Abstract: Moldable compositions comprising metallic powder or combination thereof with ceramic powder, mixed an organic binder are disclosed, at least a part of which comprises a synthetic resin component (A) having a heat deformation temperature of 130.degree. C. or higher. The component A may be used in combination with another component (B) having a melting point of 30.degree. C.-100.degree. C., with or without another thermoplastic component (C), having a heat deformation temperature of 13.degree. C. or less. Moldable compositions, comprising metallic and/or ceramic powder mixed with an organic binder comprising a secondary or tertiary amine (D), or combination thereof with a thermoplastic resin (E), are also disclosed.

Abstract: An aqueous crosslinking resin composition comprising (I) an aqueous resin dispersion obtained by emulsion polymerization of a monomer mixture consisting of (a) 2 to 50% by weight of an unsaturated carboxylic acid monomer, (b) 0.

Abstract: In a ceramic or powder metallurgical molding compound which contains waxes as binder, the addition of an ethylene-vinyl acetate copolymer, an organic peroxide, an azo ester and an alcohol in combination with an extraction with a solvent leads to an improvement in the dimensional stability and the dewaxing of injection-molded shaped parts.

Abstract: An intumescent fire-resistant coating and a fire-resistant material using the same are disclosed, the coating essentially including (A) at least one inorganic compound selected from the group consisting of a carbide, boride, nitride, carbonitride, or carboboride of titanium, zirconium, vanadium, niobium, tantalum, molybdenum, tungsten, silicon or chromium and a carbide, nitride or carbonitride of boron, (B) a synthetic resin, and (C) at least one phosphorus and/or sulfur compound capable of forming a Lewis acid on heating.

Abstract: There are disclosed a vinyl resin composition which comprises a resin composition comprising a vinyl polymer, a polyamideimide elastomer obtained by reacting a mixture of caprolactam, an aromatic polycarboxylic acid and a specified polyoxyethylene glycol, with 0-0.5 mole of a diamine, etc., per 1 mole of glycol contained in said mixture, the glycol component being present in a proportion of 85-30% by weight in said elastomer and the relative viscosity of the elastomer being at least 1.5 (at 30.degree. C.), and an electrolyte added as desired, and articles molded from the composition.

Abstract: An aqueous coating composition for applying a print retaining antistatic layer consisting essentially of an aluminum modified colloidal silica and an antistatic agent in a binder polymer, the binder polymer consisting essentially of an addition product of from about 30 to 78 mol % of an alkyl methacrylate wherein the alkyl group has from 3 to 8 carbon atoms, from about 2 to about 10 mol % of an alkali metal salt of an ethylenically unsaturated sulfonic acid and from 20 to about 65 mol % of a vinyl benzene, the polymer having a glass transition point of from 30.degree. to 65.degree. C.

Abstract: An aqueous dispersion of ceramic materials and a method for preparing the same are provided. The method involves dispersing ceramic materials using one or more polymeric dispersants. The polymeric dispersants have monomer composition of from about 20 to about 95 percent by weight of one or more carboxylic acid monomers or salts thereof, from about 5 to about 80 percent by weight of one or more sulphonic acid or phosphonic acid monomers or salts thereof, and from about 3 to about 20 percent one or more monoethylenically unsaturated acid-free monomers.

Abstract: The invention relates to thermoplastically shapeable mixtures of COOH group-containing polymers dissolvable in an aqueous neutral or aqueous-alkaline medium with fillers. Such mixtures can be processed by thermoplastic shaping to moulded articles, which are dissolvable after use. The invention also relates to suitable copolymers for this purpose and the use thereof for the production of moulded articles.

Abstract: A powder mixture of aluminium nitride in the form of sintered agglomerates with fractions of different particle size, which mixture comprises (1) 80 to 50% by weight of aluminium nitride in the form of sintered agglomerates having a mean particle diameter of 30 to 50 .mu.m, and (2) 20 to 50% by weight of aluminium nitride in the form of unsintered particles and having a mean particle diameter of 0.1 to 5 .mu.m. The mixture is suitable for use as filler for polymer materials, especially for casting resins, from which moulded parts of high thermal conductivity can be fabricated, for example potted electronic components.

