Mixing With Titanium Dioxide Material Having Numerical Limitations Other Than Amount, E.g., Included Herein Are Particle Size, Etc., Composition Or Product Thereof, Dnrm Patents (Class 524/497)
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Patent number: 5434210Abstract: Thermal spray powders are characterized by the presence of a matrix-forming component, a solid lubricant component and a plastic component. Abradable coatings formed by thermal spraying the powders abrade readily to form abradable seals. The abradable coatings have a metal, metal alloy, or ceramic matrix with discrete inclusions of solid lubricant and plastic. The thermal spray powders may be prepared as mechanically fused agglomerates.Type: GrantFiled: September 28, 1992Date of Patent: July 18, 1995Assignee: Sulzer Plasma Technik, Inc.Inventors: Subramaniam Rangaswamy, Robert A. Miller
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Patent number: 5424354Abstract: A room temperature curable polyorganosiloxane composition according to the present invention, which comprises the following components, is superior in handleability and affords a cured product superior in mechanical characteristics, particularly tear strength:1 100 parts by weight of a polyorganosiloxane having at least two silanol groups in one molecule;2 1-25 parts by weight of an organosilane or organosiloxane having in one molecule at least three hydrolyzable groups attached to silicon atom;3 0.01-10 parts by weight of a curing catalyst; and4 5-500 parts by weight of ultra-fine titanium oxide particles.Type: GrantFiled: December 28, 1993Date of Patent: June 13, 1995Assignee: Three Bond Co., Ltd.Inventor: Toru Takeoka
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Patent number: 5416150Abstract: A resin composition comprises an aqueous emulsion of an acrylic resin, titanium oxide, iron oxide, and calcium carbonate.Type: GrantFiled: August 4, 1994Date of Patent: May 16, 1995Assignee: Hachiro ShinpoInventor: Harry Boeck
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Patent number: 5412019Abstract: The tendency for hard and irregular particles of titanium dioxide pigment to adversely affect the sheen and coin mar resistance of a dried coating into which they have been incorporated is reduced by modifying the particles with polymer particles which have been preformed and are therefore of a more pre-determinable shape and size. The polymer particles are chemically bonded to a polymeric water-soluble compound containing moieties which are adsorbable onto the titanium dioxide particles so that on mixing a colloidally stabilised aqueous dispersion of the polymer particles with a colloidally stabilised aqueous dispersion of titanium dioxide particles, the moieties adsorb onto the titanium dioxide to form a colloidally stable aqueous dispersion of polymer-modified titanium dioxide which is useful in coating compositions.Type: GrantFiled: January 31, 1994Date of Patent: May 2, 1995Assignee: Imperial Chemical Industries PLCInventors: Brian J. Roulstone, Julian A. Waters
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Patent number: 5391609Abstract: A transparent polymeric film that provides a barrier to the transmission of ultra-violet light. The film results from the addition of titanium dioxide particles having an average particle size less than the wavelength of visible light, yet greater than the wavelength of ultra-violet light, to a polymeric material capable of being formed as a transparent film. More specifically, the titanium dioxide particles have an average size on the order of from about 0.010 .mu.m to 0.050 .mu.m and, preferably from about 0.018 .mu.m to 0.040 .mu.m.Type: GrantFiled: June 2, 1994Date of Patent: February 21, 1995Assignee: Mobil Oil Corp.Inventors: Anthony R. Knoerzer, Leland W. Reid, Edwin M. Wheeler
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Patent number: 5389714Abstract: Resin compositions comprising (A) polyethylene ether resins, (B) polyamide resins, (C) elastomeric substances, and (D) needle-shaped titanium oxide are disclosed. The disclosed resins exhibit an excellent balance of stiffness and impact resistance, low linear coefficient of expansion, and good heat resistance, oil resistance, forming processability and molding surface appearance.Type: GrantFiled: December 23, 1992Date of Patent: February 14, 1995Assignee: GE Plastics, Japan, Ltd.Inventors: Takashi Ohtomo, Hiromi Ishida, Hidekazu Kabaya, Hiroshi Kubo
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Patent number: 5385960Abstract: Coatings compositions including stable composite latex-pigment particles are prepared by dispersing titanium dioxide pigment particles in a first aqueous medium and preparing a dispersion of selected polymeric latex particles, which have at least one dihydrogen phosphate functional group, in a second aqueous medium. The media are mixed and the selected polymeric latex particles adsorb on the titanium dioxide particles. Dibasic phosphate is then provided to the mixture to stop adsorption and stabilize the composite particles. The coating composition gives a coating with improved hiding.Type: GrantFiled: May 20, 1993Date of Patent: January 31, 1995Assignee: Rohm and Haas CompanyInventors: William D. Emmons, William C. Finch, Meredith A. Morgan
