Phosphorus Atom Dnrm Patents (Class 524/414)
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Patent number: 6982288Abstract: A hardenable medical composition (preferably, dental composition) that includes an ionic redox polymerization system and at least one secondary ionic salt that includes a cation selected from the group consisting of a Group I ion, a Group II ion, an ammonium ion of the formula NR4+ wherein each R is H or a (C1–C4)alkyl group, and mixtures thereof.Type: GrantFiled: April 12, 2002Date of Patent: January 3, 2006Assignee: 3M Innovative Properties CompanyInventors: Sumita B. Mitra, Afshin Falsafi
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Patent number: 6951896Abstract: The invention relates to a flame-retardant thermoplastic composition which comprises at least (A) a thermoplastic polymer and (B) a flame-retardant system and which also contains (C) an n-alkanelactam-substituted polymer. Such a composition shows both a good flame retardancy, in particular a short afterflame time and little dripping, and also excellent mechanical properties. In particular, the n-alkanelactam-substituted polymer is a polyolefine, substituted with n-alkanelactam groups, with n being chosen from between 2 and 12. More in particular, the n-alkanelactam is polyvinyl pyrrolidone. Preferably, the thermoplastic polymer is a polycondensation polymer, in particular a polyamide, a polyester or a polycarbonate. Particularly suitable for use as the polyamide are PA-6, PA-6,6, PA-4,6 and semi-aromatic polyamides. The flame-retardant system may be both a halogen-containing and a halogen-free system.Type: GrantFiled: March 25, 2002Date of Patent: October 4, 2005Assignee: DSM IP Assets B.V.Inventor: Johannes H. G. Ottenheijm
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Patent number: 6949599Abstract: A clear blend of three resin components includes a first polycarbonate resin component; a second resin component of a first polyester copolymer resin derived from a cycloaliphatic diol and a cycloaliphatic dicarboxylic acid, and a third resin component of a second polyester polymer resin derived from the condensation of a cyclohexane diol with a terephthalic acid and an additional condensation reaction component selected from aliphatic or aromatic diacids or diols suitable for enhancing the clarity of said blend wherein the three component blend has a light transmission of seventy percent or greater and an elongation at break after exposure to Fuel C of forty percent or greater.Type: GrantFiled: August 28, 2003Date of Patent: September 27, 2005Assignee: General Electric CompanyInventors: Peter H. Th. Vollenberg, Gerrit de Wit
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Patent number: 6933328Abstract: A composition suitable for preparing a biodegradable implant, comprising a crosslinkable multifunctional prepolymer having at least two polymerizable end groups, the said composition having a viscosity such that it is deformable at a temperature of 0° to 60° C. into a three-dimensional shape and being crosslinkable within the said temperature range. The prepolymer comprises a hydrophilic region and/or the composition further comprises an effective amount of a mineral biologically-active component delivery system and/or a biocompatible degradable porosity-inducing component.Type: GrantFiled: April 3, 2001Date of Patent: August 23, 2005Assignee: Universiteit GentInventor: Etienne Honoré Schacht
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Patent number: 6930139Abstract: Coatings for agricultural grade fertilizer particles and industrial grade ammonium nitrate are provided which when applied to particles form a protective film which acts as a barrier to inhibit or prevent hydrocarbon infiltration of the fertilizer particle pores and also to physically separate the fertilizer particles and hydrocarbon materials. In so doing, the coating greatly reduces the efficacy of the fertilizer particles as an oxidizing agent for use in incendiary devices, thereby deterring or preventing the use of agricultural grade fertilizers or industrial grade ammonium nitrate in creating weapons of terror.Type: GrantFiled: January 24, 2003Date of Patent: August 16, 2005Assignee: Specialty Fertilizer Products, LLCInventors: John Larry Sanders, Grigory Mazo, Jacob Mazo
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Patent number: 6916872Abstract: Nanocomposites from nanofillers with preferred form of whiskers, rods, plates and fibers are disclosed. The matrix composition described includes polymers, ceramics and metals. The composition disclosed include inorganic, organic and metallic. These nanocomposites are useful in wide range of applications given their unusual properties such as refractive index, transparency to light, reflection characteristics, resistivity, permittivity, permeability, coercivity, B-H product, magnetic hysteresis, breakdown voltage, skin depth, curie temperature, dissipation factor, work function, band gap, electromagnetic shielding effectiveness, radiation hardness, chemical reactivity, thermal conductivity, temperature coefficient of an electrical property, voltage coefficient of an electrical property, thermal shock resistance, biocompatibility, and wear rate.Type: GrantFiled: May 30, 2003Date of Patent: July 12, 2005Assignee: NanoProducts CorporationInventors: Tapesh Yadav, Clayton Kostelecky
