Aromatic Hydrocarbon Patents (Class 524/484)
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Patent number: 6545075Abstract: A thermoplastic resin composition improved in compatibility, molding or forming ability, melt-flow properties and mechanical properties, which comprises 100 parts by weight of a resin component containing 40 to 99 wt. % of a poly(arylene sulfide) (A) and 1 to 60 wt. % of polyamide-imide (B), and 0.01 to 10 parts by weight of a silane compound (C) containing at least one functional group selected from the group consisting of amino, ureido, epoxy, isocyanate and mercapto groups.Type: GrantFiled: May 19, 2000Date of Patent: April 8, 2003Assignee: Kureha Kagaku Kogyo K.K.Inventors: Naomitsu Nishihata, Hiroyuki Sato, Masahito Tada
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Publication number: 20030065048Abstract: Radiation curable adhesive comprising an epoxidized block copolymer, a saturated block copolymer and/or a rosin derived alcohol, and a photoinitiator.Type: ApplicationFiled: June 26, 2001Publication date: April 3, 2003Inventor: Charles W. Paul
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Publication number: 20030060557Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneadingType: ApplicationFiled: June 13, 2002Publication date: March 27, 2003Inventors: Michihisa Tasaka, Akihiro Tamura
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Publication number: 20020188064Abstract: The present invention is directed to a polymeric composition including a poly(alkenyl-co-maleimide) and an inorganic salt. Optionally, an extender is included. The composition exhibits good strength and vibration damping properties.Type: ApplicationFiled: May 22, 2001Publication date: December 12, 2002Applicant: Bridgestone/Firestone Research, Inc.Inventors: Xiaorong Wang, Victor J. Foltz
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Patent number: 6465558Abstract: This invention relates to a solvent based adhesive composition including a major amount of a solvent system and a minor amount of an adhesive polymer system. The solvent system preferably includes a terpene and an aldehyde, ketone, or an aromatic solvent. The adhesive polymer system preferably includes one or a blend of polymers that dissolve, at least in part, in the solvent solution. The components of the solvent adhesive are compatible in that they do not separate upon standing. The solvent based adhesive composition provides good adhesion between polymer articles such as, for example, polyolefin and acrylic films, as well as good adhesion between polymeric articles and wood or metal substrates.Type: GrantFiled: February 5, 2001Date of Patent: October 15, 2002Assignee: Ferro CorporationInventors: Anthony S. Scheibelhoffer, Andrew M. Rohn, James T. Kempthorn, Kenneth D. Zabielski, Deenadayalu Chundury, Timothy W. Birch
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Patent number: 6455627Abstract: The present invention is a hot melt pressure sensitive positioning adhesive for use with an absorbent article. The adhesive comprises: (a) from 6 to less than 15 percent by weight, of the total of (a), (b) and (c) of a blend of (i) from 40 to 95% by weight of a hydrogenated styrene-(butadiene and/or isoprene)-styrene block copolymer; and (ii) from 5 to 60% by weight of a blend of a hydrogenated styrene-isoprene-styrene-isoprene block copolymer; and (iii) from 0 to 40% by weight of an amorphous ethylene/propylene copolymer having a number average molecular weight of 9,000 to 30,000; and (b) from 50 to 80 percent by weight, of the total of (a), (b) and (c), of a tackifying resin which has an aromaticity such that the MMAP cloud point is at least 45° C.; and (c) from 5 to 35 percent by weight, of the total of (a), (b) and (c), of a plasticizer.Type: GrantFiled: June 22, 2000Date of Patent: September 24, 2002Assignee: Kraton Polymers US LLCInventors: Noël Raymond Maurice De Keyzer, Carolyn Ann Stoner
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Patent number: 6433062Abstract: The invention provides a process for the preparation of a thermoplastic elastomeric resin composition comprising melt kneading (a) 100 parts by weight of a block copolymer consisting of at least two polymeric blocks (A) composed mainly of a vinyl aromatic compound and at least one polymeric block (B) composed mainly of a conjugated diene compound, and/or a hydrogenated block copolymer obtained by hydrogenating said block copolymer, (b) 40 to 240 parts by weight of a non-aromatic softening agent for rubber, (c) 5 to 300 parts by weight of polyethylene or a copolymer composed mainly of ethylene, and (d) 5 to 60 parts by weight of polypropylene or a copolymer composed mainly of propylene, characterized in that the process comprises the following steps: (I) melt kneading the whole amounts of components (a), (b) and (d) and a part of component (c), and, at the same time or subsequently, melt kneading these with (f) an organic peroxide, and (II) melt kneading the product obtained from step (I) with the remaiType: GrantFiled: July 10, 1997Date of Patent: August 13, 2002Assignee: Riken Vinyl Industry Co., Ltd.Inventors: Michihisa Tasaka, Akihiro Tamura