Abstract: Graft polysaccharides comprising a polymer backbone consisting essentially of a polydextrose having an average-weight molecular mass of less than 10,000 and grafts grafted thereon derived from a water-soluble ethylenically unsaturated monomer. The graft polysaccharides are useful as sequestering agents for alkaline-earth metal ions.

Abstract: An electro-responsive elastomeric material comprising (A) an electrically insulating polymer having a specific modulus of elasticity and (B) a fine powder dispersed in the polymer which electrically polarizes under an electric field independent of water changes its viscoelasticity upon voltage application. The powder has a mean particle size of 0.5 to 500 .mu.m and is (1) a fine carbonaceous powder having a C/H atomic ratio of from 1.2 to 5, (2) composite particles having minute particulates of an insulating material dispersed in a matrix phase of a carbonaceous or carbide material, (3) composite particles having minute particulates of a carbonaceous or carbide material dispersed in a matrix phase of an insulating material, or (4) a fine composite powder of a stratum clay mineral having a two-dimensional stratum structure with a carbonaceous or carbide material incorporated between the strata.

Abstract: Thermally conductive particles (14) for use in a polymeric resin are provided. The particles (10) are aluminum nitride coated with copper (12). The thermally conductive particles (14) are incorporated into a polymer (38) in order to provide, for example, a thermally conductive adhesive (36). The thermally conductive adhesive is used to bond an electronic component (32) to a circuit carrying substrate (34) in order to dissipate heat from the electronic component.

Abstract: NH.sub.4 Cl is used as a nucleating agent to prepare polyhydroxyalkanoate compositions.

Abstract: The depolymerization of poly(hydroxyacids) in a liquid medium is enhanced by the presence of a quaternary ammonium compound. Poly(hydroxyacid) polymers containing a quaternary ammonium salt are more readily depolymerized.

Abstract: Preceramic compositions which have particular utility in providing protective ceramic coatings on normally oxidizable materials, such as carbon/carbon and other carbon-containing composites and other materials, are obtained by dispersing solid particles comprising aluminum nitride particles in an organic solvent solution of a polysilazane. Ceramic coatings derived from the dispersions may serve as intermediate strata in multilayer ceramic coatings over substrates, such as carbon/ carbon composites, to provide even greater protection to the substrates, even when exposed to humidity.

Abstract: In a ceramic or powder-metallurgical molding composition which contains waxes as binders, the addition of an ethylene/vinyl acetate copolymer, optionally in combination with an organic peroxide and an azo ester and crosslinking of the binder, leads to an improvement in the dimensional stability and the dewaxing of injection-molded moldings.

Abstract: The composition of the present invention is composed of finely divided solid refractory material suspended in a nonaqueous liquid slip composition. The nonaqueous liquid slip composition consists essentially of a deflocculent composed of a vinyl chloride and vinyl acetate resin dissolved in an organic solvent. The composition may be slip cast or cold formed into a low density article which is then sintered into a dense product.

Abstract: A heat-stable, pigmented thermoplastic resin composition comprising A) a thermoplastic resin; B) a metal phthalocyanine pigment; and C) 0.5 to 30% by weight of, based on the weight of component B), as agent for imparting heat stability to component B), a phthalocyanine compound having the formula (I):MPc(CH.sub.2 NHCO--A).sub.y Iin which Pc is a phthalocyanine residue which is optionally substituted by up to an average of 1 chlorine or bromine atom, or of 1 sulphonic acid group; M is hydrogen or a metal capable of forming a metal phthalocyanine; y is a number ranging from 0.1 to 4.0; and A is C.sub.1 -C.sub.21 alkyl, C.sub.2 -C.sub.21 alkenyl, C.sub.5 -C.sub.8 cycloalkyl, C.sub.7 -C.sub.11 aralkyl, C.sub.6 - or C.sub.10 aryl, or a 5- or 6-membered heterocyclic residue, or a fused heterocyclic system.

Abstract: Non-whiteware ceramic articles having an increased green strength are prepared from slip compositions containing a polyalkylene polyamine as an additive or a mixture of a polyalkylene polyamine and binder as an additive. An example of such an additive is tetraethylenepentamine or a mixture of tetraethylenepentamine and a styrene butadiene latex.

