Inorganic Silicon-containing Material Having Specified Dimensions Patents (Class 524/493)
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Patent number: 9676958Abstract: A copolymer dispersion is described comprising a copolymer derived from a monomer mixture comprising: (a) 88.5 to 94% by weight of at least one vinyl ester of a saturated carboxylic acid; (b) 5 to 10.5% by weight of ethylene; (c) 0.5 to 5% by weight of at least one ethylenically unsaturated acid and/or an anhydride thereof and/or a salt thereof; and (d) 0.5 to 5% by weight of at least one ethylenically unsaturated monomer having at least one crosslinkable functional unit. The weight ratio of vinylester units to ethylene units in the copolymer is between 89:11 and 94:6 and the dispersion is stabilized with at least 1% by weight of an emulsifier, wherein the amounts of monomers and emulsifier refer to the total amount of monomers in the copolymer.Type: GrantFiled: December 16, 2011Date of Patent: June 13, 2017Assignee: CELANESE SALES GERMANY GMBHInventors: Stefan Nogai, Alistair McLennan
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Patent number: 9650491Abstract: An epoxy resin composition is provided which includes a polycrystalline structure comprised of a plurality of monocrystalline structures. The plurality of monocrystalline structures are respectively comprised of a plurality of silicon oxide colloidal particles regularly aligned in epoxy resin. The plurality of silicon oxide colloidal particles are not contacted with each other. The mean distance between the silicon oxide colloidal particles adjacent to each other is less than 330 nm. The mean particle size of the plurality of silicon oxide colloidal particles is less than 290 nm. The concentration of the plurality of silicon oxide colloidal particles is 10-50% by mass. A relative permittivity of 4 or more is ensured. A method for producing the epoxy resin composition is provided. Building materials, ornaments and optical materials, each using the epoxy resin composition, are also provided.Type: GrantFiled: October 1, 2012Date of Patent: May 16, 2017Assignees: FUJI CHEMICAL COMPANY, LIMITED, KYOCERA CORPORATIONInventors: Satoshi Kawanaka, Fumio Uchida, Yuji Nakano, Yoshiyuki Kawasumi
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Patent number: 9644085Abstract: A method of producing rubber compounds, in which the polymer base is composed partly of a first polymer material having a glass transition temperature of over ?50° C., and partly of a second polymer material having a glass transition temperature of below ?50° C. and silica as a filler. The method includes a preliminary first polymer material treating step, in which the first polymer material, a silica having a surface area of 80 to 135 m2/g, a silane bonding agent, and at least one nucleophile agent are mixed together; a preliminary second polymer material treating step, in which the second polymer material, a silica having a surface area of 150 to 220 m2/g, a silane bonding agent, and at least one nucleophile agent are mixed together; a mixing step, in which the compounds resulting from the preliminary treating steps are mixed together; and a final step, in which stearic acid and a curing system are added and mixed with the compound being produced.Type: GrantFiled: July 8, 2014Date of Patent: May 9, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Francesco Botti, Riccardo Ascione, Davide Privitera, Michele Amurri, Pasquale Agoretti
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Patent number: 9637610Abstract: A cross linkable elastomeric composition comprising silica-epoxidized natural rubber (ENR) elastomer as masterbatch, to produce crosslinkable rubber products used in industrial applications preferably the outer layer of solid tire that is capable of providing low rolling resistance and good wet grip properties, the silica-filled ENR masterbatch is a ready compounded masterbatch which is prepared via latex stage preparation which comprises antioxidant, oil emulsion, silica dispersion and ENR latex.Type: GrantFiled: September 6, 2013Date of Patent: May 2, 2017Assignee: Lembaga Getah MalaysiaInventors: Yen Wan Ngeow, Shamheza binti Suhatta, Nurul Hayati binti Yusof, Fauzi bin Mohd Som
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Patent number: 9598556Abstract: An inorganic water resistant binder composition comprising liquefied sodium silicate, which can be used to fabricate lightweight, water resistant hardcore panels, is provided herein. Specifically, the inorganic water resistant binder composition comprises 50.0-94.0 parts by weight of liquefied sodium silicate, which comprises 76.0-80.0 parts by weight of silicon, 19.6-23.0 parts by weight of sodium, 0.15-0.35 parts by weight of potassium, 0.20-0.30 parts by weight of aluminum, and 0.05-0.15 parts by weight of iron; 5.0-30.0 parts by weight of nano silica; and 0.5-10.0 parts by weight of a silane composition, which enhance water resistance of the binder composition. A process is provided for fabrication of a lightweight, highly water resistant hardcore panel by mixing the components of the binder composition described above with inorganic additives, such as an inorganic filler and a strength enhancer.Type: GrantFiled: November 27, 2014Date of Patent: March 21, 2017Inventors: Yu-Jeong Shin, Myung-Hwan Kim, Myung-Jun Moon
