Diatomite Or Diatomaceous Earth, E.g., Kieselguhr, Infusorial Earth, Etc. Patents (Class 524/448)
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Patent number: 5216104Abstract: An addition-type silicone rubber composition comprising (a) an organopolysiloxane containing at least two alkenyl groups bonded to the silicon atoms in one molecule, (b) an organopolysiloxane containing one alkenyl group bonded to the silicon atom in one molecule on an average, (c) an organohydrogenpolysiloxane containing at least two hydrogen atoms bonded to the silicon atoms, (d) a platinum catalyst; and a product of curing the composition. This silicone rubber composition can give a low-modulus silicone rubber by curing which neither contaminates the material in contact therewith nor deforms owing to shrinkage, without hindering the adhesion of the composition during its curing stage.Type: GrantFiled: July 17, 1990Date of Patent: June 1, 1993Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takehide Okami, Hironao Fujiki
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Patent number: 5206273Abstract: A method for increasing the slip of polyolefins and improving the adhesion of water based inks of polyolefins by incorporating into the polyolefin an effective amount of a lactamide having the formula: ##STR1## wherein R is alkenyl having from about 12 to about 22 carbon atoms. Optionally, there can be included with the lactamide a finely divided inorganic material. Also disclosed are compositions of matter comprising a polyolefin, such as homopolymers and copolymers of ethylene and propylene, the aforedescribed lactamide and optionally a finely divided inorganic material. Also described is the new compound, N-erucyl lactamide.Type: GrantFiled: November 12, 1991Date of Patent: April 27, 1993Assignee: Witco CorporationInventors: Bing-Lin Chen, James A. Barker
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Patent number: 5198490Abstract: The invention relates to dispersions which are obtainable from sheet silicates, a protective colloid and an aqueous dispersant and are suitable for the incorporation of sheet silicates into water-dilutable coating compositions. The dispersions according to the invention are obtainable using poly(propylene oxide) as the protective colloid, and the poly(propylene oxide) contains no hydrophobic terminal groups, has on average at least one hydroxyl group per molecule and may optionally contain up to 40% by weight of --CH.sub.2 --CH.sub.2 --O-- units.Type: GrantFiled: October 16, 1989Date of Patent: March 30, 1993Assignee: BASF Lacke & Farben AGInventors: Ralf Berg, Bodo Muller
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Patent number: 5196473Abstract: The present invention is directed to substantially dust-free granules. The granules are constituted by a normally dusty inorganic solid material and a water-dispersible nonionic vinyl polymer distributed thereon. The vinyl polymer promotes retention of dust size particles to the granules of the inorganic solid material.Type: GrantFiled: February 28, 1989Date of Patent: March 23, 1993Assignee: Oil-Dri Corporation of AmericaInventors: Rudolph C. Valenta, Leslie C. Giron
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Patent number: 5187215Abstract: A method for reducing the blocking properties of polyolefins by incorporating into the polyolefin an effective amount of a lactamide having the formula: ##STR1## wherein R is alkyl having from about 14 to 22 carbon atoms. Optionally, there can be included with the lactamide a finely divided inorganic material. Also disclosed are compositions of matter comprising a polyolefin, such as homopolymers and copolymers of ethylene and propylene, the aforedescribed lactamide and optionally a finely divided inorganic material.Type: GrantFiled: November 12, 1991Date of Patent: February 16, 1993Assignee: Witco CorporationInventor: Bing-Lin Chen
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Patent number: 5164460Abstract: Disclosed herein is a polyimide composite material which comprises a polyimide-containing resin and a layered clay mineral which is intercalated with organic onium ions and dispersed in the polyimide. Owing to the intercalated clay mineral, the composite material has improved gas and water vapor barrier properties and a small thermal expansion coefficient. Disclosed also herein is a process for producing a polyimide composite material which comprises the steps of intercalating a layered clay mineral with organic onium ions, adding by mixing the intercalated clay mineral to a solution of a monomer or prepolymer for polyimide, removing the solvent, and forming a polyimide. This process makes the layered clay mineral miscible with and dispersible in polyimide.Type: GrantFiled: May 30, 1991Date of Patent: November 17, 1992Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Kazuhisa Yano, Arimitsu Usuki, Akane Okada, Toshio Kurauchi
