Phosphorus Atom Dnrm Patents (Class 524/414)
  • Patent number: 7393885
    Abstract: A phosphorus-containing coated magnesium oxide powdered material comprising a coated magnesium oxide powdered material having a surface coating layer comprised of a double oxide, wherein the phosphorus-containing coated magnesium oxide powdered material has a coating layer comprised of a magnesium phosphate compound in at least part of a surface of the coated magnesium oxide powdered material, wherein the content of the magnesium phosphate compound in the coated magnesium oxide powdered material is 0.1 to 10% by mass, in terms of phosphorus; a method for producing a phosphorus-containing coated magnesium oxide powdered material, wherein the method comprises treating a coated magnesium oxide powdered material having a surface coating layer comprised of a double oxide with a phosphorus compound, and then calcining the resultant powdered material at 300° C.
    Type: Grant
    Filed: December 1, 2005
    Date of Patent: July 1, 2008
    Assignee: Tateho Chemical Industries Co., Ltd.
    Inventors: Toshio Kiyokawa, Kaori Yamamoto, Masaaki Kunishige
  • Publication number: 20080153963
    Abstract: The present disclosure relates a method of making a dispersion. Microparticles, nanoparticles and a fluid polymer component are mixed to form a dispersion. A sufficient amount of nanoparticles provides for an increase in material throughput relative to a comparable dispersion that is free of nanoparticles.
    Type: Application
    Filed: December 22, 2006
    Publication date: June 26, 2008
    Inventors: Jimmie R. Baran, Madeline P. Shinbach, Meghan L. Mallozzi
  • Publication number: 20080153954
    Abstract: The invention relates to polymer compositions comprising PCT (poly((cyclohexylene-dimethylene) terephthalate)) polymer and a fibrous glass filler having a non-circular cross-sectional aspect ratio of greater than at or about 4.
    Type: Application
    Filed: November 16, 2007
    Publication date: June 26, 2008
    Inventor: Thierry Arpin
  • Publication number: 20080132630
    Abstract: A composition is disclosed, comprising, based on the total weight of the composition, a combination of from 44 to 80 weight percent of a thermoplastic poly(butylene terephthalate); from 20 to 50 weight percent of a thermoplastic poly(ethylene terephthalate) having an intrinsic viscosity of 0.5 to 0.8 deciliters per gram, measured in a 60:40 by weight phenol/1,1,2,2-tetrachloroethane mixture at 23° C. using a relative viscometer operating with a closed loop system, which measures the solvent and sample viscosity simultaneously; from 5 to less than 20 weight percent of a talc filler having an average largest dimension of less than 0.9 micrometers, a median particle size of less than 0.9 micrometers, or both; and from 0.1 to 0.5 weight percent of a mold release agent. The compositions are useful in the manufacture of lighting articles, which can be directly metallized without the inclusion of a base coat.
    Type: Application
    Filed: December 6, 2006
    Publication date: June 5, 2008
    Applicant: GENERAL ELECTRIC COMPANY
    Inventor: Rama Konduri
  • Publication number: 20080113138
    Abstract: A thermoplastic composition includes the product of melt kneading a composition including a poly(arylene ether), a polyolefin, and a high molecular weight hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene. The composition exhibits substantially improved chemical resistance compared to a corresponding composition prepared with a lower molecular weight hydrogenated block copolymer. Methods of preparing the composition and articles prepared for the composition are also described. The composition is particularly useful for fabricating halogen-free tubes for sheathing automotive wiring harnesses.
    Type: Application
    Filed: November 13, 2006
    Publication date: May 15, 2008
    Inventors: William Eugene Pecak, Vijay Rajamani
  • Publication number: 20080103243
    Abstract: This invention relates to thermoplastic elastomer compositions comprising blends of polyether ester elastomers and crosslinkable poly(meth)acrylate rubbers, and the manufacture and use thereof in, for example, shaped or molded rubber articles.
    Type: Application
    Filed: October 31, 2006
    Publication date: May 1, 2008
    Inventors: Hari Babu Sunkara, Herbert Vernon Bendler
  • Publication number: 20080076864
    Abstract: A silicone rubber composition which cures by condensation is provided. After curing, the silicone rubber exhibits excellent insulation and antistatic properties, and this silicone rubber has overcome the problem of electrostatic adsorption of the dust in the air in the applications including a master template, tampon printing, and a large size industrial roll. The silicone rubber composition which cures by condensation contains an ion conductive antistatic agent.
