-polymerized with aromatic bisphenol to furnish an amorphous poly(arylester) prepolymer. The amorphous poly(arylester) prepolymer is crystallized, separated, and dried to provide a crystallized poly(arylester) prepolymer, which is heated to yield the aromatic polyester.Type: GrantFiled: February 15, 1996Date of Patent: February 3, 1998Assignee: Council of Scientific & Ind. ResearchInventors: Bhaskar Bhairavnath Idage, Sudhakar Sadashiv Mahajan, Swaminathan Sivaram
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Patent number: 5698614Abstract: A fluorescent ink composition which comprises:(a) an organic solvent which comprises propylene glycol monomethyl ether as a solvent:(b) a solution type fluorescent pigment dissolved in the organic solvent; and(c) a ketone resin.Type: GrantFiled: June 7, 1995Date of Patent: December 16, 1997Assignee: Sakura Color Products CorporationInventors: Hiroaki Ueda, Masakazu Yokoi, Yasushi Okuda
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Patent number: 5688863Abstract: A thermoplastic polyurethane urea prepared by reacting a reaction mixture ofa) one or more polyisocyanates, withb) one or more compounds having on average at least 1.8 Zerewitinoff-active hydrogen atoms and a molecular weight of between 400 and 10,000, andc) water,wherein the water is introduced into the reaction mixture with the aid of an effective quantity of one or more emulsifiers. The reaction mixture may additionally contain d) further conventional auxiliary substances and additives.Type: GrantFiled: January 5, 1996Date of Patent: November 18, 1997Assignee: Bayer AktiengesellschaftInventors: Stephan Kirchmeyer, Hanns-Peter Muller, Hans-Georg Wussow, Bodo Rehbold
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Patent number: 5665814Abstract: An improved silane/silica sol copolymer hardcoating composition for protecting optical plastic substrates from scratching is able to be manufactured at lower costs and to provide much-improved ease of use in transportation, storage, dipbath stability, and blush resistance in ordinary cleanroom atmospheres. The silane/silica sol copolymer is formed as a direct reaction product of an acidic silica sol and an monomethyl trialkoxy silane, preferably substantially monomethyltriethoxysilane, in ratios of 30:70 to 70:30, most preferably about 40:60. A tail solvent aids blush resistance and adhesion to unprimed polycarbonate. Optionally, colloidal silica sol dissolved in water-miscible solvent may be reacted in a second stage with acidic aqueous colloidal silica sol earlier silanized with monomethyl trialkoxy silane.Type: GrantFiled: May 4, 1995Date of Patent: September 9, 1997Assignee: Abchem ManufacturingInventors: William Lewis, George Galic
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Patent number: 5644005Abstract: A biodegradable block copolymer made from the transesterfication of a poly(propylene fumarate) prepolymer and a poly(ethylene oxide) prepolymer. The block copolymer poly(propylene fumarate -co- ethylene oxide) is capable of crosslinking at body temperature. Crosslinking requires an appropriate crosslinking monomer and an initiator. The biodegradable block copolymer has utility as a vascular implant became it can be injected as a fluid into the vascular system and crosslinked in situ.Type: GrantFiled: April 24, 1996Date of Patent: July 1, 1997Assignee: Rice UniversityInventors: Laura J. Suggs, Richard G. Payne, Michael J. Yaszemski, Antonios G. Mikos
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Patent number: 5643986Abstract: A composition containing 100 parts by weight of a soluble polyimidosiloxane obtained by polymerization and imidation of an aromatic tetracarboxylic acid component and a component comprising a diaminopolysiloxane, an aromatic diamine with a hydroxyl group and optionally another aromatic diamine, 1 to 50 parts by weight of an epoxy resin, and optionally, also 2 to 150 parts by weight of an inorganic filler such as mica, silica or barium sulfate, and an organic solvent. The composition is homogeneously soluble in organic solvents, and when formed into a protective film on a flexible wiring board it has high heat resistance, flexing resistance, adhesion and chemical resistance (against soldering flux and tin plating solutions).Type: GrantFiled: March 14, 1996Date of Patent: July 1, 1997Assignee: Ube Industries, Ltd.Inventors: Seiji Ishikawa, Hiroshi Yasuno, Masayuki Nakatani, Hiroyuki Fukuda, Shigeru Yamamoto