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Patent number: 5120785Abstract: Latex caulk compositions comprising 30 to 80% filler and 20 to 70% by weight of an emulsion polymer prepared for the interpolymerization of 30 to 70 parts by weight of a vinyl ester of an alkanoic acid; 15 to 60 parts of an alkyl (C.sub.2 and C.sub.8) acrylate or dialkyl (C.sub.2 to C.sub.10) maleate; 10 to 30 parts ethylene; 1 to 5 parts olefinically unsaturated carboxylic acid; 0 to 5 parts polyolefinically unsaturated monomer and 0 to 8 parts of a copolymerizable functional monomer containing hydroxyl, amide or methylol substituents, (to total 100 parts by weight).Type: GrantFiled: October 28, 1988Date of Patent: June 9, 1992Assignee: National Starch and Chemical Investment Holding CorporationInventors: James L. Walker, Paul R. Mudge
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Patent number: 5104919Abstract: A curable silicon composition comprising:(A) an organopolysiloxane containing at least two silicon-bonded unsaturated aliphatic hydrocarbon groups and having a viscosity of from 100 to 200,000 cSt at 25.degree. C.,(B) a vinyl group-containing organocyclopolysiloxane having the general formula (I): ##STR1## wherein R represents a hydrocarbon group having from 1 to 6 carbon atoms excluding unsaturated aliphatic hydrocarbon groups, and n represents an integer of from 3 to 8,(C) an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms in the molecule,(D) a platinum family metal catalyst, and(E) a triazole compound.This curable silicone composition has good curing properties and can produce cured products having a markedly small permanent compression set.Type: GrantFiled: March 15, 1990Date of Patent: April 14, 1992Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takehide Okami, Masanobu Miyakoshi, Hajime Kiriki
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Patent number: 5102948Abstract: Disclosed is a polyamide composite material comprising (A) 100 parts by weight of a polyamide resin and (B) 0.05 to 30 parts by weight of a layered silicate uniformly dispersed in the component (A), wherein the reaction ratio of the components (A) and (B) is 60% or less. Disclosed is also a method for preparing a polyamide composite material comprising making a composite in which a layered silicate, with a cation exchange capacity of 50 to 200 milliequivalents/100 g, is in the swelling condition in a dispersion medium; and mixing the composite with a polyamide resin.Type: GrantFiled: May 2, 1990Date of Patent: April 7, 1992Assignees: Ube Industries, Ltd., Toyota Jidosha Kabushiki Kaisha, Kabushiki KaishaInventors: Ryuichi Deguchi, Takeyoshi Nishio, Akane Okada
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Patent number: 5093389Abstract: A room temperature-curable composition comprising (A) a silanol-terminated polydiorganosiloxane having a viscosity measured at 25.degree. C. of from 100 to 200,000 cSt, (B) an epoxy-terminated polyether, (C) an organosilicon compound, (D) an inorganic filler, and (E) a curing catalyst. The composition is suitably used as a building sealant which causes no fouling of the areas surrounding joints even after applied to the joints.Type: GrantFiled: March 12, 1990Date of Patent: March 3, 1992Assignee: Toshiba Silicone Co., Ltd.Inventor: Chiyuki Shimizu
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Patent number: 5091445Abstract: A silicone sealant prepared by curing and cross-linking methylhydrosiloxanes by contacting and forming a mixture of an allyl amide or an allyl ester with at least one methylhydrosiloxane in the presence of a Group VIII metal catalyst, and heating the mixture of the allyl amide, the methylhydrosiloxane, a filler, and the Group VIII metal catalyst, in the presence of ambient moisture until the methylhydrosiloxane becomes cured and cross-linked.Type: GrantFiled: May 4, 1990Date of Patent: February 25, 1992Assignee: Dow Corning CorporationInventor: Anthony Revis
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Patent number: 5082891Abstract: The curable resin composition of the present invention consists of a curable resin having uniformly dispersed therein particles of a cured silicone rubber obtained from an organosiloxane composition curable by a platinum-catalyzed hydrosilation reaction, wherein said organosiloxane composition contains reaction products of an ethylenically unsaturated epoxy compound and an ethylenically unsaturated aromatic compound with the organohydrogenpolysiloxane present in said organosiloxane composition. Either or both of the epoxy compound and the aromatic compound can be prereacted with a portion of the silicon-bonded hydrogen atoms of the organohydrogenpolysiloxane.Type: GrantFiled: December 13, 1989Date of Patent: January 21, 1992Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Yoshitsugu Morita, Noriyasu Yokoyama, Keiji Yoshida