    Type: Application
    Filed: September 19, 2007
    Publication date: March 27, 2008
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventor: Hiroshi MOGI
  • Publication number: 20080076863
    Abstract: A polyester resin composition having an equivalent spherical diameter of 1 mm to 50 mm, a degree of crystallization of not less than 65% and less than 99%, an intrinsic viscosity of not more than 0.7 dl/g and a cyclic trimer content of not more than 0.4% by weight. This polymer resin composition has an excellent color tone, causes no significant viscosity lowering or viscosity rise, and can withstand a process which is exposed to a long-term thermal history. A polyester resin composition having a viscosity suitable for extrusion in a general-purpose manner, a production process thereof, and a polyester film are also provided.
    Type: Application
    Filed: May 24, 2005
    Publication date: March 27, 2008
    Inventors: Yoshihiro Honma, Jun Sakamoto, Masahiro Kimura
  • Patent number: 7345104
    Abstract: Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: March 18, 2008
    Assignee: Eastman Chemical Company
    Inventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Harold Eugene Dobbs, Spencer Allen Gilliam
  • Patent number: 7342059
    Abstract: Blends of polycarbonate and copolyester that are capable of being extrusion blow-molded are described. The blends preferably comprise (I) about 1 to 99% by weight of a linear or branched polycarbonate and (II) about 1 to 99% by weight of a mixture of (i) about 40 to 100% by weight of a first copolyester and (ii) about 0 to 60% by weight of a second copolyester. The first copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues, (B) diol residues comprising about 45 to 75 mole percent of 1,4-cyclohexanedimethanol (CHDM) residues and about 25 to 55 mole percent of ethylene glycol residues, and (C) about 0.05 to 1.0 mole percent of the residue of a trifunctional monomer. The optional second copolyester preferably comprises (A) diacid residues comprising terephthalic acid residues and (B) diol residues comprising about 52 to 90 mole percent of CHDM residues and about 10 to 48 mole percent of ethylene glycol residues.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: March 11, 2008
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Harold Eugene Dobbs, Spencer Allen Gilliam, Wesley Raymond Hale
  • Patent number: 7342068
    Abstract: Aqueous polyurethane dispersions comprising polyurethane polymer and methods for making and using same are disclosed herein. In one aspect of the present invention, aqueous polyurethane dispersions, comprising a polyurethane polymer having a weight average molecular weight ranging from 20,000 to 80,000, are prepared by controlling the weight average molecular weight of the polymer by reacting the isocyanate terminated prepolymer with at least one chain terminating agent; and/or maintaining a N/COOH molar ratio of amine in the neutralizing agent to acid functional group in the isocyanate reactive compound to from about 0.5:1 to about 1:1.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: March 11, 2008
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Eric Howard Klingenberg, Shafiq Nisarali Fazel
  • Publication number: 20080039568
    Abstract: The present invention relates to such a polyamide resin composition that is suitably used as a material of a gasoline tank and a material of a molded article, such as a hollow molded container including a beverage bottle, a film and a sheet. A polyamide resin that is good in heat stability upon molding and suffers less increase in filter back pressure is provided by regulating a polyamide resin composition to have a phosphorus content of from 30 to 200 ppm (excluding 200 ppm), and a sodium content/phosphorus content ratio (molar ratio) of from 3 to 7 (excluding 3 and 7) or regulating it to have a phosphorus content less than 30 ppm and an alkali metal content less than 45 ppm.
    Type: Application
    Filed: December 21, 2004
    Publication date: February 14, 2008
    Applicant: TOYO BOSEKI KABUSHIKI KAISHA
    Inventors: Gaku Maruyama, Kenta Suzuki, Makoto Ito, Kazuo Katayose
  • Publication number: 20080033079
    Abstract: The present invention relates to a thermoplastic composition comprising at least aluminium hypophosphite (aluminium phosphinate), corresponding to the chemical formula Al(H2PO2)3 as halogen-free flame retardant agent, and at least a polymer based on polyamide. The flame retarded halogen-free thermoplastic moulding compositions according to the invention is used to produce articles based on polyamide polymers with or without glass fiber reinforcement, which are flame retarded.
    Type: Application
    Filed: January 7, 2004
    Publication date: February 7, 2008
    Applicant: ITALMATCH CHEMICALS S.p.A.
    Inventors: Silvestro Costanzi, Maurizio Leonardi
  • Patent number: 7291664
    Abstract: The invention relates to a multicomponent composition for photodegradable and biodegradable plastic articles, and the use of said composition in the manufacture of various disposable and packaging plastic articles and the articles made therefrom. The multicomponent composition does not contain starch, and is a multicomponent compounded composition of new bioactive material of chitin, casein and the like, with biodegradable aid component, photodegradable and auto-oxidation catalysis component, and nonmetallic minerals and the like. Under natural condition, the degraded material can be utilized by microorganism to release carbon dioxide and water, and acts as an eco-friendly plastic material.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 6, 2007
    Inventor: Benzhong Hao
  • Publication number: 20070197702
    Abstract: The present invention relates to an elastomer rubber composition containing a carboxylated rubber polymer and a fluorinated additive. The present invention is also directed to an elastomer composition containing a hydrogenated carboxylated nitrile rubber and a fluorinated additive.