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Patent number: 5641847Abstract: A swellable oil-absorbent agent formed of a cross-linked polymer (P) obtained by polymerizing a monomer component comprising 90 to 99.999% by weight of a monomer having as a main moiety thereof an alkyl (meth)acrylate the alkyl group of which has 10 to 16 carbon atoms and possessing one polymerizable unsaturated group in the molecular unit thereof and 0.001 to 10% by weight of a cross-linkable monomer possessing at least two polymerizable unsaturated groups in the molecular unit thereof (providing that the total of the amount of the polymerizable monomer and that of the cross-linkable monomer is 100% by weight).Type: GrantFiled: December 28, 1995Date of Patent: June 24, 1997Assignee: Nippon Shokubai Kagaku Kogyo Co., Ltd.Inventors: Yoshiyuki Hozumi, Toru Inaoka, Tomoki Gomi, Takakiyo Goto, Toru Uno, Kenji Rakutani
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Patent number: 5637631Abstract: A process for preparing a degradable copolymer of aliphatic polyester comprising the steps of reacting two or more kinds of aliphatic polyester homopolymer in the presence of a catalyst in a reaction mixture containing an organic solvent, and a degradable copolymer of aliphatic polyester obtained by said preparation process. The copolymers exhibits high transparency in addition to excellent strength and elongation, can be processed into various molded articles and formed items such as films and filaments, and can provide heat resistance by heat treatment of said molded articles and formed items. The copolymer can be suitably utilized for processed articles such as a film, breathable film, sheet, textile, monofilament, multifilament, yarn, non-woven fabric, flat yarn, staple, crimped fiber, ribbed tape, split yarn, conjugate fiber, laminate, blow-bottle, sheet, stretched sheet, foam and net.Type: GrantFiled: November 6, 1995Date of Patent: June 10, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Ikumi Kitada, Chojiro Higuchi, Masanobu Ajioka, Akihiro Yamaguchi
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Patent number: 5626958Abstract: The invention relates to a coating composition for PVC sections, based on a polymeric vehicle, a crosslinking agent, and a thermoplastic resin powder. The coating composition is particularly useful for coating PVC sections for windows, shutters, and doors. PVC joinery coated with the composition of the invention has exceptional impact strength and resistance to abrasion, friction, and inclement weather.Type: GrantFiled: February 1, 1994Date of Patent: May 6, 1997Assignee: Elf Atochem S.A.Inventors: Bruno D'Herbecourt, Thierry Moulin
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Patent number: 5576410Abstract: A diaminourea compound having the formula (I); ##STR1## wherein R.sub.1 and R.sub.2 are independently a straight or branched alkylene group having 2 to 8 carbon atoms, an alicyclic alkylene group having 6 to 15 carbon atoms, a phenylene group, a C.sub.1 -C.sub.4 alkyl-substituted phenylene group, a C.sub.1 -C.sub.4 mono- or di-alkylene substituted phenylene group, or a methanediphenylene group, and a production process thereof as well as a high heat resistant polyurethaneurea derived therefrom and a production process thereof.Type: GrantFiled: January 25, 1995Date of Patent: November 19, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Akihiko Yosizato, Satoshi Furubeppu
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Patent number: 5574084Abstract: Modifiers for ethylene copolymers for use in hot melt adhesives are provided, particularly modifiers for ethylene vinyl acetate-based adhesives which improve adhesive properties are provided. Blends comprising ethylene copolymers, modifiers and tackifiers and applications thereof are also provided for.Type: GrantFiled: November 14, 1994Date of Patent: November 12, 1996Assignee: Exxon Chemical Patents, Inc.Inventor: Andrew J. Peacock
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Patent number: 5571567Abstract: Dip molding of thermoplastic polyurethane elastomers to form medical and surgical gloves, condoms, instrument and appliance covers, and other rubber goods is improved by a controlled viscosity, controlled rate of evaporation solvent system, including a strong polar solvent, a weak solvent or non-solvent to control viscosity, and a blush resistor to control the rate of evaporation and the effects of humidity. For particularly enhanced barrier film formation, a leveling agent is also included. One or more layers are dipped in sequential steps in thicknesses of 0.5 to 1.5 mils per layer, with complete integral film formation and substantially complete freedom from porosity and pin holes. Cross-linkable polyurethanes may be cured after fully molded.Type: GrantFiled: June 7, 1995Date of Patent: November 5, 1996Assignee: Polygenex International, IncInventor: Tilak M. Shah
