Group Iia Metal (be, Mg, Ca, Sr, Ba) Patents (Class 524/400)
  • Patent number: 6756431
    Abstract: Heterocyclic tin compounds, useful as flame retardants and/or as smoke suppressants for halogen-containing polymers, e.g., polyvinyl chloride resins having application as wire and cable coatings, are obtained by reacting a trisubstituted triazine such as melamine with a tin-containing compound such as tin tetrachloride.
    Type: Grant
    Filed: April 9, 2002
    Date of Patent: June 29, 2004
    Assignee: Crompton Corporation
    Inventors: Mukund Shah, Michael H. Fisch, Ulrich Stewen, Radu Bacaloglu
  • Patent number: 6756444
    Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: June 29, 2004
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft
  • Patent number: 6756116
    Abstract: The method of this invention for raising the stick temperature of pellets of ethylene-based copolymers with an acid content at least 5 weight percent has the steps of contacting the pellets with an aqueous solution of a water-soluble metal salt of an aliphatic acid having fewer than 12 carbon atoms, and drying the pellets. The resulting ethylene-based copolymers have a stick temperature of above 25° C. and preferably at least 5° C. above that of the untreated pellets.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: June 29, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Brian Thomas Roach
  • Patent number: 6753359
    Abstract: The present invention involves the use of powder coating methods to form coated abrasives. In one embodiment, the powder is in the form of a multiplicity of binder precursor particles comprising a radiation curable component. In other embodiments, the powder comprises at least one metal salt of a fatty acid and optionally an organic component that may be a thermoplastic macromolecule, a radiation curable component, and/or a thermally curable macromolecule. In either embodiment, the powder exists as a solid under the desired dry coating conditions, but is easily melted at relatively low temperatures and then solidified also at reasonably low processing temperatures. The principles of the present invention can be applied to form make coats, size coats, and/or supersize coats, as desired.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: June 22, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Ernest L. Thurber, Eric G. Larson, Gregg D. Dahlke, Robert J. DeVoe, Alan R. Kirk, Mark R. Meierotto, Roy Stubbs
  • Patent number: 6753370
    Abstract: A resin composition comprises a copolymer (A) comprising ethylene as a major component produced with a single-site catalyst, and an ethylene-vinyl alcohol copolymer (B) having an ethylene content of 20-60 mol. % and a degree of hydrolysis of 95% or above, the resin composition satisfying the equation (1): 1/99≦{weight of (A)}/{weight of (B)}≦<99/1  (1) A preferred resin composition comprises a copolymer (A) which has a density of 0.90-0.94 g/cm3 and the resin composition further comprises a carboxylic acid-modified polyolefin (C) and satisfies the equations (2) and (3): 60/40≦{weight of (A)}/{(weight of (B)}≦: 99/1  (2) 0.1/99.9≦X≦: 20/80  (3) wherein X={weight of (C)}/{total weight of (A) and (B)}. Another preferred resin composition comprises a copolymer (A) which has a density of 0.85-0.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: June 22, 2004
    Assignee: Kuraray Co., Ltd.
    Inventors: Shigeki Nakatsukasa, Hiroyuki Ohgi, Kazuyori Yoshimi
  • Patent number: 6750280
    Abstract: A thermosetting composition consists essentially of a mixture of (A) a polymer containing acid anhydride groups, (B) a molecular sieve being partially loaded with at least one amine, and (C) a filler capable of releasing water upon heating at a temperature above the processing temperature of the mixture of (A), (B) and (C). The processing temperature is chosen so as to be below the desorption temperature of the amine from the molecular sieve. The composition is particularly useful in making hot melt adhesives and sheetings of electric cables.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: June 15, 2004
    Assignee: Atofina
    Inventors: Thomas Abend, Jean-Michel Pierrot, Patrice Robert
  • Patent number: 6747077
    Abstract: A composition containing polypropylene prepared by polymerization over a metallocene catalyst or a polypropylene copolymer prepared by polymerization over a metallocene catalyst, and a stabilizer mixture comprising (A) for example the compound of the formula (A-I-1-a)  wherein n1 is a number from 2 to 20; and (B) for example the compound of the formula (B-I-2-a);
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: June 8, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: François Gugumus, Nicola Lelli
  • Patent number: 6740698
    Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: May 25, 2004
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
  • Patent number: 6737451
    Abstract: A magnetic compound is formed comprising: (1) 25% to 50% by volume of polyphenylene sulfide (PPS); (2) 50% to 70% by volume of coated samarium cobalt (the coating comprising 1 to 30% Kaolin by weight of the coating and 70 to 99% potassium silicate by volume of the coating); and (3) 0% to 5% by volume of an internal lubricant. The PPS polymer component of the compound renders the compound amenable to be injection molded to precise tolerances and also has a low coefficient of linear thermal expansion. The samarium cobalt constituent of the compound provides thermal stability. The potassium silicate/kaolin coating separates the PPS from the samarium cobalt, thus preventing degradation (i.e, PPS viscosity reduction) during manufacture.