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Patent number: 9567230Abstract: The invention relates to a method for preparing precipitated silica, consisting in: (i) forming a starter having a pH of between 2 and 5; (ii) simultaneously adding silicate and acid, such that the pH of the reaction medium is between 2 and 5; (iii) adding silicate until the pH is between 7 and 10; (iv) simultaneously adding silicate and acid, such that the pH is between 7 and 10; (v) adding acid until the pH is between 2.5 and 5.3; (vi) bringing the reaction medium into contact with the acid and the silicate, such that the pH is between 2.5 and 5.3; and (vii) adding silicate, such as to increase the pH to a value between 4.7 and 6.3.Type: GrantFiled: September 2, 2010Date of Patent: February 14, 2017Assignee: Rhodia OperationsInventor: Emmanuelle Allain
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Patent number: 9550890Abstract: A rubber composition, which can be used for manufacturing tires, is based on one or more diene elastomers, on one or more reinforcing fillers, and on a crosslinking system. The rubber composition includes particles of one or more thermoplastic materials chosen from thermoplastic materials with melting or softening points varying from 80° C. to 300° C. The rubber composition also includes one or more compatibilizing agents chosen from block copolymers that includes at least one diene elastomer block and at least one thermoplastic block compatible with the one or more thermoplastic materials.Type: GrantFiled: June 23, 2011Date of Patent: January 24, 2017Assignees: Compagnie Generale Des Etablissements Michelin, Michelin Recherche Et Technique S.A.Inventors: Emmanuel Custodero, Damien Thomasson, Vincent Abad
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Patent number: 9550922Abstract: There are provided a hot-melt adhesive, which is excellent in solvent resistance and is excellent in adhesion to an adherend (specifically, a polyimide film) containing an electrolytic solution of a battery therein, and also can contribute to an improvement in performances of electric instruments; and an electric instrument produced by using such hot-melt adhesive. A hot-melt adhesive for electric instruments, comprising an olefin based modified polymer (A), the olefin based modified polymer (A) being a modified polymer having a functional group containing silicon, is excellent in resistance to an electrolytic solution of a battery (that is, electrolytic solution resistance or solvent resistance), and also exhibits improved adhesion of the hot-melt adhesive to an adherend (plastic film such as a polyimide film) containing the electrolytic solution therein.Type: GrantFiled: October 24, 2014Date of Patent: January 24, 2017Assignee: HENKEL IP & HOLDING GMBHInventors: Itsuro Tomatsu, Kenji Matsuda, Ai Takamori
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Patent number: 9546264Abstract: A compound for a tyre textile body ply skim. The compound has a cross-linkable, unsaturated-chain polymer base, a reinforcing filler composite, and a curing system having at least a curing agent and accelerants. The compound has 0.1 to 20 phr of a lignin derivative, 20 to 50 phr of a first carbon black with a surface area of 90 to 150 m2/g, and 5 to 20 phr of a second carbon black with a surface area of 10 to 40 m2/g.Type: GrantFiled: February 8, 2014Date of Patent: January 17, 2017Assignee: BRIDGESTONE CORPORATIONInventors: Salvatore Cotugno, Ludovica Caliano
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Patent number: 9534140Abstract: There is provided a resist underlayer film-forming composition having excellent solubility in a solvent containing propylene glycol monomethyl ether as a main component. A resist underlayer film-forming composition comprising a polymer having a structural unit of Formula (1a) or Formula (1c) and a structural unit of Formula (1b) and a solvent containing more than 50% by mass of propylene glycol monomethyl ether, wherein in the polymer, the structural unit of Formula (1a) or Formula (1c) and the structural unit of Formula (1b) are arranged alternately. (In Formulae (1a) and (1b), Q is a phenylene group or a naphthylene group, m is 1 or 2, and each of n is independently 0 or 1).Type: GrantFiled: December 17, 2013Date of Patent: January 3, 2017Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Tomoya Ohashi, Shigeo Kimura, Hiroto Ogata
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Patent number: 9487047Abstract: This invention relates to an oil-extended natural rubber capable of improving a tensile strength and a wear resistance of a rubber composition, and more particularly to an oil-extended natural rubber formed by adding an emulsified extension oil to a natural rubber latex and further coagulating and drying them. An amount of the extension oil added is preferable to be within a range of 5-80% by mass based on a rubber component in the natural rubber latex and the oil-extended natural rubber is preferable to have a weight average molecular weight as converted to polystyrene of a rubber component of not less than 1,500,000.Type: GrantFiled: January 25, 2007Date of Patent: November 8, 2016Assignee: BRIDGESTONE CORPORATIONInventor: Hajime Kondo
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Patent number: 9474192Abstract: A method for manufacturing a housing for an electronic equipment containing metal housing configured to house an electronic equipment therein and a resin film with which the metal housing is coated includes the steps of heating a resin film so as to soften the resin film, coating a metal housing with the heated resin film, and adhering the coated resin film to the metal housing. The preferred housing is one in which an adhesive layer, a print layer, or both thereof is disposed between a resin layer contained in the resin film and the metal housing, and in which the resin film contains at least one thermoplastic resin selected from the group consisting of polycarbonate (PC), polyethylene terephthalate (PET), polymethyl methacrylate (PMMA), and polylactic acid (PLA).Type: GrantFiled: May 14, 2013Date of Patent: October 18, 2016Assignee: FUJITSU LIMITEDInventors: Koichi Kimura, Masanobu Ishiduka