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Patent number: 6433069Abstract: This invention relates to a removable grade hot melt pressure sensitive adhesive comprising from about 5% to about 30% by weight of the adhesive of a block copolymer having styrene endblocks and ethylene/butylene or ethylene/propylene midblocks and having a coupling efficiency of less than about 65% and a melt index of greater than about 20 grams/10 minutes; from about 10% to about 50% by weight of the adhesive of at least one block copolymer having styrene endblocks and a coupling efficiency from about 65% to about 100%; from about 20% to about 60% by weight of the adhesive of a tackifying resin and from about 10% to about 40% by weight of the adhesive of a liquid plasticizing oil.Type: GrantFiled: June 14, 2000Date of Patent: August 13, 2002Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Susan T. Oeltjen, Jeffrey S. Lindquist, Yoshihiro Kodama, Daisuke Asai
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Patent number: 6429248Abstract: A coating composition comprising a solution of an electrically-conductive polymer and an organic solvent media wherein the solvents are selected from the group consisting of alcohols, ketones, cycloalkanes, arenes, esters, glycol ethers and their mixtures; the media having a water content of less than 12 weight percent. Such a coating composition provides a means to protect an imaging element against the accumulation of static electrical charges before and after image processing while also providing the element with improved manufacturability and physical properties.Type: GrantFiled: June 13, 2001Date of Patent: August 6, 2002Assignee: Eastman Kodak CompanyInventors: Dwight W. Schwark, Debasis Majumdar, Charles C. Anderson, Robert J. Kress
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Patent number: 6414083Abstract: A dispersion has particles dispersed in a continuous aqueous dispersion medium. The particles, preferably no more than about 2 micrometers in size, are formed of a mixture of styrene-ethylene/butylene-styrene (S-EB-S) block copolymer having end blocks each with a weight average molecular weight of more than about 15,000 Daltons and an oil such as a mineral oil. The dispersion medium is a mixture of water and a surfactant. Articles are prepared by dipping a form into the dispersion and withdrawing the form to leave a film of the dispersion on the form. The water is evaporated from the film, leaving a coherent extensible film on the form.Type: GrantFiled: September 11, 2001Date of Patent: July 2, 2002Assignee: Tactyl Technologies, Inc.Inventor: Sebastian Plamthottam
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Patent number: 6399697Abstract: Process oil which satisfies requirements that a content of a polycyclic aromatic compound is less than 3% by weight, a content of an aromatic hydrocarbon is 18% by weight or more, a content of a polar compound is between 11 and 25% by weight, a kinematic viscosity at 100° C. is between 10 and 70 mm2/s, and a flash point is 210° C. or more.Type: GrantFiled: February 8, 2000Date of Patent: June 4, 2002Assignee: Idemitsu Kosan Co., Ltd.Inventors: Masami Takasaki, Meishi Tanaka, Hisao Anzai, Masashi Nakamura, Chisato Endo
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Patent number: 6391960Abstract: A multipurpose hot melt adhesive comprising endblock resin in combination with a radial or linear SBS copolymer having a solution viscosity greater than 1000 cPs at 25% in toluene suitable for use as both a construction and elastic attachment adhesive in disposable products is disclosed.Type: GrantFiled: April 13, 2000Date of Patent: May 21, 2002Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mahesh Sambasivam, Charles W. Paul
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Patent number: 6344518Abstract: A conjugated diolefin copolymer rubber and a rubber composition which can produce vulcanized products exhibiting well-balanced improved properties such as wet skid properties, low hysteresis loss properties, abrasion resistance, and breaking strength irrespective of the types and combinations of fillers to be added, and is useful as a tread material for low fuel consumption tires, large tires, and high performance tires. A conjugated diolefin copolymer rubber is prepared by the copolymerization of a conjugated diolefin and a vinyl aromatic compound, and (1) has a content of the bonded vinyl aromatic compound of 5-50 wt %, (2) contains 0.01-5.0 mmol of an alkoxysilyl group having substantially non-hydrolyzable Si—O—R bond (wherein R indicates a hydrocarbon group having 4-20 carbon atoms) and 0.01-2.0 mmol of a tin-carbon bond for 100 g of the copolymer rubber, and (3) has a polymodal-type molecular weight distribution.Type: GrantFiled: November 4, 1999Date of Patent: February 5, 2002Assignee: JSR CorporationInventors: Naokazu Kobayashi, Toshihiro Tadaki, Hiroshi Akema
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Publication number: 20020006999Abstract: A polyether copolymer comprising (A) an aromatic polyether block and (B) an aliphatic polyether block is provided.Type: ApplicationFiled: April 13, 2001Publication date: January 17, 2002Inventors: Yuji Yoshida, Akira Yokota, Hyuncheol Choi
