Polyvinyl Alcohol Or Modified Form Thereof Patents (Class 524/503)
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Patent number: 6187861Abstract: A process is provided for preparing crosslinkable binders in the form of the aqueous dispersions by polymerizing vinyl ester-olefin copolymers in the presence of protective colloid, which comprises polymerizing vinyl ester-olefin copolymers having a Tg of less than −10° C. by emulsion polymerization in the presence of a protective colloid based on (meth)acrylate polymers comprising from 80 to 95% by weight, based on the overall weight of the polymer, of acrylates or methacrylates of aliphatic alcohols of 1 to 12 carbon atoms and from 5 to 20% by weight, based on the overall weight of the copolymer, of ethylenically unsaturated monocarboxylic or dicarboxylic acids, the latter copolymer having a glass transition temperature Tg of from 60 to 120° C., and, after the end of polymerization, introducing the crosslinkable groups by reacting the carboxyl groups of the (meth)acrylate polymers with ethylenically unsaturated compounds comprising functions suitable for esterifying the carboxyl group.Type: GrantFiled: April 3, 1999Date of Patent: February 13, 2001Assignee: Wacker Chemie GmbHInventors: Hans-Peter Weitzel, Harald Zeh
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Patent number: 6184266Abstract: Shaped medical devices, e.g. stents, having improved mechanical properties and structural integrity are disclosed. The devices comprise shaped polymeric hydrogels which are both ionically and non-ionically crosslinked and which exhibit improved structural integrity after selective removal of the crosslinking ions. Process for making such devices are also disclosed wherein an ionically crosslinkable polymer is both ionically and non-ionically crosslinked to form a shaped medical device. When implanted in the body, selective in-vivo stripping of the crosslinking ions produces a softer, more flexible implant having improved structural integrity.Type: GrantFiled: February 2, 2000Date of Patent: February 6, 2001Assignee: Scimed Life Systems, Inc.Inventors: John M. Ronan, Samuel A. Thompson
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Patent number: 6177183Abstract: The present invention includes processes and resulting structures for producing a modified polymer having interconnecting channels. The interconnecting channels act as controlled transmission passages through the polymer. A hydrophilic agent is blended into the polymer so that it is distributed within the polymer. In one embodiment, an activation material is blended into the polymer so that the activation material is distributed within the product. The product is solidified so that the hydrophilic agent forms passages in the product through which a desired composition is communicable to the activation material that is entrained within the product. The solidified product may be used to form a desired shaped article such as plug type inserts and liners for closed containers, or it may be formed into a film, sheet, bead or pellet.Type: GrantFiled: September 18, 1998Date of Patent: January 23, 2001Assignee: Capitol Specialty Plastics, Inc.Inventor: Ihab M. Hekal
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Patent number: 6174952Abstract: The present invention includes processes and resulting structures for producing a modified polymer having interconnecting channels. The interconnecting channels act as controlled transmission passages through the polymer. A hydrophilic agent is blended into the polymer so that it is distributed within the polymer. In one embodiment, a water-absorbing material is blended into the polymer so that the water-absorbing material is distributed within the product. The product is solidified so that the hydrophilic agent forms passages in the product through which a desired composition is communicable to the water-absorbing material that is entrained within the product. The solidified product may be used to form a desired shaped article such as plug type inserts and liners for closed containers, or it may be formed into a film, sheet, bead or pellet.Type: GrantFiled: September 18, 1998Date of Patent: January 16, 2001Assignee: Capitol Specialty Plastics, Inc.Inventors: Ihab M. Hekal, Robert S. Langer, Alexander M. Klibanov, Edith Mathiowitz
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Patent number: 6169143Abstract: Polyester composition with improved impact properties, improved oxygen permeability and improved dimensional shrinkage during heating. Impact modifiers are dissolved into a molten polyester to form a eutectic alloy. On slow cooling, the eutectic alloy of the invention freezes to form a mixture of particles of the impact modifier embedded in a matrix of the polyester. By controlling the solidification of the melt, the size and distribution of the precipitates from the melt can be controlled, which allows control of the mechanical properties. The precipitation can also be controlled either by homogenous nucleation or by heterogeneous nucleation through the addition of a nucleating agent or the introduction of a suitable surface for nucleation. The invention also provides a process of manufacturing the above polyester, an article comprising this polyester and a process for making this article.Type: GrantFiled: June 7, 1995Date of Patent: January 2, 2001Assignee: Lawson Mardon Thermaplate CorporationInventors: Edward J. Dalgewicz, III, John Bond, Richard Freundlich