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: May 18, 2004
    Assignee: Arnold Engineering Co., Ltd.
    Inventors: James Carlberg, Paul R. Nastas
  • Publication number: 20040086722
    Abstract: A hydrophilic coating having a covalently cross-linked hydrophilic polymer suitable for coating medical devices or instruments for introduction into human cavities, the coating further having a water soluble compound, the water soluble compound being glucose, sorbitol a halide, nitrate, acetate, citrate or benzoate of an alkali metal or alkaline earth metal or silver; acetic acid, glycine or urea. A medical device or instrument for introduction into human cavities having a hydrophilic coating and a method of producing such a medical device or instrument.
    Type: Application
    Filed: January 24, 2003
    Publication date: May 6, 2004
    Applicant: Coloplast A/S
    Inventor: Niels Joergen Madsen
  • Patent number: 6699923
    Abstract: A flame-retardant polyacetal resin composition comprising 60 to 90% by weight of a polyacetal resin, 1 to 30% by weight of red phosphorus, 1 to 40% by weight of at least one resin selected from phenol resins and polycarbonate resins, and 0.1 to 5% by weight of a metal salt of a fatty acid. The polyacetal resin composition of the present invention is provided with flame retardancy while maintaining the excellent innate properties of polyacetal resins, so that it can be applied to the fields where the use of polyacetal resins has been restricted.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: March 2, 2004
    Assignee: Asahi Kasei Kabushiki Kaisha
    Inventors: Yukio Tanigawa, Hidehiko Yamatou
  • Publication number: 20040006166
    Abstract: In accordance with the present invention, there are provided novel coupling agents which are compatible with a wide variety of adhesive formulations and which provide substantial adhesion enhancement relative to base formulations to which they are added. Invention compounds comprise at least one free-radically polymerizable group (other than acrylate) and at least one reactive moiety which forms covalent bond(s) with substrates having free hydroxyl groups on the surface thereof. Thus, invention compounds are covalently linked to adhesive formulations upon free radical cure, while at the same time providing “residual” functionality which is capable of undergoing reaction with any substrate having reactive (e.g., hydroxyl) groups in the surface thereof.
    Type: Application
    Filed: July 3, 2002
    Publication date: January 8, 2004
    Applicant: Henkel Loctite Corporation
    Inventors: Puwei Liu, Stephen M. Dershem, Benjamin Neff, Maria Villegas
  • Publication number: 20030229169
    Abstract: A polypropylene resin composition for automobile door trims having superior impact resistance, rigidity and scratch resistance, and more particularly, to a partially-crosslinked polypropylene resin composition prepared by adding highly-crystalline polypropylene, partially-crosslinked polypropylene, polyethylene, optionally an ethylene copolymer rubber, and an inorganic filler.