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Publication number: 20020002231Abstract: New primers for the improvement of the adhesion of cross-linking adhesive systems to polyolefinic thermoplastic materials such as e.g. polypropylene, polyethylene or EPDM are disclosed. Said primers, on the one hand are characterized by a simple method of production and good storage stability, on the other hand by good wetting and good homogeneous film forming characteristics, said film forming characteristics enabling a uniform thickness of the layer, leading to good adhesion qualities. Essential constituent of such primers are prepolymers based on hydrated polyisoprene diol.Type: ApplicationFiled: April 30, 2001Publication date: January 3, 2002Inventors: Peter W. Merz, Shingo Tsuno
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Publication number: 20010034393Abstract: The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: ApplicationFiled: June 5, 2001Publication date: October 25, 2001Inventors: Xiaorong Wang, Victor J. Foltz, Takahiro Matsuse, Naruhiko Mashita, Shinichi Toyosawa
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Publication number: 20010034394Abstract: A process for preparing hot-melt pressure-sensitive adhesives from aqueous dispersions based on polyacrylate, and pressure-sensitively adhesive articles produced therefrom, which comprises producing highly concentrated aqueous dispersions with polymer contents between 68% by weight and 87% by weight of gel-free, molecularly-dispersely meltable polymer particles with an at least bimodal size distribution in size ranges between 0.5 &mgr;m and 1000 &mgr;m .Type: ApplicationFiled: March 22, 2001Publication date: October 25, 2001Inventors: Peter Gleichenhagen, Annemarie Muller
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Patent number: 6306943Abstract: This invention pertains to the art of solvent blends and solvent/resin blends. More particularly, this invention pertains to blends that reduce the atmospheric reactivity of some high volatile organic compounds. The invention is particularly applicable to solvent blends and solvent/resin blends that combine volatile organic compounds with newly discovered zero volatile organic compounds for use adhesives, coatings, inks, cleaning and blowing agents and the like and will be described with particular reference thereto. However, it will be appreciated that the invention may be advantageously employed in other environments and applications.Type: GrantFiled: February 29, 2000Date of Patent: October 23, 2001Assignee: Polymer Solvents, LLCInventor: Richard G. Henry
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Patent number: 6258885Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs, etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs, etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: January 13, 1999Date of Patent: July 10, 2001Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
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Patent number: 6248825Abstract: The present invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(alkenyl benzene-co-maleimide) polymer with a maleated polyalkylene and an alkyl diamine under substantially dry conditions sufficient to form a polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product; and, dispersing the polyalkylene grafted poly(alkenyl benzene-co-maleimide) polymer product with an extender oil sufficient to form the gel. The present invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: May 6, 1998Date of Patent: June 19, 2001Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Takahiro Matsuse, Naruhiko Mashita, Shinichi Toyosawa
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Patent number: 6218588Abstract: The invention relates to aromatic modified aliphatic hydrocarbon resins giving excellent balance between tack and shear properties even at low coating weights. These resins are characterized in that they have a Ring and Ball (R&B) softening point of 94° C. or lower, a weight average molecular weight (Mw) of not more than 2000 Dalton, a Z-average molecular weight (Mz) of not more than 6000 Dalton and a mixed methylcyclohexane aniline cloud point (MMAP) between 25 and 45° C. The aromatic modified aliphatic hydrocarbon resins of the invention may be prepared by subjecting polymerization feeds containing petroleum feeds which comprise (a) C5 and C6 olefins and/or diolefins including cycloolefins, (b) aromatic monomers and (c) (di-)cyclodiolefins to a Friedel-Crafts polymerization. The invention is also directed to the use of the aromatic modified aliphatic hydrocarbon resins as mono-tackifiers in adhesive formulations as well as to an adhesive tape comprising these resins.Type: GrantFiled: February 8, 1999Date of Patent: April 17, 2001Assignee: Hercules IncorporatedInventors: Nicolaas Adriaan Dommisse, Christiaan Pieter Louis Charles Donker, Michael Hendrikus Theelen, Jacobus van Rijn, Gerard Arie Verrijzer