    Type: Application
    Filed: February 23, 2006
    Publication date: August 23, 2007
    Inventors: Victor Nasreddine, Lorenzo Ferrari, Sharon Guo
  • Patent number: 7256232
    Abstract: The purpose of the invention is a coating precursor comprising a silicone resin, a mineral filler and an organic solvent capable of dissolving the said resin and putting the said mineral filler into suspension, the said silicone resin and the said mineral filler being capable of chemically reacting so as to produce a solid layer on a substrate after the organic solvent has evaporated and a cohesive refractory layer after a calcination operation. Another purpose of the invention is a method for coating a given surface of a substrate with at least one refractory layer containing silicon in which the substrate is coated with a coating precursor according to the invention so as to form a green layer and a heat treatment is carried out to calcine the said green layer and to form a cohesive refractory layer. The invention is a means of obtaining a protective coating capable of resisting oxidizing environments, liquid metal and solid or molten salt.
    Type: Grant
    Filed: October 14, 2002
    Date of Patent: August 14, 2007
    Assignees: Aluminium Pechiney, Pechiney Rhenalu
    Inventors: Airy-Pierre Lamaze, Christian Barthelemy, Thomas Spadone, Robert Rey-Flandrin
  • Patent number: 7256228
    Abstract: A stabilized thermoplastic resin composition is disclosed which comprises structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester and a combination of at least two quenchers, wherein said quencher is selected from a group consisting of phosphorus compound, carboxylic acid, derivates of carboxylic acids, epoxy functional polymers and boron compound. Also disclosed is a stabilized thermoplastic resin composition comprising: structural units derived at least one substituted or unsubstituted polycarbonate, at least one substituted or unsubstituted polyester, an epoxy functional polymers and a combination of at least one quenchers, wherein said quencher is selected from a group consisting of phosphorus compounds, carboxylic acid compounds, polyols, and boron compounds. In addition the composition disclosed possess good optical properties, thermal properties and stability.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: August 14, 2007
    Assignee: General Electric Company
    Inventors: Parminder Agarwal, Peter H. Th. Vollenberg, Gabrie Hoogland, Vishvajit Chandrakant Juikar, Ganesh Kannan, Abbas-Alli Ghudubhai Shaikh, Sachin Ashok Shelukar
  • Patent number: 7241827
    Abstract: The present invention relates to an inorganic compound with a lamellar structure, to its process of preparation and to its use in the reinforcement of macromolecular materials. It relates more specifically to a compound based on zirconium and/or titanium phosphate. The process for the preparation of the compound comprises a stage of treatment at a pH of between 3 and 9.
    Type: Grant
    Filed: August 23, 2001
    Date of Patent: July 10, 2007
    Assignee: Rhodianyl
    Inventors: Emmanuelle Bougelot, Dominique Dupuis, Gilles Robert, Joël Varlet
  • Patent number: 7238738
    Abstract: The invention relates to a material with high barrier properties toward gases and liquids, characterized in that it comprises a thermoplastic matrix and a nanoparticulate compound based on zirconium and/or titanium phosphate exhibiting individual leaves with an aspect ratio of equal to or greater than 250. Application to the manufacture of films, pipes, hollow bodies or tanks by forming said material.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: July 3, 2007
    Assignee: Rhodianyl
    Inventors: Carole Dupuy, Bruno Echalier, Hélène Egret, Bertrand Lousteau, Olivier Mathyeu
  • Patent number: 7232613
    Abstract: The base material for pressure-sensitive adhesive tape or sheet is constituted of a polyolefin based resin as the major component and is obtained by rolling by means of a calender having a measure capable of individually changing the rotational speed of each calender roll. Examples of the measure capable of individually changing the rotational speed of each calender roll include a measure provided with motors capable of individually driving their respective calender rolls and a measure provided with speed regulators capable of individually regulating their respective calender rolls. It may be employed that the number of calender rolls is four and that the roll arrangement is in the reverse L shape. It is preferable that the base material for pressure-sensitive adhesive tape or sheet contains an inorganic compound together with the polyolefin based resin.
    Type: Grant
    Filed: June 23, 2004
    Date of Patent: June 19, 2007
    Assignee: Nitto Denko Corporation
    Inventors: Yoshio Nakagawa, Masato Shirai, Shuzo Fujiwara, Yoshihide Kawaguchi, Hiroichi Ukei
  • Patent number: 7230046
    Abstract: A flame-retardant composition is described, containing a thermoplastic resin component which includes polyphenylene ether (PPE), along with a low-melting glass having a glass transition temperature (Tg) of less than about 500° C. The low-melting glass contains phosphate, and at least one of RO; R?2O; Al2O3; B2O3; or SO3, where R is a bivalent metal, while R? is an alkali metal. Related articles are also described.