    Type: Application
    Filed: December 31, 2002
    Publication date: December 11, 2003
    Inventors: Kyung Sik Han, Seung Wook Hwang, Byung Soon Park
  • Patent number: 6660787
    Abstract: A transparent, fire resistant branched polycarbonate-polysiloxane composition comprises polycarbonate, a short-chained polydiorganosiloxane, a branching agent, and flame retardants essentially free of bromine or chlorine, wherein the amount of short-chained polydiorganosiloxane is about 1 wt. % or less.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: December 9, 2003
    Assignee: General Electric Company
    Inventors: James Alan Mahood, Niles Richard Roscnquist, Rajendra Kashinath Singh
  • Patent number: 6653382
    Abstract: Thermoplastics with high resilience (high coefficient of restitution) and softness (low Atti compressions) and their use in golf ball components. Melt-processible, highly-neutralized ethylene acid copolymers and process for making them by incorporating an aliphatic, mono-functional organic acid in the acid copolymer and then neutralizing greater than 90% of all the acid groups present.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: November 25, 2003
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert Joseph Statz, John Chu Chen
  • Patent number: 6653381
    Abstract: Novel compounds derived from traditional semi- drying and non-drying oils featuring internally plasticizing and crosslinkable properties are disclosed and claimed. Preferred embodiments include acrylate or methacrylate esters of hydroxy long-chain olefinic compounds derived from castor oil or lesquerella oil. A process for the preparation of the novel compounds is also disclosed, which involves esterification reaction of ethylenically unsaturated carboxylic acids or its derivatives with substituted hydroxy long-chain olefinic compounds. These compounds are suitable for forming latices, which form films at low minimum film forming temperatures (MFT) ranging from −5 to 10 ° C. and cure to above ambient glass transition (Tg polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These latices are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: November 25, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Rajan Hariharan, Zhiyu Wang
  • Patent number: 6642292
    Abstract: A resin composition for a sliding member, comprises from 0.1 to less than 1.0% by weight of a fatty acid, 0.1 to 2.0% by weight of a metallic soap, 0.1 to 2.0% by weight of a phosphate, 0.3 to 2.0% by weight of a lubricating oil, and a polyester-based elastomer as the balance. A sliding member produced from such resin composition exhibits excellent friction and wear characteristics even at a low sliding speed under a high load.
    Type: Grant
    Filed: July 18, 2001
    Date of Patent: November 4, 2003
    Assignee: Oiles Corporation
    Inventor: Kazuo Hirai
  • Patent number: 6632917
    Abstract: A preblended additive composition and process for the preparation of polyester resins useful in the manufacture of plastic containers such as bottles is disclosed. The additive composition includes a cobalt-containing compound that is preblended with a phosphorous compound. The polyester resin, e.g., a PET resin, may be prepared by reacting ethylene glycol with dimethyl terephthalate (DMT) or terephthalic acid (TA) in an esterification reaction. The additive composition may be prepared by quickly dumping the phosphorus compound into the cobalt compound such as cobalt acetate, and the resulting composition is added to the reactor vessel before the polycondensation reaction. On the other hand, the additive composition may be prepared by slowly dumping the phosphorus compound into the cobalt compound over a period of at least 5 minutes. Such preblending substantially eliminates any yellow or blue color, or haze in the product article.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: October 14, 2003
    Assignee: Arteva North America S.A.R.L.
    Inventors: Rehka V. Kulkarni, Ligia Dominguez
  • Patent number: 6624223
    Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: September 23, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Zhiyu Wang, Elizabeth H. Brister, Rajan Hariharan, Corey L. King, Kamlesh Gopichand Panjnani
  • Patent number: 6624221
    Abstract: A resin composition comprising, in admixture, (A) a specific thermoplastic resin component, (B) at least one wax component selected from among (b-1) a fatty acid having 20-80 carbon atoms and/or a derivative thereof and (b-2) an oxidized natural wax and/or derivative having a neutralization value of 60-190 mg KOH/g, and optionally, (C) a basic inorganic metal compound capable of neutralizing acid groups in the thermoplastic resin component (A) and/or the wax component (B) is improved in flow, moldability and heat resistance and thus suitable to form a layer of a golf ball which exhibits improved rebound and distance properties.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: September 23, 2003
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Rinya Takesue, Yasushi Ichikawa
  • Publication number: 20030166753
    Abstract: A carbon monoxide modified ethylene-vinyl acetate copolymer composition is disclosed, having diminished tendency to cause discoloration on heating at 177° C. of a plastic composition whose major polymeric component is polyvinyl chloride, comprising carbon monoxide modified ethylene-vinyl acetate copolymer and an amount, effective in diminishing discoloration, of at least one inorganic perchlorate salt selected from the group consisting of alkali metal perchlorates and alkaline earth metal perchlorates.