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Patent number: 6878765Abstract: A method for producing a component from a glass/polymer mixture where, a component is formed from a mixture of a thermoplastic with a processing temperature T1 and first glass particles with saturated surface bonds and a glass temperature T2<T1, at a temperature T3>T1. By melting the first glass particles, second glass particles are produced with surface bonds which can be saturated. The bonds are saturated by being bonded to the thermoplastic.Type: GrantFiled: December 13, 2000Date of Patent: April 12, 2005Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Angelo Polese
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Patent number: 6858300Abstract: The red phosphorus base flame retardant for an epoxy resin is provided, which has red phosphorus particles coated with a thermosetting resin containing an anhydrous zinc compound. The coated red phosphorus has properties that a slurry having the coated red phosphorus dispersed in 10% by weight into water at 20° C. has an electric conductivity of 30 ?s/cm or below, the slurry having been left standing at 80° C. for 20 hours has an electric conductivity of 150 ?s/cm or below, and when 80 ml of water is added to 8 g of the coated red phosphorus and heated at 80° C. for 20 hours, a concentration of PO4 ions eluted is 10 ppm or below.Type: GrantFiled: May 24, 2001Date of Patent: February 22, 2005Assignee: Nippon Chemical Industrial Co., LTDInventors: Yutaka Kinose, Ryohei Imamura, Akinori Inoue, Toru Hata, Eriko Okuno
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Patent number: 6846854Abstract: A method for preparing encapsulated red phosphorus is disclosed. The method entails obtaining a material system that contains dispersed particulate red phosphorus having a mean particle size of 0.1 to 100 ?m in an aqueous phase that comprise urea, formaldehyde and a water-soluble silicon dioxide precursor, adding to the material system a sufficient amount of acid to lower the pH to 0 to 5 and maintaining the resulting acidic system at a temperature of 80 to 120° C. for a period longer than one hour. The encapsulated red phosphorus of the invention is suitable for using as a flame retarding agent for plastics molding compositions.Type: GrantFiled: May 24, 2002Date of Patent: January 25, 2005Assignee: Bayer AktiengesellschaftInventors: Michael Wagner, Wolfgang Podszun, Henricus Peerlings
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Patent number: 6841651Abstract: The polyamide resin of the present invention is produced by polycondensation of a diamine component comprising 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component comprising 70 mol % or more of a C4-C20 ?, ?-straight-chain aliphatic dicarboxylic acid in the presence of at least one phosphorus compound selected from the group consisting of phosphinic acid compounds and phosphonous acid compounds and in the presence of an alkali metal compound of a weak acid. The weak acid has a dissociation constant lower than a first dissociation constant of a dicarboxylic acid mainly constituting the polyamide resin. The polyamide resin satisfies the following requirements (A), (B) and (C): 14000?a?40000??(A) b?1.000??(B) 0.9930?b?1.1a2×10?11+3.2a×10?7?0.9980??(C) wherein a and b are as defined in the disclosure.Type: GrantFiled: April 8, 2003Date of Patent: January 11, 2005Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kazunobu Maruo, Tomomichi Kanda, Koji Yamamoto
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Patent number: 6838504Abstract: The invention provides polymeric matrices and films comprising fixation reagents that are capable of reacting with solubilized metals to form less soluble metal compounds. The fixation reagenst may include inorganic sulfides and phosphates, as well as adsorbents. The polymeric matrices may be comprised of polyvinyl alcohols and polyvinyl acetates. In some embodiments, the polymeric matrix is selected to be at least as soluble as the selected fixation reagent, particularly under the conditions in which the matrix is expected to come into contact with the solublized metal.Type: GrantFiled: May 6, 1999Date of Patent: January 4, 2005Assignee: Solucorp Industries Ltd.Inventors: William C Webster, Peter Hurley
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Publication number: 20040249039Abstract: The purpose of the invention is a coating precursor comprising a silicone resin, a mineral filler and an organic solvent capable of dissolving the said resin and putting the said mineral filler into suspension, the said silicone resin and the said mineral filler being capable of chemically reacting so as to produce a solid layer on a substrate after the organic solvent has evaporated and a cohesive refractory layer after a calcination operation. Another purpose of the invention is a method for coating a given surface of a substrate with at least one refractory layer containing silicon in which the substrate is coated with a coating precursor according to the invention so as to form a green layer and a heat treatment is carried out to calcine the said green layer and to form a cohesive refractory layer. The invention is a means of obtaining a protective coating capable of resisting oxidising environments, liquid metal and solid or molten salt.Type: ApplicationFiled: July 8, 2004Publication date: December 9, 2004Inventors: Airy-Pierre Lamaze, Christian Barthelemy, Thomas Spadone, Robert Rey-Flandrin