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Conductive agent for electrostatic coating of plastics and electrostatically coated plastic moldings
Patent number: 5071593Abstract: The electrostatic coating is effectively conducted on a plastic article with use of an electrically conductive agent comprising a polyurethane and an electrically conductive filler such as inorganic fine powder and organic substances.Type: GrantFiled: September 14, 1988Date of Patent: December 10, 1991Assignee: Polyplastics Co., Ltd.Inventors: Katsuhiko Takahashi, Yoshiharu Suzuki -
Patent number: 5036125Abstract: Single-component diorganopolysiloxane compositions, stable in storage in the absence of atmospheric moisture and crosslinkable into elastomeric state in the presence of moisture, well adapted, e.g., as sealants and adhesives for the construction industry, contain (A) a diorganopolysiloxane polymer having silanol endgroups, (B) a ketiminoxysilane crosslinking agent, (C) a stabilizing amount of an isocyanurate of the formula: ##STR1## (D) an inorganic filler material, and (E) a metal curing catalyst.Type: GrantFiled: June 29, 1990Date of Patent: July 30, 1991Assignee: Rhone-Poulenc ChimieInventor: Patrice Perrin
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Patent number: 5025057Abstract: In accordance with the present invention, there are provided 4-methyl-1-pentene polymer compositions comprising 90-10 parts by weight of 4-methyl-1-pentene polymer (A), 90-10 parts by weight of propylene polymer (B) and 70-10 parts by weight of inorganic filler (C), provided that the sum of (A), (B) and (C) total to 100 parts by weight. There are also provided 4-methyl-1-pentene polymer compositions 20-3 parts by weight of .alpha.-olefin copolymer (D) in addition to the above-mentioned components (A), (B) and (C), provided that the sum of (A), (B), (C) and (D) totals to 100 parts by weight.These compositions as illustrated above are capable of vacuum forming, injection blow-forming and the like, and they are excellent in rigidity at high temperatures, toughness at low temperature and impact strength.Type: GrantFiled: December 13, 1988Date of Patent: June 18, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Hiromi Shigemoto
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Patent number: 4996112Abstract: Organopolysiloxane compositions that are storage-stable under anhydrous conditions, but curable into elastomeric state in the presence of moisture and, thus, are well suited as sealants and coatings and which particularly strongly adhere to substrates used in the construction industry, contain at least one .alpha., .omega.-dihydroxydiorganopolysiloxane polymer; at least one ketiminoxysilane crosslinking agent therefor; a bonding agent including admixture, or reaction product of, (i) an aminoorganosilicon compound containing a primary amine group, with (ii) an organosilicon compound containing an epoxy functional group; and, advantageously, a filler material and a curing catalyst.Type: GrantFiled: April 7, 1989Date of Patent: February 26, 1991Assignee: Rhone-Poulenc ChimieInventors: Patrice Perrin, Andre Pierron
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Patent number: 4978706Abstract: A silicone composition which is stable in the absence of moisture, but cures to an elastomer upon exposure to moisture consists essentially of a hydroxyl endblocked polydiorganosiloxane; a difunctionalsilane having acetamido, urea, or urethane functional groups; and a tetrafunctionalsilane having oximino functional groups. A composition containing 100 parts by weight of the polydiorganosiloxane, from 0.1 to 7 parts by weight of difunctionalsilane, from 0.1 to 7 parts by weight of tetrafunctionalsilane, and a ratio of difunctionalsilane to tetrafunctionalsilane of from 0.1 to 3, and optional filler is useful as a sealant or adhesive, having an improved skin over time.Type: GrantFiled: August 28, 1989Date of Patent: December 18, 1990Assignee: Dow Corning CorporationInventors: John E. Dietlein, Russell P. Kamis, Jerome M. Klosowski
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Patent number: 4978704Abstract: Organopolysiloxane compositions that are storage-stable under anhydrous conditions, but curable into elastomeric state in the presence of moisture and, thus, are well suited as sealants and coatings and which particularly strongly adhere to substrate used in the construction industry, contain at least one .alpha., .omega.-dihydroxydiorganopolysiloxane polymer; at least one acyloxysilane crosslinking agent therefor; a bonding agent including admixture, or reaction product of, (i) an aminoorganosilicon compound containing a primary amine group, with (ii) an organosilicon compound containing an epoxy functional group; and, advantageously, a filler material and a curing catalyst.Type: GrantFiled: April 7, 1989Date of Patent: December 18, 1990Assignee: Rhone-Poulenc ChimieInventor: Patrice Perrin
