With Halogenated Nonreactant Material Patents (Class 524/411)
  • Patent number: 4401783
    Abstract: Disclosed is a flame retardant thermoplastic elastomeric composition that in the form of an insulation about an electrical conductor is able to meet or exceed the requirements of UL VW-1 Vertical Flame Test and in the form of a jacket about an electrical cable is able to meet or exceed the requirements of IEEE-383 Cable Tray Flame Test while having a limiting oxygen index of only 24 to 27 percent. The composition has an elastomeric component of the type comprising about 25 to about 75 parts by weight of a crystalline olefin resin and about 75 to about 25 parts by weight of a vulcanized monoolefin copolymer rubber comprising a polymer of ethylene or propylene and one other alpha olefin of the formula CH.sub.2 .dbd.CHR where R is an alkyl of 1-12 carbon atoms. The composition includes a non-elastomeric component comprising blending about 20 to about 40 parts by weight of a flame retardant compound and about 5 to about 20 parts by weight of antimony oxide and about 0.
    Type: Grant
    Filed: March 26, 1982
    Date of Patent: August 30, 1983
    Assignee: Eaton Corporation
    Inventor: Vijayraj M. Kotian
  • Patent number: 4381364
    Abstract: Thermoplastic compositions are disclosed which comprise blends of about 50 to about 85 percent by weight of a thermoplastic polyurethane and the balance of the blend comprising (a) a polyvinyl halide resin and (b) a diene-nitrile copolymer rubber, the weight ratio of (a) to (b) being within the range of from about 1:4 to about 1.5:1.The novel blends do not melt or spread flaming drip when combusted but rather form chars. The blends are optionally fire retarded by the addition of flame retardants.The fire retarded blends find utility in, inter alia, electric wire and cable jacketing where a high degree of fire retardance is required. The blends without fire retardants provide a good thermoplastic polyurethane at lower cost than the polyurethanes alone and find utility in those applications normally associated with polyurethanes such as films, footwear, wire jacketing, and particularly those applications calling for a higher degree of oil resistance than polyurethanes alone.
    Type: Grant
    Filed: June 14, 1982
    Date of Patent: April 26, 1983
    Assignee: The Upjohn Company
    Inventors: Costas N. Georgacopoulos, Curtis P. Smith
  • Patent number: 4370438
    Abstract: The present invention provides a non-burning, non-dripping polyester blend composition in which transesterification is suppressed, as indicated by, e.g., improved heat deflection temperature. The composition comprises (a) approximately 35 to 85 percent by weight of a blend of polyethylene terephthalate and polybutylene terephthalate wherein the polyethylene terephthalate comprises approximately 10 to 25 percent by weight of the blend; (b) approximately 5 to 60 percent by weight of a reinforcing agent; (c) approximately 4 to 15 percent by weight of at least one halogen-containing organic flame retardant compound; and (d) approximately 2 to 10 percent by weight of the amorphous non-abrasive reaction product of antimony trioxide, or a compound of antimony which generates antimony trioxide, and a substrate comprising a hydrous compound of silicon in a weight ratio within the range of approximately 1:1 to 1:4, on an antimony trioxide:substrate basis. The composition may further comprise approximately 0.
    Type: Grant
    Filed: April 9, 1981
    Date of Patent: January 25, 1983
    Assignee: Celanese Corporation
    Inventor: Andrea A. DeGuia
  • Patent number: 4367306
    Abstract: A polyolefin composition is described, comprising: (A) a polyolefin which is modified with an unsaturated carboxylic acid or its derivative, or a mixture of such a modified polyolefin and a polyolefin, (B) aluminum or aluminum alloy in a powdery, fibrous and/or flaky form, (C) electrically conductive carbon black, (D) a halogen-containing organic compound and antimony oxide, and (E) a hydrous inorganic substance. This polyolefin composition has good electromagnetic wave-shielding properties and flame resistance, and therefore, it can be used as a housing material for electronic equipment.
    Type: Grant
    Filed: March 25, 1982
    Date of Patent: January 4, 1983
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masahiko Maeda, Naotochi Watanabe, Kenji Fujitani
  • Patent number: 4363885
    Abstract: A bumper having excellent rigidity, resistance to thermal deformation and to mechanical impact at a low temperature and superior lacquer-bonding property is made from a propylene polymer composition comprising:(A) 55 to 65% by weight of at least one crystalline ethylene-propylene block copolymer in which the content of the polymerized ethylene is in the range of from 5 to 10% by weight, in which the polypropylene component has a fraction thereof insoluble in boiling n-heptane, in an amount of 97% or more, in which a fraction thereof soluble in p-xylene at room temperature, has an intrinsic viscosity of from 3 to 4 determined in decahydronaphthalene at a temperature of 135.degree. C. and which has a melt flow index of from 2 to 10;(B) 30 to 35% by weight of at least one amorphous ethylene-propylene copolymer having an intrinsic viscosity of from 2.0 to 3.5 determined in decahydronaphthalene at a temperature of 135.degree. C., and a Mooney viscosity ML.sub.
