Abstract: Compositions and methods for a melt processable semicrystalline poly(aryl ether ketone) incorporating phthalazinone and 4,4?-biphenol as comonomer units are described herein. The polymers are resistant to and insoluble in common organic solvents and liquids as well as in aggressive organic solvents such as chloroform and chlorinated liquids. The polymers are melt processable via techniques such as extrusion, injection molding, and compression molding. The semicrystalline poly(aryl ether ketone) containing phthalazinone comonomer units have properties which make them suitable for manufacturing high temperature resistant molded systems and other articles.

Abstract: Chain-extended nanonylon is made from the reaction of in-situ polymerized nanonylon and chain-extending agents. Knowing the viscosity/shear rate curve for a thermoplastic polymer to be replaced, such as nylon, the method of the present invention allows via adjustment of organoclay concentration and chain extension of the nylon polymer and other reaction factors to achieve a chain-extended, in-situ polymerized nanonylon to have a viscosity/shear rate curve that essentially matches the viscosity/shear rate curve for that neat nylon within a commercially operable shear rate.

Abstract: Mixtures of halogenated elastomers and latent curatives are provided that cure when subjected to sufficient heat to decompose the latent curative. Decomposition products include CO2 and N-nucleophiles, which participate in nucleophilic substitution reactions leading to crosslinking of the elastomers. Transparent thermoset products that were free of voids were produced.

Abstract: Self-primed, printable formulations comprise: A. A polyurethane binder, B. An absorptive pigment, C. A crosslinker, D. An ultraviolet (UV) absorber, E. A light stabilizer, and F. Solvent. These formulations are coated to plastic substrates without the substrate first receiving a primer coating or other surface treatment to enhance print receptivity. These coatings provide a high performance, single layer, matte-finish, universal printable plastic media for use with a wide variety of printers and photocopiers. In one embodiment the single layer matte finish universal printable media is converted to a satin finish universal printable media by applying a gloss-promoting coating formulation over the single layer matte finish base layer.

Abstract: A plastic extrusion or molding composition includes a polymer and a fibrous clay and/or a hybrid organic/inorganic pigment. The hybrid organic/inorganic pigment comprises a fibrous clay and an organic dye or organic pigment, and combinations thereof. Plastic extrusions and moldings are formed from the composition. In addition, a method of making a plastic component from the polymer and fibrous clay or hybrid organic/inorganic pigment is provided.

Abstract: Embodiments of the present disclosure include flame retardant composites, flame retardant nylon fibers, flame retardant nylon fiber carpets, methods of making each, and the like.

Abstract: A mix including at least one hydraulic and/or pozzolanic material and at least one water-soluble cationic polymer, the cationic polymer having a density of cationic charges greater than 0.5 meq/g and an intrinsic viscosity less than 1 dl/g, and the hydraulic and/or pozzolanic material not being clinker, nor limestone, nor gypsum, nor calcium sulphate, nor anhydrous calcium sulphate, nor hemi hydrated calcium sulphate, nor plaster, nor lime.

Abstract: Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH—??(I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH—??(II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and said polyamide has a melting point equal to or less than 225° C.; and 0.25 to 20 weight percent of one or more polyhydroxy polymer(s) having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene/vinyl alcohol copolymer and poly(vinyl alcohol). Also disclosed are molded or extruded articles including the polyamide composition.

Abstract: A polymeric nanocomposite comprises a non-polar hyperbranched polystyrene resin. An exfoliated or intercalated onium functionalized clay is dispersed within the resin. Such nanocomposites are more compatible with non-polar polymer matrices used in various articles of manufacture.

Abstract: A polymer composite material provides superior heat resistance, mechanical physical properties, substance permeation barrier properties, flame retardant properties, electrical conductivity and the like. Moreover, a novel surface-modified nanofiller utilizes this type of polymer composite material. The polymer composite material contains nanofillers, fluorocompounds and polymers. Fluoruocompounds bond to the surface of the nanofillers. The nanofillers to which fluorocompounds are surface-bonded are mixed with or dispersed in polymers.

Abstract: Polymer-clay nanocomposites and methods of making the same are provided. In an embodiment, a polymer-clay nanocomposite comprises a non-metal salt of an ionomer and a nanostructured layered clay. An example of the ionomer is a tetra-octyl ammonium salt of sulfonated polystyrene, and an example of the clay is sodium-montmorillonite.

