Group Vib Metal Atom Dnrm (i.e., Cr, Mo, W) Patents (Class 524/406)
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Patent number: 5055511Abstract: Permanently flexible and non-tacky coating mastic and caulking compositions having improved heat-age stability contain (a) at least one polymer having a T.sub.g of about -50.degree. C. to about -10.degree. C. and pendant functional groups attached to the polymer backbone and having the formula: ##STR1## in which R.sub.1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano; (b) a zinc-containing pigment (e.g. zinc oxide); and (c) a polyphosphate anion in an amount effective for increasing the wet adhesion of the compositions, particularly of aged compositions. The mastics and caulks typically have total non-volatile matter concentrations of about 60 to about 90 weight percent of which about 15 to about 75 weight percent comprises the described polymer and about 25 to about 85 weight percent is the zinc-containing pigment and other non-volatile solid matter other than the polymer such as fillers, other pigments, etc.Type: GrantFiled: April 29, 1988Date of Patent: October 8, 1991Assignee: Union Oil Company of CaliforniaInventor: David M. Ingle
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Patent number: 5049606Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound and a diamine compound, and a solid lubricant. The composition has low coefficient of friction and excellent wear resistance, and can be utilized for self-lubricating parts.Type: GrantFiled: February 27, 1990Date of Patent: September 17, 1991Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
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Patent number: 5043373Abstract: A high-gloss, corrosion-resistant coating which can be applied directly to surface comprising about 30 to 82 percent by weight of a polymeric binder and 18 to 70 percent by weight of a pigment system consisting essentially of zinc molybdate, zinc salt of benzoic acids, and zinc phosphate in specific ratio's. The coating exhibits good adhesion, flexibility, chemical- and weather-resistance.Type: GrantFiled: November 28, 1989Date of Patent: August 27, 1991Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, Donald J. Hirst, Anthony T. Eng, William J. Green
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Patent number: 5035836Abstract: A solid lubricated resistive ink includes solid lubricants which provide self-lubrication of the resistive ink under high vacuum and low moisture conditions. The resistive inks include a polymer-based binder and an electrically conductive solid lubricant which remains electrically conductive and lubricative under low moisture and high vacuum. Effective lubricants include MoSe.sub.2, NbSe.sub.2 graphite intercalated with bromine and graphite intercalated with a metal chloride. The resistive ink may additionally include carbon.Type: GrantFiled: June 19, 1989Date of Patent: July 30, 1991Assignee: Hughes Aircraft CompanyInventors: Michael N. Gardos, Larry C. Lipp, William S. Griffin
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Patent number: 5034430Abstract: Compositions which can be processed to moulded articles which contain as high molecular weight organic material, a thermoplastic or a thermoset plastic or an elastomer and, as coloring component, 0.001 to 3.0% by weight of molybdenum disulfide, based on said high molecular weight organic material, in conjunction with at least one inorganic or organic pigment and/or a polymer-soluble dye and/or a pearlescent pigment.Type: GrantFiled: September 5, 1989Date of Patent: July 23, 1991Assignee: Ciba-Geigy CorporationInventor: Fridolin Babler
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Patent number: 5006588Abstract: A corrosion and crack growth inhibitor and method of making are disclosed, the inhibitor being relatively non-toxic as well as unreactive with elastomeric material so as to form a coating and sealing composition for application to metal surfaces.Type: GrantFiled: June 30, 1989Date of Patent: April 9, 1991Assignee: Lockheed CorporationInventor: Robert N. Miller
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Patent number: 5006580Abstract: An improved self-bonding curable organopolysiloxane composition which contains (A) an organopolysiloxane having at least 2 silicon-bonded alkenyl groups in each molecule, (B) an organopolysiloxane having at least 2 silicone-bonded hydrogen atoms in each molecule, (C) a catalytic quantity of a platinum-type catalyst, (D) a carbonyl complex of a Group VIB element, and (E) a compound containing a silicon-bonded alkoxy group which is selected from the group consisting of silanes or siloxane oligomers. Examples of the carbonyl complex are molybdenum hexacarbonyl, tungsten hexacarbonyl, and chromium hexacarbonyl.Type: GrantFiled: June 5, 1989Date of Patent: April 9, 1991Assignee: Toray Silicone Company, LimitedInventors: Akira Kasuya, Toshio Suzuki
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Patent number: 4988751Abstract: Halogenated vinyl polymer compositions containing molybdenum smoke retardants and organotin compounds having an overall ratio of sulfur to tin of not more than 1.7 gram atoms of sulfur per gram atom of tin, typically from about 0.6 to about 1.7 and preferably from about 0.6 to about 0.9 gram atoms of sulfur per gram atom of tin.Type: GrantFiled: April 28, 1989Date of Patent: January 29, 1991Assignee: Witco CorporationInventors: Scott R. Chambers, Michael R. Croce
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Patent number: 4987175Abstract: Compositions in accordance with the invention comprise a polymer and flake reinforcing material distributed throughout the polymer in an effective amount to structurally reinforce the polymer. Individual flakes of the flake material (a) are less than or equal to 1,000 Angstroms in thickness, (b) have an aspect ratio greater than or equal to 100, and (c) are preferably significantly randomly oriented throughout the polymer. A novel apparatus for shear grinding a platy solid material into such individual flakes comprises a cylindrical shearing drum and a shear grinder received therein. The shearing drum has a longitudinal axis and an internal surface formed about a first predetermined radius of curvature. The cylindrical drum is supported for rotation about its longitudinal axis. The shear grinder has an external surface formed about a second predetermined radius of curvature. The second radius of curvature is slightly less than the first radius of curvature.Type: GrantFiled: November 21, 1988Date of Patent: January 22, 1991Assignee: Battelle Memorial InstituteInventor: Lee R. Bunnell, Sr.