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Patent number: 6218457Abstract: A polybutylene based hot melt adhesive composition having a variety of end uses, particularly in construction and elastic attachment applications for nonwoven articles such as disposable diapers. Unlike typical hot melt adhesives, the present composition can withstand high peel and shear loads at elevated temperatures for extended periods of time without experiencing catastrophic bond failure. The composition includes polybutylene polymer or a mixture of polybutylene and polyolefin polymers, and a stabilizer, with the remaining ingredients chosen from one or more of a polyolefin polymer, a tackifier resin, a plasticizer, or a wax. The hot melt adhesive composition can be applied using common application techniques such as extruding or spraying.Type: GrantFiled: March 3, 1999Date of Patent: April 17, 2001Assignee: Ato Findley, Inc.Inventors: Margaret M. Fralich, Mark Alper
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Patent number: 6214935Abstract: An improved hot-melt pressure-sensitive adhesive (HMPSA) composition contains an elastomeric component, such as a blend of SIS and SB block copolymers, and a tackifying component comprising one or more intermediate softening point resins (ISPRs) having a ring and ball softening point of from 35 to 60° C. The improved adhesive compositions are characterized by reduced volatility, less bleed and staining tendencies, and improved overall adhesive performance. The invention also provides improved label constructions in which a release liner is coated with an HMPSA composition and laminated to a flexible facestock. Notably, even when low basis weight paper facestocks are used, the construction can be converted at high speeds.Type: GrantFiled: July 15, 1998Date of Patent: April 10, 2001Assignee: Avery Dennison CorporationInventors: Yukihiko Sasaki, Jesse C. Ercillo, Catharina Eyken, Le Hoa Hong, Henk de Koning
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Patent number: 6207748Abstract: Disclosed are hot melt adhesives comprising ethylene/alpha-olefin copolymers prepared with either supported or unsupported metallocene-alumoxane catalysts for applications in hot melt adhesives used in automotive product assembly, packaging and food packaging. These ethylene copolymers have weight average molecular weight ranging from about 20,000 to about 100,000 and comonomer weight percent ranging from about 6 to about 30. The hot melt adhesive composition includes the ethylene copolymer and a compatible tackifier at a ratio of tackifier to copolymer of from 70:30 to 30:70 and may also include up to 30 weight percent of a paraffinic and microcrystalline wax of the copolymer and tackifier.Type: GrantFiled: September 2, 1998Date of Patent: March 27, 2001Assignee: Exxon Chemical Patents, Inc.Inventors: Mun Fu Tse, Aspy Keki Mehta, Vince Leo Hughes
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Patent number: 6201045Abstract: A non-birefringence optical resin material is obtained by forming a transparent matrix from a polymeric resin having an orientation birefringence with a positive or negative sign, adding a low molecular weight substance exhibiting an orientation birefringence with a sign opposite to that of the orientation birefringence of the polymeric resin for the matrix and thus offsetting the orientation birefringence of the polymeric resin for the matrix with the orientation birefringence of the low molecular weight substance.Type: GrantFiled: October 21, 1997Date of Patent: March 13, 2001Inventor: Yasuhiro Koike
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Patent number: 6184285Abstract: Novel hot melt construction adhesives for disposable articles, such as diapers, sanitary napkins, medical gowns, surgical drapes, and the like, are described which offer superior properties versus currently available hot melt adhesives. These hot melt construction adhesive compositions comprise a blend of styrene-isoprene block copolymer containing at least about 25 weight percent styrene and styrene-butadiene block copolymer containing at least about 25 weight percent styrene, at least one compatible tackifying resin and at least one plasticizer. The hot melt construction adhesive possesses a viscosity no greater than about 25,000 mPa·s at about 140° C., a shear adhesion failure temperature of at least about 60° C., and a static shear time to failure of no less than about 25 hours at about 23°.Type: GrantFiled: November 5, 1998Date of Patent: February 6, 2001Assignee: Henkel CorporationInventors: Stephen F. Hatfield, Alejandro Matassa, Robert Goodman
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Patent number: 6172156Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 40% by weight of a block copolymer having a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100° C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 40% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.Type: GrantFiled: June 12, 1997Date of Patent: January 9, 2001Assignee: H. B. Fuller Licensing & Financing, Inc.Inventors: Jeffrey S. Lindquist, Lisa L. Ryan
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Patent number: 6162859Abstract: The present invention is directed to hot melt pressure sensitive adhesive compositions, that exhibit excellent adhesion properties and improved thermal stability, said compositions comprising:a) 1 to 30 parts of styrene-butadiene-styrene triblock copolymer;b) 1 to 30 parts of styrene-isoprene-styrene triblock copolymer;c) 5 to 50 parts of a tackifier compatible with the butadiene and isoprene midblocks, but not compatible with the styrene end blocks;d) 5 to 70 parts of a tackifier compatible with the butadiene and isoprene midblocks, and the styrene end blocks;e) 5 to 30 parts of a tackifier compatible with the styrene end blocks, but not compatible with the butadiene and isoprene midblocks;f) 5 to 30 parts oil; andg) 0 to 5 parts wax.Type: GrantFiled: June 7, 1999Date of Patent: December 19, 2000Assignee: National Starch and Chemical Investment Holding CorporationInventors: Xinya Lu, Ingrid Cole