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Patent number: 5567755Abstract: A coating solution for forming a composite metal oxide film containing: (A) at least one member selected from the group consisting of a reaction product, a partial hydrolyzate of the reaction product, and a partial acylated product of the reaction product wherein the reaction product is obtained by a reaction between at least one compound containing a carbonyl group and at least one metal compound; (B) a polyhydric alcohol compound; and (C) at least one member selected from the group consisting of a metal carboxylate compound; a metal nitrate compound; and a metal nitrite compound, which coating solution may also contain an alcohol-soluble polymer. The present invention is also directed to a process of making the same.Type: GrantFiled: April 17, 1995Date of Patent: October 22, 1996Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Akira Hashimoto, Katsuya Tanitsu
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Patent number: 5563236Abstract: A resin composition for coating of the present invention includes a polyester containing an acid component and a polyol component, wherein the polyester is soluble or dispersible in a solvent consisting essentially of at least one solvent selected from the group consisting of cyclohexanone and isophorone; the polyester has a metal sulfonate group in an amount in the range of 0.1 to 5 mol % based on the total moles of the acid component or the polyol component and is slightly soluble in an organic solvent in the case where the content of the metal sulfonate group is 0%; and a specific gravity of the polyester at 30.degree. C. is in the range of 1.265 to 1.340.Type: GrantFiled: February 21, 1995Date of Patent: October 8, 1996Assignee: Toyo Boseki Kabushiki KaishaInventors: Hiroshi Murata, Hiroshi Tachika, Hiroshi Fujimoto
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Patent number: 5554673Abstract: Dip molding of thermoplastic polyurethane elastomers to form medical and surgical gloves, condoms, instrument and appliance covers, and other rubber goods is improved by a controlled viscosity, controlled rate of evaporation solvent system, including a strong polar solvent, a weak solvent or non-solvent to control viscosity, and a blush resistor to control the rate of evaporation and the effects of humidity. For particularly enhanced barrier film formation, a leveling agent is also included. One or more layers are dipped in sequential steps in thicknesses of 0.5 to 1.5 mils per layer, with complete integral film formation and substantially complete freedom from porosity and pin holes. Cross-linkable polyurethanes may be cured after fully molded.Type: GrantFiled: November 29, 1993Date of Patent: September 10, 1996Assignee: Polygenex International, Inc.Inventor: Tilak M. Shah
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Patent number: 5550179Abstract: A water based transparent or translucent lacquer composition for application to plastic items and which provides good adhesion. The lacquer composition comprises a film-forming polymer dispersion along with a water miscible organic solvent, such as an alcohol, present in an amount which does not exceed thirty percent by weight. A substantial portion of the composition e.g. at least 30% is comprised of water. A pigment or dye is incorporated in the composition to provide a color hue or tone to the composition but where the composition still remains transparent or translucent. The composition may also include a coalescing agent, such as an ester alcohol, to provide the needed film resiliency and elongation and to lower film forming temperature. The composition may also optionally include a surfactant. In addition, the composition may optionally include a wetting agent and a thickener and plasticizer.Type: GrantFiled: April 19, 1993Date of Patent: August 27, 1996Inventor: Nichan Srourian