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Patent number: 5376702Abstract: A process and an apparatus for the direct, continuous and flexible modification of polymer melts by branching off a brand melt stream from the main melt stream to be modified, dispersing the initially introduced additive in the melt in a specially designed twin-screw extruder, and subsequent recycling of the additive melt concentrate to the melt stream to be modified.Type: GrantFiled: October 21, 1991Date of Patent: December 27, 1994Assignee: EMS-Inventa AGInventors: Werner Stibal, Daniel Boni, Hans Luckert
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Patent number: 5360668Abstract: A white blackout fiber comprising a unitary fiber having a light blocking substance that substantially prevents the transmission of light therethrough and a whitening agent, where the whitening agent is present in an amount which provides for good after processing while the light blocking substance is present in the maximum amount which is masked by the whitening agent. Generally, the whitening agent is present in an amount between about 2.5-4% by weight of the fiber, and the whitening agent and light blocking substance are present in a ratio of between about 1000:1 and 800:1. Preferably, the whitening agent is TiO.sub.2 and the light blocking substance is carbon black.Type: GrantFiled: November 19, 1993Date of Patent: November 1, 1994Assignee: Charles Samelson Co.Inventor: Herschel Sternlieb
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Patent number: 5352725Abstract: Improved methods and polymer compositions are provided whereby ultraviolet radiation degradation of substrates formed of the compositions is attenuated. In accordance with the invention, ultraviolet scattering and absorbing particles having a particle size in the range of from about 0.001 micrometer to about 0.20 micrometer in diameter are dispersed in at least a surface layer of a polymer substrate.Type: GrantFiled: September 9, 1992Date of Patent: October 4, 1994Assignee: Kerr-McGee Chemical CorporationInventors: Bruce R. Palmer, James W. Kauffman, Penelope Stamatakis
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Patent number: 5308913Abstract: A wholly aromatic polyester resin composition contains:(1) a wholly aromatic polyester resin,(2) at least one member selected from a glass fiber and a silica-alumina fiber,(3) glass beads,(4) titanium oxide, and(5) a fluorocarbon polymerThe wholly aromatic polyester resin composition has high heat resistance and mechanical strengths, low anisotropy and excellent appearance, and shows low dissolution of components, excellent releasability and non-tackiness. It can be molded into an ovenware.Type: GrantFiled: January 2, 1992Date of Patent: May 3, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Kuniaki Asai, Tadayasu Kobayashi, Mituo Maeda
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Patent number: 5288320Abstract: Titanium dioxide carries an ester or a partial ester of an hydroxy compound containing 1 to 6 OH groups and an aliphatic saturated C.sub.10 to C.sub.22 monocarboxylic acid. The product is easily dispersible in plastics compositions, particularly masterbatches. The titanium dioxide can also be coated with one or more hydrous oxides.The product is prepared by milling the titanium dioxide in a fluid energy mill in the presence of the ester or partial ester.Type: GrantFiled: December 30, 1991Date of Patent: February 22, 1994Assignee: Tioxide Group Services LimitedInventor: Guy Decelles
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Patent number: 5240980Abstract: An opacified, semi-crystalline thermoplastic resin composition is provided having a poly(alkyleneoxy) substituted organic chromophore distributed throughout in an amount sufficient to color the resin. The resin composition is particularly useful for molding parts with strict dimensional tolerances as shrinkage of the molded part is minimal.Type: GrantFiled: May 22, 1992Date of Patent: August 31, 1993Assignee: Milliken Research CorporationInventors: Todd D. Danielson, David J. Moody, John W. Rekers
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Patent number: 5240779Abstract: A biaxially oriented polyester film comprising a copolyester which contains a lubricant having an average particle diameter of no greater than 2.5 .mu.m and has a melting point of from 210.degree. to 245.degree. C., the film having a plane orientation coefficient of from 0.10 to 0.16, a thermal shrinkage at 150.degree. C. of no higher than 10%, and a density of lower than 1.385 g/cm.sup.3, and optionally a refractive index in a direction of thickness of from 1.495 to 1.530 as well as a film plane refractive index of from 1.61 to 1.66 in all directions.Type: GrantFiled: April 27, 1992Date of Patent: August 31, 1993Assignee: Teijin LimitedInventors: Tadashi Ono, Kinji Hasegawa, Takeo Asai, Yoji Murakami