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Patent number: 6133378Abstract: High durometer, polymeric roofing shingles with varying colors and shades of color may be prepared from a composition of matter comprising 100 parts by weight of a ethylene-propylene-diene (EPDM) terpolymer; from 25 to about 400 parts by weight of at least one non-combustible filler per 100 parts of ethylene-propylene-diene (EPDM) terpolymer; from 0 to about 125 parts by weight of at least one combustible filler, per 100 parts of ethylene-propylene-diene (EPDM) terpolymer; from 0 to about 135 parts by weight of a thermoplastic modifying polymer; from 0 to about 10 parts by weight of reinforcing fibers, per 100 parts of ethylene-propylene-diene (EPDM) terpolymer; from about 20 to about 75 parts by weight of a processing oil per 100 parts of ethylene-propylene-diene (EPDM) terpolymer; and from about 1 to about 6 parts by weight of a sulfur cure package having at least two curing accelerators.Type: GrantFiled: November 20, 1998Date of Patent: October 17, 2000Assignee: Bridgestone/Firestone, Inc.Inventors: James A. Davis, George G. Furman, Jerry C. Rose
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Patent number: 6133354Abstract: The present invention teaches a method for enabling the formation of a high damping composition. The method includes mixing a centipede polymer, i.e., a poly(disubstituted ethylene-co-maleimide) polymer, and plasticizers or extenders within a non-vulcanized thermoplastic elastomer to form a relatively high damping gel composition.Type: GrantFiled: November 17, 1998Date of Patent: October 17, 2000Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, David F. Lawson, Naruhiko Mashita
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Patent number: 6103814Abstract: Disclosed are hot-melt adhesive compositions suitable for the manufacture of soft goods. They have a melt viscosity of 60,000 mPa.s or less at a temperature of 120.degree. C. and include: (a) 50 to 150 parts by weight of a styrenic block copolymer or mixtures and/or modified and/or hydrogenated derivatives thereof; (b) 20 to 450 parts by weight of a tackifying resin which, when incorporated into a reference composition, leads to the following properties:a tan .delta. value of 3.5 or less, wherein tan .delta. is defined as the ratio between the loss modulus and the storage modulus of said composition andan elastic retention on spandex fibers (300%) or natural latex rubber (200%) after 4 h at 40.degree. C. of 70% or more; anda crossover temperature of 95.degree. C. or less.Further disclosed are novel partially hydrogenated hydrocarbon resins which are useful as tackifying resins and have the following properties: (a) a R&B softening point (R&B) of 50.degree. C. to 150.degree. C.Type: GrantFiled: April 10, 1997Date of Patent: August 15, 2000Assignee: Hercules IncorporatedInventors: Jan vanDrongelen, Johannes Cornelis M. Simons
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Patent number: 6103808Abstract: The high aromatic oil provided in the present invention is characterized by that a glass transition point is -45 to -20.degree. C. and an aromatic component measured by Clay-Gel method accounts for 55 to 90% by weight and that a polycyclic aromatic compound measured by IP 346 method accounts for less than 3% by weight based on the whole components of hydrocarbons contained in the oil.This high aromatic oil can suitably be used for various rubber compositions such as tires, rubber vibration insulators and fenders, oil extended synthetic rubbers, printing inks and writing inks.Type: GrantFiled: September 30, 1997Date of Patent: August 15, 2000Assignee: Bridgestone CorporationInventor: Takatsugu Hashimoto
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Patent number: 6032943Abstract: An elastic roller contains EPDM rubber as a main component and has a friction coefficient of not less than 2 with respect to ordinary paper and a hardness of not more than 35.degree..The amount of softening agent added to EPDM rubber which is a main component is not more than 150 parts by weight per 100 parts by weight of rubber.Type: GrantFiled: May 2, 1994Date of Patent: March 7, 2000Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Shunichi Yabushita, Hirotoshi Murakami, Hitoshi Itani
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Patent number: 6028144Abstract: A composition, suitable for use in producing a tire carcass, is provided. The composition comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene; a rubber such as a blend of natural rubber and a copolymer of styrene and butadiene; carbon black, and a plasticizer oil. Tires comprising carcasses made of the composition are also provided.Type: GrantFiled: January 5, 1993Date of Patent: February 22, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Vi Thi Nguyen, Patrick Anthony Grosso