Abstract: The invention provides a process for readily preparing polymeric solid electrolyte, i.e., ion conductive polymer having excellent properties.The process of the invention comprises steps of subjecting at least one of the following component A and component B to contain an alkali metal salt and/or an ammonium salt and mixing the components A and the component B.Component A: a solution obtained by dissolving a radical polymerization promotor in a specific polyether base macromonomer.Component B: a solution obtained by dissolving a radical polymerization initiator in a specific polyether base oligomer and/or an organic non-aqueous solvent.To at least one of the component A and component B, a radical polymerization retarder is added, if desired.The process of the invention can be carried out by a simple step comprised of mixing the two components at room temperature and provides the solid polyelectrolyte having a high inonic conductivity.

Abstract: Thermoplastic rubber is used as part of a thermally conductive electrically insulating filled elastomer composition. The filler may be any conventional filler such as hexagonal boron nitride or alumina. The thermoplastic rubber may be crosslinked. The filled elastomer can be molded or pressed into desired shapes.

Abstract: A ceramic composition which can be extrusion or injection molded to ceramic greenbodies comprises a sinterable powder mixed within a polyacetal binder and further includes a dispersing aid comprising a polyester oligomer formed by self condensation of a hydroxy fatty acid in which the hydroxy group is attached to an internal carbon atom of the fatty acid. The dispersing aid also acts as a stabilizer for the polyacetal binder during compounding with the powder.

Abstract: Thermoplastic materials for the production of ceramic moldings containA) 40-65% by volume of a sinterable inorganic non-metallic powder,B) 35-60% by volume of a mixture ofB1) 70-90% by weight of a polyoxymethylene homo- or copolymer having up to 10 mol % of comonomer units andB2) 10-30% by weight of a polyoxymethylene copolymer with a comonomer content of 20-99 mol %, poly-1,3-dioxolane, poly-1,3-dioxane or poly-1,3-dioxepan, or of a polymer which is homogeneously dissolved or is dispersed with a mean particle size of less than 1 .mu.m in B1) or a mixture thereof,as a binder, andC) 0-5% by volume of a dispersant.

Abstract: Preceramic polysilazanes which (1) are composed of silicon, nitrogen, and hydrogen, (2) can be isolated and redissolved in common organic solvents, and (3) are capable of providing a high ceramic yield when pyrolyzed are prepared by reacting a mixture of one molar proportion of a tetrahalosilane, preferably tetrachlorosilane, and at least 4.5 molar proportions of a dihalosilane, preferably dichlorosilane, in an organic solvent. Ceramics obtained from the polysilazanes are nanoporous, amorphous silicon nitride ceramics having high purity.

Abstract: A new tire sealant and inflator composition is provided, which combines a sealant in an aqueous carrier with a non-flammable, non-ozone depleting propellant/inflator. A preferred composition combines a sealant composition with 1,1,1,2-tetrafluoroethane (134a). In a preferred embodiment, a vapor pressure depressant is combined with the sealant and 134a. A preferred sealant and inflator composition comprises from about 20% to about 80% of 134a, from about 2% to about 10% of a sealer, such as latex, or a polyvinyl acetate emulsion; from about 1% to about 8% of a freezing point depressant, such as an alkylene glycol; from about 0.1% to about 1% of a corrosion inhibitor, such as ammonia; from about 30% to about 70% of a carrier, such as water; and from about 4% to about 40% of a vapor pressure depressant, such as a glycol ether. A preferred vapor pressure depressant is 2-butoxyethanol, and a preferred freezing point depressant is ethylene glycol.

Abstract: This invention relates to a process for producing a quality-improved water-absorbent polymer in which the aqueous liquid (I), which is obtained by mixing in an aqueous medium at least one kind of a water-soluble salt (A) selected from a group of halogenated compounds, sulfates, acetates, and nitrates, which are derived from at least one kind of a polyvalent metal selected from a group of aluminum, calcium, and magnesium, with at least one kind of a water-soluble salt (B) selected from a group of monovalent metal salts and ammonium salts, which are derived from at least one kind of an oxyacid selected from a group of sulfurous acid and thiosulfuric acid, is mixed with a water-absorbent polymer (II) in a proportion of that the water-soluble salt of the polyvalent metal (A) is in a range of 0.1.about.10 parts by weight against 100 parts by weight of the water-absorbent polymer (II) and the water-soluble salt of the oxyacid (B) is in a range of 0. 1.about.