    Type: Application
    Filed: January 14, 2002
    Publication date: September 4, 2003
    Applicant: CROMPTON CORPORATION
    Inventors: Kook Jin Bae, Stuart D. Brilliant, Johannes Kaufhold
  • Patent number: 6613723
    Abstract: The present invention provides a process for preparing an overbased barium complex and an overbased barium complex prepared thereby. The process includes the steps of: heating a mixture of barium hydroxide monohydrate and an isomeric mixture of from about C10 to about C15 alcohols in the presence of a solvent, thereby producing a first mixture; contacting the first mixture and an isomeric mixture of from about C8 to about C10 branched carboxylic acids, thereby producing a second mixture which includes unreacted barium hydroxide; and contacting the second mixture and carbon dioxide, thereby producing the overbased barium complex. The overbased barium complex of the present invention is useful in the stabilization of halogen-containing polymers.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: September 2, 2003
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Philippe Buess, Cyriel Eddy Hendrickx, Bernard Francois Leroy
  • Publication number: 20030153661
    Abstract: An aluminum hydroxide composition is disclosed, having diminished tendency to cause discoloration on heating at 177° C. of a plastic composition whose major polymeric component is polyvinyl chloride, comprising aluminum hydroxide and an amount, effective in diminishing discoloration, of at least one inorganic perchlorate salt selected from the group consisting of alkali metal perchlorates and alkaline earth metal perchlorates.
    Type: Application
    Filed: January 4, 2002
    Publication date: August 14, 2003
    Applicant: CROMPTON CORPORATION
    Inventors: Kook Jin Bae, Stuart D. Brilliant
  • Patent number: 6602939
    Abstract: A thermoplastic molding composition suitable for preparing molded articles having improved mechanical properties is disclosed. The composition contains A) a (co)polymer of at least one monomer selected from the group consisting of styrene, &agr;-methylstyrene, nuclear-substituted styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride and N-substituted maleimide , and B) a graft polymer of B.1) at least one member selected from the group consisting of styrene, &agr;-methylstyrene, nuclear-substituted styrene, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic anhydride and N-substituted maleimide on B.2) a rubber having a glass transition temperature of ≦10° C. and C) a mixture of at least 3 components selected from I) metallic compounds, II) esters III) amides and IV) certain specified compounds exemplified by oil or wax.
    Type: Grant
    Filed: September 19, 2001
    Date of Patent: August 5, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventor: Herbert Eichenauer
  • Patent number: 6599972
    Abstract: Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: July 29, 2003
    Assignee: University of Southern Mississippi
    Inventors: Shelby Freland Thames, Kamlesh Gopichand Panjnani, Olan Stanley Fruchey
  • Patent number: 6599446
    Abstract: Inclusion of relatively small amounts of organic ionic species, such as calcium stearate, in the preparation of an electrically conductive polymer composite composition provides a composition having enhanced electrical properties relative to the composite composition lacking the added organic ionic species. As a result of this enhancement, normally insulating materials which rely upon a conductive filler to render them electrically conductive, can be made to achieve a given level of conductivity using less of the conductive filler than would otherwise be required. As a result, the adverse effects of the conductive filler on the polymer's physical properties can be minimized while maintaining a high level of electrical conductivity.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: July 29, 2003
    Assignee: General Electric Company
    Inventors: Michael Leslie Todt, David Ernest Rodrigues, Sai-Pei Ting
  • Patent number: 6586103
    Abstract: This invention has its object to provide an interlayer film for laminated glass an interlayer film for laminated glass which, when assembled into laminated glass, offers good transparency, weathering resistance, adhesion, penetration resistance and other characteristics, does not cause marginal whitening of laminated glass even exposed to a highly humid atmosphere, and free from the risk for a fire hazard in autoclaving or the problem associated with edge trimming and a laminate glass comprising said interlayer film. This invention is related to an interlayer film for laminated glass comprising a plasticized poly(vinyl acetal) resin film, wherein, when a laminated glass fabricated by interposing said interlayer film between a pair of glass sheets each 2.0 to 4.0 mm thick is allowed to sit in an environment of 80° C. and 95% relative humidity for 2 weeks, the distance of whitening from its edge is not greater than 7 mm, and when said interlayer film for laminated glass is allowed to sit at 150° C.