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Patent number: 4933386Abstract: A polyarylene sulfide resin composition, being improved in thermal resistance and mouldability, comprises (A) 100 parts by weight of a polyarylene sulfide resin, (B) 0.Type: GrantFiled: February 17, 1989Date of Patent: June 12, 1990Assignee: Polyplastics Co., Ltd.Inventors: Toshikatsu Nitoh, Yoshihito Tsukamoto
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Patent number: 4918130Abstract: An eraser comprises a styrene thermoplastic elastomer as a matrix with a hydrocarbon resin and a polyolefin included therein. The styrene thermoplastic elastomer is selected from the group which consists of styrene-butadiene copolymers, styrene-isoprene copolymers, styrene-ethylene-butylene copolymers and styrene-ethylene-propylene copolymers, and the hydrocarbon is a terpene resin or hydrogenated terpene resin, and the polyolefin is polyethylene or polypropylene.Type: GrantFiled: December 9, 1988Date of Patent: April 17, 1990Assignee: Buncho CorporationInventors: Yosimi Kano, Koji Seki, Ryoichi Seki
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Patent number: 4898910Abstract: A silicone sealant which is stable in the absence of moisture and cures upon exposure to moisture to give an elastomer with a controllable modulus is produced by mixing a polydiorganosiloxane having both vinyl and alkoxysilethylene endblocking, alkoxy silane crosslinker, titanium catalyst, and optional filler. The modulus is controlled by varying the ratio of vinyl to alkoxysilethylene endblocking present on the polymer.Type: GrantFiled: September 26, 1988Date of Patent: February 6, 1990Assignee: Dow Corning CorporationInventors: Russell P. Kamis, Jerome M. Klosowski, Loren D. Lower
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Patent number: 4897437Abstract: Ethylene-acrylic acid type interpolymer compositions and films having increased slip and reduced block. A compositionally uniform interpolymer is compounded with at least one amide additive of the formula R.sub.1 --CO--NH--R.sub.2 in which R.sub.1 is selected from saturated alkyl groups having from 13 to 25 carbon atoms and mono-olefinically unsaturated alkyl groups having from 17 to 23 carbon atoms and in which R.sub.2 is selected from saturated alkyl groups having 14 to 26 carbon atoms and mono-olefinically unsaturated alkyl groups having from 18 to 24 carbon atoms; and optionally, finely divided inorganic. In another embodiment, a compositionally uniform or a compositionally non-uniform interpolymer is compounded with: (i) about 0.025-1 weight percent of saturated secondary fatty acid amide; (ii) about 0.025-1 weight percent of unsaturated or mixed unsaturated secondary fatty acid amide; and optionally (iii) about 0.025-1.5 weight percent of finely divided inorganic.Type: GrantFiled: January 22, 1988Date of Patent: January 30, 1990Assignee: The Dow Chemical CompanyInventors: Osborne K. McKinney, Alfred F. Castello, Michael E. Rowland
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Patent number: 4873272Abstract: A polyether having molecular weight from 1,000 to 50,000, end-blocked with hydrolyzable silyl groups and represented by the general formula (P): ##STR1## where R.sup.1, R.sup.2, R.sup.6 and R.sup.7 individually represent a divalent hydrocarbon group, R.sup.4 represents a monovalent hydrocarbon group, R.sup.8 represents an alkyl group with 1 to 6 carbon atoms, a represents a number from 1 to 3, m represents a number from 10 to 500, n represents a number of 1 or greater and --N.dbd.X.dbd.N-- represents a residue group of a diimino heterocyclic compound, from which nitrogen-bonded hydrogen atoms are eliminated, said diimino heterocyclic compound having no ##STR2## bond in a molecule is produced and utilized in room temperature curing compositions containing inorganic filler and curing catalyst. There is also disclosed a method for producing the above polyether by reacting polyoxyalkylene end-blocked with epoxy groups, diimino heterocyclic compound and organo silicon compound.Type: GrantFiled: November 9, 1987Date of Patent: October 10, 1989Assignee: Toshiba Silicone Co., Ltd.Inventors: Chiyuki Shimizu, Tamio Yoshida
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Patent number: 4866110Abstract: A thermoplastic molded product useful in vehicle linings such as door trim, shelf covering and package trays is formed from a resin into a thin plate. The product is formed from a substantially uniform admixture of from about 50 to 60 weight percent of a polypropylene, from 30 to 35 weight percent of a wood flour, from 2 to 3 weight percent of a leather powder, from 2 to 3 weight percent of a defatted rice bran powder, from 2 to 3 weight percent of an asbestos fiber, from 2 to 2.5 weight percent of a waste cotton, from 1.7 to 2.3 weight percent of a chopped glass fiber, and from 0.8 to 1.2 weight percent of a calcined diatomaceous earth.Type: GrantFiled: July 9, 1987Date of Patent: September 12, 1989Assignee: Han Il E'wha Co., Ltd.Inventor: Chang Y. Lee