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Patent number: 6017587Abstract: The present invention relates to electrically conductive silicone compositions comprising an organopolysiloxane containing at least two alkenyl groups per molecule, an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule, a platinum group metal containing catalyst, a conductive metal particulate, a precrosslinked elastomeric silicone particle, and a non-reactive volatile diluent. The electrically conductive silicone compositions of this invention are useful as electrically conductive adhesives and coatings for electrical and electronic devices. The cured electrically conductive silicone compositions of this invention have high electroconductivity and rubbery elasticity.Type: GrantFiled: July 9, 1998Date of Patent: January 25, 2000Assignees: Dow Corning Corporation, Dow Corning Toray Silicone Co., Ltd.Inventors: Don Lee Kleyer, Michael Andrew Lutz, Katsutoshi Mine, Osamu Mitani, Kazumi Nakayoshi, Bernard Vanwert
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Patent number: 5994446Abstract: Gels of oil-extended methacrylate-alkylene-methacrylate (M-A-M) triblock copolymers having higher glass transition temperatures than known styrene-alkylene-styrene triblock gels. The preferred M-A-M triblocks for making the new gels have polymethylmethacrylate end blocks and butadiene or ethylene/butylene mid-block, and are synthesised by methods in the public domain (inter alia Shell EP-A-0431706). Includes gels of new triblocks having end blocks of higher alkyl (e.g. isobornyl) methacrylate homopolymer or copolymers. Mixed methyl- and higher alkyl-methacrylate end blocks are preferred to reduce gel-formation problems which may arise from solubility parameter of homo-isobornylmethacrylate end blocks being too close to that of extender oil. Includes gels of new multi- (preferably penta-) block copolymers including styrene (S) blocks, e.g. M-S-A-S-M.Type: GrantFiled: March 25, 1998Date of Patent: November 30, 1999Assignee: Raychem LimitedInventors: Hendrik Graulus, Noel Overbergh, John Hudson, Philip James Hammond, Jianming Yu, Anthony Perkins
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Patent number: 5994468Abstract: The instant invention teaches a method for enabling the formation of a high damping, soft polymer gel. The method includes: reacting a poly(maleimide-co-alkenyl benzene) polymer with a nylon and an alkyl diamine under substantially dry conditions sufficient to form a nylon grafted poly(maleimide-co-alkenyl benzene) polymer product; and, dispersing the nylon grafted poly(maleimide-co-alkenyl benzene) polymer product with an extender oil sufficient to form the gel. The instant invention also contemplates a polymer gel composition, a polymer composition and an article manufactured from the polymer gel composition.Type: GrantFiled: May 6, 1998Date of Patent: November 30, 1999Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, James E. Hall, Naruhiko Mashita, Hideo Takeichi
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Patent number: 5981625Abstract: The present invention provides a newspaper printing ink that has rub off resistance; is fast drying on the paper; does not mist or dry on the press; offers excellent printability, high color strength, good water balance, and sharp half tone reproduction; and is relatively inexpensive. The present invention provides an ink concentrate suitable for preparing the printing ink, the ink concentrate comprising a colorant having a particle size of from about 0.01 .mu.m to about 25 .mu.m, a hydrocarbon resin, and a binder resin selected from the group consisting of a polyamide-oil polymer and a polyester-oil polymer. The present invention further provides a printing ink comprising a colorant having a particle size of from about 0.01 .mu.m to about 25 .mu.m, a vegetable oil, a polyamide-oil polymer, and a styrene-acrylic copolymer. The present invention further provides a printing ink comprising a naphthenic oil, a colorant having a particle size of from about 0.01 .mu.m to about 25 .mu.Type: GrantFiled: May 2, 1996Date of Patent: November 9, 1999Assignee: Videojet Systems International, Inc.Inventors: Wan Kang Zou, Xiaomang Wang, Qiao Qiao Dong
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Patent number: 5962572Abstract: Oriented gels aliened by controlled stretching during the gel's transition from a heated, extremely viscous, non melting, non flowing state and the cooled solid gel state produces strong gels which are found to have greater tensile strength than gels of the same rigidity which have not been stretched to a selected degree during its heating and cooling histories. Gels which are selectively stretched during its (non melt flowing) heated state and rapidly cooled by flowing air, cold liquid bath or in contact with a cool surface exhibit optical birefringence when viewed under plane-polarized light.Type: GrantFiled: December 29, 1995Date of Patent: October 5, 1999Assignee: Applied Elastomerics, Inc.Inventor: John Y. Chen