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Patent number: 6162844Abstract: A method of incorporating radiation-absorbing agents (i.e., dyes) into polymeric materials. A preferred method involves crosslinking or polymerizing a polymerizable or crosslinkable material in the presence of a polymeric dye. A preferred product is a tinted contact lens comprising poly(vinyl alcohol). The methods offer advantages in reduced fabrication cycles, reduced extractables, elimination of post-polymerization activation steps, elimination of post-polymerization extraction steps and reduced scrap and costs associated with lens handling.Type: GrantFiled: December 22, 1999Date of Patent: December 19, 2000Assignee: Novartis AGInventors: John Martin Lally, Deborah Jean Mulcahy, Achim Muller, Beat Muller, Bernhard Seiferling, Friedrich Stockinger
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Patent number: 6150448Abstract: A flame retardant including red phosphorus in an amount of 1.5 to 15 parts by weight and an ammonium polyphosphate compound in an amount of 10 to 70 parts by weight, based on 100 parts by weight of the solid content of an aqueous dispersion of an ethylene-vinyl acetate-acrylate copolymer having an ethylene content of 2 to 30 wt %, a vinyl acetate content of 40 to 88 wt %, an acrylate content of 10 to 50 wt % and a resin solid content of 35 to 75 wt %. The flame retardant is useful to flameproof mesh sheets.Type: GrantFiled: December 18, 1998Date of Patent: November 21, 2000Assignees: Kyowa Kabushiki Kaisha, Saiji NozakiInventors: Saiji Nozaki, Kuniaki Kamiya
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Patent number: 6143363Abstract: A composition comprising a water-soluble cationic group-containing high-molecular compound (P1) derived from the reaction of (A) epichlorohydrin and a dialkyl or dialkanol amine, or (B) a glycidyl group-terminated hydrophilic oligomer and a diamine, dialkylamine or dialkanolamine; optionally, a high-molecular compound (P2) having a condensable functional group in a side chain such as alkylolacrylamide-bearing high-molecular compound (E) or hydrolyzable trialkylsilyl group-containing acrylic ester high-molecular compound (F); and a poly(meth)acrylate (P3) is coated onto a substrate and cured by ultraviolet radiation to form a printing medium.Type: GrantFiled: October 26, 1998Date of Patent: November 7, 2000Assignee: Canon Kabushiki KaishaInventors: Hiromichi Noguchi, Masami Ikeda, Makiko Kimura, Masato Katayama, Akio Kashiwazaki, Yoshie Nakata, Yuko Nishioka
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Patent number: 6143810Abstract: The invention relates to a process for preparing a conductive curable moulding compound with reduced electrical surface resistance, comprising mixing together an unsaturated polyester resin, a thermoplastic polymer, a conductive paste and optionally a filler, and is characterized in that the conductive paste is obtained by dispersing conductive pigment particles in a solution of a thermoplastic polymer in a suitable solvent. The invention further relates to the conductive paste itself and to mouldings having reduced surface resistance, obtained therefrom.Type: GrantFiled: March 24, 1999Date of Patent: November 7, 2000Assignee: DSM N.V.Inventors: Dieter Buhl, Heinz Fuerst, Harald Schneider, Jan Visser, Joachim Zwecker
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Patent number: 6139963Abstract: A polyvinyl alcohol hydrogel has a surface layer comprising a net-like structure formed by entanglement of fiber-like articles having a diameter of 0.1 to 50 .mu.m. This gel has a large surface area and high capability of adhering microorganisms and permeating liquid, thereby exhibiting excellent purifying function. Processes for producing the above hydrogel are also provided.Type: GrantFiled: November 20, 1997Date of Patent: October 31, 2000Assignee: Kuraray Co., Ltd.Inventors: Hiroaki Fujii, Masanobu Abe, Keiko Oka
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Patent number: 6140406Abstract: A coating composition for an ink jet recording medium comprises an aqueous suspension of absorptive pigment, a binder, a sizing agent, and a cationic fixing agent. The coating composition combines solids content of greater than 30% with good runnability. The composition may preferably be dispersed at pH values in the range of 4.5 to 7.0. The pigment is preferably a mixture of 75% or more silica gel having a pore volume of 0.5-2.0 cc/g, and 10% or more alumina or alumina hydrate. A method for making down the coating composition includes the sequential steps of dispersing a polyvinyl alcohol binder in water, cooling the binder dispersion, dispersing a sizing agent, and mixing the suspension thoroughly before addition of a cationic fixing agent and pigment.Type: GrantFiled: June 12, 1998Date of Patent: October 31, 2000Assignee: Consolidated Papers, Inc.Inventors: Leonard J. Schliesman, Leland O. Tritz, Karen K. Spreda