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Patent number: 4826908Abstract: The extrudability of linear polymers of ethylene such as low density copolymers of ethylene and C.sub.4 --C.sub.10 olefins (LLDPE) into thin films is improved by adding small amounts, e.g., 0.02 to 2 weight percent ethylene-vinyl polymer to reduce melt fracture, head pressure and to obtain films having excellent anti-blocking characteristics. Optionally, diatomaceous earth is added to further reduce blocking.Type: GrantFiled: December 30, 1987Date of Patent: May 2, 1989Assignee: Mobil Oil CorporationInventors: Theresa L. Cunningham, Richard G. Shaw, Tien-Kuei Su
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Patent number: 4814364Abstract: Disclosed is an inorganic porous substance-containing styrenic resin composition comprising 100 parts by weight of a styrenic resin and from 0.5 to 30 parts by weight of an inorganic porous substance. The composition is formed into packaging materials in the form of film, tray, bag or other containers, and these have an excellent freshness-keeping effect for packaging plants, especially vegetables and fruits. The effect for keeping the taste and flavor of vegetables and fruits is remarkable, and the composition of the invention is useful as a packaging material.Type: GrantFiled: March 1, 1988Date of Patent: March 21, 1989Assignee: Nippon Steel Chemical Co., Ltd.Inventors: Haruhiko Yoshizaki, Norihito Kawaguchi
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Patent number: 4786670Abstract: A non-asbestos compressible sheet material usable for high-temperature gaskets preferably containing 10-50% by weight of an inorganic fibrous material, 10-90% by weight of an inorganic filler material, 4-30% by weight of an organic elastomeric binder, 2-10% by weight of an inorganic silicate binder and 1.0-10% of an organic fibrous material. The sheet material of the present invention may be manufactured on standard paper-making machinery.Type: GrantFiled: January 9, 1987Date of Patent: November 22, 1988Assignee: Lydall, Inc.Inventors: Douglas Tracy, Frank W. Major
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Patent number: 4778860Abstract: The water permeability of cured thermosetting organic resin compositions is reduced and the dimensional stability of these compositions during molding is improved by the addition to the curable resin composition of a finely divided, cured organosiloxane material prepared from a curable organopolysiloxane, a curing agent for the organopolysiloxane, an optional silica filler and an aromatic hydrocarbon compound containing a substituted benzene ring where the substituent is a monovalent ethylenically unsaturated hydrocarbon radical or an alkenyloxy radical.Type: GrantFiled: August 31, 1987Date of Patent: October 18, 1988Assignee: Toray Silicone Company, Ltd.Inventors: Yoshitsugu Morita, Shoichi Shida
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Patent number: 4761447Abstract: Heat-vulcanizable organopolysiloxane compositions well adopted for extrusion and molding, and facilely converted into elastomeric shaped articles having improved physical and electrical properties, e.g., seals and sections, include a diorganopolysiloxane oil containing from 0.05 to 3 mol % of vinylsiloxy recurring units, as well as an amine having a pKa greater than 7.5 in aqueous solution at 25.degree. C. and a boiling point of less than 270.degree. C. at atmospheric pressure.Type: GrantFiled: February 27, 1987Date of Patent: August 2, 1988Assignee: Rhone-Poulenc ChimieInventors: Ming Shen, Robert Lagarde
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Patent number: 4751262Abstract: Ethylene-acrylic acid type interpolymer compositions and films having increased slip and reduced block. A compositionally uniform interpolymer is compounded with at least one amide additive of the formula R.sub.1 -CO-NH-R.sub.2 in which R.sub.1 is selected from saturated alkyl groups having from 13 to 25 carbon atoms and mono-olefinically unsaturated alkyl groups having from 17 to 23 carbon atoms and in which R.sub.2 is selected from saturated alkyl groups having 14 to 26 carbon atoms and mono-olefinically unsaturated alkyl groups having from 18 to 24 carbon atoms; and optionally, finely divided inorganic. In another embodiment, a compositionally uniform or a compositionally non-uniform interpolymer is compounded with: (i) about 0.025-1 weight percent of saturated secondary fatty acid amide; (ii) about 0.025-1 weight percent of unsaturated or mixed unsaturated secondary fatty acid amide; and optionally (iii) about 0.025-1.5 weight percent of finely divided inorganic.Type: GrantFiled: July 2, 1987Date of Patent: June 14, 1988Assignee: The Dow Chemical CompanyInventors: Osborne K. McKinney, Alfred F. Castello, Michael E. Rowland