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Patent number: 4966960Abstract: A process and nylon release sheet for manufacturing printed circuit boards from epoxy prepregs is disclosed. In such process layers of the prepregs are separated from one another by a release sheet. The release sheet comprises an aliphatic or aromatic nylon or nylon copolymer which is a condensation product of a dicarboxylic acid and a diamine. The nylon film contains a heat stabilizer and an inorganic particulate antiblock additive, e.g. diatomaceous earth, glass beads, amorphous silica, talc, mica and molybdenum disulphide. The nylon may be toughened by the addition of a phosphorus-containing catalyst or an epoxide.Type: GrantFiled: November 2, 1988Date of Patent: October 30, 1990Assignee: Du Pont Canada Inc.Inventors: Peter A. Sipos, Erica M. Besso
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Patent number: 4965309Abstract: A smoke suppressant additive for plastics capable of reducing the smoke development of the plastic without significantly effecting the appearance or integrity of the plastic, comprising: (i) about 1 to 8 parts zinc present as an inorganic compound, (ii) about 1 to 6 parts by weight magnesium present as an inorganic magnesium compound other than magnesium oxide, (iii) about 0.7 to 7 parts by weight molybdenum present as an inorganic molybdenum compound, and (iv) about 0 to 0.7 parts by weight copper present as an inorganic copper compound; all parts by weight based upon the total amount of the elements zinc, magnesium, molybdenum and copper in the composition.Preferably, the smoke suppressant additive further comprises up to about 80 wt-% based upon the total weight of the composition, diluent.Type: GrantFiled: April 10, 1989Date of Patent: October 23, 1990Assignee: H. B. Fuller CompanyInventor: Vern H. Batdorf
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Patent number: 4965310Abstract: Blends comprising(A.) at least one poly(aryl) ether ketone), and(B.) at least one polyimide having repeating units of the formula ##STR1## wherein R.sup.1 is a substituted or unsubstituted tetravalent radical having benzenoid unsaturation, andR.sup.2 is a substituted or unsubstituted divalent group having aromatic unsaturation which is essentially free of (i) backbone ether oxygen bonded directly to the aromatic ring forming an imide linkage and (ii) amide linkages bonded through carboxyl groups bonded to the aromatic ring forming an imide linkage. The blends exhibit good melt processability and wear resistance greater than the individual blend components.Type: GrantFiled: July 25, 1985Date of Patent: October 23, 1990Assignee: Amoco CorporationInventors: James E. Harris, John P. Gavula
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Patent number: 4962136Abstract: Compositions are disclosed containing an elastomer, particulate polytetrafluoroethytlene and an amount of molybdenum disulfide effective to permit their manufacture. The particulate polytetrafluoroethylene may include amounts from 25 percent by weight to 80 percent by weight, and/or include small amounts of fibrillated polytetrafluoroethylene. Also disclosed are additives for such compositions, and methods for preparing such compositions and additives using polytetrafluoroethylene and molybdenum disulfide, and improved compositions and products.Type: GrantFiled: April 25, 1988Date of Patent: October 9, 1990Assignee: Alphaflex Industries, Inc.Inventor: William E. Peters
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Patent number: 4946884Abstract: Compositions useful in decomposition molding procedures such as destructive foam casting or ceramic or metallic powder sintering are provided by blends of polymers having greater than 50 weight percent propylene carbonate units and polymers having greater than 50 weight percent methyl methacrylate units. Such blends exhibit an unexpectedly even decomposition profile over the range of temperatures at which their constituent polymers each decompose relatively rapidly. The controlled decomposition rate reduces problems in destructive foam casting and ceramic or metallic powder molding caused by sudden release of gases by the foam pattern or the polymer binder. Preferred blends contain 35 to 65 weight percent poly(methyl methacrylate) and 65 to 35 weight percent poly(propylene carbonate), and very even decomposition behavior is exhibited by blends of 35 to 45 weight percent poly(methyl methacrylate) and 65 to 55 weight percent poly(propylene carbonate).Type: GrantFiled: June 12, 1989Date of Patent: August 7, 1990Assignee: Air Products and Chemicals, Inc.Inventors: Jeffrey A. Kuphal, Lloyd M. Robeson, James J. Weber