    Type: Grant
    Filed: August 19, 2004
    Date of Patent: June 12, 2007
    Assignee: General Electric Company
    Inventors: Vijay R. Mhetar, Jeffery Gary Tenenbaum, Sumi
  • Patent number: 7223808
    Abstract: The invention relates to a method for the production of an adhesive and an adhesive kit for joining similar or different metal surfaces or ceramics, especially in the field of biomedicine. The objective of the invention is to avoid polymerization-linked by-products and disadvantageous effects, in addition to enabling a temporary biocompatible bond between metal and metal or metal and ceramics. The inventive method consist in using a monomer-free polymethylmethacrylate which is mixed with a suitable, non-toxic solvent and a bioactive vitreous-crystalline material with a particle size ranging from 0.05–20?, consisting of 15–45 wt. % CaO, 40–45 wt. % P2O5, 10–40 wt. % ZrO2 and 0.7–3.5 wt. % fluoride, having apatite and calcium zircon phosphate as main crystal phases and a glass phase as an auxiliary component until a flowable mixture is obtained. The invention also relates to an adhesive kit consisting of said components.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: May 29, 2007
    Assignees: Humboldt Universitaet Berlin Carite Universitaetsklinikum (CCM), Bam Bundesanstalt Fuer Materialforschung und -Pruefung, Vita Zahnfabrik H. Rauter GmbH & Co. KG
    Inventors: Wolf-Dieter Müller, Georg Berger, Emil Nagel, Klaus-Peter Lange
  • Patent number: 7223809
    Abstract: A molding composition exhibiting bleach resistance includes a polyoxymethylene matrix polymer, from about 0.5 to about 10 weight percent of a bleach stabilizer selected from alkali metal or alkaline earth element carbonates or phosphates and mixtures thereof dispersed in the matrix resin. A bleach co-stabilizer is selected from the group consisting of: (a) a poly(alkoxy) stabilizer; (b) a zinc oxide stabilizer; (c) a color stabilizer consisting of a mixture of calcium citrate and calcium propionate, wherein the calcium citrate is the predominant component of the color stabilizer mixture; or (d) mixtures of two or more of (a), (b) and (c). The compositions exhibit a bleach resistance index of at least 2.0.
    Type: Grant
    Filed: May 27, 2005
    Date of Patent: May 29, 2007
    Assignee: Ticona LLC
    Inventor: Vincent J. Notorgiacomo
  • Patent number: 7217753
    Abstract: A fire retardant intumescent coating composition comprises: (a) 30 to 60% by weight of a phosphorous containing material which decomposes to produce phosphoric acid when the coating is exposed to fire; (b) 10 to 30% by weight of a thermosetting binder; (c) 2.5 to 10% by weight of a curing agent for the thermosetting binder; and (d) 5 to 40% by weight of a thermoplastic binder, wherein the active groups of the thermosetting and thermoplastic binders are chosen so as to impart charring and blowing functions to the intumescent coating composition. The thermosetting binder is advantageously a hydroxylated thermosetting binder, suitably an epoxy resin. The thermoplastic binder is advantageously an oxygenated heterocyclic thermoplastic binder, suitably an aldehyde and/or ketone resin. The coating composition may contain 1 to 10% by weight of a colouring agent, suitably titanium dioxide. The coating composition may contain 0.1 to 10% by weight of melt viscosity modifier, suitably hydrogenated castor oil.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: May 15, 2007
    Assignees: Rohm and Haas Company, Chance & Hunt Limited
    Inventors: Michael John Sinclair, James Edward Watts
  • Patent number: 7217755
    Abstract: Nanocomposite materials having a composition including an inorganic constituent, a preformed organic polymer constituent, and a metal ion sequestration constituent are disclosed. The nanocomposites are characterized by being single phase, substantially homogeneous materials wherein the preformed polymer constituent and the inorganic constituent form an interpenetrating network with each other. The inorganic constituent may be an inorganic oxide, such as silicon dioxide, formed by the in situ catalyzed condensation of an inorganic precursor in the presence of the solvated polymer and metal ion sequestration constituent. The polymer constituent may be any hydrophilic polymer capable of forming a type I nanocomposite such as, polyacrylonitrile (PAN), polyethyleneoxide (PEO), polyethylene glycol (PEG), polyvinyl acetate (PVAc), polyvinyl alcohol (PVA), and combinations thereof. Nanocomposite materials of the present invention may be used as permeable reactive barriers (PRBs) to remediate contaminated groundwater.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: May 15, 2007
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Mason K. Harrup, Frederick F. Stewart
  • Patent number: 7202294
    Abstract: Coating materials comprising at least one electrically conductive pigment (A1) having an at least bimodal particle size distribution and at least one binder, the pigment/binder ratio being >1.5:1, can be used as coil coating materials.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: April 10, 2007
    Assignee: BASF Coatings AG
    Inventors: Horst Hintze-Brüning, Lothar Jandel, Ralf Neuhaus, Markus Ruckpaul, Marc Bäumer
  • Patent number: 7186759
    Abstract: The invention relates to a heterophasic composition which essentially consists of three immniscible components, A, B and C, and the production method of the same. The component A is some body compatible polymer, the component H is a water soluble or hydrolytically degradable substance which produces cavities or network like porosity after disappearing through solubilization or degradation, and a bioactive substance C which at least component B contains in form of particles as a blend component and which still exists in the pores or their walls after the degradation or solubilization of the component B.