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Patent number: 9448331Abstract: Polymer-inorganic particle blends are incorporated into structures generally involving interfaces with additional materials that can be used advantageously for forming desirable devices. In some embodiments, the structures are optical structures, and the interfaces are optical interfaces. The different materials at the interface can have differences in index-of-refraction to yield desired optical properties at the interface. In some embodiments, structures are formed with periodic variations in index-of-refraction. In particular, photonic crystals can be formed. Suitable methods can be used to form the desired structures.Type: GrantFiled: March 2, 2015Date of Patent: September 20, 2016Assignee: NanoGram CorporationInventors: Nobuyuki Kambe, Shivkumar Chiruvolu
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Patent number: 9403932Abstract: Provided is a process for producing silicate-comprising polyols, comprising (i) admixing an aqueous silica sol (K) having an average particle diameter 1-150 nm, silica content 1-60% by weight and a pH of 1-6, with a 0.1- to 20-fold amount of at least one organic solvent (L), (ii) admixing the resulting mixture with a polyol, (iii) removing at least partially water and the organic solvent (L) by distillation, (iv) admixing with 0.1-30 mol % of at least one compound (S) which has at least one at least monoalkoxylated silyl group and at least an alkyl, cycloalkyl or aryl substituent, which may contain heteroatoms, wherein the substituent optionally contains a group reactive toward an alcohol, an amine or an isocyanate, and (v) optionally adjusting the pH of the silicate-comprising polyol to 7-12 by addition of a basic compound.Type: GrantFiled: October 8, 2009Date of Patent: August 2, 2016Assignee: BASF SEInventors: Berend Eling, Zeljko Tomovic, Stefan Auffarth, Alexander Traut
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Patent number: 9382455Abstract: An adhesive composition includes an acrylic polymer (A), a heat curable resin (B) having unsaturated hydrocarbon group, and a filler (C) having reactive double bond on a surface.Type: GrantFiled: March 15, 2013Date of Patent: July 5, 2016Assignee: LINTEC CorporationInventors: Sayaka Tsuchiyama, Isao Ichikawa
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Patent number: 9376554Abstract: The rubber composition for tire tread and a tire includes 100 parts by weight of a raw material rubber that includes 20 parts by 80 parts by weight of a first solution polymerized styrene-butadiene rubber (SBR1) having a styrene content of 15% to 25% by weight and a vinyl content in the butadiene of 60% to 65% by weight and produced by a batch method; and 60 parts to 90 parts by weight of a silica having a specific surface area measured by nitrogen adsorption of 155 m2/g to 185 m2/g and a CTAB value of 150 m2/g to 170 m2/g.Type: GrantFiled: December 11, 2013Date of Patent: June 28, 2016Assignee: HANKOOK TIRE CO., LTD.Inventors: Ji Eun Choi, Ho Youn Kang
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Patent number: 9358767Abstract: A panel for use over a vehicle airbag includes a skin layer with a tear seam formed therein. The skin layer is made from a material that includes a polymer matrix and one or more transmissivity-reducers in the form of microflake fillers or fillers having a monomodal particle size distribution. The transmissivity-reducers are included in an amount that reduces the transmissivity of light through the material to reduce variation in laser scoring processes and also in an amount that does not substantially alter the mechanical properties of the polymer matrix. Skin layers made from these materials can be used in laser scoring processes of TPO coverings that are thinner than previously known.Type: GrantFiled: June 13, 2011Date of Patent: June 7, 2016Assignee: Faurecia Interior Systems, Inc.Inventors: Aaron Wisniewski, Mathew Barr, Daniel R. Vander Sluis
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Patent number: 9328225Abstract: The present invention relates to a rubber composition for a tire that includes silica and a rubber component that contains not less than 5% by mass of a conjugated diene polymer, based on 100% by mass of the rubber component, the conjugated diene polymer containing a constituent unit derived from a conjugated diene and a constituent unit represented by the following formula (I): at least one terminal of the conjugated diene polymer being modified by a compound represented by the following formula (II):Type: GrantFiled: July 22, 2011Date of Patent: May 3, 2016Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Kazuyuki Nishioka, Yuko Hinohara, Takahiro Mabuchi