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Patent number: 4931535Abstract: Acetal polymer and copolymer are prepared by polymerizing formaldehyde or its cyclic oligomer as a principal monomer, or copolymerizing the principal monomer with a comonomer copolymerizable therewith, using an isopoly acid or an acid salt thereof as a polymerization catalyst.Type: GrantFiled: May 1, 1989Date of Patent: June 5, 1990Assignee: Polyplastics Co., Ltd.Inventors: Kaoru Yamamoto, Toshiaki Kitano, Hiroyuki Sano
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Patent number: 4929507Abstract: A heat-resistant paint comprising a dispersion or solution of a polymetallocarbosilane and an inorganic filler in an organic solvent,wherein said polymetallocarbosilane is an organometallic polymer having a number average molecular weight of 400 to 50,000 comprising(A) carbosilane bond units of the formula ##STR1## wherein R.sub.1 and R.sub.2 may be identical or different and each represents a lower alkyl group, phenyl group or a hydrogen atom, and(B) metalloxane bond units of the formula(M--O)wherein M represents at least one element selected from the group consisting of Ti, Zr, Cr and Mo,wherein said inorganic filler is at least one material selected from the group consisting of oxides, borates, phosphates, silicates, silicides, borides, nitrides and carbides; andwherein said inorganic filler is present in an amount of 10 to 900 parts by weight per 100 parts by weight of said polymetallocarbosilane.Type: GrantFiled: March 23, 1988Date of Patent: May 29, 1990Assignee: Ube Industries, Ltd.Inventors: Yoshio Nishihara, Noriyuki Isobe, Satoshi Kotera
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Patent number: 4920167Abstract: Disclosed is dispersion of a polyurethane-urea polymer in a continuous phase. This dispersion contains about 0.1 to about 5 parts by weight of an ionizable, non-volatile salt per 100 parts by weight of polyurethane-urea polymer. Polyurethane-urea coatings made from this dispersion have excellent static dissipative properties.Type: GrantFiled: November 10, 1988Date of Patent: April 24, 1990Assignee: The Dow Chemical CompanyInventors: Sven H. Ruetman, Joginder N. Anand, G. Robert Collins
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Patent number: 4898905Abstract: A sliding material used under a boundary lubricating conditions or mixed lubricating condition, and having improved, wear-resistance, low-friction property, and seizure-resistance, and consisting of (a) 10 to less than 69% of polyimide and/or polyamide-imide, from more than 30 to 68% of graphite, and, 1 to less than 30% of polytetrafluroethylene, MoS.sub.2, Pb, and/or BN, or (b) 20 to 90% of polyimide and/or polyamide-imide, and from 0.5 to 20% clay, mullite, silica, and/or alumina, and at least 5% and balance of graphite.Type: GrantFiled: July 11, 1988Date of Patent: February 6, 1990Assignee: Taiho Kogyo Co., Ltd.Inventors: Shinya Kawakami, Masahara Kikuchi
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Patent number: 4898906Abstract: Compositions based on vinylidene fluoride polymers which have a reduced smoke-generating capacity, comprising an effective amount of a molybdenum derivative, such as the molybdate of calcium, zinc or aluminium, as a smoke reducer.The compositions are very particularly suitable for the manufacture of shaped articles used in building and in aeronautics.Type: GrantFiled: August 28, 1987Date of Patent: February 6, 1990Assignee: Solvay & CieInventor: Etienne Hannecart
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Patent number: 4897439Abstract: A coating composition comprising a major amount of resin and a minor amount of a property-improving additive,said resin being:(A) a fluorocarbon resin selected from the group consisting of (1) perfluoroalkoxy tetrafluoroethylene copolymer resin (PFA), (2) ethylenechlorotrifluoroethylene copolymer resin (E-CTFE), (3) ethylenetetrafluoroethylene copolymer resin (E-TFE), (4) poly(vinylidine fluoride) resin (PVDF), (5) tetrafluoroethylene-hexafluoropropylene copolymer resin (FEP), (6) poly(chlorotrifluoroethylene) resin (CTFE), or a mixture of two or more of said fluorocarbon resins; or(B) a polyether resin selected from the group consisting of (7) polyethersulfone resin (PES), (8) polyether ketone resin (PEK) and (9) polyether ether ketone resin (PEEK) or a mixture of two or more of said polyether resins;said additive being:(C) a poly(phenylene sulfide) (PPS); or(D) an inorganic crystalline ceramic powder and/or fluorocarbon resin when said resin is a polyether of (B) above; or(E) an inorganic material selectedType: GrantFiled: June 30, 1987Date of Patent: January 30, 1990Assignee: Edlon Products, Inc.Inventors: Steven E. Rau, Robert Roberts, Kevin P. Pochopien, Charles W. Paul, Royce A. Butler, Allan J. Mackinlay, Harris L. Morris, Raymond J. Weinert