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Patent number: 6132870Abstract: A composite including an elastomer of low unsaturation, a coated reinforcing fiber, an adhesive composition that bonds the elastomer to the coated reinforcing fiber including a halogenated polyolefin, a nitroso compound, a maleimide, the maleimide present in an amount of at least 50% by weight of the halogenated polyolefin.Type: GrantFiled: March 27, 1998Date of Patent: October 17, 2000Assignee: Lord CorporationInventors: James R. Halladay, Douglas H. Mowrey, Michael Z. Wang
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Patent number: 6130263Abstract: The present invention includes processes and resulting structures for producing moisture absorbing desiccant entrained polymers. A polymer is caused to assume a molten state, typically by applying heat and melting the polymer. To achieve certain results in the hardened end product, such as rigidity and durability, the polymer normally acts as a moisture barrier in a solidified state, both before and after melting. A desiccating agent is blended into the polymer so that the desiccating agent is distributed within the polymer. A channeling agent is also blended into the polymer so that it is distributed within the polymer. The blending of the components is preferably done before the polymer is caused to assume a molten state. Together, the polymer, desiccating agent and channeling agent create a blended mixture. The mixture is solidified so that the channeling agent forms passages in the mixture through which moisture is communicable to desiccating agent that is entrained within the mixture.Type: GrantFiled: March 5, 1997Date of Patent: October 10, 2000Assignee: Capitol Specialty Plastics, Inc.Inventor: Ihab M. Hekal
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Patent number: 6123871Abstract: Photoluminescence polymers, processes for preparing these novel photoluminescence polymers and methods for their use are provided. The photoluminescence polymers having one or more photoluminescence pigments dispersed in an aqueous solution of polyvinyl alcohol in the ratios from about 2:1 to 1:5 by weight. These novel photoluminescence polymers are moldable, non-toxic, non-radioactive, environmentally safe and have been found to be potent photoluminescence polymers that provide a bright after glow for extended periods of time up to 10 hours or more.Type: GrantFiled: January 11, 1999Date of Patent: September 26, 2000Inventor: Michael Lee Carroll
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Patent number: 6121368Abstract: A silicone composition for preparing a silicone pressure sensitive adhesive, the composition comprising (A) 20 to 55 parts by weight of a polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule; (B) 45 to 80 parts by weight of an organopolysiloxane resin comprising R.sup.3.sub.3 SiO.sub.1/2 units and SiO.sub.4/2 units wherein each R.sup.3 is independently selected from the group consisting of monovalent hydrocarbon and monovalent halogenated hydrocarbon groups, the mole ratio of R.sup.3.sub.3 SiO.sub.1/2 units to SiO.sub.4/2 units is from 0.6:1 to 1.Type: GrantFiled: September 7, 1999Date of Patent: September 19, 2000Assignee: Dow Corning CorporationInventors: Michael David Heying, Michael Andrew Lutz, Patricia Kathryn Moline, Michael John Watson
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Patent number: 6121375Abstract: The present invention, which addresses the needs of the prior art, provides irreversible, hydrophilic gels which can be incorporated into dressing compositions, dermatologically compatible compositions, wound packings, wound dressings, burn dressings, drug delivery dressings, dry films, cosmetic masks and cosmetic wrap dressings. The gels of the invention include a blend of a hydrophilic poly(aldehyde) and a polymer selected from the group consisting of a poly(amide), a poly(amine) and a poly(alcohol).Type: GrantFiled: February 11, 1999Date of Patent: September 19, 2000Assignee: Hydromer, Inc.Inventor: Michael Eknoian
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Patent number: 6117933Abstract: A silicone rubber particulate composition useful as an additive for cosmetics, rubbers, resins and paints is disclosed, said composition comprising:(A) a silicone rubber particulate having an average particle size of 0.1 to 1,000 .mu.m;(B) a water-absorptive resin particulate having a water-free average particle size of 0.1 to 1,000 .mu.m; and(C) water,wherein said component (B) is present at a level of 0.01 to 5 weight percent measured on a water-free basis relative to component (A) and said water is present at a level of 10 to 10,000 weight parts for each 100 weight parts of component (B).Type: GrantFiled: June 22, 1999Date of Patent: September 12, 2000Assignee: Dow Corning Toray Silicone Co., Ltd.Inventors: Kouichi Ozaki, Norio Matsuda, Makoto Tanoue, Toyohiko Yamadera, Mitsuo Hamada