    Type: Grant
    Filed: July 12, 2001
    Date of Patent: March 6, 2007
    Assignee: Vivoxid Oy
    Inventors: Jukka Veli Seppälä, Riitta Minna Hannele Malin
  • Patent number: 7179400
    Abstract: The invention is a stabilizer composition for halogen-containing polymers, comprising a carrier material of the general formula CaxAl2(OH)2(x+2)HPO3.m H2O, wherein x is a number from 2 to 12 and m is a number from 0 to 12, and a salt of a halogen-containing oxy acid or a mixture of two or more such salts, at least one salt of a halogen-containing oxy acid being present in finely distributed form on the carrier material, to a process for the preparation thereof, and to the use thereof.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: February 20, 2007
    Assignee: Baerlocher GmbH
    Inventors: Bernd Frischkemuth, Christian Helbig
  • Patent number: 7169728
    Abstract: A condensed phosphate containing an alkaline earth metal is caused to be present on the surface of titanium dioxide fine particles, and as a result, the condensed phosphate is firmly coupled with the fine particles and is barely liberated from the surface of the fine particles into a medium such as a binder or a resin. As a result, photo-functional particles exhibiting durability and dispersion stability are obtained. By use of the photo-functional particles, a powder and a slurry exhibiting excellent photo-functional property, durability, dispersion stability, and hydrophilicity are produced. In addition, by use of the powder and slurry, a polymer composition, a coating agent, a photo-functional formed article, and a photo-functional structure are produced.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: January 30, 2007
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masayuki Sanbayashi, Hiroyuki Hagihara, Jun Tanaka, Yoshinori Ueyoshi
  • Patent number: 7164046
    Abstract: The present invention relates to a process of manufacture of polytrimethylene ether glycol, in which one or more inorganic compounds selected from an inorganic salt and an inorganic base is utilized during certain purification steps to reduce phase separation time.
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: January 16, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Hari Babu Sunkara, Howard C. Ng, Wei Zheng, Zhihong Wu
  • Patent number: 7161045
    Abstract: A process of manufacture of polytrimethylene ether glycol comprising: (a) polycondensing reactant comprising diol selected from the group consisting of 1,3-propanediol, 1,3-propanediol dimer and 1,3-propanediol trimer or mixtures thereof in the presence of acid polycondensation catalyst to form polytrimethylene ether glycol; (b) adding water to the polytrimethylene ether glycol and hydrolyzing the acid esters formed during the polycondensation to form a hydrolyzed mixture containing the polytrimethylene ether glycol and the hydrolyzed acid esters; (c) adding organic solvent that is miscible with water to the hydrolyzed mixture to form an aqueous-organic mixture comprising (i) organic phase containing polytrimethylene ether glycol and residual acid polycondensation catalyst from the polycondensing and (ii) water phase; (d) separating the water phase and the organic phase; (e) adding base to the separated organic phase to neutralize the residual acid polycondensation catalyst by forming salts of the residual ac
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: January 9, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Hari Babu Sunkara, Howard C. Ng, Wei Zheng
  • Patent number: 7157607
    Abstract: A process of manufacture of polytrimethylene ether glycol comprising: (a) polycondensing reactant comprising diol selected from the group consisting of 1,3-propanediol, 1,3-propanediol dimer and 1,3-propanediol trimer or mixtures thereof in the presence of acid polycondensation catalyst to form polytrimethylene ether glycol; (b) adding water to the polytrimethylene ether glycol to form an aqueous mixture; (c) heating the aqueous mixture to hydrolyze acid esters formed during the acid catalyzed polycondensation; (d) adding to the hydrolyzed aqueous mixture organic solvent that is miscible with polytrimethylene ether glycol to form (i) organic phase containing the polytrimethylene ether glycol and residual acid polycondensation catalyst from the polycondensing and (ii) aqueous phase; (e) separating the aqueous phase and the organic phase; (f) adding base to the separated organic phase to neutralize the residual acid polycondensation catalyst by forming salts of the residual acid polycondensation catalyst; (g
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: January 2, 2007
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Hari Babu Sunkara, Howard C. Ng, Wei Zheng
  • Patent number: 7157503
    Abstract: An antibacterial, antifouling paint for construction materials contains a coating resin composition and powdery metal-modified apatite. Part of metal atoms in the apatite crystal structure is provided by an optically catalytic metal. Preferably, the metal-modified apatite is a calcium hydroxyapatite which has part of its Ca atoms substituted by Ti.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: January 2, 2007
    Assignee: Fujitsu Limited