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Patent number: 5962560Abstract: The present invention relates to a low VOC solvent based adhesive comprising a mixture of at least two organic solvents and a thermoplastic resin. Desirably the adhesive has a flash point of at least 100.degree. F. when measured in accordance with ASTM D3828-87. The solvent blend of the low VOC solvent based adhesive of the instant invention volatilizes at substantially reduced rates as compared to conventional solvent blends in solvent based adhesives. Furthermore, this novel low VOC solvent based adhesive is easy to apply, cost effective, and cures within a reasonable time without the use of heat, ultraviolet light or other mechanical devices. In addition, the novel low VOC solvent based adhesive has good storage stability in metal or non-metal containers.Type: GrantFiled: August 14, 1998Date of Patent: October 5, 1999Assignee: The B.F. Goodrich CompanyInventors: Carmen D. Congelio, Andrew M. Olah
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Patent number: 5948843Abstract: A lithographic printing ink contains an ester-modified carboxyl-containing copolymer as a pigment dispersant. The ester-modified carboxyl-containing copolymer is the reaction product of a long chain alcohol and a styrene maleic anhydride copolymer, wherein at least 35% of the carboxyl groups of the styrene maleic anhydride copolymer are esterified. The ink further includes a liquid carrier resin; a pigment; and a solvent selected from the group consisting of aliphatic hydrocarbons, aromatic hydrocarbons, and mixtures thereof and/or a modifying oil. The pigment dispersants improve color development when incorporated into the ink during the grinding stage.Type: GrantFiled: May 24, 1996Date of Patent: September 7, 1999Assignee: Elf Atochem North America, Inc.Inventors: Robert H. Boutier, Bruce K. McEuen, Michael F. Heilman
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Patent number: 5902849Abstract: A filling compound for electrical and optical equipment in the form of cables, connectors, plugs etc. and to assemblies thus produced, is provided. Electrical and optical equipment in the form of cables, connectors, plugs etc. have to be protected against harmful influences penetrating from outside, particularly water, and also against mechanical damage during laying or as a result of exposure to heat. The filling compound is based on a stellate substance, i.e. a substance having a branched molecular structure in which, ideally, 3 or more branches, more particularly polymeric chains, radiate from a single branching point. The filling compound is flexible at very low temperatures but, on the other hand, does not run out, even at extremely high temperatures.Type: GrantFiled: November 12, 1996Date of Patent: May 11, 1999Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Reimar Heucher, Juergen Wichelhaus, Johannes Andres
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Patent number: 5874492Abstract: A process is provided for the preparation of a bitumen-polymer composition which comprises(a) producing at a temperature of between 100.degree. C. and 230.degree. C., a mixture of(i) a bitumen(ii) a linear block copolymer of styrene and a conjugated diene, the block copolymer being used in a quantity of from 0.5% to 25% by weight of bitumen and having a weight-average molecular weight of between 170,000 and 250,000 and a structure of A-B-A with A denoting a polymer block consisting of a polystyrene block which may be extended on the B side by a random copolymer of styrene and of the conjugated diene and B denoting a polymer block consisting of conjugated diene units, and(iii) a coupling agent containing at least one sulphur-donor compound and used in an amount to provide a quantity of sulphur representing, by weight, 0.1% to 10% of the weight of the linear block copolymer of styrene and conjugated diene; and(b) keeping the mixture thus produced at a temperature of between 100.degree. C. and 230.degree. C.Type: GrantFiled: February 21, 1997Date of Patent: February 23, 1999Assignee: Koch Material CompanyInventors: Jean-Pascal Planche, Laurent Germanaud, Pascal Nicol, Fran.cedilla.ois Travers
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Patent number: 5853874Abstract: A low melt viscosity hot melt pressure sensitive adhesive composition having enhanced tack properties is provided. The composition is based on an S-I-S block copolymer having polystyrene and polyisoprene block segments blended with a petroleum tackier resin which is the Friedel Crafts polymerization product of (i) a cracked petroleum feed containing C.sub.5 olefins and diolefins or a mixture of C.sub.5 and C.sub.6 olefins and dioelefins copolymerized with (ii) from about 5 to 15% by weight of a monovinyl aromatic monomer having 8 or 9 carbon atoms, e.g., styrene. The composition optionally also includes a polystyrene--polyisoprene diblock copolymer and a processing oil. The composition may be readily applied as solvent-free melt to various substrates using coating die technology because of its low melt viscosity at coating temperatures.Type: GrantFiled: July 22, 1997Date of Patent: December 29, 1998Assignee: Exxon Chemical Patents, Inc.Inventor: Lutz Erich Jacob