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Patent number: 4892683Abstract: Flame retardant low smoke PVC-based thermoplastic compositions for use in wire insulation and cable jacketing. The compositions include poly(vinyl chloride), an additional chlorinated resin, tribasic lead sulfate, a molybdenum-containing smoke suppressing material, alumina trihydrate, a brominated aromatic ester plasticizer, at least one additional plasticizer, and at least one lubricant.Type: GrantFiled: May 20, 1988Date of Patent: January 9, 1990Assignee: Gary Chemical CorporationInventor: Homaira Naseem
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Patent number: 4885324Abstract: A coating for metallic or polymeric composite substrates is disclosed which erforms both as a primer and as a topcoat. It comprises a two component aliphatic polyurethane binder, with titanium dioxide, zinc molybdate, zinc phosphate, an organo-zinc salt, and titanium dioxide vesiculated bead pigments in controlled amounts. The coating exhibits good adhesion, corrosion inhibition, flexibility, chemical and weather resistance, and opacity.Type: GrantFiled: March 28, 1989Date of Patent: December 5, 1989Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles R. Hegedus, William J. Green
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Patent number: 4866117Abstract: A deep drawing process, comprising melt-softening a resin sheet obtained from a resin composition comprising:(a) from 15 to 82% by weight of a propylene-series resin,(b) from 15 to 82% by weight of an ethylene-series resin, and(c) from 3 to 50% by weight of carbon black, each based on the total amount of the components (a), (b), and (c), and(d) from 1 to 50 parts by weight, per 100 parts by weight of the total amount of the components (a), (b), and (c), of an inorganic filler,at a temperature not lower than the melting point of the propylene-series resin and molding the softened resin sheet by differential pressure molding or press molding, wherein the resin sheet is molded at a draw ratio of from 2.0 to 3.5.Type: GrantFiled: May 22, 1987Date of Patent: September 12, 1989Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Akihiko Egashira, Takao Yazaki, Tetsuzi Kakizaki, Toshikazu Mizutani
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Patent number: 4845139Abstract: Very good masking of pack diffusion aluminizing on any metal to keep portions from being diffusion coated, is effected by localized coating layers the lowest of which is inert or depletion-reducing masking powder that can have same composition as substrates, mixed with non-contaminating film-former such as acrylic resin. The upper coating layer or layers can be of non-contaminating particles like nickel or Cr.sub.2 O.sub.3 that upon aluminizing or chromizing become coherently held together to form a secure sheath. Such sheath can also be used for holding localized diffusion-coating layer in place. Film-former can be dissolved in volatile solvent, preferably methyl chloroform, in which masking powder or sheath-forming powder is suspended. Chromizing can be performed before aluminizing for greater effects.Type: GrantFiled: February 28, 1984Date of Patent: July 4, 1989Assignee: Alloy Surfaces Company, Inc.Inventor: Alfonso L. Baldi
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Patent number: 4801626Abstract: Mechanical properties, especially tensile and flexural properties and impact strength, of glass fiber reinforced oxymethylene polymer molding compositions can be enhanced by incorporating into the molding composition an effective amount of a prepolymeric amino resin, whereby the glass fiber reinforcing agent and the oxymethylene polymer are coupled. The amino resin can be a condensation product of formaldehyde and melamine, urea, guanidine, guanamine or a substituted guanamine. An acid catalyst is preferably employed to promote the cross-linking of the prepolymeric amino resin.Type: GrantFiled: September 16, 1986Date of Patent: January 31, 1989Assignee: Celanese CorporationInventors: Andrew B. Auerbach, Derrick B. McKie