    Type: Grant
    Filed: March 22, 2002
    Date of Patent: July 1, 2003
    Assignee: Sekisui Chemical Co., Ltd.
    Inventors: Hajime Shohi, Tsuyoshi Hattori, Jiro Miyai
  • Patent number: 6586513
    Abstract: It is an object of the invention to provide an aqueous dispersion for electrodeposition which has excellent shelf life and can form thin, high dielectric constant films, as well as a high dielectric constant film formed from the aqueous dispersion and electronic parts provided with the high dielectric constant film. The aqueous dispersion for electrodeposition according to the invention is characterized in that organic particles with a mean particle size of no greater than 1 &mgr;m and a dielectric constant of at least 30 (titanium dioxide particles and the like) and organic particles composed of either or both a polymerizable compound and a polymer (polyimide-based resin and the like) are dispersed in an aqueous medium, allowing storage for a period of 7 days or longer at 20° C.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: July 1, 2003
    Assignee: JSR Corporation
    Inventors: Hirofumi Goto, Nobuyuki Ito
  • Patent number: 6583206
    Abstract: Compounds of and compositions comprising specific salts of saturated [2.2.2] dicarboxylate in order to provide highly desirable properties within thermoplastic (e.g., polyolefin) articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such thermoplastics, are easy to produce and handle, and relatively inexpensive to manufacture. Such compounds induce high peak crystallization and improved stiffness within thermoplastics. Also, thermoplastic compositions comprising such novel nucleating agents exhibit improved heat distortion properties and clarity levels in comparison with the closest unsaturated salt nucleating agents. Thermoplastic additive compositions and methods of producing thermoplastics with such compounds are also contemplated within this invention.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: June 24, 2003
    Assignee: Milliken & Company
    Inventor: Xiaodong Edward Zhao
  • Publication number: 20030100647
    Abstract: A halogen scavenging system is provided for inhibiting the corrosion-causing tendency and coloration of halogen-containing olefin polymers or copolymers, comprising incorporating about 0.01% to about 1% of a hydroltalcite-like solid solution having the formula Al2(Mg)a(OH)b(CO3)c(G)d.eH2O and a crystallite size in the <003> direction of about 190 Å to about 225 Å, and having bidentate coordination for carbonate ion as shown by an infrared spectrum, and wherein 3≦a≦5.5; 8≦b≦14; 1.2≦c≦3; 0≦d≦1; 1≦e≦10 and G is a surface active agent into the halogen containing olefin polymer.
    Type: Application
    Filed: September 21, 2001
    Publication date: May 29, 2003
    Inventors: Jawahar C. Parekh, Rajanikant D. Desai
  • Patent number: 6565935
    Abstract: A structure comprising a filled thermosetting polymer composition. The filled thermosetting polymer composition has a mineral filler content of at least 92% by weight and not more than 8% by weight of thermosetting polymer and a co-efficient of thermal expansion that is less than 15×10−6 in/in/° C. The filler is a mineral particulate filler with generally rounded edges and the thermosetting polymer composition has a density that is at least 95% of the theoretical density for the filler and polymer. Embodiments of the composition per se may be used to form a structure for resisting acid solutions.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: May 20, 2003
    Assignee: Cappar Limited
    Inventor: Steve Lohnes
  • Patent number: 6559201
    Abstract: The antifouling composition of the present invention includes a glassy matrix formed by crosslinking a mixture of a silanol-terminated silicone and an alkoxy functionalized siloxane to provide an interpenetrating polymer network of glass and silicone and at least two materials capable of microphase separation, at least one of which is graftable to the glassy matrix.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: May 6, 2003
    Assignee: Microphase Coatings, Inc.