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Publication number: 20040249036Abstract: The present invention provides a coating that includes a thermoplastic resin having a glass transition point of more than 100° C. and an acid value of from 20 to 350 mg-KOH/g, a metallic soap of metal stearate, an anti-galling agent, and a surface-treated metal sheet having a film of this coating. The coating according to the present invention has the superior durability of the film, in particular, wear resistance and peel resistance. The surface-treated metal sheet having the film of this coating has superior press formability, in particular, galling resistance and lubricity, and further, a temporary antirust property and alkaline solubility of the film even in a high temperature environment caused by severe ironing.Type: ApplicationFiled: March 25, 2004Publication date: December 9, 2004Inventors: Kazuhiko Higai, Kazuaki Kyono
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Publication number: 20040235989Abstract: The invention relates to thickened aqueous compositions which comprise xanthan gum and a water-softening polymer.Type: ApplicationFiled: March 2, 2004Publication date: November 25, 2004Inventors: Mike Kosub, Fabio Corradini
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Patent number: 6790882Abstract: Machine elements such as bearings and toothed wheels, which consist of a thermoplastic-based glass/plastic compound containing a sulfophosphate glass with a low melting point and with the following composition: 4 to 10% Li2O, 4 to 10% Na2O, 4 to 8% K2O, 1 to 2% CaO, 35 to 37% ZnO, 0 to 3% La2O3, 19 to 22% P2O5 and 19 to 22% SO3; and a high performance thermoplastic.Type: GrantFiled: October 2, 2002Date of Patent: September 14, 2004Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Heinrich Kapitza, Manfred Ochsenkuehn
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Publication number: 20040176506Abstract: The invention relates to novel fusible zinc phosphinates of the formula (I) and/or polymers thereof 1Type: ApplicationFiled: March 4, 2004Publication date: September 9, 2004Applicant: Clariant GmbHInventors: Martin Sicken, Elke Schlosser, Wolfgang Wanzke, Detlef Burghardt
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Publication number: 20040167265Abstract: A water- and oil-repellent, antistatic composition comprises (a) at least one nonpolymeric ionic salt consisting of (i) at least one cation selected from the group consisting of monovalent metal cations, divalent metal cations, and organic onium cations, and (ii) at least one weakly coordinating anion, the conjugate acid of the anion having an acidity greater than or equal to that of a hydrocarbon sulfonic acid, and with the proviso that the anion is organic or fluoroorganic when the cation is a metal; (b) at least one fluorochemical repellency-imparting additive or repellent; and (c) at least one insulating material.Type: ApplicationFiled: February 24, 2004Publication date: August 26, 2004Applicant: 3M Innovative Properties CompanyInventors: Delton R. Thompson, Thomas P. Klun, William M. Lamanna
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Patent number: 6780963Abstract: The polyamide resin composition of the invention is characterized by having a solder reflow heat-resistant temperature of not lower than 250° C. Since the polyamdie resin composition has low water absorption and is excellent in moldability, heat resistance, shape stability and mechanical strength, it can be suitably used for, for example, automobile parts and electric or electronic parts.Type: GrantFiled: August 21, 2002Date of Patent: August 24, 2004Assignee: Mitsui Chemicals, Inc.Inventors: Masahiro Sawada, Kunihiro Ohuchi
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Patent number: 6770694Abstract: The present invention provides a powder coating composition for forming a multilayer film, obtainable by dry blending a lower layer-forming thermosetting powder coating material (A) and an upper layer-forming thermosetting powder coating material (B), wherein at least one of the following conditions is satisfied: (I) the material (A) contains an onium salt compound; (II) particles of 45 &mgr;m or smaller diameter account for at least 90 wt. % of each of the materials (A) and (B); and (III) the material (A) is higher than the material (B) in melt viscosity (Pa·s) measured at 130° C. The powder coating composition of the invention is capable of sufficiently separating into layers and forming a multilayer film with excellent properties.Type: GrantFiled: April 22, 2002Date of Patent: August 3, 2004Assignee: Kansai Paint Co., Ltd.Inventors: Kazuhiko Ohnishi, Isamu Takabayashi, Masami Kobata
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Publication number: 20040147654Abstract: The present invention provides a resin composition having excellent dispersibility, discoloration resistance and antimicrobial properties by blending a resin (A) with an antimicrobial agent (B) in which at least one kind of metal ion selected from the group consisting of silver, copper, zinc, and tin is supported on zeolite, and an antimicrobial agent (C) that includes a silver ion-containing phosphate as an active ingredient, or an antimicrobial agent (D) made of a soluble glass powder containing silver ion.Type: ApplicationFiled: January 23, 2003Publication date: July 29, 2004Applicants: Kanebo Limited, Kanebo Chemical Industries, LtdInventor: Yoshikazu Kimura