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Patent number: 6113811Abstract: A dichroic polarizing film is made, for example, by, first combining polyvinyl alcohol and a second polymer, such as, polyvinyl pyrrolidone or a sulfonated polyester, in a solvent. The ratio of polyvinyl alcohol to second polymer is between about 5:1 to 100:1 by weight. The film is coated on a substrate, dried, and then stretched to orient at least a portion of the film. The film incorporates a dichroic dye material, such as iodine, to form a dichroic polarizer. This polarizer may be used in conjunction with a multilayer optical film, such as a reflective polarizer, to form an optical polarizer. The multilayer optical film may contain two or more sets of polyester films, where at least one of the sets is birefringent and orientable by stretching. The polyvinyl alcohol/second polymer film and the multilayer optical film may be simultaneously stretched to orient both polymer films.Type: GrantFiled: January 13, 1998Date of Patent: September 5, 2000Assignee: 3M Innovative Properties CompanyInventors: William L. Kausch, Brian H. Williams, William W. Merrill
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Patent number: 6107401Abstract: This invention relates to a process for producing an aminoalkylal derivative of polymer containing a plurality of polymerized vinyl alcohol units which are vicinal, preferably a process for producing the 4-aminobutyral of poly(vinyl alcohol). The improved process for the amino-acetalization of such polymers described herein comprises reacting a 5 of 6 member cyclic imine of the structure ##STR1## wherein n is an integer from 3 to 4 with the polymer containing a plurality of polymerized vinyl alcohol units. In a preferred reaction, 1,2-pyrroline is reacted with the polymer containing polymerized vinyl alcohol units under acidic conditions. Preferably the reaction is carried out by a slurry phase process employing a non solvent carrier such as methanol for the poly(vinyl alcohol). The reaction scheme for preparing the 4-aminobutyral of poly(vinyl alcohol) may be characterized by the following equation.Type: GrantFiled: March 26, 1998Date of Patent: August 22, 2000Assignee: Air Products and Chemicals, Inc.Inventors: Gregory Paul Dado, Kevin Rodney Lassila, Kenneth Merle Kem
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Patent number: 6103388Abstract: The use of up to about 20 parts by weight of an organic solvent selected from the group consisting of the water soluble polyalkylene glycol ethers in conventional waterborne packaging and converting adhesives provides comparable or better adhesive products with reduced environmental and health related problems.Type: GrantFiled: January 21, 1998Date of Patent: August 15, 2000Assignee: National Starch and Chemical Investment Holding CorporationInventors: Kristina Babcock, Joseph Wieczorek, Jr.
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Patent number: 6090868Abstract: A process is provided for treating mineral hydraulically or non-hydraulically setting coating agent and binder compositions using water-redispersible powders wherein one or more organopolymer powders and one or more organosilicon powders are added to the dry coating agent and binder composition.Type: GrantFiled: May 13, 1998Date of Patent: July 18, 2000Assignee: Wacker-Chemie GmbHInventors: Herbert Eck, Peter Ball, Reiner Figge
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Patent number: 6077904Abstract: Polyester composition with improved impact properties, improved oxygen permeability and improved dimensional shrinkage during heating. Impact modifiers are dissolved into a molten polyester to form a eutectic alloy. On slow cooling, the eutectic alloy of the invention freezes to form a mixture of particles of the impact modifier embedded in a matrix of the polyester. By controlling the solidification of the melt, the size and distribution of the precipitates from the melt can be controlled, which allows control of the mechanical properties. The precipitation can also be controlled either by homogenous nucleation or by heterogeneous nucleation through the addition of a nucleating agent or the introduction of a suitable surface for nucleation. The invention also provides a process of manufacturing the above polyester, an article comprising this polyester and a process for making this article.Type: GrantFiled: July 17, 1992Date of Patent: June 20, 2000Assignee: Lawson Mardon Thermaplate CorporationInventors: Edward J. Dalgewicz, III, John Bond, Richard Freundlich
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Patent number: 6074761Abstract: A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of ammonium groups, (2) first cationic addition polymer consisting essentially of quaternary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, and (3) second cationic addition polymer consisting essentially of secondary, tertiary, or both secondary and tertiary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble filler particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of coating.Type: GrantFiled: June 13, 1997Date of Patent: June 13, 2000Assignee: PPG Industries Ohio, Inc.Inventors: Alan E. Wang, Louis J. Nehmsmann, Suk H. Cho, Robert H. Tang, William C. Allison