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Patent number: 4791160Abstract: This invention provides a flame-retardant resin composition comprising:(A) about 100 parts by weight of a base polymer containing about 99 to about 20% by weight of a linear polyethylene and about 1 to about 80% by weight of a polyethylene-.alpha.-olefin copolymer having a melt flow rate (MFR) of about 1 to about 10 and a density of about 0.900 to about 0.850, said linear polyethylene having a MFR and a density both restricted to the range defined by a segment having points a, b, c and d at the corners thereof in the accompanying drawing, FIG. 1, showing the relationship between the MFR (according to ASTM D1238) and the density (according to ASTM D1505) of said linear polyethylene, and(B) about 50 to about 300 parts by weight of a hydrate of metallic oxide.Type: GrantFiled: February 9, 1987Date of Patent: December 13, 1988Assignee: Mitsubishi Cable Industries, Ltd.Inventors: Hiroshi Kato, Kazuhiko Kanemitsuya, Kiyoshi Furukawa
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Patent number: 4786662Abstract: Storage-stabilized compositions based on vinylidene fluoride polymers containing a metal molybdate and, as stabilizer, an effective quantity of alkali metal or alkaline-earth metal carbonate.The compositions are most particularly suitable for the manufacture of shaped objects employed in building and in aeronautics.Type: GrantFiled: December 3, 1987Date of Patent: November 22, 1988Assignee: Solvay & CieInventors: Jean-Marie De Berraly, Anthony Simoens
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Patent number: 4778704Abstract: A flame retardant polyamide is prepared and used to make a flame retardant carpet. The polyamide fiber has incorporated therein 0.01 to 2.9 weight percent zinc, 0.002 to 0.58 weight percent molybdenum, and 0.05 to 1.3 weight percent chlorine, and is made from a masterbatch containing 1 to 20 percent of the polyamide in the extruded fiber.Type: GrantFiled: September 2, 1987Date of Patent: October 18, 1988Assignee: Allied CorporationInventors: Rodney L. Wells, Charles J. Cole
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Patent number: 4749752Abstract: Fluoropolymer alloys made of melt fabricatable extra-high-molecular weight fluorinated ethylene-propylene copolymer (EHMW-FEP) and one or more other polymers. In fluoropolymer alloys made of EHMW-FEP and polytetrafluoroethylene, the weight percentage of the former is 0.1-99.9% and the latter is 99.9-0.1% respectively. The processes for preparing the fluoropolymer alloys are dried powder co-mill or wetted powder co-mill. Using the fluoropolymer alloys of this invention various kinds of articles have been fabricated by melt compression or cold compaction and sintering. These articles show a great improvement in creep property and also a prolonged service life in comparison with those made from ordinary polytetrafluoroethylene.Type: GrantFiled: March 24, 1986Date of Patent: June 7, 1988Assignee: Shanghai Institute of Organic Chemistry Academia SinicaInventors: Duan Youlu, Jin Shanrong, Huang Tingchun, Sun Jin, Yu Xinying
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Patent number: 4748167Abstract: Disclosed herein are ambient temperature-curable compositions of improved pot life comprising epoxy-containing vinyl polymers and oxygen-containing amines. Coating compositions comprising the same cure at ambient temperature to produce films of excellent properties.Type: GrantFiled: August 1, 1984Date of Patent: May 31, 1988Assignee: PPG Industries, Inc.Inventors: Suryya K. Das, Kurt G. Olson, James A. Claar
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Patent number: 4735982Abstract: A thermoplastic-rubber polymer alloy contains a tough, wear resistant low friction thermoplastic such as ultra high molecular weight polyethylene, a cured rubber compound such as nitrile rubber, an a lubricant such as graphite in effective amounts to produce a composition which has good wet and dry friction and wear properties. The ultra high molecular weight polyethylene is typically utilized in a sufficient amount so as to form a continuous phase with the thermoset rubber being present as particles dispersed throughout the polyethylene as a discontinuous phase. The polymer alloy is made by dry blending the thermoplastic compound with ground thermoset rubber whereby the rubber is coated, heating and mixing the composition to above the glass transition temperature of the thermoplastic compound and subsequently cooling under pressure. The alloy can be easily transfer molded because of the lubricating action of the heated, softened plastic.Type: GrantFiled: July 25, 1986Date of Patent: April 5, 1988Assignee: The B. F. Goodrich CompanyInventor: Roy L. Orndorff, Jr.