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Patent number: 4749598Abstract: The surface smoothness and adhesion to metal of poly(arylene sulfide) is improved by the addition of an effective amount of a silica composition.Type: GrantFiled: February 19, 1987Date of Patent: June 7, 1988Assignee: Phillips Petroleum CompanyInventor: Dawn E. Miles
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Patent number: 4748166Abstract: Storage stable, water-free, RTV organopolysiloxane adhesives curable in the presence of water or atmospheric moisture, and comprising a dihydroxydiorganopolysiloxane polymer, fillers, an amine fraction and a curing catalyst, are characterized by incorporation therein of a polyalkoxylated organosilane having the formula:R'.sub.x Si[(OCH.sub.2 CH.sub.2).sub.p OCH.sub.3 ].sub.4-xwherein R' is methyl, vinyl, allyl, methallyl or phenyl, and p and x are each one or two.Type: GrantFiled: May 28, 1986Date of Patent: May 31, 1988Assignee: Rhone-Poulenc IndustriesInventors: Alain Gautier, Bernard Laisney, Michel Letoffe
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Patent number: 4737561Abstract: A process for producing room temperature-vulcanizable silicone compositions which comprises mixing, in a first step, crosslinkable diorgano(poly)siloxanes, filler(s) and either catalyst(s) or crosslinking agent(s) and a part or all of the optional additives to be used in a continuusly operating closed mixer, and in a second step, metering the crosslinking agents and/or catalyst(s) not added in the first step and the remainder of the optional additivies to be used into the mixture thus obtained in an oscillating pilgrim-step kneader where the mixture is homogenized and degassed.Type: GrantFiled: December 31, 1986Date of Patent: April 12, 1988Assignee: Wacker-Chemie GmbHInventors: Fridolin Stary, Peter Kremer
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Patent number: 4728699Abstract: A composition comprising an aromatic polycarbonate in admixture with a diatomaceous earth, the said diatomaceous earth having a major quantity of cristabolite, the quantity of diatomaceous earth such that the kinetic coefficient of friction is substantially decreased when a self supporting film is prepared from the composition.Type: GrantFiled: November 4, 1985Date of Patent: March 1, 1988Assignee: General Electric CompanyInventor: Ping Y. Liu
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Patent number: 4728687Abstract: A vulcanizable silicone elastomer composition which has novel crosslinking points comprises (A) 100 parts by weight of a polyorganosiloxane having a polymerization degree of at least 100, wherein the organic groups are selected from monovalent substituted and unsubstituted hydrocarbon groups and are attached to silicon atoms at a rate, on average, in the range of 1.98 to 2.02 per silicon atom and at least two of the organic groups are monovalent hydrocarbon groups possessing at least five carbon atoms and a carbon-carbon double bond issuing from a silicon atom through at least one carbon atom, (B) 5 to 200 parts by weight of an inorganic filler having a specific surface area of at least 50 m.sup.2 /g, and (C) 0.05 to 15 parts by weight of an organic peroxide.Type: GrantFiled: January 29, 1987Date of Patent: March 1, 1988Assignee: Toshiba Silicone Co., Ltd.Inventors: Junichiro Watanabe, Yuichi Funahashi, Kazuo Sugiura, Hironori Matsumoto
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Patent number: 4720516Abstract: A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.Type: GrantFiled: December 16, 1982Date of Patent: January 19, 1988Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori, Yasuaki Ii
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Patent number: 4716188Abstract: A paint for outdoor surfaces and surfaces in wet rooms, especially for concrete walls exposed to strong weathering, contains pigment, binder of which a part is (meth)acrylic polymers and/or copolymers, volatile solvent(s), fillers and optionally known additives and it is characterized by (a) having a pigment-volume concentration of 47 to 65%, preferbly 55 to 60%, (b) containing diatom shells as part of the filler, and (c) containing one or more oligomieric alkyl-alkoxy-organosiloxanes as part of the continuous binder phase. There is obtained on one hand a high degree of imperviousness to water in the liquid form and on the other hand a high degree of diffusion of aqueous vapor.Type: GrantFiled: June 6, 1986Date of Patent: December 29, 1987Inventors: Oskar Mariusson, Jon Bjarnason