Abstract: A polymeric nanocomposite comprises a non-polar hyperbranched polystyrene resin. An exfoliated or intercalated onium functionalized clay is dispersed within the resin. Such nanocomposites are more compatible with non-polar polymer matrices used in various articles of manufacture.

Abstract: The invention relates to rubber nanocomposites particularly suitable for innerliners and other tire applications. The uncured nanocomposite comprises an elastomer, tackifier and nanoclay.

Abstract: A starch-polyester graft copolymer and chemically modified starch-polyester graft copolymer composition comprising a chemically modified starch or chemically modified starch-nanoclay product is described. The composition can be produced continuously in a twin-screw co-rotating extruder. The starch-polyester graft copolymer can be solvent cast, melt cast and blown into clear transparent film particularly for use in single use disposable applications and can be biodegradable.

Abstract: A biodegradable gas barrier vessel comprising 100 parts of mass of a biodegradable polyester resin having a polylactic acid content of not less than 50% by mass and 0.1 to 10 parts by mass of a phyllosilicate. The degree of crystallization as measured by X-ray diffractometry is not less than 15%, and the coefficient of oxygen permeation as measured under conditions of 20° C. and relative humidity 90% is not more than 50 ml·mm/m2·day·MPa. Since the biodegradable polyester resin reinforced with the phyllosilicate has excellent heat resistance, the molded product can be heat treated at an elevated temperature. Such enhanced heat treatment conditions can further enhance the degree of crystallization of the polyester resin and thus can contribute to significantly improved gas barrier properties.

Abstract: A method is disclosed concerning discovering how the use of an additive in a polyolefin compound affects the weatherability of that compound, Applying that technique, a weatherable polyolefin nanocomposite is disclosed, which contains UV stabilizers that filter wavelengths in a range influenced by presence of organoclay in the nanocomposite.

Abstract: The present invention involves the creation of fiber clay sculpting material and use of the material as a medium, including techniques for producing the material and non-fired and non-dried clay products. A fiber clay sculptural material is disclosed, while alternative embodiments may encompass fiber clay products. The fiber clay sculptural material in accordance with the present invention may incorporate fiber material such as paper, nylon or fiberglass. One embodiment of the invention disclosed is a method of producing fiber clay sculpting material, featuring the provision of an acrylic emulsion, adding the acrylic emulsion to fiber clay and mixing the acrylic emulsion with the fiber clay to form an acrylic fiber clay sculpting material. A fiber clay product may be produced from the disclosed methods. Further embodiments of the invention are fiber clay sculpting materials made of fiber clay and an acrylic emulsion mixed with the fiber clay to form an acrylic fiber clay sculpting material.

Abstract: A composition is disclosed comprising a styrenic first polymer, nanoclay, and an emulsifier compound, which can be blended with an additional polymer. A nanocomposite exhibits improved heat resistant properties and stiffness. In one embodiment, the additional polymer is poly(phenylene ether). An article and a method for the preparation a nanocomposite are also disclosed.

Abstract: An elastomeric thermoplastic non-vulcanized terpolymer composition formed from acrylonitrile, styrene, and liquid 1,3-butadiene is disclosed herein. The terpolymer can have from 20 percent by weight to 50 percent by weight of the acrylonitrile, from 0.5 percent by weight to 20 percent by weight of the styrene, and from 30 percent by weight to 79.5 percent by weight of the butadiene. The acrylonitrile can be cross-linked to the styrene. The thermoplastic non-vulcanized terpolymer can include fillers, UV stabilizers, and plasticizers. Also disclosed is an article formed by the elastomeric thermoplastic non-vulcanized terpolymer and a process for making the composition.

Abstract: A process for forming a compatibilized silica and nitrile polymer blend in latex form is described herein. The process can include treating a silica with a coupling agent in aqueous suspension to form a compatibilized silica slurry. The coupling agent can have the capacity of chemically reacting with the surface of the silica to bond the coupling agent thereto. The process can include blending at least a portion of the compatibilized silica slurry into a styrene butadiene polymer latex, forming a silica styrene butadiene polymer latex, and blending at least a portion of the compatibilized silica slurry into an acrylonitrile butadiene polymer latex, forming a silica acrylonitrile butadiene polymer latex. The process can include blending the silica styrene butadiene polymer latex with the silica acrylonitrile butadiene polymer latex, forming the compatibilized silica and nitrile polymer blend.

