Microcrystalline Wax Patents (Class 524/488)
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Patent number: 4764549Abstract: A novel curable rubber composition is described which is curable at low temperatures.Type: GrantFiled: September 9, 1986Date of Patent: August 16, 1988Assignee: Vulkor, IncorporatedInventors: Milton S. Greenhalgh, Joseph E. Vostovich
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Patent number: 4761450Abstract: Compatible polymer blends useful as melt adhesives comprising a low density ethylene polymer, a copolymer of butene-1 and ethylene or propylene, a hydrocarbon tackifier and a low molecular weight polymer selected from the group consisting of a low molecular weight liquid polybutene, an amorphous polypropylene and mixtures thereof.Type: GrantFiled: December 11, 1987Date of Patent: August 2, 1988Assignee: Baychem International, Inc.Inventors: Pallavoor R. Lakshmanan, Paula J. Carrier
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Patent number: 4761444Abstract: An elastomeric blend composition having improved tear properties and having a viscosity at 0.73 sec.sup.-1 and at 200.degree. C. of about 8.times.10.sup.3 to about 8.times.10.sup.5 poises, said composition formable into an elastomeric article, which comprises:(a) a neutralized sulfonated EPDM terpolymer having a viscosity at 0.73 sec.sup.-1 and at 200.degree. C. of about 5.times.10.sup.4 poises to about 5.times.10.sup.6 poises and about 10 to about 50 meq. sulfonate groups per 100 grams of said sulfonated EPDM terpolymer, said sulfonate groups being neutralized; and(b) about 2 to about 60 parts by weight of a fluorohydrocarbon elastomer per 100 parts of such sulfonated EPDM terpolymer.Type: GrantFiled: June 9, 1986Date of Patent: August 2, 1988Assignee: Exxon Research and Engineering CompanyInventors: Pawan K. Agarwal, William M. Petrik, Richard T. Garner
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Patent number: 4749616Abstract: In a heat sealable coating composition for application to a polymer film wherein the composition contains (a) a film-forming aqueous latex based on an interpolymer or blend one or more acrylate esters and, optionally, one or more alpha, beta ethylenically unsaturated carboxylic acids, (b) inorganic particulate hot slip agent and (c) wax-containing cold slip agent, an improvement is provided which comprises the presence therein of such an aqueous latex in which the average particle size of the interpolymer component is from about 0.03 to about 0.5 microns.Type: GrantFiled: June 20, 1986Date of Patent: June 7, 1988Assignee: Mobil Oil CorporationInventors: Leland L. Liu, Robert H. Steiner
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Patent number: 4716191Abstract: A flooding compound for a waterproof communications cable is formed from a heated mixture of 92-94% by weight of a microcrystalline wax, 3-5% polyethylene and 2-4% of a rubber. The heated mixture is extruded between the plastic jacket and core sheath of a cable. The compound exhibits the adhesive and slip characteristics of, and is a replacement for, atactic polypropylene.Type: GrantFiled: May 16, 1985Date of Patent: December 29, 1987Assignee: Witco Corp.Inventors: Thomas D. Hindman, Thomas J. Roessing, Joseph D. Burkhard
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Patent number: 4684672Abstract: Novel rubber connectors and other rubber parts for use in human infusion sets and rubber compositions and other rubber parts for use in human infusion sets and products produced thereby, such compositions comprising by weight a major amount of rubber selected from mixtures of natural rubber and synthetic natural rubber, the novel composition further comprising by weight a minor amount of a high density polyolefin and a filler, the composition being capable of being cured with an effective amount of a peroxide curing agent and an activator to achieve cross-linking of the rubber and the high density polyolefin.Type: GrantFiled: May 13, 1985Date of Patent: August 4, 1987Inventors: Robert L. Buchanan, Henry F. Dull, Jr.