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Patent number: 5525656Abstract: The invention provides a coating composition for coating aluminum which is based on vinyl ester copolymers and an organic solvent, the vinyl ester copolymer comprisinga) 20 to 90 parts by weight of a vinyl ester of saturated aliphatic monocarboxylic acids having 1 to 5 C atoms,b) 0 to 70 parts by weight of a vinyl ester of saturated aliphatic monocarboxylic acids which have 9 to 10 C atoms and a quaternary C atom in the .alpha.-position relative to the carboxyl group,c) 0.05 to 10 parts by weight of one or more ethylenically unsaturated mono- or dicarboxylic acids having 3 to 10 C atoms or anhydrides thereof andd) 0 to 50 parts by weight of one or more ethylenically unsaturated monomers, the homopolymers of which have a glass transition temperature above 30.degree. C.The coating composition is free of chlorine-containing polymers and also avoids the necessity for using a chlorine-containing primer.Type: GrantFiled: August 3, 1994Date of Patent: June 11, 1996Assignee: Wacker Chemie GmbHInventors: Peter Heiling, Dieter Gorzel, Peter Tschirner
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Patent number: 5509959Abstract: The present invention relates to precursor coating compositions which are particularly suitable for being admixed with at least one supercritical fluid used as a viscosity reduction diluent and then spraying this resultant liquid mixture of supercritical fluid and precursor coating composition onto a substrate to be coated.Type: GrantFiled: April 15, 1991Date of Patent: April 23, 1996Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Kenneth A. Nielsen, Charles W. Glancy
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Patent number: 5508332Abstract: A coating composition for forming a composite metal oxide film containing: (A) at least one member selected from the group consisting of a reaction product, a partial hydrolyzate of the reaction product, and a partial acylated product of the reaction product wherein the reaction product is obtained by a reaction between at least one compound containing a carbonyl group and at least one metal compound; (B) a polyhydric alcohol compound; and (C) at least one member selected from the group consisting of a metal carboxylate compound; a metal nitrate compound; and a metal nitrite compound, which coating solution may also contain an alcohol-soluble polymer, and a process of making the same.Type: GrantFiled: November 22, 1993Date of Patent: April 16, 1996Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Akira Hashimoto, Katsuya Tanitsu
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Patent number: 5502097Abstract: A fluororesin powder liquid dispersion comprising heat-flowable fluororesin powder, liquid dispersion medium having a surface tension of not more than 45 dyne/cm, and organic liquid with a boiling point of 150.degree.-340.degree. C. provides thick film fluororesin treatment by a single application.Type: GrantFiled: May 26, 1994Date of Patent: March 26, 1996Assignee: DuPont-Mitsui Fluorochemicals Co., Ltd.Inventor: Takumi Saito
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Patent number: 5502096Abstract: A room temperature curable rubber composition of a condensation curing type that comprises as a base polymer a diorganopolysiloxane or a polyoxyalkylene in which both ends of the molecular chain are blocked with a hydrolyzable silyl group, and a carbonyl compound, an amino group containing organic compound, and an .alpha.,.beta.-unsaturated carbonyl compound that are blended with the base polymer. Since the room temperature curable rubber composition is cured with water in the air and at the same time the dehydration condensation of the carbonyl group and the amino group produces water in the composition, the quick curability and deep curability are improved remarkably.Type: GrantFiled: October 19, 1994Date of Patent: March 26, 1996Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Tsuneo Kimura, Masatoshi Arai
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Patent number: 5486567Abstract: This invention provides a primer composition comprising (A) a polyorganosiloxane resin containing at least 0.01 mole of hydroxyl groups per 100 g of the resin represented by the average composition formula: (R.sup.1).sub.a SiO.sub.(4-a)/2 wherein each R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon group, and a is a value of 0.4 to 1.8; (B) an alkoxytitanium or a partially hydrolyzed product thereof; (C) an acid; and (D) a solvent. The primer composition can strongly adhere a condensation type room temperature curable silicone elastomer to the surface of the coated metal formed by applying a fluororesin coating, an acrylic resin coating or the like to a metal.Type: GrantFiled: February 15, 1995Date of Patent: January 23, 1996Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Masatoshi Arai, Yoshifumi Inoue, Toshiyuki Ozai