Abstract: A recycled elastomeric composition that can include a natural rubber, a synthetic elastomeric polymer, or combinations thereof is described herein. The synthetic elastomeric polymer can include butadiene and styrene. The recycled elastomeric composition can also include a compatibilized silica with a coupling agent, a crumb rubber, a carbon black, a filler, and an extender oil. Articles comprising the recycled elastomeric composition can include: floor mats, tires, belts, rollers, footwear, wire or cable jacketing, roof edging, tubulars, and marine impact bumpers.

Abstract: A resin composition which reduces hydrolysis thereof and reduces the color change thereof at the time of heating and a resin molded object which reduces hydrolysis thereof and reduces quality change of content therein are provided. The resin composition includes a resin and an organically modified layered silicate in which a substituted silyl group having a substituted or non-substituted alkyl group bonds to a layered silicate. The resin molded object is obtained by molding a resin composition including a resin and an organically modified layered silicate in which a substituted silyl group having a substituted or non-substituted alkyl group bonds to a layered silicate.

Abstract: Disclosed is a novel polymeric composite including a nanoparticle filler and method for the production thereof. More particularly, the present invention provides a novel halloysite nanoparticle filler which has the generally cylindrical or tubular (e.g. rolled scroll-like shape), in which the mean outer diameter of the filler particle is typically less than about 500 nm. The filler is effectively employed in a polymer composite in which the advantages of the tubular nanoparticle filler are provided (e.g., reinforcement, flame retardant, chemical agent elution, etc.) with improved or equivalent mechanical performance of the composite (e.g., strength and ductility).

Abstract: A seal member includes a hydrogenated acrylonitrile-butadiene rubber (HNBR) and carbon nanofibers. The seal member has a number of cycles to fracture of 7000 or more when subjected to a tensile fatigue test at a temperature of 70° C., a maximum tensile stress of 4 N/mm, and a frequency of 1 Hz. The seal member exhibits excellent abrasion resistance.

Abstract: An insulation composition that comprises at least one nitrile butadiene rubber, basalt fibers, and nanoclay is disclosed. Further disclosed is an insulation composition that comprises polybenzimidazole fibers, basalt fibers, and nanoclay. The basalt fibers may be present in the insulation compositions in a range of from approximately 1% by weight to approximately 6% by weight of the total weight of the insulation composition. The nanoclay may be present in the insulation compositions in a range of from approximately 5% by weight to approximately 10% by weight of the total weight of the insulation composition. Rocket motors including the insulation compositions and methods of insulating a rocket motor are also disclosed.

Abstract: Embodiments of the disclosure include elastomeric stretch fibers containing an anti-tack agent, methods of preparing the fiber, methods of using this fiber, articles including this fiber, and the like.

Abstract: Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH—??(I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH—??(II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and wherein said polyamide has a melting point equal to or less than 225° C. Also disclosed are molded articles including the polyamide composition.

Abstract: A two-component adhesive composition suitable for structural bonding of concrete/concrete, steel/concrete, or steel/steel, as well as for structural strengthening and reinforcing applications with fiber reinforced polymers, is disclosed. The composition includes a resin component A with a peroxide containing at least one norbornene group and at least one methacrylate containing compound and a hardener component B comprising a peroxide and at least one thiol. The resin component A and the hardener component B are spatially separated from one another to inhibit any reaction before mixing of the components.

Abstract: Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of 40 to 60 mole percent repeat units of the formula —C(O)(CH2)4C(O)NHCH2ArCH2NH—??(I) and 40 to 60 mole percent repeat units of the formula —C(O)(CH2)4C(O)NH(CH2)6NH—??(II) wherein Ar is a meta-substituted benzene ring. Also disclosed are molded articles including the polyamide composition.

Abstract: The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.

Abstract: A polymer is characterized by a repeat unit represented by Structural Formula (I), or a copolymer thereof. A crosslinked polymer characterized by a repeat unit represented by Structural Formula (II), (III), (IV) or (V), or a copolymer thereof, wherein at least one such repeat unit of a first polymer strand is crosslinked with at least one repeat unit of a second polymer strand by at least one bridging unit, the first and second polymer strands and the repeat unit being components of the crosslinked polymer.