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Patent number: 9315608Abstract: A conjugated diene polymer rubber is provided that includes component (A) and component (B) below, component (A) having a content, with the total amount of component (A) and component (B) as 100% by weight, of from 5% to 90% by weight, and component (B) having a content of from 95% to 10% by weight, Component (A): a conjugated diene polymer rubber component modified with a carbonyl group- and substituted amino group-containing compound Component (B): a conjugated diene polymer rubber component modified with a compound represented by formula (IIa) below (R21O)mSi(R22A)nR234-m-n??(IIa) wherein m denotes a number from 1 to 3, n denotes a number from 1 to 3, m+n is from 2 to 4, R21 and R23 denote a hydrocarbyl group, R22 denotes a hydrocarbylene group, A denotes a substituted amino group or an optionally substituted hydrocarbyloxy group, when there are a plurality of R21s the plurality of R21s may be identical to or different from each other, when there are a plurality of R22s the plurality of R22s may be idenType: GrantFiled: March 19, 2014Date of Patent: April 19, 2016Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Toru Fujii, Takuya Sudo, Mayumi Oshima, Katsunari Inagaki
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Patent number: 9303150Abstract: A composition contains a polymer component comprising a crosslinked product of a polyarylene, a crosslinked product of a substituted polyphenylene, a crosslinked product of a polyphenylene sulfide and a polyphenylsulfone, or a combination comprising at least one of the foregoing; and a mesoporous silicate having an average pore size of about 5 nanometers to about 50 nanometers. The composition has high-temperature elastomeric properties and excellent mechanical strength. The compositions are useful in oil and gas downhole applications. Methods for the manufacture of the composition and articles comprising the composition are also disclosed.Type: GrantFiled: April 3, 2014Date of Patent: April 5, 2016Assignee: BAKER HUGHES INCORPORATEDInventors: Sayantan Roy, Bennett M. Richard, Jeffrey R. Potts, Anil K. Sadana
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Patent number: 9284439Abstract: A rubber composition for tires comprises: per 100 parts by weight of diene rubber containing from 5 to 50 wt. % of terminally modified S-SBR, from 2 to 50 parts by weight of an aromatic modified terpene resin having a softening point of 100° C. or higher. A total content of 60 to 130 parts by weight of two types of silica, that is silica X and silica Y. A functional group of the modified S-SBR has reactivity with a silanol group. A proportion of the silica relative to a total amount of a reinforcing filler containing the silica X, the silica Y, and an optionally compounded carbon black is 85 wt. % or greater. A nitrogen adsorption specific surface area of the silica X is 140 m2/g or greater; a nitrogen adsorption specific surface area of the silica Y is greater than 100 m2/g and less than 140 m2/g.Type: GrantFiled: April 24, 2013Date of Patent: March 15, 2016Assignee: The Yokohama Rubber Co., LTD.Inventor: Shinya Takeda
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Patent number: 9267020Abstract: A rubber composition that can improve in good balance the fuel economy, wet-grip performance, and abrasion resistance, and a pneumatic tire that uses this rubber composition are provided. This rubber composition contains a rubber component, and carbon black and/or silica, wherein based on 100% by mass of the rubber component, the rubber component contains 5 to 50% by mass of natural rubber, 0.3 to 10% by mass of an epoxidized natural rubber, and at least 5% by mass of a conjugated diene polymer that has a constituent unit based on a conjugated diene and a constituent unit represented by formula (I) below, at least one terminal of the polymer being modified, and wherein a total content of the carbon black and the silica is 3 to 100 parts by mass per 100 parts by mass of the rubber component.Type: GrantFiled: December 12, 2011Date of Patent: February 23, 2016Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Toshikazu Kondo, Jun Okamoto, Sakae Okubo, Ryoichi Kasahara, Kenji Murata, Kazuhiro Kodama, Kazuyuki Nishioka
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Patent number: 9260600Abstract: A rubber composition comprises from 2 to 50 parts by weight of an aromatic modified terpene resin having a softening point of ?100° C., and two types of silica, a silica X and a silica Y, at a total quantity of 60 to 130 parts by weight relative to 100 parts by weight of a diene rubber containing from 5 to 50 weight % of a modified S-SBR having a vinyl content of not lower than 60 weight %. A functional group in the modified S-SBR reacts with a silanol group, a proportion of silica relative to the total quantity of a reinforcing filler containing the silica and carbon black is not lower than 85 weight %, a nitrogen specific surface area of the silica X is not lower than 140 m2/g, and a nitrogen specific surface area of the silica Y is not lower than 100 m2/g but lower than 140 m2/g.Type: GrantFiled: July 13, 2012Date of Patent: February 16, 2016Assignee: The Yokohama Rubber Co., Ltd.Inventor: Shinya Takeda
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Patent number: 9265156Abstract: A curable composition to be used for a printed wiring board is disclosed, which has an excellent flexibility and an excellent adhesive property with respect to both a plastic substrate and a conductive layer in the printed wiring board. The curable composition includes (A) a (meth)acrylate compound having a polyene structure, (B) a (meth)acrylate compound having a hydroxyl group; and (C) a photopolymerization initiator. From the curable composition, a cured coating film, and a printed wiring board including the cured coating film in the form of a predetermined pattern are obtained.Type: GrantFiled: March 27, 2014Date of Patent: February 16, 2016Assignee: Taiyo Ink Mfg. Co., Ltd.Inventors: Masayuki Shimura, Yoshiyuki Furuta, Masao Yumoto, Shoji Minegishi