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Patent number: 4681910Abstract: Aqueous, air drying latex coating compositions contain a large proportion of wax which dries to provide a continuous and durable film from which the wax exudes slowly and progressively to the surface over a long period of time to provide long-term water repellency. The coatings are primarily intended for application to exterior wood surfaces.Type: GrantFiled: January 13, 1986Date of Patent: July 21, 1987Assignee: DeSoto, Inc.Inventors: William B. Crockatt, John Rimma
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Patent number: 4636258Abstract: An ink composition for thermal transfer printing of about 30 to 50 weight percent of a masterbatch including a pigment or dye uniformly dispersed in a copolymer of at least one of styrene and an .alpha.-olefin and at least one of a maleic anhydride and a dialkyl maleate and about 50 to 70 weight percent wax or resin is provided. The ink composition is suitable for use as the ink layer of an electrothermal transfer recording sheet.Type: GrantFiled: August 20, 1985Date of Patent: January 13, 1987Assignee: Seiko Epson Kabushiki KaishaInventors: Seiichi Hayashi, Katsumori Takei, Takahiro Usui, Yoshitaka Yamaguchi, Makoto Taniguchi
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Patent number: 4631308Abstract: A hot melt adhesive and coating composition is provided comprising a copolymer of ethylene and acrylic acid or methacrylic acid; a compatible wax and a tackifier. The copolymer characterized as having a melt flow of at least about 0.77 and an acrylic acid or methacrylic acid content such that the copolymer has an acid number ranging from about 8 to about 93.Type: GrantFiled: May 20, 1985Date of Patent: December 23, 1986Assignee: The Dow Chemical CompanyInventors: Stephen L. Graham, David O. Plunkett, Robert S. Lacey
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Patent number: 4614758Abstract: The present invention relates to the use of paraffin waxes or microwaxes in silicone pastes, in particular in kneadable compositions for the production of accurate impressions of teeth. The silicone pastes are preferably cold-vulcanizing two-component silicone rubber systems which are known per se and in which two pastes are mixed and then crosslink after about 2-5 minutes at room temperature.Type: GrantFiled: April 30, 1985Date of Patent: September 30, 1986Assignee: Bayer AktiengesellschaftInventors: Peter Schwabe, Reiner Voigt
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Patent number: 4609591Abstract: A non-aqueous coating for glass fibers consisting of 100 percent solids formulation of organosilane, an ethylene-ethyl acrylate copolymer, a hydrogenated heterocyclic hydrocarbon thermoplastic resin, a microcrystalline wax, a viscosity-reducing agent, an antioxidizing agent, and a whitening agent. When employing glass fibers coated with the size composition of the present invention in a non-acid modified polypropylene resin, the size formulation also includes a maleic anhydride-modified polyolefin. Glass fibers coated with the size composition of this invention are suitable for use in reinforcing resinous products, particularly polypropylene, to achieve a white or translucent molded glass fiber-reinforced product.Type: GrantFiled: May 10, 1985Date of Patent: September 2, 1986Assignee: Owens-Corning Fiberglas CorporationInventors: Jean-Claude Pollet, Gordon P. Armstrong, Martin C. Flautt
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Patent number: 4598019Abstract: The present invention is directed to a method for surface treatment characterized by making use of a surface treating agent, for a powdery and granular material stored in the open air, containing 0.5 to 50% by weight of a solid content as an essential component and a residue which is water, said solid content comprising (I) 100 parts by weight of a petroleum wax component selected from the group consisting of slack waxes containing 1% by weight or more of an oil content, slack microcrystalline waxes including 1% by weight or more of an oil content, paraffin waxes, microcrystalline waxes and their mixtures and (II) 5 to 500 parts by weight of a polymer component having adhesive properties and the lowest film-forming temperature of 40.degree. C. or less.Type: GrantFiled: December 5, 1984Date of Patent: July 1, 1986Assignee: Nippon Oil Company, Ltd.Inventor: Nobuo Yokoyama