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Patent number: 6767949Abstract: The invention relates to a composition comprising, a) at least one oligomer, cooligomer, polymer or copolymer or blends thereof, containing a stable free nitroxyl radical (1); and b) a reducing agent; with the proviso that the composition is essentially free of a polymerizable monomer.Type: GrantFiled: May 22, 2002Date of Patent: July 27, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Rudolf Pfaendner, Michael Roth, Wiebke Wunderlich
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Patent number: 6765047Abstract: A method for microencapsulating red phosphorus in polymerized urea resorcinol formaldehyde resin is disclosed. The method entails (i) preparing an aqueous mixture containing urea, resorcinol and formaldehyde, (ii) adding hexamethylene tetramine and optionally water to the mixture to yield a stabilized mixture (iii) dispersing red phosphorus in the to the stabilized mixture (iv) adding acid to the reaction mixture, and (v) collecting the resulting encapsulated red phosphorus. The product is suitable as flame retarding agent in molding compositions.Type: GrantFiled: May 24, 2002Date of Patent: July 20, 2004Assignee: Bayer AktiengesellschaftInventors: Henricus Peerlings, Michael Wagner, Wolfgang Podszun
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Patent number: 6765046Abstract: Products based on polymethylmethacrylate (PMMA) so resistant to yellowing and so highly transparent that even the edges of plates produced from this material have a neutral colour, i.e. do not display any yellow tone. This effect is obtained by the admixture of 5 to 50 ppm inorganic, reducing phosphorus compounds after polymerisation. This enables the brightener content to be reduced under 10 ppb, and so the end product may also be used in contact with foodstuffs.Type: GrantFiled: September 3, 1999Date of Patent: July 20, 2004Assignee: Roehm GmbH & Co. KGInventors: Uwe Numrich, Michael Wicker, Klaus Albrecht, Heinz Vetter, Hermann Jaksch, Ernst Mohr
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Patent number: 6762219Abstract: A glass/plastic compound based on thermoplastics includes a low-melting sulphoshosphate glass with the following composition: between 4 and 10% Li2O, between 4 and 10% Na2O, between 4 and 8% K2O, between 1 and 2% CaO, between 35 and 37% ZnO, between 0 and 3% La2O3, between 19 and 22% P2O5 and between 19 and 22% SO3, in addition to a high-performance thermoplastic.Type: GrantFiled: October 21, 2002Date of Patent: July 13, 2004Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Heinrich Kapitza, Manfred Ochsenkuehn, Angelo Polese
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Publication number: 20040127620Abstract: A reactive coating composition and method for treating a surface including heavy metals by applying the reactive coating composition to the surface. The surface can be, for example, a paint layer containing heavy metals. The reactive coating composition includes a stabilizing agent to stabilize the heavy metal and a permeability enhancing agent to increase the permeability of the paint layer, facilitating the reaction of the heavy metal with the stabilizing agent. The structure including the treated paint layer can be left in place or can be disposed in a non-hazardous landfill.Type: ApplicationFiled: December 12, 2003Publication date: July 1, 2004Inventors: James Barthel, Mark A. Peters
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Patent number: 6753363Abstract: A polyacetal resin composition of high flame retardancy and stability comprises a polyacetal resin, a flame retardant, and a basic nitrogen-containing compound (urea, amidine, aminotriazine, hydrazine, derivatives thereof, amide, urethane). The flame retardant may comprise an aromatic compound reactive to formaldehyde and a phosphorus-containing compound (e.g., red phosphorus, organic phosphonates, organic phosphinates, ammonium polyphosphate, and other phosphoric acid salts, phosphates), and the aromatic compound may be a hydroxyl group and/or amino group-containing compound or an aromatic ring-containing resin (e.g., novolak resins, aralkyl resins, vinylphenol resins, aniline resins, aromatic nylon resins, polycarbonate resins, polyarylate resins, aromatic epoxy resins, aromatic polyether resins). The ratio of the phosphorus-containing compound per 100 parts by weight of the aromatic compound is 1 to 500 parts by weight.Type: GrantFiled: March 8, 2001Date of Patent: June 22, 2004Assignee: Polyplastics Co., Ltd.Inventor: Hatsuhiko Harashina