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Patent number: 5475056Abstract: The invention relates to plastisols which prevent a yellowing of top coats applied thereon, to a process for their preparation and to their use. The plastisols based on PVC or methacryl contain, in addition to basic adhesion promoters, aldehydes, ketones, their derivatives, oligomers or mixtures of same.Type: GrantFiled: April 13, 1995Date of Patent: December 12, 1995Assignee: Teroson GmbHInventors: Bernhard Koesters, Xaver Muenz, Manfred Asang
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Patent number: 5468795Abstract: Priming composition containing a homogeneous liquid solution containing a polymeric material and at least one water-miscible solvent in an amount sufficient to provide adhesion between wet or dry road surface materials and adhesive coated articles. The priming composition allows the marking of roadways with pressure sensitive adhesive articles even on wet or damp roadway surfaces. Also a method for priming roadway surfaces.Type: GrantFiled: June 17, 1993Date of Patent: November 21, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventor: Harald Guder
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Patent number: 5427998Abstract: A polycarbonate resin solution for forming a thermal-sublimating dye-receiving layer film, comprising a random copolycarbonate resin dissolved in an organic solvent, the resin having a structural unit represented by following formula (1) and a structural formula represented by following formula (2) or (3), the molar ratio of the structural unit represented by formula (1) to the structural unit represented by formula (2) or (3) being from 35/65 to 65/35, and having a number average molecular weight of from 5,000 to 50,000. ##STR1## wherein R.sup.1 to R.sup.12 each represents a hydrogen atom, a halogen atom, or an alkyl group having from 1 to 4 carbon atoms and in formula (1), A represents a straight chain, branched, or cyclic alkylidene group having from 1 to 10 carbon atoms, an aryl-substituted alkylidene group, an arylene group, or a sulfonyl group.Type: GrantFiled: June 20, 1994Date of Patent: June 27, 1995Assignee: Mitsubishi Gas Chemical Co., Ltd.Inventors: Toshikazu Umemura, Satoshi Kanayama
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Patent number: 5399604Abstract: An epoxy group-containing thermosetting resin composition comprising (A) a copolymer obtained from (a) at least one member selected from an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride, (b) an epoxy group-containing unsaturated compound, (c) a monoolefin unsaturated compound, and optionally (d) a conjugated diolefin unsaturated compound, and (B) an organic solvent for dissolving the above copolymer. There is also provided another epoxy-group containing thermosetting resin composition which contains the above component (A), (C) a polymerizable compound having at least one ethylenically unsaturated double bond, and (D) a photopolymerization initiator. These epoxy-group containing thermosetting resin compositions are excellent in storage stability.Type: GrantFiled: July 21, 1993Date of Patent: March 21, 1995Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Kimiyasu Sano, Masayuki Endo, Atsufumi Shimada, Yasuaki Yokoyama, Nobuo Bessho
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Patent number: 5397826Abstract: A coating composition for applying a transparent magnetic recording layer to a support which comprises a polymeric binder, ferromagnetic particles and a dispersing medium for the polymeric binder, the dispersing medium comprising (a) a compound having the formula ##STR1## where R is alkyl having 1 to 8 carbon atoms, phenyl or benzyl;R' is hydrogen, methyl or ethyl; andR" is alkyl having 1 to 5 carbon atoms; and(b) methylene chloride, or lower alkyl ketones or mixtures of methylene chloride and lower alkyl ketones.Type: GrantFiled: December 22, 1993Date of Patent: March 14, 1995Assignee: Eastman Kodak CompanyInventor: Ronald M. Wexler
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Patent number: 5348998Abstract: A coating composition comprising(A) a film-forming binder resin,(B) a volatile organic liquid diluent dissolving the film-forming binder resin (A) and(C) fine particles of a polymer which does not dissolve in a solution of the binder resin (A) in the diluent (B) but are dispersed stably in said solution, andthe fine polymer particles (C) being fine particles of gelled polymer obtained by emulsion polymerization of(a) a polymerizable monomer having at least two radical-polymerizable unsaturated groups in the molecule, and(b) a radical polymerizable unsaturated monomer other than the monomer (a),in the presence of a reactive emulsifier having an allyl group in the molecule.Type: GrantFiled: September 11, 1992Date of Patent: September 20, 1994Assignee: Kansai Paint Co., Ltd.Inventors: Satoru Ito, Takao Matoba, Kenji Yamamoto, Shinji Sugiura