    Inventor: William H. Simendinger, III
  • Patent number: 6545071
    Abstract: A stabilizer mixture containing A) for example at least one compound of the formula (I)  wherein the radicals R1, independently of one another, are hydrogen, C1-C8alkyl, —O, —CH2CN, C3-C6alkenyl, C7-C9phenylalkyl, C7-C9phenylalkyl which is substituted on the phenyl radical by C1-C4alkyl; or C1-C8acyl; and B) magnesium oxide, magnesium hydroxide, zinc oxide, zinc hydroxide or an organic salt of zinc or magnesium, or a hydrotalcite; and C) either (C1) an UV absorber or (C2) a pigment or (C3) an UV absorber and a pigment. Such a stabilizer mixture is particularly useful for stabilizing a polyolefin against light-induced degradation.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: April 8, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: François Gugumus
  • Patent number: 6534576
    Abstract: A flame retardant organic resin composition comprising (A) 100 parts by weight of an aromatic ring-containing organic resin and (B) 0.01-50 parts by weight of a branched organopolysiloxane described by average molecular formula (R13SiO1/2)a(R2SiO3/2)b(SiO4/2)c(R3O1/2)d(HO1/2)e, where each R1 is independently selected from alkyl groups comprising 1 to 12 carbon atoms and alkenyl groups comprising 2 to 12 carbon atoms; each R2 is independently selected from alkyl groups comprising 1 to 12 carbon atoms, alkenyl groups comprising 2 to 12 carbon atoms, and aryl groups comprising 6 to 12 carbon atoms, where the aryl groups of R2 are at least 30 mol % based on total monovalent hydrocarbon in R1 and R2, R3 represents an alkyl group, subscripts a and b are positive numbers, and subscripts c, d, and e are 0 or positive numbers.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: March 18, 2003
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Koji Nakanishi, Hidekatsu Hatanaka, Haruhiko Furukawa, Koji Shiromoto, Hiroshi Ueki, Yoshitsugu Morita
  • Patent number: 6525158
    Abstract: Recycled mixtures of plastics, predominantly thermoplastics, as predominantly produced in the household, in commerce and also in industry and useful material collections, can be stabilized against thermooxidative degradation by adding a combination of a sterically hindered phenol with an organic phosphite or phosphonite and an inorganic compound from the series consisting of metal oxides, hydroxides and carbonates.
    Type: Grant
    Filed: September 17, 1997
    Date of Patent: February 25, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Kurt Hoffmann, Heinz Herbst, Rudolf Pfaendner, Hans-Jürgen Sander, Franciszek Sitek
  • Patent number: 6518344
    Abstract: The present invention provides a new and improved flame retarded polyolefin composition that displays good retained physical properties upon aging. The composition also exhibits excellent moldability and it may be easily colored. In a preferred embodiment the composition includes a polyolefin, a halogen-containing flame retardant additive, from at least about 1.00% by weight to about 2.5% by weight of a stabilizer package, and from about 0% to about 1.0% by weight of an acid/halogen scavenger. The stabilizer package includes by weight from about 20% to about 80% of a hindered phenolic antioxidant, from about 20% to about 80% of a phosphite containing antioxidant, and from about 0% to about 40% of a thio-ester antioxidant. In addition to displaying excellent color and physical property development and retention characteristics, the composition of the present invention displays an improved UL94 vertical burn rating.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: February 11, 2003
    Assignee: Ferro Corporation
    Inventors: Deenadayalu Chundury, Ann Mendel, Howard E. Munro, Roy C. Sanford
  • Patent number: 6514606
    Abstract: A pressure-sensitive adhesive sheet for skin adhesion in which an adhesive force of the pressure-sensitive adhesive on the backing film does not lower greatly even with the lapse of long term and the initial adhesive force is substantially maintained, and a first-aid adhesive plaster using the same are disclosed. The pressure-sensitive adhesive sheet for skin adhesion comprises a backing film and a pressure-sensitive adhesive layer for skin adhesion formed on one side of the backing film, wherein the backing film comprises about 40 to about 70 parts by weight of a polyester plasticizer having a number average molecular weight of about 1,500 to about 3,000, an appropriate amount of a stabilizer comprising at least one metallic soap selected from the group consisting of fatty acid calcium, fatty acid zinc and fatty acid barium, and about 0.1 to about 1.0 part by weight of hydrotalcite per 100 parts by weight of a vinyl chloride polymer.