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Patent number: 4719038Abstract: Corrosive resistant, coated laminate consisting of metal substrate, anti-corrosive layer and paint layer, which is characterized by the fact that the anti-corrosive layer is formed by a composition containing, as essential components, at least one hexa-valent chromium containing chromium compound having a solubility of 20 to 10.sup.-5 and aqueous silica and/or aqueous resin as binder, and as optional component, a water soluble chromium compound having a solubility of more than 20, and the paint layer is free from chromium compound. The laminate is excellent, inter alia, in adhesion of coating and anti-corrosive property. The invention also provides a coated metal plate having excellent corrosion resistance and continuous spot weldability.Type: GrantFiled: May 28, 1986Date of Patent: January 12, 1988Assignee: Nippon Paint Co., Ltd.Inventors: Tamotsu Sobata, Masaaki Takimoto, Yuichi Yoshida
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Patent number: 4711796Abstract: A poly(arylene sulfide) coating composition, method of preparing the composition, and method of coating are disclosed. The composition comprises a finely-divided poly(arylene sulfide) having from about 75 to about 99 mole percent para-polymerized aromatic units and from about 1 to about 25 mole percent ortho- or meta- polymerized aromatic units and, optionally, from about 0.1 to about 2 mole percent trifunctionally-polymerization aromatic units. The coating resin can be prepared in a polymerization reaction medium containing a molar excess of base, with respect to sulfur present, and can be washed with water at at least about 100.degree. C. to lower the curing temperature of the coating composition. The compositions are particularly suited for application in which curing temperatures of 350.degree. C. or lower are desired.Type: GrantFiled: June 30, 1986Date of Patent: December 8, 1987Assignee: Phillips Petroleum CompanyInventors: Michael C. Yu, Roy F. Wright
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Patent number: 4710531Abstract: Self-extinguishing polycarbonates are disclosed, which consist of mixtures of polycarbonates with at least one salt of metals of the I and/or the II A and B Groups of the Periodic Table, and/or ammonium salts of organic carboxylic compounds having the general formula (I) ##STR1## and, as an adjuvant, at least one compound which is a member selected from the group consisting of the following classes of compounds:(i) a halogenated phenyl ether;(ii) a phthalimide or naphthalimide;(iii) an organic sulphone or a derivative thereof;(iv) an inorganic compound selected from the group consisting of halides of alkali metals or of alkaline earth metals, oxides of metals of the Groups IB,VIB,VIIB,IIIA,IVA and VIII of the Periodic Table, of the lanthanide group, carbon black and the residues of the pyrolysis of the organic acid salts of formula (I).Type: GrantFiled: August 19, 1983Date of Patent: December 1, 1987Assignee: Anic, S.p.A.Inventors: Giovanni Dozzi, Giorgio Della Fortuna, Salvatore Cucinella
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Patent number: 4701488Abstract: Combustion-resistant heat-curable compositions comprising:(a) an aminoorganopolysiloxane polymer containing an average of at least one hydrogen atom bonded to nitrogen in at least two of the silicon-bonded primary or secondary aminoorgano groups;(b) the reaction product of an organic polyisocyanate and a compound containing at least one alcoholic, phenolic, silanic or oximyl hydroxyl group or thiol group as a curing agent; and(c) a combustion inhibiting amount of an additive selected from the group consisting of:(i) a chromium compound;(ii) an iridium compound;(iii) a molybdenum compound;(iv) a rhodium compound;(v) a mixture of (I) platinum or a platinum compound and (II) a compound selected from the group consisting of a barium compound, a bismuth compound, a boron compound, a calcium compound, a chromium compound, a cobalt compound, a gallium compound, an iridium compound, a magnesium compound, a manganese compound, a molybdenum compound, a nickel compound, a palladium compound, a rhodium compound, a thoriuType: GrantFiled: March 31, 1986Date of Patent: October 20, 1987Assignee: Union Carbide CorporationInventor: Thomas C. Williams
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Patent number: 4675357Abstract: Disclosed is a near infrared absorbing polymerizate prepared from bis(allyl carbonate) monomer containing the reaction product of tungsten hexachloride and phenolic compounds.Type: GrantFiled: May 29, 1984Date of Patent: June 23, 1987Assignee: PPG Industries, Inc.Inventor: Cletus N. Welch
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Patent number: 4670494Abstract: A flame retardant low smoke PVC-based thermoplastic composition for use in wire insulation and cable jacketing is disclosed. The composition includes poly(vinyl chloride), chlorinated poly(vinyl chloride), molybdenum oxide, alumina trihydrate, and isodecyl diphenyl phosphate as its primary ingredients, and additionally includes at least one heat stabilizer, at least one antioxidant, at least one lubricant, and at least one plasticizer besides the isodecyl diphenyl phosphate. It may also include antimony oxide, fillers, and chlorinated paraffins. The composition has excellent flame retardancy and produces only a relatively small amount of light-colored smoke when burned.Type: GrantFiled: July 30, 1985Date of Patent: June 2, 1987Assignee: Gary Chemical Corp.Inventor: Nicholas J. Semenza, Jr.