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Patent number: 5232971Abstract: A polyolefin resin composition including(1) 67 to 96 wt.%, based on the total quantity of (1), (2) and (3), of polyolefin,(2) 3 to 25 wt.%, based on the total quantity of (1), (2) and (3), of titanium oxide,(3) 3 to 30 wt.%, based on the total quantity of (1), (2) and (3), of a plate-shaped inorganic filler, and(4) 5 to 150 ppm, based on the total quantity of (1), (2) and (3), of carbon black. The polyolefin resin composition of the present invention is superior in brightness and light intercepting properties and may be advantageously employed in e.g. a material of a meter casing for an automobile.Type: GrantFiled: March 13, 1992Date of Patent: August 3, 1993Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Manabu Nomura, Kouji Sato, Kaoru Wada
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Patent number: 5227421Abstract: A resin having both an acidic and a basic functional group is dissolved in an aqueous medium by neutralizing the acidic functional group with a basic compound and a pigment is dispersed in the aqueous medium by the action of the resin. To improve the dispersibility of the pigment and dispersion stability and coated film performance, a pK.sub.b value of the basic functional group of the resin is equal to or less than a pK.sub.b value of the basic compound.Type: GrantFiled: November 2, 1992Date of Patent: July 13, 1993Assignee: Nippon Paint Co., Ltd.Inventors: Hiroyuki Kageyama, Toshikatsu Kobayashi, Shouji Ikeda
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Patent number: 5216122Abstract: Residual ethylene oxide is removed from poly(ethylene oxide) by the steps of adding to particles of high molecular weight poly(ethylene oxide) a finely divided solid particulate material which is capable of coating the poly(ethylene oxide) particles and impeding their agglomeration under conditions of heating, heating the particles of poly(ethylene oxide) at a temperature of at least 40.degree. C. and preferably which is near their crystalline melting point, and maintaining the temperature for a sufficient time to reduce the ethylene oxide in the particles of poly(ethylene oxide) to ten ppm or less. In one embodiment, the poly(ethylene oxide) is heated by holding the particles in a heated enclosure; in another, it is heated as a slurry in a liquid medium; in yet another, it is heated by warm gas in a gaseously-fluidized bed; and in a fourth, it is heated by microwave radiation.Type: GrantFiled: May 21, 1991Date of Patent: June 1, 1993Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Walter T. Reichle, Geoffrey A. D'Netto, Guy M. Troy, Meyer R. Rosen, Elke M. A. Clark
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Patent number: 5212214Abstract: The present invention provides an inventive arylene sulfide coating composition which exhibits enhanced hardness, inertness, abrasion-resistance, and durability. The, inventive composition comprises an arylene sulfide polymer resin and a ceramic microsphere filler. The inventive coating composition can be applied to a substrate in order to improve the degradation resistance of the substrate and provide an article of manufacture well suited for use in high temperature, abrasive, and/or corrosive environments.Type: GrantFiled: May 7, 1991Date of Patent: May 18, 1993Assignee: Phillips Petroleum CompanyInventor: Lyle R. Kallenbach
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Patent number: 5141985Abstract: The wholly aromatic polyester resin composition of the present invention comprises a wholly aromatic polyester resin, at least one fibrous reinforcing agent, glass beads and titanium oxide.The composition of the present invention has high heat resistance and mechanical strengths, low anisotropy and excellent appearance, being safe and shows a low dissolution amount in an extraction test according to No. 20 of the Welfare Ministry. Accordingly, the vessel obtained by molding the composition is suitable for use as an ovenware.Type: GrantFiled: March 11, 1991Date of Patent: August 25, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Kuniaki Asai, Tadayasu Kobayashi
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Patent number: 5137942Abstract: The method of compounding a high strength, cost-effective, composite of a high temperature, water sensitive, polar, polyamide-inide resin mixed with a talc, water absorbent/adsorbent filler. The method comprises raising said mixture to a temperature of about; 500.degree. F. to develop plasticity in said engineering resin. Thereafter there is added a lower temperature softening, water repellant, polypropylene resin and a compatibilizing additive. Finally all components are mixed in a mixing chamber sufficiently to obtain complete dispersion and homogeneity of the composite.Type: GrantFiled: October 31, 1990Date of Patent: August 11, 1992Assignee: Ralph B. AndyInventor: Norman Shorr
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Patent number: 5134179Abstract: A novel composite board of mineral wool, perlite, and cellulosic newsprint fibers for use primarily as a ceiling tile is disclosed. The board displays virtually no sag (less than 200 mils) when exposed to high temperature and high humidity while displaying quite acceptable strength. The board is manufactured by selective deposition of a composition of latex and extender particles on the cellulosic newsprint fibers.Type: GrantFiled: October 1, 1990Date of Patent: July 28, 1992Assignee: Armstrong World Industries, Inc.Inventors: John Felegi, Jr., Kenneth P. Kehrer, Edward E. Wise, Jr.