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Patent number: 6063865Abstract: A crosslinkable powder composition is provided which is redispersible in water and comprisesa) from 30 to 95 parts by weight of one or more water-insoluble, film-forming polymers of free-radically polymerizable, ethylenically unsaturated monomers, where from 0.5 to 10% by weight of the monomers, based on the total weight of the polymer a), are ones having one or more substituents selected from the group consisting of aldehyde, keto, epoxide, isocyanate, carboxylic anhydride and aziridine groups,b) from 5 to 70 parts by weight of one or more water-soluble, film-forming polymers, where the parts by weight of a) and b) add up to 100 parts by weight, andc) one or more compounds containing at least two functional groups which are present in salt form and are selected from the group consisting of amines, hydrazides, hydroxylamine esters, aryl- and alkylhydrazines or -hydrazones.Type: GrantFiled: July 30, 1998Date of Patent: May 16, 2000Assignee: Wacker-Chemie GmbHInventors: Peter Ball, Herbert Eck
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Patent number: 6054523Abstract: Aqueous dispersions of organopolysiloxanes comprising (A) an organopolysiloxane containing groups which are capable of condensation, (B) a condensation catalyst, (C) an organopolysiloxane resin which is at least partly soluble in organopolysiloxane (A) when present in amounts of up to 50% by weight based on the weight of (A), (D) a compound containing basic nitrogen and (E) polyvinyl alcohol. The aqueous dispersions are prepared by dissolving the organopolysiloxane resin (C) in the organopolysiloxane (A) and then emulsifying the solution with polyvinyl alcohol (E) and water. The stable aqueous dispersions of the present invention cure to form transparent films.Type: GrantFiled: November 15, 1994Date of Patent: April 25, 2000Assignee: Wacker-Chemie GmbHInventors: Rudolf Braun, Karl Braunsperger, Herbert Sollradl, Stefan Oberneder, Robert Braunsperger
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Patent number: 6054519Abstract: Polyvinyl alcohol compositions in the form of an aqueous solution are disclosed, where the aqueous polyvinyl alcohol compositions include: (i) polyvinyl alcohol; (ii) at least one polyaldehyde having at least 3 carbon atoms and being masked completely as a water-soluble hydrogen sulfite adduct; and (ii) at least one compound which is acidic in water. The aqueous polyvinyl alcohol compositions are suitable as adhesives and for use in cast films.Type: GrantFiled: September 5, 1997Date of Patent: April 25, 2000Assignee: Clariant GmbHInventors: Martin Jakob, Richard Gutte
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Patent number: 6048938Abstract: A method for producing creped paper products comprising applying to a drying surface, a film-forming semi-crystalline polymer and a non-thermosetting cationic resin containing no secondary amine. The invention also comprises a method for producing creped paper products comprising applying to a drying surface a film-forming semi-crystalline polymer, a non-thermosetting cationic resin containing no secondary amines and an optional plasticizer.Type: GrantFiled: March 31, 1999Date of Patent: April 11, 2000Assignee: The Procter & Gamble CompanyInventors: Charles William Neal, Lois Jean Forde-Kohler, Donald Arthur Salsman
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Patent number: 6045726Abstract: A fire suppressant composition is provided which exhibits a low pressure and low flame temperature. The composition comprises ammonium nitrate and a guanidine salt or derivative which produces greater than 3 moles of inert gas per 100 grams of composition and alkali metal or alkaline earth salts for flame suppression. The composition may also include iron or iron oxide.Type: GrantFiled: July 2, 1998Date of Patent: April 4, 2000Assignee: Atlantic Research CorporationInventors: Edna M. Williams, Brian K. Wheatley, Jamie B. Neidert, Robert D. Lynch, James D. Martin
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Patent number: 6025111Abstract: The present invention describes an aqueous coating composition useful in an imaging element which includes polymeric matte beads, an ionic surfactant and a dispersant selected from the group of polymers represented by the generic structures shown below ##STR1## wherein A comprises up to 150 repeat units of ethylene oxide, B comprises 3 to about 100 repeat units of a propylene oxide or higher alkylene oxide or combinations thereof, Q represents a multivalent linking group, x represents 1 or 2 and z represents 1 or 2.Type: GrantFiled: October 23, 1996Date of Patent: February 15, 2000Assignee: Eastman Kodak CompanyInventors: Brian A. Schell, Mridula Nair
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Patent number: 6017979Abstract: To control the orientation of curative groups in an elastomer formulation, in order to maximize the properties obtained in the vulcanized elastomer, cure accelerators are deposited on the surface of a fiber. This method results in a fiber type orientation of crosslink sites in an elastomer matrix, resulting in enhanced modulus properties. An added benefit of the method is the chemical attachment of the fiber to the elastomer formulation, which also results in enhanced modulus properties.Type: GrantFiled: May 3, 1993Date of Patent: January 25, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Bruce Raymond Hahn, Douglas David Callander