Abstract: Disclosed is a thermoplastic polyolefin (TPO) nanocomposite composition, more particularly a TPO nanocomposite composition including a polypropylene resin, a polyethylene resin, a rubber resin, a nanoclay master batch and a glass bubble master batch. Since the disclosed TPO nanocomposite composition has low specific gravity and superior gloss reducing effect and scratch resistance, it may be usefully applied to light automobile parts, uncoated automobile exterior parts, or the like.

Abstract: An organic/inorganic hybrid material is provided, including an organic polymer, and a plurality of inorganic nano-platelets, wherein the inorganic nano-platelets are self-connected or connected via a linker to constitute an inorganic platelet network. By the formation of the inorganic network structure, the hybrid materials can keep their transparency and flexibility at a high inorganic content, and exhibit greatly reduced coefficients of thermal expansion A method for fabricating the organic/inorganic hybrid material is also provided.

Abstract: Polymer composite materials having improved gas barrier properties are generally disclosed, along with process of making the same. The polymer composite materials can include phosphonate particles, oxide particles, and combinations thereof. For example, the particles can be metal phosphonate particles, synthetic oxide particles, or combinations thereof.

Abstract: A hybrid pigment composition is provided including a pigment or a dye and a fibrous clay. The pigment composition has higher reflectance in a near infrared region than a visible light region of the electromagnetic spectrum. The fibrous clay can be selected from palygorskite, sepiolite, and mixtures thereof. The hybrid pigment composition is tunable to provide high reflectance at a desired wavelength in the near infrared region.

Abstract: Branched polydiorganosiloxane polyamide, block copolymers and methods of making the copolymers are provided. The method of making the copolymers involves reacting one or more amine compounds including at least one polyamine with a precursor having at least one polydiorganosiloxane segment and at least two ester groups.

Abstract: Solution blending of masterbatch of cationically functionalized polyvinyl acetate copolymer/silicate nanocomposite where the silicate is substantially exfoliated, and ethylene-vinyl acetate copolymer (EVA), produces product of increased tensile strength and Young's Modulus compared to neat EVA and reduced flammability compared to neat EVA. The product can be injection molded or compression molded or extruded without loss of these advantages.

Abstract: The present invention relates to novel flame retardant polycarbonate resin compositions comprising at least one aromatic polycarbonate resin, at least one anti-drip agent, and at least one salt as defined herein. The present invention also provides methods for preparing articles comprising said flame retardant composition, and articles made therefrom.

Abstract: A composition for artificial marble includes (a) about 100 parts by weight of an acrylic resin; (b) about 1 to about 30 parts by weight of an ocher powder having a particle size of about 1 to about 50 ?m; (c) about 100 to about 200 parts by weight of an inorganic filler; (d) about 0.1 to about 10 parts by weight of cross-linking agent; and (e) about 0.1 to about 10 parts by weight of a polymerization initiator.

Abstract: A surge-resistant and abrasion resistant flexible insulating enamel has resin in an amount of 12 wt % to 76 wt % per 100 wt % by weight of the enamel, an organic solvent in an amount of 20 wt % to 80 wt % per 100 wt % by weight of the enamel, polyethylene oxide (PEO) intercalated clay in an amount of 0.005 wt % to 16 wt % per 100 wt % by weight of the enamel, and organic dispersible silica nano-particles in an amount of 0.995 wt % to 16 wt % per 100 wt % by weight of the enamel. The clay and silica nano-particles have high dielectric constant to absorb, disperse evenly and evacuate surge, which prevents an insulating layer made by the insulating enamel from being damaged from the surge. PEO provides the insulating layer has good flexibility, adhesion and abrasion resistance.

Abstract: The surface of hydrophobically-modified smectite clays (i.e., organophilic clays) are modified using a hydrophilic polymer, wherein the hydrophilic surface-modification of a hydrophobically-modified smectite clay with a hydrophilic polymer, renders the organoclays adequately dispersible in water.

Abstract: An object of the present invention is to improve abrasion-resistance and spin performance of a golf ball having a polyurethane cover. The golf ball of the present invention is a golf ball having a core and a cover covering the core. The cover contains a layered silicate and a polyurethane resin having a secondary or a tertiary amine structure in a molecular chain thereof. In the present invention, the polyurethane resin used as a resin component constituting the cover has a secondary or tertiary amine structure in a molecular chain. Thus, it has a strong interaction with the layered silicate, and a reinforcing effect of the filler becomes even higher. As a result, abrasion-resistance and spin performance of the resultant cover are improved.