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Patent number: 9193806Abstract: Provided are a method for producing a relatively uniformly epoxidized natural rubber in a simple and inexpensive manner, a rubber composition for tires that includes the epoxidized natural rubber, and a pneumatic tire formed from the rubber composition for tires. The present invention relates to a method for producing an epoxidized natural rubber, including: Step 1 of coagulating natural rubber latex into granules to prepare a granular solid rubber; and Step 2 of treating the granular solid rubber with an epoxidizing liquid to epoxidize the granular solid rubber.Type: GrantFiled: January 22, 2013Date of Patent: November 24, 2015Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Toshiaki Sakaki, Lucksanaporn Tarachiwin, Kamolchat Charungchitaree, Hathainat Kum-Ourm
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Patent number: 9176411Abstract: An electrostatic charge image developing toner includes toner particles and silica particles, wherein the silica particles have an average equivalent circle diameter of from 70 nm to 400 nm, an average circularity of from 0.5 to 0.9, and a pore volume of from 0.05 cm3/g to 2.5 cm3/g.Type: GrantFiled: October 28, 2013Date of Patent: November 3, 2015Assignee: FUJI XEROX CO., LTD.Inventors: Koji Sasaki, Satoshi Inoue, Yutaka Saito, Yasuaki Hashimoto, Emi Takahashi
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Patent number: 9126457Abstract: The invention is directed to a pneumatic tire having a rubber tread of a cap/base construction comprising an outer rubber tread cap layer containing an outer running surface and an underlying rubber tread base layer; wherein said tread cap layer comprises at least two circumferential, longitudinal rubber tread cap zones; wherein said tread cap zones individually extend from said tread cap running surface radially inward to said tread base layer; wherein said at least two tread cap zones comprises a first tread cap zone and a second tread cap zone adjacent to the first tread cap zone; the first tread cap zone and the second tread cap zone each independently comprising a vulcanizable rubber composition.Type: GrantFiled: November 16, 2011Date of Patent: September 8, 2015Assignee: The Goodyear Tire & Rubber CompanyInventors: Christian Jean-Marie Kaes, Carlo Kanz, Olivio Jean-Baptiste Pagliarini, Marc Weydert
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Patent number: 9120916Abstract: The present invention is directed to acrylic polymers comprising: (i) hydroxyl functional groups; (ii) polydialkylsiloxane functional groups; and (iii) silica nanoparticles that are chemically bonded to and pendant from the acrylic polymer. The present invention is further directed to curable film-forming compositions comprising acrylic polymers, and to coated substrates comprising the curable film-forming composition applied to at least one surface of the substrates. The present invention is also drawn to methods of mitigating dirt build-up on a substrate, comprising applying to at least a portion of the substrate the curable film-forming composition described above and at least partially curing the curable film-forming composition.Type: GrantFiled: June 12, 2014Date of Patent: September 1, 2015Assignee: PPG Industries Ohio, Inc.Inventors: Shanti Swarup, Xiangling Xu, Noel Rawle Vanier, Mark Edward Endlish, Dennis Simpson
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Patent number: 9073041Abstract: The present invention is directed to a separation medium comprising rotary dried or spray dried precipitated silica. The silica has a pore surface area P wherein log10 P>2.2, and the ratio of BET to CTAB is at least 1.0 measured prior to any surface modification of the silica. The present invention is further directed to a method of separating suspended or dissolved materials from a fluid stream, comprising contacting the stream with the separation medium described above.Type: GrantFiled: August 30, 2012Date of Patent: July 7, 2015Assignee: PPG Industries Ohio, Inc.Inventors: Qunhui Guo, Carol L. Knox, Raphael O. Kollah, Justin J. Martin, Shantilal M. Mohnot, Timothy A. Okel, Daniel E. Rardon
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Patent number: 9045620Abstract: An object of the present invention is to provide: a rubber composition which, when it is applied to a component member (such as a tread) of a tire, exhibits good wear resistance without deteriorating rolling resistance of the tire; a cross-linked rubber composition obtained by cross-linking the rubber composition; and a tire using the rubber composition or the cross-linked rubber composition as a material thereof. Specifically, the present invention provides a rubber composition obtained by blending and kneading a rubber component and hydrated silica together, characterized in that: provided that D represents the average primary particle diameter and LP represents the log differential pore volume at a pore diameter of 30 nm, of the hydrated silica in the rubber composition, D and LP satisfy relationships represented by following formula (1) and (2). LP>?0.045×D+1.45??(1) D<30 nm??(2).Type: GrantFiled: August 31, 2012Date of Patent: June 2, 2015Assignee: BRIDGESTONE CORPORATIONInventors: Kouichi Saitou, Keiichi Aomatsu, Masaki Yanagioka