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Patent number: 6011115Abstract: A thermoplastic resin composition comprising 50 to 85 parts by weight of an ethylene-vinyl alcohol copolymer, 10 to 40 parts by weight of an ionomer of ethylene-unsaturated carboxylic acid copolymer containing about 5 to 12 mole % of unsaturated carboxylic acid, and 1 to 25 parts by weight of a polyamide and a packaging material comprising said resin composition are provided. The resin composition is excellent in gas barrier property, impact resistance, pinhole resistance, stretchability, drawability and transparency and is preferably used for packaging material.Type: GrantFiled: September 2, 1997Date of Patent: January 4, 2000Assignee: DuPont-Mitsui Polychemicals Co. Ltd.Inventors: Kenji Miharu, Hitoshi Tachino
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Patent number: 6008281Abstract: A powder injection molding composition or feedstock is made of 70% or more by weight of a powdered metal or ceramic and 30% or less by weight of a binder system. The binder system contains a sufficient amount of polypropylene or polyethylene to hold the so-called brown preform of the molded metal or ceramic powder together for the sintering step of the injection molding process and a sufficient amount of partially hydrolyzed cold water soluble polyvinyl alcohol water and plasticizer to facilitate molding of the composition into the so- called green preform of the article to be manufactured. The debinding step of the injection molding process for transforming the green preform into the brown preform consists simply of immersing the green preform in water at ambient temperature to dissolve the polyvinyl alcohol. The binder system is nonhazardous, safe, harmless and fully degradable.Type: GrantFiled: March 9, 1999Date of Patent: December 28, 1999Assignee: Planet Polymer Technologies, Inc.Inventors: Xiaoming Yang, Robert J. Petcavich
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Patent number: 6001903Abstract: There is disclosed a synthetic resin powder comprising a polymer made from an ethylenically unsaturated monomer or a diolefinic monomer and a polyvinyl alcohol chemically bonded through a sulfide bond at an end thereof to the surface of a particle of the polymer. Although the synthetic resin powder of the present invention can be in the form of powder during transportation, it can easily be dispersed in water by adding water thereto under stirring, because it is excellent in dispersibility in water and blocking resistance. The synthetic resin powder is excellent also in film forming properties, and thus can preferably be used as an admixture for a mortar, etc.Type: GrantFiled: September 13, 1996Date of Patent: December 14, 1999Assignee: Kuraray Co., Ltd.Inventors: Masato Nakamae, Toshiaki Sato
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Patent number: 5994449Abstract: Disclosed are resin compositions that are the reaction product of epihalohydrin with a mixture of polyaminoamide and vinyl amine polymer containing a minimum of about 1 mole % vinyl amine monomer units, wherein said polyaminoamide comprises the reaction product of dicarboxylic acid, or a derivative thereof, with polyamine selected from the group consisting of methyl bis(3-aminopropyl)amine and polyalkylenepolyamine containing from two to four alkylene groups having two to four carbons, two primary amine groups, and one to three secondary amine groups. Also disclosed are a process for creping fibrous webs utilizing the resin compositions, and creped paper prepared by the process. Also disclosed is wet and dry strength paper containing the resin compositions and processes for creping fibrous webs utilizing the resin compositions as creping adhesives.Type: GrantFiled: January 23, 1997Date of Patent: November 30, 1999Assignee: Hercules IncorporatedInventor: William Walter Maslanka
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Patent number: 5989701Abstract: The invention relates to a recording material for the inkjet process, having a sheet-like substrate layer and at least one porous recording layer which is arranged on at least one side of the substrate layer and contains a binder combination comprising a film-forming plastics dispersion and a film-forming water-soluble polymer and from 30 to 90 k by weight, based on the dry recording layer, of an organic pigment which consists of porous particles or of primary particles which form porous agglomerates and has a mean pore diameter of from 0.1 to 0.5 .mu.m, an internal pore volume of from 1.0 to 4.0 cm.sup.3 /g, an oil absorption (DBP) of from 200 to 350 ml/100 g and a mean diameter of the porous particles or of the porous agglomerates of from 1 to 30 .mu.m, the ratio of pigment to binder being from 0.5:1 to 2:1. The recording material is particularly suitable for use with pigmented ink.Type: GrantFiled: September 23, 1997Date of Patent: November 23, 1999Assignee: Sihl GmbHInventors: Klaus Goetzen, Axel Niemoeller
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Patent number: 5990205Abstract: The invention is directed to a cross-linked gel-like polyvinyl-based composition of matter having unique elasticity. The composition is capable of being used as a kneading compound, as well as being moldable, stretchable, and bouncing, for use in play activities. The composition is based on a cohesive polyvinyl alcohol/polyvinyl pyrrolidone nonadhesive and substantially nondrying binder composition that is appropriate for child use. The invention is also directed to a method of making the instant polyvinyl-based composition of matter.Type: GrantFiled: August 18, 1997Date of Patent: November 23, 1999Assignee: Mattel, Inc.Inventor: Abimael Cordova