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Publication number: 20040097619Abstract: Polymeric substrates, for example polyolefins such as polypropylene, can be made flame retardant by the incorporation therein of a synergistic mixture of (i.) at least one compound selected from the group consisting of nitroxyl stabilizers, hydroxylamine stabilizers, nitrone stabilizers, substituted hydroxylamine stabilizers, amine oxide stabilizers, benzofuranone stabilizers phosphite and phosphonite stabilizers, quinone methide stabilizers and monoacrylate esters of 2,2′- alkylidenebisphenol stabilizers and (ii.) at least one compound selected from the group consisting of brominated flame retardants, phosphorus containing flame retardants and inorganic flame retardants such as ammonium polyphosphate or decabromodiphenyl oxide; wherein the amount of organic or inorganic flame retardant of component (ii.) required to achieve an acceptable level of flame retardancy is significantly reduced compared to that needed when component (i.) is not present.Type: ApplicationFiled: September 16, 2003Publication date: May 20, 2004Inventors: Malisa V. Troutman, Ramanathan Ravichandran, Rangarajan Srinivsan, Roswell Easton King, Douglas Wayne Horsey
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Publication number: 20040096475Abstract: A calcium phosphate-synthetic resin composite body produced by pressing a calcium phosphate block (or a calcium phosphate block and calcium phosphate particles), and synthetic resin particles I, which are at least partially cross-linked in advance, and uncross-linked, synthetic resin particles II while heating, the calcium phosphate block being exposed on at least part of the surface of the composite body. The above composite body is produced by a method comprising the steps of (a) introducing the calcium phosphate block (or a calcium phosphate block and calcium phosphate particles), the synthetic resin particles I and II into a cavity of a forming die such that the calcium phosphate block is present on at least part of the surface of the composite body, and that the synthetic resin particles surround the calcium phosphate particles, if any; and (b) pressing them in the cavity of the forming die while heating, so that the synthetic resin particles are bonded to each other.Type: ApplicationFiled: July 9, 2003Publication date: May 20, 2004Applicant: PENTAX CorporationInventors: Tsuneo Hiraide, Yukio Kubota
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Patent number: 6737462Abstract: The invention relates to thermally stable, weather-resistant polyamide moulding compositions containing as stabiliser, a mixture of a copper halide, one or more halogen compounds and hypophosphorous acid or an alkali metal or alkaline earth metal salt of this acid, wherein the individual components of the stabiliser mixture are added in an amount such that the molar amount of halogen contained in the moulding composition is greater than or equal to six times the molar amount of and less than or equal to fifteen times the molar amount of copper contained in the moulding composition and the molar amount of phosphorus is greater than or equal to the molar amount of and less than or equal to ten times the molar amount of copper contained in the moulding composition.Type: GrantFiled: November 20, 2001Date of Patent: May 18, 2004Assignee: Bayer AGInventors: Andreas Gittinger, Aziz El-Sayed, Edgar Ostlinning, Ralf Lange
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Patent number: 6734243Abstract: A component (1) which includes a material formed from a glass/polymer mixture. The component has first regions, in which the glass is present substantially in the form of spherical particles (2) and second regions, in which the glass is present in the form of fibre-type particles (3). A component of this type advantageously provides both mechanical stability and dimensional consistency in separate areas within the same component.Type: GrantFiled: November 1, 2002Date of Patent: May 11, 2004Assignee: Siemens AktiengesellschaftInventors: Robert Greiner, Angelo Polese
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Publication number: 20040063815Abstract: The present invention provides a decolorized red phosphorus composition capable of inhibiting coloring in dark red peculiar to red phosphorus even when kneaded with a resin or the like, modified red phosphorus used for the decolorized red phosphorus composition and a production method therefor, and a flame-retardant polymer composition using the decolorized red phosphorus composition. The modified red phosphorus includes red phosphorus particles (A) whose surfaces are coated with a modified resin film (F) containing white particles (B) having a whiteness of 70 or more, color particles (C) having a hue H of 30 to 80 in the Munsell color-system hue circle, and a binder resin (D). The decolorized red phosphorus composition includes a mixed powder containing the modified red phosphorus and white particles (B) having a whiteness of 70 or more. The flame-retardant polymer composition contains the decolorized red phosphorus composition and a polymer compound (I).Type: ApplicationFiled: July 15, 2003Publication date: April 1, 2004Inventors: Yutaka Kinose, Akinori Inoue, Takahiro Nishita, Takahiro Nagayama
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Publication number: 20040054053Abstract: The polyester-based resin composition of the present invention comprises a polyamide resin, a polyester resin containing an antimony compound and a compound selected from the group consisting of inorganic acid salts and hydroxides of group-1 or -2 metals of the periodic table and transition metals. In the polyester-based resin composition, the phosphorus atom concentration, the antimony atom concentration, and the blending ratio of the inorganic acid salt or hydroxide to the phosphorus compound are regulated so as to satisfy the specific relationships to effectively prevent the darkening due to the deposition of antimony metal, thereby providing the polyester-based resin composition having excellent gas barrier properties and a good appearance with minimized darkening.Type: ApplicationFiled: September 12, 2003Publication date: March 18, 2004Inventor: Akira Mori