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Patent number: 4581392Abstract: A non-aqueous hot melt coating for glass fibers consisting of a silane, an ethylene-ethyl acrylate copolymer, a microcrystalline wax, a phenolic-modified terpene resin and a chemically modified polyolefin for coating glass fibers which can be employed as resin reinforcement.Type: GrantFiled: May 24, 1984Date of Patent: April 8, 1986Assignee: Owens-Corning Fiberglas CorporationInventors: Gordon P. Armstrong, Martin C. Flautt, Jean-Claude Pollet
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Patent number: 4576987Abstract: An aqueous coating composition is disclosed which contains a large proportion of wax which dries to provide a continuous and durable film from which the wax exudes slowly and progressively to the surface over a long period of time to provide long term water resistance. This composition comprises: (1) from 5% to 40% of an aqueous microcrystalline wax dispersion; (2) from 40% to 93% of an aqueous emulsion of copolymerized monoethylenically unsaturated monomers having a sufficiently low glass transition temperature to coalesce on air drying; and (3) from 1% to 20% of an N-methylol functional self crosslinking polyurethane aqueous dispersion in which the polyurethane contains sufficient volatile amine-neutralized carboxyl groups for water dispersibility, these proportions being by weight based on the solids content of the three components which are blended together.Type: GrantFiled: December 13, 1984Date of Patent: March 18, 1986Assignee: DeSoto, Inc.Inventors: William B. Crockatt, John Rimma
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Patent number: 4568713Abstract: Hot melt adhesives with long open time and good cold metal bonding are made of blends of an at least partially crystalline copolymer of butene-1 and ethylene, an aliphatic, substantially non-polar resin, an antioxidizing agent and, optionally, microcrystalline wax.Type: GrantFiled: May 30, 1984Date of Patent: February 4, 1986Assignee: Shell Oil CompanyInventors: David R. Hansen, David J. St. Clair
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Patent number: 4554304Abstract: Hot melt adhesives with long open time good bonding to cold metals are made of blends of a maleic anhydride modified copolymer of butene-1 and ethylene, an aliphatic, substantially non-polar resin, a antioxidizing agent and, optionally, microcrystalline wax, a block copolymer and atactic polypropylene.Type: GrantFiled: May 31, 1984Date of Patent: November 19, 1985Assignee: Shell Oil CompanyInventors: David R. Hansen, William H. Korcz
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Patent number: 4554303Abstract: Disclosed are blends of low-melting, slowly crystallizing copolyesters or of substantially amorphous copolyesters having relatively high glass transition temperatures containing very small amounts of low-molecular-weight polyolefins. These blends have sharply increased crystallinity and crystallization rates and provide significant improvements in production because of the enhanced crystallization.Type: GrantFiled: December 14, 1984Date of Patent: November 19, 1985Assignee: Eastman Kodak CompanyInventors: Frederick D. Petke, Charles W. Ramsey, Richard L. McConnell
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Patent number: 4539364Abstract: A non-aqueous hot melt coating composition consisting of a thermoplastic rubber block copolymer, a polyethylene wax and a low molecular weight resin compatible with the end styrenic block of the rubber block copolymer is useful as a hot melt size.Type: GrantFiled: May 29, 1984Date of Patent: September 3, 1985Assignee: Owens-Corning Fiberglas CorporationInventors: Jean-Claude Pollet, Martin C. Flautt, Gordon P. Armstrong
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Patent number: 4504434Abstract: A composition adapted for processing into stretch wrap film. The composition comprises between about 40 and about 90% by weight of a high molecular weight copolymer of ethylene and vinyl acetate containing between about 4 and about 25% by weight of repeating units derived from vinyl acetate and having a melt index of between about 0.1 and about 4.0. The composition further comprises between about 8 and about 55% by weight of a linear copolymer of ethylene and a higher alkene. Such linear copolymer has a specific gravity of between about 0.917 and about 0.945. The invention further includes stretch wrap film, a method of producing stretch wrap film of differential cling properties, and a composite film constituted of a layer of the aforesaid ethylene vinyl acetate copolymer and a layer of the linear copolymer of ethylene and a higher alkene.Type: GrantFiled: December 1, 1982Date of Patent: March 12, 1985Assignee: Bemis Company, Inc.Inventor: Barry A. Cooper
