Abstract: Disclosed is a flame retardant thermoplastic elastomeric composition that in the form of an insulation about an electrical conductor is able to meet or exceed the requirements of UL VW-1 Vertical Flame Test and in the form of a jacket about an electrical cable is able to meet or exceed the requirements of IEEE-383 Cable Tray Flame Test while having a limiting oxygen index of only 24 to 27 percent. The composition has an elastomeric component of the type comprising about 25 to about 75 parts by weight of a crystalline olefin resin and about 75 to about 25 parts by weight of a vulcanized monoolefin copolymer rubber comprising a polymer of ethylene or propylene and one other alpha olefin of the formula CH.sub.2 .dbd.CHR where R is an alkyl of 1-12 carbon atoms. The composition includes a non-elastomeric component comprising blending about 20 to about 40 parts by weight of a flame retardant compound and about 5 to about 20 parts by weight of antimony oxide and about 0.
Abstract: Thermoplastic compositions are disclosed which comprise blends of about 50 to about 85 percent by weight of a thermoplastic polyurethane and the balance of the blend comprising (a) a polyvinyl halide resin and (b) a diene-nitrile copolymer rubber, the weight ratio of (a) to (b) being within the range of from about 1:4 to about 1.5:1.The novel blends do not melt or spread flaming drip when combusted but rather form chars. The blends are optionally fire retarded by the addition of flame retardants.The fire retarded blends find utility in, inter alia, electric wire and cable jacketing where a high degree of fire retardance is required. The blends without fire retardants provide a good thermoplastic polyurethane at lower cost than the polyurethanes alone and find utility in those applications normally associated with polyurethanes such as films, footwear, wire jacketing, and particularly those applications calling for a higher degree of oil resistance than polyurethanes alone.
Type:
Grant
Filed:
June 14, 1982
Date of Patent:
April 26, 1983
Assignee:
The Upjohn Company
Inventors:
Costas N. Georgacopoulos, Curtis P. Smith
Abstract: The present invention provides a non-burning, non-dripping polyester blend composition in which transesterification is suppressed, as indicated by, e.g., improved heat deflection temperature. The composition comprises (a) approximately 35 to 85 percent by weight of a blend of polyethylene terephthalate and polybutylene terephthalate wherein the polyethylene terephthalate comprises approximately 10 to 25 percent by weight of the blend; (b) approximately 5 to 60 percent by weight of a reinforcing agent; (c) approximately 4 to 15 percent by weight of at least one halogen-containing organic flame retardant compound; and (d) approximately 2 to 10 percent by weight of the amorphous non-abrasive reaction product of antimony trioxide, or a compound of antimony which generates antimony trioxide, and a substrate comprising a hydrous compound of silicon in a weight ratio within the range of approximately 1:1 to 1:4, on an antimony trioxide:substrate basis. The composition may further comprise approximately 0.
Abstract: A polyolefin composition is described, comprising: (A) a polyolefin which is modified with an unsaturated carboxylic acid or its derivative, or a mixture of such a modified polyolefin and a polyolefin, (B) aluminum or aluminum alloy in a powdery, fibrous and/or flaky form, (C) electrically conductive carbon black, (D) a halogen-containing organic compound and antimony oxide, and (E) a hydrous inorganic substance. This polyolefin composition has good electromagnetic wave-shielding properties and flame resistance, and therefore, it can be used as a housing material for electronic equipment.
Abstract: A bumper having excellent rigidity, resistance to thermal deformation and to mechanical impact at a low temperature and superior lacquer-bonding property is made from a propylene polymer composition comprising:(A) 55 to 65% by weight of at least one crystalline ethylene-propylene block copolymer in which the content of the polymerized ethylene is in the range of from 5 to 10% by weight, in which the polypropylene component has a fraction thereof insoluble in boiling n-heptane, in an amount of 97% or more, in which a fraction thereof soluble in p-xylene at room temperature, has an intrinsic viscosity of from 3 to 4 determined in decahydronaphthalene at a temperature of 135.degree. C. and which has a melt flow index of from 2 to 10;(B) 30 to 35% by weight of at least one amorphous ethylene-propylene copolymer having an intrinsic viscosity of from 2.0 to 3.5 determined in decahydronaphthalene at a temperature of 135.degree. C., and a Mooney viscosity ML.sub.
Type:
Grant
Filed:
June 24, 1981
Date of Patent:
December 14, 1982
Assignees:
UBE Industries, Ltd., Toyota Jidosha Kigyo Kabushiki Kaisha
Abstract: A solid solution of zinc oxide and magnesium oxide and/or calcium oxide when added to a halogen-containing plastic composition serves as a smoke and/or fire retardant agent.This solid solution agent may be added to the plastic composition, preferably with an antimony compound.
Type:
Grant
Filed:
February 13, 1981
Date of Patent:
November 23, 1982
Assignee:
Anzon America, Inc.
Inventors:
Joseph M. G. Huang, Robert J. Capwell, Michael A. De Sesa
Abstract: The present invention provides novel flame retardant, non-dripping thermoplastic molding compositions of polyphenylene ether resins or acrylonitrile-butadiene-styrene copolymers which include a flame retardant agent, and polytetrafluoroethylene.
Abstract: The disclosure of this application is directed to a water-curable composition comprising a water-curable, silane modified alkylene-alkyl acrylate copolymer, a mineral filler and a halogenated flame retardant additive. These compositions are useful as extrudates about wires and cables providing insulation or jacketing thereon characterized by resistance to deformation and by flame retardancy.
Abstract: Flexible polyvinyl chloride having improved flame retardancy and reduced smoke generating properties. The plastics are characterized in that they contain about from 0.01 to 0.2 parts, by wt., based on the iron content, of a high molecular weight ferrocene derivative and about 0.1 to 20 parts, by wt., of antimony oxide per 100 parts of polyvinyl chloride resin. A composition comprising the ferrocene derivative and antimony oxide useful for preparing the improved plastic is also disclosed.
Abstract: Flame retardant resin compositions are disclosed, comprising a thermoplastic condensation polymer selected from the group consisting of polyesters, polycarbonates and polyamides, a halogenated flame-retardant, and a rubber-occluded flame retardant synergist. The compositions possess superior stability in melt processing and improved flame retardancy and impact strength.
Abstract: Use of a selected antimonate has been found to increase flame-retardancy without lowering thermal resistivity of a polyurethane terephthalate molding blend which contains an ionic hydrocarbon copolymer or ionic salt of a hydrocarbon acid and a low molecular weight compound.
Abstract: New polymeric compositions based on polytetramethylene terephthalate (PTMT) polymers are disclosed. PTMT polymers are subject to embrittlement, especially at elevated temperatures and when a flame retardant is incorporated therein. This problem is substantially reduced by blending the PTMT polymer with a second polymer which has a flex modulus of 500 to 100,000 psi and a solubility parameter within .+-.1.5 of the PTMT polymer, for example an ethylene/vinyl acetate copolymer or a block copolymer containing polyether and polyester blocks. The compositions are particularly useful as wire insulation.
Abstract: This disclosure deals with novel antimony oxide colloidal sols and formulations of the same containing halogens that provide a vastly improved fire-retarding quality to textiles, plastics and other materials to which the compounds are applied.