Abstract: The present invention is directed to the provision of premixed aqueous compositions which are used to provide a paint composition of varying finish characteristics at the point of sale. Thus, the merchant distributing the paint composition made from the subject premixed compositions need only maintain inventory of four compositions. The particular compositions which are the subject of the invention exhibit stable characteristics during storage in their respective reservoirs. The compositions include a pigment composition, a dispersant thickening agent, a high resin content binder, and a low resin content binder. The compositions are combined in differing amounts to produce paint compositions being suitable for either interior or exterior use and having differing sheens, quality levels, and color bases.

Abstract: Poly(trimethylene terephthalate compositions comprising (a) molding resin comprising a poly(trimethylene terephthalate) resin and 0.1 to 4 weight percent of one or more ionomer polymers or a combination of the ionomer polymers and acid copolymers; (b) 0 to about 50 weight percent of one or more fillers, based on the total weight of the molding resin; and (c) about 1.0 to about 5 weight percent of one or more Group A polymeric tougheners based on the total weight of components (a) and (c); wherein: each ionomer polymer and acid copolymer has: C3 to C8 carboxylic acid repeat units; a weight percent, W, based on the weight of components (a) and (c); a weight fraction of C3 to C8 carboxylic acid repeat units, Z, based on the weight of each ionomer or acid copolymer; and a neutralization ratio, N, ranging in value from 0 to 1.

Abstract: A vulcanizable elastomeric composition and a method of forming said composition is presented. The method generally comprises the mixing of sulfur and an ultra-accelerator into a mixture of an elastomeric polymer matrix, fillers, and silane coupling agent during the silanization reaction step, prior to the occurrence of vulcanization. The addition of the ultra-accelerator, such as TBzTD, enhances the efficiency of the silanization reaction and forms at least one bond with the elastomeric polymer matrix. The silanization reaction step may comprise multiple mixing substeps in which the ultra-accelerator may be incorporated into the elastomeric composition.

Abstract: A method is disclosed concerning discovering how the use of an additive in a polyolefin compound affects the weatherability of that compound. Applying that technique, a weatherable polyolefin nanocomposite is disclosed, which contains UV stabilizers that filter wavelengths in a range influenced by presence of organoclay in the nanocomposite.

Abstract: The present invention provides a method for preparing an imidazolium surfactant using a mixing apparatus. The present invention also provides a nano-composite comprising a clay and the imidazolium surfactant, and a composition comprising a polymer and the nano-composite. The nano-composite is practically useful in formulating compositions such as rubber and tire products with improved and well-balanced properties including gas permeability, cure properties, and/or mechanical properties etc.

Abstract: A transparent flexible film is provided, formed by curing a composition, comprising: about 40-75 parts by weight of a clay; about 15-45 parts by weight of a water-soluble polymer; about 1-10 parts by weight of a mono-functional acrylic oligomer of formula (I), wherein n1 is an integer 2-25, R1 is C1-10 alkyl or H, and R2 is H or CH3; and about 10-45 parts by weight of a bi-functional acrylic oligomer of formula (II), wherein n2 is an integer 3-50, R3 and R4 are H or CH3.

Abstract: The present invention relates to novel composites that incorporate carbon nanospheres into a polymeric material. The polymeric material can be any polymer or polymerizable material compatible with graphitic materials. The carbon nanospheres are hollow, graphitic nanoparticles. The carbon nanospheres can be manufactured from a carbon precursor using templating catalytic nanoparticles. The unique size, shape, and electrical properties of the carbon nanospheres impart beneficial properties to the composites incorporating these nanomaterials.

Abstract: The present invention relates to a composite material, particularly a composite material designed as a molded body and/or suited for the production of molded bodies, composed of polymer materials and a porous mineral matrix, said composite material expanding under the action of liquids, particularly aqueous liquids and/or aqueous oil emulsions, and storing said liquids, characterized in that the matrix it comprises includes crushed and/or ground, open-pored, expanded/expanded perlite in the form of sharp-edged perlite particles and at least one natural and/or synthetic cross-linked and/or partially cross-linked polymer and/or polymer forming a hydrogel.