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Patent number: 4497792Abstract: A histological specimen infiltrating and embedding composition including paraffin and a copolymer of ethylene and vinyl acetate. The copolymer may be between 0.5 and 5% by weight of the paraffin. A surface active compatibilizer soluble in molten paraffin and which reduces the turbidity of the molten paraffin may be added to the composition in an amount between about 0.4% and 2% by weight of the paraffin.Type: GrantFiled: December 18, 1981Date of Patent: February 5, 1985Assignee: Sherwood Medical CompanyInventor: E. Melvin Gindler
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Patent number: 4460724Abstract: A hot melt composition is provided which comprises (1) a hydrogenated resin (II) having a softening point ranging from 50.degree. C. to 140.degree. C., said hydrogenated resin (II) being prepared by hydrogenating a copolymer resin (I) obtained by copolymerizing 20 to 60 wt % of a component (A) selected from the group consisting of five-member cyclic compounds each having a conjugated double bond and represented by the general formula (A) given below and Diels-Alder addition products thereof (A):GENERAL FORMULA (A): ##STR1## wherein H is hydrogen; R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers of not less than 1 and are in the relation of m+n=6;with 25 to 70 wt % of a codimer (component B) of said five-member cyclic compound and an aliphatic conjugated diolefin having 4 to 5 carbon atoms and 2.Type: GrantFiled: August 13, 1982Date of Patent: July 17, 1984Assignee: Nippon Oil Co., Ltd.Inventors: Shozo Tsuchiya, Akio Ohshima, Hideo Hayashi
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Patent number: 4456713Abstract: A composition for injection molding a sinterable material such as silicon nitride.This composition includes a binder system which imparts a greater flexibility to the, as molded, green body. The binder-system contains a major component of paraffin wax, a minor component of epoxy resin, and a surfactant.Type: GrantFiled: December 20, 1982Date of Patent: June 26, 1984Assignee: GTE Laboratories IncorporatedInventors: Kenneth W. French, Jeffrey T. Neil, Larry L. Turnbaugh
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Patent number: 4456649Abstract: This invention relates to holt melt adhesives for use in coating and/or laminating paper. Conventional hot melt adhesives used to manufacture a coated or laminated product with good vapor barrier characteristics are based on ingredients compounded with significantly lower proportions of inert low cost filler materials. The present invention provides a hot melt adhesive/coating blend which not only provides a moisture vapor barrier and/or bonding but also significantly reduces the quantity of more expensive ingredients through the use of a large quantity of a lower cost ultra fine ground inert inorganic filler material and a low cost modifying hydrocarbon resin. The blend or composition consists essentially of, in parts by weight, up to about 25 parts of a hi melt point paraffin wax, 10-30 parts of a modifying hydrocarbon resin, 1-20 parts of an elastomeric copolymer, and 20-85 parts of an inert inorganic filler material.Type: GrantFiled: March 15, 1982Date of Patent: June 26, 1984Assignee: Manville Service CorporationInventor: Wayne C. Clarke