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Patent number: 5110854Abstract: An anti-nitriding composition comprising a water-based alkyd resin having suspended therein particulate tin and titanium dioxide; a thixotropic agent maintains the particulates in suspension during storage and application; the composition includes surfactant and co-solvent to impart paint-like characteristics. The composition is suitable for use as a local shield during the heat treatment of metals to prevent nitriding or ferritic nitro-carburization at temperatures in the range of about 850.degree. F. to about 1150.degree. F. The water-based formulation is safe to use and to transport, and has an air drying time at normal working temperatures comparable to those drying times previously achievable only with organic-solvent based anti-nitriding compositions.Type: GrantFiled: March 8, 1990Date of Patent: May 5, 1992Inventor: Glenn O. Ratliff
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Patent number: 5102935Abstract: The invention relates to new, free-flowing polyamide molding compounds and blends, characterized in that they are prepared by mixing of polyamides known per se in the melt with low molecular weight, liquid-crystalline esters and/or ester amides corresponding to formula (I) and/or liquid-crystalline, oligomeric esters and/or ester amides corresponding to formula (II) and, optionally, other additives, at least one polymeric blending component being used as a further additive in the case of polyamide blends, and to the use of these liquid-crystalline (LC) additives I and/or II as flow promoters in polyamide molding compounds and blends and to a process for the production of the new polyamide molding compounds and blends. The invention also relates to the new oligomeric esters and/or ester amides corresponding to formula (II).Type: GrantFiled: September 5, 1989Date of Patent: April 7, 1992Assignee: Bayer AktiengesellschaftInventors: Hans-Detlef Heinz, Harald Pielartzik, Aziz El-Sayed, Rolf-Volker Meyer, Martin Wandel, Peter-Roger Nyssen
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Patent number: 5073582Abstract: A mildew-resistant paint composition comprising a film-forming, non-wood penetrating organic polymeric paint vehicle; an isothiazolone mildewcide compound; and a stabilizing amount of a water insoluble organic soluble copper compound; articles comprising a substrate coated with said paint composition; and methods of stabilizing isothiazolones in paint compositions are disclosed.Type: GrantFiled: July 11, 1989Date of Patent: December 17, 1991Assignee: Rohm and Haas CompanyInventor: Stanley LeSota
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Patent number: 5001181Abstract: There is discloses a resin composition which comprises a polyphenylene ether resin, a polyamide resin, an alkenylaromatic compound-conjugated diene copolymer; a compound having unsaturated group and polar group in combination within the same molecule; and an inorganic filler, and the polyphenylene ether resin being dispersed into the polyamide resin which forms continuous phase, and the inorganic filler being dispersed into dispersed phases of the polyphenylene ether resin.Type: GrantFiled: August 28, 1989Date of Patent: March 19, 1991Assignee: Mitsubishi Petrochemical Company, Ltd.Inventors: Kiyoji Takagi, Koji Nishida
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Patent number: 4946641Abstract: A metallic, gold colored composition comprising an olefin polymer, a mica-based gold pigment, a mica-based bronze pigment, carbon black, and optionally, a yellow pigment is provided. Additionally, a process to produce a glossy, metallic, gold colored polyolefin product in a grit blasted mold is provided.Type: GrantFiled: December 9, 1988Date of Patent: August 7, 1990Assignee: Phillips Petroleum CompanyInventor: Majorie B. Skinner
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Patent number: 4943611Abstract: A resin composition for spacers of an information recording disc which comprises: (A) a random copolymer of ethylene and at least one cycloolefin having an intrinsic viscosity [.eta.] of from 0.05 to 10 dl/g, as measured in decalin at a temperature of 135.degree. C., and (B) from 0.01 to 5 parts by weight, based on 100 parts by weight, of said copolymer A, of an inorganic particles such as titania and silica having a particle size of not more than 300 .mu.m. Spacers made of the composition described herein can be welded to disc substrates within a shortened period of ultrasonic vibration to produce an information recording disc having a reduced warp angle.Type: GrantFiled: July 27, 1988Date of Patent: July 24, 1990Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Akira Todo, Toshio Kimura, Takeshi Minoda, Masayoshi Kurisu