Abstract: The hydrolytic polycondensation of a monomer of ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently alkyl groups containing from 1 to 4 carbon atoms, R.sup.a, R.sup.b, R.sup.c, and R.sup.d are independently alkenyl or alkyl groups containing from 2 to 6 carbon atoms with the proviso that at least one of R.sup.a, R.sup.b, R.sup.c, or R.sup.d group is an alkenyl group; can be carried out directly in the presence of a phenolic resin. This in situ polymerization reaction results in the formation of a new family of polysilazoxane-modified phenolic resins. Modified phenolic resins may also be prepared by the controlled hydrolysis of the above monomers in the presence of initiators. The polysilazoxane so formed is blended into a phenolic resin. The organic soluble thermosetting resins exhibit synergistic char yields of 63 to 80 wt. % (1500.degree. C./N.sub.2).

Abstract: The curable resin composition of the present invention consists of a curable resin having uniformly dispersed therein particles of a cured silicone rubber obtained from an organosiloxane composition curable by a platinum-catalyzed hydrosilation reaction, wherein said organosiloxane composition contains reaction products of an ethylenically unsaturated epoxy compound and an ethylenically unsaturated aromatic compound with the organohydrogenpolysiloxane present in said organosiloxane composition. Either or both of the epoxy compound and the aromatic compound can be prereacted with a portion of the silicon-bonded hydrogen atoms of the organohydrogenpolysiloxane.

Abstract: This invention provides a water-soluble binder and a hot-melt binder for ceramics molding, said binder being composed of a polyvinyl alcohol-based copolymer containing (meth)allyl group-containing nonionic monomer units or nitrogeneous group-containing nonionic monomer units.

Abstract: A self-leveling silicone composition, which is useful as a sealant in contact with asphalt, cures upon exposure to moisture in the atmosphere to an elastomer having an elongation of at least 1200 percent, and a modulus at both 50 and 100 percent elongation of less than 25 pounds per square inch. The composition consists essentially of a hydroxyl endblocked polydiorganosiloxane, non-acidic, non-reinforcing treated filler, diacetamido functional silane, aminoxysilicon crosslinking compound, and non-reactive silicone fluid diluent.

Abstract: A thermal conductive polymer composition comprising a mixture of a polymer and a thermally conductive filler material, said filler material having a median particle size of between about 130 to 260 microns and a size distribution characterized by the formula: ##EQU1## where % represents the wt. % of the particles below or above the median particle size and M represents the median particle size in microns.

Abstract: The combination of known thermally conductive fillers having an average particle size of from about 10 to about 100 microns with aluminum nitride having an average particle size of less than one micron improves the thermal conductivity of organosiloxane compositions. The thermal conductivity values achieved using this combination of fillers is higher than can be achieved using the maximum loading of either filler alone that can be present without adversely affecting the ability of the organosiloxane composition to cure or to serve as useful coatings and encapsulates for electronic solid state devices and other substrates.

Abstract: The invention relates to a two phase cement mixture which is particularly suitable for orthopaedic use, in which the solid phase comprises a polymer, polymetyl methacrylate, and a catalyst, benzoyl peroxide, while the liquid phase comprises a monomer, monomethyl methacrylate, an accelerator, N-N-dimethyl-p-toluidine and hydroquinone. The said polymetyl methacrylate is in powder form with particles of a spherical shape which are of a suitable particle size. Fluoride in form of salt can be added to the said solid phase, realizing fluoride ions, making them available to the part of the bone with which the said mixture is in contact when is used to attach a prothesis to a bone.

Abstract: Polyvinyl chloride resin stabilizer compositions are provided, comprising a 2,2,6,6-tetramethyl piperidinyl compound and an ammonium or metal perchlorate; and also stabilized polyvinyl chloride resin compositions containing such stabilizers, and optionally including a plasticizer, and particularly as molded articles with polyurethane foam backing.

Abstract: A device, e.g., an electrical or electromechanical assembly, comprising a housing with a mechanism disposed therein which is potted by a cured mass of a self-leveling liquid composition. The composition comprises an actinic radiation cured first resin component and a subsequently cured second resin component which is non-cured under the actinic radiation conditions effective for curing the first resin component. Also disclosed is an appertaining method of making such devices.Depending on the depth of the composition which is to be cured in the housing, it may be desirable to utilize the self-leveling liquid composition as either a single homogeneous mixture of the first and second resin components, or, where the depth of the housing is greater than the depth of UV penetration, as a cured mass wherein the first resin component is in a separate and discrete resin layer overlying a lower resin layer containing the second resin component but not the first resin component.