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Patent number: 6699923Abstract: A flame-retardant polyacetal resin composition comprising 60 to 90% by weight of a polyacetal resin, 1 to 30% by weight of red phosphorus, 1 to 40% by weight of at least one resin selected from phenol resins and polycarbonate resins, and 0.1 to 5% by weight of a metal salt of a fatty acid. The polyacetal resin composition of the present invention is provided with flame retardancy while maintaining the excellent innate properties of polyacetal resins, so that it can be applied to the fields where the use of polyacetal resins has been restricted.Type: GrantFiled: May 23, 2001Date of Patent: March 2, 2004Assignee: Asahi Kasei Kabushiki KaishaInventors: Yukio Tanigawa, Hidehiko Yamatou
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Publication number: 20040010065Abstract: An object of the present invention is to provide a discoloration inhibitor for metals, for protecting metal artifacts, such as those made of silver, copper, and nickel, or their alloys, from discoloration due to sulfur-containing gases such as sulfur oxide (SOx), mercaptans, and hydrogen sulfide, for example, during display or storage of the metal artifacts. A discoloration inhibitor for metals comprising: a fiber having a crosslinking structure and containing carboxyl groups therein, at least part of said carboxyl groups being present as a salt of an alkali metal, an alkali earth metal or ammonia; and fine particles of a metal and/or a metal compound substantially insoluble in water and reactive with a sulfur-containing compound dispersed in said fiber is disclosed.Type: ApplicationFiled: July 11, 2003Publication date: January 15, 2004Inventors: Noriyuki Kohara, Hideyuki Tsurumi
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Publication number: 20040006168Abstract: A flame retardant molding composition is disclosed. The composition that contains a polymeric component, preferably a polyamide, red phosphorus, zinc borate, talcum and a lanthanide compound, is characterized by its combined flame resistance and good mechanical properties. The composition may also contain fillers or reinforcing substances, an impact modifier and further conventional additives.Type: ApplicationFiled: May 29, 2003Publication date: January 8, 2004Inventors: Michael Wagner, Jochen Endtner, Henricus Peerlings, Peter Persigehl
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Patent number: 6673866Abstract: A polymer composition formed by: I) fluoropolymers selected from one or more of the following: copolymers based on ethylene, TFE and/or CTFE modified with hydrogenated monomers, or blends of these fluoropolymers with PCTFE; said fluoropolymers and/or the corresponding blends optionally mixed with hydrogenated plasticizers; II) one or more inorganic fire-retardants, treated and not with dispersing agents; III) one or more crosslinking agents; IV) optional additives.Type: GrantFiled: September 26, 2001Date of Patent: January 6, 2004Assignee: Ausimont S.p.A.Inventors: Mikhail Zolotnitsky, Julio A. Abusleme
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Patent number: 6660792Abstract: A thermoplastic composition, such as PET, contains an inert iron compound such as FeP, FeSi, or combinations thereof, having no chemical activity in the PET, with or without certain quantities of elemental metals, such as antimony, and a reducing agent or other stabilizer such as phosphite or phosphoric acid. A method for forming this composition is also disclosed. The composition may also optionally contain a color stabilizer, a DEG inhibitor and stress crack inhibiting agents.Type: GrantFiled: December 14, 2000Date of Patent: December 9, 2003Assignee: M & G USA CorporationInventors: Freddie Lee Massey, George Aaron Deisz, Kevin Rollick, William C. Tung
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Patent number: 6656377Abstract: A coagulant which is the reaction product of a trivalent metal salt, excluding chromium salts, an acid phosphorous compound and an aluminum hydroxy chloride, and a process for preparing such coagulant. This coagulant may be effectively used to remove suspended solids and various impurities in most water treatment applications.Type: GrantFiled: May 21, 2001Date of Patent: December 2, 2003Assignee: Calgon CorporationInventors: Denis E. Hassick, Michael P. Flaherty, Pamela J. Dotter, Robert J. Guerrini
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Patent number: 6649674Abstract: A flame-proof polyester molding compositions is disclosed. The composition that exhibits good flame-resistance, particularly in thin-walled moldings, contains red phosphorus, nitrogen-containing compounds and a small amount of a hydrotalcite. The composition is particularly suitable for the preparation of moldings, sheeting and fibers.Type: GrantFiled: June 24, 2002Date of Patent: November 18, 2003Assignee: Bayer AktiengesellschaftInventors: Michael Wagner, Henricus Peerlings