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Patent number: 4935463Abstract: The invention is a composition for forming a surface on a suitable substrate comprising(a) a water soluble polymer crosslinkable into a water-insoluble form;(b) a pigment component;(c) silica; and(d) a crosslinking agent.In a preferred embodiment, the polymer is an organic colloid such as polyvinyl alcohol, the pigment component comprises a water dispersible pigment such as titanium dioxide and clay, silica particles have diameters smaller than that of the pigment, and the crosslinking agent comprises a water soluble organic compound containing both an acid and carbonyl group, a water soluble dicarbonyl compound, and a suitable polymerizable resin.Type: GrantFiled: June 15, 1987Date of Patent: June 19, 1990Assignee: Chemco Technologies, Inc.Inventors: Elfriede Stockel, Cynthia L. Buchan
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Patent number: 4879120Abstract: A TiO.sub.2 -containing polycaprolactam contains, based on TiO.sub.2, less than 0.1% by weight of 100.degree. C. water solubles and from 2 to 15% by weight of monomeric caprolactam and oligomers thereof, based on polycaprolactam.Type: GrantFiled: August 25, 1988Date of Patent: November 7, 1989Assignee: BASF AktiengesellschaftInventor: Rudolf Wehr
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Patent number: 4877819Abstract: A process for producing a titanium dioxide containing polyester resin composition from which a white film useful as a reflective photographic support can be prepared is disclosed.Said process is performed by first supplying a polyester resin and titanium dioxide into a continuous kneading extruder, kneading them in molten state, and supplying an additional charge of the polyester resin to give a desired concentration of the titanium dioxide, wherein the first supplied polyester resin has an intrinsic viscosity of at least 0.40, said titanium dioxide having an average particle size of 0.1-0.5 .mu.m and a water content of no more than 0.5% and having been surface-treated with an aluminum compound and/or a silicon compound, and the concentration of titanium dioxide being in the range of 20-70 wt % when kneaded with the polyester resin in molten state.Type: GrantFiled: April 21, 1988Date of Patent: October 31, 1989Assignees: Konica Corporation, Kanebo Ltd.Inventors: Kazuto Kiyohara, Toshiyuki Hagiwara, Takanori Nakadate, Ichiya Harada, Kentaro Noguchi, Shigeru Sakae, Kazuhiro Okuma
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Patent number: 4822833Abstract: Rigid polyvinyl chloride stabilized against the adverse effects of ultraviolet radiation by the addition thereto of effective amounts of 2,2,6,6-tetraalkylpiperidine compound and an organotin carboxylate thermal stabilizer, optionally with reduced amounts of titanium dioxide, organotin mercapto esters and/or organotin mercaptide thermal stabilizers.Type: GrantFiled: February 3, 1988Date of Patent: April 18, 1989Assignee: Ciba-Geigy CorporationInventors: Jean M. Zappia, Gerald A. Capocci
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Patent number: 4771086Abstract: Finely divided water insoluble solid particles free of ionic charges and ranging in size from about 0.01 to several hundred microns or higher, including but not limited to paint pigment particles, are given a generally uniform polymeric encapsulation by admixing such particles in an aqueous reaction medium with a water insoluble monomer polymerizable to form a generally water insoluble polymer free of ionic charges in the presence of a nonionic surface active stabilizing agent, preferably a polyethoxylated alkyl phenol containing at least about eight carbon atoms in the alkyl group thereof and preferably at least about 40-50 ethylene oxide groups per molecule, and polymerization of the monomer is then initiated, usually with heating, with a redox polymerization initiating system which is free of ionic groups and does not decompose to release ionic groups in the reaction medium.Type: GrantFiled: August 22, 1986Date of Patent: September 13, 1988Assignee: Union Carbide CorporationInventor: Robert W. Martin