    Type: Grant
    Filed: June 24, 1981
    Date of Patent: December 14, 1982
    Assignees: UBE Industries, Ltd., Toyota Jidosha Kigyo Kabushiki Kaisha
    Inventors: Osamu Fukui, Yoshiro Umemoto, Tsugumi Sanmiya, Yutaka Sano, Kazuyoshi Tanaka
  • Patent number: 4360624
    Abstract: A solid solution of zinc oxide and magnesium oxide and/or calcium oxide when added to a halogen-containing plastic composition serves as a smoke and/or fire retardant agent.This solid solution agent may be added to the plastic composition, preferably with an antimony compound.
    Type: Grant
    Filed: February 13, 1981
    Date of Patent: November 23, 1982
    Assignee: Anzon America, Inc.
    Inventors: Joseph M. G. Huang, Robert J. Capwell, Michael A. De Sesa
  • Patent number: 4355126
    Abstract: The present invention provides novel flame retardant, non-dripping thermoplastic molding compositions of polyphenylene ether resins or acrylonitrile-butadiene-styrene copolymers which include a flame retardant agent, and polytetrafluoroethylene.
    Type: Grant
    Filed: February 26, 1979
    Date of Patent: October 19, 1982
    Assignee: General Electric Company
    Inventors: William R. Haaf, Donald L. Reinhard
  • Patent number: 4353997
    Abstract: The disclosure of this application is directed to a water-curable composition comprising a water-curable, silane modified alkylene-alkyl acrylate copolymer, a mineral filler and a halogenated flame retardant additive. These compositions are useful as extrudates about wires and cables providing insulation or jacketing thereon characterized by resistance to deformation and by flame retardancy.
    Type: Grant
    Filed: April 2, 1981
    Date of Patent: October 12, 1982
    Assignee: Union Carbide Corporation
    Inventor: Michael J. Keogh
  • Patent number: 4341881
    Abstract: Flexible polyvinyl chloride having improved flame retardancy and reduced smoke generating properties. The plastics are characterized in that they contain about from 0.01 to 0.2 parts, by wt., based on the iron content, of a high molecular weight ferrocene derivative and about 0.1 to 20 parts, by wt., of antimony oxide per 100 parts of polyvinyl chloride resin. A composition comprising the ferrocene derivative and antimony oxide useful for preparing the improved plastic is also disclosed.
    Type: Grant
    Filed: April 19, 1979
    Date of Patent: July 27, 1982
    Assignee: Syntex (U.S.A.) Inc.
    Inventors: John J. Kracklauer, Charles J. Sparkes
  • Patent number: 4339556
    Abstract: Flame retardant resin compositions are disclosed, comprising a thermoplastic condensation polymer selected from the group consisting of polyesters, polycarbonates and polyamides, a halogenated flame-retardant, and a rubber-occluded flame retardant synergist. The compositions possess superior stability in melt processing and improved flame retardancy and impact strength.
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: July 13, 1982
    Assignee: Monsanto Company
    Inventor: Massimo Baer
  • Patent number: 4338243
    Abstract: Use of a selected antimonate has been found to increase flame-retardancy without lowering thermal resistivity of a polyurethane terephthalate molding blend which contains an ionic hydrocarbon copolymer or ionic salt of a hydrocarbon acid and a low molecular weight compound.
    Type: Grant
    Filed: May 7, 1980
    Date of Patent: July 6, 1982
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: James L. Hecht, Paul C. Yates
  • Patent number: 4332855
    Abstract: New polymeric compositions based on polytetramethylene terephthalate (PTMT) polymers are disclosed. PTMT polymers are subject to embrittlement, especially at elevated temperatures and when a flame retardant is incorporated therein. This problem is substantially reduced by blending the PTMT polymer with a second polymer which has a flex modulus of 500 to 100,000 psi and a solubility parameter within .+-.1.5 of the PTMT polymer, for example an ethylene/vinyl acetate copolymer or a block copolymer containing polyether and polyester blocks. The compositions are particularly useful as wire insulation.
    Type: Grant
    Filed: April 14, 1978
    Date of Patent: June 1, 1982
    Assignee: Raychem Corporation
    Inventors: Steven C. Zingheim, Hans E. Lunk
  • Patent number: RE31214
    Abstract: This disclosure deals with novel antimony oxide colloidal sols and formulations of the same containing halogens that provide a vastly improved fire-retarding quality to textiles, plastics and other materials to which the compounds are applied.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: April 19, 1983
    Inventors: Henry G. Petrow, Robert J. Allen