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Patent number: 4670500Abstract: A surface coating composition comprising an amino-functional silicone polymer, a metal chelated acrylic polymer a hydrocarbon solvent and water. The metal-chelated acrylic polymer preferably comprises zinc, and the composition may further comprise abrasive materials, surfactants, thickeners and stabilizers. The surface coating composition is particularly adapted for providing a glossy and durable finish on a surface.Type: GrantFiled: December 20, 1985Date of Patent: June 2, 1987Assignee: Pennzoil CompanyInventor: D. V. Satyanarayana Gupta
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Patent number: 4666063Abstract: An integral seal member is formed across the outlet in the neck of a tamper evident, thermoplastic container by adding to the thermoplastic material such as polyethylene, 3% to 16%, and preferably about 8% by weight, of an anhydrous solid inorganic particulate additive such as an anhydrous siliceous material or calcium carbonate so that the material becomes brittle enough that the seal member tears cleanly from the neck within the confines of an undercut at the interface between the seal member and neck. Torque is applied to the seal member by providing in the top of a conventional screw cap which forms a resealing closure for the container once opened, a recess with serrations which, when the cap is removed and turned upside down, engage serrations on the peripheral edge of the seal.Type: GrantFiled: August 23, 1985Date of Patent: May 19, 1987Assignee: Wheeling Stamping CompanyInventors: George H. Holoubek, Eugene M. Anthony, Allan B. Hans
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Patent number: 4613643Abstract: A process for the preparation of soft porous sheets, comprises forming into a sheet a composition comprising (i) 40 to 80% by weight of an inorganic filler and (ii) 60 to 20% by weight of a polyolefin type thermoplastic elastomer composition comprising at least 50% by weight of a polyolefin type thermoplastic elastomer substantially free of a polar group, in which the tensile stress at a temperature of 25.degree. C. under 100% stretching (100% modulus) is 10 to 100 Kg/cm.sup.2, the elongation at break under stretching is at least 100% and the permanent strain under 100% stretching is less than 50% and up to 50% by weight of a thermoplastic plastomer, and stretching the sheet at a temperature lower than the softening temperature of the polyolefin type thermoplastic elastomer. A porous sheet obtained according to this process has a good combination of flexibility, air permeability and water resistance.Type: GrantFiled: February 9, 1984Date of Patent: September 23, 1986Assignee: Tokuyama Soda Kabushiki KaishaInventors: Shunichi Nakamura, Kenji Okamura, Shingo Kaneko, Kiyoshi Sumi
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Patent number: 4604321Abstract: An adsorbing agent and a method of preparation thereof is disclosed, which agent is capable of selectively adsorbing mercury from various mercury-containing gaseous or aqueous media at high rate of efficiency. The agent essentially comprises a porous material having a specific surface area in excess of 10 m.sup.2 /g. and a conjugated diolefin lower polymer deposited in a predetermined amount on the porous material.Type: GrantFiled: September 27, 1984Date of Patent: August 5, 1986Assignee: Nippon Petrochemicals Co., Ltd.Inventors: Mitsuo Okahara, Isao Ikeda
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Patent number: 4600744Abstract: The invention relates to a process for the preparation of clay mineral-containing gels with stabilized structure and reversible water absorption ability.According to the invention an aqueous suspension containing a thixotropic, activated, swelling clay mineral of three-layer structure and/or a swelling chain silicate is treated with a water soluble polymer capable of reacting with the clay mineral and/or chain silicate, the clay mineral:polymer:water ratios are determined at which the resistance of medium of the resulting suspension is at least ten times higher than that of the initial, polymer-free suspension, and then the components are reacted with each other in the pre-determined ratios.Type: GrantFiled: October 25, 1984Date of Patent: July 15, 1986Assignee: MTA Termeszettudomanyi Kutato LaboratoriumaiInventors: Oszkar Libor, Gabor Nagy, Tamas Szekely
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Patent number: 4599370Abstract: A powdered elastomeric composition is formed by combining a powder elastomer and a powdered predispersion of liquid or pasty components, such as process oil, lubricants and waxes, in a dry powder filler. The powdered predispersion is combined with the powder elastomer using a ribbon blender to form a consistent homogenous powder dry blend which can be directly injection molded without any additional mixing other than that occurring in the extruder portion of the injection molding apparatus.Type: GrantFiled: December 6, 1984Date of Patent: July 8, 1986Assignee: Plastic Specialties and Technologies, Inc.Inventors: Richard F. Grossman, Francis W. McKane, Jr.