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Patent number: 4758396Abstract: A process for the preparation of a biaxially stretch-oriented film having at least one opaque layer is described. The opaque layer is composed essentially of propylene polymer and fillers in a quantity of about 10 to 40% by weight, relative to the total weight of propylene polymer and fillers. In production, the granules are melted in a screw extruder, are forced through a die and are formed by cooling to give a preformed film. The preformed film is then stretch-oriented both along the machine direction and transversely perpendicular to the machine direction and is then heat-set. The fillers are added in the form of a masterbatch to the granules of unfilled polymers. The masterbatch should have a filler content of more than about 30% by weight.Type: GrantFiled: September 9, 1986Date of Patent: July 19, 1988Assignee: Hoechst AktiengesellschaftInventors: Guenther Crass, Gunter Schloegl, Lothar Bothe, Herbert Peiffer
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Patent number: 4755551Abstract: An electrodeposition resinous paint composition comprising (a) a modified alkyd resin, (b) a melamine resin, (c) a water-soluble silicone resin and (d) an inorganic filler, in which these components (a), (b), (c) and (d) are contained in the following ratios by weight:[(a)/[(a)+(b)]]=0.4-0.9;[(c)/[(a)+(b)]]=0.01-0.1;and[(d)/[(a)+(b)+(c)]]=0.1-1.0.Type: GrantFiled: July 7, 1987Date of Patent: July 5, 1988Assignee: UBE Industries, Ltd.Inventors: Tsunetomo Nakano, Fumio Sakatani, Mitsushi Taguchi
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Patent number: 4753863Abstract: An improved laser markable material useful for encapsulation of electroic devices is obtained by adding TiO.sub.2 or TiO.sub.2 +CrO.sub.3 to common plastic encapsulants formed from a mixture of a resin+filler+carbon black+mold release agent. When irradiated by a laser, the originally grey material turns bright gold, providing a high contrast durable mark. The material has excellent marking contrast as well as better stability with time and temperature as compared to prior art laser markable encapsulants. Desirable concentrations, in weight percent of the compound, are 1-5% TiO.sub.2 and 0-3% CrO.sub.3, with 1-3%TiO.sub.2 and 0.5-2% CrO.sub.3 being preferred. Carbon black is optional but a concentration in the range 0.1-3% by weight is desirable with 0.5-1% preferred. Improved encapsulation and marking methods and improved devices using this material are described.Type: GrantFiled: November 4, 1986Date of Patent: June 28, 1988Assignee: Motorola Inc.Inventor: Keith G. Spanjer
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Patent number: 4753829Abstract: Automotive coating compositions are disclosed. The compositions comprise a metallic or a metallic-like pigment and a metal oxide pigment, wherein the metal oxide pigment has a particle size of about 20 nm to about 30 nm. The coating compositions exhibit high chromaticity with excellent downflop. The coating compositions also have an opalescent appearance.Type: GrantFiled: November 19, 1986Date of Patent: June 28, 1988Assignee: BASF CorporationInventor: Sol Panush
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Patent number: 4752630Abstract: Composite materials consisting of heat-resistant thermoplastic polymers and metal oxide reinforcing fibers having diameters of less than 1000 nm are prepared by hydrolyzing an organometallic compound, preferably an aluminum alkoxide, in a melt or solution of the thermoplastic under the action of a high shear gradient.Type: GrantFiled: August 29, 1986Date of Patent: June 21, 1988Assignee: BASF AktiengesellschaftInventors: Hans-Josef Sterzel, Michael Portugall
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Patent number: 4748166Abstract: Storage stable, water-free, RTV organopolysiloxane adhesives curable in the presence of water or atmospheric moisture, and comprising a dihydroxydiorganopolysiloxane polymer, fillers, an amine fraction and a curing catalyst, are characterized by incorporation therein of a polyalkoxylated organosilane having the formula:R'.sub.x Si[(OCH.sub.2 CH.sub.2).sub.p OCH.sub.3 ].sub.4-xwherein R' is methyl, vinyl, allyl, methallyl or phenyl, and p and x are each one or two.Type: GrantFiled: May 28, 1986Date of Patent: May 31, 1988Assignee: Rhone-Poulenc IndustriesInventors: Alain Gautier, Bernard Laisney, Michel Letoffe
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Patent number: 4689364Abstract: An improved process for preparing pulverulent coating compositions pigmented with titanium dioxide and based on polyamides having at least ten aliphatically bound carbon atoms per carbonamide group using the precipitation method. The titanium dioxide pigments used are without nucleating effects or only have weak nucleating effects on the polyamide precipitation. The pigments have nucleating effects less than or equal to 3.degree. C. where .DELTA.T=(T.sub.max p)-(T.sub.o). T.sub.max p is the maximum temperature at which precipitation takes place in a solution of polyamide having pigment therein and T.sub.o is the maximum temperature at which precipitation takes place in polyamide solution having no pigment therein.Type: GrantFiled: March 18, 1986Date of Patent: August 25, 1987Assignee: Huls AktiengesellschaftInventors: Salih Mumcu, Hans P. Aurich, Helmut Winzer