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Patent number: 9029436Abstract: An artificial silica marble comprises a matrix and a line pattern portion. The line pattern portion comprises fine lines having a width of about 50 to about 500 ?m and forms a web- or net-like pattern. The line pattern portion divides or partitions the artificial silica marble into a plurality of irregularly shaped pattern portions to form an amorphous pattern in the cross section of the artificial silica marble.Type: GrantFiled: October 31, 2013Date of Patent: May 12, 2015Assignee: Cheil Industries Inc.Inventors: Cheol Yeon Hwang, Chang Ho Son, Su Sun Jeong, Hee Cheol Lee, Han Ju Kang, Sung Jin An
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Patent number: 9028605Abstract: Disclosed herein are architectural coating compositions comprising spheroid shaped silica or silicate. The compositions exhibit a number of improved properties and are useful on a variety of substrates.Type: GrantFiled: February 16, 2012Date of Patent: May 12, 2015Assignee: J.M. Huber CorporationInventors: William J. Hagar, Ronald L. Romer, William C. Fultz, Karl W. Gallis
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Patent number: 9029457Abstract: A particle-polymer hybrid material can include: a substance having the structure of Formula 1 Z(Y-FP)m, wherein Z is a particle smaller than 1 mm; m is an integer; Y is a linker including a silicon atom linked to the particle; FP is a functionalized polymer having: a first structure derived from a first norbornene compound linked to the Y; and one or more repeating units linked to the first structure, each unit being derived from a second norbornene compound and having a functional group.Type: GrantFiled: June 3, 2011Date of Patent: May 12, 2015Assignee: The University of KansasInventors: Paul Ronald Hanson, Alan Rolfe
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Publication number: 20150126666Abstract: Disclosed is a method of making a polystyrene based nanocomposite by combining a monomer with a nanoparticle to form a mixture and subjecting the mixture to polymerization conditions to produce a polymeric composite. In an embodiment the nanoparticle has been treated with an additive prior to combining with the monomer and the additive contains a silane moiety.Type: ApplicationFiled: January 12, 2015Publication date: May 7, 2015Inventors: James R. Butler, David W. Knoeppel
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Patent number: 9023905Abstract: The present invention relates to a cleaning implement based on melamine formaldehyde foams comprising, abrasive particles and to a method of cleaning a hard surface with said cleaning implement.Type: GrantFiled: February 24, 2012Date of Patent: May 5, 2015Assignee: The procter & Gamble CompanyInventors: David John Pung, Denis Alfred Gonzales, Tobias Heinz Steinke, Peter Nessel
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Publication number: 20150119516Abstract: A method of producing a rubber compound containing silica, the method including a step of dispersing the silica in a polymer base, and a following step of mixing the previously formed mixture with curing agents. The step of dispersing the silica in the polymer base includes the following sequence of operations: soaking the polymer base in a liquid silica precursor to form a swollen polymer; —adding the swollen polymer to an organic solvent, and continually stirring the swollen polymer solution; —adding water and a silica synthesizing catalyst to the swollen polymer solution; —precipitating a polymer gel matrix by adding a precipitating agent; —separating and washing the precipitated polymer gel matrix.Type: ApplicationFiled: April 18, 2013Publication date: April 30, 2015Applicant: BRIDGESTONE CORPORATIONInventors: Francesco Botti, Alessandra Bartoloni, Giancarlo Cossu
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Patent number: 9012558Abstract: There is provided herein a one-part, moisture-curable, elastomeric, translucent coating composition comprising: (a) a di-hydroxy-terminated dimethylpolysiloxane polymer; (b) a reinforcing filler; (c) an organic solvent; (d) a polyalkoxysilane crosslinking agent; (e) an organo-silane adhesion promoter; and, (f) a titanium condensation cure catalyst, wherein the composition is a one-part, moisture-curable, elastomeric, translucent coating composition, and a process of making the composition.Type: GrantFiled: September 13, 2011Date of Patent: April 21, 2015Assignee: Momentive Performance Materials Inc.Inventor: Gary Morgan Lucas
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Patent number: 9012560Abstract: The present invention provides a rubber composition that can enhance the fuel economy, wet-grip performance, and abrasion resistance in a balanced manner, and a pneumatic tire using this rubber composition. The present invention relates to a rubber composition that contains a rubber component, silica, and a silane coupling agent, wherein the rubber component contains, based on 100% by mass of the rubber component, not less than 5% by mass of a conjugated diene polymer containing a constituent unit based on a conjugated diene and a constituent unit represented by formula (I) below, at least one terminal of the polymer being modified with a specific compound; an amount of the silica is 5 to 150 parts by mass per 100 parts by mass of the rubber component; and the silane coupling agent contains a mercapto group.Type: GrantFiled: March 22, 2012Date of Patent: April 21, 2015Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Tetsuya Kunisawa, Tsuyoshi Tsuchida, Kenichi Uesaka, Isamu Tsumori, Reika Otake, Noboru Okabe, Naoya Omura, Tatsuhiro Tanaka, Takafumi Taguchi, Kenya Watanabe, Toru Iizuka