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Patent number: 5989687Abstract: A printing medium comprising a substrate having at least one surface and a coating adhered to the surface wherein the coating comprises (a) binder comprising film-forming organic polymer, and (b) the polymerization reaction product of the hydrolyzate of an aluminum alkoxide and an organoalkoxysilane.Type: GrantFiled: December 9, 1997Date of Patent: November 23, 1999Assignee: PPG Industries Ohio, Inc.Inventor: Huawen Li
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Patent number: 5981645Abstract: A creping adhesive is described which provides the ability to readily control glass transition temperature (Tg) and adhesion and which can be easily removed from dryer surfaces. The creping adhesive contains a crosslinkable polymer and preferably an ionic crosslinking agent such as metal cations having a valence of three or more.Type: GrantFiled: September 22, 1994Date of Patent: November 9, 1999Assignee: James River Corporation of VirginiaInventors: David Henry Hollenberg, Phuong Van Luu, Stephen Risley Collins
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Patent number: 5981646Abstract: The invention relates to an aqueous polyvinyl alcohol/polyvinyl acetate-based composition which can be applied to a cured rubber surface, such as the white sidewall of a tire, to provide a protective coating against staining and scuffing. Preferably, the aqueous composition includes a polysiloxane agent for increasing the scuff resistance and high humidity resistance.Type: GrantFiled: March 11, 1998Date of Patent: November 9, 1999Assignees: The Goodyear Tire & Rubber Company, Quality Manufacturing IncorporatedInventors: Mortimer Joseph Huber, Bharat Kanchanlal Kansupada, Fredrick Lewis Magnus
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Patent number: 5977230Abstract: A powder injection molding composition or feedstock is made of 70% or more by weight of a powdered metal or ceramic and 30% or less by weight of a binder system. The binder system contains a sufficient amount of polypropylene or polyethylene to hold the so-called brown preform of the molded metal or ceramic powder together for the sintering step of the injection molding process and a sufficient amount of partially hydrolyzed cold water soluble polyvinyl alcohol, water and plasticizer to facilitate molding of the composition into the so-called green preform of the article to be manufactured. The debinding step of the injection molding process for transforming the green preform into the brown preform consists simply of immersing the green preform in water at ambient temperature to dissolve the polyvinyl alcohol. The binder system is nonhazardous, safe, harmless and fully degradable.Type: GrantFiled: January 13, 1998Date of Patent: November 2, 1999Assignee: Planet Polymer Technologies, Inc.Inventors: Xiaoming Yang, Robert J. Petcavich
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Patent number: 5977236Abstract: Disclosed are improved vinyl acetate/ethylene copolymers emulsion polymerized in the presence of colloidal, nonionic, water dispersible polyurethanes. The improvement resides in vinyl acetate and ethylene polymerized in the presence of a costabilizer comprising the colloidal, nonionic, water dispersible polyurethanes and polyvinyl alcohol.Type: GrantFiled: April 18, 1997Date of Patent: November 2, 1999Assignee: Air Products and Chemicals, Inc.Inventors: Frank Vito DiStefano, Bruce Alan Gruber
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Patent number: 5959029Abstract: The invention relates to a chemical composition containing a) a copolymer based on styrene and/or at least one alkyl (meth)acrylate, the quantity of styrene and/or alkyl (meth)acrylate being .gtoreq.50% by weight, based on the total monomers, and at least one further comonomer, and b) a water-soluble polymeric protective colloid, wherein about 2 to 30 parts per weight of the water-soluble polymeric protective colloid are allotted to 100 parts by weight of the copolymer, and c) optional further additives as required. The copolymer contains appoximately 0.1 to 50% by weight units of an epoxide-group-containing ethylenically unsaturated comonomer. Such units show reactive epoxide groups. The invention relates further to an aqueous polymer dispersion of said chemical composition, the production of same and a special method for obtaining the chemical composition from the polymer dispersion and special applications of the aqueous polymer dispersion and the chemical composition.Type: GrantFiled: August 18, 1997Date of Patent: September 28, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Robert Koelliker, Harald Bachler
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Patent number: 5948848Abstract: A process of preparing biodegradable plastics material comprising 1) mixing a stabilizer such as an amide or metal salt with a partially hydrolyzed, water-soluble polyvinyl alcohol (PVA) copolymer, 2) adding a plasticizer to the mixture, 3) mixing said materials in the temperature range of between 106 and 140 C. and 4) compounding the blend by known processes.Type: GrantFiled: March 6, 1998Date of Patent: September 7, 1999Assignee: Solplax LimitedInventor: Bayan Oleg Thadius Giltsoff