    Inventor: Masato Wakamura
  • Patent number: 7150879
    Abstract: The present invention provides a novel process for producing a calcium phosphate cement or filler which hardens in a temperature dependent fashion in association with an endothermic reaction. In the reaction a limited amount of water is mixed with dry calcium phosphate precursors to produce a hydrated precursor paste. Hardening of the paste occurs rapidly at body temperature an is accompanied by the conversion of one or more of the reactants to poorly crystalline apatitic calcium phosphate. The hardened cements, fillers, growth matrices, orthopedic and delivery devices of the invention are rapidly resorbable and stimulate hard tissue growth and healing.
    Type: Grant
    Filed: May 11, 2000
    Date of Patent: December 19, 2006
    Assignee: Etex Corporation
    Inventors: Dosuk D. Lee, Christian Rey, Maria Aiolova, Aliassghar Tofighi
  • Patent number: 7151129
    Abstract: The resin in a fiber-reinforced resin material that uses a single fiber reinforcing ply or a number of fiber reinforcing plies for reinforcing the resin material is reinforced by dispersing carbon nanofibers therein, whereby a fiber-reinforced composite resin material having improved strength such as compressive strength is provided. In a carbon nanofiber-dispersed resin fiber-reinforced composite material 1, an uncured resin 4 having carbon nanofibers 5 dispersed therein is impregnated into a number of fiber reinforcing plies 2a laid one upon another. Upon curing the resin 4, the strength of the matrix 3 itself is increased through the carbon nanofibers 5 dispersed in the resin 4. Moreover, the fiber reinforcement 2 and the resin 4 are joined together strongly by the carbon nanofibers 5, and hence the strength of the composite material, for example the compressive strength, which hitherto has been dependent on the strength of the resin 4 only, is improved.
    Type: Grant
    Filed: August 20, 2003
    Date of Patent: December 19, 2006
    Assignee: Japan Aerospace Exploration Agency
    Inventors: Takashi Ishikawa, Yutaka Iwahori, Shin Ishiwata, Shunji Higaki
  • Patent number: 7122251
    Abstract: The resin composition for a platable substrate of the present invention comprises 100 parts by weight of a resin composition (C) comprising 10 to 60% by weight of a graft copolymer (A) prepared by graft polymerization of a rubbery polymer (A1) and a monomer component (A2) containing an aromatic alkenyl compound monomer unit (a) and a vinyl cyanide compound monomer unit (b) and 40 to 90% by weight of the other polymer (B) (provided that the total amount of the components (A) and (B) is 100% by weight), and 5 to 40 parts by weight of a phosphate ester flame retardant (D) having a molecular weight of more than 326 or 2 to 40 parts by weight of a red phosphorus flame retardant (D?). The resin composition for a platable substrate of the present invention is excellent in production stability such as moldability, dimensional stability, mechanical strength and plating properties, and is also environmentally friendly.
    Type: Grant
    Filed: May 29, 2002
    Date of Patent: October 17, 2006
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kouichi Tezuka, Seizo Fujii
  • Patent number: 7060643
    Abstract: A condensed phosphate containing an alkaline earth metal is caused to be present on the surface of titanium dioxide fine particles, and as a result, the condensed phosphate is firmly coupled with the fine particles and is barely liberated from the surface of the fine particles into a medium such as a binder or a resin. As a result, photo-functional particles exhibiting durability and dispersion stability are obtained. By use of the photo-functional particles, a powder and a slurry exhibiting excellent photo-functional property, durability, dispersion stability, and hydrophilicity are produced. In addition, by use of the powder and slurry, a polymer composition, a coating agent, a photo-functional formed article, and a photo-functional structure are produced.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: June 13, 2006
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masayuki Sanbayashi, Hiroyuki Hagihara, Jun Tanaka, Yoshinori Ueyoshi
  • Patent number: 7056968
    Abstract: A calcium phosphate-synthetic resin composite body produced by pressing a calcium phosphate block (or a calcium phosphate block and calcium phosphate particles), and synthetic resin particles I, which are at least partially cross-linked in advance, and uncross-linked, synthetic resin particles II while heating, the calcium phosphate block being exposed on at least part of the surface of the composite body. The above composite body is produced by a method comprising the steps of (a) introducing the calcium phosphate block (or a calcium phosphate block and calcium phosphate particles), the synthetic resin particles I and II into a cavity of a forming die such that the calcium phosphate block is present on at least part of the surface of the composite body, and that the synthetic resin particles surround the calcium phosphate particles, if any; and (b) pressing them in the cavity of the forming die while heating, so that the synthetic resin particles are bonded to each other.