Abstract: Compositions useful in decomposition molding procedures such as destructive foam casting or ceramic or metallic powder sintering are provided by blends of polymers having greater than 50 weight percent propylene carbonate units and polymers having greater than 50 weight percent methyl methacrylate units. Such blends exhibit an unexpectedly even decomposition profile over the range of temperatures at which their constituent polymers each decompose relatively rapidly. The controlled decomposition rate reduces problems in destructive foam casting and ceramic or metallic powder molding caused by sudden release of gases by the foam pattern or the polymer binder. Preferred blends contain 35 to 65 weight percent poly(methyl methacrylate) and 65 to 35 weight percent poly(propylene carbonate), and very even decomposition behavior is exhibited by blends of 35 to 45 weight percent poly(methyl methacrylate) and 65 to 55 weight percent poly(propylene carbonate).

Abstract: A heat-resistant paint comprising a dispersion or solution of a polymetallocarbosilane and an inorganic filler in an organic solvent,wherein said polymetallocarbosilane is an organometallic polymer having a number average molecular weight of 400 to 50,000 comprising(A) carbosilane bond units of the formula ##STR1## wherein R.sub.1 and R.sub.2 may be identical or different and each represents a lower alkyl group, phenyl group or a hydrogen atom, and(B) metalloxane bond units of the formula(M--O)wherein M represents at least one element selected from the group consisting of Ti, Zr, Cr and Mo,wherein said inorganic filler is at least one material selected from the group consisting of oxides, borates, phosphates, silicates, silicides, borides, nitrides and carbides; andwherein said inorganic filler is present in an amount of 10 to 900 parts by weight per 100 parts by weight of said polymetallocarbosilane.

Abstract: A coating composition comprising a major amount of resin and a minor amount of a property-improving additive,said resin being:(A) a fluorocarbon resin selected from the group consisting of (1) perfluoroalkoxy tetrafluoroethylene copolymer resin (PFA), (2) ethylenechlorotrifluoroethylene copolymer resin (E-CTFE), (3) ethylenetetrafluoroethylene copolymer resin (E-TFE), (4) poly(vinylidine fluoride) resin (PVDF), (5) tetrafluoroethylene-hexafluoropropylene copolymer resin (FEP), (6) poly(chlorotrifluoroethylene) resin (CTFE), or a mixture of two or more of said fluorocarbon resins; or(B) a polyether resin selected from the group consisting of (7) polyethersulfone resin (PES), (8) polyether ketone resin (PEK) and (9) polyether ether ketone resin (PEEK) or a mixture of two or more of said polyether resins;said additive being:(C) a poly(phenylene sulfide) (PPS); or(D) an inorganic crystalline ceramic powder and/or fluorocarbon resin when said resin is a polyether of (B) above; or(E) an inorganic material selected

Abstract: The preparation of highly densified ceramic bodies by sintering certain curable organopolysiloxanes filled with silicon carbide powders, metal-containing sintering aids, and organopolysiloxane curing agents described. Such highly densified ceramic bodies can be prepared by either a pressure-less or a hot press sintering process. The compositions of this invention can be formed into desired shapes and then sintered to form ceramic, shaped bodies with high densities. One advantage of the present invention is that the green bodies have relative high strengths and thus can be easily handled and, if desired, machined before sintering. The curable organopolysiloxanes useful in this invention must yield a ceramic char which contains free or excess carbon in addition to carbon in the form of silicon carbide upon pyrolysis to elevated temperatures.

Abstract: The present invention relates to a binder and a method for making and shaping a green body of ceramic powder and subsequently producing a formed ceramic body. The method of the present invention comprises admixing a ceramic powder with a binder comprising a polyalkylene carbonate to form a ceramic-binder mixture. The binder of the present invention comprises a polyalkylene carbonate, preferably polyethylene carbonate or polypropylene carbonate.