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Patent number: 4668719Abstract: This invention provides an insulating protective material effective for protection of electronic and electric devices such as electronics elements. This insulating protective material contains at least one hydrous oxide of a metal which has ion exchange properties together with a fusion bonding component such as low-melting glass, epoxy resin, phenolic resin, silicone resin, etc. and a filler such as fused silica, .beta.-eucryptite, glass fiber, glass beads, etc.Said specific hydrous oxide can be used together with a sulfur-containing organic high molecular weight compound.The hydrous oxides used in protective materials as a sealing material for electronic and electric devices can capture an ionic impurity eluted from the components of the protective material and fix it therein thereby to provide stable electronic materials excellent in performance.Type: GrantFiled: September 23, 1985Date of Patent: May 26, 1987Assignee: Toagosei Chemical Industry Co., Ltd.Inventors: Hideki Kato, Noriyuki Yamamoto, Takahisa Ogasawara, deceased, Masami Asai, deceased
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Patent number: 4666947Abstract: Compositions based on ethylene/vinylacetate copolymers provided with self-extinguishing properties and suitable for the preparation of foamed materials, comprising for 100 parts by weight of the EVA copolymers:from 5 to 10 parts by weight of at least a bromodiphenylether containing at least 3 bromine atoms;from 2 to 4 parts by weight of a metal oxide selected from antimony, bismuth and tungsten oxides; andfrom 0.1 to 1 part by weight of a compound having general formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, equal or different from each other, can by hydrogen, chlorine, bromine, aliphatic hydrocarbon radicals containing from 1 to 6 carbon atoms, cyclohexyl or phenyl radicals, the nitro group or the --CN group.R.sub.5, R.sub.6, equal or different, can be hydrogen, chlorine, bromine, aliphatic hydrocarbon radicals containing from 1 to 3 carbon atoms, or alkoxy radicals containing 1 to 4 carbon atoms or ##STR2## groups, R.sub.7 being an alkyl radical containing from 1 to 3 carbon atoms.Type: GrantFiled: November 13, 1984Date of Patent: May 19, 1987Assignee: Montepolimeri S.p.A.Inventors: Corrado Brichta, Annibale Vezzoli, Pietro Origgi
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Patent number: 4657963Abstract: A heat-resisting coating composition prepared by binding with modified silicone resin added with an aluminium chelate compound, pulverized inorganic material principally including a mixture of powder containing one kind selected from a group consisting of aluminium phosphate, zinc molybdate and calcium carbonate or a mixture of them, cleaving scale-shaped powder principally containing aluminium silicate or magnesium silicate, and metallic zinc powder; reveals excellent rust-preventing performance in a temperature range spreading from a low temperature to a high temperature, as a heat-resisting painting material for use on an exhaust pipe connected with a motor car engine. Upon applying said heat-resisting coating composition onto a metal surface, it is effective for enhancing adhesion to preliminarily form a group of fine protrusions having "turn-rounds" on the metal surface.Type: GrantFiled: August 27, 1985Date of Patent: April 14, 1987Assignees: Honda Giken Kogyo Kabushiki Kaisha, Mie Yushikako Kabushiki Kaisha, Sankei Giken Kogyo Kabushiki KaishaInventors: Tooru Matsumoto, Satoshi Ishikawa, Eiji Nakamura, Tomio Izuoka, Tomoyuki Okada
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Patent number: 4640793Abstract: The instant invention is directed to an admixture, and its use in inhibiting scale and corrosion in aqueous systems, comprising:(a) a water-soluble polymer having a weight average molecular weight of less than 25,000, as determined by low angle laser light scattering, comprising an unsaturated carboxylic acid and an unsaturated sulfonic acid, or their salts, having a ratio of 1:20 to 20:1, and(b) at least one compound selected from the group consisting of water-soluble polycarboxylates, phosphonates, phosphates, polyphosphates, metal salts and sulfonates.The instant invention is also directed to a method of inhibiting the formation of insoluble alluvial, metal oxide and metal hydroxide deposits in an aqueous system, comprising adding to the system at least 0.Type: GrantFiled: May 9, 1985Date of Patent: February 3, 1987Assignee: Calgon CorporationInventors: Leonard J. Persinski, Jerry L. Walker, Bennett P. Boffardi
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Patent number: 4636324Abstract: The present invention provides: a composition for use in preventing the formation of ice comprising (A) organopolysiloxane, (B) alkali metal compound and (C) liquid or solid paraffin; a method for preventing the formation of ice by applying the composition to the surface of an object; and another method for preventing the formation of ice by applying a primer containing a silane coupling agent to the surface of an object and applying the composition to the primer coat formed.Type: GrantFiled: March 18, 1985Date of Patent: January 13, 1987Assignee: Kansai Paint Company, Ltd.Inventors: Heihachi Murase, Kiyoshi Nanishi