    Type: Grant
    Filed: July 9, 2003
    Date of Patent: June 6, 2006
    Assignee: PENTAX Corporation
    Inventors: Tsuneo Hiraide, Yukio Kubota
  • Patent number: 7053143
    Abstract: The polyester-based resin composition of the present invention comprises a polyamide resin, a polyester resin containing an antimony compound and a compound selected from the group consisting of inorganic acid salts and hydroxides of group-1 or -2 metals of the periodic table and transition metals. In the polyester-based resin composition, the phosphorus atom concentration, the antimony atom concentration, and the blending ratio of the inorganic acid salt or hydroxide to the phosphorus compound are regulated so as to satisfy the specific relationships to effectively prevent the darkening due to the deposition of antimony metal, thereby providing the polyester-based resin composition having excellent gas barrier properties and a good appearance with minimized darkening.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: May 30, 2006
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Akira Mori, Koji Yamamoto
  • Patent number: 7053172
    Abstract: The fuel-barrier polyamide resin of the present invention is a product of the polycondensation of a diamine component comprising 70 mol % or higher of m-xylylenediamine and a dicarboxylic acid component comprising 70 mol % or higher of a mixed dicarboxylic acid which comprises a C4 to C20 ?,?-linear aliphatic dicarboxylic acid and at least one dicarboxylic acid selected from the group consisting of isophthalic acid and naphthalenedicarboxylic acid in a molar ratio of 30:70 to 95:5. The polyamide resin is excellent in not only fuel-barrier property and heat resistance, but also moldability and recyclability, and therefore suitably used as a barrier material of fuel containers.
    Type: Grant
    Filed: May 4, 2004
    Date of Patent: May 30, 2006
    Assignee: Mitsubishi Gas Chemical Co., Inc.
    Inventors: Kazunobu Sato, Kazunobu Maruo, Jun Mitadera, Masashi Kurokawa
  • Patent number: 7045561
    Abstract: The present invention provides a decolorized red phosphorus composition capable of inhibiting coloring in dark red peculiar to red phosphorus even when kneaded with a resin or the like, modified red phosphorus used for the decolorized red phosphorus composition and a production method therefor, and a flame-retardant polymer composition using the decolorized red phosphorus composition. The modified red phosphorus includes red phosphorus particles (A) whose surfaces are coated with a modified resin film (F) containing white particles (B) having a whiteness of 70 or more, color particles (C) having a hue H of 30 to 80 in the Munsell color-system hue circle, and a binder resin (D). The decolorized red phosphorus composition includes a mixed powder containing the modified red phosphorus and white particles (B) having a whiteness of 70 or more. The flame-retardant polymer composition contains the decolorized red phosphorus composition and a polymer compound (I).
    Type: Grant
    Filed: July 15, 2003
    Date of Patent: May 16, 2006
    Assignee: Nippon Chemical Industrial Co., Ltd.
    Inventors: Yutaka Kinose, Akinori Inoue, Takahiro Nishita, Takahiro Nagayama
  • Patent number: 7026384
    Abstract: The invention relates to a process for the preparation of an aqueous dispersion of halogenated vinyl polymers by polymerization, according to which, after polymerization, a basic agent is added in an amount such that the pH of the aqueous dispersion is less than approximately 5. The invention also relates to the aqueous dispersion obtained, which can be coated onto polymeric substrates made of paper or of regenerated cellulose.
    Type: Grant
    Filed: February 24, 2004
    Date of Patent: April 11, 2006
    Assignee: SOLVAY (Société Anonyme)
    Inventors: Yves Vanderveken, Bernard Guenaire, Xavier Bacque
  • Patent number: 7026385
    Abstract: The invention relates to a clay-containing mixture or blend capable of forming a moisture resistant gel, which comprises a powdered or ground smectite and/or a smectite-containing natural rock and at least 0.8–10% by weight, calculated for the smectite content, of an at least partially water-soluble and/or water swellable polymer and optionally at least 0.5% by weight of a solid activating agent. Such a mixture may also additionally comprise as a diluting agent more than 0.5% by weight of one or more solid inert filler(s); this diluted version is termed in the specification as a blend.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: April 11, 2006
    Assignee: Trisoplast International B.V.