    Type: Grant
    Filed: September 13, 1999
    Date of Patent: February 4, 2003
    Assignee: Nitto Denko Corporation
    Inventors: Takashi Kinoshita, Yasuyuki Sasaki, Masayoshi Kuniya
  • Publication number: 20030004242
    Abstract: Compounds of and compositions comprising specific salts of saturated [2.2.2] dicarboxylate in order to provide highly desirable properties within thermoplastic (e.g., polyolefin) articles are provided. The inventive salts and derivatives thereof are useful as nucleating and/or clarifying agents for such thermoplastics, are easy to produce and handle, and relatively inexpensive to manufacture. Such compounds induce high peak crystallization and improved stiffness within thermoplastics. Also, thermoplastic compositions comprising such novel nucleating agents exhibit improved heat distortion properties and clarity levels in comparison with the closest unsaturated salt nucleating agents. Thermoplastic additive compositions and methods of producing thermoplastics with such compounds are also contemplated within this invention.
    Type: Application
    Filed: June 5, 2001
    Publication date: January 2, 2003
    Inventor: Xiaodong Edward Zhao
  • Patent number: 6500888
    Abstract: This invention is directed to ethylene based copolymer pellets having an acid content at least 5% by weight and having an effective amount of a surface coating to increase the stick temperature of the copolymer above 25° C.; wherein the ethylene based copolymer comprises repeating polymerized units of (d) at least 50% by weight, based on the weight of the copolymer, of ethylene, (e) 5 to 30% by weight, based on the weight of the copolymer, of acrylic acid or methacrylic acid; and (f) up to 40% by weight, based on the weight of the copolymer, of an alkyl acrylate or an alkyl methacrylate, wherein the copolymer has 0-100% of the acid groups neutralized with metal ion selected from the following group: zinc, magnesium, sodium and lithium and the surface coating comprises an effective amount of a metal salt of an aliphatic acid having 12 to 22 carbon atoms, generally in an amount of 25 to 6,000 ppm (parts per million).
    Type: Grant
    Filed: December 27, 2000
    Date of Patent: December 31, 2002
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Steven G. Baumgartner, Bruce M. Hasch
  • Patent number: 6492448
    Abstract: A resin composition is provided which composition comprises 100 parts by weight of (A) polyarylene sulfide, and 0.01 to 5.0 parts by weight of (B) a product compound of an element selected from the group consisting of group IIA and group IIB of the periodic table, wherein said product compound has such alkalinity that a mixture of said product compound with a 20-fold weight of ultrapure water of grade A4 specified in the Japanese Industrial Standards (JIS) K0557 has a pH of from 10.0 to 12.0. The composition is particularly suited to be used for an optical instrument part such as an object lens driving unit and the like.
    Type: Grant
    Filed: July 11, 2000
    Date of Patent: December 10, 2002
    Assignee: Dainippon Ink and Chemicals, Incorporated
    Inventors: Masaru Miyoshi, Osamu Komiyama
  • Patent number: 6482887
    Abstract: The invention concerns a compound containing calcium or magnesium acetylacetonate, at least partially coated with a compatible agent selected among alcohol's, carboxylic or sulphonic acids, or their derivatives, phosphates or titanates, &bgr;-ketone compounds; said agents having at least a long chain radical; waxes; polyols; epoxidized vegetable oils; polysiloxane oils or resins or silanes. The invention also concerns the preparation of such a compound and the use of said compound as additive in formulations based on halogenated polymers.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: November 19, 2002
    Assignee: Rhodia Chimie
    Inventors: Michel Gay, Francoise Henrio
  • Publication number: 20020136906
    Abstract: This invention has its object to provide an interlayer film for laminated glass an interlayer film for laminated glass which, when assembled into laminated glass, offers good transparency, weathering resistance, adhesion, penetration resistance and other characteristics, does not cause marginal whitening of laminated glass even exposed to a highly humid atmosphere, and free from the risk for a fire hazard in autoclaving or the problem associated with edge trimming and a laminate glass comprising said interlayer film.
    Type: Application
    Filed: March 22, 2002
    Publication date: September 26, 2002
    Applicant: SEKISUI CHEMICAL CO., LTD.