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Patent number: 4607073Abstract: Disclosed is a molding reinforced polyamide composition comprising [A] a polyamide selected from a polyamide composed of (a) aromatic dicarboxylic acid component units comprising 60 to 77 mole % of terephthalic acid component units and 23 to 40 mole % of aromatic dicarboxylic acid component units other than terephthalic acid component units and (b) 1,6-diaminohexane units and a polyamide composed of (a) aromatic dicarboxylic acid component units comprising 60 to 100 mole % of terephthalic acid component units and 0 to 40 mole % of aromatic dicarboxylic acid component units other than terephthalic acid component units and (b) units of a linear aliphatic alkylene-diamine component having 7 to 18 carbon atoms, and [B] a filler in an amount of 0.5 to 200 parts by weight per 100 parts by weight of said polyamide.This composition has excellent heat resistance characteristics, mechanical properties, chemical and physical properties and molding characteristics in combination.Type: GrantFiled: February 7, 1985Date of Patent: August 19, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takeshi Sakashita, Hidehiko Hashimoto, Takayuki Nakano
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Patent number: 4596839Abstract: A composition is disclosed containing particulate polytetrafluoroethylene in amounts from 15 percent by weight to 80 percent by weight incorporated in an elastomer with an amount of molybdenum disulfide effective to permit its manufacture and in some cases lend its properties, and methods for preparing such compositions and for using molybdenum disulfide, and fibrillated particulate polytetrafluoroethylene to improve compositions and products are also disclosed.Type: GrantFiled: August 17, 1984Date of Patent: June 24, 1986Inventor: William E. Peters
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Patent number: 4594297Abstract: Apparatus and method for producing electricity from a fuel gas containing hydrogen and/or compounds capable of dissociating into hydrogen ions using a solid electrolyte concentration cell and a catalyst. A novel solid electrolyte membrane is used which comprises an organic polymer-inorganic compound blend prepared by admixing an organic polymer such as poly(vinyl alcohol) with a heteropoly acid or salt thereof such as dodecamolybdophosphoric acid or uranyl orthophosphate in a mutually miscible solvent.Type: GrantFiled: December 29, 1983Date of Patent: June 10, 1986Assignee: UOP Inc.Inventors: Anthony J. Polak, Allyson J. Beuhler
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Patent number: 4578409Abstract: The present invention relates to a novel halogenated silane conforming to the structure ##STR1## where X is a halogen atom, n is an integer of from 1 to 4, p is an integer of from 1 to 9 and m is an integer of from 1 to 5. The silane thus disclosed was found to be particularly suitable as a flame retarding additive for thermoplastic molding compositions.Type: GrantFiled: January 14, 1985Date of Patent: March 25, 1986Assignee: Mobay Chemical CorporationInventors: Sivaram Krishnan, Ulrich R. Grigo, Donald A. Folajtar
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Patent number: 4576985Abstract: A hot-melt adhesive which is particularly suitable for an adherend surface carrying silanol groups. The adhesive contains a compound capable of combining chemically with oxygen in the silanol groups to render the adherend surface hydrophobic.Type: GrantFiled: August 8, 1984Date of Patent: March 18, 1986Assignee: Alps Electric Co., Ltd.Inventor: Yasuichi Ono
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Patent number: 4567229Abstract: Polyphosphazenes containing 20-80 mole percent phenoxy, 20-80 mole percent alkylphenoxy and 2-30 mole percent alkoxy substituents possess low glass transition temperature while still exhibiting good smoke values in standard tests.Type: GrantFiled: December 18, 1984Date of Patent: January 28, 1986Assignee: Ethyl CorporationInventors: F. Alexander Pettigrew, Harold R. Penton
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Patent number: 4559167Abstract: A varistor of metal oxides, predominantly zinc oxide (ZnO), is provided on its lateral surface between two contact faces, with a coating consisting at least partially of an organic polymer. In order to prevent rapid degradation in oxygen-free surroundings, the coating contains at least one oxygen barrier layer or is formed entirely as such a layer, which contains filler particles in an organic matrix material. The filler is here taken from the group comprising the following substances or groups of substances: synthetic mica, natural mica, vermiculite, micaceous iron ore, glass and other non-metallic inorganic substances present in the form of platelets or flakes; metal oxides, active part material in a pulverulent form and other oxygen-releasing inorganic substances. The organic matrix material is selected from the group comprising epoxide resins, alkyd resins, polyurethanes, silicone resins, unsaturated polyester resins and acrylates.Type: GrantFiled: November 29, 1984Date of Patent: December 17, 1985Assignee: BBC Brown, Boveri & Company, LimitedInventors: Elias Julke, Tony Kaiser, Maged A. Osman, Roger Perkins
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Rubber compositions and articles thereof having improved metal adhesion and metal adhesion retention
Patent number: 4551391Abstract: Rubber compositions and metal-reinforced rubber ply members have improved metal adhesion and metal adhesion retention to brass and brass-plated metallic reinforcement. The improvement comprises admixing from about 0.5 to about 10.0 parts per hundred rubber (phr) of nickel molybdate, cobalt molybdate or a mixture thereof with a vulcanizable rubber composition prior to embedding the metallic reinforcement therein and curing. A method for improving the metal adhesion and metal adhesion retention between a vulcanizable rubber and brass or brass-plated metallic reinforcement includes the steps of dispersing from about 0.5 to about 10.0 phr of nickel molybdate, cobalt molybdate or a mixture thereof in a vulcanizable rubber composition prior to curing.Type: GrantFiled: January 20, 1984Date of Patent: November 5, 1985Assignee: The Firestone Tire & Rubber CompanyInventors: Jung W. Kang, James A. Davis