    Inventors: Jacobus Cornelis Wammes, Oszkar Libor
  • Patent number: 7019059
    Abstract: It has now been surprisingly found that addition of a phosphorous-containing oxy acid to a glass-filled polycarbonate composition substantially improves its fire retardant performance. Thus, the present invention provides a method for making a flame-retarded glass-filled polycarbonate resin comprising adding to the resin an effective flame-retardant amount of a phosphorous-containing oxy acid. Where appropriate, the melt strength of the polycarbonate is enhanced by the addition of an antidrip agent and the performance can be further enhanced by the addition of a flame retardant. Use of such a composition results in superior fire-retardant performance.
    Type: Grant
    Filed: August 1, 2003
    Date of Patent: March 28, 2006
    Assignee: General Electric Company
    Inventors: Ye-Gang Lin, Kapil Chandrakant Sheth, Rajendra Kashinath Singh
  • Patent number: 7012106
    Abstract: The present invention is directed to reinforced, biocompatible, biodegradable compositions suitable for use in implantable medical devices and medical devices made at least in part from such compositions, where the compositions include a biocompatible, biodegradable polymer; a biocompatible, biodegradable wax; and greater than about 30 weight percent of an inorganic filler material.
    Type: Grant
    Filed: March 28, 2003
    Date of Patent: March 14, 2006
    Assignee: Ethicon, Inc.
    Inventors: Jenny J. Yuan, Joseph H. Contiliano, Yufu Li, Zhigang Li, Mark B. Roller, Murty N. Vyakarnam
  • Patent number: 7001942
    Abstract: Articles and processes are provided whereby flame-retardant SAP particles are incorporated into synthetic resins, especially curable thermosettable resins. The SAP particles are most preferably hydrated with an aqueous flame-retardant solution. In this regard, the flame-retardant solution may consist essentially of water alone or a water solution containing one or more water soluble inorganic flame retardants. When SAP particles are hydrated with an aqueous inorganic flame retardant solution, the SAP particles may thereafter be dried to remove substantially the water component. In such a manner, the inorganic flame retardant will remain as a dried residue physically entrained within the SAP particles. As such, the SAP particles serve as a physical matrix in which the inorganic flame retardant is homogenously dispersed.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: February 21, 2006
    Assignee: Luna Innovations Incorporation
    Inventors: Martin E. Rogers, Pascal Deschatelets, Janice P. Phillips
  • Patent number: 7001858
    Abstract: Glass fiber which substantially has the following composition as represented by mol percentage and has a glass transition temperature higher than 300° C. and lower than 400° C.: Li2O+Na2O+K2O: 5 to 35%, P2O5: 20 to 27%, SO3: 3 to 20%, ZnO: 10 to 55%, MgO: 0 to 20%, ZnO+MgO: 10 to 55%, Al2O3: 1 to 5%, and B2O3: 8 to 20%.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: February 21, 2006
    Assignees: Asahi Glass Company, Limited, Asahi Fiber Glass Company, Limited
    Inventors: Hideki Nakagawa, Yoshiro Niino, Yoshinao Kobayashi
  • Patent number: 7001944
    Abstract: A mineral-filled, impact-resistant thermoplastic molding composition is disclosed. The composition contains at least one resin selected from the group consisting of polycarbonate and polyester carbonate B) impact resistance modifier, and C) wollastonite having carbon content greater than 0.1% relative to the weight of the wollastonite as determined by elemental analysis. Exhibiting high modulus of elasticity and a good toughness, in particular also at low temperatures, the composition is suitable for car body external applications.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: February 21, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Marc Vathauer, Andreas Seidel, Detlev Joachimi, Dieter Wittmann
  • Patent number: 6992127
    Abstract: A device containing a support member, a cross-linked polymer, and a pH buffer agent. A surface of the support member is coated with the cross-linked polymer in which the pH buffer agent is embedded.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: January 31, 2006
    Assignee: AST Products, Inc.
    Inventors: Tung-Liang Lin, Min-Shyan Sheu, Ih-Huong Loh
  • Patent number: 6989190
    Abstract: Disclosed is a transparent/translucent molding composition and process for making prepared from an impact modifier and a resin blend of polycarbonate and a cycloaliphatic polyester having a matching index of refraction.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: January 24, 2006
    Assignee: General Electric Company
    Inventors: Satish Kumar Gaggar, Johannes Jacobus de Moor, Paul Honigfort, Gabrie Hoogland, Mark van Heeringen, Eelco M. S. van Hamersveld