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Patent number: 5939467Abstract: The present invention relates to polymeric compositions that are biodegradable and that can be melt processed into various forms, including films, fibers, and nonwovens. The compositions include compatible or semicompatible blends of biodegradable polymers and have physical and thermomechanical integrity. Films formed from preferred polymeric compositions are suitable for use as backsheets in disposable absorbent articles. In a preferred embodiment, the polymeric composition includes a polyhydroxyalkanoate and at least one other biodegradable polymer selected from aliphatic polyester-based polyurethanes, a polylactide, polycaprolactone, or a mixture of two or more of these polymers. Where the second polymer is polycaprolactone, the composition preferably also includes a third polymer for enhancing the melt processability of the composition.Type: GrantFiled: September 16, 1994Date of Patent: August 17, 1999Assignee: The Procter & Gamble CompanyInventors: Andrew Julian Wnuk, David Harry Melik, Terrill Alan Young
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Patent number: 5932647Abstract: A wood glue powder which is easily dispersible in water is provided having improved bond strength, thermal stability and rapid setting properties and is prepared by mixing aqueous dispersions, prepared by emulsion polymerization technique of:a) from 70 to 90% by weight of one or more vinyl ester homopolymers or vinyl ester copolymers of vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 18 carbon atoms, withb) from 10 to 30% by weight of one or more fully hydrolyzed vinyl alcohol homopolymers or vinyl alcohol copolymers having a degree of hydrolysis of from 96 to 100 mol % and a Hoppler viscosity of from 2 to 15 mPa.s, measured in 4% strength aqueous solution, based in each case on the overall weight of the polymeric constituents a) and b), and if desired, with further additives and then spray drying the mixture.Type: GrantFiled: January 22, 1997Date of Patent: August 3, 1999Assignee: Wacker - Chemie GmbHInventors: Bernd Schilling, Reiner Figge, Manfred Selig
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Patent number: 5922119Abstract: The invention is directed to the use of an aqueous protective coating composition containing a binder system and an associative thickener for industrial coatings. The associative thickener is not a polyurethane thickener and is selected so that its concentration required by the specific application method is below the critical concentration C*, defined as the thickener concentration at which the coils of the thickener polymer start to overlap of entangle calculated according to the Mark Houwink equation.Type: GrantFiled: March 27, 1998Date of Patent: July 13, 1999Assignee: Hercules IncorporatedInventor: Kroon Gijsbert
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Patent number: 5922124Abstract: An additive for, a method of adding thereof to uncured mixes for and resulting cured cement-type concreations such as cured embodiments of concrete, marcadam, and roof-top shingles each exhibiting improved heat and freeze-thaw durability resulting from reduced efflorescence and stability against sun ultraviolet light exposure.Type: GrantFiled: September 12, 1997Date of Patent: July 13, 1999Inventor: William W. Supplee
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Patent number: 5908886Abstract: Disclosed are a method for restoring a water-soluble quenching medium being used, of which the cooling characteristics have been deteriorated during use, to its original condition to have nearly the original cooling characteristics which the fresh medium has before use, and a water-soluble quenching medium thus restored to its original condition to have nearly the original cooling characteristics thereof. The method comprises adding to a quenching bath being used an aqueous solution comprising a water-soluble polymer (B) that has a larger weight average molecular weight than that of the water-soluble polymer (A) existing in the fresh water-soluble quenching medium to be in the fresh bath.Type: GrantFiled: February 4, 1997Date of Patent: June 1, 1999Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hitoshi Uchida, Eiichi Nakamura
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Patent number: 5907011Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.Type: GrantFiled: March 31, 1997Date of Patent: May 25, 1999Assignee: Clariant GmbHInventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
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Patent number: RE37023Abstract: The invention is directed to a stable phenolic dispersion of hydrophilic phenolic resin polymer using polyvinyl alcohol as protective colloid. Incorporation of a small proportion of an etherified bisphenol-A resin into an aqueous solution of a phenolic resin and a protective colloid (e.g., polyvinyl alcohol) forms a stable dispersion with low volatile organics content.Type: GrantFiled: February 9, 1999Date of Patent: January 16, 2001Assignee: Georgia-Pacific Resins, IncInventors: Ken A. Bourlier, Peggy S. Mulrenin