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Patent number: 9006332Abstract: A weatherable, flame-resistant thermoplastic vulcanizate composition comprising a thermoplastic matrix; and dispersed within said matrix, an at least partially cured rubber, a flame retardant, and carbon black.Type: GrantFiled: August 22, 2011Date of Patent: April 14, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: Randal H. Kerstetter, III, Karla D. Caton, Edward J. Blok, Eugene R. Uhl
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Patent number: 9006326Abstract: Provided are a rubber composition capable of achieving a balanced improvement in fuel economy, tensile strength at break, and processability, and a pneumatic tire including the rubber composition. The invention relates to a rubber composition including a conjugated diene polymer and silica, the conjugated diene polymer being obtained by polymerizing a monomer component including a conjugated diene compound and a silicon-containing vinyl compound in the presence of a polymerization initiator represented by the following formula (I): to produce a copolymer, and reacting a compound containing a nitrogen atom and/or a silicon atom with an active terminal of the copolymer, wherein the rubber composition includes the conjugated diene polymer in an amount of not less than 10% by mass per 100% by mass of a rubber component of the rubber composition, and the silica in an amount of 10-70 parts by mass per 100 parts by mass of the rubber component.Type: GrantFiled: June 26, 2012Date of Patent: April 14, 2015Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Shuichiro Ono, Ryuichi Tokimune
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Publication number: 20150099844Abstract: A rubber composition for tires comprises: per 100 parts by weight of diene rubber containing from 5 to 50 wt. % of modified BR having a vinyl unit content of 10 to 60 wt. %, from 2 to 50 parts by weight of an aromatic modified terpene resin having a softening point of 100 to 130° C., and a total content of 60 to 130 parts by weight of two types of silica, that is silica X and silica Y; a proportion of the silica relative to a total amount of a reinforcing filler containing carbon black being 85 wt. % or greater; a nitrogen adsorption specific surface area of the silica X is 140 m2/g or greater; and a nitrogen adsorption specific surface area of the silica Y is greater than 100 m2/g and less than 140 m2/g.Type: ApplicationFiled: April 16, 2013Publication date: April 9, 2015Applicant: The Yokohama Rubber Co., LTD,Inventors: Shinya Takeda, Makoto Ashiura
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Patent number: 8999199Abstract: An artificial marble includes unsaturated polyester resin (A), compound including silica (B), and luminescent pigment (C). An artificial marble according to a second embodiment includes about 70 to about 95% by weight of a non-luminescent base material (I) comprising unsaturated polyester resin (A), compound including silica (B), and organic/inorganic pigment (C) and about 5 to about 30% by weight of a luminescent amorphous pattern part (II) comprising unsaturated polyester resin (A), compound including silica (B), and luminescent pigment (D). An artificial marble according to a third embodiment includes unsaturated polyester resin (A), compound including silica (B), and amorphous luminescent chip (C).Type: GrantFiled: December 27, 2012Date of Patent: April 7, 2015Assignee: Cheil Industries Inc.Inventors: Hee Cheol Lee, Chang Ho Son, Sung Jin An, Su Sun Jeong, Cheol Yeon Hwang, Han Ju Kang
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Publication number: 20150094386Abstract: The invention relates to a silicon dioxide dispersion that comprises a) an outer flowable phase containing 1) polymerizable monomers, oligomers and/or prepolymers that can be converted to polymers by non-radical reaction; and/or 2) polymers, and b) a disperse phase containing amorphous silicon dioxide. The inventive dispersion is characterized in that the average particle size dmax of the silicon dioxide as measured by small angle neutron scattering (SANS) is between 3 and 50 nm at a maximum half-width of the distribution curve of 1.5 dmax. Such a silicon dioxide dispersion can be easily manufactured even at higher concentrations of the disperse phase and can be used to produce polymer materials that have advantageous properties, especially advantageous mechanical properties.Type: ApplicationFiled: October 10, 2014Publication date: April 2, 2015Inventors: Johannes ADAM, Christof ROSCHER, Christian EGER, Thorsten ADEBAHR, Robert WIECZORRECK, Manfred PYRLIK
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Patent number: 8993664Abstract: The present invention provides a rubber composition for tires capable of improving handling stability, fuel economy, wet grip performance, elongation at break, and abrasion resistance together while maintaining the balance between them. The present invention also provides a pneumatic tire including the rubber composition. The present invention relates to a rubber composition for tires containing a diene rubber, silica having a BET specific surface area of 170 to 270 m2/g, sulfur, and a liquid resin having a softening point of ?20 to 45° C., wherein the amount of the liquid resin is 0.5 to 20 parts by mass, and the amount of the silica is 40 to 120 parts by mass, each per 100 parts by mass of the rubber component of the rubber composition.Type: GrantFiled: April 24, 2012Date of Patent: March 31, 2015Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Tatsuya Miyazaki