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Patent number: 4436866Abstract: An aqueous coating composition is provided for filamentary materials that yields coated filamentary material with improved weavability and that yields reinforced elastomeric materials having improved properties of flexibility and fatigue resistance. The aqueous adhesive coating composition has a vinyl-pyridine-containing copolymer or terpolymer latex, a non-selfcrosslinkable elastomeric latex, a carboxylated butadiene polymer, and a phenolic aldehyde condensate polymer. The vinyl pyridine-containing elastomeric latex is produced from a vinyl pyridine-containing monomer, 1,3-diene hydrocarbon monomer or the terpolymer is produced in the same way with the addition of a vinyl containing monomer. The non-selfcrosslinkable elastomeric latex has a low gel content of less than around 40 weight percent and a low average particle size of less than around 2000 angstroms.Type: GrantFiled: November 25, 1981Date of Patent: March 13, 1984Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4435469Abstract: A relatively high melting point thermoplastic hot melt adhesive suitable for bonding a paper facing to glass fiber based insulating materials to produce good adhesion and superior water vapor barrier properties, containing in percent by weight:______________________________________ Microcrystalline Wax 8-12% Synthetic Polyethylene Wax 8-12% Hydrocarbon Resin 13-17% Ethylene-Vinyl Acetate 6-12% copolymer Calcium Carbonate Filler Up to 65% BHT antioxidant .002-.Type: GrantFiled: April 28, 1982Date of Patent: March 6, 1984Assignee: Manville Service CorporationInventor: Ralph M. Fay
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Patent number: 4425268Abstract: A composition adapted for processing into stretch wrap film. The composition comprises between about 40 and about 90% by weight of a high molecular weight copolymer of ethylene and vinyl acetate containing between about 4 and about 25% by weight of repeating units derived from vinyl acetate and having a melt index of between about 0.1 and about 4.0. The composition further comprises between about 8 and about 55% by weight of a linear copolymer of ethylene and a higher alkene. Such linear copolymer has a specific gravity of between about 0.917 and about 0.945. The invention further includes stretch wrap film, a method of producing stretch wrap film of differential cling properties, and a composite film constituted of a layer of the aforesaid ethylene vinyl acetate copolymer and a layer of the linear copolymer of ethylene and a higher alkene.Type: GrantFiled: February 6, 1980Date of Patent: January 10, 1984Assignee: Bemis Company, Inc.Inventor: Barry A. Cooper
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Patent number: 4412030Abstract: Resins suitable for adhesives are based on .alpha.-methyl styrene, styrene and phenol in certain percentages, viz. 25 to 63, 35 to 73 and 2 to 15 percent by weight, respectively.Combinations of resin, ethylene vinyl acetate copolymer, atactic polypropylene, ethyl acrylate copolymer or a thermoelastomer and optionally a wax or tackifying oil yield excellent adhesives, in particular hot-melt adhesives.Type: GrantFiled: April 30, 1982Date of Patent: October 25, 1983Assignee: National Starch and Chemical CorporationInventors: Yves Runavot, Georges Billault, Jaques Salvetat
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Patent number: 4405746Abstract: An aqueous coating composition for filamentary materials that are to be used in reinforcing elastomeric matrix materials is provided that renders reinforced elastomeric materials having improved properties of flexibility and fatigue resistance. The aqueous adhesive coating composition has a vinyl-pyridine-containing copolymer or terpolymer latex, a phenolic aldehyde condensate polymer, and a non-self-crosslinkable elastomeric latex with a low gel content of less than around 40 weight percent and a low average particle size of less than around 2000 angstroms. The vinyl pyridine-containing elastomeric latex is produced from a vinyl pyridine-containing monomer, 1,3 diene hydrocarbon monomer or the terpolymer is produced in the same way with the addition of a vinyl containing monomer. In addition the aqueous adhesive coating composition may contain a wax emulsion, antioxidant, and carboxylated styrene butadiene copolymer latex.Type: GrantFiled: February 27, 1981Date of Patent: September 20, 1983Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
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Patent number: 4404299Abstract: A composition for the manufacture of hot-melt adhesives, in which the improvement comprises a terpolymer of ethylene having a melt index between 5 and 500 dg/minute and comprising from 1 to 10 mol % of units derived from an ester selected from alkyl acrylates and methacrylates, the alkyl group having from 1 to 6 carbon atoms, and from 0.3 to 3 mol % of units derived from maleic anhydride. The composition also contains at least one tackifying resin and may contain at least one compound selected from paraffin, microcrystalline polymeric wax, and esters of a hydrogenated rosinic acid and of a lower alcohol.Type: GrantFiled: April 15, 1982Date of Patent: September 13, 1983Assignee: Societe Chimique des Charbonnages-CDF CHIMIEInventor: Jean-Claude Decroix