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Patent number: 4683253Abstract: The present invention relates to a resin molding compound for sealing electronic parts.In general, electronic parts are sealed in ceramic packages or synthetic resin molding compounds in order to protect them from an external circumstance in the use thereof.In many cases, materials consisting of synthetic resins and inorganic fillers mainly comprising silicon oxide have been used as sealing materials for synthetic resin molding compounds.However, a defect has occurred in that since an infinitesimal quantity of radioactive elements such as uranium and thorium is contained in inorganic fillers, a memory element in electronic parts produces misactions by alpha-rays radiated from radioactive elements according to circumstances and thereby the fidelity of electronic parts is greatly influenced.Type: GrantFiled: February 12, 1986Date of Patent: July 28, 1987Assignee: Risho Kogyo Co., Ltd.Inventors: Yoshifumi Miyake, Sumio Sakka
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Patent number: 4668732Abstract: A polyester composition having an enhanced melt-spinnability and processability and useful for producing polyester fibers having excellent mechanical properties and whiteness, comprises (A) a polyester resin derived from esterification or interesterification and polycondensation of a diol component with an acid component which comprises a terephthalic acid, 0.1 to 20 molar % based on the amount of the terephthalic acid, of a naphthalene dicarboxylic acid compound and/or diphenyl dicarboxylic acid compound, and 0.01 to 20 molar % based on the amount of the terephthalic acid, of a p-hydroxybenzoic acid compound and/or benzoic acid compound and/or 0.005 to 0.15 molar % based on the amount of the terephthalic acid, of at least one member selected from alkali and alkaline earth metal salts of organic carboxylic acids; and (B) 0.01 to 3% based on the weight of the polyester resin (A), of titanium dioxide particles dispersed in the polyester resin (A), having an average size of 0.5 .mu.Type: GrantFiled: May 16, 1986Date of Patent: May 26, 1987Assignee: Teljin LimitedInventors: Masashi Kuno, Kimihiro Ogawa
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Patent number: 4664983Abstract: A polyester composition according to the subject invention is composed of thermoplastic polyesters and the titanium dioxide and/or aluminum oxide having specific particle diameters.The polyester composition provides the molded articles which display reduced warpage.The polyester composition has high plating characteristic and provide superior metal-plated moldings.Type: GrantFiled: January 8, 1985Date of Patent: May 12, 1987Assignee: Toray Industries Inc.Inventors: Kiyokazu Nakamura, Kiichi Kometani, Toshihide Inoue
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Patent number: 4624979Abstract: A method for increasing the heat distortion temperature of certain blends of polyphenylene ether resin and styrene polymers is described in which an admixture is formed of a polyphenylene ether resin and a flame retardant copolymer of styrene and up to 50 percent dibromostyrene. The resulting compositions can be formulated to include one or more additional ingredients and are moldable into articles characterized by good flame retardancy and light stability, as well as a higher heat distortion temperature compared with articles formed from corresponding blends using homopolystyrene or styrene-bromostyrene copolymer.Type: GrantFiled: November 28, 1984Date of Patent: November 25, 1986Assignee: General Electric CompanyInventors: Robert J. Axelrod, Glenn D. Cooper
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Patent number: 4608401Abstract: Finely divided water insoluble solid particles free of ionic charges and ranging in size from about 0.01 to several hundred microns or higher, including but not limited to paint pigment particles, are given a generally uniform polymeric encapsulation by admixing such particles in an aqueous reaction medium with a water insoluble monomer polymerizable to form a generally water insoluble polymer free of ionic charges in the presence of a nonionic surface active stabilizing agent, preferably a polyethoxylated alkyl phenol containing at least about eight carbon atoms in the alkyl group thereof and preferably at least about 40-50 ethylene oxide groups per molecule, and polymerization of the monomer is then initiated, usually with heating, with a redox polymerization initiating system which is free of ionic groups and does not decompose to release ionic groups in the reaction medium.Type: GrantFiled: July 26, 1985Date of Patent: August 26, 1986Assignee: Union Carbide CorporationInventor: Robert W. Martin