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Patent number: 5854322Abstract: A modified coal tar pitch useful in roofing applications, containing coal tar pitch, and a nitrile butadiene rubber, is blended by heating the coal tar pitch to a molten temperature, adding the rubber in powder form and agitating the material in a suitable high shear mixing apparatus until adequate phase inversion occurs between the polymer and the coal tar phase. After preparation, the material is cooled in containers until use, at which time it is heated to a flowable temperature and applied using a roofing mop or squeegee.Type: GrantFiled: August 20, 1997Date of Patent: December 29, 1998Assignee: The Garland CompanyInventor: Joseph W. Mellott
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Patent number: 5804661Abstract: An EPDM flashing composition comprises 100 parts by weight of an elastomeric polymer comprising from about 85 to 100 parts by weight of at least one ethylene-propylene-diene terpolymer having up to about 2 percent by weight crystallinity and from 0 to about 15 parts by weight of an ethylene-propylene-diene terpolymer having more than 2 percent by weight crystallinity; from about 40 to 120 parts by weight of a filler selected from the group consisting of reinforcing and non-reinforcing materials and mixtures thereof, per 100 parts of the polymer; from about 40 to 105 parts by weight of a processing material and mixtures thereof, per 100 parts of the polymer; and from about 0.5 to 6 parts by weight of a cure package, per 100 parts of the polymer, the cure package comprising from about 0.1 to 1.25 parts by weight sulfur and from 0.4 to 5 parts by weight of at least one sulfur vulcanizing accelerator and being devoid of hexasulfides and thioureas.Type: GrantFiled: February 21, 1996Date of Patent: September 8, 1998Assignee: Bridgestone/Firestone, Inc.Inventors: James A. Davis, Joseph J. Kalwara, Brian S. Alexander
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Patent number: 5773506Abstract: The present invention provides a block copolymer pressure sensitive adhesive (PSA) composition. The block copolymer has at least one midblock segment and at least one endblock segment. The midblock comprises a polymerized conjugated diene segment or hydrogenated derivative thereof. The endblock comprises a polymerized monovinyl aromatic segment having a number average molecular weight less than about 8,000. The PSA further comprises at least one tackifier or oil that is compatible with the low molecular weight endblock segment of the block copolymer. The PSA composition of the invention has a reduced elastic index and is capable of dissipating stress. This is useful in providing tapes which are capable of withstanding stresses such as those caused by temperature fluctuations, dimensional changes in the backing, or the recovery forces of a backing applied under tension. The present invention also provides a method of reducing the elastic index of a block copolymer PSA composition.Type: GrantFiled: December 9, 1996Date of Patent: June 30, 1998Assignee: Minnesota Mining and ManufacturingInventors: Mark K. Nestegard, Jingjing Ma
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Patent number: 5741840Abstract: A hot melt pressure sensitive adhesive comprising a) from about 15% to about 30% by weight of a linear styrene-ethylene/butylene-styrene copolymer having a styrene content from about 15% to about 35% by weight and a coupling efficiency of less than about 75%; b) from about 20% to about 50% by weight of a tackifying resin selected from the group consisting of those tackifying resins having a softening point of less than about 100.degree. C.; c) from about 30% to about 50% by weight of a plasticizing oil; and d) up to about 15% of a compatible polymer wherein the total polymer content does not exceed 30% by weight of the adhesive wherein the hot melt pressure sensitive adhesive fails cohesively during use.Type: GrantFiled: July 3, 1996Date of Patent: April 21, 1998Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Jeffrey S. Lindquist, Lisa L. Ryan
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Patent number: 5717021Abstract: The present invention involves blends of polycarbonate resin with rubber grafted terpolymer resin, one or more styrenic rigid coplymers wherein a small amount of an aliphatic C.sub.4 to C.sub.16 polyalpha olefin homopolymer or copolymer or its functionalized derivatives is included in the blend.Type: GrantFiled: November 18, 1996Date of Patent: February 10, 1998Assignee: General Electric CompanyInventors: Jianing Huang, Ronald L. Jalbert, Mark Giammattei, Gregory J. Stoddard
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Patent number: 5714254Abstract: A low melt viscosity, hot melt pressure sensitive adhesive composition having enhanced tack properties is provided. The composition is based on an S-I-S block copolymer having polystyrene and polyisoprene block segments blended with a petroleum tackifier resin which is a blend of a C.sub.5 -C.sub.9 aromatic modified aliphatic petroleum resin and a hydrogenated, alicyclic monomer containing hydrocarbon resin. The composition optionally also includes a polystyrene-polyisoprene diblock copolymer and a processing oil. The composition may be readily applied as solvent-free melt to various substrates using coating die technology because of its low melt viscosity at coating temperatures.Type: GrantFiled: May 29, 1997Date of Patent: February 3, 1998Assignee: Exxon Chemical Patents Inc.Inventor: Lutz Erich Jacob