    Inventors: Hajime Schohi, Tsuyoshi Hattori, Jiro Miyai
  • Patent number: 6455612
    Abstract: This invention provides an apparatus and method for injecting an additive directly into a polymer melt stream. The method comprises supplying a melt flow of a polymeric host material to a die assembly having a thin-plate assembly and injecting at least one additive into at least one predetermined location in a cross-section of the melt flow of the polymeric host material while the melt flow passes through the die assembly. The method achieves uniform dosing of the one or more additives in the extrusion direction in the polymeric host material without homogeneously mixing the one or more additives and the polymeric host material. The apparatus for directly injecting one or more additives into a polymer melt stream comprises a pumping system, a die assembly having a thin-plate assembly, and a distribution line.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: September 24, 2002
    Assignee: BASF Corporation
    Inventors: Charles F. Helms, Jr., Dominick A. Burlone, James L. Huff, Thomas Kessler, Herman Brandt, Walter Gotz, Jürgen Hofmann
  • Patent number: 6437030
    Abstract: A process for forming a thermoplastic vulcanizate compromising the steps of dynamically vulcanizing a rubber within a blend that comprises the rubber and a thermoplastic polymer, where said step of vulcanizing is carried out by using a phenolic resin in the presence of a catalyst system formed by combining a metal halide and a metal carboxylate. Also, a thermoplastic vulcanizate having low moisture pick-up with a technologically useful cure.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: August 20, 2002
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Aubert Coran, Sabet Abdou-Sabet
  • Patent number: 6433053
    Abstract: The present invention relates to compositions which modify the surface adhesion properties of a surface such as, tableware, cutting boards and food preparation areas generally.
    Type: Grant
    Filed: May 14, 2001
    Date of Patent: August 13, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Chandrika Kasturi, Keith Homer Baker, William Michael Scheper, Peter Yau-Tak Lin, Magda El-Nokaly
  • Patent number: 6432552
    Abstract: A saponified ethylene-vinyl acetate copolymer is characterized in that, in the relationship between the heating time and the extrusion rate as measured with a Koka flow tester at at least one temperature higher by 10-80° C. than the melting point thereof, it shows an extrusion rate at any time within the period of 15 minutes to 2 hours of heating which is 0.1-50 times the extrusion rate at 15 minutes of heating and an extrusion rate at any time within the period of 2-10 hours of heating which is less than 2 times the extrusion rate at 15 minutes of heating and that, in the relationship between the heating time and the torque at at least one temperature higher by 30-60° C. than the melting point, it shows, at any time within the range of 1-2 hours of heating, a toruque value within the range of ⅙ to ⅚ of the maximum torque value found within the initial 20 minutes of heating.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: August 13, 2002
    Assignee: Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha
    Inventor: Hideshi Onishi
  • Patent number: 6429246
    Abstract: A nonflammable, halogen-free mixture for making thermoplastic polymer materials with increased heat resistance, particularly for manufacturing electrical and optical cables and lines. The mixture comprises: a block or randon block copolymer of polypropylene; a salt of a metal selected from the group consisting of Group II, IIa and IIb metals; a metal hydroxide; a silicone material-selected from the group silicone oil, silicone rubber, and combinations thereof.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: August 6, 2002
    Assignee: Alcatel
    Inventor: Friedemann Rous
  • Patent number: 6423776
    Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life, packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: July 23, 2002
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
  • Publication number: 20020091188
    Abstract: A thermoplastic composition of (a) an acid copolymer, (b) a salt of a high molecular weight, monomeric organic acid; (c) a thermoplastic polymer selected from copolyetheresters, elastomeric polyolefins, styrene diene block copolymers, elastomeric polyolefins thermoplastic polyurethanes and copolyetheramides; (d) cation source; and (d) optionally a filler. Also included is use of such compositions in components of one-, two- and three-piece golf balls or multi-layered golf balls made therefrom.
    Type: Application
    Filed: September 22, 2001
    Publication date: July 11, 2002
    Inventors: Robert Joseph Statz, John C. Chen, John Francis Hagman
  • Patent number: 6403229
    Abstract: Laminate structures, for example for use in circuit boards, comprise a metal foil and at least one cured composition layer disposed on at least one surface of the metal foil, wherein the cured composition layer comprises (a) at least one compound selected from the group consisting of cyanate esters and cyanate ester prepolymers, (b) a flame retardant which is substantially toluene soluble and substantially free of hydroxy residues in the cured state, and (c) a curing catalyst.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: June 11, 2002
    Assignee: General Electric Company
    Inventors: Gary William Yeager, Yiqun Pan