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Patent number: 4594211Abstract: A thin polyolefine based film, having a thickness of from about 15 to about 200 microns, which is perfectly non-transparent in spite of its low thickness. The film is composed of polyolefine as a homopolymer, an ethylene-vinyl acetate copolymer, and a pigment filler such as titanium dioxide as rutile, and aluminium powder. Color pigments and dispersing agents may also be present. The film is made by extrusion. It is used for table-clothes, book covers, protective sheets, wallpaper decoration, and, in pleated state, for flowerpot covers.Type: GrantFiled: November 5, 1984Date of Patent: June 10, 1986Inventor: Dietrich Mohnhaupt
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Patent number: 4579894Abstract: Self-extinguishing compositions comprising:(1) from 35.5 to 87% by weight of at least a polyolefin(2) from 5 to 20% by weight of an ammonium polyphosphate(3) from 2 to 20% by weight of polycarbonylpiperazine(4) from 3 to 10% by weight of melamine phosphate(5) from 0.5 to 3% by weight of titanium dioxide(6) from 0 to 1.5% by weight of a compound of formula R--SH wherein R is a radical of imidazole or of uracil.Type: GrantFiled: May 10, 1984Date of Patent: April 1, 1986Assignee: Montedison S.p.A.Inventors: Guido Bertelli, Renato Locatelli
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Patent number: 4554307Abstract: Pigment dispersions contain, as dispersing agent novel water soluble polymers containing acid groups, preferably polyacrylic acid or copolymers of polyacrylic acid with AMPS, having polydispersity below 1.5 and molecular weight in the range about 1,000 to about 5,000.Type: GrantFiled: November 16, 1984Date of Patent: November 19, 1985Assignee: Allied Colloids LimitedInventors: David Farrar, Malcolm Hawe
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Patent number: RE31992Abstract: A reinforced, filled thermoplastic polymer composition, having increased strength and ductility, contains a reinforcement promoter having at least two reactive olefinic double bonds and a positive promoter index, based on the double bond resonance and polarity, and the promoter adsorptivity.Type: GrantFiled: November 29, 1983Date of Patent: September 24, 1985Assignee: Union Carbide CorporationInventors: Fred H. Ancker, Arnold C. Ashcraft, Jr., Martin S. Leung, Audrey Y. Ku
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Patent number: RE34066Abstract: A primer composition usable for steel sheets and plastic sheets in vehicle bodies consists essentially of a component (A) consisting essentially of at least one resin having a glass transition temperature of not higher than -20.degree. C., preferably not lower than -75.degree. C., and an elongation at break of not less than 400%, preferably not greater than 900%, at 20.degree. C. and a component (B) consisting essentially of at least one crosslinking resin, the weight ratio as solid content of (A) to (B) being 70-99:30-1.Type: GrantFiled: May 2, 1990Date of Patent: September 15, 1992Assignee: Nippon Oil & Fats Co., Ltd.Inventors: Shosaku Yamamoto, Kazuo Kakinuma
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Patent number: RE34145Abstract: Finely divided water insoluble solid particles free of ionic charges and ranging in size from about 0.01 to several hundred microns or higher, including but not limited to paint pigment particles, are given a generally uniform polymeric encapsulation by admixing such particles in an aqueous reaction medium with a water insoluble monomer polymerizable to form a generally water insoluble polymer free of ionic charges in the presence of a nonionic surface active stabilizing agent, preferably a polyethoxylated alkyl phenol containing at least about eight carbon atoms in the alkyl group thereof and preferably at least about 40-50 ethylene oxide groups per molecule, and polymerization of the monomer is then initiated, usually with heating, with a redox polymerization initiating system which is free of ionic groups and does not decompose to release ionic groups in the reaction medium.Type: GrantFiled: September 12, 1990Date of Patent: December 15, 1992Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Robert W. Martin