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Patent number: 5342868Abstract: The crystalline synthetic resin composition of the present invention comprises 100 parts by weight of a crystalline synthetic resin compounded with (a) 0.01 to 5 parts by weight of at least one of alkali-metal carboxylates, alkali metal .beta.-diketonates and alkali metal salts of .beta.-ketoacetic esters and (b) 0.01 to 5 parts by weight of at least one of basic polyvalent metal salts of cyclic organophosphoric esters of the following general formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R.sub.2 and R.sub.3 each represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, M represents a group III or IV metal atom of the periodic table, and X represents HO--when M represents a group III metal atom of the periodic table and X represents 0.dbd. or (HO).sub.2 --when M represents a group IV metal atom of the periodic table. The compositions can be used for packaging materials, and coated molded articles.Type: GrantFiled: March 4, 1993Date of Patent: August 30, 1994Assignee: Asahi Denka Kogyo Kabushiki KaishaInventors: Ryoji Kimura, Tetuo Tuboi, Kazunori Nishikawa
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Patent number: 5321054Abstract: Compositions, with controlled and programmed hardening, to record mucodynamic dental impressions, characterized in that they comprise:______________________________________ Polyvinyl acetate (PVAc) 50-85% by weight C.sub.3 to C.sub.6 aliphatic ketones 2-25% by weight C.sub.3 to C.sub.8 aliphatic esters 1-25% by weight C.sub.2 to C.sub.10 aliphatic alcohols 1-25% by weight and/or aliphatic ethers Non-toxic, non-aromatic 0.5-10% by weight plasticizing oils selected from the group consisting of dioctyl adipate, glycerol triacetate and polyglycols Non-toxic and non-extractable 0-2% by weight black, yellow, red or white organic pigments or a combination thereof ______________________________________and is free of any gel-forming components, peroxide-based catalysts, aromatic compounds and incompatible plasticizers.Type: GrantFiled: September 18, 1992Date of Patent: June 14, 1994Inventor: Giovanni Pasini
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Patent number: 5306752Abstract: A cyanoacrylate monomer adhesive formulation which has improved thermal properties resulting from the inclusion in the formulation of an effective amount for enhancing the thermal resistance of the cured polymer of a compound of the formula: ##STR1## where R is C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or C(Ph).sub.2 ; R.sup.a, R.sup.b, R.sup.c and R.sup.d are independently H, monovalent hydrocarbon, halogen or strong electron withdrawing groups; or two of R.sup.a, R.sup.b, R.sup.c and R.sup.d combined form a fused hydrocarbon ring; R.sup.1 is C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or C(Ph).sub.2, or R.sup.1 and R.sup.b combined form a fused ring having a C(CN).sub.2, C(CO.sub.2 R.sup.e).sub.2, C(SO.sub.2 R.sup.e).sub.2 or C(Ph).sub.2 group in conjugation with R; R.sup.e is alkyl and Ph is phenyl orR and R.sup.1 are both O; and R.sup.a, R.sup.b, R.sup.c and R.sup.Type: GrantFiled: October 9, 1992Date of Patent: April 26, 1994Assignee: Loctite CorporationInventor: Shabbir Attarwala
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Patent number: 5290354Abstract: The present invention relates to a method of forming a ceramic or ceramic-like coating on a substrate, especially electronic devices, as well as the substrate coated thereby. The method comprises coating said substrate with a solution comprising a solvent, hydrogen silsesquioxane resin and a modifying ceramic oxide precursor selected from the group consisting of tantalum oxide precursors, niobium oxide precursors, vanadium oxide precursors, phosphorous oxide precursors and boron oxide precursors. The solvent is then evaporated to thereby deposit a preceramic coating on the substrate. The preceramic coating is then ceramified by heating the to a temperature of between about 40.degree. C. and about 1000.degree. C. This coating, moreover, may be covered by additional passivation and barrier coatings.Type: GrantFiled: August 7, 1990Date of Patent: March 1, 1994Assignee: Dow Corning CorporationInventor: Loren A. Haluska