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Publication number: 20150087762Abstract: The present invention is a polyester composition for a film, wherein the polyester composition comprises a masterbatch polyester composition including 1.0 to 2.0%, by mass of inorganic particles having an average particle diameter of 0.5 to 3.0 ?m and having been prepared using a polycondensation catalyst containing, and an inorganic particle-free polyester resin in a mass ratio of 1:15 to 35; and wherein the polyester composition will cause little filter clogging and can provide a polyester film that is excellent in slipping properties, running properties and wear resistance and will suffer from little deterioration in quality due to defects or insoluble particles located on the film.Type: ApplicationFiled: March 21, 2013Publication date: March 26, 2015Inventors: Satoru Nakagawa, Hideto Ohashi, Kunihiro Maeda
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Publication number: 20150087763Abstract: The present invention relates to a copolymer including a monomer unit (a) derived from isoprene and a monomer unit (b) derived from farnesene; a process for producing the copolymer including at least the step of copolymerizing isoprene with farnesene; a rubber composition including (A) the copolymer, (B) a rubber component and (C) carbon black; a rubber composition including (A) the copolymer, (B) a rubber component and (D) silica; a rubber composition including (A) the copolymer, (B) a rubber component, (C) carbon black and (D) silica; and a tire using the rubber composition at least as a part thereof.Type: ApplicationFiled: April 2, 2013Publication date: March 26, 2015Applicants: KURARAY CO., LTD., AMYRIS, INC.Inventors: Daisuke Koda, Kei Hirata
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Patent number: 8987358Abstract: The invention provides an adhesion-imparting agent having heat-resistant transparency and a high refractive index best suited for an addition hardening type composition including a reaction product of silsesquioxane and organopolysiloxane. The invention relates to a compound obtained by allowing a hydrosilylation addition reaction of (A), (B), and when necessary, (C) as described below, and a compound including an organopolysiloxane or silsesquioxane skeleton including as an essential component an isocyanuric ring skeleton and an epoxy group, and having an SiH group residue: (A) a compound including an organopolysiloxane or silsesquioxane skeleton and having three or more SiH groups in one molecule; (B) an epoxy derivative having one aliphatic unsaturated group in one molecule; and (C) organopolysiloxane having two alkenyl groups in one molecule, and having a number average molecular weight of 100 to 500,000, or an isocyanurate compound having two alkenyl groups in one molecule.Type: GrantFiled: June 28, 2012Date of Patent: March 24, 2015Assignee: JNC CorporationInventors: Kiichi Kawabata, Akio Tajima, Takashi Matsuo, Yoshiko Watanabe, Koichi Ayama
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Patent number: 8980988Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing from 90 to 100% by mass of at least one kind of diene rubber synthesized by solution polymerization and from 0 to 10% by mass of another kind of diene rubber; (B) a silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of 180 m2/g or more measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 1,700 or less, and thus provides a rubber composition that is improved in low-heat-generation property.Type: GrantFiled: April 27, 2012Date of Patent: March 17, 2015Assignee: Bridgestone CorporationInventors: Satoshi Horie, Takaaki Igarashi
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Patent number: 8980989Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing 10% by mass or more of at least one kind of rubber selected from diene rubber synthesized by emulsion polymerization and natural rubber and 90% by mass or less of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of less than 140 m2/g measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 3,300 or less, and thus provides a rubber composition that is improved in low-heat-generation property.Type: GrantFiled: April 27, 2012Date of Patent: March 17, 2015Assignee: Bridgestone CorporationInventors: Satoshi Horie, Takaaki Igarashi
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Patent number: 8980990Abstract: The present invention provides a rubber composition containing: (A) a rubber component containing 10% by mass or more of at least one kind of rubber selected from diene rubber synthesized by emulsion polymerization and natural rubber and 90% by mass or less of another kind of diene rubber; (B) silica having a n-hexadecyltrimethylammonium bromide (CTAB) adsorption specific surface area of 140 m2/g or more and less than 180 m2/g measured according to a method described in ASTM D3765-92; (C) at least one silane coupling agent selected from a polysulfide compound and a thioester compound; and (D) a vulcanization accelerator, the rubber composition after vulcanization having an average aggregated aggregate area (nm2) of the silica of 2,300 or less, and thus provides a rubber composition that is improved in low-heat-generation property.Type: GrantFiled: April 27, 2012Date of Patent: March 17, 2015Assignee: Bridgestone CorporationInventors: Satoshi Horie, Takaaki Igarashi