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Patent number: 6642294Abstract: A mixture Ia comprises a mix IIa composed of a) from 1 to 95% by weight of a solid III, preferably a basic solid III, with a primary particle size of from 5 nm to 20 &mgr;m and b) from 5 to 99% by weight of a polymeric composition IV, obtainable by polymerizing b1) from 5 to 100% by weight, based on the composition IV, of a condensation product V of &agr;) at least one compound VI which is capable of reacting with a carboxylic acid or with a sulfonic acid or with a derivative or a iixture of two or more of these, and &bgr;) at least 1 mol per mole of the compound VI of a carboxylic acid or sulfonic acid VII which has at least one functional group capable of free-radical polymerization, or of a derivative thereof or of a mixture of two or more thereof and b2) from 0 to 95% by weight, based on the composition IV, of another compound VIII with an average molecular weight (number average) of at least 5000 having polyether segments in its main or side chain and at least one ester of the formula (E1) to (E5)Type: GrantFiled: July 17, 2000Date of Patent: November 4, 2003Assignee: BASF AktiengesellschaftInventors: Stephan Bauer, Bernd Bronstert, Helmut Möhwald, Hans-Josef Sterzel, Werner Hesse
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Patent number: 6639045Abstract: A method of producing an aliphatic polyester, including polycondensing an aliphatic diol and an aliphatic dicarboxylic acid compound, or a prepolymer thereof in the presence of a metal-containing ester interchange catalyst and a phosphorus-containing co-catalyst such as an ammonium, calcium or magnesium salt of hydrogen-containing phosphoric acid or an organic phosphinic acid. An oxycarboxylic acid compound or its prepolymer may also be used as a raw material.Type: GrantFiled: September 6, 2001Date of Patent: October 28, 2003Assignees: National Institute of Advanced Industrial Science and TechnologyInventors: Takashi Masuda, Amin Cao
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Publication number: 20030197159Abstract: A red phosphorus base flame retardant for an epoxy resin, which can suppress oxo acid of phosphorus from eluting from red phosphorus and can impart remarkable flame retardancy to an epoxy resin for a semiconductor sealing material. The red phosphorus base flame retardant for an epoxy resin comprises coated red phosphorus which has the surface of red phosphorus particles coated with a thermosetting resin containing an anhydrous zinc compound or the surface of red phosphorus particles coated with an inorganic substance and further coated with a thermosetting resin containing an anhydrous zinc compound. The coated red phosphorus has properties that a slurry having the coated red phosphorus dispersed in 10% by weight into water at 20° C. has an electric conductivity of 30 &mgr;s/cm or below, the slurry having been left standing at 80° C. for 20 hours has an electric conductivity of 150 &mgr;s/cm or below, and when 80 ml of water is added to 8 g of the coated red phosphorus and heated at 80 ° C.Type: ApplicationFiled: November 18, 2002Publication date: October 23, 2003Inventors: Yutaka Kinose, Ryohei Imamura, Akinori Inoue, Toru Hata, Eriko Okuno
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Patent number: 6632917Abstract: A preblended additive composition and process for the preparation of polyester resins useful in the manufacture of plastic containers such as bottles is disclosed. The additive composition includes a cobalt-containing compound that is preblended with a phosphorous compound. The polyester resin, e.g., a PET resin, may be prepared by reacting ethylene glycol with dimethyl terephthalate (DMT) or terephthalic acid (TA) in an esterification reaction. The additive composition may be prepared by quickly dumping the phosphorus compound into the cobalt compound such as cobalt acetate, and the resulting composition is added to the reactor vessel before the polycondensation reaction. On the other hand, the additive composition may be prepared by slowly dumping the phosphorus compound into the cobalt compound over a period of at least 5 minutes. Such preblending substantially eliminates any yellow or blue color, or haze in the product article.Type: GrantFiled: June 2, 2000Date of Patent: October 14, 2003Assignee: Arteva North America S.A.R.L.Inventors: Rehka V. Kulkarni, Ligia Dominguez
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Patent number: 6630526Abstract: Flame-retardant mixture comprising: a) a polymer composition b) a phosphorus-containing compound c) a triazine flame retardant, the weight ratio of a, b and c lying between 94:1:5 and 35:30:35, the triazine flame retardant comprising at least: c1) 1-95 wt. % melem, c2) 0.01-25 wt. % melam, c3) 0.01-20 wt. % melamine, c4) 0.1-95 wt. % higher condensation products of melamine and/or of melem, the wt. % being relative to the total of c1) up to and including c4) and together amounting to 100%, and the concentration of volatile components in the flame retardant being at most 5 wt. %. Also a process for the preparation of the triazine flame retardant.Type: GrantFiled: March 21, 2002Date of Patent: October 7, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Wouter Heinen, Maurits F. H. Van Tol, Renier H. M. Kierkels, Gerhard Van Vliet