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Patent number: 4598110Abstract: A resin composition comprising(I) a granular or powdery resin which is a condensation product of a phenol, an aldehyde and optionally a nitrogen-containing compound having at least two active hydrogens and is characterized by (A) containing spherical primary particles and their secondary agglomerated particles each having a particle diameter of 0.1 to 150 microns, (B) having such a size that at least 50% by weight thereof can pass through a 100 Tyler mesh sieve, and (C) having a free phenol content, determined by liquid chromatography, of not more than 500 ppm, and(II) at least one member selected from the group consisting of (1) a rubbery elastic material, (2) a thermoplastic resin and (3) a curable resin other than said granular or powdery resin (I) and/or a filler material other than said granular or powdery resin (I).Type: GrantFiled: June 12, 1984Date of Patent: July 1, 1986Assignee: Kanebo Ltd.Inventors: Hiroaki Koyama, Shigeo Shimizu
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Patent number: 4596845Abstract: A resin composition comprising(I) a granular or powdery resin which is a condensation product of a phenol, an aldehyde and optionally a nitrogen-containing compound having at least two active hydrogens and is characterized by (A) containing spherical primary particles and their secondary agglomerated particles each having a particle diameter of 0.1 to 150 microns, (B) having such a size that at least 50% by weight thereof can pass through a 100 Tyler mesh sieve, and (C) having a free phenol content, determined by liquid chromatography, of not more than 500 ppm, and(II) at least one member selected from the group consisting of (1) a rubbery elastic material, (2) a thermoplastic resin and (3) a curable resin other than said granular or powdery resin (I) and/or a filler material other than said granular or powdery resin (I).Type: GrantFiled: July 23, 1985Date of Patent: June 24, 1986Assignee: Kanebo Ltd.Inventors: Hiroaki Koyama, Shigeo Shimizu
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Patent number: 4590123Abstract: A soft, low-resilience, cured rubber composition is prepared by mixing(a) 100 parts by weight of a polymeric material comprising a styrene-butadiene copolymer or styrene-butadiene copolymer mixture having a styrene content of 53 to 75% by weight, and 0 to 40% by weight of the polymeric material of another rubber ingredient,(b) 30 to 300 parts by weight of a filler, and(c) 5 to 100 parts by weight of a plasticizer, adding effective amounts of a vulcanizing agent and a vulcanizing accelerator to the mixture, and then heat curing the mixture. A similar composition further containing a foaming agent may be heat cured into a low-resilience rubber foam. Rubber and foamed rubber compositions have improved vibration-attenuating and shock-absorbing properties.Type: GrantFiled: July 16, 1985Date of Patent: May 20, 1986Assignee: Bridgestone Tire Co., Ltd.Inventors: Takatsugu Hashimoto, Takashi Ohashi
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Patent number: 4588769Abstract: A composition which has excellent fire resistance properties, never hardens or slumps, and is reusable is provided. The composition can be extruded into a caulking or sealing compound which has a high fire resistance rating of VO as measured by UL 94 Test Procedure.The fire resistant composition of the present invention comprises:(a) 45-60 wt. % of filler;(b) 12-30 wt. % ceramic fiber;(c) 0.1-0.5 wt. % reinforcing agent;(d) 18-30 wt. % tackifying agent; and(e) 2-5 wt. % oleoresinous oil.Type: GrantFiled: January 31, 1985Date of Patent: May 13, 1986Assignee: Manville Sales CorporationInventors: Olavi E. Vehmas, Bernard L. Kotyuk, John M. Pallo
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Patent number: 4587278Abstract: Sound-insulating boards which are based on mineral fibers and thermoplastic binders and may or may not additionally contain fillers, flameproofing agents and water repellants contain, as the binder, from 4 to 20%, based on the weight of the mineral fibers, of polymers having a glass transition temperature of from 30.degree. to 80.degree. C. and consisting of not less than 60% by weight, based on the copolymer, of (meth)acrylates of 1 to 4 carbon atoms and as much as 40% by weight of acrylonitrile and/or styrene.Type: GrantFiled: April 12, 1984Date of Patent: May 6, 1986Assignee: BASF AktiengesellschaftInventors: Bernhard Dotzauer, Hans Kast, Gernot Franzmann, Gregor Ley, Wilhelm F. Beckerle, Wolfgang Schilder
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Patent number: 4550130Abstract: A polyolefin resin composition comprising a polyolefin modified with an unsaturated carboxylic acid, at least one member selected from the group consisting of polyepoxides, polyisocyanates, and polyamines, and a reinforcement.Type: GrantFiled: February 28, 1984Date of Patent: October 29, 1985Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Kazuo Kishida, Isao Sasaki, Hiroshi Mori, Yasuaki Ii
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Patent number: 4546127Abstract: A soft, low-resilience, cured rubber composition is prepared by mixing(a) 100 parts by weight of a polymeric material comprising a styrene-butadiene copolymer or styrene-butadiene copolymer mixture having a styrene content of 53 to 75% by weight, and 0 to 40% by weight of the polymeric material of another rubber ingredient,(b) 30 to 300 parts by weight of a filler, and(c) 5 to 100 parts by weight of a plasticizer, adding effective amounts of a vulcanizing agent and a vulcanizing accelerator to the mixture, and then heat curing the mixture. A similar composition further containing a foaming agent may be heat cured into a low-resilience rubber foam. Rubber and foamed rubber compositions have improved vibration-attenuating and shock-absorbing properties.Type: GrantFiled: August 13, 1984Date of Patent: October 8, 1985Assignee: Bridgestone Tire Co., Ltd.Inventors: Takatsugu Hashimoto, Takashi Ohashi