Abstract: The amine resistance of peroxide-cured fluorocarbon elastomers is improved by dispersing certain normally solid, inorganic chloride or bromide salts in the elastomer gum formulation.

Abstract: Corrosion inhibiting calcium-containing amorphous precipitated silica is described. The silica is prepared by admixing simultaneously in a reactor aqueous alkali metal silicate, e.g., sodium silicate, acidifying agent, e.g., hydrochloric acid, and a water-soluble source of calcium, e.g., calcium chloride. The product contains from 6 to 9 weight percent calcium (as CaO). The silica product may be incorporated into a coating composition used for corrodible metallic surfaces.

Abstract: Disclosed is a biaxially oriented poly-p-phenylene sulfide film prepared from a resin composition comprising poly-p-phenylene sulfide as its principal component, 20-1000 ppm of at least one metal belonging to IA group or IIA group of the periodic table and 100-600 ppm of nitrogen, the poly-p-phenylene sulfide having an weight average molecular weight Mw of 30,000-90,000, and a ratio of weight average molecular weight to number average molecular weight Mw/Mn of 3-10. The film of the present invention has an excellent mechanical properties and dimensional stability, as well as excellent clearness.

Abstract: The amine resistance of peroxide-cured fluorocarbon elastomers is improved by dispersing certain normally solid, inorganic chloride or bromide salts in the elastomer gum formulation.

Abstract: A composition for selectively reducing the permeability of the higher permeability zones of a subterranean reservoir having heterogeneous permeability, such permeability reduction extending continuously from nearby the well as far into the reservoir as is desired. Said composition comprises an aqueous solution or solutions of a water-soluble polymer, a material capable under certain conditions of at least partially cross-linking the polymer to form a gelatinuous precipitate, a water-soluble alkaline material in an amount sufficient to maintain the pH of the polymer-containing composition above the pH at which cross-linking occurs until the composition has passed a desired distance through the reservoir, and a temperature-activated water-soluble acidic material dissolved in the aqueous solution in an amount sufficient to lower the pH of the overall solution to the pH at which cross-linking occurs when said solution is subjected to an elevated temperature.

Abstract: The water permeability of cured thermosetting organic resin compositions is reduced and the dimensional stability of these compositions during molding is improved by the addition to the curable resin composition of a finely divided, cured organosiloxane material prepared from a curable organopolysiloxane, a curing agent for the organopolysiloxane, an optional silica filler and an aromatic hydrocarbon compound containing a substituted benzene ring where the substituent is a monovalent ethylenically unsaturated hydrocarbon radical or an alkenyloxy radical.

Abstract: An insoluble infusible electroconductive polymer is provided, which is derived from an organic compound having 3 to 6 carbon atoms and having a cyano group and an ethylenically or acetylenically unsaturated bond by mutually reacting this compound at an elevated temperature.

Abstract: Method of spinning fibers and coating from an organopolysilazane composition that can be crosslinked by an energy input. The organopolysilazane composition comprises an organopolysilazane and a free radical generator in an amount effective to crosslink the organopolysilazane. The energy input capable of generated the radical may be provided in the form of heat, ultraviolet radiation, an electron beam, and the like.The crosslinked organopolysilazane compositions exhibit good thermal behavior and, in particular, can be used, after pyrolysis, as precursors of ceramic products.

Abstract: Heat-vulcanizable organopolysiloxane compositions well adopted for extrusion and molding, and facilely converted into elastomeric shaped articles having improved physical and electrical properties, e.g., seals and sections, include a diorganopolysiloxane oil containing from 0.05 to 3 mol % of vinylsiloxy recurring units, as well as an amine having a pKa greater than 7.5 in aqueous solution at 25.degree. C. and a boiling point of less than 270.degree. C. at atmospheric pressure.

Abstract: Compositions comprising elastomeric polyurethane prepolymers comprising the reaction product of at least one diisocyanate selected from the group consisting of p-phenylene diisocyanate, m-phenylene diisocyanate, 1,4-cyclohexyl diisocyanate, tetramethylxylyl diisocyanate and dimethylphenyl diisocyanate and at least one polyol or polythiol characterized by the presence of two hydroxyl or thiol groups or one hydroxy and one thiol group; a monomeric diol or dithiol curing agent and vein forcing fiber are especially useful for preparing fiber-reinforced composite structures, especially for dynamic applications.