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Publication number: 20030187118Abstract: The present invention provides a composition for use in forming an abrasion-resistant easy-to-clean coating on a substrate. The composition according to the invention includes a mixture of a fluorocarbon polymer component and an enamel-forming component. The enamel-forming component includes at least a first lead-free and cadmium-free glass frit. The first lead-free and cadmium-free glass frit includes from about 30% to about 50% P2O5, from about 15% to about 30% Al2O3, and from about 2% to about 40% X2O where X=Na and/or K. The present invention also provides a method of forming an abrasion-resistant easy-to-clean coating on a substrate. The method includes applying the composition according to the invention to a substrate and sintering the applied composition to fuse an abrasion-resistant easy-to-clean coating to the substrate.Type: ApplicationFiled: May 16, 2003Publication date: October 2, 2003Inventors: Alain Aronica, David Coutouly, Damian Macaya, Remy Caisse
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Publication number: 20030175541Abstract: A conductive and weldable anti-corrosion composition for coating metal surfaces which contains:Type: ApplicationFiled: November 6, 2002Publication date: September 18, 2003Inventors: Wolfgang Lorenz, Andreas Kunz, Eva Wilke
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Publication number: 20030168631Abstract: In the process for producing an oxygen absorbing polyamide resin composition of the present invention, a diamine component containing 70 mol % or higher of m-xylylenediamine is polycondensed with a dicarboxylic acid component containing 50 mol % or higher of adipic acid in the presence of a phosphorus compound. A compound or complex containing at least one metal selected from the group consisting of transition metals of Group VIII of the Periodic Table, manganese, copper and zinc is added to reaction system either prior to initiation of the polycondensation reaction or during the polycondensation reaction such that a ratio (P/M) of a concentration of phosphorus P (mmol/g) in the phosphorus compound contained in the polyamide resin composition to a concentration of the metal M (mmol/g) in the polyamide resin composition is 0.02 to 1.0.Type: ApplicationFiled: March 11, 2003Publication date: September 11, 2003Inventors: Ryoji Otaki, Sotaro Hiramatsu
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Patent number: 6617381Abstract: Disclosed is a polyamide resin composition, a method for producing the composition, and articles from the composition. The polyamide resin composition polyamide resin composition is formed by melt-kneading (A) 100 parts by weight of nylon resin, and (B) 5-150 parts by weight of at least one of a non-fibrous inorganic filler having an average particle diameter of 0.05-10 &mgr;m and a fibrous inorganic filler, excluding glass fiber, having a fiber diameter of 0.05-10 &mgr;m. In the polyamide resin composition, an amount of a polyamide resin component deposit remaining on the inorganic filler when the inorganic filler is recovered by dissolving the polyamide resin composition into hexafluoroisopropanol is at least 4 g/m2 per unit surface area of the inorganic filler measured by a BET method. The nylon resin composition is excellent in rigidity and toughness and particularly excellent in high-speed surface impact fracture characteristic.Type: GrantFiled: March 4, 1998Date of Patent: September 9, 2003Assignee: Toray Industries, Inc.Inventors: Jiro Kumaki, Mitsunari Sotokawa, Kouzou Murata, Koya Kato
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Publication number: 20030166755Abstract: The invention relates to comb polymers and macromonomers based on acrylates prepared by the ATRP (Atom Transfer Radical Polymerization) method. These polymers have an improved capability of dispersing pigments in the given solvent. The invention also relates to compositions comprising the comb polymers and macromonomers dispersible inorganic or organic pigment particles. The compositions are used by applying them to any suitable substrate, for example to metal, wood plastic or ceramic materials.Type: ApplicationFiled: July 10, 2002Publication date: September 4, 2003Inventors: Andreas Muhlebach, Francois Rime, Clemens Auschra, Ernst Eckstein
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Publication number: 20030158302Abstract: Self-forming hybrid compositions consisting in admixed liquid and solid components enable the formation of bio-materials. The present invention proposes a) a thermo-sensitive self-forming liquid component, being water-based and containing at least a polycationic polymer such as chitosan, and an organic mono-phosphate source, which is a solution at a pH ranging from 6.5 to 7.4; b) a solid component being mineral and composed of at least one of calcium, fluoride, strontium, carbonate and phosphate salts. Solid mineral salts preferentially have a recognized bioactive potential such as the calcium phosphate salts for bones. Both solid and liquid components are admixed to form an injectable liquid slurry or pre-gelled paste that turn in situ into a hybrid uniform gel-like bio-material.Type: ApplicationFiled: December 3, 2002Publication date: August 21, 2003Inventors: Cyric Chaput, Abdellatif Chenite