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Patent number: 4394418Abstract: An aqueous sizing composition for glass fibers and the resultant sized glass fiber strands are provided, where the sized glass fiber strands have an improved slip/flow property and resultant thermosetting articles reinforced with the sized glass fiber strands have improved impact properties. The aqueous sizing composition has a poly(vinyl acetate) silane copolymer, epoxy polymer, one or more lubricants, an organo silane coupling agent, which may be an amino-silane coupling agent, lubricant modified-amino-organo silane coupling agent, epoxy-containing silane coupling agent or a mixture of one or more of these coupling agents, one or more nonionic surfactants, a polyethylene-containing polymer, a wax, a hydrocarbon acid and water. The aqueous sizing composition is applied to glass fibers which are then produced into wet chopped glass fiber strands or continuous sized glass fiber strands.Type: GrantFiled: December 24, 1981Date of Patent: July 19, 1983Assignee: PPG Industries, Inc.Inventor: Chester S. Temple
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Patent number: 4394475Abstract: Sized glass fiber strands are provided that have improved slip/flow characteristics. This improved characteristic is achieved by sizing glass fibers with an aqueous sizing composition having one or more nonstarch film forming polymers, one or more coupling agents, one or more lubricants or a mixture thereof, polyethylene-containing polymer with limited branching and water. The aqueous sizing composition can also have a wax having a melting point greater than 50.degree. C. where the total amount of the polyethylene polymer and wax is not greater than about 15 weight percent of the aqueous sizing composition.Type: GrantFiled: December 24, 1981Date of Patent: July 19, 1983Assignee: PPG Industries, Inc.Inventors: Chester S. Temple, Ed C. Hsu
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Patent number: 4371634Abstract: A microcapsule-containing wax composition, which comprises (a) microcapsules of from 2 to 10 .mu.m diameter, (b) waxes and (c) dispersants, with or without pigments, fillers, volatile constituents and other agents conventionally present in wax compositions for the hot carbon process.The wall material of the microcapsules is a cross-linked urea-melamine condensate.The wax compositions may be applied over all or part of the surface of a base material, and give deeply colored copies with color-forming (CF) layers.Type: GrantFiled: November 16, 1981Date of Patent: February 1, 1983Assignee: BASF AktiengesellschaftInventors: Dietrich Hoffman, Wolfgang Sliwka
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Patent number: 4360628Abstract: Solid copolymer tackifying resins based on dicyclopentadiene, a vinylaromatic hydrocarbon and a benzene carrying 1 to 3 lower alkyl, hydroxyl or halogen substituents and adhesive formulations containing these resins.Type: GrantFiled: January 19, 1981Date of Patent: November 23, 1982Assignee: National Starch and Chemical CorporationInventors: Yves Runavot, Georges Billault, Jacques Salvetat
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Patent number: 4356036Abstract: An anti-corrosion coating for metals comprising a mixture of aluminum paste or zinc paste, microcrystalline wax, aromatic hydrocarbon resin, chlorinated rubber, neutral barium sulfonate, chlorinated solvent, aromatic hydrocarbon solvent, and mineral spirits.Type: GrantFiled: July 2, 1981Date of Patent: October 26, 1982Inventor: Nicolas Kaliardos
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Patent number: 4317755Abstract: A water based self-polishing sealing composition as a protective coating for floors, metal parts and the like, utilizes a film forming polymeric coating agent and a hydrocarbon solvent having a solubility parameter from about 7.8 to 9.8 emulsified with a compatible surfactant.Type: GrantFiled: June 11, 1980Date of Patent: March 2, 1982Assignee: S. C. Johnson & Son, Inc.Inventor: Gordon K. Gregory